Organic Chemistry Reactions - nygh.sg · Organic Chemistry Reactions of the Alkenes –Combustion...
Transcript of Organic Chemistry Reactions - nygh.sg · Organic Chemistry Reactions of the Alkenes –Combustion...
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Organic
Chemistry
Reactions
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What are the
essential reactions
of organic
compounds?
Organic Chemistry
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What are the
essential
reactions of
the alkanes?
Combustion
Substitution
Cracking
Organic Chemistry
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H C
H
H
H O C O+ +O O
O O
H HO
H HO
Methane Oxygen CarbonDioxide
Water
The complete combustion of an alkane produces carbon
dioxide and water. The reaction is very important because it is
highly exothermic.
CH4(g) + 2O2(g) CO2(g) + 2H2O(l)
Organic ChemistryReactions of the Alkanes – Combustion
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Write the balanced
chemical equation to
describe the complete
combustion of ethane.
Organic ChemistryReactions of the Alkanes – Combustion
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++
O O
O O
O O
O O
O O
O O
O O
H HO
H HO
H HO
H HO
H HO
H HO
O C O
O C O
O C O
O C O
H C
H
H
C
H
H
H
H C
H
H
C
H
H
H
Ethane Oxygen CarbonDioxide
Water
2C2H6(g) + 7O2(g) 4CO2(g) + 6H2O(l)
Organic ChemistryReactions of the Alkanes – Combustion
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Organic ChemistryReactions of the Alkanes – Combustion
Which chemical, X, can be used to detect the presence of water? What
change would you observe in X if water were present?
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Organic ChemistryReactions of the Alkanes – Combustion
Which chemical, X, can be used to detect the presence of water? What
change would you observe in X if water were present?
Anhydrous copper(II) sulfate can be used to test for water.
The white anhydrous copper(II) sulfate will change into blue hydrated
copper(II) sulfate upon the addition of water.
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Organic ChemistryReactions of the Alkanes – Combustion
Which chemical, Y, can be used to detect the presence of carbon dioxide?
What change would you observe in Y if carbon dioxide were present?
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Organic ChemistryReactions of the Alkanes – Combustion
Which chemical, Y, can be used to detect the presence of carbon dioxide?
What change would you observe in Y if carbon dioxide were present?
Limewater (an aqueous solution of calcium hydroxide) can be used to test
for carbon dioxide. A white precipitate will be formed when carbon dioxide is
bubbled through limewater.
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H C
H
H
H Cl Cl H ClH C
H
H
Cl+ +
Methane Chloromethane
UltravioletLight
The hydrogen of an alkane can be substituted by a Group VII
element in the presence of ultraviolet light. The reaction
produces a complex mixture of products.
Organic ChemistryReactions of the Alkanes – Substitution
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The hydrogen of an alkane can be substituted by a Group VII
element in the presence of ultraviolet light. The reaction
produces a complex mixture of products.
Organic ChemistryReactions of the Alkanes – Substitution
++ Cl ClH C
H
H
Cl H C
H
Cl
Cl H Cl
DichloromethaneChloromethane
UltravioletLight
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The hydrogen of an alkane can be substituted by a Group VII
element in the presence of ultraviolet light. The reaction
produces a complex mixture of products.
Organic ChemistryReactions of the Alkanes – Substitution
H C
H
Cl
Cl Cl Cl H Cl+ +
H
CCl
Cl
Cl
TrichloromethaneDichloromethane
UltravioletLight
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The hydrogen of an alkane can be substituted by a Group VII
element in the presence of ultraviolet light. The reaction
produces a complex mixture of products.
Organic ChemistryReactions of the Alkanes – Substitution
++ H ClCl ClCl C
H
Cl
Cl
Cl
CCl
Cl
Cl
TetrachloromethaneTrichloromethane
UltravioletLight
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UltravioletLight
Ethane
+ 6 Cl ClPossibleReactionProducts?
H C
H
H
C
H
H
H
Organic ChemistryReactions of the Alkanes – Substitution
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Cl C
Cl
H
C
Cl
H
Cl
1,1,2,2-Tetrachloroethane
Cl C
H
H
C
H
H
H
1-Chloroethane(or just Chloroethane)
Cl C
Cl
H
C
H
H
H
1,1-Dichloroethane
Cl C
H
H
C
H
H
Cl
1,2-Dichloroethane
Cl C
Cl
H
C
H
H
Cl
1,1,2-Trichloroethane
Cl C
Cl
Cl
C
H
H
H
1,1,1-Trichloroethane
Cl C
Cl
Cl
C
H
H
Cl
1,1,1,2-Tetrachloroethane
Cl C
Cl
Cl
C
Cl
H
Cl
1,1,1,2,2-Pentachloroethane (or just Pentachloroethane)
Cl C
Cl
Cl
C
Cl
Cl
Cl
1,1,1,2,2,2-Hexachloroethane (or just Hexachloroethane)
UltravioletLight
Ethane
+ 6 Cl ClPossibleReactionProducts?
