Page 774 of 2729 - Webflow

of 2729

80 of 2729

of 2729

Client: Makah Tribe Emergency Spill Dock ExtensionProject:

Laboratory: Analytical Resources, Inc. SDG: 16K0314

EPA 6020A UCT-KED

INITIAL AND CONTINUING

CALIBRATION CHECK

BergerABAM

Control Limt: +/- 10.00% Sequence: SEL0001

Instrument ID: ICPMS2 Calibration: ZL00003

Analyte True Found %R UnitsLab Sample ID Method

10080.000 80.3 ug/LSEL0001-ICV1 EPA 6020A UCT-KEDSelenium-78

10250.000 51.1 ug/LSEL0001-CCV1 EPA 6020A UCT-KEDSelenium-78

99.750.000 49.8 ug/LSEL0001-CCV2 EPA 6020A UCT-KEDSelenium-78








99.050.000 49.5 ug/LSEL0001-CCVA EPA 6020A UCT-KEDSelenium-78

98.150.000 49.0 ug/LSEL0001-CCVB EPA 6020A UCT-KEDSelenium-78

96.250.000 48.1 ug/LSEL0001-CCVC EPA 6020A UCT-KEDSelenium-78

* Values outside of QC limits

Page 811 of 2729

ANALYSIS BATCH (SEQUENCE) SUMMARY

EPA 6020A UCT-KED

SDG:

Project:

Instrument:Sequence:

Client:

Laboratory:

Calibration:

Analytical Resources, Inc. 16K0314

BergerABAM Makah Tribe Emergency Spill Dock Extension

SEL0001 ICPMS2

ZL00003

Sample Name Lab Sample ID Lab File ID Analysis Date/TimeMatrix

CAL 0 SEL0001-CAL1 XDT_m2161130-006 11/30/16 10:09Water

CAL 1 - LOW CHECK SEL0001-CAL2 XDT_m2161130-007 11/30/16 10:14Water





RINSE SEL0001-IBL1 XDT_m2161130-012 11/30/16 10:44Water

Initial Cal Check SEL0001-ICV1 XDT_m2161130-014 11/30/16 10:52Water

Initial Cal Blank SEL0001-ICB1 XDT_m2161130-015 11/30/16 11:00Water

Calibration Check SEL0001-CCV1 XDT_m2161130-016 11/30/16 11:05Water

Calibration Blank SEL0001-CCB1 XDT_m2161130-017 11/30/16 11:12Water

Instrument RL Check SEL0001-CRL1 XDT_m2161130-018 11/30/16 11:17Water

Interference Check A SEL0001-IFA1 XDT_m2161130-019 11/30/16 11:22Water

Interference Check B SEL0001-IFB1 XDT_m2161130-020 11/30/16 11:27Water

LR200 SEL0001-HCV1 XDT_m2161130-021 11/30/16 11:35Water

LR300 SEL0001-HCV2 XDT_m2161130-022 11/30/16 11:39Water

Instrument Blank SEL0001-IBL2 XDT_m2161130-023 11/30/16 11:47Water

Instrument Blank SEL0001-IBL3 XDT_m2161130-024 11/30/16 11:54Water





ZZZZZ BEK0664-BLK1 XDT_m2161130-039 11/30/16 13:31Solid

Blank BEK0686-BLK1 XDT_m2161130-040 11/30/16 13:36Solid

Reference BEK0686-SRM1 XDT_m2161130-041 11/30/16 13:41Solid

DMMU-2 16K0314-10 XDT_m2161130-042 11/30/16 13:46Solid

DMMU-3 16K0314-15 XDT_m2161130-043 11/30/16 13:51Solid

ZZZZZ 16K0323-01 XDT_m2161130-045 11/30/16 14:01Solid

ZZZZZ BEK0664-BS1 XDT_m2161130-047 11/30/16 14:11Solid

LCS BEK0686-BS1 XDT_m2161130-048 11/30/16 14:16Solid


Page 812 of 2729


EPA 6020A UCT-KED

SDG:

Project:


Client:

Laboratory:

Calibration:



SEL0001 ICPMS2

ZL00003

Sample Name Lab Sample ID Lab File ID Analysis Date/TimeMatrix




DMMU-4 16K0314-20 XDT_m2161130-062 11/30/16 15:33Solid

DMMU-5 16K0314-25 XDT_m2161130-063 11/30/16 15:38Solid

DMMU-6 16K0314-30 XDT_m2161130-064 11/30/16 15:43Solid

DMMU-7 16K0314-35 XDT_m2161130-065 11/30/16 15:48Solid

DMMU-1 BEK0686-DUP1 XDT_m2161130-069 11/30/16 16:10Solid

DMMU-1 16K0314-05 XDT_m2161130-070 11/30/16 16:15Solid

DMMU-1 BEK0686-MS1 XDT_m2161130-071 11/30/16 16:20Solid









Calibration Check SEL0001-CCVA XDT_m2161130-115 11/30/16 20:15Water

Calibration Blank SEL0001-CCBA XDT_m2161130-116 11/30/16 20:23Water

Calibration Check SEL0001-CCVB XDT_m2161130-127 11/30/16 21:18Water

Calibration Blank SEL0001-CCBB XDT_m2161130-128 11/30/16 21:26Water

Calibration Check SEL0001-CCVC XDT_m2161130-134 11/30/16 21:57Water

Calibration Blank SEL0001-CCBC XDT_m2161130-135 11/30/16 22:05Water

Page 813 of 2729

ZL00003Calibration:Instrument ID: ICPMS2

Makah Tribe Emergency Spill Dock ExtensionProject:Client:

SDG:Laboratory: Analytical Resources, Inc. 16K0314

EPA 6020A UCT-KED

ICP INTERFERENCE CHECK SAMPLE

Sequence: SEL0001

BergerABAM

Standard ID: E007009

Lab Sample ID Analyte True Found %R Units

SEL0001-IFA1 0 ug/LSelenium-78 0.1490

* Indicates %R outside of QC limitsNOTE: True value and %R are populated only for analytes found in the interference check standards, and will be seen only if those analytes were requested.

Page 814 of 2729

ZL00003Calibration:Instrument ID: ICPMS2

Makah Tribe Emergency Spill Dock ExtensionProject:Client:

SDG:Laboratory: Analytical Resources, Inc. 16K0314

EPA 6020A UCT-KED

ICP INTERFERENCE CHECK SAMPLE

Sequence: SEL0001

BergerABAM

Standard ID: E007009

Lab Sample ID Analyte True Found %R Units

SEL0001-IFB1 0 ug/LSelenium-78 0.0610

* Indicates %R outside of QC limitsNOTE: True value and %R are populated only for analytes found in the interference check standards, and will be seen only if those analytes were requested.

Page 815 of 2729

DETECTION LEVEL STANDARD

Calibration:

Project:

SDG:

Instrument ID:

Client:

Laboratory:

EPA 6020A UCT-KED

Analytical Resources, Inc.

ICPMS2

16K0314

Makah Tribe Emergency Spill Dock Extension

ZL00003

BergerABAM

Analyte True Found %R Units QC Limts

Sequence: SEL0001 Lab Sample ID: SEL0001-CRL1

0.50000 0.742 148 ug/L 50 - 150Selenium-78


Page 816 of 2729

HIGH-CONCENTRATION

CALIBRATION VERIFICATION

EPA 6020A UCT-KED

Laboratory:

Sequence:

Calibration:

Client:

SDG:

Laboratory ID:

Project:

Standard ID:


BergerABAM

ZL00003

SEL0001

16K0314


SEL0001-HCV1

E007074

ANALYTE

EXPECTED FOUND

% DRIFT QC LIMIT(ug/L) (ug/L)

-3.5 10.00200.00 193Selenium-78


Page 817 of 2729

HIGH-CONCENTRATION

CALIBRATION VERIFICATION

EPA 6020A UCT-KED

Laboratory:

Sequence:

Calibration:

Client:

SDG:

Laboratory ID:

Project:

Standard ID:


BergerABAM

ZL00003

SEL0001

16K0314


SEL0001-HCV2

E007075

ANALYTE

EXPECTED FOUND

% DRIFT QC LIMIT(ug/L) (ug/L)

-3.9 10.00300.00 288Selenium-78


Page 818 of 2729

Date

Collected

Date

Received

Date

Prepared

Days

to

Prep

Max

Days to

Prep

Date

Analyzed

Days

to

Analysis

Max

Days to

AnalysisSample Name Q

HOLDING TIME SUMMARY

Analysis: EPA 6020A UCT-KED

Laboratory:

Project:

SDG:

Client:


BergerABAM

16K0314


DMMU-1 180 180 9

11/21/16

09:15

11/22/16

15:08

11/28/16

06:56

11/30/16

16:1516K0314-05 6

DMMU-2 180 180 9

11/21/16

10:10

11/22/16

15:08

11/28/16

06:56

11/30/16

13:4616K0314-10 6

DMMU-3 180 180 9

11/21/16

11:00

11/22/16

15:08

11/28/16

06:56

11/30/16

13:5116K0314-15 6

DMMU-4 180 180 9

11/21/16

11:50

11/22/16

15:08

11/28/16

06:56

11/30/16

15:3316K0314-20 6

DMMU-5 180 180 9

11/21/16

13:05

11/22/16

15:08

11/28/16

06:56

11/30/16

15:3816K0314-25 6

DMMU-6 180 180 9

11/21/16

13:55

11/22/16

15:08

11/28/16

06:56

11/30/16

15:4316K0314-30 6

DMMU-7 180 180 9

11/21/16

15:15

11/22/16

15:08

11/28/16

06:56

11/30/16

15:4816K0314-35 6

Duplicate 180 180 9

11/21/16

09:15

11/22/16

15:08

11/28/16

06:56

11/30/16

16:10BEK0686-DUP1 6

Matrix Spike 180 180 9

11/21/16

09:15

11/22/16

15:08

11/28/16

06:56

11/30/16

16:20BEK0686-MS1 6

* Indicates hold time exceedance.

Page 819 of 2729

Analyte MDL Units

METHOD DETECTION

AND REPORTING LIMITS

EPA 6020A UCT-KED

Laboratory:

Matrix:

Client:

SDG:

Project:

Instrument:


Solid

16K0314


ICPMS2

BergerABAM

RL

0.39 mg/kgSelenium-78 0.50

Page 820 of 2729

Dual Column

ORGANIC ANALYSIS DATA SHEET DMMU-1

EPA 8081B

Laboratory:

Client:

Matrix:

Sampled:

Solids:

Batch:

Instrument:

Laboratory ID:

Sequence:

Prepared:

Preparation:

Column 1:

SDG:

Project:

File ID:

Analyzed:

Initial/Final:

Calibration:

Column 2:


BergerABAM

Solid

11/21/16 09:15

69.40

BEK0726

ECD6

16K0314-05

11/29/16 13:55

EPA 3546 (Microwave)

SEL0137

STX-CLP STX-CLP2

ZK00009

19.08 g / 2.5 mL

12/09/16 16:41

16120914.D


16K0314

QCol # MDLDILUTIONCOMPOUNDCAS NO. CONC. (ug/kg dry) RL

1 0.041 0.47 0.47 U76-44-8 Heptachlor

1 0.351 0.47 0.47 U309-00-2 Aldrin

1 0.311 0.47 0.47 U5103-74-2 trans-Chlordane (beta-Chlordane)

1 0.101 0.47 0.47 U5103-71-9 cis-Chlordane (alpha-chlordane)

1 0.131 0.94 0.94 U72-55-9 4,4'-DDE

1 0.111 0.94 0.94 U60-57-1 Dieldrin

1 0.301 0.94 0.94 U72-54-8 4,4'-DDD

1 0.311 0.94 0.94 U50-29-3 4,4'-DDT

1 0.321 0.94 0.94 U87-68-3 Hexachlorobutadiene

1 0.141 0.94 0.94 U118-74-1 Hexachlorobenzene

1 0.121 0.94 0.94 U27304-13-8 Oxychlordane

1 0.201 0.94 0.94 U5103-73-1 cis-Nonachlor

1 0.221 0.94 0.94 U39765-80-5 trans-Nonachlor

SURROGATES ADDED (ug/kg dry) CONC (ug/kg dry) % REC QC LIMITSCol # Q

1Decachlorobiphenyl 30 - 1607.5520 68.25.15

1Tetrachlorometaxylene 30 - 1607.5520 78.85.95

Page 821 of 2729

of 2729

Dual Column


EPA 8081B

Laboratory:

Client:

Matrix:

Sampled:

Solids:

Batch:

Instrument:

Laboratory ID:

Sequence:

Prepared:

Preparation:

Column 1:

SDG:

Project:

File ID:

Analyzed:

Initial/Final:

Calibration:

Column 2:


