Safe Handling of Polyisocyanates in Spray Application July 2011 version.
Polyisocyanates and Prepolymers
Transcript of Polyisocyanates and Prepolymers
Polyisocyanates and Prepolymers
3Polyisocyanates and Prepolymers
Contents 5 Building a circular future, together
6 Efficiencymeetssustainability
8 Grades with shining properties
9 Desmodur® ultra/Bayhydur® ultra Setting new standards in industrial hygiene
10 Desmodur® N family HDI trimer
11 Blulogiq® Smart for several applications
12 Desmodur® N family HDIbiuret
13 Desmodur® N family HDI specialties
14 Desmodur®/Desmodur® ultra Aliphatic polyisocyanates
15 Desmodur® Z family IPDI-basedcrosslinkers
16 Desmodur® eco N family/ Bayhydur® eco family PDI-basedcrosslinker
17 Desmodur®/Bayhydur® eco family PDI-basedcrosslinker
18 Bayhydur® family Hydrophilic-modifiedpolyurethanehardener
20 Bayhydur®/Bayhydur® ultra Aliphatic, hydrophilic polyisocyanates
21 Desmodur® D family and hardeners for latent-reactive adhesives Hydrophilic-modifiedpolyurethanehardener/ Hardeners for latent-reactive adhesives
22 Desmodur® BL family Thermally activated polyurethane hardener
24 Bayhydur® BL and Baybond® XL family Thermally activated polyurethane hardener and waterbornecarbodiimidecrosslinker
25 Bayhytherm®/Desmotherm® Self-crosslinkingurethaneresin
26 Crelan® family Powder hardeners
27 Desmocap® BlockedTDIprepolymers
28 Desmodur® R family
29 Desmodur® L family TDI-andTDI-/HDI-basedcrosslinkers
30 Desmodur® monomers Aliphatic diisocyanates
31 Desmodur® monomers Monomeric TDI and MDI products
32 Desmodur® polymeric MDI products (pMDI) For adhesives
33 Desmodur® polymeric MDI products (pMDI) Forcoatingsandmembranes
34 Desmodur® aliphatic prepolymers HDI-based/IPDI-based
35 Desmodur® aromatic prepolymers PrepolymersbasedonTDI
37 Desmodur® and Desmoseal® M PrepolymersbasedonMDI
39 Desmoseal® S family Silane-terminated polyurethanes
40 Legend
41 Fast-lane access to polyurethane innovations
5Polyisocyanates and Prepolymers
The demand for more circular solutions is rising at a fasterpacethaneverbeforeasthe world collectively strivestotackletoday’sglobalchallenges.Climatechange, populationgrowth,urbanization,digitalizationandmobilityarepushingplayersfrom every sector to findmoresustainablesolutionsandlaythefoundationsforclimateneutralitybydrivingaCircularEconomy.Thechallenge is not only to create these circular solutions butalsotomaintainquality,durabilityandproductivity.
Innovationiskeytosatisfyingthesedemandsandcreating added value for customers, society and the environmentbyturningtargetsintorealities.At Covestro,ourlong-standingexpertiseinaliphaticandaromatic polyisocyanates andmoresustainableresinsgoes hand-in-hand with our purpose of constantly pushingboundariesinthesearchforfuture-oriented
solutions.Throughjointsolutions, alternative raw materials,innovativerecycling,andharnessingrenewableenergy,we’reenablingcoatingsandadhesivesproducerstomeetthecircularchallenge,hereandnow.
We’reexpandingourportfoliotoincludebio-basedorrecycled raw materials in coatings, adhesives, and specialtyareasrangingfromcosmeticstotextilesto3D printing.Thankstoourmassbalancingapproach,we’rehelpingclosetheloopbygraduallyreplacingfossilfuelswithISCC-certifiedrenewableresources.Ourdrop-insolutionsensurethehighquality,consistentperformanceandeasyprocessingthatkeepyourproductionrunningsmoothly.Andwe’reconstantlyworkingtoprovidetheglobalsupport,facilitiesandsupplychainsecurityyouneed to forge yet more circular innovations in infrastructure,automotive,furnitureandmore.
Material solutions can help turn circular targets into realities.Let’smaketheworldabrighterplace,together.
Buildingacircularfuture,together.
6Polyisocyanates and Prepolymers
Efficiencymeetssustainability.Solutions to enhance your process efficiencyNowadays,thequalitystandardsmadeonindustrialprocessesareveryhigh.Thisisequallytrueofthecost-cuttingrequirements.However,bothgoalscanbeachievedbyincreasingprocessefficiency.AtCovestro, we have a wide range of solutions designed to enhance your process efficiency.Whynottakeadvantageofourknow-how?Thesesolutions willbenefityourbottomline.
SustainabilitySustainabilityisattheheartoftheCovestrostrategy.Weinspireinnovation anddrivegrowththroughprofitableproductsandtechnologiesthatbenefit societyandreducetheimpactontheenvironment.
Ourcoatings,adhesivesandspecialtyproductsandsolutionscontributetosustainabilitythrough:
• Saving energy – fast and smart Polyurethanesystemsrepresentabenchmarkinproductivityandprocessefficiencyinmanyindustries.Westrivetofurtherpushthelimitsofefficiencybydevelopinggame-changingnewsolutions.
• Reducing waste Weoffersolutionssuchasinnovative1Ktechnologiesthatenableourvaluechainpartnerstousematerialsmoreefficientlyandreducewaste.
• Cutting emissions Bayhydur® and Desmodur®gradesarekeyenablersforlow-emissionsolutionsinthe coatingsandadhesivesindustries–waterborneandhighsolids/100%solids!
• Responsible management of natural resources HighlydurablePU-basedcoatingsandadhesivessignificantlyextendthelifetimeof acoatedproductandthushelptoprolongresourceuse.
• Closing the loop (circularity) Througheconomicallyviableproductsmadefrompartlybio-basedrawmaterials–withno deterioration in performance – we help our customers and value chain partners to reduce theircarbonfootprintandoffersolutionsthatincorporaterenewablebuildingblocks.
• Food contact Anyinformationaboutfoodordrinkingwatercontactforproductsexclusively refers to the regulationquotedinthetable:pleaserequestaDeclarationofCompliancebeforeuse.Foranyuseswhichrequirecompliancewithanotherjurisdictionornationallegislation,theappropriatelegalassessmentneedstobeperformedpriortoanyapplicationofaproductinthefield.
8Polyisocyanates and Prepolymers
Pioneering polyurethane chemistryEversinceOttoBayer’sdiscoveryofthepolyisocyanate-polyaddition process in 1937, Bayer–nowCovestro–haspioneeredpolyurethanechemistry.70yearsago,ourcompanydevelopedthefirstapplicationsusingpolyisocyanatesforthecoatingsandadhesivessectors.Weworkclosely with our customers to systematically advance thestateoftheartinpolyurethanetechnology. Usingmarket-orientedresearchanddevelopment, wespecificallyadaptourproductportfoliotoourcustomers’increasinglystringentrequirements.Together with you, we want to continue our successful journeyalongthispath.
Wide variety of applicationsOurpolyisocyanatescompriseabroadrangeofproductsforone-andtwo-component(1K/2K)polyurethanesystemsusedinnumerousapplications.Whetherascrosslinkersfor2Kpolyurethanecoatingsandadhesives,blockedpolyisocyanatesfor1Kpolyurethanebakingcoatingsorhydrophilizedpolyisocyanatesascrosslinkersforwater-reduciblepoly urethane systems, our products come into play wherevercrosslinkingisusedtoachievehighresistancesandreliableadhesionunderefficientconditions.Oursolutionsareinusetodayinavarietyofapplications,suchasautomotiveOEMs,automotiverefinishingandcoatingsforwood,industrialgoodsandplastics.Theyarealsousedinreactiveadhesives,textilecoatingsandanticorrosioncoatings.
CustomizedpropertiesGloss,leveling,scratchresistance,hardnessandflexibilitycanbepreciselyadjustedbythechoiceofpolyisocyanateandpolyol.Chemicalresistance,adhesion,lightfastnessandweatherstabilityareadditionalpropertiesthatcanbeindividuallyadaptedtoyourspecificrequirements.Moreover,coatingswitheasy-to-clean,soft-touchorreflowpropertiescanalsobeproducedthroughsmartformulations.