H C
H
H
C
H
H
H
Organic ChemistryReactions of the Alkanes – Substitution
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Octane Hexane Ethene
H C
H
H
C
H
C
H
C
H
C
H
C
H
C
H
C
H
H
H H H H H H H
H C
H
H
C
H
H
C
H
H
C
H
H
C
H
H
C
H
H
H C C
H
H H
H
+
HighTemperature /
Catalyst
The catalytic cracking of long-chain alkanes produces short-
chain alkanes and alkenes as reaction products. Short-chain
alkanes tend to be more useful than long-chain alkanes, and
alkenes can be used in organic synthesis.
Organic ChemistryReactions of the Alkanes – Cracking
Al2O3
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HighTemperature /
Catalyst
Octane Pentane
H C
H
H
C
H
C
H
C
H
C
H
C
H
C
H
C
H
H
H H H H H H H
H C
H
H
C
H
H
C
H
H
C
H
H
C
H
H
H + ?
Organic ChemistryReactions of the Alkanes – Cracking
Al2O3
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Octane Pentane Propene
H C
H
H
C
H
C
H
C
H
C
H
C
H
C
H
C
H
H
H H H H H H H
H C
H
H
C
H
H
C
H
H
C
H
H
C
H
H
H + C C
H
H
H
C
H
H
H
HighTemperature /
Catalyst
HighTemperature /
Catalyst
Octane Butane
H C
H
H
C
H
C
H
C
H
C
H
C
H
C
H
C
H
H
H H H H H H H
H C
H
H
C
H
H
C
H
H
C
H
H
H + ?
Organic ChemistryReactions of the Alkanes – Cracking
Al2O3
Al2O3
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Octane Pentane Propene
H C
H
H
C
H
C
H
C
H
C
H
C
H
C
H
C
H
H
H H H H H H H
H C
H
H
C
H
H
C
H
H
C
H
H
C
H
H
H + C C
H
H
H
C
H
H
H
HighTemperature /
Catalyst
Octane Butane But-1-ene
H C
H
H
C
H
C
H
C
H
C
H
C
H
C
H
C
H
H
H H H H H H H
H C
H
H
C
H
H
C
H
H
C
H
H
H + C C
H
H
H
C
H
H
C
H
H
H
HighTemperature /
Catalyst
Organic ChemistryReactions of the Alkanes – Cracking
Al2O3
Al2O3
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What are the
essential reactions
of the
halogenoalkanes?
Substitution
Organic Chemistry
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H C
H
H
C
H
H
Br H C
H
H
C
H
H
O
H
++ NaOH NaBrWarm
Bromoethane AqueousSodium
Hydroxide
Ethanol AqueousSodiumBromide
Warming a halogenoalkane with an aqueous solution of sodium hydroxide
forms an alcohol as the main reaction product. This is an example of a
substitution reaction.
H C
H
H
C
Br
H
C
H
H
HH C
H
H
C
O
H
C
H
H
H
H
+ +NaOH NaBrWarm
AqueousSodiumBromide
AqueousSodium
Hydroxide
2-Bromopropane Propan-1-ol
?
Organic ChemistryReactions of the Halogenoalkanes – Substitution
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H C
H
H
C
H
H
Br H C
H
H
C
H
H
O
H
++ NaOH NaBrWarm
Bromoethane AqueousSodium
Hydroxide
Ethanol AqueousSodiumBromide
H C
H
H
C
Br
H
C
H
H
HH C
H
H
C
O
H
C
H
H
H
H
+ +NaOH NaBrWarm
AqueousSodiumBromide
AqueousSodium
Hydroxide
2-Bromopropane Propan-2-ol
Organic Chemistry
Warming a halogenoalkane with an aqueous solution of sodium hydroxide
forms an alcohol as the main reaction product. This is an example of a
substitution reaction.
Reactions of the Halogenoalkanes – Substitution
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What are the
essential
reactions of
the alkenes?
Combustion
Organic Chemistry
Addition
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Organic ChemistryReactions of the Alkenes – Combustion
Alkenes tend to undergo incomplete combustion,
producing luminous (orange / yellow) sooty flames.
Luminous, sooty flames are evidence that the organic
compound undergoing combustion is unsaturated.
Unsaturated organic compounds undergo incomplete
combustion because they contain a relatively high
percentage carbon. Compare saturated with unsaturated:
Percentage carbon in butane CH3CH2CH2CH3:
[(4 12) ((4 12) + 10)] 100 = 82.8%
Percentage carbon in buta-1,3-diene CH2=CHCH=CH2:
[(4 12) ((4 12) + 6)] 100 = 88.9%
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Organic ChemistryReactions of the Alkenes – Addition
H C
X
H
C
Y
H
H
saturatedproduct
C=C double
bond breaks
open
Addition of
reactant to
the alkene
X Y
+
CH
H
C
H
H
X Y
+
H
C
H
C
H
H
unsaturatedalkene
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Ni CatalystHigh
PressureH
H
C C
H
H
H H+ H C
H
H
C
H
H
H
Ethene EthaneHydrogen
Alkenes (unsaturated hydrocarbons) react with hydrogen in the presence
of a nickel catalyst to form an alkane. This is an example of an addition
reaction.
