Nickel Powders - Hart Materials Ltd · Nickel Powders available from Hart Materials Chemically...

4
Specialist supplier of high performance metals and metallic compounds for over 35 years Nickel metal and nickel containing alloys are essential materials used in a wide variety of technologies and applications. Elemental nickel, without any alloying additives, exhibits excellent mechanical properties, good resistance to corrosion, high electrical conductivity and ferro-magnetic properties. A further critical advantage of elemental nickel is that it is readily available as a high purity powder in different morphologies. For many years Hart Materials has specialised in suppling nickel powders and consequently developed a comprehensive level of technical expertise related to these products. Furthermore the company has initiated studies into the properties of nickel powders thereby enabling it to provide technical information that has not previously been available. As a result the company is in a unique position to advise customers on the optimum choice of nickel powder available from a range of manufacturers. Nickel Powders Hart Materials Limited Technology Centre, Planks Lane, Wombourne, South Staffordshire, WV5 8EB, United Kingdom. t. +44 (0) 1902 895446 f. +44 (0) 1902 897469 e. [email protected] www.hartmaterials.com

Transcript of Nickel Powders - Hart Materials Ltd · Nickel Powders available from Hart Materials Chemically...

Specialist supplier of high performance metals andmetallic compounds for over 35 years

it also exhibits a tightly-

c

n the highest

l

I

m

N 99.6% O 3,000 ppm F 800 ppm C 30 ppm S 30 ppm

d d50 d90 Tapped D

4.4µm 11.4 µm 25.2 µm 5.57

4 3.0 µm 6.3 µm 11.2 µm 5.48 S 11.4 µm 17.1 µm 5.45 S 12.6 µm 20.8 µm 34.6 µm 5.37

Nickel metal and nickel containing alloysare essential materials used in a wide varietyof technologies and applications. Elementalnickel, without any alloying additives,exhibits excellent mechanical properties,good resistance to corrosion, high electricalconductivity and ferro-magnetic properties.A further critical advantage of elementalnickel is that it is readily available as a highpurity powder in different morphologies.

For many years Hart Materials hasspecialised in suppling nickel powders andconsequently developed a comprehensivelevel of technical expertise related to theseproducts. Furthermore the company hasinitiated studies into the properties of nickelpowders thereby enabling it to providetechnical information that has not previouslybeen available. As a result the company isin a unique position to advise customers onthe optimum choice of nickel powderavailable from a range of manufacturers.

Nickel Powders

Hart Materials LimitedTechnology Centre, Planks Lane,Wombourne, South Staffordshire,

WV5 8EB, United Kingdom.

t. +44 (0) 1902 895446f. +44 (0) 1902 897469

e. [email protected]

Nickel Powders available from Hart MaterialsCarbonyl nickel powdersThe purest grades of nickel powder that are readily available in commercial quantities are manufact to react with carbon monoxide to form nickel tetra carbonyl. The extremely pure gaseous Ni(CO)4 is

Spherical Vale Carbonyl Nickel - Type 123The specified nickel content of Vale Type 123 carbonyl nickel powder – 99.98 %nickel – represent the highest level of purity available in regular commercial pro-duction. It is manufactured in very large quantities and is not merely a specialgrade with limited production.

Vale Nickel Powder Type 123 has been the backbone of nickel powder technologyfor decades. The product consists of discrete, approximately spherical, particleswith a tightly controlled and consistently reproducible particle sizedistribution. It is used extensively in the production of powdermetallurgical parts and in synthesis of synthetic diamonds. It is alsothe primary binder, together with carbonyl iron powder, used in themanufacture of Tungsten Heavy Alloy components used primarilyfor medical, defence and aerospace applications.

Type 123 special Hart Materials’ gradesHart Materials also offers a number of different size fractions ofcarbonyl nickel powders, all based on Vale Type 123, but availablein four different size ranges.

Filamentary Carbonyl Nickel Powders - Vale Nickel Type 255Vale Type 255 carbonyl nickel powder consists of filamentary particles a completely differe reproducible particle distribution and the same high level of chemical purity as Vale 123.

The advantage of the filamentary structure is that it can be used to create an electrically c the construction of nickel-containing batteries where the nickel matrix acts as the carrier

Type 255 is also the primary binder in nickel based tungsten carbide components used in stee

In addition Vale Type 255 nickel powder is also used in the manufacture of electrically cond

n the highest

l .

I

m

F

I

. Page2 Page2

Particle Size Distribution

0.1 1 10 100 1000 3000

Particle Size (µm)

0

1

2

3

4 5

6

7

8

)%(

em

ulo

V

10/104M PRE, 14 April 2011 10:38:22

it also exhibits a tightly-

c

Particle Size Distribution

0.1 1 10 100 1000 3000

Particle Size (µm)

0

2

4

6

8

10

)%(

em

ulo

V

JEFF JONES SPECIAL, 21 May 2011 08:17:55

Particle Size Distribution

0.1 1 10 100 600

Particle Size (µm)

0 1 2 3

4 5 6 7 8

)%(

em

ulo

V

Hart T123 <325 mesh, 09 October 2013 09:49:16

Particle Size Distribution

0.1 1 10 100 600

Particle Size (µm)