BergerABAM

Solid

11/21/16 10:10

63.86

BEK0726

ECD6

16K0314-10

11/29/16 13:55


SEL0137

STX-CLP STX-CLP2

ZK00009

20.14 g / 2.5 mL

12/09/16 17:00

16120915.D


16K0314


1 0.051 0.49 0.49 U76-44-8 Heptachlor

1 0.361 0.49 0.49 U309-00-2 Aldrin



1 0.131 0.97 0.97 U72-55-9 4,4'-DDE

1 0.111 0.97 0.97 U60-57-1 Dieldrin

1 0.311 0.97 0.97 U72-54-8 4,4'-DDD

1 0.321 0.97 0.97 U50-29-3 4,4'-DDT



1 0.121 0.97 0.97 U27304-13-8 Oxychlordane

1 0.201 0.97 0.97 U5103-73-1 cis-Nonachlor





Page 829 of 2729

of 2729

Dual Column


EPA 8081B

Laboratory:

Client:

Matrix:

Sampled:

Solids:

Batch:

Instrument:

Laboratory ID:

Sequence:

Prepared:

Preparation:

Column 1:

SDG:

Project:

File ID:

Analyzed:

Initial/Final:

Calibration:

Column 2:


BergerABAM

Solid

11/21/16 11:00

45.72

BEK0726

ECD6

16K0314-15

11/29/16 13:55


SEL0137

STX-CLP STX-CLP2

ZK00009

28.04 g / 2.5 mL

12/09/16 17:19

16120916.D


16K0314


1 0.051 0.49 0.49 U76-44-8 Heptachlor

1 0.361 0.49 0.49 U309-00-2 Aldrin



1 0.131 0.98 0.98 U72-55-9 4,4'-DDE

1 0.111 0.98 0.98 U60-57-1 Dieldrin

1 0.311 0.98 0.98 U72-54-8 4,4'-DDD

1 0.321 0.98 0.98 U50-29-3 4,4'-DDT



1 0.121 0.98 0.98 U27304-13-8 Oxychlordane

1 0.201 0.98 0.98 U5103-73-1 cis-Nonachlor





Page 835 of 2729

of 2729

Dual Column


EPA 8081B

Laboratory:

Client:

Matrix:

Sampled:

Solids:

Batch:

Instrument:

Laboratory ID:

Sequence:

Prepared:

Preparation:

Column 1:

SDG:

Project:

File ID:

Analyzed:

Initial/Final:

Calibration:

Column 2:


BergerABAM

Solid

11/21/16 11:50

59.71

BEK0726

ECD6

16K0314-20

11/29/16 13:55


SEL0137

STX-CLP STX-CLP2

ZK00009

25.03 g / 2.5 mL

12/09/16 17:37

16120917.D


16K0314


1 0.041 0.42 0.42 U76-44-8 Heptachlor

1 0.311 0.42 0.42 U309-00-2 Aldrin



1 0.111 0.84 0.84 U72-55-9 4,4'-DDE

1 0.101 0.84 0.84 U60-57-1 Dieldrin

1 0.271 0.84 0.84 U72-54-8 4,4'-DDD

1 0.271 0.84 0.84 U50-29-3 4,4'-DDT



1 0.111 0.84 0.84 U27304-13-8 Oxychlordane

1 0.181 0.84 0.84 U5103-73-1 cis-Nonachlor





Page 844 of 2729

of 2729

Dual Column


EPA 8081B

Laboratory:

Client:

Matrix:

Sampled:

Solids:

Batch:

Instrument:

Laboratory ID:

Sequence:

Prepared:

Preparation:

Column 1:

SDG:

Project:

File ID:

Analyzed:

Initial/Final:

Calibration:

Column 2:


BergerABAM

Solid

11/21/16 13:05

60.63

BEK0726

ECD6

16K0314-25

11/29/16 13:55


SEL0137

STX-CLP STX-CLP2

ZK00009

21.11 g / 2.5 mL

12/09/16 17:56

16120918.D


16K0314


1 0.051 0.49 0.49 U76-44-8 Heptachlor

1 0.361 0.49 0.49 U309-00-2 Aldrin



1 0.131 0.98 0.98 U72-55-9 4,4'-DDE

1 0.111 0.98 0.98 U60-57-1 Dieldrin

1 0.311 0.98 0.98 U72-54-8 4,4'-DDD

1 0.321 0.98 0.98 U50-29-3 4,4'-DDT



1 0.131 0.98 0.98 U27304-13-8 Oxychlordane

1 0.211 0.98 0.98 U5103-73-1 cis-Nonachlor





Page 855 of 2729

of 2729

8 of 2729

of 2729

Dual Column


EPA 8081B

Laboratory:

Client:

Matrix:

Sampled:

Solids:

Batch:

Instrument:

Laboratory ID:

Sequence:

Prepared:

Preparation:

Column 1:

SDG:

Project:

File ID:

Analyzed:

Initial/Final:

Calibration:

Column 2:


BergerABAM

Solid

11/21/16 13:55

71.28

BEK0726

ECD6

16K0314-30

11/29/16 13:55


SEL0137

STX-CLP STX-CLP2

ZK00009

18.1 g / 2.5 mL

12/09/16 18:14

16120919.D


16K0314


1 0.041 0.48 0.48 U76-44-8 Heptachlor

1 0.361 0.48 0.48 U309-00-2 Aldrin



1 0.131 0.97 0.97 U72-55-9 4,4'-DDE

1 0.111 0.97 0.97 U60-57-1 Dieldrin

1 0.311 0.97 0.97 U72-54-8 4,4'-DDD

1 0.311 0.97 0.97 U50-29-3 4,4'-DDT



1 0.121 0.97 0.97 U27304-13-8 Oxychlordane

1 0.201 0.97 0.97 U5103-73-1 cis-Nonachlor





Page 863 of 2729

of 2729

Dual Column


EPA 8081B

Laboratory:

Client:

Matrix:

Sampled:

Solids:

Batch:

Instrument:

Laboratory ID:

Sequence:

Prepared:

Preparation:

Column 1:

SDG:

Project:

File ID:

Analyzed:

Initial/Final:

Calibration:

Column 2:


BergerABAM

Solid

11/21/16 15:15

72.01

BEK0726

ECD6

16K0314-35

11/29/16 13:55


SEL0137

STX-CLP STX-CLP2

ZK00009

18.11 g / 2.5 mL

12/09/16 18:33

16120920.D


16K0314


1 0.041 0.48 0.48 U76-44-8 Heptachlor

1 0.351 0.48 0.48 U309-00-2 Aldrin



1 0.131 0.96 0.96 U72-55-9 4,4'-DDE

1 0.111 0.96 0.96 U60-57-1 Dieldrin

1 0.311 0.96 0.96 U72-54-8 4,4'-DDD

1 2.401 2.40 2.40 Y1, U50-29-3 4,4'-DDT



1 0.121 0.96 0.96 U27304-13-8 Oxychlordane

1 0.201 0.96 0.96 U5103-73-1 cis-Nonachlor





Page 870 of 2729

of 2729

PREPARATION BATCH SUMMARY

EPA 8081B

Analytical Resources, IncorporatedAnalytical Chemists and Consultants

Laboratory:

Client:

Batch Matrix:Batch: Preparation:

SDG:

Project:



16K0314

BEK0726 Solid EPA 3546 (Microwave)

SAMPLE NAME LAB SAMPLE ID LAB FILE ID DATE PREPARED OBSERVATIONS

DMMU-1 16K0314-05 16120914.D 11/29/16 13:55

DMMU-2 16K0314-10 16120915.D 11/29/16 13:55

DMMU-3 16K0314-15 16120916.D 11/29/16 13:55

DMMU-4 16K0314-20 16120917.D 11/29/16 13:55

DMMU-5 16K0314-25 16120918.D 11/29/16 13:55

DMMU-6 16K0314-30 16120919.D 11/29/16 13:55

DMMU-7 16K0314-35 16120920.D 11/29/16 13:55

Blank BEK0726-BLK1 16120908.D 11/29/16 13:55

LCS BEK0726-BS1 16120909.D 11/29/16 13:55

MRL Check BEK0726-MRL1 16120910.D 11/29/16 13:55

DMMU-6 BEK0726-MS1 16120912.D 11/29/16 13:55

DMMU-6 BEK0726-MSD1 16120913.D 11/29/16 13:55

Reference BEK0726-SRM1 16120911.D 11/29/16 13:55

Page 879 of 2729

of 2729

CLEANUP BATCH SUMMARY

Laboratory:

Client:

Cleanup Batch: Cleanup Type:

SDG:

Project:


BergerABAM

CEL0036

16K0314


GPC

Cleanup Method: EPA 3640A GPC Cleanup Analysis: EPA 8081B

SAMPLE NAME LAB SAMPLE ID LAB FILE ID DATE PREPARE OBSERVATIONS

DMMU-3 16K0314-15 16120916.D 12/02/2016

DMMU-2 16K0314-10 16120915.D 12/02/2016

DMMU-4 16K0314-20 16120917.D 12/02/2016

DMMU-5 16K0314-25 16120918.D 12/02/2016

DMMU-6 16K0314-30 16120919.D 12/02/2016

DMMU-7 16K0314-35 16120920.D 12/02/2016

DMMU-1 16K0314-05 16120914.D 12/02/2016

Page 897 of 2729

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Page 898 of 2729


Laboratory:

Client:


SDG:

Project:


BergerABAM

CEL0037

16K0314


Sulfur

Cleanup Method: EPA 3660B Sulfur Cleanup Analysis: EPA 8081B


DMMU-4 16K0314-20 16120917.D 12/06/2016

DMMU-2 16K0314-10 16120915.D 12/06/2016

DMMU-5 16K0314-25 16120918.D 12/06/2016

DMMU-1 16K0314-05 16120914.D 12/06/2016

DMMU-7 16K0314-35 16120920.D 12/06/2016

DMMU-3 16K0314-15 16120916.D 12/06/2016

DMMU-6 16K0314-30 16120919.D 12/06/2016

Page 899 of 2729

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Page 900 of 2729


Laboratory:

Client:


SDG:

Project:


BergerABAM

CEL0038

16K0314


Silica Gel

Cleanup Method: EPA 3630C Silica Gel Cleanup Analysis: EPA 8081B


DMMU-7 16K0314-35 16120920.D 12/06/2016

DMMU-1 16K0314-05 16120914.D 12/06/2016

DMMU-2 16K0314-10 16120915.D 12/06/2016

DMMU-3 16K0314-15 16120916.D 12/06/2016

DMMU-4 16K0314-20 16120917.D 12/06/2016

DMMU-6 16K0314-30 16120919.D 12/06/2016

DMMU-5 16K0314-25 16120918.D 12/06/2016

Page 901 of 2729

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Page 902 of 2729

Form I

METHOD BLANK DATA SHEET Blank

EPA 8081B

Laboratory:

Client:

Matrix:

Sampled:

Solids:

Batch: Sequence: Calibration:


BergerABAM Project: Makah Tribe Emergency Spill Dock Extension

SDG: 16K0314

Laboratory ID: File ID:BEK0726-BLK1 16120908.D

Prepared: Analyzed:11/29/16 13:55 12/09/16 14:49

Preparation: Initial/Final:EPA 3546 (Microwave)

BEK0726 SEL0137 ZK00009

12.5 g / 2.5 mL

Instrument: ECD6 Column: STX-CLP

Solid

N/A

CAS NO. QCONC. (ug/kg wet)COMPOUND DILUTION DL RL

76-44-8 Heptachlor 0.50 U 0.05 0.501

309-00-2 Aldrin 0.50 U 0.37 0.501

5103-74-2 trans-Chlordane (beta-Chlordane) 0.50 U 0.33 0.501

5103-71-9 cis-Chlordane (alpha-chlordane) 0.50 U 0.11 0.501

72-55-9 4,4'-DDE 1.00 U 0.14 1.001

60-57-1 Dieldrin 1.00 U 0.12 1.001

72-54-8 4,4'-DDD 1.00 U 0.32 1.001

50-29-3 4,4'-DDT 1.00 U 0.33 1.001

87-68-3 Hexachlorobutadiene 1.00 U 0.34 1.001

118-74-1 Hexachlorobenzene 1.00 U 0.15 1.001

27304-13-8 Oxychlordane 1.00 U 0.13 1.001

5103-73-1 cis-Nonachlor 1.00 U 0.21 1.001

39765-80-5 trans-Nonachlor 1.00 U 0.23 1.001

SURROGATES ADDED (ug/kg wet) CONC (ug/kg wet) % REC QQC LIMITS

Decachlorobiphenyl 8.0000 1018.12 30 - 160

Decachlorobiphenyl [2C] 8.0000 1088.63 30 - 160

Tetrachlorometaxylene 8.0000 85.96.87 30 - 160

Tetrachlorometaxylene [2C] 8.0000 83.46.67 30 - 160

[2C] indicates second-column analyte, present if quantification on any batch samples used second column data.

Page 903 of 2729

of 2729

LCS / LCS DUPLICATE RECOVERY

EPA 8081B


Project:

SDG:

Initial/Final:

Preparation:

Laboratory ID:Batch:

Matrix:

Client:

Laboratory:

12.5 g / 2.5 mL



BEK0726

Solid


BEK0726-BS1

Analyzed: 12/09/16 15:08

LCSSequence Name:

COMPOUND

SPIKE

ADDED

(ug/kg wet)

LCS

CONCENTRATION

(ug/kg wet)

LCS

%

REC. #

QC

LIMITS

REC.