FlexibilityinprepolymersOurproductrangeofprepolymerscomprisesaromaticandaliphaticNCO-andsilane-terminatedproducts.Theseprepolymersmakeawiderangeofpropertiespossibleincoatings,adhesivesandsealants.Thetypical areas of application include wood coatings, corrosion protection, floorcoatings,elasticadhesivesintransportation,parquetadhesives,engineeredwoodconstructions,flexiblefilmlaminationandsealants.
Grades with shining properties.
9Polyisocyanates and Prepolymers
Safeguardyourbusinessbyofferinganimprovedindustrialhygienestandardwith<0.1%residualmonomercontent.
Desmodur® ultra / Bayhydur® ultra Setting new standards in industrial hygiene.
Technical drop-in solution with improved industrial hygiene standard Improvedindustrialhygienestandardsareimportantfortheentirevaluechain.Covestrois committedtocontinuallyimprovingproductsandsettingnewstandards,especiallyinthefield ofindustrialhygiene.ThenewUltraLineopensupthepotentialforfurtherincreasingproductsafetythroughacontinuedreductionofthespecifiedresidualmonomercontent.
With our new Covestro Ultra Line we are introducing a product line with the following beneficial features:
• Further improves industrial hygiene standardsthankstoaresidualmonomercontentofbelow0.1%–inlinewiththesafetymeasuresrecommendedinthesafetydatasheets.
• Can be used in the same way as the Desmodur® and Bayhydur® predecessors in your current formulations,soyoucancontinuetofocusonyourcorebusiness.
• Makeseasy-to-use 2K PU technology available.
• State-of-the-art and technically equivalenttoourexistingproducts.
The performance and composition of the Ultra products have not changed in any way – except for their residual monomer content (RMC) specification.
CONVENTIONAL 2K PU
COVESTRO’S ULTRA LINE
High-performance isocyanates technology
Improved industrial hygiene standard
No additional efforts to comply with the proposed isocyanate use restriction*
* TheEUCommissionuserestrictionproposalcameintoforceonAugust24,2020
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Desmodur® N familyHardenersforhigh-performancetwo-componentpolyurethanecoatingswithexcellentweatherabilityand resistanceproperties.Desmodur® ultra qualitiesperformwith<0.1%monomercontent.
HDI trimer
NCOCONTENTONSUPPLYFORMAPPROX.[%]
FUNCTIONALITYAPPROX.
VISCOSITYAT23°CAPPROX.[mPa · s]
EQUIVALENTWEIGHTAPPROX. COMMENTS
Desmodur® blulogiq 3190 BA 90 in BA 700 19.6 214 3.5Thermolatentcrosslinkerforsolvent-borne2KPURsystemswithstandardreactivityatambientconditions butactsasahighlycatalyzedcrosslinkeratelevatedtemperatures.Bakingtemperatureof75°Corhigherrecommended.Especiallyforhigh-glossspraycoatings.
Desmodur® ultra N 3300 100 3,000 21.8 195 3.5 Outstandingweatherstabilityandglossretention,non-yellowing;forautomotiveOEM,automotiverefinish,plasticsandindustrialcoatings,structuralcoatingsandtopcoats.
Desmodur® ultra N 3390 BA/SN 90inBA/SN 550 19.6 215 3.5 Special supply forms of Desmodur® ultra N 3300forautomotiveOEM,automotiverefinish,plasticsand industrialcoatings,structuralcoatingsandtopcoats.Othersupplyformsalsoavailable.
Desmodur® ultra N 3380 BA/SN 80inBA/SN 150 17.4 241 3.5 Special supply forms of Desmodur® ultra N 3300forautomotiveOEM,automotiverefinish,plasticsand industrialcoatings,structuralcoatingsandtopcoats.Othersupplyformsalsoavailable.
Desmodur® ultra N 3368 BA/SN 68inBA/SN 45 14.8 284 3.5 Special supply forms of Desmodur® ultra N 3300forautomotiveOEM,automotiverefinish,plasticsand industrialcoatings,structuralcoatingsandtopcoats.Othersupplyformsalsoavailable.
Desmodur® ultra N 3600 100 1,200 23.0 185 3.2
Low-viscositycrosslinkerforUVstableandgoodglossretentionfor2KPURcoatings(highsolids/waterborne,e.g.,incombinationwithBayhydur®types)forautomotiverefinish,automotiveOEM,construction,corrosionprotection,windenergyandindustrialapplications;alsoforstructuralcoatingsandtopcoats.Recommendableforaliphaticcastsystems.
Desmodur® ultra N 3689 SN 89 in SN 325 20.3 207 3.2 Special supply form of Desmodur® ultra N 3600.Desmodur® ultra N 3700 100 16,000 20.0 210 3.9 100%supplyformbasedonDesmodur® ultra N 3790 BA.Previouslyknownas Desmodur® XP 2675.
Desmodur® ultra N 3790 BA 90 in BA 1,800 17.8 236 3.9 Highfunctionalcrosslinkerforfast-drying,weather-stableandnon-yellowing2KPURcoatingsforautomotiverefinish,industrialapplications,corrosionprotectionandwindenergy.
Desmodur® N 3800 100 6,000 11.0 380 3.8Forhighlyelasticcoatingswithexcellentweatherresistance;combinationwithsuitablepolyisocyanates allowsadjustmentsoftheelasticityusingthesamepolyolmillbase.Especiallysuitableforplasticcoatings,construction,corrosionprotectionandwindenergy.
Desmodur® ultra N 3900 100 730 23.5 180 3.2
Low-viscositycrosslinkerforUVstableandgoodglossretentionfor2KPURcoatings(highsolids/waterborne,e.g.,incombinationwithBayhydur®types)forautomotiverefinish,automotiveOEM,transportationand plasticsfinishingapplications.Recommendableforaliphaticcastsystems,construction,corrosionprotectionandwindenergy.
Desmodur® ultra 2822 55inBA/SN 15 12.0 350 3.5 Special supply forms of Desmodur® ultra N 3300fordifferentapplications.Othersupplyformsalsoavailable.
SUPPLYFORMAPPROX.[%]
NEW
NEW
NEW
11Polyisocyanates and Prepolymers
Blulogiq® Smart for several applications.Fromefficiencytolowtemp–withoutcompromisingappearance.
Blulogiq® technology:TheuniquethermolatenthardenertechnologyinventedbyCovestroadressesseveralneeds,urgenciesandunsolvedproblemsofthecoatingsindustry. Blulogiq® deliversthepossibilitytoimprovelevellingbyseparatingfilmformationfromcrosslinking,andbringsincuring-on-demandpropertiesintoa 2KPUsystem.
Key benefits: • BoostsprocessefficiencyofOEMplasticandmetal applications.
• Quiteslowreactionduringfilmformation– fastcrosslinkingat>75°Cenablesverygoodappearance.
• Crosslinkingspeedat90°Ciscomparabletoa140°Cnoncatalyzedprocess.
• Improvedearlyresistancepropertiesenablebetterpost-processinglike:earlier&easierpolishing,morerobusthandling,lessdamageduringtransport.
• Littleformulationmodificationrequiredfor plastic-applications–justreplacethehardener andconventionalcatalyst.
Exterior plastic coatings for hang-on parts:Speed meets appearance
Thermolatency combined with proven high-performance 2K PU technology
Crosslinking
Time
Blulogiq®Standard CatalyzedH
eat
1
2
3
Auto OEM high-bake line coating:Increaseefficiency&de-bottleneck
Auto OEM low temp line coating:ReducetempafterEDCto<100°C
Electro-depositioncoating
Underbodyprotection
PURBC
2CPURCC
Electro-depositioncoating
Underbodyprotection
PURBC
2CPURCC
140–160°C< 100°C
ON
12Polyisocyanates and Prepolymers
HDI biuret
NCOCONTENTONSUPPLYFORMAPPROX.[%]
FUNCTIONALITYAPPROX.
VISCOSITYAT23°CAPPROX.[mPa · s]
EQUIVALENTWEIGHTAPPROX. COMMENTS
Desmodur® N 100 100 10,000 22.0 190 3.8 Weather-stableandnon-yellowingtopcoats.Verygoodcompatibility withhighlybranchedpolyols.