?Ni Catalyst
HighPressure
Propene Hydrogen
H
C
H
C
H
C
H
H
H H H+
Organic ChemistryReactions of the Alkenes – Addition
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Ni CatalystHigh
PressureH
H
C C
H
H
H H+ H C
H
H
C
H
H
H
Ethene EthaneHydrogen
PropanePropene Hydrogen
H
C
H
C
H
C
H
H
H H H+ H C
H
H
C
H
H
C
H
H
H
Ni CatalystHigh
Pressure
Organic ChemistryReactions of the Alkenes – Addition
Alkenes (unsaturated hydrocarbons) react with hydrogen in the presence
of a nickel catalyst to form an alkane. This is an example of an addition
reaction.
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Alkenes (unsaturated hydrocarbons) react with Group VII elements at room
temperature and pressure to form a halogenoalkane. This is an addition
reaction.
RoomTemperatureand Pressure
Propene Bromine
H
C
H
C
H
C
H
H
H Br Br+ ?
RoomTemperatureand Pressure
1,2-Dibromoethane Ethene Bromine
Br Br
H
H
C C
H
H
+ H C
Br
H
C
Br
H
H
Organic ChemistryReactions of the Alkenes – Addition
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1,2-Dibromopropane Propene Bromine
H
C
H
C
H
C
H
H
H Br Br+ H C
Br
H
C
Br
H
C
H
H
H
RoomTemperatureand Pressure
RoomTemperatureand Pressure
1,2-Dibromoethane Ethene Bromine
Br Br
H
H
C C
H
H
+ H C
Br
H
C
Br
H
H
Organic ChemistryReactions of the Alkenes – Addition
Alkenes (unsaturated hydrocarbons) react with Group VII elements at room
temperature and pressure to form a halogenoalkane. This is an addition
reaction.
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Organic ChemistryReactions of the Alkenes – Addition
IMPORTANT NOTE
Bromine adds across the C=C bond. Each of the two
bromine atoms bonds to a different carbon atom.
The two bromine atoms DO NOT bond to the same
carbon atom.
C C
H
H H
H
H C
Br
H
C
Br
H
HBr Br+
C C
H
H H
H
H C
Br
Br
C
H
H
HBr Br+
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Organic ChemistryReactions of the Alkenes – Addition
IMPORTANT NOTE
Bromine adds across the C=C bond. Each of the two
bromine atoms bonds to a different carbon atom.
The two bromine atoms DO NOT bond to the same
carbon atom.
C C
H
H H
H
H C
Br
H
C
Br
H
HBr Br+
C C
H
H H
H
H C
Br
Br
C
H
H
HBr Br+
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Organic ChemistryReactions of the Alkenes – Addition
+C
H
H
C
H
C
H
H
H Br Br H C
Br
H
C
Br
H
C
H
H
H
+C
H
H
C
H
C
H
H
H Br Br H C
Br
Br
C
H
H
C
H
H
H
+C
H
H
C
H
C
H
H
H Br Br H C
H
H
C
Br
Br
C
H
H
H
+C
H
H
C
H
C
H
H
H Br Br H C
Br
H
C
H
H
C
Br
H
H
C
H
H
C
H
C
H
H
H Br Br C
Br
H
C
H
C
H
H
H+ H Br+
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Organic ChemistryReactions of the Alkenes – Addition
+C
H
H
C
H
C
H
H
H Br Br H C
Br
H
C
Br
H
C
H
H
H
+C
H
H
C
H
C
H
H
H Br Br H C
Br
Br
C
H
H
C
H
H
H
+C
H
H
C
H
C
H
H
H Br Br H C
H
H
C
Br
Br
C
H
H
H
+C
H
H
C
H
C
H
H
H Br Br H C
Br
H
C
H
H
C
Br
H
H
C
H
H
C
H
C
H
H
H Br Br C
Br
H
C
H
C
H
H
H+ H Br+
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A molecule that contains more than one carbon-to-carbon double covalent
bond is said to be polyunsaturated. The catalytic hydrogenation of
polyunsaturated plant oils to produce solid fats is used in the manufacture
of margarine.
Organic ChemistryReactions of the Alkenes – Addition
H C
H
H
C
H
H
C C C
H
H
C C C
H
H
C C C
H
H
C
H
H
C
H
H
C
O H
O
H H H H H H
H H H H H H
H C
H
H
C
H
H
C C C
H
H
C C C
H
H
C C C
H
H
C
H
H
C
H
H
C
O H
O
H H H H H H
H H H HH H
+ + +
Liquid
Solid
Nickel Catalyst
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A molecule that contains more than one carbon-to-carbon double covalent
bond is said to be polyunsaturated. The catalytic hydrogenation of
polyunsaturated plant oils to produce solid fats is used in the manufacture
of margarine.
