Part 1 TMoore Artificial Photosynthesis 22 Oct 2018

70
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

Transcript of Part 1 TMoore Artificial Photosynthesis 22 Oct 2018

Page 1: Part 1 TMoore Artificial Photosynthesis 22 Oct 2018

!

!"#$%"&#'(#)*+#,"-./0-1##23/*4/#-"(/#(%*(#4"&/#"5#(%/#&*(/06*3#6-#(%64#70/4/-(*(6"-#."&/4#50"&#."7+068%(#70"(/.(/9#4":0./41#'(4#:4/#5"0#/9:.*(6"-*3#7:07"4/4#64#7/0&6((/9#;:(#6(#&:4(#-"(#;/#0/70"9:./9#"0#7"4(/9#"-#*-#"7/-#</;#46(/#"0#&*9/#8/-/0*33+#*=*63*;3/#6-#*-+#5"0&1#'(#64#6-(/-9/9#*4#*#0/4":0./#5"0#4(:9/-(4#*(#(%/#4:&&/0#4.%""3#6-#*0(656.6*3#7%"("4+-(%/464>#??#("#?@#A.(1>#?BCD>#E:/-"4#F60/4>#F08/-(6-*1#23/*4/#."-(*.(#&/#<6(%#G:/4(6"-41#

(&""0/H*4:1/9:

!%"&*4#F#)""0/#CD#A.(1#?BCD>#!/&7/#FI>#JKF

Page 2: Part 1 TMoore Artificial Photosynthesis 22 Oct 2018

!

"#$%&%'%()*+,-$-./0$,1.%.

!"#$%&'()'*##+,'%-.'(-%'/)'*##+,

234567*80%91#.%$/*-&*:;10-.*"%#1.<'$-=1#*!!*$-*!>7*!?@>*

Page 3: Part 1 TMoore Artificial Photosynthesis 22 Oct 2018

!

!"#$"%&'$%$!"#$$%&'(&)*+','"'-%&.#$+$/0(+#1/'/2

Page 4: Part 1 TMoore Artificial Photosynthesis 22 Oct 2018

!

!"#$"%&'$%$!"#$$%&'(&)*+','"'-%&.#$+$/0(+#1/'/2

!"#"$%&"'()&*+&,-)./01&$"02.00&3)-&45).(&67&8"'.(%0&4'$&(9%'&0)8%)'%&3-)8&%429&,-)./&:";;&,"#%&4&09)-(&4'0:%-<

Page 5: Part 1 TMoore Artificial Photosynthesis 22 Oct 2018

!"#$%"#&'#(&)*$+&)'#),#+-"#+-"#.%&'/&.*"#),#0'+"%1"'"%$+&)'$*#234&+56#7-&/-#8+$+"89#-4:$'8#;-)*<#+-"#'$+4%$*#$'<#/4*+4%$*#"'(&%)':"'+#),#+-"#2$%+-#&'#/)::)'#=)+-#7&+-#)+-"%#:":="%8#),#+-"#.%"8"'+#1"'"%$+&)'#$'<#7&+-#)+-"%#1"'"%$+&)'86#.$8+#$'<#,4+4%";#>!"&886#?@@A6#.B#CDB

!-$+#&8#+-"#.%)=*":E

!-$+#<)"8#&+#:"$'E

F)7#+)#,&G#&+E

H)8+#/)'+%)*#),#+-"#1*)=$*#/$%=)'#/5/*"

!

Page 6: Part 1 TMoore Artificial Photosynthesis 22 Oct 2018

!"#$%"#&'#(&)*$+&)'#),#+-"#+-"#.%&'/&.*"#),#0'+"%1"'"%$+&)'$*#234&+56#7-&/-#8+$+"89#-4:$'8#;-)*<#+-"#'$+4%$*#$'<#/4*+4%$*#"'(&%)':"'+#),#+-"#2$%+-#&'#/)::)'#=)+-#7&+-#)+-"%#:":="%8#),#+-"#.%"8"'+#1"'"%$+&)'#$'<#7&+-#)+-"%#1"'"%$+&)'86#.$8+#$'<#,4+4%";#>!"&886#?@@A6#.B#CDB

!-$+#&8#+-"#.%)=*":E

!-$+#<)"8#&+#:"$'E

F)7#+)#,&G#&+E

H)8+#/)'+%)*#),#+-"#1*)=$*#/$%=)'#/5/*"

!

Page 7: Part 1 TMoore Artificial Photosynthesis 22 Oct 2018

!""#$%%&#'()*&+&),'-%&#'(%&#./.0.1)!"23

!"#$#%&'$"(%)%*+,)-(++.'/+$"(+0,#1.,+2.31#'+2&2,(4"(+5.3$"+)'+$36(+2#,#3+

71#6$+".,-+#-+5.3$"8%+9"#$#%&'$"(%)%+$.:(%+9,.2(+)'+$"(+#2(.'% 4

Page 8: Part 1 TMoore Artificial Photosynthesis 22 Oct 2018

!"##$%&&'''()*+$(,-./-0-1(-2)&*3.,4567-.4)8&*3.,4567-.4)8($"$

!"#$#%&'$"(%)%*+,-(*.,/$"*$"(*0,/1#')2(/#3%*!(/)#4*,'4*$"(*5"(6)5,7*('(/+&*$#*%388#/$*5#687(9*7)2(*