0

1

2

3

4

5

6

7

)%(

em

ulo

V

Hart HML Ni -325 +20u, 09 October 2013 09:51:34

Particle Size Distribution

0.1 1 10 100 600

Particle Size (µm)

0 1 2 3 4 5 6 7 8 9

)%(

em

ulo

V

Hart HML Ni -20u, 09 October 2013 09:53:28

Plus 325 mesh Minus 325 mesh

-325 mesh - +20 microns -20 micron

www.hartmaterials.com

ured by the vapour phase nickel carbonyl process. This process is based upon the ability of nickel

subsequently decomposed to form nickel metal as powders of various shapes and sizes.

ent structure to that of Vale 123 powder. However, it also exhibits a tightly- controlled

conductive matrix into which other materials can be introduced. This is a vital part of for the electrons generated by the active mass.

el rollers, canning dies and in fluid flow control situations in the oil and gas industries.

ductive paints for electromagnetic compatibility applications.

Particle Size Distribution

0.01 0.1 1 10 100 1000 3000

Particle Size (µm)

0

1

2

3

4

5

6

7

)%(

em

ulo

V

Hart T255 As rec'd, 20 December 2011 10:50:29

NOVAMET Type 525 Regular and Type 525 Low DensityNovamet Specialty Products Corporation manufactures two highly refined gradesof filamentary carbonyl nickel powder. These are designated Type 525 Regularand Type 525 Low Density. Since they are derived from material refined by thenickel carbonyl process they exhibit the same high purity as Vale Type 123 andVale Type 255.

These two grades of filamentary carbonyl nickel powder are employed in similarapplications to Vale 255, such as nickel battery manufacture and the productionof electrically conductive coatings used in RFI/EMI shielding application.

N 99.6% O 3,000 ppm F 800 ppm C 30 ppm S 30 ppm

d d50 d90 Tapped D

4.4µm 11.4 µm 25.2 µm 5.57

4 3.0 µm 6.3 µm 11.2 µm 5.48 S 11.4 µm 17.1 µm 5.45 S 12.6 µm 20.8 µm 34.6 µm 5.37

Novamet Nickel Powder Type 525 Regular Novamet Nickel Powder Type 525 Low Density

NOVAMET Special Spherical Nickel Powders - Type 4SP and SNPNovamet Specialty Products Corporation manufactures five different grades of highpurity smooth spherical nickel powders produced, not by the carbonyl process, but bygas atomisation.

Novamet Type 4SP – 10 μm powder at 5,000 times magnification demonstratesthe precise spherical nature of the 4SP/SNP particles and the smoothness of theirsurfaces. This morphology accounts for the very high values of Tapped Density of theseproducts.

The typical chemical compositionof all of this range of powders is:

Ni 99.6%

O2 3,000 ppm

Fe 800 ppm

C 30 ppm

S 30 ppm

There are four separate grades available of this type of nickel powder with typical physical properties as shown below.

d10 d50 d90 Tapped DensitySNP – 400 4.4μm 11.4 μm 25.2 μm 5.57

4SP – 10 μm 3.0 μm 6.3 μm 11.2 μm 5.48

SNP -20/+10 μm 7.2 μm 11.4 μm 17.1 μm 5.45

SNP + 20 μm 12.6 μm 20.8 μm 34.6 μm 5.37

Nickel Powders available from Hart MaterialsChemically reduced Nickel PowdersHart Materials also supplies a number of nickel powders manufactured by chemical reduction from high purity nickel salts.

Hart Type 1A powder, as shown below, is a very fine material with a d50 in the region of 3 microns.

Material choiceThe wide choice of nickel powders offered by Hart Materials gives our customers considerable flexibility in relation to chemicalcomposition, particle size and morphology.

Nickel powders have many on-going traditional applications. The range and type of industries in which they are being used,however, is constantly expanding as their many advantages in terms of metallurgical properties, chemical stability electricalconductivity are being exploited in new and developing technologies.

Hart Materials endeavours to offer as wide a range as possible of nickel powders to suit the requirements of individualcustomers and applications.

Hart Materials also invites enquiries in relation to non-standard types of nickel powder not included in our current productrange.

3 m

Ha

Particle Size Distribution

0.1 1 10 100 600

Particle Size (µm)

0

2

4

6

8

10

)%(

em

ulo

V

HART - GEM 1A, 23 April 2012 13:27:18

Hart Type 1A nickel powder

Hart Materials type 2A, nickel powder has a slightly larger particle size than the Type 1A with a d50 of around 6 microns

3 m

Ha

Particle Size Distribution

0.1 1 10 100 600

Particle Size (µm)

0

2

4

6

8

10

)%(

em

ulo

V

HART - GEM 2a, 23 April 2012 13:31:52

Hart Type 2A nickel powder

Hart Materials Type 3A, has the largest particle size of the special chemically reduced nickel powders with a D50 in theregion of 15 microns.

c

Particle Size Distribution

0.1 1 10 100 600

Particle Size (µm)

0

1

2

3

4

5

6

7

)%(

em

ulo

V

HART - GEM 3A, 23 April 2012 13:33:49

Hart Materials Type 3A

Hart Materials LimitedTechnology Centre, Planks Lane, Wombourne,South Staffordshire, WV5 8EB, United Kingdom.

t. +44 (0) 1902 895446f. +44 (0) 1902 897469

e. [email protected]