PAPER-1 Academic Session: 2017-18 C 0 MAJOR TEST-1 (MT-1) · MATHEMATICS MATHEMATICS Space for...
Transcript of PAPER-1 Academic Session: 2017-18 C 0 MAJOR TEST-1 (MT-1) · MATHEMATICS MATHEMATICS Space for...
®
Academic Session: 2017-18
MMAAJJOORR TTEESSTT--11 ((MMTT--11))((JJEEEE AADDVVAANNCCEEDD PPAATTTTEERRNN))
TTaarrggeett :: JJEEEE ((MMaaiinn++AAddvvaanncceedd)) 22001188
Please read the last page of this booklet for the instructions.(Ñi;k funsZ'kksa ds fy;s bl iqfLrdk ds vfUre i`"B dks i<+sA)
RReessoonnaannccee EEdduuvveennttuurreess LLttdd..CCOORRPPOORRAATTEE OOFFFFIICCEE :: CCGG TToowweerr,, AA--4466 && 5522,, IIPPIIAA,, NNeeaarr CCiittyy MMaallll,, JJhhaallaawwaarr RRooaadd,, KKoottaa ((RRaajj..)) -- 332244000055
PPhh..NNoo.. :: ++9911--774444--33001122222222,, 66663355555555 || TToollll FFrreeee :: 11880000 225588 55555555RReegg.. OOffffiiccee :: JJ--22,, JJaawwaahhaarr NNaaggaarr,, MMaaiinn RRooaadd,, KKoottaa ((RRaajj..))--332244000055 || PPhh.. NNoo..:: ++9911--774444--33119922222222 || FFAAXX NNoo.. :: ++9911--002222--3399116677222222
WWeebbssiittee ::wwwwww..rreessoonnaannccee..aacc..iinn || EE--mmaaiill :: ccoonnttaacctt@@rreessoonnaannccee..aacc..iinn || CCIINN:: UU8800330022RRJJ22000077PPLLCC002244002299
DDaattee:: 1177--1122--22001177 || DDuurraattiioonn :: 33 HHoouurrss || MMaaxx.. MMaarrkkss:: 224400
CCOODDEE -- 00
P21-17PPAAPPEERR--11
DO
NO
T B
RE
AK
TH
E
SE
AL
W
ITH
OU
T B
EIN
GIN
ST
RU
CT
ED
TO
DO
SO
BY
TH
E I
NV
IGIL
AT
OR
CCOOUURRSSEE :: VVIIJJEETTAA ((0022JJPP))
MA
TH
EM
AT
ICS
MATHEMATICS
Space for Rough Work
Corporate Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.)-324005
Website : www.resonance.ac.in | E-mail : [email protected]
Toll Free : 1800 258 5555 | CIN: U80302RJ2007PLC024029P102JPMT1ADV171217C0-1
PART : I MATHEMATICS
SECTION – 1 : (Maximum Marks : 60)
This section contains FIFTEEN questions Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these
four option(s) is(are) correct For each question, darken the bubble(s) corresponding to all the correct option(s) in the ORS Marking scheme :
+4 If the bubbles corresponding to the answers are darkened0 If none of the bubbles is darkened
–2 In all other cases
1. Let f(x) =
x
0(5 1 t )dt if x 2
5x 1, if x 2
then the function is
(A) continuous at x = 2 (B) differentiable at x = 2(C) discontinuous at x = 2 (D) not differentiable at x = 2
2. The coordinates of a point on the linex 1 y 1
z2 3
at a distance 4 14 from the point (1, –1, 0)
are
(A) 9, 13, 4 (B) 8 14 1, 12 14 1, 4 14
(C) 7, 11, 4 (D) 8 14 1, 12 14 1, 4 14
MA
TH
EM
AT
ICS
MATHEMATICS
Space for Rough Work
Corporate Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.)-324005
Website : www.resonance.ac.in | E-mail : [email protected]
Toll Free : 1800 258 5555 | CIN: U80302RJ2007PLC024029P102JPMT1ADV171217C0-2
3. For any complex number w = a + bi, where a, b R and i 1 . If w cos40 isin40 , then
| 2 3 9w 2w 3w .... 9w |–1 equals
(A) (1
sin409
)sec(20º) (B)2
sin209
(C)1
cos409
(D)9
cosec 202
4. If locus of z is a curve satisfying )z(Re|)i23(z| and z1 & z2 are two point on the curve such
that
)i23(z
)i23(zarg
2
1 then
(A) locus of z is a parabola
(B) locus of z is an ellipse
(C)2i2z
i2zarg
2
1
for all z1, z2 satisfying given condition
(D)2z
zarg
2
1
for all z1, z2 satisfying given condition
5. Let point P moves in first quadrant while satisfying (given O : (0,0), A : (4, 4 3 ) and B : (4,0))(1) It is closer to x - axis than to line OA, and(2) It is closer to origin than to point B,Then area of the region in which point P can move is greater than or equal to .
