Page1|4 · 2018-10-10 · Ver/1/Jun 2018 Page1|4 MATERIAL SAFETY DATA SHEET 1: IDENTIFICATION OF...

P a g e 1 | 4Ver/1/Jun 2018

MATERIAL SAFETY DATA SHEET

1: IDENTIFICATION OF THE SUBSTANCE / PREPARATION AND OF THE COMPANY /UNDERTAKING

Product Name : ArmGrout EP-78Product Description : Epoxy grout – BaseCompany : MYK Schomburg India Pvt LtdAddress : 8-2-703/A, 3rd Floor Leela Gopal Towers,

Road No. 12, Banjara HillsHyderabad -500034 – INDIA.

Telephone : TEL: +91 40 3040 0000, FAX: +91 40 3040 0099Email : Email : [email protected] , www.mykarment.com

2: COMPOSITION/INFORMATION ON INGREDIENTS

3: HAZARDS IDENTIFICATION

IRRITANT Irritating to eyes, respiratory system and skin

4: FIRST AID MEASURES

Eyes : Irrigate immediately with copious quantities of water for several minutes.Obtain medical attention if irritation persists.

Skin : Wash thoroughly with soap and water or suitable skin cleanser as soonas possible. Obtain medical advice if skin disorders develop

Inhalation : Remove from exposure. If feeling unwell obtain medical attention.Ingestion : Obtain medical attention. Do NOT induce vomiting. Beware of aspiration

if vomiting occurs.

5: FIRE FIGHTING MEASURES

Suitable Extinguishing Media : Carbon dioxide, powder, foam or water fog - Do not use water jets.Special Exposure Hazards : Toxic fumes. For further information see section 10Special Protective Equipment : Self-contained breathing apparatus

6: ACCIDENTAL RELEASE MEASURES

Personal Precautions : Wear suitable protective clothing, gloves and eye/face protection.Environmental Precautions : Prevent entry into drains, sewers and water courses.Decontamination Procedures : Soak up with inert absorbent or contain and remove by best

available means. Dispose of as waste.

Composition portland cements, silica sands, additives.

Hazardous Ingredient(s) Symbol Risk Phrases Other Information % Conc. %

epoxy resin ( number average Xi R36/38,43,51/53 Cas No:25068-38-6 >50molecular weight < 700)

All constituents of this product are listed in EINECS (European Inventory of Existing Commercial ChemicalSubstances)or ELINCS (European List of New Chemical Substances) or are exempt.

Refer to Section 8 for Occupational Exposure Limits

P a g e 1 | 4Ver/1/Jun 2018













if vomiting occurs.











P a g e 1 | 4Ver/1/Jun 2018













if vomiting occurs.











P a g e 2 | 4Ver/1/Jun 2018

7: HANDLING AND STORAGE

Handling : Maintain good standards of personal hygiene. Avoid skin and eyecontact. Do not eat, drink or smoke whilst using thi product Ensureadequate ventilation.

Storage : Keep containers dry and tightly closed.

8: EXPOSURE CONTROLS/PERSONAL PROTECTION

Occupational Exposure Limits: - Silica,crystalline 0.4 mgm EH40 -3 respirable dust

Engineering Control Measures : No specific ventilation requirement noted.Personal Protective Equipment : Impervious gloves (e.g. PVC). Safety glasses/goggles. Change

contaminated clothing and clean before re-use.

9: PHYSICAL AND CHEMICAL PROPERTIES

Physical State : LiquidColour : StrawOdour : MildpH (working dilution) : Not applicable (non-aqueous)Boiling Point/Range (°C) : > 200°CFlash Point (closed, °C) : >200°CAuto flammability (°C) : Not determinedExplosive Properties (%) : Not determinedRelative Density (at 20°C) : 1.14Vapour Pressure (kPa at 20 C): 0.001Fat Solubility : Not determined

Water Solubility : Insoluble

10: STABILITY AND REACTIVITY

Stability : Stable: reacts with compounds containing amino, hydroxyl or carboxylgroups to give stable, cross linked materials

Conditions to Avoid : None KnownMaterials to Avoid : Strong acids. Strong alkalis. Strong oxidising agents.Hazardous Decomposition Products : Thermal decomposition: - Oxides of carbon. Irritant fumes.