Organic ChemistryReactions of the Alkenes – Addition
H C
H
H
C
H
H
C C C
H
H
C C C
H
H
C C C
H
H
C
H
H
C
H
H
C
O H
O
H H H H H H
H H H H H H
H C
H
H
C
H
H
C C C
H
H
C C C
H
H
C C C
H
H
C
H
H
C
H
H
C
O H
O
H H H H H H
H H H HH H
+ + +
Liquid
Solid
Nickel Catalyst
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Organic ChemistryReactions of the Alkenes – Addition
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The number of carbon-to-carbon double covalent bonds that are present in
a molecule can be determined by reacting it with bromine. In this example,
1 mol of the organic compound reacts with 3 mol of bromine, so one
molecule must contain three carbon-to-carbon double covalent bonds.
Organic ChemistryReactions of the Alkenes – Addition
H C
H
H
C
H
H
C C C
H
H
C C C
H
H
C C C
H
H
C
H
H
C
H
H
C
O H
O
H H H H H H
Br Br Br Br Br Br
H C
H
H
C
H
H
C C C
H
H
C C C
H
H
C C C
H
H
C
H
H
C
H
H
C
O H
O
H H H H H H
Br Br Br BrBr Br
+ + +
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The number of carbon-to-carbon double covalent bonds that are present in
a molecule can be determined by reacting it with bromine. In this example,
1 mol of the organic compound reacts with 3 mol of bromine, so one
molecule must contain three carbon-to-carbon double covalent bonds.
Organic ChemistryReactions of the Alkenes – Addition
H C
H
H
C
H
H
C C C
H
H
C C C
H
H
C C C
H
H
C
H
H
C
H
H
C
O H
O
H H H H H H
Br Br Br Br Br Br
H C
H
H
C
H
H
C C C
H
H
C C C
H
H
C C C
H
H
C
H
H
C
H
H
C
O H
O
H H H H H H
Br Br Br BrBr Br
+ + +
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The decolourisation of bromine water is an important
qualitative test for an alkene.
Organic ChemistryReactions of the Alkenes – Addition
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Organic ChemistryReactions of the Alkenes – Addition
The decolourisation of bromine water is an important
qualitative test for an alkene.
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Organic ChemistryReactions of the Alkenes – Addition
The decolourisation of bromine water is an important
qualitative test for an alkene.
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Organic ChemistryReactions of the Alkenes – Addition
The decolourisation of bromine water is an important
qualitative test for an alkene.
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Organic ChemistryReactions of the Alkenes – Addition
The decolourisation of bromine water is an important
qualitative test for an alkene.
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Organic ChemistryReactions of the Alkenes – Addition
Note: In addition to using bromine water, a solution of bromine dissolved in
an inert solvent, e.g. CCl4, may be used.
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RoomTemperatureand Pressure
1-Chloroethane Ethene HydrogenChloride
H Cl
H
H
C C
H
H
+ H C
H
H
C
Cl
H
H
Alkenes (unsaturated hydrocarbons) react with hydrogen halides at room
temperature and pressure to form a halogenoalkane. This is an addition
reaction.
?Room
Temperatureand Pressure
Propene HydrogenChloride
H
C
H
C
H
C
H
H
H H Cl+
Organic ChemistryReactions of the Alkenes – Addition
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RoomTemperatureand Pressure
1-Chloroethane Ethene HydrogenChloride
H Cl
H
H
C C
H
H
+ H C
H
H
C
Cl
H
H
Propene 2-Chloropropane 1-ChloropropaneHydrogenChloride
H
C
H
C
H
C
H
H
H H Cl+ H C
H
H
C
Cl
H
C
H
H
HH C
Cl
H
C
H
H
C
H
H
Hand /
or
RoomTemperatureand Pressure
Organic ChemistryReactions of the Alkenes – Addition
Alkenes (unsaturated hydrocarbons) react with hydrogen halides at room
temperature and pressure to form a halogenoalkane. This is an addition
reaction.
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EthanolEthene Water
H HO
H
H
C C
H
H
+ H C
H
H
C
H
H
O
H
Conc.H2SO4
as Catalyst
Alkenes (unsaturated hydrocarbons) react with water in the presence of an
acid catalyst to form an alcohol. This is an example of an addition reaction.
Propene
Conc.H2SO4
as Catalyst
Water
H
C
H
C
H
C
H
H
H H HO+ ?