0#,7:7,'4;

<)7:=(,;

+,%

Page 9: Part 1 TMoore Artificial Photosynthesis 22 Oct 2018

!"##$%&&'''()*+$(,-./-0-1(-2)&*3.,4567-.4)8&*3.,4567-.4)8($"$

!"#$#%&'$"(%)%*+,-(*.,/$"*$"(*0,/1#')2(/#3%*!(/)#4*,'4*$"(*5"(6)5,7*('(/+&*$#*%388#/$*5#687(9*7)2(*

0#,7:7,'4;

<)7:=(,;

+,%

,'4*#9&+('

Page 10: Part 1 TMoore Artificial Photosynthesis 22 Oct 2018

!"#$$%&''((()*+,%)-./0.1.2).3*'+4/-5678./5*9'+4/-5678./5*9)%#%

!"#$#%&'$"(%)%*+,-(*.,/$"*$"(*0,/1#')2(/#3%*!(/)#4*,'4*$"(*5"(6)5,7*('(/+&*$#*%388#/$*5#687(9*7)2(*

0#,7:7,'4;

<)7:=(,;

+,%

,'4*#9&+('$#*13/'*:#9)4)>(;*$"(*/(435(4*5,/1#'*$#*&)(74*?)'($)5*,'4*

8#$('$),7*('(/+&

Page 11: Part 1 TMoore Artificial Photosynthesis 22 Oct 2018

!!"##$%&&'''()*+$(,-./-0-1(-2)&*3.,4567-.4)8&*3.,4567-.4)8($"$

!"#$#%&'$"(%)%*+,-(*.,/$"*$"(*0,/1#')2(/#3%*!(/)#4*,'4*$"(*5"(6)5,7*('(/+&*$#*%388#/$*5#687(9*7)2(*

0#,7:7,'4;

<)7:=(,;

+,%

,'4*2#/*"36,'%*$#*+/#>*$"()/*

?@!

Page 12: Part 1 TMoore Artificial Photosynthesis 22 Oct 2018

!

"EE

#$

%&'(

)

*"

+,-,./01*&&

*"

!"#$%&'$(#)*$+",-'&.,,

+234

(5%.

'6.*

%7(0

*"8&%

9

:%07.;*<('6.;0=%905=%'%(>.'=*(,(0=6(0'<6.(8%<?*;046<'=@09*0&%%A08,<('06'060B6(,C0<*D7,<*?*.'08%<0&,8*0

+,8*0<*D7,<*(0*&*C'<%.08&%90;%9.060/<6;,*.'0%80C=*?,C6&0*.*</>E0

+,-,./0C*&&(0=6<-*('0'=*06-6,&6B&*0C=*?,C6&05%'*.',6&0*.*</>0'%0?6A*060&,-,./E

4&*C'<%.0;%.%<(

4&*C'<%.06CC*5'%<(

F=%'%(>.'=*(,(@0&,8*06.;0'=*0/&%B6&0C6<B%.0C>C&*

!"

Page 13: Part 1 TMoore Artificial Photosynthesis 22 Oct 2018

!

"EE

#$

%&'(

)

*"

+,-,./01*&&

*"

!"#$%&'$(#)*$+",-'&.,,

+234

(5%.

'6.*

%7(0

*"8&%

9

:*8%;*05<%'%(=.'<*(,(0'<*0*&*>';%.0?%.%;(06.?0*&*>';%.06>>*5'%;(09*;*0.6'7;6&&=0%>>7;;,./0>%@5%7.?(06.?0@6'*;,6&(00,.046;'<A(0>;7('B0

3%;0@%('0?%.%;0C6>>*5'%;056,;(0'<*0*.*;/=0/;6?,*.'096(0(@6&&B0D0E&%90-%&'6/*F0G6''*;=

4&*>';%.0?%.%;(

4&*>';%.06>>*5'%;(

H<%'%(=.'<*(,(I0&,8*06.?0'<*0/&%G6&0>6;G%.0>=>&*

!"J&%90/;%9'<I0G7'0*88,>,*.'0>6'6&=('(

Page 14: Part 1 TMoore Artificial Photosynthesis 22 Oct 2018

!"#$#%&'$"(%)%*+,)-(+.'/+$"(+0,#1.,+2.31#'+2&2,(

4

5EE

67

#,$%

8

(5

9):)'0+;(,,

(5

!"#$%&'$(#)*$+",-'&.,,

/01!

%<#'

$.'(

#=%+

(5-,#

>?,(2$3#'+/#'#3

@A ?,(2$3#'+.22(<$#3

!"#$#%&'$"(%)%+0.:(+?.3$"+#B&0('*+>")2"+<3#:)/(/+.+C=2"+,.30(3+('(30&+03./)('$D+

E+FG)0"+:#,$.0(H+1.$$(3&+$#+<#>(3+,)-(D

I$+)%+<#3$.1,(

!"

Page 15: Part 1 TMoore Artificial Photosynthesis 22 Oct 2018

!"#$#%&'$"(%)%*+,)-(+.'/+$"(+0,#1.,+2.31#'+2&2,(

4

5EE

67

#,$%

8

(5

9):)'0+;(,,

(5

!"#$%&'$(#)*$+",-'&.,,

/01!