11: TOXICOLOGICAL INFORMATION

" The following toxicological assessment is based on a knowledge of the toxicity of the product's components:Expected Oral LD50, rat >2g/kg "Health EffectsOn Eyes : May cause transient irritation.On Skin : Irritation. may cause sensitisation.By Inhalation : May cause respiratory irritation.By Ingestion : May cause irritation of mouth, throat and digestive tract.Chronic : Repeated and prolonged skin contact may lead to skin disorders

12: ECOLOGICAL INFORMATION

Environmental Assessment : When used and disposed of as intended, no adverse environmentaleffects are foreseen

P a g e 2 | 4Ver/1/Jun 2018


















P a g e 2 | 4Ver/1/Jun 2018


















P a g e 3 | 4Ver/1/Jun 2018

Mobility : Mobile liquid. Insoluble in waterPersistence and Degradability : Expected to be not readily biodegradableBio accumulative Potential : Not expected to be inoculative.Ecotoxicity : Expected to be ecotoxic to fish / daphnia / algae.

13: DISPOSAL CONSIDERATIONS

Unused Product : Dispose of through an authorised waste contractor to a licensed site.Used/Contaminated Product : As for Unused product.Packaging : Must be disposed of through an authorised waste contractor.

14: TRANSPORT INFORMATION

UN Number : 3082IMO : Class: 9 Packing Group: IIIADR : Class: 9 Item: 11(c)Transport Name : Environmentally hazardous substance, liquid, nos. (Epoxy Resin)Hazchem/Kemler Code : 90

15: REGULATORY INFORMATION

Hazard Label Data: -Named Ingredients : cement powdersSymbol(s) : XiRisk Phrases : Irritating to eyes and skinSafety Phrases : "May cause sensitisation by skin contact. In case of contact with eyes,

rinse immediately with plenty of water and seek medical advice.After contact with skin, wash immediately with plenty soap and water.Wear suitable gloves and eye / face protection contain epoxyconstituents See information supplied by the manufacturer

EC Directives : "Dangerous Substances Directive, 67/548/EEC and adaptations.Dangerous Preparations Directive, 88/379/EEC.Safety Data Sheets Directive, 91/155/EEC.Hazardous Waste Directive,91/689/EEC."

Statutory Instruments : Chemicals (Hazard Information and Packaging for Supply)(Amendment) Regs. 1996 (SI1092)"Control of Substances Hazardous to Health Regs. 1994 (SI 3246).Health & Safety at Work, etc. Act 1974.Environmental Protection Act 1990."

Codes of Practice : "Waste Management. The Duty of Care. Operational Provisions of theRoad Traffic (Carriage of Dangerous Substances in packagesetc.) Regs. 1986 (COP 17). "

Guidance Notes : "Occupational skin diseases: health and safety precautions (EH 26).Storage of packaged dangerous substances [HS(G)71]."

The above publications are available from HMSO

Disposal must be in accordance with local and national legislation.

P a g e 3 | 4Ver/1/Jun 2018















P a g e 3 | 4Ver/1/Jun 2018















P a g e 4 | 4Ver/1/Jun 2018

16: OTHER INFORMATION

Department issuing data specificationsheet

: Environment protection department

Contact : Safety department/Technical service.

Also refer to the Safety Data Sheet(s) for information on other components of this product.

The data and advice given apply when the product is used for the stated application or applications. The product isnot sold as suitable for any other application. Use of the product for applications other than as stated in this sheetmay give rise to risks not mentioned in this sheet. The product should not be used other than for the statedapplication or applications without seeking advice from MYK Schomburg India Pvt Ltd. If this product has beenpurchased for supply to a third party for use at work, it is the purchaser's duty to take all necessary steps to securethat any person handling or using the product is provided with the information in this sheet. It is the responsibilityand duty of the employer to inform employees and others who may be affected of any hazards described in thissheet and of any precautions which should be taken.

This sheet does not constitute or substitute for the users own assessment of workplace risk, as required by otherhealth and safety legislation. Further copies of this Safety Data Sheet may be obtained from MYK SchomburgIndia Pvt Ltd.

P a g e 4 | 4Ver/1/Jun 2018








P a g e 4 | 4Ver/1/Jun 2018








P a g e 1 | 4Ver/1/Jun 2018



Product Name : ArmGrout EP-78 (Hardener)Product Description : Epoxy grout –HardenerCompany : MYK Schomburg India Pvt LtdAddress : 8-2-703/A, 3rd Floor Leela Gopal Towers,





"Causes burnsHarmful by inhalation, in contact with skin and if swallowed. May cause sensitisation by skin contact.”





if vomiting occurs.