Desmodur® N 3200 100 2,500 23.0 185 3.5 Lower viscosity than Desmodur® N 100;especiallyforweather-stableandnon-yellowinghighsolidscoatings,structuralcoatingsandtopcoats.
Desmodur® N 75 MPA/X 75inMPA/X 250 16.5 255 3.8Special supply forms of Desmodur® N 100fordifferentapplications. Othersupplyformsavailable.Desmodur® N 75 MPA 75 in MPA 250 16.5 255 3.8
Desmodur® N 75 BA 75 in BA 160 16.5 255 3.8
SUPPLYFORMAPPROX.[%]
Desmodur® N family
13Polyisocyanates and Prepolymers
HDI specialtiesCOMMENTS
Desmodur® 2873 Silanemodifiedpolyisocyanate 100 450 12.3 341 2.0 Silane-modifiedcrosslinkerwithexcellentscratchresistance,highoutdoor
weatheringresistanceinwaterborneandsolventborne2KPUcoatings.
Desmodur® N 3400 Uretdione 100 150 21.8 195 2.5Extremelylow-viscositycrosslinkerforwaterborneandsolventborne2KPURcoatings;alsoformoisture-curing1KPURsystems,fortopcoatsinmany constructionandcorrosionprotectionapplications.
Desmodur® N 3500 Allophanate/ isocyanurate 100 35,000 19.5 215 >5 Highfunctionalcrosslinkerforfastdrying2KPURcoatingswithexcellentscratch
resistanceinvariousautomotiveandindustrialapplications.
Desmodur® N 3580 BA Allophanate/ isocyanurate 80 in BA 500 15.4 273 >5 Highfunctionalcrosslinker,goodweatherability,highglossandimproved
resistance.SpecialsupplyformofDesmodur® N 3500.
Desmodur® N 31000 Uretdione/ isocyanurate 100 500 23.0 185 3.0 Low-viscositycrosslinkerforwaterborneandsolventborne2KPURcoatings;
alsoformoisture-curing1KPURsystems.Previouslyknownas Desmodur® XP 2840.
Desmodur® N 31100 Allophanate 100 500 20.0 215 2.5
Flexible,low-viscositycrosslinkerforweather-stablehighsolidsandwaterborne2KPURcoatings(e.g.,incombinationwithBayhydur® or Desmodur®types), especiallyforindustrial,automotiverefinishing,transportationandplasticcoatings.Recommendableforflexiblealiphaticcastsystemsandconstructioncoatings.PreviouslyknownasDesmodur® XP 2860.
SUPPLYFORMAPPROX.[%]
VISCOSITYAT23°CAPPROX.[mPa · s]TYPE
EQUIVALENTWEIGHTAPPROX.
NCOCONTENTONSUPPLYFORMAPPROX.[%]
FUNCTIONALITYAPPROX.
Desmodur® N family
NEW
NEW
NEW
* Other solventvariations available
** ultra: < 0.1 % residual monomer content
HDI polyisocyanate
IPDI polyisocyanate
HDI/IPDI blend
PDI
Lower viscosityCompatibility
Elasticity,Low viscosity
High elasticity
Fast curing
Thermo-
latent
Lowest viscosity
Low viscosity
Fastest curingSelf healingPartly
bio-based
eco N 7300Blulogiq® 3190
E 30700E 30600N 3800
N 100N 75*
ultra N 3300*ultra N 3390*
ultra N 3700ultra N 3790 BA
N 3500N 3580 BA
Lower viscosity
Blends
Lower viscosityElasticity
Lower viscosity
Elasticity
Fast dryingHardness
NZ 300 ultra NZ 200 ultra Z 4470*
E 40480 MPA Z 4580 BA NZ 486 BA
ultra N 3600
ultra N 3900
N 31000 N 31100N 3400
N 3200
Partly bio-based
14Polyisocyanates and Prepolymers
Desmodur® / Desmodur® ultra** Aliphatic polyisocyanates.
15Polyisocyanates and Prepolymers
IPDI-basedcrosslinkers
COMMENTS
Desmodur® ultra NZ 200 HDI/IPDI isocyanurate 100 22,500 21.0 200 3.2 Goodweatherability,glossandimprovedresistance;especiallyfor100%
solidsapplications,e.g.,in-mouldcoating.PreviouslyknownasDesmodur® XP 2489.
Desmodur® NZ 300 HDI/IPDI isocyanurate 100 3,000 21.0 200 3.0 Crosslinkerforlightfast2KPURsystems;mainlyusedasabinderfor100%
solidsdecorativefloorcoatings.PreviouslyknownasDesmodur® XP 2838.
Desmodur® NZ 486 BA HDI/IPDIallophanate/prepolymer 86 in BA 2,100 10.2 412 3.0
Crosslinkerforweather-stable2KPURandpolyasparticcoatings;longer potlifeandextendedapplicationwindow,reduceddependencyofhumidity withpolyasparticcoatings.Previouslyknownas Desmodur® XP 2763.
Desmodur® ultra Z 4470 BA IPDI isocyanurate 70 in BA 600 11.9 360 3.5 Fast-dryinghardenersforlightfast2KPURcoatingswithhighchemicaland weatheringresistance.ForautomotiveOEM,refinishandindustrialapplications. Due to its high hardness, Desmodur® Zisrecommendedtobecombinedwith Desmodur® Nproducts.Recommendableforcorrosionprotectionandconstructioncoatings.
Desmodur® ultra Z 4470 MPA/X IPDI isocyanurate 70inMPA/X 1,500 11.9 360 3.5
Desmodur® ultra Z 4470 SN IPDI isocyanurate 70 in SN 2,000 11.9 360 3.5
Desmodur® Z 4580 BA IPDI allophanate 80 in BA 2,800 12.0 350 2.5Crosslinkerforweather-stable,fast-dryinghighsolidsandwaterborne2KPURcoatings,e.g.,incombinationwithBayhydur®types,forautomotiverefinishandtransportationapplications.Previouslyknownas Desmodur® XP 2565.
SUPPLYFORMAPPROX.[%]
VISCOSITYAT23°CAPPROX.[mPa · s]TYPE
EQUIVALENTWEIGHTAPPROX.
NCOCONTENTONSUPPLYFORMAPPROX.[%]
FUNCTIONALITYAPPROX.
Desmodur® Z familyFast-dryingtwo-componentpolyurethanecoatingswithhighchemicalresistance.
NEW
NEW
NEW
NEW
16Polyisocyanates and Prepolymers
Desmodur® eco N family / Bayhydur® eco family Partlybio-basedpolyurethanecoatingswithexcellentweatherabilityandresistancebasedonbio-basedpentamethylene diisocyanate (PDI).
• Partly bio-based andsignificantlyimproved carbon footprint cradle-to-gate in comparison to HDI, basedonlife-cycle-assessmentstudiesconductedaccordingtoISO14040/14044standards.
• By using partly bio-basedrawmaterials,theconsumptionoffossilfuelsisreduced.• Atthesametime,therenewablebiomassabsorbsCO2fromtheenvironment.• FurtherCO2savingsthroughfewerprocesssteps.• Forfurtherinformation,pleasegetintouchwithyourCovestrocontactperson.
5
4
3
2
1
0
Potlife
Drying
Compatibility
Pendulum hardness
Biocontent
Scratch resistance
Chemicalresistance
Weathering resistance
Partlybio-basedhardener
Petro-basedhardener
5excellent0bad HDI
HDA
Precursor 2
Precursor 1
Refinery
Crudeoil
4
3
2
1
PDI
PDA fermentation
Bio-refinery
Biomass
2
1
CO2
4-step petro-based synthesis 2-step bio-based synthesis
Comparison of clearcoat film properties
17Polyisocyanates and Prepolymers
PDI-basedcrosslinker
COMMENTS
Desmodur® eco BL 7175 75inSN/MPA 8,500 10.9 385 3.7** 32 Thermallyactivatedpolyurethanehardenerwhichcontainsrenewablecarbonfor1KPUstovingsystems.