%<#'

$.'(

#=%+

(5-,#

>?,(2$3#'+/#'#3

@A ?,(2$3#'+.22(<$#3

B"(+")0"+:#,$.0(+1.$$(3&+)%+3(2".30(.1,(6%#+,#'0+.%+>(+/#'C$+13(.D+)$8

!"#$#%&'$"(%)%+$3.'%-#3E(/+?.3$".'/+E./(+<#%%)1,(+$"(+(:#,=$)#'+#-+2#E<,(F*+,.30(+"($(3#$3#<")2+#30.')%E%+G .'/+03#>)'0+$"()3+HI! !"

Page 16: Part 1 TMoore Artificial Photosynthesis 22 Oct 2018

!"#$%&'%()#*+,-./ 01%+2'%!"#$ 3456755389655:965;!"#$%&'(&)*+,-.*/&01*234(&-5&61,3.137

<#"1"-=$1#0-/-%#+-%1*/).20%)#+*>0?%1#0%@+*1#:-A+)0%B+110*=%C"*%D3'6%

B/22/"$%=*-'%EF-%1#/-%0$0*>=%/-%?/--/A+10?%B=%#G,+$-H%/1%0I0$1G+22=%*+?/+10-%

+-%#0+1%1"J+*?%1#0%)#0,/)+2%0KG/2/B*/G,%"C%?00A%-A+)0%L+$"?0M'%N#0%

B+110*=%/-%*+A/?2=%?/-)#+*>/$>%J/1#"G1%*0A20$/-#,0$1'O

P/-)#+*>/$> 1#0%@+*1#:-A+)0%B+110*=%/-%)#+$>/$>%@+*1#%+$?%/-%$"1%-G-1+/$+B20'

N#0%@+*1#:(A+)0%B+110*=%A+*+B20

N#0%.0=%*"20%"C%A#"1"-=$1#0-/-%/$%1*+$-C"*,/$>%@+*1#

!"

#$%&'()$*+,-.)$/$0()1+-'&2&.3)+(.(4*,0()$5(6&$*0)1-%(.%&*0)%-)7*+%589)$+:9%);9:11-+%&.3)0&<(

=.*$%&'()$*+,-.)$/$0(); $*+,-.)6-9%0/)&.)+-$>9)

Page 17: Part 1 TMoore Artificial Photosynthesis 22 Oct 2018

!"#$%&"'()*+',-.%/'0)#+&)/'1**)&/'1**)&'2'3&)+##./'145'6-77&%89!"#$$%

!"#$%&'()$*(++#),$-"().#)/$!"#$0#,$)&'#$&1$2"&+&%,3+"#%4%$43$+)(3%1&)543.$6()+"

789:;<<$!=

>8?$!=$+#))#%+)4('$2"&+&%,3+"#+4-$@AA

&'

>7B:<<<$!=$43-4C#3+$&3$'(3C

>DE8$!=$2)45(),$1&&C$$

!""#$%% &'()*(+),-.(/01)(123(-14)+523.3#(,/12)+523.3#(267.)+523.3(-07(8/)+523.3

F"#)5(3$#+$('G:$A"&+&%,3+"$H#%IJK$7<G7<<8L%7779<E<7MEN8N;ED

Page 18: Part 1 TMoore Artificial Photosynthesis 22 Oct 2018

!"

!"#$%##"&'

(&)*+%$,*-&&.*#,&%/.*01*213%"21.*4&*-11.*567*8*9:; <1&</1=

>-*4,1*?@12?A1*<12#&'*&<12?41#*?4*?0&%4*9::*B*C?*D:::*E$?/F.?G*."14H

Page 19: Part 1 TMoore Artificial Photosynthesis 22 Oct 2018

!"

!"#$%##"&'

(%))&#*+,+-+&.+)/&0&#1'0/*#"#+"#+"'+0/*+&$*2'+2'3+,+-+"#+&'+42'35++(%))&#*+677+8+977+&'+42'3+2'3+"'+0/*+#*25

:/20+"#+0/*+0&024+)&;*<+&.+)/&0&#1'0/*#"#+=>4&?24@+677A+".+42'3+)/&0&#1'0/*#"#+)&;*<+"#+BC+D:E

F'*<>1+)*<+1*2<E

Page 20: Part 1 TMoore Artificial Photosynthesis 22 Oct 2018

!""#$%%&'()*+*#&,*-(./0%)*+*%1-/2.'3,*.4*,&56&,*-7*&)&/%8*9&$:;".<-',3!&"&/."/.#!=(#'0

!"#$#%&'$"(%)%*+',*$"(*-.#/+.*0+1/#'*0&0.(*2 3)-*4)0$51(6"(*78+%$9*-.#/+.*0+1/#'*0&0.(*! :8.5;(%<*=$>?&1@

6"(*7%.#A9*-.#/+.*0+1/#'*0&0.(*2 8#%%).*85(.%<*1#0B%<*,((4*%(+*%(,)C('$%*:%$#0B%*#1*1(%(1D#)1%<*=$>@*E!-*F*EGEH -*F*E=$

6")%*A+%*$"(*'#1C+.*0&0.(*/(8#1(*$"(*I'$"1#4#0('(*>?

