odour and solvent retention in packaging printing era ... · For EU Countries: Regulation ......
Transcript of odour and solvent retention in packaging printing era ... · For EU Countries: Regulation ......
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ODOUR AND SOLVENT RETENTION IN
PACKAGING PRINTING
Wolfgang Mauer
ERA Packaging Conference – 14/15 November 2007
Poznan, Polen
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OVERVIEW
� Why and what we smell
� How to test
� What has that to do with packaging
� Some examples for typical impact of
components of packaging (incl. ink)
� What can we learn from that
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� Human senses have been developed and sharpened during
evolution to help us survive
� Our nose helps us to identify threats to our health, avoid
poisoning or attract us to the right food
� Direct connections into the underconcious part of the brain
� Smell may be associated with personal experiences and moods
� Our senses can get used to a certain stimulus – „if you had it
long enough you don‘t smell it any more“
AND
� Analytical identification of smelling substances may be
extremley difficult
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Legal background
� Our industries produce packaging materials for food, beverages, sweets,
pharmazeuticals aso
� Close contact of packaging to foodstuff
� For EU Countries: Regulation (EC) No 1935/2004
� This Regulation requires that no food contact material (whether printed or not) should endanger
human health, change the composition of the food or alter the organoleptic properties of the food
� This Regulation repealed Framework Directive 89/109/EEC
� Objective is for every printer to supply material which meets the legislation and
specific requirements of the package in question
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SMELL AND TASTE
Our tongues can
distinguish only 5
different categories
of taste: sweet,
sour,salty, bitter
and umami
Smell „happens“ in
our nose and brain
It is volatile
substances that
smell, at sometime
very low
concentration
What man
perceives in every
day life as „taste“ is
about 90 % „smell“
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Odour threshold is the lowest detectable concentration
of a certain substance (mg/ m³)
Red Pepper
2 kg in50 railway waggons
Grapefruit mercaptan
1g ina swimming pool
Trichloranisol (TCA)
33 g Lac Leman (CH) (Cork smell)
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SOLVENT odour thresholdmg/m³
Ethylacetate
Ethanol pure
MEK
Isopropanol
Solvent Naphtha 80/110
Isopropylacetate
n-Propanol
Ethoxypropanol
Hexanal
141
988
126
491
448
68
16
0,3
0,001
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� Comparison with not printed
substrate; accepted quality of printed material
� Odour panel – trained people
� Man is mediocre in his ability to detect smell
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RESIDUAL SOLVENTS IN THE LAB
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RESIDUAL SOLVENTS AT PRESS SIDE
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Potential threat for genuine taste of foodstuff from all components of a packaging material
SUBSTRATE(S)
INKS / LACQUERS
RETAINEDSOLVENTS
ADHESIVESCOLDSEALS
Secondary reactions with something from „outside of the package“or crossreaction
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SUBSTRATE
� Corona treatment of coex OPP („Maggi“ or condiment smell)
� Aging of Polyefines and film additives
� Residual monomers in plastic films like PS
� Hexanal smell of paper or board
� Cellophanes „sulfur smell“
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INK, LACQUERS AND PRIMERS
� Chemistry of ink system
All parts of the formulation have to be selected carefully for low smell
(standard procedure in Siegwerk)
Binders, pigments, additives
� Mostly used solvents
Alcohols, Esters, Ketones, Retarders (Glycolethers)
Monitoring by GC state of the art
Ink manufacturer and printer buy solvents (incoming inspection !)
� Ink layer thickness: the more ink the higher the tendency to retain solvents
� Machine drying capacities
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SOLVENT RETENTION
� Kind of solvent (mixture)
� Quality of solvents
Impurities from manufacturing process of solvents
synthetical Ethanol vs agraric Ethanol
� Process conditions (printing speed, drying conditions)
� Thickness of layers (viscosity, solvent mixture, engravings, aniloxes)
� Retained solvent level to be monitored by GC
further information on the following slides
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� Redissolving, swelling of substrates
Acrylic coated films; PVDC coated films, Cellophane
PVC, Polystyrene
� Kind of substrate: absorbing, Yes / No; coated, lacquered
further information on the following slides
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EtOH = Ethanol
EAc = Ethylacetate
Model printing ink under lab conditions; results in mg/m²
SUBSTRATE EtOH/EAc
Paper
Coex. BOPP
CN primed Alu
Polyamid
Cellophane (PVdC)
EtOH
35 35
6 8
28 35
85 78
15 47
EAc
20
6
45
22
52
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ADHESIVES COLDSEALS
� Smell of the binder system� Solvent based adhesives can also
lead to retained solvents Redissolving into reverse printed inks. � It can make a difference in
retained solvents if the adhesive is
applied to printed substrate or not
printed substrate� No such danger from solventfree
adhesives
� typical genuine smell, Ammonia which is removed by thorough drying
� Smell of the binder system
� Catalytical decomposition through copper ions; microorganisms
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SECONDARY REACTIONS
„Cat piss“ 4- methyl-4-mercapto-pentan-2-
one sulphur containing peptides
from packed ham + Diaceton
alcohol from a retarded Flexo ink
TCA Phenols (preservative) from wooden
paletts transformed by microbes to
Chloro-anisols and migrated into
packaging material
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IMPACT OF RETAINED SOLVENTS ON FOODSTUFF
� Consistancy of foodstuff
� Coarse, fine, powdered, pasty, liquid
� Absorbancy of foodstuff
� Fatty, dry
� Ratio of packaging material surface to filling weight
� Chips, piece of meat
� Genuine smell of foodstuff
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A COFFEE BREAK
WATER GRINDED COFFEE PIECE OF CHOCOLATE
SUGAR
Chemical structure
Genuine smell
Known chemical composition
polar
none
H2O
complex
strong, typcial
complex
mixture, identified
Some 600
fatty
typical, sweet
to bitter
fat and butter
type, complex
aromas identified
some 500
yes,
Disaccharide
none
water soluble
Consistancy liquid dry brown
powdersolid cristals white
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RESIDUAL SOLVENTS AS HEALTH RISK?
Coming back to Regulation (EC) No 1935/2004 Estimation health risk for typical packages with specific or global migration limits
5 mg/m² Ethylacetate (EAc) in chocolate bar (50 g) packaging
Under worst case conditions (100% transfer) ���� 0,1 mg EAc per chocolate bar
One apple contains 3-4 mg EAc (natural content)
You need to eat 30 to 40 chocolate bars to take in the amount of EAc which naturally occurs in one apple
No danger for human health from retained solvents in
professionally produced packaging material
Some food brings more solvent with it than retained solvents from
packaging (dry fruit, raisins contain often esters like Ethylacetate )
� no sensorical impact
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SCRATCH AND SNIFF
Smelling substances like perfume oils can be encapsulated and printed
(gravure and offset)
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SCRATCH AND SNIFF
Typical application advertisments free samples of perfume
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CONCLUSION
� Smell is complex
� Possible threats for the respective foodstuff have to be excluded for
combination of packaging materials, inks and adhesives / coldseals
� Food manufacturers do qualify packaging material together with
converter
� Measures to safeguard sensorically flawless quality
� Raw materials to be specified
� Incoming inspection of solvents (sensorical test and GC)
� Monitor machine parameters
� GC for QC
� and evtl sensorical tests (random sampling or even permanent)
� All tests in comparison to accepted quality
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THANK YOU FOR YOUR KIND ATTENTION!