Desmodur® eco N 7300 100 9,500 21.5 195 3.7 71
Containsrenewablecarbon.Outstandingweatherstabilityandglossretention,non-yellowing;forautomotiveOEM,automotiverefinish,plasticsandindustrialcoatings,structuralcoatingsandtopcoats.Recommendableforcorrosion protectionandwindenergy.
Bayhydur® eco 701-90 90 in PGDA 5,000 17.9 232 3.6 61 Ionicallymodified(sulfonicacid)crosslinkerforhighestchemicalresistance,easymixingandhighglossfor2KWBcoatingscontainingrenewablecarbon.
SUPPLYFORMAPPROX.[%]
VISCOSITYAT23°CAPPROX.[mPa · s]
EQUIVALENTWEIGHTAPPROX.
BIO-BASEDCONTENTON
SUPPLYFORM[%] APPROX.*
NCOCONTENTONSUPPLY FORMAPPROX.[%]
FUNCTIONALITYAPPROX.
* Basedonresultsof14C/totalCaccordingtoASTMD6866 ** Thermallyactivatedpolyurethanehardener
Desmodur® / Bayhydur® eco family Partlybio-basedpolyurethanecoatingswithexcellentweatherabilityandresistancebasedonbio-basedpentamethylene diisocyanate (PDI).
NEW
18Polyisocyanates and Prepolymers
Bayhydur® ultra 3100 HDI 100 2,800 17.4 240 3.1 Polyether-modified,standard.Versatileandeconomical.
Bayhydur® ultra 304 HDI 100 4,000 18.2 230 3.8 Polyether-modified,versatileuseandimprovedmixing.Excellentwaterandweatheringresistance.
Bayhydur® ultra 305 HDI 100 6,500 16.2 260 4.0 Polyether-modified,easiestmixingandhighgloss.
Bayhydur® ultra 2700 HDI 65 in PGDME 75 10.6 400 4.0 Ready-to-usehardenerbasedonBayhydur® ultra 305,easiestmixingandhighgloss.
Bayhydur® ultra 2487/1 HDI 100 5,400 20.6 205 3.4 Ionicallymodified(sulfonicacid),highestchemicalresistanceandveryfastcuring.
Bayhydur® 2547 HDI 100 650 22.5 185 3.0 Ionicallymodified(sulfonicacid),highestchemicalresistance,lowviscosity, suitablefor100%solidsformulationsandforpurewater-basedformulations.
Bayhydur® ultra 2655 HDI 100 3,500 20.8 205 3.2 Ionicallymodified(sulfonicacid),highestchemicalresistance,easymixing. Indoor-air-qualitycompliantandveryfastcuring.
Thekeytoeasyandreliableapplicationofwaterbornetwo-component polyurethanesystems.Bayhydur® ultraqualitiesperformwith<0.1%monomercontent.
Hydrophilic-modified polyurethane hardener
Bayhydur® family
COMMENTS
SUPPLYFORMAPPROX.[%]
VISCOSITYAT23°CAPPROX.[mPa · s]TYPE
EQUIVALENTWEIGHTAPPROX.
NCOCONTENTONSUPPLYFORMAPPROX.[%]
FUNCTIONALITYAPPROX.
NEW
19Polyisocyanates and Prepolymers
Thekeytoeasyandreliableapplicationofwaterbornetwo-component polyurethanesystems.Bayhydur® ultra qualitiesperformwith<0.1%monomercontent.
Bayhydur® family
Hydrophilic-modified polyurethane hardener
COMMENTS
SUPPLYFORMAPPROX.[%]
VISCOSITYAT23°CAPPROX.[mPa · s]TYPE
EQUIVALENTWEIGHTAPPROX.
NCOCONTENTONSUPPLYFORMAPPROX.[%]
FUNCTIONALITYAPPROX.
Bayhydur® ultra 2858 HDI/IPDI 70 in PGDA 500 13.3 315 3.4 Ionicallymodified(sulfonicacid)ready-to-usehardener,fastdrying,easymixing,highhardness,highchemicalresistanceandlongpotlife.
Bayhydur® ultra 401-70 MPA IPDI 70 in MPA 1,500 9.4 440 2.9 Product contains no intentionally added aromatic solvents (BTXbenzene/toluene/xylene).
Bayhydur® ultra 401-70 MPA/X IPDI 70inMPA/X 600 9.4 440 2.9 Polyether-modified.Higherhardness,longerpotlifeandimprovedblisterfree filmthicknesscomparedtoHDIbasedtypes.
Bayhydur® ultra 2759 IPDI 70 in MPA 6,000 11.0 380 3.1 Ionicallymodified(sulfonicacid),fastdrying,easymixing,highchemicalresistance.
Bayhydur® quix 306-70 HDI/TDI 70 in MPA 250 13.5 311 3.3 Ionicallymodified(sulfonicacid),fastestdryingandhighchemicalresistance,speciallydesignedforwoodcoatings.
NEW
NEW
NEW
NEW
ultra 305
ultra 3100ultra 304
ultra 401-70
ultra 2700
quix 306-70
ultra 2858
ultra 2487/1
eco 701-90
ultra 2759
2547
ultra 2655
Chemical resistanceImproved Best in class
Easy
mix
ing
High gloss with manual stirring
Low shear stirring
Fast drying
Longer potlife
Partly bio-based
Low viscous for neat zero VOC
Ready to use
Best in earlywater resistance
* < 0.1 % residualmonomer content
HDI polyisocyanate
IPDI polyisocyanate
HDI/IPDI blend
HDI/TDI
PDI
20Polyisocyanates and Prepolymers
Bayhydur®/ Bayhydur® ultra*Aliphatic, hydrophilic polyisocyanates.
21Polyisocyanates and Prepolymers
HydrophilichardenerforlargelypH-neutralaqueouspolymerdispersionsinadhesive applications.Desmodur® ultraqualitiesperformwith<0.1%monomercontent.Hardenersforformulationsoflatent-reactivewaterborneadehsivelayersorfilms.
Hydrophilic-modified polyurethane hardener
Hardeners for latent-reactive adhesives
Desmodur® D family and hardeners for latent-reactive adhesives
COMMENTS
COMMENTS
Desmodur® ultra DA-L HDI 100 3,000 20.0 210 CrosslinkingagentsforOH-functionaldispersions,e.g.,polyurethane,polyvinylacetate, polyacrylateorsyntheticrubberdispersions.Improvedresistancetoheat,water,plasticizers andmanysolvents.Desmodur® ultra DN HDI 100 1,250 21.8 195
Desmodur® Z 2589 IPDI Micronizedpowder 65 17.0 250
Aftersuitabledeactivation,Desmodur® Z 2589canbeusedincombinationwithDispercoll® U as a curing component for one-component latent-reactive polyurethane dispersion adhesives, toformulatelatent-reactiveadhesivelayersorfilm.
Dispercoll® BL XP 2514 TDI 40 in water 9.0 465 Dispercoll® BL XP 2514 canbeusedasthecrosslinkingcomponentincombinationwithDispercoll® U toformulateone-component,latent-reactivepolyurethanedispersionadhesives.
SUPPLYFORMAPPROX.[%]
SUPPLYFORMAPPROX.[%]
VISCOSITYAT23°CAPPROX.[mPa · s]
Tg[°C]
TYPE
TYPE
EQUIVALENTWEIGHTAPPROX.
EQUIVALENTWEIGHTAPPROX.
NCOCONTENTONSUPPLYFORMAPPROX.[%]
NCOCONTENTONSUPPLYFORMAPPROX.[%]
22Polyisocyanates and Prepolymers
Solvent-bornegradesfor1KPUstovingsystemswithhigh-performanceproperties.Thealiphaticgradesarelight-stableandweather-resistant.
Thermally activated polyurethane hardener
Desmodur® BL family
COMMENTS
Desmodur® BL 3475 HDI/IPDI DEM 75inSN/BA 1,000 510 8.2/(10.9) Highestreactivity,transesterificationofblockingagent.
Desmodur® BL 3370 HDI DEM/DIPA 70 in MPA 3,800 470 8.9/(12.7) Highestreactivity.Desmodur® PL 340 IPDI DMP 60inBA/SN 600 575 7.3/(12.2) Excellentthermalyellowingresistance,highchemicalresistance.Desmodur® PL 350 HDI DMP 75inSN/MPA 4,300 400 10.5/(14.0) Excellentthermalyellowingresistance,moreflexible.Desmodur® BL 3575/1 HDI DMP 75inSN/MPA 3,600 400 10.5/(14.0) Excellentthermalyellowingresistanceandlowestcolorvalue.