Heptachlor [2C] 39 - 1204.00 3.16 79.0

Aldrin [2C] 41 - 1204.00 3.11 77.8

trans-Chlordane (beta-Chlordane) [2C] 45 - 1304.00 3.54 88.6

cis-Chlordane (alpha-chlordane) [2C] 44 - 1294.00 3.47 86.6

4,4'-DDE 57 - 1438.00 7.11 88.9

Dieldrin 44 - 1358.00 7.20 90.0

4,4'-DDD [2C] 55 - 1248.00 7.05 88.1

4,4'-DDT [2C] 45 - 1338.00 6.89 86.1

Hexachlorobutadiene 30 - 1204.00 2.47 61.6

Hexachlorobenzene 26 - 1204.00 2.72 68.0


Page 908 of 2729

of 2729

MS / MS DUPLICATE RECOVERY

EPA 8081B

DMMU-6


Project:

SDG:

Initial/Final:

Preparation:


Matrix:

Client:

Laboratory:

Source Sample:



16K0314

Solid

BEK0726 BEK0726-MS1

18.06 g / 2.5 mL DMMU-6


12/09/16 16:04Analyzed:

Sequence Name:: Matrix Spike

COMPOUND

SPIKE

ADDED

(ug/kg dry)

SAMPLE

CONCENTRATION

(ug/kg dry)

MS

CONCENTRATION

(ug/kg dry)

MS

%

REC. #

QC

LIMITS

REC.

3.88 ND 3.05 39 - 120Heptachlor 78.4

3.88 ND 2.40 41 - 120Aldrin 61.8

3.88 ND 3.63 45 - 130trans-Chlordane (beta-Chlordane) 93.6

3.88 ND 2.81 44 - 129cis-Chlordane (alpha-chlordane) [2C] 72.3

7.77 ND 6.14 57 - 1434,4'-DDE 79.1

7.77 ND 5.89 44 - 135Dieldrin 75.8

7.77 ND 5.86 55 - 1244,4'-DDD 75.4

7.77 ND 5.62 45 - 1334,4'-DDT 72.4

3.88 ND 2.20 30 - 120Hexachlorobutadiene 56.6

3.88 ND 2.54 26 - 120Hexachlorobenzene 65.3



Page 913 of 2729

MS / MS DUPLICATE RECOVERY

EPA 8081B

DMMU-6


Project:

SDG:

Initial/Final:

Preparation:


Matrix:

Client:

Laboratory:

Source Sample:



16K0314

Solid

BEK0726 BEK0726-MSD1

18.06 g / 2.5 mL DMMU-6


12/09/16 16:23Analyzed:

Sequence Name:: Matrix Spike Dup

SPIKE

ADDED

(ug/kg dry)

MSD

CONCENTRATION

(ug/kg dry)

MSD

%

REC. #

%

RPD #

QC LIMITS

RPD

REC.COMPOUND

3.88 2.62 15.0 30 39 - 120Heptachlor 67.5

3.88 2.74 13.3 30 41 - 120Aldrin 70.6

3.88 3.18 15.1 30 45 - 130trans-Chlordane (beta-Chlordane) [2C] 82.0

3.88 2.74 2.34 30 44 - 129cis-Chlordane (alpha-chlordane) [2C] 70.6

7.77 6.08 1.12 30 57 - 1434,4'-DDE 78.2

7.77 5.55 5.94 30 44 - 135Dieldrin 71.5

7.77 5.94 1.32 30 55 - 1244,4'-DDD 76.4

7.77 5.95 5.72 30 45 - 1334,4'-DDT 76.6

3.88 2.35 6.91 30 30 - 120Hexachlorobutadiene 60.6

3.88 2.72 7.11 30 26 - 120Hexachlorobenzene 70.1



Page 914 of 2729

of 2729

STANDARD REFERENCE MATERIAL RECOVERY

EPA 8081B

Laboratory:

Preparation:

Batch:

Matrix:

Client:

SDG:

Initial/Final:

Laboratory ID:

Project:


Solid

BEK0726


16K0314


BEK0726-SRM1

2.54 g / 2.5 mL

BergerABAM

Analyzed: 12/09/2016 15:45

Standard ID: C002496 Description: SRM 1944 Expires: 03/31/2017

ANALYTE

TRUE

(ug/kg wet)

FOUND

(ug/kg wet)

SRM

%

REC.

QC

LIMITS

REC.

trans-Chlordane (beta-Chlordane) 19.000 ND 0.0173 - 0.0044

cis-Chlordane (alpha-chlordane) 16.510 ND 0.0173 - 0.01734

4,4'-DDE 86.000 140 163 0.074 - 0.098

4,4'-DDD 108.00 131 122 0.092 - 0.124

4,4'-DDT 170.00 297 175 0.138 - 0.202

Hexachlorobenzene 6.0300 ND 0.00568 - 0.00638

cis-Nonachlor 3.7000 ND 0.003 - 0.0044

trans-Nonachlor 8.2000 ND 0.00769 - 0.00871


Page 933 of 2729

of 2729

EPA 8081B

INITIAL CALIBRATION DATA


Laboratory:

Instrument:

Project:

SDG:

Calibration:

Client:

ZK00009


BergerABAM

16K0314


ECD6

Calibration Date: 11/01/2016 15:35 STX-CLPColumn (1):

Compound

Level 01

RF

Level 02

RF

Level 03

RF

Level 04

RF

Level 05

RF RF

Level 06

Heptachlor 2.5 1.305096 5 1.335238 10 1.503016 1.535032 40 1.64764420

Aldrin 2.5 1.212028 5 1.279862 10 1.451018 1.494267 40 1.60940720

trans-Chlordane

(beta-Chlordane)

2.5 1.247851 5 1.230743 10 1.330832 1.369719 40 1.47781120

cis-Chlordane

(alpha-chlordane)

2.5 1.146437 5 1.148725 10 1.270658 1.302774 40 1.39558620

4,4'-DDE 5 1.083569 10 1.132839 20 1.261367 1.298744 80 1.40252340

Dieldrin 5 1.229685 10 1.254845 20 1.413278 1.431881 80 1.52261740

4,4'-DDD 5 0.8137256 10 0.8896288 20 1.00402 1.010792 80 1.03308340

4,4'-DDT 5 0.7811947 10 0.8712041 20 0.9651347 0.974982 80 1.00647940

Hexachlorobutadiene 2.5 1.942583 5 1.94891 10 2.171102 2.173177 40 2.31566120

Hexachlorobenzene 2.5 1.729324 5 1.590063 10 1.675267 1.63711 40 1.70265120

Decachlorobiphenyl 5 1.179659 10 1.166962 20 1.159971 1.069123 80 1.02234740

Tetrachlorometaxylene 5 0.5849222 10 0.5462581 20 0.58187 0.5704067 80 0.590431240

Page 942 of 2729

EPA 8081B



Laboratory:

Instrument:

Project:

SDG:

Calibration:

Client:

ZK00009


BergerABAM

16K0314


ECD6


Compound

Level 07

RF

Level 08

RF

Level 09

RF

Level 10

RF

Level 11

RF RF

Level 12

Heptachlor 80 1.620086

Aldrin 80 1.588582

trans-Chlordane

(beta-Chlordane)

80 1.468647

cis-Chlordane

(alpha-chlordane)

80 1.377695

4,4'-DDE 160 1.40268

Dieldrin 160 1.502884

4,4'-DDD 160 0.956125

4,4'-DDT 160 0.9454041

Hexachlorobutadiene 80 2.306914

Hexachlorobenzene 80 1.653538

Oxychlordane 5 0.9828942 1.02330110 20 1.023823

cis-Nonachlor 5 1.199051 1.22526410 20 1.244693

trans-Nonachlor 5 1.151512 1.17082210 20 1.178959

Decachlorobiphenyl 160 0.8973763

Tetrachlorometaxylene 160 0.5709033

Page 943 of 2729

EPA 8081B



Laboratory:

Instrument:

Project:

SDG:

Calibration:

Client:

ZK00009


BergerABAM

16K0314


ECD6


Compound

Level 13

RF

Level 14

RF

Level 15

RF

Level 16

RF

Level 17

RF RF

Level 18

Oxychlordane 40 80 1601.06015 1.048437 1.048327

cis-Nonachlor 40 80 1601.306945 1.314629 1.326637

trans-Nonachlor 40 80 1601.234809 1.237001 1.240245

Page 944 of 2729

EPA 8081B



Laboratory:

Instrument:

Project:

SDG:

Calibration:

Client:

ZK00009


BergerABAM

16K0314


ECD6


COMPOUND Mean RF RF RSD

Linear

COD

Quad

COD Q

Limit Type

& Limit

Heptachlor 9.6 RSD ()1.491019

Aldrin 11.3 RSD ()1.439194

trans-Chlordane (beta-Chlordane) 7.8 RSD ()1.354267

cis-Chlordane (alpha-chlordane) 8.5 RSD ()1.273646

4,4'-DDE 10.6 RSD ()1.26362

Dieldrin 8.9 RSD ()1.392532

4,4'-DDD 8.9 RSD ()0.9512291

4,4'-DDT 9.0 RSD ()0.9240664

Hexachlorobutadiene 7.7 RSD ()2.143058

Hexachlorobenzene 3.0 RSD ()1.664659

Oxychlordane 2.7 RSD ()1.031155

cis-Nonachlor 4.2 RSD ()1.269536

trans-Nonachlor 3.3 RSD ()1.202225

Decachlorobiphenyl 10.2 RSD ()1.082573

Tetrachlorometaxylene 2.7 RSD ()0.5741319

Page 945 of 2729

EPA 8081B



Laboratory:

Instrument:

Project:

SDG:

Calibration:

Client:

ZK00009


BergerABAM

16K0314


ECD6

Calibration Date: 11/01/2016 15:35 STX-CLP2Column (2):

Compound

Level 01

RF

Level 02

RF

Level 03

RF

Level 04

RF

Level 05

RF RF

Level 06

Heptachlor [2C] 2.5 1.097521 5 1.072157 10 1.13883 1.136832 40 1.18064720

Aldrin [2C] 2.5 1.112224 5 1.104518 10 1.170775 1.173468 40 1.21763220

trans-Chlordane

(beta-Chlordane) [2C]

2.5 1.04205 5 0.9843579 10 1.036454 1.0369 40 1.08138520

cis-Chlordane

(alpha-chlordane) [2C]

2.5 1.005693 5 0.9625755 10 1.008424 1.003306 40 1.04071320

4,4'-DDE [2C] 5 0.9086527 10 0.9324462 20 1.001745 1.003572 80 1.0408940

Dieldrin [2C] 5 1.051808 10 1.053343 20 1.112343 1.091843 80 1.11507540

4,4'-DDD [2C] 5 1.213923 10 1.245956 20 1.382114 1.371456 80 1.3998140

4,4'-DDT [2C] 5 1.115686 10 1.125882 20 1.232783 1.229313 80 1.28229440

Hexachlorobutadiene [2C] 2.5 1.809018 5 1.758659 10 1.849729 1.810515 40 1.89508420

Hexachlorobenzene [2C] 2.5 1.159408 5 1.051937 10 1.060775 1.020421 40 1.03609720

Decachlorobiphenyl [2C] 5 1.127927 10 1.013868 20 1.057182 0.9938107 80 0.981091940

Tetrachlorometaxylene [2C] 5 0.8634072 10 0.8311225 20 0.859984 0.8366384 80 0.850178640

Page 946 of 2729

EPA 8081B



Laboratory:

Instrument:

Project:

SDG:

Calibration:

Client:

ZK00009


BergerABAM

16K0314


ECD6


Compound

Level 07

RF

Level 08

RF

Level 09

RF

Level 10

RF

Level 11

RF RF

Level 12

Heptachlor [2C] 80 1.134297

Aldrin [2C] 80 1.179027

trans-Chlordane

(beta-Chlordane) [2C]

80 1.056694

cis-Chlordane

(alpha-chlordane) [2C]

80 1.012319

4,4'-DDE [2C] 160 1.010247

Dieldrin [2C] 160 1.071171

4,4'-DDD [2C] 160 1.314068

4,4'-DDT [2C] 160 1.242886

Hexachlorobutadiene [2C] 80 1.823313

Hexachlorobenzene [2C] 80 0.9886726

Oxychlordane [2C] 5 1.368012 1.33032910 20 1.305533

cis-Nonachlor [2C] 5 1.634367 1.6114810 20 1.605371

trans-Nonachlor [2C] 5 1.554747 1.52193810 20 1.497686

Decachlorobiphenyl [2C] 160 0.9162358

Tetrachlorometaxylene [2C] 160 0.8164507

Page 947 of 2729

EPA 8081B



Laboratory:

Instrument:

Project:

SDG:

Calibration:

Client:

ZK00009


BergerABAM

16K0314


ECD6


Compound

Level 13

RF

Level 14

RF

Level 15

RF

Level 16

RF

Level 17

RF RF

Level 18

Oxychlordane [2C] 40 80 1601.340038 1.320963 1.361897

cis-Nonachlor [2C] 40 80 1601.666385 1.675416 1.740365

trans-Nonachlor [2C] 40 80 1601.554117 1.550592 1.627541

Page 948 of 2729

EPA 8081B



Laboratory:

Instrument:

Project:

SDG:

Calibration:

Client:

ZK00009


BergerABAM

16K0314


ECD6


COMPOUND Mean RF RF RSD

Linear

COD

Quad

COD Q

Limit Type

& Limit

Heptachlor [2C] 3.3 RSD ()1.126714

Aldrin [2C] 3.7 RSD ()1.159607

trans-Chlordane (beta-Chlordane) [2C] 3.1 RSD ()1.03964

cis-Chlordane (alpha-chlordane) [2C] 2.5 RSD ()1.005505

4,4'-DDE [2C] 5.2 RSD ()0.9829255

Dieldrin [2C] 2.6 RSD ()1.082597

4,4'-DDD [2C] 5.8 RSD ()1.321221

4,4'-DDT [2C] 5.6 RSD ()1.204807

Hexachlorobutadiene [2C] 2.5 RSD ()1.824386

Hexachlorobenzene [2C] 5.5 RSD ()1.052885

Oxychlordane [2C] 1.8 RSD ()1.337795

cis-Nonachlor [2C] 3.0 RSD ()1.655564

trans-Nonachlor [2C] 2.8 RSD ()1.551103

Decachlorobiphenyl [2C] 7.1 RSD ()1.015019

Tetrachlorometaxylene [2C] 2.2 RSD ()0.8429636

Page 949 of 2729

of 2729

SECOND-SOURCE CALIBRATION VERIFICATION

EPA 8081B

Laboratory:

Sequence:

Calibration:

Client:

SDG:

Laboratory ID:

Project:

Sequence Name:


BergerABAM

ZK00009

SEK0011

SEK0011-SCV1

16K0314


E002544Standard ID:

INDAICV

ANALYTE

EXPECTED FOUND

% DRIFT QC LIMIT(ng/mL) (ng/mL)

20.0012.845.140.000Heptachlor

20.005.342.140.000Heptachlor [2C]

20.0016.846.740.000Aldrin

20.006.542.640.000Aldrin [2C]

20.0010.444.240.000trans-Chlordane (beta-Chlordane)

20.002.841.140.000trans-Chlordane (beta-Chlordane) [2C]

20.0011.344.540.000cis-Chlordane (alpha-chlordane)

20.002.941.240.000cis-Chlordane (alpha-chlordane) [2C]

20.009.143.640.0004,4'-DDE

20.005.342.140.0004,4'-DDE [2C]

20.006.842.740.000Dieldrin

20.001.340.540.000Dieldrin [2C]

20.0011.244.540.0004,4'-DDD

20.003.541.440.0004,4'-DDD [2C]

20.0012.244.940.0004,4'-DDT

20.003.941.640.0004,4'-DDT [2C]

* Indicates values outside of QC limits

[2C] indicates second-column analyte.

Page 1113 of 2729

SECOND-SOURCE CALIBRATION VERIFICATION

EPA 8081B

Laboratory:

Sequence:

Calibration:

Client:

SDG:

Laboratory ID:

Project:

Sequence Name:


BergerABAM

ZK00009

SEK0011

SEK0011-SCV2

16K0314


E004706Standard ID:

WNDICV

ANALYTE

EXPECTED FOUND

% DRIFT QC LIMIT(ng/mL) (ng/mL)

20.008.154.050.000Oxychlordane

20.00-1.149.450.000Oxychlordane [2C]

20.0010.655.350.000cis-Nonachlor

20.001.750.850.000cis-Nonachlor [2C]

20.0010.655.350.000trans-Nonachlor

20.002.151.050.000trans-Nonachlor [2C]

* Indicates values outside of QC limits

[2C] indicates second-column analyte.

Page 1114 of 2729

INITIAL CALIBRATION CHECK

EPA 8081B


Instrument ID:

Lab File ID:

Client:

Laboratory:

Sequence: Injection Date:

Project:

SDG:

Injection Time:Lab Sample ID:

Calibration:

Calibration Date:



16K0314

SEL0137

ZK00009

16120906.D

ECD6

SEL0137-ICV1

12/09/16

14:12

11/01/16 15:35

Sequence Name: Initial Cal Check

COMPOUND TYPE ICV MIN ICV LIMITICV ICAL

CONC. (ng/mL) % DRIFT/DIFFRESPONSE FACTOR

STD

1.5402320A 3.5 2020.7 1.491019020.000Heptachlor

1.0836200A -4.0 2019.2 1.126714020.000Heptachlor [2C]

1.5105980A 5.0 2021.0 1.439194020.000Aldrin

1.1550170A -0.5 2019.9 1.159607020.000Aldrin [2C]

1.3872580A 2.5 2020.5 1.354267020.000trans-Chlordane (beta-Chlordane)

1.0344440A -0.5 2019.9 1.039640020.000trans-Chlordane (beta-Chlordane) [2C]

1.2897540A 1.0 2020.2 1.273646020.000cis-Chlordane (alpha-chlordane)

1.0019780A -0.5 2019.9 1.005505020.000cis-Chlordane (alpha-chlordane) [2C]

1.3307100A 5.3 2042.1 1.263620040.0004,4'-DDE

1.0186440A 3.5 2041.4 0.982925540.0004,4'-DDE [2C]

1.4449040A 3.8 2041.5 1.392532040.000Dieldrin

1.1208380A 3.5 2041.4 1.082597040.000Dieldrin [2C]

0.9314947A -2.0 2039.2 0.951229140.0004,4'-DDD

1.1999300A -9.3 2036.3 1.321221040.0004,4'-DDD [2C]

0.9238067A 0.0 2040.0 0.924066440.0004,4'-DDT

1.0296910A -14.5 2034.2 1.204807040.0004,4'-DDT [2C]

2.1802800A 1.5 2020.3 2.143058020.000Hexachlorobutadiene

1.8332360A 0.5 2020.1 1.824386020.000Hexachlorobutadiene [2C]

1.6680070A 0.0 2020.0 1.664659020.000Hexachlorobenzene

1.0371470A -1.5 2019.7 1.052885020.000Hexachlorobenzene [2C]

1.0495620A -3.0 2038.8 1.082573040.000Decachlorobiphenyl

0.8899907A -12.3 2035.1 1.015019040.000Decachlorobiphenyl [2C]

0.5930222A 3.3 2041.3 0.574131940.000Tetrachlorometaxylene

0.8580008A 1.8 2040.7 0.842963640.000Tetrachlorometaxylene [2C]



Page 1115 of 2729

of 2729

INITIAL CALIBRATION CHECK

EPA 8081B


Instrument ID:

Lab File ID:

Client:

Laboratory:


Project:

SDG:


Calibration:

Calibration Date:



16K0314

SEL0137

ZK00009

16120907.D

ECD6

SEL0137-ICV3

12/09/16

14:31

11/01/16 15:35

Sequence Name: Initial Cal Check

COMPOUND TYPE ICV MIN ICV LIMITICV ICAL


STD

0.9864528A -4.3 2038.3 1.031155040.000Oxychlordane

1.1866950A 0.8 2040.3 1.337795040.000Oxychlordane [2C]

1.2287400A -3.3 2038.7 1.269536040.000cis-Nonachlor

1.4690020A -11.3 2035.5 1.655564040.000cis-Nonachlor [2C]

1.0527270A -12.5 2035.0 1.202225040.000trans-Nonachlor

1.3800200A -11.0 2035.6 1.551103040.000trans-Nonachlor [2C]



0.5716877A -0.5 2039.8 0.574131940.000Tetrachlorometaxylene

0.8185174A -3.0 2038.8 0.842963640.000Tetrachlorometaxylene [2C]


Page 1120 of 2729

of 2729

CONTINUING CALIBRATION CHECK

EPA 8081B


Instrument ID:

Lab File ID:

Client:

Laboratory:


Project:

SDG:


Calibration:

Calibration Date:



16K0314

SEL0137

ZK00009

16120922.D

ECD6

SEL0137-CCV1

12/09/16

19:10

11/01/16 15:35

Sequence Name: INDC2

COMPOUND TYPE CCV MIN CCV LIMITCCV ICAL


STD

1.5146120A 1.5 2020.3 1.491019020.000Heptachlor

1.0877250A -3.5 2019.3 1.126714020.000Heptachlor [2C]

1.4834040A 3.0 2020.6 1.439194020.000Aldrin

1.1156310A -4.0 2019.2 1.159607020.000Aldrin [2C]

1.3557940A 0.0 2020.0 1.354267020.000trans-Chlordane (beta-Chlordane)

0.9771672A -6.0 2018.8 1.039640020.000trans-Chlordane (beta-Chlordane) [2C]

1.2608270A -1.0 2019.8 1.273646020.000cis-Chlordane (alpha-chlordane)

0.9618338A -4.5 2019.1 1.005505020.000cis-Chlordane (alpha-chlordane) [2C]

1.2878330A 2.0 2040.8 1.263620040.0004,4'-DDE

0.9822269A 0.0 2040.0 0.982925540.0004,4'-DDE [2C]

1.4000320A 0.5 2040.2 1.392532040.000Dieldrin

1.0640910A -1.8 2039.3 1.082597040.000Dieldrin [2C]

0.9134096A -4.0 2038.4 0.951229140.0004,4'-DDD

1.2393290A -6.3 2037.5 1.321221040.0004,4'-DDD [2C]

0.8662309A -6.3 2037.5 0.924066440.0004,4'-DDT

1.1010080A -8.5 2036.6 1.204807040.0004,4'-DDT [2C]

2.1758930A 1.5 2020.3 2.143058020.000Hexachlorobutadiene

1.8060780A -1.0 2019.8 1.824386020.000Hexachlorobutadiene [2C]

1.6477630A -1.0 2019.8 1.664659020.000Hexachlorobenzene

1.0077310A -4.5 2019.1 1.052885020.000Hexachlorobenzene [2C]



0.5868164A 2.3 2040.9 0.574131940.000Tetrachlorometaxylene




Page 1125 of 2729

of 2729

CONTINUING CALIBRATION CHECK

EPA 8081B


Instrument ID:

Lab File ID:

Client:

Laboratory:


Project:

SDG:


Calibration:

Calibration Date:



16K0314

SEL0137

ZK00009

16120923.D

ECD6

SEL0137-CCV3

12/09/16

19:29

11/01/16 15:35

Sequence Name: WND

COMPOUND TYPE CCV MIN CCV LIMITCCV ICAL


STD

1.0007140A -3.0 2038.8 1.031155040.000Oxychlordane

1.2209410A -0.8 2039.7 1.337795040.000Oxychlordane [2C]

1.2415300A -2.3 2039.1 1.269536040.000cis-Nonachlor

1.4746520A -11.0 2035.6 1.655564040.000cis-Nonachlor [2C]

1.0607190A -11.8 2035.3 1.202225040.000trans-Nonachlor

1.4059580A -9.5 2036.2 1.551103040.000trans-Nonachlor [2C]


0.8038917A -20.8 *2031.7 1.015019040.000Decachlorobiphenyl [2C]

0.5617919A -2.3 2039.1 0.574131940.000Tetrachlorometaxylene



Page 1130 of 2729

of 2729

ORGANIC ANALYSIS DATA SHEET

EPA 8081B

Performance Mix

PEM COMPOUND RTRT WINDOW

FROM TO

CALC

AMOUNT

(ng)

NOM

AMOUNT

(ng)

%D

Laboratory:

Client:

SDG:

Project:

Laboratory ID:

Calibration:

Analyzed:

Matrix:

File ID:

Instrument:

Sequence:

Column:16K0314 1ZK00009

SEK0011-PEM1

BergerABAM



Solid

11/01/2016

16110102.D

ECD6

SEK0011

4,4'-DDT 7.42 0.73 0.83 0.112 0.100 9.1

Form 7B-ORSOM02.2 (08/2014)Page 1135 of 2729


EPA 8081B

Performance Mix


FROM TO

CALC

AMOUNT

(ng)

NOM

AMOUNT

(ng)

%D

Laboratory:

Client:

SDG:

Project:

Laboratory ID:

Calibration:

Analyzed:

Matrix:

File ID:

Instrument:

Sequence:

Column:16K0314 2ZK00009

SEK0011-PEM1

BergerABAM



Solid

11/01/2016

16110102.D

ECD6

SEK0011

4,4'-DDT 8.30 0.70 0.80 0.103 0.100 1.6



EPA 8081B

PEMA2


FROM TO

CALC

AMOUNT

(ng)

NOM

AMOUNT

(ng)

%D

Laboratory:

Client:

SDG:

Project:

Laboratory ID:

Calibration:

Analyzed:

Matrix:

File ID:

Instrument:

Sequence:

Column:16K0314 1ZK00009

SEL0137-PEM2

BergerABAM



Solid

12/09/2016

16120921.D

ECD6

SEL0137

4,4'-DDT 7.42 0.73 0.83 0.098 0.100 -2.4



EPA 8081B

PEMA2


FROM TO

CALC

AMOUNT

(ng)

NOM

AMOUNT

(ng)

%D

Laboratory:

Client:

SDG:

Project:

Laboratory ID:

Calibration:

Analyzed:

Matrix:

File ID:

Instrument:

Sequence:

Column:16K0314 2ZK00009

SEL0137-PEM2

BergerABAM



Solid

12/09/2016

16120921.D

ECD6

SEL0137

4,4'-DDT 8.29 0.70 0.80 0.083 0.100 -16.8



EPA 8081B

Performance Mix


FROM TO

CALC

AMOUNT

(ng)

NOM

AMOUNT

(ng)

%D

Laboratory:

Client:

SDG:

Project:

Laboratory ID:

Calibration:

Analyzed:

Matrix:

File ID:

Instrument:

Sequence:

Column:16K0314 1ZK00009

SEL0137-PEM1

BergerABAM



Solid

12/09/2016

16120905.D

ECD6

SEL0137

4,4'-DDT 7.42 0.73 0.83 0.105 0.100 4.8



EPA 8081B

Performance Mix


FROM TO

CALC

AMOUNT

(ng)

NOM

AMOUNT

(ng)

%D

Laboratory:

Client:

SDG:

Project:

Laboratory ID:

Calibration:

Analyzed:

Matrix:

File ID:

Instrument:

Sequence:

Column:16K0314 2ZK00009

SEL0137-PEM1

BergerABAM



Solid

12/09/2016

16120905.D

ECD6

SEL0137

4,4'-DDT 8.29 0.70 0.80 0.087 0.100 -13.4



EPA 8081B

Dual Column

SDG:

Project:


Client:

Laboratory:

Calibration:



SEK0011 ECD6

ZK00009

Sample Name Lab Sample ID Column 1 File ID Analysis Date/TimeMatrixColumn 2 File ID

Performance Mix SEK0011-PEM1 11/01/16 15:07Solid16110102.D 16110102.D

Cal Standard SEK0011-CAL1 11/01/16 15:26Solid16110103.D 16110103.D







Secondary Cal Check SEK0011-SCV1 11/01/16 17:37Solid16110110.D 16110110.D



Cal Standard SEK0011-CALA 11/01/16 18:33Solid16110113.D 16110113.D

Cal Standard SEK0011-CALB 11/01/16 18:52Solid16110114.D 16110114.D

Cal Standard SEK0011-CALC 11/01/16 19:10Solid16110115.D 16110115.D

Cal Standard SEK0011-CALD 11/01/16 19:29Solid16110116.D 16110116.D

Cal Standard SEK0011-CALE 11/01/16 19:48Solid16110117.D 16110117.D

Cal Standard SEK0011-CALF 11/01/16 20:06Solid16110118.D 16110118.D

Secondary Cal Check SEK0011-SCV2 11/01/16 20:25Solid16110119.D 16110119.D

Cal Standard SEK0011-CALG 11/01/16 20:44Solid16110120.D 16110120.D

Page 1141 of 2729


EPA 8081B

Dual Column

SDG:

Project:


Client:

Laboratory:

Calibration:



SEL0137 ECD6

ZK00009

Sample Name Lab Sample ID Column 1 File ID Analysis Date/TimeMatrixColumn 2 File ID

Performance Mix SEL0137-PEM1 12/09/16 13:53Solid16120905.D 16120905.D

Initial Cal Check SEL0137-ICV1 12/09/16 14:12Solid16120906.D 16120906.D

Initial Cal Check SEL0137-ICV3 12/09/16 14:31Solid16120907.D 16120907.D

Blank BEK0726-BLK1 12/09/16 14:49Solid16120908.D 16120908.D

LCS BEK0726-BS1 12/09/16 15:08Solid16120909.D 16120909.D

MRL Check BEK0726-MRL1 12/09/16 15:27Solid16120910.D 16120910.D

Reference BEK0726-SRM1 12/09/16 15:45Solid16120911.D 16120911.D

DMMU-6 BEK0726-MS1 12/09/16 16:04Solid16120912.D 16120912.D

DMMU-6 BEK0726-MSD1 12/09/16 16:23Solid16120913.D 16120913.D

DMMU-1 16K0314-05 12/09/16 16:41Solid16120914.D 16120914.D

DMMU-2 16K0314-10 12/09/16 17:00Solid16120915.D 16120915.D

DMMU-3 16K0314-15 12/09/16 17:19Solid16120916.D 16120916.D

DMMU-4 16K0314-20 12/09/16 17:37Solid16120917.D 16120917.D

DMMU-5 16K0314-25 12/09/16 17:56Solid16120918.D 16120918.D

DMMU-6 16K0314-30 12/09/16 18:14Solid16120919.D 16120919.D

DMMU-7 16K0314-35 12/09/16 18:33Solid16120920.D 16120920.D

Performance Mix SEL0137-PEM2 12/09/16 18:52Solid16120921.D 16120921.D

Calibration Check SEL0137-CCV1 12/09/16 19:10Solid16120922.D 16120922.D

Calibration Check SEL0137-CCV3 12/09/16 19:29Solid16120923.D 16120923.D

Page 1142 of 2729

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of 2729

EPA 8081B

Laboratory: SDG/WO:

Project:


Client:

Calibration:



SEK0011 ECD6

ZK00009

16K0314

Calibration Date: 11/01/2016


SURROGATE RECOVERY AND RT SUMMARY

Surrogate

Compound

Spike Level

ng/mL Recovery

%

RT

Calibration

Mean RT

Recovery

Limits RT Diff Limit

RT Diff

Q

SEK0011-PEM1 (Solid) Lab File ID: 16110102.D Analyzed: 11/01/16 15:07

Decachlorobiphenyl 40.000 89.5 9.382 9.3808330 - 200 0.0012 +/-0.1

Decachlorobiphenyl [2C] 40.000 80.5 10.467 10.466330 - 200 0.0007 +/-0.1

Tetrachlorometaxylene 40.000 82.5 3.825 3.8231670 - 200 0.0018 +/-0.1

Tetrachlorometaxylene [2C] 40.000 82.8 4.228 4.2268330 - 200 0.0012 +/-0.1

Page 1151 of 2729

EPA 8081B

Laboratory: SDG/WO:

Project:


Client:

Calibration:



SEL0137 ECD6

ZK00009

16K0314




Surrogate

Compound

Spike Level

ng/mL Recovery

%

RT

Calibration

Mean RT

Recovery


RT Diff

Q

SEL0137-PEM1 (Solid) Lab File ID: 16120905.D Analyzed: 12/09/16 13:53

Decachlorobiphenyl 40.000 87.5 9.373 9.38083330 - 160 -0.0078 +/-0.1

Decachlorobiphenyl [2C] 40.000 79.1 10.451 10.4663330 - 160 -0.0153 +/-0.1

Tetrachlorometaxylene 40.000 97.0 3.818 3.82316730 - 160 -0.0052 +/-0.1

Tetrachlorometaxylene [2C] 40.000 94.2 4.219 4.22683330 - 160 -0.0078 +/-0.1

SEL0137-ICV1 (Solid) Lab File ID: 16120906.D Analyzed: 12/09/16 14:12



Tetrachlorometaxylene 40.000 103 3.819 3.82316780 - 120 -0.0042 +/-0.1

Tetrachlorometaxylene [2C] 40.000 102 4.219 4.22683380 - 120 -0.0078 +/-0.1

SEL0137-ICV3 (Solid) Lab File ID: 16120907.D Analyzed: 12/09/16 14:31





BEK0726-BLK1 (Solid) Lab File ID: 16120908.D Analyzed: 12/09/16 14:49

Decachlorobiphenyl 8.0000 101 9.373 9.38083330 - 160 -0.0078 +/-0.1

Decachlorobiphenyl [2C] 8.0000 108 10.451 10.4663330 - 160 -0.0153 +/-0.1



BEK0726-BS1 (Solid) Lab File ID: 16120909.D Analyzed: 12/09/16 15:08





BEK0726-MRL1 (Solid) Lab File ID: 16120910.D Analyzed: 12/09/16 15:27





Page 1152 of 2729

EPA 8081B

Laboratory: SDG/WO:

Project:


Client:

Calibration:



SEL0137 ECD6

ZK00009

16K0314




Surrogate

Compound

Spike Level

ug/kg wet Recovery

%

RT

Calibration

Mean RT

Recovery


RT Diff

Q

BEK0726-SRM1 (Solid) Lab File ID: 16120911.D Analyzed: 12/09/16 15:45

Decachlorobiphenyl 39.370 271 9.377 9.38083330 - 160 -0.0038 +/-0.1 NRS

Decachlorobiphenyl [2C] 39.370 211 10.461 10.4663330 - 160 -0.0053 +/-0.1 NRS

Tetrachlorometaxylene 39.370 111 3.818 3.82316730 - 160 -0.0052 +/-0.1


BEK0726-MS1 (Solid) Lab File ID: 16120912.D Analyzed: 12/09/16 16:04





BEK0726-MSD1 (Solid) Lab File ID: 16120913.D Analyzed: 12/09/16 16:23





16K0314-05 (Solid) Lab File ID: 16120914.D Analyzed: 12/09/16 16:41















Page 1153 of 2729

EPA 8081B

Laboratory: SDG/WO:

Project:


Client:

Calibration:



SEL0137 ECD6

ZK00009

16K0314




Surrogate

Compound

Spike Level

ug/kg dry Recovery

%

RT

Calibration

Mean RT

Recovery


RT Diff

Q





















SEL0137-PEM2 (Solid) Lab File ID: 16120921.D Analyzed: 12/09/16 18:52





Page 1154 of 2729

INTERNAL STANDARD AREA AND RT SUMMARY

EPA 8081B


SDG:

Project:


Client:

Laboratory:

Calibration:


BergerABAM

SEK0011 ECD6

ZK00009


16K0314

RTResponseInternal Standard Area % RT DiffResponse

Reference

RT

Reference Area %

Limits

RT Diff

Limit Q

Performance Mix (SEK0011-PEM1 ) Lab File ID: 16110102.D Analyzed: 11/01/16 15:07(Solid)

1-Bromo-2-Nitrobenzene 654160 3.143 945911 3.141 50 - 20069 -0.0020 +/-0.50

Hexabromobiphenyl 722145 9.533 1024064 9.532 50 - 20071 -0.0010 +/-0.50

1-Bromo-2-Nitrobenzene [2C] 249554 3.369 352439 3.367 50 - 20071 -0.0020 +/-0.50

Hexabromobiphenyl [2C] 157369 11.053 214079 11.053 50 - 20074 0.0000 +/-0.50

Secondary Cal Check (SEK0011-SCV1 ) Lab File ID: 16110110.D Analyzed: 11/01/16 17:37(Solid)

1-Bromo-2-Nitrobenzene 914445 3.141 945911 3.141 50 - 20097 0.0000 +/-0.50

Hexabromobiphenyl 979379 9.531 1024064 9.532 50 - 20096 0.0010 +/-0.50

1-Bromo-2-Nitrobenzene [2C] 341042 3.367 352439 3.367 50 - 20097 0.0000 +/-0.50


Secondary Cal Check (SEK0011-SCV2 ) Lab File ID: 16110119.D Analyzed: 11/01/16 20:25(Solid)





Page 1155 of 2729


EPA 8081B


SDG:

Project:


Client:

Laboratory:

Calibration:


BergerABAM

SEL0137 ECD6

ZK00009


16K0314


Reference

RT

Reference Area %

Limits

RT Diff

Limit Q

Performance Mix (SEL0137-PEM1 ) Lab File ID: 16120905.D Analyzed: 12/09/16 13:53(Solid)





Initial Cal Check (SEL0137-ICV1 ) Lab File ID: 16120906.D Analyzed: 12/09/16 14:12(Solid)





Initial Cal Check (SEL0137-ICV3 ) Lab File ID: 16120907.D Analyzed: 12/09/16 14:31(Solid)





Blank (BEK0726-BLK1 ) Lab File ID: 16120908.D Analyzed: 12/09/16 14:49(Solid)





LCS (BEK0726-BS1 ) Lab File ID: 16120909.D Analyzed: 12/09/16 15:08(Solid)





MRL Check (BEK0726-MRL1 ) Lab File ID: 16120910.D Analyzed: 12/09/16 15:27(Solid)





Page 1156 of 2729


EPA 8081B


SDG:

Project:


Client:

Laboratory:

Calibration:


BergerABAM

SEL0137 ECD6

ZK00009


16K0314


Reference

RT

Reference Area %

Limits

RT Diff

Limit Q

Reference (BEK0726-SRM1 ) Lab File ID: 16120911.D Analyzed: 12/09/16 15:45(Solid)





Matrix Spike (BEK0726-MS1 ) Lab File ID: 16120912.D Analyzed: 12/09/16 16:04(Solid)