(A)2
3(B) 3
4
(C)
10
9(D) 1
MA
TH
EM
AT
ICS
MATHEMATICS
Space for Rough Work
Corporate Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.)-324005
Website : www.resonance.ac.in | E-mail : [email protected]
Toll Free : 1800 258 5555 | CIN: U80302RJ2007PLC024029P102JPMT1ADV171217C0-3
6. Given/ 2 / 2 / 2
0 0 0
I cos(sinx)dx, J sin(cos x)dx, K cos xdx,
then which of the following is wrong
(A) I > K > J (B) I > J > K (C) K > I > J (D) K > J > I
7. Let In = /2
n
0
sin x dx
then which of the following statement (s) is (are) true.
(A) 2I 4
(B) 4
3I
16
(C) 1I 1 (D) 3I 3
8. Ten passengers get into an elevator on the ground floor which stops at 20- different floors above
ground floor then the probability that they will all get out at different floors is
(A) 10
20!
10! 20(B)
10
1.3.5...17.19
10(C)
919!
10! 20(D) 20
10!
10
9. Solution to the equation 13x tan (tanx) for x 0, 2 may contain
(A) (0, / 2) (B) ( / 2, ) (C) ( , 3 / 2) (D) (3 / 2, 2 )
MA
TH
EM
AT
ICS
MATHEMATICS
Space for Rough Work
Corporate Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.)-324005
Website : www.resonance.ac.in | E-mail : [email protected]
Toll Free : 1800 258 5555 | CIN: U80302RJ2007PLC024029P102JPMT1ADV171217C0-4
10. Let2n
e e
2n 1n
alog (2 x ) bx log (4 x )f(x) lim
a bx
where a, b R, ab ≠ 0. Then
(A)x 1limf(x)
exists (B)x 1limf(x)
does not exist
(C)x 1lim f(x)
exists (D)x 1lim f(x)
does not exist
11. Let g(x) be a differentiable function for all x, and f(x) = f() + (x – ).g(x) x R. Then
(A) f(x) is necessarily continuous at x = .
(B) f(x) is necessarily differentiable at x = .
(C) f(x) is necessarily continuous at all x R – {}
(D) f '( ) g( )
12. A fair coin is tossed n times. Then
(A) the probability of getting tails an odd number of times is2
1 when n is odd.
(B) the probability of getting tails an odd number of times is2
1 when n is even.
(C) the probability of getting at least one tail is more than 0.99 for n = 7.
(D) the probability of getting at least one tail is more than 0.99 for n = 8.