Page 21: Part 1 TMoore Artificial Photosynthesis 22 Oct 2018

!""#$%%&'()*+*#&,*-(./0%)*+*%1-/2.'3,*.4*,&56&,*-7*&)&/%8*9&$:;".<-',3!&"&/."/.#!=(#'0

!"#$#%&'(#)*"+#,-.&#/0$)&#12'-&3#1-*.$//4#5'*,&0,&3#6'*.#!74#0*"%&',/#08&.-0$))(#,*#6*//-)#62&)/98&#:/)*;<#+)*1$)#0$'1*"#0(0)&#= 6*//-)#62&)/4#'*0>/4#3&&5#/&$#/&3-.&",/#?/,*0>/#*'#'&/&'%*-'/4#@,AB#CD+#E#CFCG +#E#C@,

98-/#;$/#,8&#"*'.$)#0(0)&#1&6*'&#,8&#H",8'*5*0&"&# >?

Page 22: Part 1 TMoore Artificial Photosynthesis 22 Oct 2018

!"#$% &""!"'%$""&""()*+,""!! #!'-%$!" &""!"$%

-."/01)23"

4)56788"

915,2:,23"),";156"

$% 85"$% 40)(,"09"

)<"7,6589+212."

%."/)56788",01<8"

,5";588)(";02(8.

=."/01<)<*";588)("

;02(8":5<80628"

5>?*2<"7<3"

91530:28"6512"

#$%",+7<"

9+5,58?<,+28)8"

:7<"+7<3(2

@+5,58?<,+28)8

%-"A"5;"501"

7,6589+212

/01)23"

4)56788",01<8"

,5"B588)("B02(8"

$:27<"(2C2("(5D2123"

4?"E.F"62,218

#51<;)2(3G"$17<*2G"#H!"#$%&'()'*#+,'-+./012

I;"9+5,58?<,+28)8 8,598";122"

$%D50(3"42"*5<2")<"7450,"

JGKKK"?2718."

+,,9LMMDDD.78,15<56?<5,28.:56M85(718?8M8--.

+,6

+,,98LMM2<.D)N)923)7.51*MD)N)M$>?*2<O:?:(2

Page 23: Part 1 TMoore Artificial Photosynthesis 22 Oct 2018

!"

!"#$#%&'$"(%)%*+,)-(%*$"(*./%$*0/,1#'*0&02(!"#"$%&'()*$&*#%+,+%-&%.*$/0"./&#*.12$&0.2)&/324&%2&

0*/%&#-#3"&5+/#'*.6+$6&%'"&7*.%'8/9*#"&1*%%".-

#$$%&'((%)*+,-./01+.2/3(&,$4(25++406(/0,2,15+&(7,/8/9%/141$&:850*/1.;%2

Page 24: Part 1 TMoore Artificial Photosynthesis 22 Oct 2018

!"#$%&'()$*&'+,*&-"$".&/.&01230/1.&0456777*8"#$%9)()$9)+,9:"$"*;8$</<012<0456<:=,>54*25?6<8)):9/901290456@&AB$%=#C)D&0456 &EE&A$$#,FB$,=;&1 4&G,+8;)8

!"#$%&'()#*%&+&",

-,&,*.%/01'*%'&.232.+%.('*45,(4%&'()#*%5(#1%./,%4"#$%.#%./,%5'4.%&+&",%.#%6(#$%#0(%789%)0.%:,4.')2"2;2*6%./,%&'()#*%&+&",

<&,'*%'&2:252&'.2#*

06

Page 25: Part 1 TMoore Artificial Photosynthesis 22 Oct 2018

!"

#$$%&''((()*+,-.$/*#.01/!234)561',-.1/7'8%+5.97':;<=>"?:;<@3!A5*!B?C,0.+A6.D$?E#.%$/62F)%9D

!"#$#%&'$"(%)%*+,)-(%*$"(*./%$*0/,1#'*0&02(

!"#$%&'()*+,-&#'.&#,,/0-&1'.1$#2+&,+-+,3/1,&)#--&#'.&+4$5#'6+&7"(4+-&+-21)#2+.&7/,&25+&21)+&8,1/,&2/&25+&9'.(-2,1#"&:,#;&$1,$#&<=>?&@-++&A+$21/'&BC<C<C<&7/,&,+7+,+'$+-DC&E+.&#,,/0-&#'.&'()*+,-&1'.1$#2+&#''(#"&F#'25,/8/6+'1$G&7"(4+-&#3+,#6+.&/3+,&25+&H???IH??J&21)+&8+,1/.C

Page 26: Part 1 TMoore Artificial Photosynthesis 22 Oct 2018

!"#$$%&'(()))*+&,-*./00*1/2(,+&+0,3#($#+4+&(30,5/.(

!"##$%&&'$#()*+,$#-./0

Page 27: Part 1 TMoore Artificial Photosynthesis 22 Oct 2018

!""#$%&'()*+"',-."'$(/%'/0'-."'1%-.*/2/("%"3'4'/56"*+7-$/%6

83 976-'(7*5/%'(:(#"'$6';"6-75$#$<";

=3'>)*%$%&'0/66$#'0)"#6';$;'$-

43'?6($##7-$/%6'7*"'2./-/6:%-."6$6'7-'@/*A

!"