Matrix Spike Dup (BEK0726-MSD1 ) Lab File ID: 16120913.D Analyzed: 12/09/16 16:23(Solid)





DMMU-1 (16K0314-05 ) Lab File ID: 16120914.D Analyzed: 12/09/16 16:41(Solid)















Page 1157 of 2729


EPA 8081B


SDG:

Project:


Client:

Laboratory:

Calibration:


BergerABAM

SEL0137 ECD6

ZK00009


16K0314


Reference

RT

Reference Area %

Limits

RT Diff

Limit Q





















Performance Mix (SEL0137-PEM2 ) Lab File ID: 16120921.D Analyzed: 12/09/16 18:52(Solid)





Page 1158 of 2729

Date

Collected

Date

Received

Date

Prepared

Days

to

Prep

Max

Days to

Prep

Date

Analyzed

Days

to

Analysis

Max

Days to

AnalysisSample Name Q

HOLDING TIME SUMMARY

Analysis: EPA 8081B

Laboratory:

Project:

SDG:

Client:


BergerABAM

16K0314


DMMU-1 14 40 10

11/21/16

09:15

11/22/16

15:08

11/29/16

13:55

12/09/16

16:4116K0314-05 8

DMMU-2 14 40 10

11/21/16

10:10

11/22/16

15:08

11/29/16

13:55

12/09/16

17:0016K0314-10 8

DMMU-3 14 40 10

11/21/16

11:00

11/22/16

15:08

11/29/16

13:55

12/09/16

17:1916K0314-15 8

DMMU-4 14 40 10

11/21/16

11:50

11/22/16

15:08

11/29/16

13:55

12/09/16

17:3716K0314-20 8

DMMU-5 14 40 10

11/21/16

13:05

11/22/16

15:08

11/29/16

13:55

12/09/16

17:5616K0314-25 8

DMMU-6 14 40 10

11/21/16

13:55

11/22/16

15:08

11/29/16

13:55

12/09/16

18:1416K0314-30 8

DMMU-7 14 40 10

11/21/16

15:15

11/22/16

15:08

11/29/16

13:55

12/09/16

18:3316K0314-35 7

Matrix Spike 14 40 10

11/21/16

13:55

11/22/16

15:08

11/29/16

13:55

12/09/16

16:04BEK0726-MS1 8

Matrix Spike Dup 14 40 10

11/21/16

13:55

11/22/16

15:08

11/29/16

13:55

12/09/16

16:23BEK0726-MSD1 8

* Indicates hold time exceedance.

Page 1159 of 2729

Analyte MDL Units

METHOD DETECTION

AND REPORTING LIMITS

EPA 8081B

Laboratory:

Matrix:

Client:

SDG:

Project:

Instrument:


Solid

16K0314


ECD6

BergerABAM

RL

0.05 ug/kgHeptachlor 0.50

0.05 ug/kgHeptachlor [2C] 0.50

0.37 ug/kgAldrin 0.50

0.37 ug/kgAldrin [2C] 0.50

0.33 ug/kgtrans-Chlordane (beta-Chlordane) 0.50

0.33 ug/kgtrans-Chlordane (beta-Chlordane) [2C] 0.50

0.11 ug/kgcis-Chlordane (alpha-chlordane) 0.50

0.11 ug/kgcis-Chlordane (alpha-chlordane) [2C] 0.50

0.14 ug/kg4,4'-DDE 1.00

0.14 ug/kg4,4'-DDE [2C] 1.00

0.12 ug/kgDieldrin 1.00

0.12 ug/kgDieldrin [2C] 1.00

0.32 ug/kg4,4'-DDD 1.00

0.32 ug/kg4,4'-DDD [2C] 1.00

0.33 ug/kg4,4'-DDT 1.00

0.33 ug/kg4,4'-DDT [2C] 1.00

0.34 ug/kgHexachlorobutadiene 1.00

0.34 ug/kgHexachlorobutadiene [2C] 0.50

0.15 ug/kgHexachlorobenzene 1.00

0.15 ug/kgHexachlorobenzene [2C] 0.50

0.13 ug/kgOxychlordane 1.00

0.13 ug/kgOxychlordane [2C] 1.00

0.21 ug/kgcis-Nonachlor 1.00

0.21 ug/kgcis-Nonachlor [2C] 1.00

0.23 ug/kgtrans-Nonachlor 1.00

0.23 ug/kgtrans-Nonachlor [2C] 1.00

Page 1160 of 2729

Form I


DMMU-1

EPA 8270D


8270D SVOC (20-200 ug/kg) (0.2-2 ug/L SepF)

Laboratory:

Client:

Matrix:

Sampled:

Solids:




SDG: 16K0314

Soil Laboratory ID: File ID:16K0314-05 N1416120913.D

Prepared: Analyzed:11/21/16 09:15 11/29/16 15:40 12/09/16 22:23

69.40 Preparation: Initial/Final:EPA 3546 (Microwave)

BEK0736 SEL0144 ZK00072

15.03 g / 1 mL

Instrument: NT14 Column: ZB-5MS

CAS NO. QCONC. (ug/kg dry)COMPOUND DILUTION DL RL

108-95-2 Phenol 2401 7.9 19.2

106-46-7 1,4-Dichlorobenzene 19.21 U 4.2 19.2


100-51-6 Benzyl Alcohol 19.21 U 14.3 19.2

95-48-7 2-Methylphenol 19.21 U 7.5 19.2

106-44-5 4-Methylphenol 23.81 14.1 19.2

105-67-9 2,4-Dimethylphenol 95.91 U 25.7 95.9

120-82-1 1,2,4-Trichlorobenzene 19.21 U 5.7 19.2

91-20-3 Naphthalene 8.91 J 5.0 19.2

65-85-0 Benzoic acid 1921 U 56.7 192


91-57-6 2-Methylnaphthalene 13.01 J 5.4 19.2

208-96-8 Acenaphthylene 19.21 U 4.6 19.2

131-11-3 Dimethylphthalate 19.21 U 6.2 19.2

83-32-9 Acenaphthene 19.21 U 4.9 19.2

132-64-9 Dibenzofuran 19.21 U 4.4 19.2

86-73-7 Fluorene 5.61 J 4.7 19.2

84-66-2 Diethyl phthalate 19.21 U 17.0 19.2

86-30-6 N-Nitrosodiphenylamine 19.21 U 9.2 19.2


87-86-5 Pentachlorophenol 95.91 U 30.0 95.9

85-01-8 Phenanthrene 32.31 4.5 19.2

120-12-7 Anthracene 7.31 J 5.7 19.2

84-74-2 Di-n-Butylphthalate 19.21 U 5.1 19.2

206-44-0 Fluoranthene 32.21 4.3 19.2

129-00-0 Pyrene 33.41 5.3 19.2

85-68-7 Butylbenzylphthalate 19.21 U 7.7 19.2

56-55-3 Benzo(a)anthracene 15.81 J 5.0 19.2

218-01-9 Chrysene 24.51 5.0 19.2

117-81-7 bis(2-Ethylhexyl)phthalate 47.91 U 27.6 47.9

117-84-0 Di-n-Octylphthalate 19.21 U 8.4 19.2

Benzofluoranthenes, Total 39.51 9.8 38.3

50-32-8 Benzo(a)pyrene 12.91 J 6.2 19.2

193-39-5 Indeno(1,2,3-cd)pyrene 9.41 J 5.7 19.2

53-70-3 Dibenzo(a,h)anthracene 19.21 U 5.9 19.2

191-24-2 Benzo(g,h,i)perylene 12.01 J 5.6 19.2

Page 1161 of 2729

Form I


DMMU-1

EPA 8270D



Laboratory:

Client:

Matrix:

Sampled:

Solids:




SDG: 16K0314




BEK0736 SEL0144 ZK00072

15.03 g / 1 mL


SURROGATES ADDED (ug/kg dry) CONC (ug/kg dry) % REC QQC LIMITS

2-Fluorophenol 719.02 64.4463 27 - 120

Phenol-d5 719.02 66.0475 29 - 120

2-Chlorophenol-d4 719.02 67.6486 31 - 120

1,2-Dichlorobenzene-d4 479.35 67.0321 32 - 120

Nitrobenzene-d5 479.35 72.0345 30 - 120

2-Fluorobiphenyl 479.35 69.2332 35 - 120

2,4,6-Tribromophenol 719.02 84.9610 24 - 134

p-Terphenyl-d14 479.35 77.8373 37 - 120

Page 1162 of 2729

of 2729

Data File: \\Target\share\chem3\nt14.i\20161209.b\N1416120913.D Page 1 Report Date: 13-Dec-2016 12:16 ARI Labs, Inc. Semivolatile Report SW846 Method 8270DData file : \\Target\share\chem3\nt14.i\20161209.b\N1416120913.DLab Smp Id: 16K0314-05 Inj Date : 09-DEC-2016 22:23 Operator : YZ Inst ID: nt14.iSmp Info : 16K0314-05Misc Info : Comment : 1ul InjectionMethod : \\Target\share\chem3\nt14.i\20161209.b\ABNSTDICAL.mMeth Date : 12-Dec-2016 09:26 yev Quant Type: ISTDCal Date : 25-NOV-2016 18:18 Cal File: N1416112509.DAls bottle: 12 Dil Factor: 1.00000 Integrator: HP RTE Compound Sublist: PSDDAICAL.subTarget Version: 4.14 Processing Host: ORGDATA03

CONCENTRATIONS QUANT SIG ON-COLUMN FINAL

Compounds MASS RT EXP RT REL RT RESPONSE (ug/mL) (ug/mL)

========================== ==== ==== ======== ======== ======== ======= ======= 1 N-Nitrosodimethylamine 74 Compound Not Detected. 2 Pyridine 79 Compound Not Detected.

$ 3 2-Fluorophenol 112 6.443 6.412 (0.751) 417182 4.82675 4.827

$ 4 Phenol-d5 99 7.988 7.973 (0.931) 571779 4.95229 4.952 5 Phenol 94 8.004 7.996 (0.932) 306941 2.50743 2.507 6 Aniline 93 Compound Not Detected. 7 Bis(2-Chloroethyl)ether 93 Compound Not Detected.

$ 8 2-Chlorophenol-d4 132 8.235 8.228 (0.959) 465583 5.07105 5.071 9 2-Chlorophenol 128 Compound Not Detected. 10 1,3-Dichlorobenzene 146 Compound Not Detected.

* 11 1,4-Dichlorobenzene-d4 152 8.584 8.584 (1.000) 267959 4.00000 12 1,4-Dichlorobenzene 146 Compound Not Detected. 13 Benzyl alcohol 108 Compound Not Detected.

$ 14 1,2-Dichlorobenzene-d4 152 8.933 8.933 (1.041) 211535 3.34846 3.348 15 1,2-Dichlorobenzene 146 Compound Not Detected. 16 2-Methylphenol 108 Compound Not Detected. 17 2,2'-oxybis(1-Chloropropane) 121 Compound Not Detected. 18 4-Methylphenol 108 9.375 9.352 (1.092) 19161 0.24805 0.2481(H) 19 N-Nitroso-di-n-propylamine 70 Compound Not Detected. 20 Hexachloroethane 117 Compound Not Detected.

$ 21 Nitrobenzene-d5 82 9.655 9.655 (0.876) 384061 3.59758 3.598 22 Nitrobenzene 77 Compound Not Detected. 23 Isophorone 82 Compound Not Detected. 24 2-Nitrophenol 139 Compound Not Detected. 25 2,4-Dimethylphenol 107 Compound Not Detected. 26 Benzoic acid 105 Compound Not Detected. 27 Bis(2-Chloroethoxy)methane 93 Compound Not Detected. 28 2,4-Dichlorophenol 162 Compound Not Detected. 29 1,2,4-Trichlorobenzene 180 Compound Not Detected.

* 30 Naphthalene-d8 136 11.021 11.021 (1.000) 1051821 4.00000 31 Naphthalene 128 11.059 11.060 (1.004) 23775 0.09320 0.09320(H) 32 4-Chloroaniline 127 Compound Not Detected. 33 Hexachlorobutadiene 225 Compound Not Detected.

Page 1188 of 2729

Data File: \\Target\share\chem3\nt14.i\20161209.b\N1416120913.D Page 2 Report Date: 13-Dec-2016 12:16



========================== ==== ==== ======== ======== ======== ======= ======= 34 4-Chloro-3-methylphenol 107 Compound Not Detected. 35 2-Methylnaphthalene 142 12.436 12.437 (1.128) 26962 0.13567 0.1357 36 1-methylnaphthalene 142 12.653 12.653 (1.148) 21014 0.09952 0.09952 37 Hexachlorocyclopentadiene 237 Compound Not Detected. 38 2,4,6-Trichlorophenol 196 Compound Not Detected. 39 2,4,5-Trichlorophenol 196 Compound Not Detected.