13. 1
4n 1
4ntan
n 5
(A)4
+ tan–1 2 (B)
4
3–tan–1 2 (C) tan–13 (D)
4
+ cot–12
MA
TH
EM
AT
ICS
MATHEMATICS
Space for Rough Work
Corporate Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.)-324005
Website : www.resonance.ac.in | E-mail : [email protected]
Toll Free : 1800 258 5555 | CIN: U80302RJ2007PLC024029P102JPMT1ADV171217C0-5
14. Let f : [a, b] R be a function such that for c (a, b), f i(c) = fii(c) = fiii(c) = fiv(c) = fv(c) = 0, then
(fn(c) represents nth derivative of f(x))
(A) f has local extremism at x = c
(B) f has neither local maximum nor local minimum at x = c
(C) f is necessarily a constant function
(D) None of these
15. Which of the following is/are correct
(A) The number of skew symmetric 3×3 matrices than can be formed using elements –1, 0, 1 and 2 is 27
(B) The number of skew symmetric 3×3 matrices than can be formed using elements –1, 0, 1 and 2 is 64
(C) The number of symmetric 3×3 matrices than can be formed using elements –1, 0, 1 and 2 is (12)3
(D) The number of either symmetric or skew symmetric 3 x 3 matrices than can be formed using
elements –1, 0, 1 and 2 is 1754
MA
TH
EM
AT
ICS
MATHEMATICS
Space for Rough Work
Corporate Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.)-324005
Website : www.resonance.ac.in | E-mail : [email protected]
Toll Free : 1800 258 5555 | CIN: U80302RJ2007PLC024029P102JPMT1ADV171217C0-6
SECTION – 2 : (Maximum Marks : 20) This section contains FIVE questions The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 to 9, both inclusive For each question, darken the bubble corresponding to the correct integer in the ORS Marking scheme :
+4 If the bubble corresponding to the answer is darkened0 If none of the bubbles is darkened
–1 In all other cases
16. Let f(x) x sinx be an invertible function in
2
,0 . If area bounded by y = f–1 (x) and y = f(x) in
2
,0 is k then value of [6k] will be ({ } represents GIF)
17. If
2n 2n
r 1 r 1
nn
r 1
1r
rlim
34 r
, then =
18. The domain of definition of the function, f (x) =2
1
2
3x 7x 8cos
x 1
where [.] denotes the greatest
integer function, is (a, b). Then a + b =
19. Let (h, k) be a point with integral co-ordinates from which two tangents drawn to the hyperbola2 2x y
17 3 are perpendicular, then the number of distinct values of (h + k) is
20. The solution of the differential equation1
3(x 1)dy ydx x(x 1)y dx is given by2 2
23 31 2
y A(x 1) (x 1) (x 1),4
then the value of should be
Space for Rough Work
PHYSICS
PH
YS
ICS
Corporate Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.)- 324005
Website : www.resonance.ac.in | E-mail : [email protected]®
Toll Free :1800 258 5555 | CIN: U80302RJ2007PLC024029P102JPMT1ADV171217C0-7
PART - II : PHYSICS
SECTION – 1 : (Maximum Marks : 60) This section contains FIFTEEN questions Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these
four option(s) is(are) correct For each question, darken the bubble(s) corresponding to all the correct option(s) in the ORS Marking scheme :
+4 If the bubbles corresponding to the answers are darkened 0 If none of the bubbles is darkened–2 In all other cases
21. Two series resonant circuits with component values L1, C1 and L2, C2 respectively have the sameresonant frequency. They are then connected in series ; the resonant frequency of the combinationis :
(A)1 1
1
2 L C(B)
2 2
1
2 L C
(C) 1 2 1 2
1
2 L L C C (D)
1 2
1
2 L C
22. A non-relativistic particle of mass m is held in a circular orbit around the origin by an attractive
force. The potential energy of the force is given by U(r) =2kr
2.
Assuming the Bohr quantization of the angular momentum of the particle select correctalternatives.
(A)1/2
2 n kv
m m
(B)
1/2n k
rk m
(C)
1/2
nk
E nm
(D) n
kE n
m
Space for Rough Work
PHYSICS
PH
YS
ICS
Corporate Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.)- 324005
Website : www.resonance.ac.in | E-mail : [email protected]®
Toll Free :1800 258 5555 | CIN: U80302RJ2007PLC024029P102JPMT1ADV171217C0-8
23. Two half convex lenses of focal lengths f1 = 16 cm and f2 = 21 cm respectively are placed such
that their principal axes coincide. Both the lenses form image of a real point object O on a fixedscreen as shown. The distance between object and screen is 100 cm. Then pick up the correctstatement(s)
O
f =16cm1
f =21cm2
lens1
lens2principal axis
fixed screen
(A) The distance of lens1 from object O can be 20 cm(B) The distance of lens 1 from object O can be 80 cm(C) The distance of lens 2 from object O can be 30 cm(D) The distance of lens 2 from object O can be 70 cm
24. A positive charge q is placed inside a neutral hollow conducting sphere of radius R, as shown infigure. Whole system is placed in uniform external vertical electric field pointing downward(line PCQ is also vertical) then select the correct statement(s) about electric field at point P. PointP is a point of the material inside the conductor.