Organic ChemistryReactions of the Alkenes – Addition
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EthanolEthene Water
H HO
H
H
C C
H
H
+ H C
H
H
C
H
H
O
H
Conc.H2SO4
as Catalyst
Propan-1-ol Propan-2-olPropene Water
H
C
H
C
H
C
H
H
H H HO
H C
H
H
C
O
H
C
H
H
H
H
O C
H
H
C
H
H
C
H
H
H
H
+and /
or
Conc.H2SO4
as Catalyst
Organic ChemistryReactions of the Alkenes – Addition
Alkenes (unsaturated hydrocarbons) react with water in the presence of an
acid catalyst to form an alcohol. This is an example of an addition reaction.
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Organic Chemistry
C C
H
H H
H
H C
Cl
H
C
Cl
H
HCl Cl+
Compare the Reactions of Alkanes and Alkenes with Halogens
Alkane and a halogen: Substitution reaction in the
presence of ultraviolet light.
Alkene and a halogen: Addition reaction at room
temperature and pressure (no U.V. light required).
H
CH
H
H Cl Cl
H
CH
H
Cl H Cl+ +
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Organic Chemistry Which one of the following is the best way of preparing
a sample of propan-2-ol?
a) Reacting propene with water in the presence of an
acid catalyst (addition reaction).
b) Reacting 2-bromopropane with aqueous sodium
hydroxide (substitution reaction).
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Organic Chemistry Which one of the following is the best way of preparing
a sample of propan-2-ol?
a) Reacting propene with water in the presence of an
acid catalyst (addition reaction).
b) Reacting 2-bromopropane with aqueous sodium
hydroxide (substitution reaction).
Propan-1-ol Propan-2-olPropene Water
H
C
H
C
H
C
H
H
H H HO
H C
H
H
C
O
H
C
H
H
H
H
O C
H
H
C
H
H
C
H
H
H
H
+and /
or
Conc.H2SO4
as Catalyst
Using propene will produce a mixture of two organic
reaction products (low yield of each isomer).
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Organic Chemistry
H C
H
H
C
Br
H
C
H
H
HH C
H
H
C
O
H
C
H
H
H
H
+ +NaOH NaBrWarm
AqueousSodiumBromide
AqueousSodium
Hydroxide
2-Bromopropane Propan-2-ol
Which one of the following is the best way of preparing
a sample of propan-2-ol?
a) Reacting propene with water in the presence of an
acid catalyst (addition reaction).
b) Reacting 2-bromopropane with aqueous sodium
hydroxide (substitution reaction).
Using 2-bromopropane is preferred because it will
produce only one organic reaction product (high yield).
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What are the
essential
reactions of the
alcohols?
Combustion
Oxidation
Organic Chemistry
Sodium
Dehydration
Preparation
Substitution
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Ethanol can be produced by the fermentation of glucose.
C6H12O6(aq) 2CH3CH2OH(aq) 2CO2(g)
Glucose Ethanol CarbonDioxide
Enzymesin Yeast
+
H
CH
H
C
H
H
O
H
H
CH
H
C
H
H
O
H
O C O
O C O
C O
C
CC
C
C
H
O
H
O
H
H
H H
OH
H
O
O
H
H
H
H
Organic ChemistryReactions of the Alcohols – Preparation
Temperature
37 C
Anaerobic
(no oxygen)
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Organic ChemistryReactions of the Alcohols – Preparation
Enzymes in the yeast increase the
rate of the reaction by lowering the
activation energy.
The optimum temperature is 37C.
At higher temperatures, the
enzymes in the yeast are denatured.
The air lock allows CO2 (g) to
escape while preventing O2 (g) from
entering the container. O2 (g) will
oxidise the ethanol to ethanoic acid
(vinegar).
Ethanol is obtained by distillation
of the reaction mixture.
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EthanolEthene Water
H HO
H
H
C C
H
H
+ H C
H
H
C
H
H
O
H
Conc.H2SO4
as Catalyst
Remember, ethanol can be prepared by reacting ethene with water in the
presence of concentrated sulfuric acid as a catalyst. This is an
addition reaction.
Organic ChemistryReactions of the Alcohols – Preparation
C2H4(g) + H2O(l) CH3CH2OH(l)
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Remember, ethanol can be prepared by warming bromoethane with
aqueous sodium hydroxide. This is a substitution reaction.
Organic ChemistryReactions of the Alcohols – Preparation
CH3CH2Br(l) + NaOH(aq) CH3CH2OH(l) + NaBr(aq)
H C
H
H
C
H
H
Br H C
H
H
C
H
H
O
H
++ NaOH NaBrWarm
Bromoethane AqueousSodium
Hydroxide
Ethanol AqueousSodiumBromide
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Organic ChemistryReactions of the Alcohols – Combustion
Alcohols undergo complete combustion to form
carbon dioxide and water as the reaction products.
This exothermic reaction releases energy that can
be used to power certain automobiles.
ethanol + oxygen carbon dioxide + water
C2H5OH + 3O2 2CO2 + 3H2O
propanol + oxygen carbon dioxide + water
2C3H7OH + 9O2 6CO2 + 8H2O
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Organic ChemistryReactions of the Alcohols – Substitution
The hydroxyl group, –OH, of an alcohol can be
substituted by a halogen, e.g. –Cl or –Br.