$ 40 2-Fluorobiphenyl 172 13.218 13.218 (0.907) 665569 3.45957 3.460 41 2-Chloronaphthalene 162 Compound Not Detected. 42 2-Nitroaniline 65 Compound Not Detected. 43 Retene 219 Compound Not Detected. 44 Dimethylphthalate 163 Compound Not Detected. 45 2,6-Dinitrotoluene 165 Compound Not Detected. 46 Acenaphthylene 152 Compound Not Detected. 47 3-Nitroaniline 138 Compound Not Detected.

* 48 Acenaphthene-d10 164 14.572 14.580 (1.000) 514932 4.00000 49 Acenaphthene 153 Compound Not Detected. 50 2,4-Dinitrophenol 184 Compound Not Detected. 51 4-Nitrophenol 109 Compound Not Detected. 52 Dibenzofuran 168 Compound Not Detected. 53 2,4-Dinitrotoluene 165 Compound Not Detected. 54 2,3,4,6-Tetrachlorophenol 232 Compound Not Detected. 55 Diethylphthalate 149 15.562 15.562 (1.068) 24704 0.13162 0.1316 56 Fluorene 166 15.662 15.663 (1.075) 10385 0.05808 0.05808 57 4-Chlorophenyl-phenylether 204 Compound Not Detected. 58 4-Nitroaniline 138 Compound Not Detected. 59 4,6-Dinitro-2-methylphenol 198 Compound Not Detected. 60 N-Nitrosodiphenylamine 169 Compound Not Detected. 61 Azobenzene (1,2-DP-Hydrazine) 77 Compound Not Detected.

$ 62 2,4,6-Tribromophenol 330 16.195 16.195 (1.111) 173402 6.36383 6.364 63 4-Bromophenyl-phenylether 248 Compound Not Detected. 64 Hexachlorobenzene 284 Compound Not Detected. 65 Pentachlorophenol 266 Compound Not Detected.

* 66 Phenanthrene-d10 188 17.562 17.563 (1.000) 956125 4.00000 67 Phenanthrene 178 17.609 17.609 (1.003) 81936 0.33737 0.3374 68 Anthracene 178 17.694 17.702 (1.007) 18368 0.07620 0.07620 69 Carbazole 167 18.034 18.035 (1.027) 7658 0.07688 0.07688 70 Di-n-butylphthalate 149 18.885 18.886 (1.075) 5513 0.01881 0.01881 71 Fluoranthene 202 19.999 20.000 (0.884) 89196 0.33570 0.3357 72 Benzidine 184 Compound Not Detected. 73 Pyrene 202 20.417 20.418 (0.903) 96004 0.34867 0.3487

$ 74 Terphenyl-d14 244 20.742 20.743 (0.917) 714884 3.89103 3.891 75 Butylbenzylphthalate 149 Compound Not Detected. 76 3,3'-Dichlorobenzidine 252 Compound Not Detected. 77 Benzo(a)anthracene 228 22.585 22.586 (0.999) 41273 0.16442 0.1644

* 78 Chrysene-d12 240 22.616 22.616 (1.000) 907483 4.00000 79 Chrysene 228 22.655 22.655 (1.002) 57159 0.25521 0.2552 80 bis(2-Ethylhexyl)phthalate 149 22.732 22.725 (0.959) 33831 0.17126 0.1713

* 81 Di-n-octylphthalate-d4 153 23.700 23.700 (1.000) 1536755 4.00000 82 Di-n-octylphthalate 149 Compound Not Detected. 83 Benzo(b)fluoranthene 252 24.342 24.343 (0.974) 52394 0.22862 0.2286 85 Benzo(k)fluoranthene 252 24.373 24.382 (0.976) 48225 0.20144 0.2014(M) 84 Total Benzofluoranthenes 252 24.342 24.382 (0.974) 92177 0.41253 0.4125 86 Benzo(a)pyrene 252 24.892 24.893 (0.996) 27867 0.13433 0.1343

* 87 Perylene-d12 264 24.985 24.993 (1.000) 813034 4.00000

Page 1189 of 2729




========================== ==== ==== ======== ======== ======== ======= ======= 88 Perylene 252 25.032 25.032 (1.002) 39536 0.14753 0.1475 89 Indeno(1,2,3-cd)pyrene 276 27.178 27.178 (1.088) 22603 0.09783 0.09783 90 Dibenzo(a,h)anthracene 278 27.201 27.194 (1.089) 9692 0.05060 0.05060(M) 91 Benzo(g,h,i)perylene 276 27.815 27.815 (1.113) 24609 0.12557 0.1256

QC Flag Legend M - Compound response manually integrated.H - Operator selected an alternate compound hit.

Page 1190 of 2729

Data File: \\Target\share\chem3\nt14.i\20161209.b\N1416120913.D Page 1 Report Date: 13-Dec-2016 12:16 ARI Labs, Inc. INTERNAL STANDARD COMPOUNDS AREA AND RT SUMMARY Instrument ID: nt14.i Calibration Date: 09-DEC-2016 Lab File ID: N1416120913.D Calibration Time: 16:39Lab Smp Id: 16K0314-05 Analysis Type: SV Level: Quant Type: ISTD Sample Type: Operator: YZMethod File: \\Target\share\chem3\nt14.i\20161209.b\ABNSTDICAL.mMisc Info: Test Mode: Use Initial Calibration Level 5. _________________________________________________________________________| | | AREA LIMIT | | || COMPOUND | STANDARD | LOWER | UPPER | SAMPLE | %DIFF ||=====================|==========|==========|==========|==========|=======|| 11 1,4-Dichlorobenze| 262244| 131122| 524488| 267959| 2.18|| 30 Naphthalene-d8 | 1028555| 514278| 2057110| 1051821| 2.26|| 48 Acenaphthene-d10 | 505255| 252628| 1010510| 514932| 1.92|| 66 Phenanthrene-d10 | 898548| 449274| 1797096| 956125| 6.41|| 78 Chrysene-d12 | 831926| 415963| 1663852| 907483| 9.08|| 81 Di-n-octylphthala| 1349307| 674654| 2698614| 1536755| 13.89|| 87 Perylene-d12 | 731711| 365856| 1463422| 813034| 11.11||_____________________|__________|__________|__________|__________|_______| _________________________________________________________________________| | | RT LIMIT | | || COMPOUND | STANDARD | LOWER | UPPER | SAMPLE | %DIFF ||=====================|==========|==========|==========|==========|=======|| 11 1,4-Dichlorobenze| 8.58| 8.08| 9.08| 8.58| -0.00|| 30 Naphthalene-d8 | 11.02| 10.52| 11.52| 11.02| -0.00|| 48 Acenaphthene-d10 | 14.58| 14.08| 15.08| 14.57| -0.06|| 66 Phenanthrene-d10 | 17.56| 17.06| 18.06| 17.56| -0.00|| 78 Chrysene-d12 | 22.62| 22.12| 23.12| 22.62| -0.00|| 81 Di-n-octylphthala| 23.70| 23.20| 24.20| 23.70| -0.00|| 87 Perylene-d12 | 24.99| 24.49| 25.49| 24.99| -0.03||_____________________|__________|__________|__________|__________|_______| AREA UPPER LIMIT = +100% of internal standard area.AREA LOWER LIMIT = - 50% of internal standard area.RT UPPER LIMIT = + 0.50 minutes of internal standard RT.RT LOWER LIMIT = - 0.50 minutes of internal standard RT.

Page 1191 of 2729

REVIEW SUMMARY FOR FILE - N1416120913.D Lab ID: 16K0314-05 nt14.i, ABNSTDICAL.m, 09-DEC-2016 22:23

RT CO-ELUTION COMPOUNDS --------------------------------------------------------------------------- NO CO-ELUTIONS Quant Method: ICAL RRT CHECK RRT CCV RRT DELTA COMPOUND ------------------------------------- NONE On Column LOD for nt14.i, ABNSTDICAL.m, PSDDAICAL.sub = 0.0000

Page 1192 of 2729

Quant Ion Manual Peak Adjustment Report

Datafile: //Target/share/chem3/nt14.i/20161209.b/SIM.b/N1416120913.DInjection Date: 09-DEC-2016 22:23Lab ID:16K0314-05 Client ID: Report Date: 12/13/2016 11:45

Page 1193 of 2729

Form I


DMMU-2

EPA 8270D



Laboratory:

Client:

Matrix:

Sampled:

Solids:




SDG: 16K0314




BEK0736 SEL0144 ZK00072

16.08 g / 1 mL



108-95-2 Phenol 24.31 8.0 19.5



100-51-6 Benzyl Alcohol 19.51 U 14.5 19.5

95-48-7 2-Methylphenol 19.51 U 7.6 19.5

106-44-5 4-Methylphenol 19.51 U 14.3 19.5



91-20-3 Naphthalene 9.41 J 5.1 19.5

65-85-0 Benzoic acid 1951 U 57.6 195


91-57-6 2-Methylnaphthalene 14.31 J 5.5 19.5

208-96-8 Acenaphthylene 19.51 U 4.6 19.5


83-32-9 Acenaphthene 19.51 U 5.0 19.5

132-64-9 Dibenzofuran 19.51 U 4.5 19.5

86-73-7 Fluorene 6.31 J 4.8 19.5





85-01-8 Phenanthrene 38.51 4.6 19.5

120-12-7 Anthracene 15.41 J 5.8 19.5


206-44-0 Fluoranthene 56.71 4.4 19.5

129-00-0 Pyrene 53.21 5.4 19.5


56-55-3 Benzo(a)anthracene 25.81 5.0 19.5

218-01-9 Chrysene 43.01 5.1 19.5

117-81-7 bis(2-Ethylhexyl)phthalate 48.71 U 28.0 48.7


Benzofluoranthenes, Total 66.31 9.9 39.0

50-32-8 Benzo(a)pyrene 24.61 6.3 19.5

193-39-5 Indeno(1,2,3-cd)pyrene 15.91 J 5.8 19.5

53-70-3 Dibenzo(a,h)anthracene 19.51 U 6.0 19.5

191-24-2 Benzo(g,h,i)perylene 19.11 J 5.7 19.5

Page 1194 of 2729

Form I


DMMU-2

EPA 8270D



Laboratory:

Client:

Matrix:

Sampled:

Solids:




SDG: 16K0314




BEK0736 SEL0144 ZK00072

16.08 g / 1 mL



2-Fluorophenol 730.38 68.4499 27 - 120

Phenol-d5 730.38 68.0497 29 - 120

2-Chlorophenol-d4 730.38 70.8517 31 - 120


Nitrobenzene-d5 486.92 75.4367 30 - 120

2-Fluorobiphenyl 486.92 71.5348 35 - 120

2,4,6-Tribromophenol 730.38 85.2623 24 - 134

p-Terphenyl-d14 486.92 79.7388 37 - 120

Page 1195 of 2729

of 2729

Data File: \\Target\share\chem3\nt14.i\20161209.b\N1416120914.D Page 1 Report Date: 13-Dec-2016 12:19 ARI Labs, Inc. Semivolatile Report SW846 Method 8270DData file : \\Target\share\chem3\nt14.i\20161209.b\N1416120914.DLab Smp Id: 16K0314-10 Inj Date : 09-DEC-2016 22:57 Operator : YZ Inst ID: nt14.iSmp Info : 16K0314-10Misc Info : Comment : 1ul InjectionMethod : \\Target\share\chem3\nt14.i\20161209.b\ABNSTDICAL.mMeth Date : 12-Dec-2016 09:26 yev Quant Type: ISTDCal Date : 25-NOV-2016 18:18 Cal File: N1416112509.DAls bottle: 13 Dil Factor: 1.00000 Integrator: HP RTE Compound Sublist: PSDDAICAL.subTarget Version: 4.14 Processing Host: ORGDATA03



========================== ==== ==== ======== ======== ======== ======= ======= 1 N-Nitrosodimethylamine 74 Compound Not Detected. 2 Pyridine 79 Compound Not Detected.

$ 3 2-Fluorophenol 112 6.443 6.412 (0.751) 431706 5.12763 5.128

$ 4 Phenol-d5 99 7.981 7.973 (0.930) 573722 5.10128 5.101 5 Phenol 94 8.004 7.996 (0.932) 29797 0.24989 0.2499 6 Aniline 93 Compound Not Detected. 7 Bis(2-Chloroethyl)ether 93 Compound Not Detected.

$ 8 2-Chlorophenol-d4 132 8.228 8.228 (0.959) 474768 5.30863 5.309 9 2-Chlorophenol 128 Compound Not Detected. 10 1,3-Dichlorobenzene 146 Compound Not Detected.

* 11 1,4-Dichlorobenzene-d4 152 8.584 8.584 (1.000) 261017 4.00000 12 1,4-Dichlorobenzene 146 Compound Not Detected. 13 Benzyl alcohol 108 Compound Not Detected.

$ 14 1,2-Dichlorobenzene-d4 152 8.933 8.933 (1.041) 212988 3.46113 3.461 15 1,2-Dichlorobenzene 146 Compound Not Detected. 16 2-Methylphenol 108 Compound Not Detected. 17 2,2'-oxybis(1-Chloropropane) 121 Compound Not Detected. 18 4-Methylphenol 108 Compound Not Detected. 19 N-Nitroso-di-n-propylamine 70 Compound Not Detected. 20 Hexachloroethane 117 Compound Not Detected.