R/2C
P
E
(A) Electric field due to outer surface of sphere at point P is zero
(B) Magnitude of electric field due to inner surface of sphere at point P is2
0
q
9 R(C) Magnitude of electric field at point P, due to hollow sphere is less than E(D) Direction of resultant electric field at point P due to charge q and hollow sphere is verticallyupward
Space for Rough Work
Space for Rough Work
PHYSICS
PH
YS
ICS
Corporate Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.)- 324005
Website : www.resonance.ac.in | E-mail : [email protected]®
Toll Free :1800 258 5555 | CIN: U80302RJ2007PLC024029P102JPMT1ADV171217C0-9
25. The range of voltage of a meter used as a voltmeter can be changed to n times its original valuewith the help of a 27 multiplier. Using the same meter as an ammeter, its range of current can bechanged to n times its original value using a 3 shunt. The power dissipated by the moving-coil ofthe meter when giving a full-scale reading is 9 × 10–4 W. Select the correct statement(s).(A) The resistance of the coil is 9 (B) The resistance of the coil is 81 (C) The full deflection current is 9 mA(D) The full deflection current is 10 mA
26. A tightly-wound rigid solenoid coil has been partly inserted into another. They are connected to aconstant current source so that the same current I flows through them ; both generate a magnetic
field in the same direction. The solenoids have N turns both, their length is , their cross-sectional
areas are A1 and A2. It may be assumed that A1, A2 < 2. The centers of the coils are at a distance
x < along their common axis [A1, A2 << (x – )2, x2].
(A) Total energy of the magnetic field in the system is 2 2
01 22
N[A A 3 2x ]
2
(B) The electromotive forces generated in the inner coils is2
0 22
A N
(C) The electromotive forces generated in the outer coils is2
0 22
A N
(D) The electromotive forces generated in the outer coils is zero
27. When no current is passed through a conductor(A) the free electrons do not move(B) the average speed of a free electron over a large period of time is zero(C) the average velocity of a free electron over a large period of time is zero(D) the average of the velocities of all the free electrons at an instant is zero
Space for Rough Work
PHYSICS
PH
YS
ICS
Corporate Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.)- 324005
Website : www.resonance.ac.in | E-mail : [email protected]®
Toll Free :1800 258 5555 | CIN: U80302RJ2007PLC024029P102JPMT1ADV171217C0-10
28. In the given circuit all ammeters are ideal. Then choose correct statement.
A4
A3
A2
A1
A5
10V
5V
10V
8V
(A) Reading of A2 = Reading of A5.(B) Reading of A2 and Reading of A4 both are zero.(C) Reading of A1 is 5 amp(D) Reading of A1 = 2.5 times reading of A3.
29. Two capacitors of capacitance 1 µF and 2 µF are separately charged by a common battery. Thetwo capacitors start discharging through equal resistances separately at t = 0.(A) The current in each of the two discharging circuit is zero at t = 0(B) The currents in the two discharging circuits at t = 0 are equal but not zero(C) The currents in two discharging circuits are equal at all times(D) Capacitor of 1 µF capacity loses 50% of its charge earlier than capacitor of capacity 2 µF
30. The radii of a spherical capacitor are equal to a and b (b > a). The space between them is filledwith a dielectric of dielectric constant K and resistivity . At t = 0, the inner electrode is given acharge q0. Choose the correct option(s) :
(A) Charge q on the inner electrode as a function of time is given by 0
t
K0q q e
(B) In a short time, the charge on the inner electrode will become zero(C) After a long time, the charge on the outer sphere will become q0
(D) The total amount of heat generated during the spreading of charge will be given by2
0
0
q1 1H
a b 8
Space for Rough Work
Space for Rough Work
PHYSICS
PH
YS
ICS
Corporate Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.)- 324005
Website : www.resonance.ac.in | E-mail : [email protected]®
Toll Free :1800 258 5555 | CIN: U80302RJ2007PLC024029P102JPMT1ADV171217C0-11
31. A small current element of length ‘ d’ and carrying current is placed at (1, 1, 0) and is carrying
current in ‘ + z ’ direction. If magnetic field at origin be 1B
and at point (2, 2, 0) be 2B
then :
(A) 1 2|B | |B |
(B) 1 2B B
(C) 1 2| ||B | 2B
(D) 1 2B 2B
32. A charged particle is projected in magnetic field B
= 10 k̂ from origin in x-y plane. The particle moves in a
circle and just touches a line y = 5 m at x = 5 3 m. Then (mass of particle = 5 × 10–5 kg, charge = 1µc) -
(A) The particle is projected at an angle 60° with x-axis
(B) The radius of circle is 10 m
(C) speed of particle is 2m/s
(D) workdone by magnetic force on the particle is zero.