The reaction converts an alcohol into a
halogenoalkane.
A sodium halide is treated with concentrated
sulfuric acid to produce a hydrogen halide, e.g.
NaBr + H2SO4 HBr + NaHSO4
This mixture is then warmed with the alcohol:
CH3CH2OH + HBr CH3CH2Br + H2O
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Ethanol Ethene Water
C C
H
H H
HH
CH
H
C
H
H
O
H
+ HO
H
conc.H3PO4
Catalyst
The dehydration of an alcohol results in the formation of an alkene as the
main reaction product. This is an example of an elimination reaction.
?Propan-1-ol
conc.H3PO4
CatalystH C
H
H
C
H
H
C
H
H
O
H
Organic ChemistryReactions of the Alcohols – Dehydration
Sulfuric acid can also be used as a catalyst, and the
reaction mixture is warmed to approximately 170 C.
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Ethanol Ethene Water
C C
H
H H
HH
CH
H
C
H
H
O
H
+ HO
H
conc.H3PO4
Catalyst
Propan-1-ol Propene Water
H C
H
H
C
H
H
C
H
H
O
H
H C
H
H
C
H
C
H
H
+ H HO
conc.H3PO4
Catalyst
The dehydration of an alcohol results in the formation of an alkene as the
main reaction product. This is an example of an elimination reaction.
Organic ChemistryReactions of the Alcohols – Dehydration
Sulfuric acid can also be used as a catalyst, and the
reaction mixture is warmed to approximately 170 C.
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Ethanol Ethanoic AcidAcidified Dichromate(VI)
H C
H
H
C
H
H
O
H
H C
H
H
C
O H
O
2Cr2O72-
4Cr3+
3 + 16H+
+ 3 + + 11H2O
Alcohols can be oxidised to carboxylic acids using i) acidified potassium
dichromate(VI) or ii) acidified potassium manganate(VII). This is an
important reaction in organic synthesis.
Organic ChemistryReactions of the Alcohols – Oxidation
Ethanol Ethanoic AcidAcidified Manganate(VII)
H C
H
H
C
H
H
O
H
H C
H
H
C
O H
O
4MnO4-
4Mn2+
5 + 12H+
+ 5 + + 11H2O
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Ethanol Ethanoic AcidAcidified Dichromate(VI)
H C
H
H
C
H
H
O
H
H C
H
H
C
O H
O
2Cr2O72-
4Cr3+
3 + 16H+
+ 3 + + 11H2O
Alcohols can be oxidised to carboxylic acids using i) acidified potassium
dichromate(VI) or ii) acidified potassium manganate(VII). This is an
important reaction in organic synthesis.
Organic ChemistryReactions of the Alcohols – Oxidation
Ethanol Ethanoic AcidAcidified Manganate(VII)
H C
H
H
C
H
H
O
H
H C
H
H
C
O H
O
4MnO4-
4Mn2+
5 + 12H+
+ 5 + + 11H2O
Orange Green
Purple Colourless
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Organic ChemistryReactions of the Alcohols – Oxidation
Ethanol is the alcohol found
in alcoholic beverages such
as beer, wine and spirits.
If a glass of wine is left
exposed to the air, oxygen in
the air can oxidise the ethanol
to ethanoic acid, making the
wine taste like vinegar.
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Organic ChemistryReactions of the Alcohols – Sodium
2CH3CH2OH + 2Na 2Na+CH3CH2O– + H2
Ethanol reacts with sodium to form a salt and hydrogen.
ethanol + sodium sodium ethoxide + hydrogen
Compare: 2H2O + 2Na 2Na+ OH– + H2
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Organic ChemistryReactions of the Alcohols – Sodium
The density of sodium = 0.968 g cm–3
The density of water = 1.00 g cm–3
The density of ethanol = 0.789 g cm–3
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Organic ChemistryReactions of the Alcohols – Sodium
Consequence: Sodium floats on water,
but sinks in ethanol.
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What are the
essential
reactions of the
carboxylic acids?
Source of H+(aq)
Organic Chemistry
Esterification
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Organic ChemistryProperties of the Carboxylic Acids
Remember, carboxylic acids are weak acids.
This means that they only partially ionize when
dissolved in water to produce hydrogen ions (H+)
as the only positive ion.
The reactions of carboxylic acids tend to be
slower than the reactions of mineral acids of the
same concentration. Even though the acids are
the same concentration, the carboxylic acid
contains a lower concentration of hydrogen ions.
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Organic ChemistryReactions of the Carboxylic Acids
Carboxylic acids react with carbonates and hydrogen carbonates to form a
salt, water and carbon dioxide. This can be used as a qualitative test for a
carboxylic acid.