Desmodur® eco BL 7175 PDI DMP 75inSN/MPA 8,500 385 10.9(14.5) Containsrenewablecarbon.Outstandingweatherstabilityandglossretention,excellentthermalyellowingresistance.
Desmodur® BL 3175 HDI MEKO 75 in SN 3,300 380 11.1/(14.8) Standardgrade,flexible.Desmodur® BL 4265 IPDI MEKO 65 in SN 11,000 520 8.1/(12.5) Standardgrade,highchemicalresistance,highhardness.
Desmodur® BL 5375 H12MDI MEKO 75inSN/MPA 4,000 470 8.9/(11.9) Extremelyflexible,asadditiveforstovingsystemstoimproveflexibilityandadhesion.
Desmodur® BL 2078/2 IPDI Ɛ-CAP 60 in SN 1,750 600 7.0/(11.7)Highchemicalresistanceandhardness,realizationofhigh filmthicknesspossible,excellentthermalyellowingresistance; classifiedaccordingFoodContactNotification,FCNNo.695.
Desmodur® BL 3272 HDI Ɛ-CAP 72 in MPA 2,700 410 10.2/(14.2) Flexible,realizationofhighfilmthicknesspossible,excellentthermalyellowingresistance.
Desmodur® BL 1100/1 TDI Ɛ-CAP 100 43,000 1,400 3.0/(3.0)1Kstovingprimerwithgoodstone-chipresistance,highfilmthick-nesspossible;incombinationwithcycloaliphaticdiaminesintendedforcoilcoatingprimer.
Desmodur® BL 1265/1 TDI Ɛ-CAP 65inMPA/X 20,000 875 4.8/(7.4)Hard elastic, intended for primer with good stone-chip resistance, incombinationwithDesmodur® BL 1100/1 for coil coating primer toimprovehardnessandcold-resistance.
SUPPLYFORMAPPROX.[%]TYPE
VISCOSITYAT23°CAPPROX.[mPa · s]
BLOCKINGAGENT
CALCULATEDBLOCKEDNCOCONTENTON
SUPPLYFORMAPPROX.[%]/(ONRESIN[%])
EQUIVALENTWEIGHTAPPROX.
* See page 6
NEW
Desmodur®BL 4265
Desmodur®BL 2078/2
Desmodur®BL 3272
Bayhydur®BL 2781
Bayhydur®BL 2867
Bayhydur®BL XP 2706
Desmodur®BL 3475
Desmodur®BL 3175
Desmodur®BL 5375
Desmodur®BL 1265/1
Desmodur®BL 1100/1
Desmodur®BL 3370
Desmodur®BL 3575/1
Desmodur®PL 350Desmodur®
PL 340
PMT > 180°C10–15 min, 140°C25–30 min, 120°C
PMT > 210°C10–15 min, 160°C30 min, 140°C
PMT
= pe
ak m
etal
tem
pera
ture
PMT > 230°C10–15 min, 180°C30 min, 160°C
PMT > 240°C10–15 min, 200°C30 min, 170°C
High film thickness
Waterborne system
HDI polyisocyanate
TDI Prepolymer
IPDI polyisocyanate
H12MDI polyisocyanateHigh thermo-yellowing resistance
Flexibility
Reac
tivity
Food Contact Notification No. 695 since 2007
Partly bio-based
PDI polyisocyanate
Desmodur®eco BL 7175
23Polyisocyanates and Prepolymers
Desmodur® eco / Desmodur® BL (Solventborne) / Bayhydur® BL (Waterborne) Thermally activated PU hardeners.
24Polyisocyanates and Prepolymers
Waterbornegradesforwater-based1KPUstovingsystemswith high-performancepolyurethaneproperties.Thealiphaticgrades arelight-stableandweather-resistant.
Thermally activated polyurethane hardener
Bayhydur® BL and Baybond® XL family
Waterborne carbodiimide crosslinker
COMMENTS
Bayhydur® BL XP 2706 HDI/IPDI DMP 40 in water < 2,500 1,275 3.3/(8.2) Highreactive,goodchemicalresistance,lowestthermalyellowing,neutralizedwithDMEA.
Bayhydur® BL 2867 HDI DMP 38 in water < 1,500 960 4.4/(11.5) Highreactive,goodchemicalresistance,lowestthermalyellowing,highflexibilityandoutstandingadhesion.
Bayhydur® BL 2781 HDI MEKO 37 in water 4,900 1,200 3.5/(9.5) Highflexibility,goodadhesion.NeutralizedwithDMEA.Baybond® XL 6366 HDI MEKO 45 in water < 200 975 5.6/(12.5) Highsolidcontent,highflexibility.Deblockingtemperatureapprox.150°C.Baybond® XL 1187 HDI MEKO 30 in water < 200 1,450 2.9/(9.8) Highparticlesize,flexibleandnonioniccharacter.Deblockingtemperatureapprox.150°C.
Baybond® XL 825 HDI Ɛ-CAP 30 in water < 200 1,400 3.0/(10.0) Lowthermalyellowing,improvedimpactstrength,adhesionandflexibility. Deblockingtemperatureapprox.170°C.
Baybond® XL 7270 HDI Ɛ-CAP 30 in water < 100 1,000 3.9/(13.1) Lowthermalyellowing,improvedimpactstrength,adhesionandflexibility. Deblockingtemperatureapprox.170°C. Food contact acc. to EU 10/2011.*
Baybond® XL 3674 HDI Ɛ-CAP 30 in water < 200 1,310 3.2/(10.7) Improvedimpactstrength,adhesionandflexibility.Deblockingtemperatureapprox.170°C. Food contact acc. to EU 10/2011.*
Desmodur® 2802 Carbodiimide 40 in water 100 1mmol–N=C=N–/g 210Polycarbodiimidecrosslinkercanbeusedincombinationwithcarboxylgroupscontainingdispersionpolymers(PUD,PACdispersions)toformulatewaterbornereactivesystemswithverylongpotlife.Ithastheadvantageofhavingaverylowenviromentalimpact.
SUPPLYFORMAPPROX.[%]
VISCOSITYAT23°CAPPROX.[mPa · s]
TYPE
TYPE
VISCOSITYAT23°CAPPROX.[mPa · s]
FUNCTIONALGROUPSAPPROX.
BLOCKINGAGENT
SUPPLYFORMAPPROX.[%]
CALCULATEDBLOCKEDNCO CONTENTONSUPPLYFORM APPROX.[%]/(ONRESIN[%])
COMMENTS
EQUIVALENTWEIGHTAPPROX.
EQUIVALENTWEIGHTAPPROX.
* See page 6
25Polyisocyanates and Prepolymers
Self-crosslinking urethane resin
COMMENTS
Bayhytherm® 3246/1 HDI DMP 44inwater/PnB/SN 800Wellbalancedhardness-flexibilityprofile,lowthermalyellowing,highgloss. Suitableforadditionalmelaminecrosslinking.ForOEMprimersurfacers, alsogeneralindustrialcoatings.
Desmotherm® 2170 MDI DEM 70inBA/SN/IB 2,000 Forsolvent-borne1KPURstovingcoatings(primerandprimersurfacer).
BLOCKING AGENT
SUPPLYFORMAPPROX.[%]TYPE
VISCOSITYAT23°CAPPROX.[mPa · s]
Bayhytherm® / Desmotherm®
NEW
26Polyisocyanates and Prepolymers
Powder hardeners
Crelan® family
COMMENTS
Crelan® EF 403 Internallyblockedlinear IPDI polyisocyanate Flakes 40–55 310 15minat180°C For emission-free powder coatings with outstanding leveling and
pigmentwettingandforspecialone-shotmattecoatings.
Crelan® NI-2 Blockedlinear IPDI polyisocyanate Prills 55–60 280 15minat180°C For economical standard powder coatings with good leveling,
goodpigmentwettingandgoodcorrosionresistance.
Crelan® NW-5 Blockedlinear H12MDI polyisocyanate Prills 48–58 335 15minat175°C Forhigherreactivepowdercoatingswithexcellentflexibilityand
corrosionresistanceproperties.