33. A neutron beam, in which each neutron has same kinetic energy, is passed through a sample of
hydrogen like gas (but not hydrogen) in ground state and at rest. Due to collision of neutrons with
the ions of the gas, ions are excited and then they emit photons. Six spectral lines are obtained in
which one of the lines is of wavelength (6200/51) nm. The mass of neutron and proton can be
assumed to be nearly same. Use hc = 12400 eVÅ.
(A) The gas is helium
(B) This gas is lithium
(C) minimum possible value of kinetic energy of the neutrons for this to be possible is 63.75 eV
(D) minimum possible value of kinetic energy of the neutrons for this to be possible is 12.75 eV
Space for Rough Work
PHYSICS
PH
YS
ICS
Corporate Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.)- 324005
Website : www.resonance.ac.in | E-mail : [email protected]®
Toll Free :1800 258 5555 | CIN: U80302RJ2007PLC024029P102JPMT1ADV171217C0-12
34. In a decay process A decays to B,
AB
Two graphs of number of nucli of A and B versus time is given then :
(A) t2 – t1 = 4 (B) t2 – t1 = 2 (C) t1 = 2 log25 (D) t2 = log2100
35. Graph shows variation of source emf V and current i in a series RLC circuit, with time.
i
V
t
V/i
(A) The current leads the emf in the circuit.
(B) The circuit is more inductive than capacitive.
(C) To increase the rate at which energy is transferred to the resistive load, L should be decreased.
(D) To increase the rate at which energy is transferred to the resistive load, L should be increased.
Space for Rough Work
PHYSICS
PH
YS
ICS
Corporate Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.)- 324005
Website : www.resonance.ac.in | E-mail : [email protected]®
Toll Free :1800 258 5555 | CIN: U80302RJ2007PLC024029P102JPMT1ADV171217C0-13
SECTION – 2 : (Maximum Marks : 20)
This section contains FIVE questions
The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 to 9, both inclusive
For each question, darken the bubble corresponding to the correct integer in the ORS
Marking scheme :+4 If the bubble corresponding to the answer is darkened 0 If none of the bubbles is darkened–1 In all other cases
36. A parallel beam of light falls on a quarter cylinder of radius 9 cm, as shown in figure (A). Refractive
index of the material of the cylinder is 3 . Maximum value of OP (in cm ), as shown in figure (B),
so that rays don’t suffer TIR at the curved surface is (consider refractive index of surroundingmedium equal to 1)
(B)
PO
(A)
O600
37. Light of wavelength 6000Å falls normally on a thin wedge shape film of refractive index 1.5, fringesthat are 2mm apart. The angle of the wedge is nearly P × 10–4 rad. Find the value of P.
38. The K line has a wavelength for an element with atomic number Z = 19. The atomic number of
an element with has wavelength /4 for the K line is 10P + Q. Find the value of Q – P ?
Space for Rough Work
PHYSICS
PH
YS
ICS
Corporate Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.)- 324005
Website : www.resonance.ac.in | E-mail : [email protected]®
Toll Free :1800 258 5555 | CIN: U80302RJ2007PLC024029P102JPMT1ADV171217C0-14
39. The electric field in a region is radially outwards with magnitude E = r/. In a sphere of radius R
centered at the origin, calculate the value of charge in coulombs if5
V/m2 and
1/ 33
R m10
.
40. In the L–C circuit, the capacitor C1 is charged to a potential of 1 volt, and the capacitor C2 and the
inductor were initially uncharged. Now switch S1 is closed at t = 0, and at t =1.5
100
sec. switch S2 is
closed and S1 is opened. After0.5
100
sec. , S2 is also opened. Find final potential difference across
the capacitor C2 in volt.