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Organic ChemistryReactions of the Carboxylic Acids
Acid + Carbonate Salt + Water + Carbon Dioxide
ethanoic acid + calcium carbonate calcium ethanoate + water + carbon dioxide
2CH3COOH(aq) + CaCO3(s) Ca(CH3COO)2(aq) + H2O(l) + CO2(g)
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Organic ChemistryReactions of the Carboxylic Acids
Acid + Metal Salt + Hydrogen
ethanoic acid + magnesium magnesium ethanoate + hydrogen
2CH3COOH(aq) + Mg(s) Mg(CH3COO)2(aq) + H2(g)
Acid + Alkali / Base Salt + Water
ethanoic acid + sodium hydroxide sodium ethanoate + water
CH3COOH(aq) + NaOH(aq) NaCH3COO(aq) + H2O(l)
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Ethanoic Acid Methanol Methyl Ethanoate Water
H C
H
H
C
O H
O
O C
H
H
H
HH
OH+
H
CH
H
C
O C
O
H
H
H+
Conc.H2SO4
Catalyst
Esters are have a sweet aroma and are used in the food and
perfume industry.
?EthanolPropanoic Acid
Conc.H2SO4
CatalystH C
H
H
C
H
H
C
O H
O
O C
H
H
C
H
H
H
H
+
Organic ChemistryReactions of the Carboxylic Acids – Esterification
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Ethanoic Acid Methanol Methyl Ethanoate Water
H C
H
H
C
O H
O
O C
H
H
H
HH
OH+
H
CH
H
C
O C
O
H
H
H+
Conc.H2SO4
Catalyst
Ethanol Ethyl PropanoatePropanoic Acid Water
H C
H
H
C
H
H
C
O H
O
O C
H
H
C
H
H
H
HH
OH+
H C
H
H
C
H
H
C
O C
O
H
H
C
H
H
H+
Conc.H2SO4
Catalyst
Esters are have a sweet aroma and are used in the food and
perfume industry.
Organic ChemistryReactions of the Carboxylic Acids – Esterification
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Organic ChemistryReactions of the Carboxylic Acids – Esterification
O H
H C
H
H
C
O
O C
H
H
C
H
H
H
HH H
O+ +
H
CH
H
C
O C
O
H
H
C
H
H
H
+ OH H+
C C
H
H
H
O
C O
H
H
C
H
H
H
H
CH
H
C
H
H
O
H
C
H
H
HC
O
OH
H C
H
H
C
H
H
O
HH H
O+ +H C
H
H
C
O
O H
H
CH
H
C
O
C
H
H
C
H
H
O
H
H HOC C
H
H
H
O
OH H
O C
H
H
C
H
H
H+ +
H
CC
H
C
O
H O
H
H
C
H
H
H
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Organic ChemistryReactions of the Carboxylic Acids – Esterification
O H
H C
H
H
C
O
O C
H
H
C
H
H
H
HH H
O+ +
H
CH
H
C
O C
O
H
H
C
H
H
H
+ OH H+
C C
H
H
H
O
C O
H
H
C
H
H
H
H
CH
H
C
H
H
O
H
C
H
H
HC
O
OH
H C
H
H
C
H
H
O
HH H
O+ +H C
H
H
C
O
O H
H
CH
H
C
O
C
H
H
C
H
H
O
H
H HOC C
H
H
H
O
OH H
O C
H
H
C
H
H
H+ +
H
CC
H
C
O
H O
H
H
C
H
H
H
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Organic ChemistryReactions of the Carboxylic Acids – Esterification
The carboxylic acid and
alcohol are heated under
reflux in the presence of a
catalyst (a few drops of
concentrated sulfuric acid).
The condenser prevents
volatile organic chemicals
escaping from the reaction
flask.
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Organic ChemistryReactions of the Carboxylic Acids – Esterification
Esters have a
pleasant, sweet,
fruity aroma.
Esters occur
naturally in fruits
and are used in the
food industry and in
perfumery.
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Organic ChemistryReactions of the Carboxylic Acids
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C C
H
H
C
O C
O
H
H
C
H
H
C
H
H
C
H
H
H
H
H
C
H
H
C
H
H
H
C C
H
H
C
O C
O
H
H
C
H
H
H
H
H
C
H
H
H
H C
H
H
C
O C
O
H
H
C
H
H
C
H
H
C
H
H
H
Butyl
Pentanoate
Ethyl
Butanoate
Butyl
Ethanoate
Pineapple
Banana
Pineapple
Strawberry
Apple
Organic ChemistryReactions of the Carboxylic Acids
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Organic ChemistryReactions of the Carboxylic Acids – Ester Hydrolysis
Esters can be hydrolysed (broken down by water) to form the
original carboxylic acid and alcohol.
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Organic ChemistryReactions of the Carboxylic Acids – Ester Hydrolysis
Step 1: Break the C–O bond that is attached to the
C=O group.
Esters can be hydrolysed (broken down by water) to form the
original carboxylic acid and alcohol.