B$6(.7*&$%&'-."'C7*-.D627("'57--"*:'2*/;)("6'E?=7%;';"6-75$#$<"6'-."'&#/57#'(7*5/%'(:(#"

F"7*'#$$%&'((&)*+%%&,-)&.,/.-(%*01*23&(4//5+61)-*7/(8%9)06$/6$(%5-1+6&(&+09:5-/3006(1*2%#&()0!;<==4;>003,%61

Page 28: Part 1 TMoore Artificial Photosynthesis 22 Oct 2018

!"#$$%&'((&)*+%%&,-)&.,/.-(%*01*23&(4//5+61)-*7/(8%9)06$/6$(%5-1+6&(&+09:5-/3006(1*2%#&()0!;<=4,%61

!" #$%&'($)*+,'(-(./'0%'1/%&$*0.02/1

Page 29: Part 1 TMoore Artificial Photosynthesis 22 Oct 2018

!"!""#$%&&$'()##$*+'$,*-,+&#(./(01$&2--3)4/'+(5-&6#7'.4"-4"&#3+/)4$&$).783+-1..4&/(0#!$&'.9:;<<2*#4/

!"#$%&'(")(*+%,*-&'+%.#/&$,*0&++,'1*/'234$,#*567&)3*3,#+&0"8"9,#*+%,*(820&8*$&'02)*$1$8,

Page 30: Part 1 TMoore Artificial Photosynthesis 22 Oct 2018

!"#$%"$#&$'("#$)*"+,$-./ 0&1&02$*&3"4&$,5&$6&)2+4&6&(,2$"3$$7&&08(9:

!"#"$%&#'(()*)+',-".#/0-"")0-#,)0$"#1,#1$,%#"%+12#1(-#&1,3#,0'//-2#'10#4)44+-"5#63-"-#(%$,'1$#7'"-"#")(3#'"#89: !"#$%&'()'*'!")+,-

;4"6$8<&$<"4&2$#&$5)1&$)$9""%$4&<"4%$"3$,5&$=)4,5>2$?)2,$<086),&

./

Page 31: Part 1 TMoore Artificial Photosynthesis 22 Oct 2018

!"

!" #$%%&'()*$+,-&).&&+,&/0&11,()2$134&%*0,#5! (+6,-7%+*+8,9$11*',97&'1,3'71,0&2&+),3%$670)*$+

#$$%&''()*+%%(),-./)(0.10/'2*3%#+)(423551*6'73/8345,34*1),*0'73/8345,349,((+549/154$*180

:&6,#7%;&<,=$11*',97&',)%&+6,$9,(,9*/&6,9%(0)*$+,>?@A",$9,)4&,0727'()*;&,*+671)%*(',&2*11*$+1,$9,#5! 9%$2,9$11*',97&',0$2-71)*$+,(+6,0&2&+),3%$670)*$+B,

Page 32: Part 1 TMoore Artificial Photosynthesis 22 Oct 2018

!"#$$%&''()**+++,$-./,0122,314*356*17'.$28&*906$:,&'5/

!"#$%&'((#)*')#)*%#+,%-- .//%&)#0-#)*%#12-%34%5#5%&3%'-%#06#789:#'65#;8<:#4'(,%-#5,%#)1#/1--0(#/,%(#%=0--016->#?*0&*#'3%#5%@(%)%5#06#89:#'65#51#61)#&16)'06#8<:A#

&''()**+++,$-./,0122,314*356*17'.$28&*9-1'1($-*8;!'$//-7-,&'5/

;!<*;"<%%%-25(/$;!<*;"<%%%.$=$.$08$

>; ?%;@@@!89:#A

BC<<%D'& E--$--5$0'%F$(1.'

&''()**+++,8/952'$8&203$"@;!,1.3*.$(1.'*.$(1.'->3.2(&98*8&G>3.2(&98-*

619);@,;@;H*<IJKHL;;@HM;D!"M,@;D,

F$6%#17'&%C1/$I/28N%OPJ

Page 33: Part 1 TMoore Artificial Photosynthesis 22 Oct 2018

!"#$%&'(&)*+,$*,$-).+/'0&1*2$#34*/$)0&$/*5,-)61&$7+1$2-18+,$2+.*,5$71+.$)0&$'1+%62)/$+7$'0+)+/9,)0&/*/$:7+//*($76&(/;$

<,21&-/*,5$-).+/'0&1*2$#34

4; </+)+'*2$/*5,-)61&$2+,7*1./$)0-)$&=2&//$#34 2+.&/$71+.$861,*,5$7+//*($76&(/

!!"##$%&''((()(*+,-)./0'1234'25'6/7.89*.:6,+%;%:89#"+/$/<,9*.:.8+=/9:-*/>*-,:8--,9-;0'

!"#$%&'()*'(+,(-.*(/01234'(5(6+7$8+9(2111:;+-6(-,<&8=>+6$?(@23ABAC0 6+?&69(D6&<(E-F(G&<+(-%9(H&",>(I&.+'(5%,-6?,$?-'(J*(K+&=>;8*(!+8*(5,<&8*'(22L'(LML0NLMOO'(9&$P21*2110QRS69*T1UUL*

Page 34: Part 1 TMoore Artificial Photosynthesis 22 Oct 2018

!"

"##$%&$'()*$%#+%$,-)$!!&$./012/1$33345678968:;<4=><

Page 35: Part 1 TMoore Artificial Photosynthesis 22 Oct 2018

!"

!"#$%&'(()*'+,%#)-.#/0+*+%1,*0.%'%#)*#2+-3

4..(',5#&6-7.#8*0.#'&+,#+9#*0.#:,*0-+/+&.,."