Crelan® UI Blockedlinear IPDI polyisocyanate Flakes >60 365 15minat180°C For powder coating with good leveling and good pigment wetting or
toimprovecoatingpropertiesofhybridsystems.
Crelan® VP LS 2256 Blockedlinear IPDI polyisocyanate Flakes 48–58 280 15minat180°C For high chemical resistance powder coatings with easy-to-clean
propertiesandstandardpowdercoatingswithgoodoverallproperties.
Tg APPROX.[°C]TYPE
EQUIVALENTWEIGHTAPPROX.SUPPLYFORM[%]
STANDARDBAKINGCYCLE
Solidblockedpolyisocyanatecrosslinkersforpolyurethanepowder coatingswithhighchemicalresistanceandsmoothsurfaces.
27Polyisocyanates and Prepolymers
Blockedaromaticurethaneresinsforflexibilizationofepoxysystems.
Blocked TDI prepolymers
Desmocap®
Desmocap® 14 CNB 100 25,000 Forelasticcoatingsandsealants;forflexibilizationofepoxyresins.Targetapplications:industrialflooring,parkingdecks, corrosionprotection,adhesivesforfloorcoverings.Cashewnutshellliquidasblockingagent.
SUPPLYFORMAPPROX.[%]
VISCOSITYAT23°CAPPROX.[mPa · s]
COMMENTS
28Polyisocyanates and Prepolymers
Hardenersforreactive,high-performance2KPURindustrialadhesives.
Desmodur® R:colorofthedriedadhesivefilm
Desmodur® R family
COMMENTS
VISCOSITYAT23°CAPPROX.[mPa · s]TYPE
NCOCONTENT ONSUPPLYFORM
APPROX.[%]SUPPLYFORMAPPROX.[%]
EQUIVALENTWEIGHTAPPROX.
Desmodur® RC TDI isocyanurate 35 in EA 3 7.0 600 Especiallypale-coloredadhesives.
Desmodur® RFE Tris(p-isocyanatophenyl)thiophosphate 27 in EA 3 7.2 583
Crosslinkerwithveryuniversalsuitabilityforadhesivesbased on Desmocoll®,naturalorsyntheticrubber.Suitableasprimeronglasssubstrates.
Desmodur® ultra RN TDI/HDIisocyanurate 40 in EA 11 7.2 585 Especiallypale-coloredadhesives.Lowerdiscoloration.
29Polyisocyanates and Prepolymers
Aromaticcrosslinkerforcoatingsandadhesives. Desmodur® ultra qualitiesperformwith<0.1%monomercontent.
Desmodur® L family
TDI-based crosslinkers
Desmodur® L 67 BA Adduct 67 in BA 600 11.9 350 2.7 17.0 180 Crosslinkerforuseincorrosionprotectioncoatings, industrialcoatings,woodandfurniturefinishes, concretecoatingsaswellassolvent-borneadhesives.
Desmodur® L 67 MPA/X Adduct 67inMPA/X 1,600 11.9 350 2.7 13.0 255Desmodur® L 75 Adduct 75 in EA 1,600 13.3 315 2.7 9.5 240Desmodur® ultra L 75 Adduct 75 in EA 1,600 13.3 315 2.7 9.5 240 Ultra-lowmonomergradeof Desmodur® L 75.Desmodur® ultra IL BA Isocyanurate 51 in BA 2,000 8.0 525 4.5 2.0 6
Very hard and very fast-drying coatings for wood, furnitureandpaper.Desmodur® ultra IL EA Isocyanurate 51 in EA 700 8.0 525 4.5 3.5 5
Desmodur® ultra IL 1351 BA Isocyanurate 51 in BA 1,300 8.0 525 4.5 2.5 6
Desmodur® IL 1451 BA Isocyanurate 51 in BA 250 7.4 565 4.8 3.0 8 See Desmodur® ultra IL 1351 BAbutwith improvedcompatibility.
TYPEVISCOSITYAT23°CAPPROX.[mPa · s]
NCOCONTENT ONSUPPLYFORM
APPROX.[%]SUPPLYFORMAPPROX.[%] COMMENTS
EQUIVALENTWEIGHTAPPROX.
GEL TIME WITH DESMOPHEN®1300X
APPROX.[h]DRYINGSTAGE3WITH DESMOPHEN®1300X DINENISO9117/5 APPROX.[MIN]
FUNCTIONALITYAPPROX.
TheseproductsrepresentonlyaselectionoftheTDI-basedproductsprimarilyusedincoatingapplications. AdditionalTDI-basedproductscanbefound,forexample,ontheCovestroCASwebsite:www.coatings.covestro.com
TDI-/HDI-basedcrosslinkers
Desmodur® HL BA Isocyanurate 60 in BA 2,200 10.5 400 4.4 3.0 12 Fast-drying coatings for wood, furniture, metal,plasticandpaperwithbetterelasticity than Desmodur® IL andbetterlightfastness.Desmodur® HL EA Isocyanurate 60 in EA 1,100 10.5 400 4.4 4.0 10
30Polyisocyanates and Prepolymers
Desmodur® monomers
Aliphatic diisocyanates
COMMENTS
Desmodur® H HDI 3 84 2 ≤30 RawmaterialforDesmodur® N family, buildingblock.Desmodur® I IPDI 10 111 2 ≤30 RawmaterialforDesmodur® Z family,buildingblock.Desmodur® W H12 MDI 30 131 2 ≤30 Buildingblock.
EQUIVALENTWEIGHTAPPROX.TYPE
FUNCTIONALITYVISCOSITYAT23°CAPPROX.[mPa · s]
COLORINDEX[HAZEN]
Covestroistheleadingcompanythatoffersyouthecompleterangeofaliphaticandaromaticmonomericdiisocyanates(monomers)aswellasoligomericisocyanates (polyisocyanates)andNCO-functionalprepolymers.Especiallythemonomersarewidelyusedasbuildingblocks:• tocreateadiverseportfolioofpolyurethanedispersions(PUDs),• tomodifyacrylic/alkydpolymertoimprovepropertiessuchasfasterdryingorbetterUVstability,• tocreateurethaneacrylatesorusethemforotherurethanizations,• tocreateadiverseportfolioofthermoplasticpolyurethanes(TPU)withdifferentcharacteristics,• to create a diverse portfolio of low and high Tg-castpolyurethanes(CPU)withdifferentcharacteristicsforindustrialCPUs,electricalencapsulation,labeldomingetc.
31Polyisocyanates and Prepolymers
Forcoatingsandadhesives.
Desmodur® monomers
Monomeric TDI products
Desmodur® T 65 N 48 67.0 3 2 87 100/40Desmodur® T 80 48 80.5 3 2 87 100/40 Stabilizer:Irganox® 1076 FD.Desmodur® T 100 48 ≥99.0 3 2 87 20/20 Stabilizer:Irganox® 1076 FD.
Desmodur® T 100 SP 48 ≥99.0 3 2 87 50/50 Stabilizer: Irganox® 1076 FD, for prepolymers with improvedstoragestability.
VISCOSITYAT25°CAPPROX.[mPa · s]
NCOCONTENT APPROX.[%]
FUNCTIONALITYHCMAX./ACIDITYMAX.[mg/kgCl-]/[mg/kgHCL]
2,4-TDICONTENT APPROX.[%] COMMENTS
EQUIVALENTWEIGHT
Monomeric MDI products
FUNCTIONALITY APPROX.
NCOCONTENT APPROX.[%]
EQUIVALENTWEIGHT
VISCOSITYAT25°CAPPROX.[mPa · s] COMMENTS
Desmodur® 44 M liquid 33.6 4(40°C) 2.0 125 Flexiblepackaging,hotmelts,sealants;additionalsupplyforms:fusedandflakes.
Desmodur® 44 MC liquid 33.6 4(40°C) 2.0 125 Hotmelts,sealants,prepolymerswithimprovedstorageandcolorstability; additionalsupplyforms:fusedandflakes.
Desmodur® LS 2424 33.6 12 2.0 125 Flexiblepackaging,hotmelts,approx.55%2,4’-MDI/45%4,4’-MDI.Desmodur® 2460 M 33.6 12 2.0 125 Flexiblepackaging,hotmelts,approx.55%2,4’-MDI/45%4,4’-MDIcolorstabilized.