Space for Rough Work
CH
EM
IST
RY
CHEMISTRY
Space for Rough Work
Corporate Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.)-324005
Website : www.resonance.ac.in | E-mail : [email protected]
Toll Free : 1800 258 5555 |CIN: U80302RJ2007PLC024029P102JPMT1ADV171217C0-15
PART - III : CHEMISTRYAtomic masses : [H = 1, D = 2, Li = 7, C = 12, N = 14, O = 16, F = 19, Na = 23, Mg = 24, Al = 27, Si = 28,
P = 31, S = 32, Cl = 35.5, K = 39, Ca = 40, Cr = 52, Mn = 55, Fe = 56, Cu = 63.5, Zn = 65, As = 75,
Br = 80, Ag = 108, I = 127, Ba = 137, Hg = 200, Pb = 207]
SECTION – 1 : (Maximum Marks : 60)
This section contains FIFTEEN questions
Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these
four option(s) is(are) correct
For each question, darken the bubble(s) corresponding to all the correct option(s) in the ORS
Marking scheme :
+4 If the bubbles corresponding to the answers are darkened
0 If none of the bubbles is darkened
–2 In all other cases
41. For the endothermic reaction
3A(g) B(g) + C(g)
select the option(s) by which equilibrium concentration of A(g) can be increased ?
(A) Decreasing the temperature
(B) Increasing the volume of the container
(C) Decreasing the volume of the container
(D) Adding B(g) at equilibrium
CH
EM
IST
RY
CHEMISTRY
Space for Rough Work
Corporate Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.)-324005
Website : www.resonance.ac.in | E-mail : [email protected]
Toll Free : 1800 258 5555 |CIN: U80302RJ2007PLC024029P102JPMT1ADV171217C0-16
42. Which of the following statement(s) is/are correct ?
(A) Diamond have dangling bonds
(B) Fullerenes are cage-like molecules.
(C) Graphite is thermodynamically most stable allotrope of carbon.
(D) Graphite is slippery and therefore is used as dry lubricant in machines.
43. Which of the following is/are correctly matched for given species ?
(A) XeO3 : Three (p-d) bonds (B) H2SO3 : One (p-d) bonds
(C) SO3 : Three (p-d) bonds (D) HClO3 : Two (p-d) bonds
44. At Boyle’s temperature, the graph of Z v/s P is drawn for H2. Select incorrect graph(s) :
(A)
P 200 atm
(B)
200 atm
(C)
200 atm
(D)
Z
P 200 atm
CH
EM
IST
RY
CHEMISTRY
Space for Rough Work
Corporate Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.)-324005
Website : www.resonance.ac.in | E-mail : [email protected]
Toll Free : 1800 258 5555 |CIN: U80302RJ2007PLC024029P102JPMT1ADV171217C0-17
45. An amount of 20g potassium sulphate was dissolved in 150 cm3 of water. The solution was then
electrolysed. After electrolysis the content of potassium sulphate in the solution was 15% by mass.
Determine volume of the gases obtained at NTP ? ( OH2d = 1 g cm–3)
(A) 45.6 L H2 gas (B) 22.8L O2 gas
(C) 42 L H2 gas (D) None of these
46. Titanium metal is extensively used in aerospace industry because the metal imparts strength to
structures but does not unduly add to their masses. The metal is produced by the reduction of
TiCl4() which in turn is produced from mineral rutile TiO2(s). The following reaction for production
of TiCl4() be carried out at 25ºC: TiO2(s) + 2Cl2(g) TiCl4()+O2(g)
Given that ºfH for TiO2(s), TiCl4(), Cl2(g) and O2(g) is –944.7, –804.2, 0.0, 0.0 KJ mol–1. Sº for
TiO2 (s), TiCl4 (), Cl2 (g) and O2(g) is 50.3, 252.3, 233.0, 205.1 Jmol–1K–1 respectively. Select
correct option(s) :
(A) ºrH 0
(B) ºrS 0
(C) ºrG 0
(D) Reaction is not possible under standard conditions
47. A buffer solution can be prepared by mixing solution of :
(A) Potassium chloride and Potassium hydroxide.
(B) Ammonium hydroxide and Ammonium chloride.
(C) Acetic acid and Sodium acteate.
(D) Boric acid and borax.
CH
EM
IST
RY
CHEMISTRY
Space for Rough Work
Corporate Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.)-324005
Website : www.resonance.ac.in | E-mail : [email protected]
Toll Free : 1800 258 5555 |CIN: U80302RJ2007PLC024029P102JPMT1ADV171217C0-18
48. Sodium thiosulphate is prepared by ?
(A) Boiling Na2SO3 solution with S in acidic medium.