Page 36: Part 1 TMoore Artificial Photosynthesis 22 Oct 2018

!""#$%%&&&'()*+',-..'/-0%/12%33//%"*(,2)%

!"#$#%&'$"(%)%*+,)-(%*$"(*.''/.0*1&10(%

!"#$%&'("$)(*%+&,%-.%/012

233%($*+/(*$#*4)'+/%$,).0*,(%5),.$)#'67"(*829 3,#:*;,#<)';*#/,*=>!

!"#$#%&'$"(%)%*5#<(,%*$"(*?)#%5"(,(*.'+*$"(*!"#$%&'$()( @ ?/$*)$*1.''#$*%/%$.)'.?0&*:(($*$"(*'((+%*#3*AB*?)00)#'*"/:.'%

Page 37: Part 1 TMoore Artificial Photosynthesis 22 Oct 2018

!"

!"#$%&'($)*+,-$.*/0$01)-$2-#-34$5"3$67% 89:-3$;&&$<<)

Page 38: Part 1 TMoore Artificial Photosynthesis 22 Oct 2018

!"#$%&'(#)*)*&+$,#)-##+$("&)&./+)"#.*.$0+1$2#.(*20)*&+$3$1#%0/

("&)&./+)"#.*.456 3$7

68$$$9:$$4765$3$56

;#.(*20

)*&+$3$1#

%0/456

3$768$$$<

9 4765$3

$56

!""#$%&&$'()##$*+'$,*-,+&#(./(01$&2--3)4/'+(5-&'0"-/.(6&2--3)4/7'+(5-7!)$".(6&

Page 39: Part 1 TMoore Artificial Photosynthesis 22 Oct 2018

!"#$%%&'() *++,++-,.(&/,012()((03445556789-:(,7):.;,<=>!612;42,012(42,012(+?;2:0)9747)@?;2:0)97+4 A193>=6>=>B4%CD"BE>>=BF>'!<F6=>'6

!"#$% !&'()*$+,-,.,+/0$% +,1'$/(23*$!45)(,&2,

6"0$7 6,4-,$"8,$095'(:,)8(;<=0$7 <84)>$=8&'$095'(:,)8(;

!"#$%& '()"#*+,#%& '()"#-(./###############0$#1#%& 2#$%&3%& 45#&67#8"#&69,999#++:

)((03445556.15G7671-6:G450?71.(,.(4G081:A+4<=>!4=!4%):.;,+?9.?%:2H1.A91I9A,?:.A?1IJ;,.?8,K,8+6L0;

Page 40: Part 1 TMoore Artificial Photosynthesis 22 Oct 2018

!"

!"#$% !&'()*$+,-,.,

+/0$% +,1'$/(23*$!45)(,&2,

6"0$7 6,4-,$"8,$095'(:,)8(;

<=0$7 <84)>$=8&'$095'(:,)8(;

Page 41: Part 1 TMoore Artificial Photosynthesis 22 Oct 2018

!"

!"#$% !&'()*$+,-,.,

+/0$% +,1'$/(23*$!45)(,&2,

6"0$7 6,4-,$"8,$095'(:,)8(;

<=0$7 <84)>$=8&'$095'(:,)8(;

Page 42: Part 1 TMoore Artificial Photosynthesis 22 Oct 2018

!" #$%&'()*)+',&-!!./0"&('123*45%&'(&,6%357&8452'21&9)(('6&94%6(&'(&*$%&:3;)5&()45,%&)9&0<! 3==%=&5%,%2*6>&*)&?35*$@(&3*:)(+$%5%&

!""#$%%&&&'()*+',-..'/-0%/12%-3"*(.4!%5)-"-#()%467"(++)3)'!"1+

Page 43: Part 1 TMoore Artificial Photosynthesis 22 Oct 2018

!"

!"#$%&#'()#*(+$,-&.#$%&#)/0'1/#2/034#02#56 1"7#+1-'0"#1"7#1440+(1$&7#&"&-)8#7-(9&"#'8#*%0$048"$%&4(4#1-&#

:,1/($1$(9&/8#,"7&-4$007;##

Page 44: Part 1 TMoore Artificial Photosynthesis 22 Oct 2018

!"#$%&#'()*+,,'-./)0122)*.%3$"4&4)5"67-3/)879):;;< ==

Page 45: Part 1 TMoore Artificial Photosynthesis 22 Oct 2018

!"#$%&#'()*+,,'-./)0122)*.%3$"4&4)5"67-3/)879):;;<*"")'(47)))!"#$%& !"#$%&#'%(!"#$)

*+%,##$###%-.%/-/01

2+%&&# 34%&"5!#",$###%-. /-/01

6+%&7$###%-./-/01

=&('%>79&3#$ #.#("4)?-&9")3$")@('#&'(A&%3"-@('#&'()6"-&7?4

"!

Page 46: Part 1 TMoore Artificial Photosynthesis 22 Oct 2018

!"

Figure 1 | Milankovitch cycles. In 1976, Hays, Imbrie and Shackleton1 provided the first clear evidence that variations in Earth’s orbit around the Sun dramatically change our planet’s climate, a concept known as the Milankovitch theory2. There are three types of variation: eccentricity, obliquity and precession1,2. a, Eccentricity describes the shape of Earth’s orbit around the Sun, and varies from being almost a circle to an ellipse, with a period of about 96,000 years6. b, Obliquity is the tilt of Earth’s axis of rotation with respect to the plane of its orbit, and it oscillates with a period of about 41,000 years6,8. c, Both Earth’s rotational axis and its orbital path precess (rotate) over time — the combined effects of these two components and the eccentricity produce an approximately 21,000-year cycle6,7.