Desmodur® CD-S 29.5 35 2.1 142 Hotmelts,sealants,modifiedmonomericMDI,liquidatroomtemperature, storage-stableatlowtemperatures.
32Polyisocyanates and Prepolymers
Aromaticcrosslinkerforcoatingsandadhesives.
Desmodur® polymeric MDI products (pMDI)
For adhesives COMMENTS
EQUIVALENTWEIGHTAPPROX.
VISCOSITYAT25°CAPPROX.[mPa · s]
FUNCTIONALITY APPROX.
NCOCONTENT ONSUPPLYFORM
APPROX.[%]
GEL TIME WITH CASTOROIL APPROX.[min]
Desmodur® VK 5 23 32.5 130 2.2 60 Buildingblockforprepolymers,high2,4’-MDIcontent,goodcompatibility withpolyethers.
Desmodur® VK 10 90 31.5 135 2.6 40 1Kand2Kadhesives,high2,4’-MDIcontent,lowpMDIcontent, goodcompatibilitywithpolyethers.
Desmodur® VK 10 L 90 31.5 135 2.6 50 1Kand2Kadhesives,high2,4’-MDIcontent,lowpMDIcontentgood compatibilitywithpolyethers,lowerreactivitythanDesmodur® VK 10.
Desmodur® VL R 10 120 31.5 135 2.8 45 Standard2Kadhesives,lowviscosity.Desmodur® VKS 20 200 31.5 135 2.9 45 Standard2Kadhesives,lowacidity.Desmodur® VKS 20 F 200 31.5 135 2.9 40 Standard2Kadhesives,highacidity.Desmodur® 44V40 L 400 31.0 135 3.0 50 Standard2Kadhesives,highfunctionality.Desmodur® 44V70 L 680 31.3 135 3.2 50 Standard2Kadhesives,highestfunctionality.
33Polyisocyanates and Prepolymers
Aromaticcrosslinkerforcoatingsandadhesives.
Desmodur® polymeric MDI products (pMDI)
For coatings and membranes
Desmodur® VL 50 23 32.5 130 2.2 60 Verylowviscosity;sameapplicationsasDesmodur® VLbutbetter compatibilitywithpolyethersandlowerreactivity;moreflexible.
Desmodur® VL 51 21 32.5 130 2.2 50 Verylowviscosity;sameapplicationsas Desmodur® VLbutbetter compatibilitywithpolyethersandlowerreactivity;moreflexible.
Desmodur® VP.PU 60RE11 21 32.5 130 2.2 45 Verylowviscosity;high2-ringcontent.Desmodur® XP 2551 66 32.0 130 2.5 50 Crosslinkerprimarilyforpolyolemulsions.Desmodur® VL 90 31.5 135 2.6 40 Crosslinkerfor100%solidscoatings,sealantsandmembranes.
Desmodur® VL R 10 120 31.5 135 2.8 45 Higher reactivity than Desmodur® VL;for100%solidsspraycoatings andmembranes.
Desmodur® VL R 20 200 31.5 135 2.9 45 Lower reactivity than Desmodur® VL;for100%solidsspraycoatings andmembranes.
Desmodur® VKS 20 F 200 31.5 135 2.9 40 Higher reactivity than Desmodur® VL R 20; for100%solidscoatings andmembranes.
COMMENTS
EQUIVALENTWEIGHTAPPROX.
VISCOSITYAT25°CAPPROX.[mPa · s]
FUNCTIONALITY APPROX.
NCOCONTENT ONSUPPLYFORM
APPROX.[%]
GEL TIME WITH CASTOROIL APPROX.[min]
34Polyisocyanates and Prepolymers
Prepolymersbasedonaliphaticdiisocyanatesdisplaygoodweatherstabilityandarecolor-stable. Theseuniquepropertiesareimportantforapplicationssuchascorrosionprotectionornon-yellowing coatingsandadhesives.Desmodur® ultra qualitiesperformwith<0.1%monomercontent.
Desmodur® aliphatic prepolymers
Prepolymers based on HDI
Prepolymers based on IPDI
Desmodur® ultra E 30500 12.5 <0.1 335 100 4,250 2.0 2,400 1Kbondingofrubberpellets,2Kadhesives. PreviouslyknownasDesmodur® XP 2617.
Desmodur® E 30700 11.0 <0.3 380 100 1,350 2.2 N/A
Highlyelasticprepolymerforwaterproofingmembranes,floorcoatings,suitablecombinationwithasparticesters.Recommendableforcorrosionprotectionandwindebladecoatings.Previouslyknownas Desmodur®E 2863 XP.
Desmodur® ultra E 3370 9.8 ≤0.1 420 70inMPA/SN 1,400 4.0 4,900 Corrosionprotectioncoatings,goodweatherstability,non-yellowing, 1Kapplication.
Desmodur® E 30600 6.0 ≤0.3 700 100 2,500 4.0 3,500 2Kcoatingsand2Kadhesives.PreviouslyknownasDesmodur® XP 2599.
Desmodur® E 3265 MPA/SN 10.4 ≤0.26 405 65inMPA/SN 1,200 4.2 3,100 Corrosionprotectioncoatings,goodweatherstability,non-yellowing, 1Kapplication.
Desmodur® VP LS 2371 3.7 <2.0 1,100 100 9,800 2.0 11,500 1Kconstructioncoatings,1Ksealants.
Desmodur® E 40480 MPA 2.8 <0.5 1,500 80 in MPA 7,000 2.0 >5,800 Elasticcoatingsandsealantswithverygoodweatherstability. PreviouslyknownasDesmodur® XP 2406.
EQUIVALENTWEIGHTAPPROX.
NCOCONTENTONSUPPLY-FORM
APPROX.[%]
SUPPLYFORMAPPROX.[%]
FUNCTIONALITYAPPROX.
MONOMERCONTENT[%] COMMENTS
VISCOSITY AT23°CAPPROX.
[mPa · s]
DRYINGTIME (MOISTURECURING
SYSTEM)23°C/50%r.h.APPROX.[min]
NEW
35Polyisocyanates and Prepolymers
PrepolymersareNCO-functionalreactionproductsofaromaticoraliphaticisocyanatesandpolyols,suchaspolyethersorpolyesters. Thewidevariabilityoftheisocyanatecontentandfunctionalityenablesthe viscosity of the prepolymers and the mechanical properties of thefinishedproductstobepreciselyadjusted.
Desmodur® aromatic prepolymers
Prepolymers based on TDI
Desmodur® E 1361 MPA/X 6.8 620 61inMPA/X 500 2.8 ≤0.4 120 Fast-drying1Kmoisture-curingcoatings.Recommendablefor corrosionprotection.
Desmodur® E 1361 BA 6.8 620 61 in BA 250 2.8 <0.5 90 Fast-drying1Kmoisture-curingcoatings.Recommendablefor corrosionprotection.
Desmodur® E 1160 MPA/X 5.4 780 60inMPA/X 550 3.0 ≤0.4 740 1Kmoisture-curingcoatings.
Desmodur® E 1660 5.3 790 60 in BA 1,600 2.0 <0.5 25 Veryfast-drying1Kmoisture-curingcoatingsincombinationwith other Desmodur® Etypes.
Desmodur® E 15 4.4 955 100 7,000 2.0 <0.5 2,800 Recommendablefor2Kelasticparkdeckcoatings,1Ksealantsandcorrosionprotection.
Desmodur® E XP 2605/1 4.3 975 50 in BA 250 3.7 ≤0.4TDI<1.0MDI 25 Veryfastdrying,forparquetandfurniture.
Desmodur® E 14 3.3 1,270 100 6,800 2.5 <0.5 1,400 Recommendablefor2Kelasticparkdeckcoatings,1Ksealants, flexibilizationofanti-corrosionsystemsandcorrosionprotection.
SUPPLYFORMAPPROX.[%]
NCOCONTENT ONSUPPLYFORM
APPROX.[%]
VISCOSITYAT23°CAPPROX.[mPa · s]
MONOMERCONTENT[%]
EQUIVALENTWEIGHTAPPROX. COMMENTS
FUNCTIONALITYAPPROX.
