Oxygen and Hot Work

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    Paul McCluskie May 2007

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    OXYGEN ENRICHED CLOTHING FIRE FINNART 21st MARCH 2007

    IP was burning 8 guidepole from inside Tank 715

    The oxygen hose was found to be punctured next to the torch connection.

    Oxygen leaked from this hole and filtered inwardly through IPs clothing.

    Sparks ignited the oxygen enriched clothing beneath the overalls.

    IP suffered burn injury to groin area & required a skin graft.

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    What is OXYGEN ENRICHMENT?

    The air we breathe is composed of a number of elements:

    Nitrogen 77.2%

    Oxygen 20.9%

    Argon 0.9%

    Water Vapour 0.9%

    Carbon Dioxide 0.03%

    Other Gases 0.07%

    Oxygen levels are potentially dangerous at just

    23%

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    OXYGEN ENRICHMENT

    what happens?Oxygen Enrichment gives no warning tasteless, odourless, colourless

    It can bring on a feeling of euphoria

    You will neither know, nor care, that you are in danger

    Clothing & hair can easily catch fire

    Textiles can burn fiercely

    6%

    Death within

    seconds

    Loss of

    consciousness

    10%

    16%

    Judgement

    & breathing

    impaired

    Normal level in air

    21%

    23%

    Sparks will

    burst into

    flame

    Oil & Grease

    will ignite

    40%

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    OXYGEN ENRICHMENT

    what happens?This photograph

    shows a normal cotton

    work shirt, stuffed with

    paper and saturated

    with oxygen.

    Inside the shirt is a

    flash bulb with the glass

    removed.

    The bulb is connected

    to a battery to provide

    ignition.

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    OXYGEN ENRICHMENT

    what happens?THE RESULTS OF THE IGNITION ARE CATASTROPHIC

    We must ensure ouremployees know the

    dangers of oxygen

    enrichment.

    Pressurised oxygen is

    not for blowing dust or

    cleaning clothing.

    Oxygen can saturate

    the material making it 8

    times more flammable.

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    OXYGEN RELATED INCIDENTS

    Industry Stats

    In the period 1996 2002, 168 incidents were associatedwith the use or handling of oxygen.

    Including :

    5 fatalities

    26 major injuries

    61 minor injuries

    Almost 50% of all incidents were related toHOT WORK

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    OXYGEN RELATED INCIDENTS

    Industry StatsSummary of incidents:Year 1996 1997 1998 1999 2000 2001 2002

    Activity Total

    Hot Work 19 12 6 11 10 15 10 83 1 FATAL9 MAJOR

    48 MINOR

    Cylinder filling 4 5 1 2 1 2 3 18 1 FATAL5 MAJOR

    2 MINOR

    Breathing /

    respiratory

    5 2 4 2 5 7 10 35 2 FATAL2 MAJOR

    4 MINOR

    Substitution 1 1 2 2 1 4 4 15 10 MAJOR4 MINOR

    Liquid Oxygen

    (LOX)

    0 2 1 0 0 0 2 5 0 INJURIES

    Miscellaneous 1 3 4 3 0 0 1 12 1 FATAL0 MAJOR

    3 MINOR

    Total 30 25 18 20 17 28 30 168 5 FATAL26 MAJOR

    61 MINOR

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    OXYGEN ENRICHMENT

    PPEIT IS IMPOSSIBLE TO AVOID DANGER

    FROM AN OXYGEN FIRE SOLELY BYPROTECTIVE CLOTHING

    BASIC PPE REQUIREMENTS

    Safety Boots

    Burning goggles

    Leather Gloves/Gauntlets3M mask (P3)

    FR Overalls

    Full-face visor

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    OXYGEN ENRICHMENT

    PPEIT IS IMPOSSIBLE TO AVOID DANGER

    FROM AN OXYGEN FIRE SOLELY BYPROTECTIVE CLOTHING

    ADDITIONAL PPE

    Proban Hood

    Leather Sleeves

    Leather SpatsLeather Apron

    Leather Jacket

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    Clothing should be :

    well fi ttingeasy to remove

    free from oil and grease

    OXYGEN ENRICHMENT

    Clothing considerations

    Synthetic materials

    Can be fire-resistant to an

    extent

    Can melt

    Can cause serious burns dueto adhesion to the skin.

    Wool

    Considered best

    Quickly extinguishes when

    brought into normal air

    Remember :

    IT IS IMPOSSIBLE TO AVOID DANGERFROM AN OXYGEN FIRE SOLELY BY

    PROTECTIVE CLOTHING

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    OXYGEN ENRICHMENT

    Reduce the riskOpen the valve slowly -

    rapid opening can result inhigh oxygen velocities and

    can result in fire

    Carry out leak tests

    using a spray or liquid

    solution.Check oxygen levels in

    confined spaces and

    continue to monitor.

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    OXYGEN ENRICHMENT

    Reduce the riskEnsure employees are

    trained in set-up & use ofoxy-acetylene equipment.

    Ensure employees are

    aware of the dangers.

    Carry out & record pre-

    job checklists.

    Do not misuse the

    equipment.

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    DONTS

    Do not smoke where oxygen is

    being used

    Never use replacement parts

    which have not been approved for

    oxygen service.

    Never exceed pressures certified

    by the manufacturer.

    Never use oil or grease to lubricateoxygen equipment.

    Never use oxygen in equipment

    that is not designed for oxygenservice.

    OXYGEN ENRICHMENT

    ChecklistDOS

    Be aware of the dangers ofoxygen

    Ensure equipment is leak tight.

    Ensure adequate ventilation.

    Use oxygen cylinders &

    equipment carefully & correctly.

    Always open oxygen cylinder

    valves slowly.

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    References & Standards

    References

    INDG297 Safety in Gas welding, cutting & similar processes

    HSE8 (rev2)Take care with Oxygen : fire & explosion hazards in the use of oxygen

    Standards

    Pressure regulators must comply with BS EN ISO 2503

    Oxygen hoses should comply with BS EN 559 or BS EN 739

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