In Retrospect Forty years of linking orbits to ice ages

!"#$%& #!$%&'$(&)!"#$*

Page 47: Part 1 TMoore Artificial Photosynthesis 22 Oct 2018

!"

#$%&'()'($*+',$%+

-((./011$*2/34&5635)*15)*$5/1+78(-9(+*.+87(:8+9($*+,$%+3.%2

-((./0114&5635)*1;"<=1

Page 48: Part 1 TMoore Artificial Photosynthesis 22 Oct 2018

!"

#$%&%'$&()*+$&,%&'%%-.//0001$23415),,16)*/6(7/8866/%3$572/'+2%)391'%(4

Measuring the Atmospheric CO2Increase

Page 49: Part 1 TMoore Artificial Photosynthesis 22 Oct 2018

!"

!"#$%&'(")$*+&'%,'"*,-&./0 -%#%-'&,*1&2(,*+%&3%4)%%*&5&,*1&6&(%7$'8(%9%'

#$$%&''((()*+,-.+-/01)231'%324-+$*'50$06*$23,-*'(,..-3*'789:

Page 50: Part 1 TMoore Artificial Photosynthesis 22 Oct 2018

!"

!"#$%%&'&("#'(#)*+"&",#-(..&/#-*0/.#$.#10#%(#'(%$23#14$'#$+0#.(50#('40+#.(*+60.#(-#789:

Page 51: Part 1 TMoore Artificial Photosynthesis 22 Oct 2018

!"#$$%&''(%)*+,(-(+.)/'(%)*'(%"0"012+#$34

!"#"$%"&'()'*+,*

-"'./0#12"&".'314'51'5&6708"&'#6&%17'8&1$'53"'0914'#6&%17'#:#9"'51'53"'8605'#6&%17'#:#9"'67.';&14'1<&'=!>

Page 52: Part 1 TMoore Artificial Photosynthesis 22 Oct 2018

!"#$$%&''(%)*+,(-(+.)/'(%)*'(%0011"2+#$34

!"#$%&$'()*+(),,,

-.$(/01.'"2"3$0$ 4'5 "000567(8469:8$;<,

Page 53: Part 1 TMoore Artificial Photosynthesis 22 Oct 2018

!"

!"#$%&'()*(+,-(".(//(01$(234(1',5".6(78/(49:;<(/7(1)#,1(94(=#$(9>4?

Page 54: Part 1 TMoore Artificial Photosynthesis 22 Oct 2018

!"

!"#$%##"&'(

)*+,-.%'/,+/#-&0-1"22"&'#-&0-3+4,#-5+0&,+-6.+-7'6.,&8&$+'+-94#-:4,6.-4-;,++'-.&%#+-824'+6<

Page 55: Part 1 TMoore Artificial Photosynthesis 22 Oct 2018

!!

!"#$%##"&'(

)*+,-"#-,*.-/+0&1-21..'-*&%#.-2+#-"'-3+1,*4#-+,/&#5*.1.-,&6+78+9)+,.1-:+5&1;9<.,*+'.$9=>?69@>A

Page 56: Part 1 TMoore Artificial Photosynthesis 22 Oct 2018

!"

!"#$%"$ !!" #!"$%&'(')

!""#$%&'($")#*+$,(&-('.&-/0$1&233&4&/*&56&78

9(&:(*1&,$*(+#%&;"&,<$"=;"=&8>2 %(:(%)

Page 57: Part 1 TMoore Artificial Photosynthesis 22 Oct 2018

!"

!"#$"%&#'(%")*+#,-#'.(-/,-/#012#+"$"+3

Page 58: Part 1 TMoore Artificial Photosynthesis 22 Oct 2018

!"

#$$%&'()(*+,%-,($.-%&/%012%+*$%3+45.%67.%$4*+3(8-%-,($.-

!"#$%#&'(&)*++,$-).$/'+*&'0$%/#-+'1231'&4*('$5+*&4/*&'2%'/1*6/#2&

Page 59: Part 1 TMoore Artificial Photosynthesis 22 Oct 2018

!"

#$$%&'(()*+,+)-./+0(12$3/,*&(0*$#14*5#-621$*&(0*$#14*5#-621$*5347*4$+2-501%.8%)

#$$%&'(()*+,+)-./+0(12$3/,*&(0*$#14*5#-621$*&(

!"#$%&'#(%)*+&$#(*#,-./$.(&+#(0#1/#2#*($-(0#(&(1&+3#+(%)*+-4&+0-'(+#.-5+4#($%&'(&11(-6($%#(7-+1*8.(-/19('&$5+&1(3&.(&'*(4-&1 +#.-5+4#.(4-"0/'#*:;<=

9:;<!"#"$#%&$'()*%+,&$-%.'<=$*%#*4<>*&&*,,&?<@1A21<=$*24?<=$*7*<B32C-D<E43$*6<=$1$*&<F*+,+)3/1,<=A27*-<GA,$30*631<F1,,*2-<H36*+?<IJ:I.<

Page 60: Part 1 TMoore Artificial Photosynthesis 22 Oct 2018

!"#$$%&'(()*+,)$&-).++/,)0-*1(2"34("5("6(-78&,9:*)97%%)*%).7$,9-*;-,);9*<,)97)-$.-91,$#7;,9*<,)+8)=,;9%/81,&9,)8%$.*;&97;=9/7)>,9*-,7;9-)7$,)&(

Page 61: Part 1 TMoore Artificial Photosynthesis 22 Oct 2018

!"#$$%&'(()*+,)$&-).++/,)0-*1(23"4(35(36(-78&,9:*)97%%)*%).7$,9-*;-,);9*<,)97)-$.-91,$#7;,9*<,)+8)=,;9%/81,&9,)8%$.*;&97;=9/7)>,9*-,7;9-)7$,)&

Page 62: Part 1 TMoore Artificial Photosynthesis 22 Oct 2018

!"

