Part 1:Lewis Dot Diagrams and Structures Lesson 4 – Lewis Diagrams and Molecular Geometry.
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Transcript of Part 1:Lewis Dot Diagrams and Structures Lesson 4 – Lewis Diagrams and Molecular Geometry.
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Part 1:Lewis Dot Diagrams and
Structures
Lesson 4 – Lewis Diagrams and Molecular Geometry
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Review of Chemical BondsReview of Chemical Bonds There are 3 forms of bonding:There are 3 forms of bonding: __________________—complete —complete transfer transfer of 1 or more of 1 or more
electrons from one atom to another (one electrons from one atom to another (one loses, the other gains) forming oppositely loses, the other gains) forming oppositely charged ions that attract one anothercharged ions that attract one another
__________________—some valence electrons —some valence electrons sharedshared between atoms between atoms
_________ – holds atoms of a metal _________ – holds atoms of a metal togethertogether
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The type of bond can The type of bond can usuallyusually be be calculated by finding the difference in calculated by finding the difference in electronegativity of the two atoms that are electronegativity of the two atoms that are going together.going together.
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Electronegativity Difference If the difference in electronegativities is
between:
– ≥ 2.0: Ionic
– 0.>0.4 to < 2.0: Polar Covalent
– 0.0 to 0.4: Non-Polar Covalent
Example: NaClNa = 0.8, Cl = 3.0Difference is 2.2, sothis is an ionic bond!
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Review of Valence ElectronsReview of Valence ElectronsReview of Valence ElectronsReview of Valence Electrons Remember from the electron Remember from the electron
arrangement that valence electrons arrangement that valence electrons are the electrons in the OUTERMOST are the electrons in the OUTERMOST energy level. energy level.
BB is is 1s1s22 2s 2s22 2p 2p11; so the outer energy ; so the outer energy level is 2, and there are 2+1 = 3 level is 2, and there are 2+1 = 3 electrons in level 2. These are the electrons in level 2. These are the valence electrons!valence electrons!
BrBr is is [Ar] 4s[Ar] 4s22 3d 3d1010 4p 4p55
How many valence electrons are How many valence electrons are present?present?
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Lewis Dot Diagrams A way of keeping track of
valence electrons in ionic compounds.
How to write them? Write the symbol. Put one dot for each
valence electron Don’t pair up until they
have to (Hund’s rule)
X
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The Lewis Dot diagram for Nitrogen
Nitrogen has 5 valence electrons.
First we write the symbol.
NThen add 1 electron at a time to each side.Until they are forced to pair up.
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Lewis Dots For Cations Metals will have few valence
electrons (usually 3 or less)
Ca
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Lewis Dots For Cations Metals will have few valence electrons These will come off
Ca
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Lewis Dots For Cations Metals will have few valence electrons These will come off Forming positive ions
Ca2+Pseudo-noble gas configuration
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Lewis Dots For Anions Nonmetals will have many valence
electrons (usually 5 or more) They will gain electrons to fill outer shell.
P P3-
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Ionic Bonding Anions and cations are held
together by opposite charges. The bond is formed through the
transfer of electrons. Electrons are transferred to achieve
noble gas configuration (octet rule).
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Lewis Dot Diagrams Ionic Bonding
Na Cl
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Lewis Dot Diagrams Ionic Bonding
Na+ Cl-
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Lewis Dot Diagrams Ionic Bonding
All the electrons must be accounted for!
Ca P
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Lewis Dot Diagrams-Ionic Bonding
Ca P
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Lewis Dot Diagrams Ionic Bonding
Ca2+ P
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Lewis Dot Diagrams Ionic Bonding
Ca2+ P
Ca
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Lewis Dot Diagrams Ionic Bonding
Ca2+ P 3-
Ca
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Lewis Dot Diagrams Ionic Bonding
Ca2+ P 3-
Ca P
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Lewis Dot Diagrams Ionic Bonding
Ca2+ P 3-
Ca2+ P
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Lewis Dot Diagrams Ionic Bonding
Ca2+ P 3-
Ca2+ P
Ca
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Lewis Dot Diagram Ionic Bonding
Ca2+ P 3-
Ca2+ P
Ca
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Ionic Bonding
Ca2+ P 3-
Ca2+P
3-
Ca2+
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Lewis Dot Diagram Ionic Bonding
= Ca3P2Formula Unit
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Lewis Structures –Covalent Bonding
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Covalent bonds Nonmetals hold on to their valence
electrons. Still want noble gas configuration. By sharing, both atoms get to count the
electrons toward a noble gas configuration.