$ 21 Nitrobenzene-d5 82 9.655 9.655 (0.876) 387649 3.77185 3.772 22 Nitrobenzene 77 9.841 9.694 (0.893) 4529 0.04355 0.04355 23 Isophorone 82 10.134 10.135 (0.920) 2360 0.01270 0.01270 24 2-Nitrophenol 139 Compound Not Detected. 25 2,4-Dimethylphenol 107 10.404 10.381 (0.944) 984 0.01030 0.01030 26 Benzoic acid 105 10.597 10.589 (0.962) 2939 0.04886 0.04886 27 Bis(2-Chloroethoxy)methane 93 10.581 10.582 (0.960) 220 0.00209 0.002088 28 2,4-Dichlorophenol 162 Compound Not Detected. 29 1,2,4-Trichlorobenzene 180 Compound Not Detected.

* 30 Naphthalene-d8 136 11.021 11.021 (1.000) 1012597 4.00000 31 Naphthalene 128 11.060 11.060 (1.004) 23654 0.09631 0.09631 32 4-Chloroaniline 127 11.229 11.199 (1.019) 956 0.00901 0.009010 33 Hexachlorobutadiene 225 Compound Not Detected.

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========================== ==== ==== ======== ======== ======== ======= ======= 34 4-Chloro-3-methylphenol 107 12.150 12.158 (1.102) 226 0.00281 0.002815 35 2-Methylnaphthalene 142 12.436 12.437 (1.128) 28159 0.14718 0.1472 36 1-methylnaphthalene 142 12.653 12.653 (1.148) 22059 0.10852 0.1085 37 Hexachlorocyclopentadiene 237 Compound Not Detected. 38 2,4,6-Trichlorophenol 196 Compound Not Detected. 39 2,4,5-Trichlorophenol 196 Compound Not Detected.

$ 40 2-Fluorobiphenyl 172 13.218 13.218 (0.907) 670627 3.57619 3.576 41 2-Chloronaphthalene 162 13.419 13.412 (0.920) 315 0.00205 0.002049 42 2-Nitroaniline 65 13.698 13.675 (0.939) 796 0.01352 0.01352 43 Retene 219 Compound Not Detected. 44 Dimethylphthalate 163 14.031 14.124 (0.962) 1286 0.00724 0.007237 45 2,6-Dinitrotoluene 165 Compound Not Detected. 46 Acenaphthylene 152 14.263 14.263 (0.978) 10477 0.04305 0.04305 47 3-Nitroaniline 138 14.510 14.518 (0.995) 384 0.01936 0.01936

* 48 Acenaphthene-d10 164 14.580 14.580 (1.000) 501926 4.00000 49 Acenaphthene 153 14.642 14.642 (1.004) 4467 0.02968 0.02968 50 2,4-Dinitrophenol 184 15.028 14.727 (1.031) 170 0.00698 0.006978 51 4-Nitrophenol 109 15.121 14.851 (1.037) 35562 1.14806 1.148 52 Dibenzofuran 168 14.967 14.967 (1.027) 10854 0.04347 0.04347 53 2,4-Dinitrotoluene 165 15.059 15.044 (1.033) 641 0.01255 0.01255 54 2,3,4,6-Tetrachlorophenol 232 Compound Not Detected. 55 Diethylphthalate 149 15.562 15.562 (1.067) 21030 0.11495 0.1149 56 Fluorene 166 15.662 15.663 (1.074) 11354 0.06515 0.06515 57 4-Chlorophenyl-phenylether 204 15.616 15.670 (1.071) 190 0.00230 0.002303 58 4-Nitroaniline 138 15.748 15.771 (1.080) 3367 0.08148 0.08148 59 4,6-Dinitro-2-methylphenol 198 15.863 15.863 (0.903) 296 0.00714 0.007138 60 N-Nitrosodiphenylamine 169 15.917 15.925 (0.906) 1469 0.00915 0.009151 61 Azobenzene (1,2-DP-Hydrazine) 77 16.033 15.987 (1.100) 1447 0.00540 0.005403

$ 62 2,4,6-Tribromophenol 330 16.195 16.195 (1.111) 169783 6.39247 6.392 63 4-Bromophenyl-phenylether 248 16.627 16.658 (0.947) 92 0.00151 0.001508 64 Hexachlorobenzene 284 Compound Not Detected. 65 Pentachlorophenol 266 17.323 17.307 (0.986) 157 0.00534 0.005336

* 66 Phenanthrene-d10 188 17.563 17.563 (1.000) 942466 4.00000 67 Phenanthrene 178 17.609 17.609 (1.003) 94735 0.39573 0.3957 68 Anthracene 178 17.702 17.702 (1.008) 37623 0.15835 0.1584 69 Carbazole 167 18.035 18.035 (1.027) 8520 0.08677 0.08677 70 Di-n-butylphthalate 149 18.886 18.886 (1.075) 4499 0.01557 0.01557 71 Fluoranthene 202 20.000 20.000 (0.884) 147868 0.58204 0.5820 72 Benzidine 184 20.247 20.263 (0.895) 215 0.01140 0.01140 73 Pyrene 202 20.425 20.418 (0.903) 143887 0.54654 0.5465

$ 74 Terphenyl-d14 244 20.743 20.743 (0.917) 700196 3.98584 3.986 75 Butylbenzylphthalate 149 21.672 21.687 (0.958) 514 0.00439 0.004393 76 3,3'-Dichlorobenzidine 252 22.562 22.562 (0.998) 557 0.00968 0.009682 77 Benzo(a)anthracene 228 22.585 22.586 (0.999) 63585 0.26492 0.2649

* 78 Chrysene-d12 240 22.616 22.616 (1.000) 867694 4.00000 79 Chrysene 228 22.655 22.655 (1.002) 94569 0.44161 0.4416 80 bis(2-Ethylhexyl)phthalate 149 22.732 22.725 (0.959) 32649 0.16938 0.1694

* 81 Di-n-octylphthalate-d4 153 23.700 23.700 (1.000) 1499523 4.00000 82 Di-n-octylphthalate 149 23.708 23.708 (1.000) 6921 0.01911 0.01911 83 Benzo(b)fluoranthene 252 24.343 24.343 (0.974) 78814 0.35189 0.3519 85 Benzo(k)fluoranthene 252 24.343 24.382 (0.974) 78814 0.33686 0.3369 84 Total Benzofluoranthenes 252 24.343 24.382 (0.974) 148588 0.68044 0.6804 86 Benzo(a)pyrene 252 24.892 24.893 (0.996) 51320 0.25312 0.2531

* 87 Perylene-d12 264 24.985 24.993 (1.000) 794579 4.00000

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========================== ==== ==== ======== ======== ======== ======= ======= 88 Perylene 252 25.032 25.032 (1.002) 49190 0.18782 0.1878 89 Indeno(1,2,3-cd)pyrene 276 27.178 27.178 (1.088) 36777 0.16287 0.1629 90 Dibenzo(a,h)anthracene 278 27.194 27.194 (1.088) 8539 0.04561 0.04561 91 Benzo(g,h,i)perylene 276 27.807 27.815 (1.113) 37575 0.19619 0.1962

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Data File: \\Target\share\chem3\nt14.i\20161209.b\N1416120914.D Page 1 Report Date: 13-Dec-2016 12:19 ARI Labs, Inc. INTERNAL STANDARD COMPOUNDS AREA AND RT SUMMARY Instrument ID: nt14.i Calibration Date: 09-DEC-2016 Lab File ID: N1416120914.D Calibration Time: 16:39Lab Smp Id: 16K0314-10 Analysis Type: SV Level: Quant Type: ISTD Sample Type: Operator: YZMethod File: \\Target\share\chem3\nt14.i\20161209.b\ABNSTDICAL.mMisc Info: Test Mode: Use Initial Calibration Level 5. _________________________________________________________________________| | | AREA LIMIT | | || COMPOUND | STANDARD | LOWER | UPPER | SAMPLE | %DIFF ||=====================|==========|==========|==========|==========|=======|| 11 1,4-Dichlorobenze| 262244| 131122| 524488| 261017| -0.47|| 30 Naphthalene-d8 | 1028555| 514278| 2057110| 1012597| -1.55|| 48 Acenaphthene-d10 | 505255| 252628| 1010510| 501926| -0.66|| 66 Phenanthrene-d10 | 898548| 449274| 1797096| 942466| 4.89|| 78 Chrysene-d12 | 831926| 415963| 1663852| 867694| 4.30|| 81 Di-n-octylphthala| 1349307| 674654| 2698614| 1499523| 11.13|| 87 Perylene-d12 | 731711| 365856| 1463422| 794579| 8.59||_____________________|__________|__________|__________|__________|_______| _________________________________________________________________________| | | RT LIMIT | | || COMPOUND | STANDARD | LOWER | UPPER | SAMPLE | %DIFF ||=====================|==========|==========|==========|==========|=======|| 11 1,4-Dichlorobenze| 8.58| 8.08| 9.08| 8.58| -0.00|| 30 Naphthalene-d8 | 11.02| 10.52| 11.52| 11.02| -0.00|| 48 Acenaphthene-d10 | 14.58| 14.08| 15.08| 14.58| -0.00|| 66 Phenanthrene-d10 | 17.56| 17.06| 18.06| 17.56| -0.00|| 78 Chrysene-d12 | 22.62| 22.12| 23.12| 22.62| -0.00|| 81 Di-n-octylphthala| 23.70| 23.20| 24.20| 23.70| -0.00|| 87 Perylene-d12 | 24.99| 24.49| 25.49| 24.99| -0.03||_____________________|__________|__________|__________|__________|_______| AREA UPPER LIMIT = +100% of internal standard area.AREA LOWER LIMIT = - 50% of internal standard area.RT UPPER LIMIT = + 0.50 minutes of internal standard RT.RT LOWER LIMIT = - 0.50 minutes of internal standard RT.

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REVIEW SUMMARY FOR FILE - N1416120914.D Lab ID: 16K0314-10 nt14.i, ABNSTDICAL.m, 09-DEC-2016 22:57

RT CO-ELUTION COMPOUNDS --------------------------------------------------------------------------- 24.343 Benzo(k)fluoranthene and Benzo(b)fluoranthene Quant Method: ICAL RRT CHECK RRT CCV RRT DELTA COMPOUND ------------------------------------- NONE On Column LOD for nt14.i, ABNSTDICAL.m, PSDDAICAL.sub = 0.0000

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Form I


DMMU-3

EPA 8270D



Laboratory:

Client:

Matrix:

Sampled:

Solids:




SDG: 16K0314




BEK0736 SEL0144 ZK00072

22.18 g / 1 mL



108-95-2 Phenol 27.81 8.1 19.7



100-51-6 Benzyl Alcohol 19.71 U 14.7 19.7

95-48-7 2-Methylphenol 19.71 U 7.7 19.7

106-44-5 4-Methylphenol 19.71 U 14.5 19.7



91-20-3 Naphthalene 17.61 J 5.2 19.7

65-85-0 Benzoic acid 1971 U 58.3 197


91-57-6 2-Methylnaphthalene 24.01 5.6 19.7

208-96-8 Acenaphthylene 11.21 J 4.7 19.7


83-32-9 Acenaphthene 11.11 J 5.1 19.7

132-64-9 Dibenzofuran 10.01 J 4.5 19.7

86-73-7 Fluorene 16.41 J 4.9 19.7





85-01-8 Phenanthrene 1171 4.6 19.7

120-12-7 Anthracene 57.91 5.8 19.7


206-44-0 Fluoranthene 2331 4.5 19.7

129-00-0 Pyrene 2021 5.5 19.7


56-55-3 Benzo(a)anthracene 90.11 5.1 19.7

218-01-9 Chrysene 1521 5.1 19.7

117-81-7 bis(2-Ethylhexyl)phthalate 74.41 28.4 49.3


Benzofluoranthenes, Total 2131 10.1 39.4

50-32-8 Benzo(a)pyrene 84.91 6.4 19.7

193-39-5 Indeno(1,2,3-cd)pyrene 50.21 5.9 19.7

53-70-3 Dibenzo(a,h)anthracene 18.51 J 6.1 19.7

191-24-2 Benzo(g,h,i)perylene 60.31 5.7 19.7

Page 1253 of 2729

Form I


DMMU-3

EPA 8270D



Laboratory:

Client:

Matrix:

Sampled:

Solids:




SDG: 16K0314




BEK0736 SEL0144 ZK00072

22.18 g / 1 mL



2-Fluorophenol 739.59 70.9524 27 - 120

Phenol-d5 739.59 71.4528 29 - 120

2-Chlorophenol-d4 739.59 72.6537 31 - 120


Nitrobenzene-d5 493.06 76.8379 30 - 120

2-Fluorobiphenyl 493.06 75.1370 35 - 120

2,4,6-Tribromophenol 739.59 91.6678 24 - 134

p-Terphenyl-d14 493.06 81.8403 37 - 120

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