(B) Boiling NaOH solution with S.
(C) Neutralising H2SO3 solution with NaOH.
(D) Boiling Na2SO3 with S in absence of air.
49. Choose the correct statement(s) from the following :
(A) Beryllium is not readily attacked by acids because of the presence of an oxide film on the
surface of the metal.
(B) Beryllium sulphate is readily soluble in water as the greater hydration enthalpy of Be2+
overcomes the lattice enthalpy factor.
(C) Beryllium exhibits Co-ordination number more than four.
(D) Beryllium oxides is purely acidic in nature.
50. In a cubic unit cell, atoms A are present at all corner, B atoms are present at non-adjacent face
center and also at edge centers which are not common to the faces containing B atoms at the
centres. C atoms are present at body centre & remaining face centers. The formula of given solid
cannot be:
(A) AB2C3 (B) AB2C2
(C) ABC (D) AB2C
CH
EM
IST
RY
CHEMISTRY
Space for Rough Work
Corporate Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.)-324005
Website : www.resonance.ac.in | E-mail : [email protected]
Toll Free : 1800 258 5555 |CIN: U80302RJ2007PLC024029P102JPMT1ADV171217C0-19
51. Which of the following is the correct option/s of reagent for the given conversion
COOHCH4
(A) Br2/h(1eq.) , MgCl, Br2/h(1eq.), HCOOH
(B) Br2/h(1eq.) , MgCl, Br2/h(1eq.), Mg/dry ether, CO2/H3O
(C) Cl2/h(1eq.) , MgCl, Br2/h(1eq.), KCN/H3O
(D) Cl2/h(1eq.),CH3–MgBr, Br2/h(1eq.), CH3–COOH
52. Observe the following reaction & choose the correct option/s :
XY + Z
KOHHO
OK
O(formed from Z)
(A) X is KMnO4/H (B) Y is
O
O
(C) Z isCH=O
CH=O(D) X is O3/Zn–H2O
CH
EM
IST
RY
CHEMISTRY
Space for Rough Work
Corporate Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.)-324005
Website : www.resonance.ac.in | E-mail : [email protected]
Toll Free : 1800 258 5555 |CIN: U80302RJ2007PLC024029P102JPMT1ADV171217C0-20
53. Observe the following reaction
(1) CH3–C–Cl/AlCl3
O
(2) Zn-Hg/HCl XNBS/
YNaOH
ZMnO2/
W
Choose the correct options
(A) W gives +ve test with 2,4-DNP (B) W gives +ve test with tollens reagent
(C) W gives iodoform with I2/NaOH (D) W is acetophenone
54. In which of the following reaction's, carbocation is involved as intermediate
(A) O—H/H2O (B)
Cl
Na,dry acetone
(C)HBr(1eq.)
(D)HCl/Peroxide
55. The structures of the compound that gives a tribromo derivative on treatement with bromine water
is/are:
(A)
CH3
OH
(B)
CH3
OH
(C)
SO3H
OH
(D)
COOH
OH
CH
EM
IST
RY
CHEMISTRY
Space for Rough Work
Corporate Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.)-324005
Website : www.resonance.ac.in | E-mail : [email protected]
Toll Free : 1800 258 5555 |CIN: U80302RJ2007PLC024029P102JPMT1ADV171217C0-21
SECTION – 2 : (Maximum Marks : 20)
This section contains FIVE questions
The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 to 9, both inclusive
For each question, darken the bubble corresponding to the correct integer in the ORS
Marking scheme :
+4 If the bubble corresponding to the answer is darkened
0 If none of the bubbles is darkened
–1 In all other cases
56. Orbital angular momentum of an electron ish
3 , then the number of possible orientations of this
orbital in space is:
57. How many of the following underlined element are sp3 hybridized.
[Cu(NH3)4]+2 , 3PCl , 3BCl , [Pt(en)2]
+2 , [Ni(CO)4], 2CS ,
24SO , 2SnCl 4SnCl , 2HgCl , 4ClO , 42C H , 3CH , 3CH ,
4NH , 3C F , 3NO , 3ClO , 3PH , 2
4Ni CN
, 5PCl ,
2CH O , 6SF , 2Cl CO , 3
, 2H S
CH
EM
IST
RY
CHEMISTRY
Space for Rough Work
Corporate Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.)-324005
Website : www.resonance.ac.in | E-mail : [email protected]
Toll Free : 1800 258 5555 |CIN: U80302RJ2007PLC024029P102JPMT1ADV171217C0-22
58. When pyrolusite is heated with KOH in presence of air, a green colored compound results. What is
the oxidation number of Mn in this compound ?