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Covalent bonding Fluorine has seven valence
electrons
F
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Covalent bonding Fluorine has seven valence
electrons A second atom also has seven
F F
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Covalent bonding Fluorine has seven valence
electrons A second atom also has seven By sharing electrons…
F F
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Covalent bonding Fluorine has seven valence
electrons A second atom also has seven By sharing electrons…
F F
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Covalent bonding Fluorine has seven valence
electrons A second atom also has seven By sharing electrons…
F F
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Covalent bonding Fluorine has seven valence
electrons A second atom also has seven By sharing electrons…
F F
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Covalent bonding Fluorine has seven valence
electrons A second atom also has seven By sharing electrons…
F F
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Covalent bonding Fluorine has seven valence electrons A second atom also has seven By sharing electrons… …both end with full orbitals
F F
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Covalent bonding Fluorine has seven valence electrons A second atom also has seven By sharing electrons… …both end with full orbitals
F F8 Valence electrons
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Drawing Lewis Structures Find total # of valence e-.
Arrange atoms - singular atom is usually in the middle.
Form bonds between atoms (2 e-).
Distribute remaining e- to give each atom an octet
If there aren’t enough e- to go around, form double or triple bonds.
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Water
H
O
Each hydrogen has 1 valence
Electron (Total of 2e)
Each hydrogen wants 1 more
The oxygen has 6 valence electrons
The oxygen wants 2 more
They share to make each other happy
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Water Put the pieces together (8 e to distribute). The first hydrogen is happy The oxygen still wants one more
H O
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Water The second hydrogen attaches Every atom has full energy levels Remember to check count.
H OH
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Drawing Lewis Structures CF4
1 C × 4e- = 4e-
4 F × 7e- = 28e-
32e- FF C F
F
- 8e-
24e-
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Drawing Lewis Structures BeCl2
1 Be × 2e- = 2e-
2 Cl × 7e- = 14e-
16e-
Cl Be Cl - 4e-
12e-
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Multiple Bonds Sometimes atoms share more than
one pair of valence electrons. A double bond is when atoms share
two pairs (4 total) of electrons A triple bond is when atoms share
three pairs (6 total) of electrons Know which elements are diatomic
(Oxygen?)
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Carbon dioxide CO2 - Carbon is central
atom ( more metallic ) Carbon has 4 valence
electrons Oxygen has 6 valence
electrons (total of 12e) 16e must be distributed.O
C
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Carbon dioxide Attaching 1 oxygen leaves the
oxygen 1 short, and the carbon 3 short
OC
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Carbon dioxide Attaching the second oxygen leaves both
oxygen 1 short and the carbon 2 short IF the central atom is not surrounded by 4
electron pairs, it does not have an octet. You must convert one or more of the lone pairs on the terminal atoms to a double or triple bonds.
OCO
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Carbon dioxide The only solution is to share more
OCO
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Carbon dioxide The only solution is to share more
OCO
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Carbon dioxide The only solution is to share more
OCO
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Carbon dioxide The only solution is to share more
OCO
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Carbon dioxide The only solution is to share more
OCO
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Carbon dioxide The only solution is to share more
OCO
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Carbon dioxide The only solution is to share more Requires two double bonds Each atom can count all the
electrons in the bond
OCO
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Carbon dioxide The only solution is to share more Requires two double bonds Each atom can count all the electrons in the
bond Count e’s
OCO8 valence electrons
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Carbon dioxide The only solution is to share more Requires two double bonds Each atom can count all the electrons in
the bond
OCO8 valence electrons