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Organic ChemistryReactions of the Carboxylic Acids – Ester Hydrolysis
Step 1: Break the C–O bond that is attached to the
C=O group.
Step 2: Draw the fragments that are produced after the
C–O bond has been broken.
Esters can be hydrolysed (broken down by water) to form the
original carboxylic acid and alcohol.
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Organic ChemistryReactions of the Carboxylic Acids – Ester Hydrolysis
Step 3: Add water, H2O, to the fragments that are formed.
O–H is bonded to the C=O group. This completes the carboxylic
acid functional group, –COOH.
H is bonded to the single O. This completes the alcohol functional
group, –OH.
Esters can be hydrolysed (broken down by water) to form the
original carboxylic acid and alcohol.
Propanoic Acid
Methanol
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How would you
synthesise the
ester ethyl
ethanoate from the
alkene ethene?
Organic Chemistry
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Synthesis
Ethene Ethyl Ethanoate
H C
H
H
C
O C
O
H
H
C
H
H
HC C
H
H H
H
The synthesis of useful organic compounds from relatively small and
simple starting materials is one of the main objectives of an organic
chemist. For example, how would you synthesise the sweet smelling ester,
ethyl ethanoate, from ethene?
Organic ChemistrySynthetic Pathway
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Ethyl Ethanoate
Ethene
H C
H
H
C
O C
O
H
H
C
H
H
H
Ethanol Ethanoic Acid
H2O /
H2SO4
(catalyst) Cr2O72-
/ H+
H2SO4
(catalyst)
C C
H
H H
H H
CH
H
C
H
H
O
H
H
CH
H
C
O H
O
+ H HO
Organic ChemistrySynthetic Pathway
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Ethyl Ethanoate
Ethene
H C
H
H
C
O C
O
H
H
C
H
H
H
Ethanol Ethanoic Acid
H2O /
H2SO4
(catalyst) Cr2O72-
/ H+
H2SO4
(catalyst)
C C
H
H H
H H
CH
H
C
H
H
O
H
H
CH
H
C
O H
O
+ H HO
Organic ChemistrySynthetic Pathway
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Ethyl Ethanoate
Ethene
H C
H
H
C
O C
O
H
H
C
H
H
H
Ethanol Ethanoic Acid
H2O /
H2SO4
(catalyst) Cr2O72-
/ H+
H2SO4
(catalyst)
C C
H
H H
H H
CH
H
C
H
H
O
H
H
CH
H
C
O H
O
+ H HO
Organic ChemistrySynthetic Pathway
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Ethyl Ethanoate
Ethene
H C
H
H
C
O C
O
H
H
C
H
H
H
Ethanol Ethanoic Acid
H2O /
H2SO4
(catalyst) Cr2O72-
/ H+
H2SO4
(catalyst)
C C
H
H H
H H
CH
H
C
H
H
O
H
H
CH
H
C
O H
O
+ H HO
Organic ChemistrySynthetic Pathway
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Could I please
have a summary of
the essential
reactions in
organic chemistry?
Organic Chemistry
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Organic ChemistrySummary: Reactions of Organic Compounds
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Organic ChemistrySummary: Reactions of Organic Compounds
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Organic ChemistrySummary: Reactions of Organic Compounds
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Organic ChemistrySummary: Reactions of Organic Compounds
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Organic ChemistrySummary: Reactions of Organic Compounds
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Organic ChemistrySummary: Reactions of Organic Compounds
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Organic ChemistrySummary: Reactions of Organic Compounds
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Organic ChemistrySummary: Reactions of Organic Compounds
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Organic ChemistrySummary: Reactions of Organic Compounds
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Organic ChemistrySummary: Reactions of Organic Compounds
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Organic ChemistrySummary: Reactions of Organic Compounds
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Organic ChemistrySummary: Reactions of Organic Compounds
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Organic ChemistrySummary: Reactions of Organic Compounds
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Organic ChemistrySummary: Reactions of Organic Compounds
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Organic ChemistrySummary: Reactions of Organic Compounds
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Organic ChemistrySummary: Reactions of Organic Compounds
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Organic ChemistrySummary: Reactions of Organic Compounds
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Organic ChemistrySummary: Reactions of Organic Compounds
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Organic ChemistrySummary: Reactions of Organic Compounds
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Organic ChemistrySummary: Reactions of Organic Compounds
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Organic ChemistrySummary: Reactions of Organic Compounds
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Organic ChemistrySummary: Reactions of Organic Compounds
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Organic ChemistrySummary: Reactions of Organic Compounds
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Organic ChemistrySummary: Reactions of Organic Compounds
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Organic ChemistrySummary: Reactions of Organic Compounds
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Organic ChemistrySummary: Reactions of Organic Compounds
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Organic ChemistrySummary: Reactions of Organic Compounds
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Organic Chemistry
Presentation on
Organic Chemistry
By Dr. Chris Slatter
Nanyang Girls’ High School
2 Linden Drive
Singapore
288683
14th February 2016