59. Observe the following reaction
(1) CH3–CH=CH2/H
CH3O(2) KMnO4/
(3) H
Major product
Number of –COOH functional groups are present in major product
60. (P)
NH2
OH
Number of chiral carbon in P = x
(Q)
CH=CH–CH3
CH=CH–CH3
Number of geometrical isomers in Q = y
The value ofy
xis :
Please read the instructions carefully. You are allotted 5 minutes specifically for this purpose.GENERAL %1. The sealed booklet is your Question Paper. Do not break the seal till you are instructed to do so.2. The question paper CODE is printed on the right hand top corner of this sheet and the right hand top corner of the back cover of
this booklet.3. Use the Optical Response Sheet (ORS) provided separately for answering the question.4. Blank spaces are provided within this booklet for rough work.5. Write your Name and Roll Number in the space provided on the below cover.6. After the open booklet, verify that the booklet contains all the 60 questions along with the options are legible.
QUESTION PAPER FORMAT AND MARKING SCHEME :7. The question paper has three parts : Mathematics, Physics and Chemistry. Each part has two sections.8. Each section as detailed in the following table :
Full Marks Partial Marks Zero MarksNegative
Marks
1
One orMore
CorrectOption(s)
15
+4If only the bubble(s)corresponding to allthe correct option(s)
is(are) darkened
–
0If none of
the bubblesis darkened
–2In all other
cases60
2Single digitInteger (0-9)
5
+4If only the bubbles
corresponding to thecorrect answer is
darkened
–0
if notattempted
–1In all other
cases20
SectionQuestion
TypeNumber ofQuestions
Category-wise Marks for Each Question MaximumMarks of
the Section
OPTICAL RESPONSE SHEET :9. Darken the appropriate bubbles on the original by applying sufficient pressure.10. The original is machine-gradable and will be collected by the invigilator at the end of the examination.11. Do not tamper with or mutilate the ORS.12. Write your name, roll number and the name of the examination centre and sign with pen in the space provided for this purpose on
the original. Do not write any of these details anywhere else. Darken the appropriate bubble under each digit of your rollnumber.
DARKENING THE BUBBLES ON THE ORS :13. Use a BLACK BALL POINT to darken the bubbles in the upper sheet.14. Darken the bubble COMPLETELY.15. Darken the bubble ONLY if you are sure of the answer.
16. The correct way of darkening a bubble is as shown here :
17. There is NO way to erase or "un-darkened bubble.18. The marking scheme given at the beginning of each section gives details of how darkened and not darkened bubbles are
evaluated.
Resonance Eduventures Ltd.CORPORATE OFFICE : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.) - 324005
Ph.No. : +91-744-3012222, 6635555 | Toll Free : 1800 258 5555Reg. Office : J-2, Jawahar Nagar, Main Road, Kota (Raj.) 324005 | Ph. No.: +91-744-3192222 | FAX No. : +91-022-39167222
Website : www.resonance.ac.in | E-mail : [email protected] | CIN: U80302RJ2007PLC024029
MMAAJJOORR TTEESSTT--11 ((MMTT--11)) ((JJEEEE AADDVVAANNCCEEDD PPAATTTTEERRNN))CCOOUURRSSEE :: VVIIJJEETTAA ((0022JJPP)) CCOODDEE -- 0
0
NAME OF THE CANDIDATE : ………………………………………………………………..………………………
ROLL NO. : ………………………..………………………
I have read all the instructions I have verified the identity, name and roll numberand shall abide by them of the candidate.
- - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - -Signature of the Candidate Signature of the Invigilator
DO
NO
T B
RE
AK
TH
E
SE
AL
S
WIT
HO
UT
BE
ING
INS
TR
UC
TE
D T
O D
O S
OB
Y T
HE
IN
VIG
ILA
TO
R
P21-17 PPAAPPEERR--11