DRYINGTIME (MOISTURECURINGSYSTEM)23°C/50%r.h.APPROX.[min]
37Polyisocyanates and Prepolymers
Prepolymers are the reaction products of aromatic or aliphatic isocyanates and polyols, such as polyethers orpolyesters.Thewidevariabilityofthebuildingblocks,isocyanatecontentandfunctionalityenablestheviscosityoftheprepolymersandthemechanicalpropertiesofthefinalproductstobepreciselyadjusted.
Desmodur® and Desmoseal® M
Prepolymers based on MDI
VISCOSITYAT23°C (* 25°C)APPROX.[mPa · s]
NCOCONTENTONSUPPLYFORM APPROX.[%]
FUNCTIONALITY APPROX.
EQUIVALENTWEIGHTAPPROX. COMMENTS
DRYINGTIME(MOISTURECURINGSYSTEM)23°C/50%r.h.APPROX.[min]
Desmodur® VH 20 N 24.5 173 280* 2.1 770 Sportsfloors,storage-stableatlowtemperatures.
Desmodur® E 29 24.0 175 220* 2.2 140 1Kprimerforflooringapplications,binderforcorrosionprotection.Desmodur® 2665A 16.3 255 4,500* 2.7 65 1Kwoodbonding(D4)–higherreacitivitycomparedtoE21,2Kadhesives.Desmodur® E 21 16.0 260 5,400* 2.8 110 1Kwoodbonding(D4),2Kadhesives,binderforcorrosionprotection.Desmodur® E 2190 X 14.3 295 1,100* 2.8 115 90%supplyformofDesmodur® E 21inxylene.
Desmodur® E 20100 15.7 265 1,100 2.0 180 1Kresinforsealingofwater-conveyingcracksinstructuresaboveand belowground,rawmaterialforinjectionsystems.
Desmodur® E XP 2723 15.4 270 1,500* 2.3 480 1Kassemblingadhesives,2Kadhesives.
Desmodur® E 23 15.4 270 1,800 2.1 130 1Kwoodbonding(D4),2Kflexiblepackagingadhesives,binderfor corrosionprotection.
Desmodur® E XP 2727 15.3 275 800 2.0 640 For one and two-component polyurethane and polyurea coatings, adhesivesandsealants.
Desmodur® E XP 2715 15.1 280 950(70°C) 2.0 – Precursorforlowmonomer1KPURhotmelts.Desmodur® E XP 2762 14.3 295 4,500 2.1 15 1Kwoodbonding(D4)–higherreacitivitycomparedtoE23,2Kadhesives.Desmodur® E 2200/76 9.9 425 2,750* 2.0 1,100 Flexiblepackaging.Desmodur® E 22 8.6 490 2,800 2.0 190 1Kbondingofrubberpellets,2Kadhesives.Desmoseal® M 280 2.1 2,000 33,000 2.7 200 1Ksealants,1Kelasticadhesives.
38Polyisocyanates and Prepolymers
BK 10 drying recorder (test method PV 123)
Measuring conditions:Filmthickness: 250μmTemperature: 23°CHumidity: 50%Speed: 5.1cm/h
NCOprepolymersforreactiveadhesives reactivity of low-monomer prepolymers
NCOprepolymersforreactiveadhesives reactivityofMDIbasedprepolymers
Endofneedletrack/startdottedneedletrack
Glass strip
Film building time (FBT)
Film drying time (FDT)
Beginningofvisible needletrack
Measuring needle(weight10g)Start of recording
Drying Recorder test FBT–FilmbuildingtimeFDT – Film drying time
Drying Recorder test FBT–FilmbuildingtimeFDT – Film drying time
39Polyisocyanates and Prepolymers
Silane-terminatedpolyurethanes(STP)combinetheadvantagesofapolyurethanebackboneand silane-basedcuringmechanism,suchasexcellentcohesivestrengthandgoodadhesionproperties. Theycoverthecompleteapplicationrangefromlowmodulussealantsuptostructuraladhesives.
Desmoseal® S family
Silane-terminated polyurethanes
COMMENTS
Desmoseal® S XP 2774 100 50,000 Very high Forlowmodulussealantswithveryhighelongation.Startingformulationavailablewhichhasbeen classifiedaccordingtoISO11600-F-25LM(iftRosenheim).
Desmoseal® S XP 2636 100 40,000 High Forlowmodulussealantsandelasticadhesiveswithhighelongation.Desmoseal® S XP 2458 90 in Mesamoll 35,000 Medium Forelasticadhesivesandhigh-modulussealantswithmediumelongation.Desmoseal® S 2876 100 25,000 Medium Forelasticadhesivesandhigh-modulussealantswithmediumelongation.Desmoseal® S XP 2749 100 5,100 Low Foradhesiveswithhighhardnesswithoutaddedplasticizer.Desmoseal® S XP 2821 100 20,000 Low Forstructuraladhesiveswithhightensilestrengthandlapshearstrengthwithoutaddedplasticizer.
VISCOSITYAT23°CAPPROX.[mPa · s]
SUPPLYFORM APPROX.[%]
MOLECULARWEIGHT
Legend Solvents
BA Butyl acetateSN Solvent naphthaMPA MethoxypropylacetateX XyleneEA Ethyl acetatePGDME Dipropylene glycol dimethyl etherPGDA Propylene glycol diacetateIB Isobutanol
Isocyanates
HDI HexamethylenediisocyanateIPDI Isophorone diisocyanatePDI Pentamethylene diisocyanateH12MDI DicyclohexylmethanediisocyanateTDI Toluene diisocyanateMDI Diphenylmethane diisocyanate
Blocking agents
DEM DiethylmalonateDIPA DiisopropylamineDMP DimethylpyrazoleMEKO MethylethylketoximeƐ-CAP Ɛ-Caprolactam
Other abbreviations
Tg Glass transition temperature
41Polyisocyanates and Prepolymers
AtCovestro,innovationisinourDNA.EversinceOttoBayerdiscoveredpolyurethanesin1937,wehavebeen driving polyurethane innovations in coatings and adhesivesaswellasinotherapplicationareas.Asourpartner,youenjoyfast-laneaccesstopolyurethane innovations and can help us in developing thenextgenerationofpolyurethanestomeettheindustry’supcomingchallengesandneeds.Whatcanwe offeryou?
Fast-lane access to polyurethane innovations
• Powerfulknow-howonbothestablishedandnewpolyisocyanates, as well as on new poly urethane hybridtechnologies.
• The prospect of new application technologies to enableefficientprocesses.
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The manner in which you use our products, technical assistance and information (whether verbal, written or by way of production evaluations), including any suggested formulations and recommendations, is beyond our control. Therefore, it is imperative that you test our products to determine suitability for your processing and intended uses. Your analysis must at least include testing to determine suitability from a technical, health, safety, and environmental and regulatory standpoint. Such testing has not necessarily been done by Covestro, and Covestro has not obtained any approvals or licenses for a particular use or application of the product, unless explicitly stated otherwise. [EMEA only: If the intended use of the product is for the manufacture of a pharmaceutical/medicinal product, medical device1 or of pre-cursor products for medical devices or for other specifically regulated applications which lead or may lead to a regulatory obligation of Covestro, Covestro must explicitly agree to such application before the sale.] Any samples provided by Covestro are for testing purposes only and not for commercial use. Unless we otherwise agree in writing, all products are sold strictly pursuant to the terms of our standard conditions of sale which are available upon request. All information, including technical assistance is given without warranty or guarantee and is subject to change without notice. It is expressly understood and agreed by you that you assume and hereby expressly release and indemnify us and hold us harmless from all liability, in tort, contract or otherwise, incurred in connection with the use of our products, technical assistance, and information. Any statement or recommendation not contained herein is unauthorized and shall not bind us. Nothing herein shall be construed as a recommendation to use any product in conflict with any claim of any patent relative to any material or its use. No license is implied or in fact granted under the claims of any patent. 1 Please see the “Guidance on Use of Covestro Products in a Medical Application” document.Typical value: These values are typical values only. Unless explicitly agreed in written form, the do not constitute a binding material specification or warranted values.
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[email protected] Edition: 2021 · Printed in Germany