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

4*%'(6*I2C*+B$+D*6I:0$4*1I*+$:%5261I(6DI0(+7*I2;*(6I;+(%*+1

!"#$%&"'()"#$%&"(*+%#$,%#"("-.+/01/&

Page 63: Part 1 TMoore Artificial Photosynthesis 22 Oct 2018

!"

!"#$%##"&'

(&)*+&',*-&.#*/01 #234*"'*25.*326&#75.8.9*

Page 64: Part 1 TMoore Artificial Photosynthesis 22 Oct 2018

!"

#$%#&'&(&)*%+,%-'$*%!"#$%&'()*%&+$(,%&-$.%&/%-%+%&./!*%.0/"%12//34$

!"#$%"&'$(")*$+,- *./0$1&$.2)$/.3"*42)5)6

!"#$%

&'-

Page 65: Part 1 TMoore Artificial Photosynthesis 22 Oct 2018

!"!"#$

!"#$

!"#$

#$%#&'&(&)*%+,%-'$*%!"#$%&'()*%&+$(,%&-$.%&/%-%+%&./!*%.0/1%23//45$

!"#$%"&'$(")*$+,- *./0$1&$.2)$/.3"*42)5)6

!"#$%

Page 66: Part 1 TMoore Artificial Photosynthesis 22 Oct 2018

!!"##$%&''((()*%+,)-.//)0.1'023'4400'4/+5.-#+/46*+'

!"#$%

!"#$%&'($%)#*)#$#+&%,%$&,-(.(/#0%.#1#.%"2%345 (+%&'#%,&6"$*'#)#7

Page 67: Part 1 TMoore Artificial Photosynthesis 22 Oct 2018

!"

!"#$%&'()'()*%+'$,-#.&/)012 $%*3&4&5*%&'(6&7#()%-#)*%+'$,-#.&/)012 4#7#4$)89:)*(;).*%#$)'<)#+&$$&'()'<)012 8=:)$-'>()'()%-#)?.*,-$)3#4'>@)>-*%).*%#)'<),.';"/%&'()'<)*%+'$,-#.&/)012 $-'>()&()8=:)>'"4;)$%*3&4&5#)*%+'$,-#.&/)4#7#4$)*%)*3'"%)ABC),,+@)$-'>()&()89:)DEEEEEEEEEEEFG)H#4#/%)D*F)$%*3&4&5#;).*%#)'<)#+&$$&'($@)D3F);#/.#*$&(?).*%#)'<)#+&$$&'($@)D/F)5#.').*%#)'<)#+&$$&'()$%*.%&(?)%';*IJ

!"#$%&'%()*+,&-./#0&1%2304"#&1/",5&1%67$",8

#$

#%

$

%K&+#)DI#*.$F

9#:&;+<$,0/%()* =$>$=%2++:8

$%%

&%%

'%%

K&+#)DI#*.$F

EEEEEEEEEEEEEEEEEEEEEEEEEEEEEEEE

%';*I 2BBL

M*%#)'<)012.#+'7*4

D3FD/F

D*F

89:

8=:

H##)H%#.+*(@)!"#$%"$D2CCNF)&''( OP2EOPP)

()*+,-,./01*)23456/7,81-/9/-

%';*I 2BBL

Page 68: Part 1 TMoore Artificial Photosynthesis 22 Oct 2018

24 OCTOBER 2008 VOL 322 SCIENCE www.sciencemag.org

Page 69: Part 1 TMoore Artificial Photosynthesis 22 Oct 2018
Page 70: Part 1 TMoore Artificial Photosynthesis 22 Oct 2018

!""

#""

$""

%""

&""

'""

(""

)*"" )*%" !""" !"%" !)"" !)%" !!""

+,-./-012345,-1-./678

9:,;.<88

+,-=.6-.83>/==/,-=6?.1:8!")"

)""@,?8!")"8:6.1

##@

)"@"@A:1/-20=.:/678B1C17

!("855>

D6E6:2,0=8B1C17$%"855>

D6E6:2,0=8B1C17$%"855>

!"#$%&%'()*+,*(,"-#"%+,). ,+")-#"()+/)(0%11%+,1

!"#$%%&

'

()*+

2+3)04*5)678 %1)#**(9"#$&(:;,<%-+,0(,"#&)=%0%"1). >+")?(1+4-*()=%0%"1

@(-)*#9%"#)(0%11%+,1)5#<()"+)A+)"+)'(-+)-(A#-B&(11)+/)"5()&%0%"

,-*./012314516*7/.)+ *21!8!9

,-*./012314516*7/.)+:1!).2)+1;3+18)<*2=>)1!*+?3.19&=00=3.0