Composition mixture of aliphatic and aromatic amines.

Hazardous Ingredient(s) Symbol Risk Phrases Other Information %

4,4'-diaminodiphenyl methane T, N R45-20/21/22-

All constituents of this product are listed in EINECS (European Inventory of Existing Commercial ChemicalSubstances)

or ELINCS (European List of New Chemical Substances) or are exempt.


P a g e 1 | 4Ver/1/Jun 2018













if vomiting occurs.












P a g e 1 | 4Ver/1/Jun 2018













if vomiting occurs.












P a g e 2 | 4Ver/1/Jun 2018


Handling : Maintain good standards of personal hygiene. Avoid skin and eyecontact. Do not eat, drink or smoke whilst using the product Ensureadequate ventilation.



Occupational Exposure Limits: - :Substance 8 Hour TWA STEL Source / Other information4,4'-methylenedianiline 0.08 mgm-3 ----- EH 40Engineering Control Measures : Use only in well ventilated areas. Local exhaust ventilation is

recommendedPersonal Protective Equipment : Avoid skin an eye contact. Impervious gloves (e.g. PVC). Safety

glasses/goggles. Change contaminated clothing and clean before re-use.


Physical State : LiquidColour : Brown.Odour : AminepH (working dilution) : Not applicable (non-aqueous)Boiling Point/Range (°C) : >200 °CFlash Point (closed, °C) : >120°CAuto flammability (°C) : Not determinedAutoignition temperature : >300

Relative Density (at 20°C) : 1.1Vapour Pressure (kPa at 20 C): : >0.3Fat Solubility : Not determined



Stability : Stable if used as directed.Conditions to Avoid : Any source of ignition.Materials to Avoid : Strong oxidising agents. Strong acids. Strong alkalisHazardous Decomposition Products : Oxides of carbon. Nitrogen compounds, in some fire circumstances,

hydrogen cyanide.


" The following toxicological assessment is based on a knowledge of the toxicity of the product's components:

Health EffectsOn Eyes : Causes irreversible damage to eye tissue if not removed promptly.On Skin : Corrosive - may cause burns. May cause - sensitisation.By Inhalation : Harmful by inhalation. May cause respiratory irritation.By Ingestion : Harmful if swallowed. Corrosive - causes severe damage to mouth,

throat and digestive tract.Chronic : "Based on the results of studies on experimental animals (rodents) 4,4'-

diaminodiphenyl methane hasshown to be an animal carcinogen. If absorbed into the body by

P a g e 2 | 4Ver/1/Jun 2018














hydrogen cyanide.






P a g e 2 | 4Ver/1/Jun 2018














hydrogen cyanide.






P a g e 3 | 4Ver/1/Jun 2018

ingestion, inhalation or by contact withskin or eyes it may cause damage to liver, kidney and eyes, especiallyfrom excessive exposure byaccident or misuse."







UN Number : 2922


Hazard Label Data: -Named Ingredients : isophorone diamine

4,4'-diaminodiphenylmethaneUN Number 2922

Symbol(s) : TRisk Phrases : May cause cancer.

Causes burns.Harmful: danger of serious damage to health by prolonged exposure incontact with skin. Harmful if swallowed

Safety Phrases : Wear suitable protective clothing, gloves and eye/face protectionIn case of accident or if you feel unwell, seek medical adviceimmediately (show the label where possible)Avoid exposure - obtain special instructions before useRestricted to professional users

EC Directives : Dangerous Substances Directive 67/548/EEC and adaptationsDangerous Preparations Directive, 88/379/EEC. Safety Data SheetsDirective, 91/155/EEC.

Statutory Instruments : Chemicals (Hazard Information and Packaging for Supply)(Amendment) Regs. 1996 (SI1092).Control of Substances Hazardous to Health Regs. 1994 (SI 3246).The Special Waste Regulations 1996 (SI 972).

Health & Safety at Work, etc Act 1974.Codes of Practice : Control of substances hazardous to health & control of carcinogenic

substances (L5).Waste Management. The Duty of Care.

Guidance Notes : Occupational skin diseases: health and safety precautions (EH 26).


P a g e 3 | 4Ver/1/Jun 2018








UN Number : 2922













P a g e 3 | 4Ver/1/Jun 2018








UN Number : 2922













P a g e 4 | 4Ver/1/Jun 2018

Occupational exposure limits (EH 40).









P a g e 4 | 4Ver/1/Jun 2018










P a g e 4 | 4Ver/1/Jun 2018










P a g e 1 | 4Ver/1/Jun 2018



Product Name : ArmGrout EP-78 (Aggregate)Product Description : Epoxy grout - fillerCompany : MYK Schomburg India Pvt LtdAddress : 8-2-703/A, 3rd Floor Leela Gopal Towers,





Long term inhalation may cause health problems





if vomiting occurs.


Suitable Extinguishing Media : None, not flammableSpecial Exposure Hazards : NoneSpecial Protective Equipment : None




Composition silica flour

None of the ingredients of this product are classified as hazardous.




P a g e 1 | 4Ver/1/Jun 2018













if vomiting occurs.











P a g e 1 | 4Ver/1/Jun 2018













if vomiting occurs.











P a g e 2 | 4Ver/1/Jun 2018


Handling : Avoid breathing dust. In case of insufficient ventilation, wear suitablerespiratory equipment. Avoid skin and eye contact

Storage : Store in cool, dry area


Occupational Exposure Limits: - :Substance 8 Hour TWA STEL Source / Other informationSilica, crystalline 0.4 mgm ----- EH40 -3Engineering Control Measures : Use only in well ventilated areas. Local exhaust ventilation is




Physical State : PowderColour : Off-whiteOdour : OdourlesspH (working dilution) : Not applicable (non-aqueous)Boiling Point/Range (°C) : Not applicableFlash Point (closed, °C) : NoneAuto flammability (°C) : Not applicableAutoignition temperature : Not applicable

Explosive Properties (%): : Can form explosive dust cloudRelative Density (at 20°C) : 2.65Water Solubility : Insoluble


Stability : StableConditions to Avoid : None knownMaterials to Avoid : Strong oxidising agentsHazardous Decomposition Products : None


Health EffectsOn Eyes : Irritating and may injure eye tissue if not removed promptly.On Skin : Unlikely to irritate on brief or occasional exposureBy Inhalation : May cause respiratory irritationBy Ingestion : Low order of acute toxicity.Chronic : Respirable dust, if inhaled over a prolonged period, constitute a health

hazard. Inhalation of particles of free silica in the respirable range cangive rise to fibrosis of the lungs.

P a g e 2 | 4Ver/1/Jun 2018
















P a g e 2 | 4Ver/1/Jun 2018
















P a g e 3 | 4Ver/1/Jun 2018



Mobility : Insoluble in waterPersistence and Degradability : Not applicableBio accumulative Potential : Not expected to be bio accumulativeEcotoxicity : Not Ecotoxic to fish / daphnia / algae.


Unused Product : Dispose of in an approved manner.Used/Contaminated Product : Dispose of through an authorised waste contractor to a licensed site.Packaging : The method of disposal must be acceptable to the local authority


This product is NOT classified as dangerous for transport


Hazard Label Data: - This product is NOT classified as dangerous for supply in the UKSafety Phrases : Do not breathe dust. Wear suitable gloves and eye/face protectionEC Directives : Dangerous Substances Directive 67/548/EEC and adaptations

Dangerous Preparations Directive, 88/379/EEC. Safety Data SheetsDirective, 91/155/EEC.

Statutory Instruments : Chemicals (Hazard Information a d Packaging) Regs. 1993 (SI 1746).Environmental Protection (Duty of Care) Regs. 1991 (SI2839)

Codes of Practice : Waste Management. The Duty of Care.Guidance Notes : Occupational exposure limits (EH 26).

Dust in the workplace: general principles of protection (EH44)



P a g e 3 | 4Ver/1/Jun 2018
















P a g e 3 | 4Ver/1/Jun 2018
















P a g e 4 | 4Ver/1/Jun 2018








P a g e 4 | 4Ver/1/Jun 2018








P a g e 4 | 4Ver/1/Jun 2018








Page1|4 · 2018-10-10 · Ver/1/Jun 2018 Page1|4 MATERIAL SAFETY DATA SHEET 1: IDENTIFICATION OF...

Documents

Transcript of Page1|4 · 2018-10-10 · Ver/1/Jun 2018 Page1|4 MATERIAL SAFETY DATA SHEET 1: IDENTIFICATION OF...