New chm 152_unit_13_power_points-su13
Transcript of New chm 152_unit_13_power_points-su13
![Page 1: New chm 152_unit_13_power_points-su13](https://reader035.fdocuments.net/reader035/viewer/2022062307/5550434db4c905b2788b4b05/html5/thumbnails/1.jpg)
15-1
ORGANIC CHEMISTRY III
• CARBOXYLIC ACIDS• DERIVATIVES OF ACIDS• ALDEHYDES/KETONES• AMINES• ETHERS• Chapter 15.4 Silberberg
![Page 2: New chm 152_unit_13_power_points-su13](https://reader035.fdocuments.net/reader035/viewer/2022062307/5550434db4c905b2788b4b05/html5/thumbnails/2.jpg)
15-2
Chapter 15
Organic Compounds and the
Atomic Properties of Carbon
![Page 3: New chm 152_unit_13_power_points-su13](https://reader035.fdocuments.net/reader035/viewer/2022062307/5550434db4c905b2788b4b05/html5/thumbnails/3.jpg)
15-3
Organic Compounds and the Atomic Properties of Carbon
15.3 Some Important Classes of Organic Reactions
15.4 Properties and Reactivities of Common Functional Groups
![Page 4: New chm 152_unit_13_power_points-su13](https://reader035.fdocuments.net/reader035/viewer/2022062307/5550434db4c905b2788b4b05/html5/thumbnails/4.jpg)
15-4
Goals & Objectives
• See the following Learning Objectives on page 676.
• Master these Skills:• 15.6, 8-10.
![Page 5: New chm 152_unit_13_power_points-su13](https://reader035.fdocuments.net/reader035/viewer/2022062307/5550434db4c905b2788b4b05/html5/thumbnails/5.jpg)
15-5
Table 15.5 Important Functional Groups in Organic Compounds
![Page 6: New chm 152_unit_13_power_points-su13](https://reader035.fdocuments.net/reader035/viewer/2022062307/5550434db4c905b2788b4b05/html5/thumbnails/6.jpg)
15-6
Table 15.5 Important Functional Groups in Organic Compounds
![Page 7: New chm 152_unit_13_power_points-su13](https://reader035.fdocuments.net/reader035/viewer/2022062307/5550434db4c905b2788b4b05/html5/thumbnails/7.jpg)
15-7
Amines
The amine functional group contains a N atom.
The systematic name for an amine is formed by dropping the final –e of the alkane and adding the suffix –amine.
C N
Common names that use the name of the alkyl group followed by the suffix –amine are also widely used.
CH3CH2NH2
ethanamine ORethylamine
CH3CH2 NH CH2CH3
diethylamine
![Page 8: New chm 152_unit_13_power_points-su13](https://reader035.fdocuments.net/reader035/viewer/2022062307/5550434db4c905b2788b4b05/html5/thumbnails/8.jpg)
15-8
Figure 15.17 General structures of amines.
Amines are classified according to the number of R groups directly attached to the N atom.
![Page 9: New chm 152_unit_13_power_points-su13](https://reader035.fdocuments.net/reader035/viewer/2022062307/5550434db4c905b2788b4b05/html5/thumbnails/9.jpg)
15-9
Figure 15.18 Some biomolecules with the amine functional group.
Lysine (1° amine)amino acid found in proteins
Adenine (1° amine)component of nucleic acids
Epinephrine (adrenaline; 2° amine)neurotransmitter in brain; hormone released during stress
Cocaine (3° amine)brain stimulant; widely abused drug
![Page 10: New chm 152_unit_13_power_points-su13](https://reader035.fdocuments.net/reader035/viewer/2022062307/5550434db4c905b2788b4b05/html5/thumbnails/10.jpg)
15-10
Properties and Reactions of Amines
Primary and secondary amines can form H bonds; therefore they have higher melting and boiling points than hydrocarbons or alkyl halides of similar mass.
Amines of low molar mass are fishy smelling, water soluble, and weakly basic.
Tertiary amines cannot form H bonds between their molecules because they lack a polar N–H bond.
Amines undergo a variety of reactions, including substitution reactions.
![Page 11: New chm 152_unit_13_power_points-su13](https://reader035.fdocuments.net/reader035/viewer/2022062307/5550434db4c905b2788b4b05/html5/thumbnails/11.jpg)
15-11
Sample Problem 15.4 Predicting the Reactions of Alcohols, Alkyl Halides, and Amines
PLAN: We first determine the functional group(s) of the reactant(s) and then examine any inorganic reagent(s) to decide on the reaction type. Keep in mind that, in general, these functional groups undergo substitution or elimination.
PROBLEM: Determine the reaction type and predict the product(s) for each reaction:
(a) CH3 CH2 CH2 I + NaOH
(b) CH3 CH2 CH2 Br + 2 CH3 CH2 CH2 NH2
(c) CH3 CH
OH
CH3
Cr2O72-
H2SO4
![Page 12: New chm 152_unit_13_power_points-su13](https://reader035.fdocuments.net/reader035/viewer/2022062307/5550434db4c905b2788b4b05/html5/thumbnails/12.jpg)
15-12
SOLUTION:
Sample Problem 15.4
(a) In this reaction the OH of the NaOH reaction substitutes for the I in the organic reagent:
CH3 CH2 CH2 OH + NaI
(b) This is a substitution reaction:
CH3 CH2 CH2 NH
CH2CH3
+ CH3 CH2 CH2 NH2Br
(c) This is an elimination reaction since acidic Cr2O72- is a strong
oxidizing agent:CH3 C
O
CH3
![Page 13: New chm 152_unit_13_power_points-su13](https://reader035.fdocuments.net/reader035/viewer/2022062307/5550434db4c905b2788b4b05/html5/thumbnails/13.jpg)
15-13
Amines
• Classification• NH3 RNH2 R2NH R3N
• 1O 2O 3O
![Page 14: New chm 152_unit_13_power_points-su13](https://reader035.fdocuments.net/reader035/viewer/2022062307/5550434db4c905b2788b4b05/html5/thumbnails/14.jpg)
15-14
Amines
• Nomenclature• CH3NH2
• (CH3)2NH
• (CH3)3N
• CH3NHCH2CH3
• (CH3)2NCH2CH3
![Page 15: New chm 152_unit_13_power_points-su13](https://reader035.fdocuments.net/reader035/viewer/2022062307/5550434db4c905b2788b4b05/html5/thumbnails/15.jpg)
15-15
![Page 16: New chm 152_unit_13_power_points-su13](https://reader035.fdocuments.net/reader035/viewer/2022062307/5550434db4c905b2788b4b05/html5/thumbnails/16.jpg)
15-16
Amines
• Reactions– organic bases– RNH2 + H2O ---> RNH3
+ + OH-
– CH3NH2 + HCl ---> CH3NH3+ + Cl-
– CH3NH2.
HCl– methylamine
hydrochloride
![Page 17: New chm 152_unit_13_power_points-su13](https://reader035.fdocuments.net/reader035/viewer/2022062307/5550434db4c905b2788b4b05/html5/thumbnails/17.jpg)
15-17
Aldehydes and Ketones
Aldehydes and ketones both contain the carbonyl group, C=O.
Aldehydes are named by replacing the final –e of the alkane name with the suffix –al.
Ketones have the suffix –one and the position of the carbonyl must always be indicated.
R and R′ indicate hydrocarbon groups.
H C
O
Raldehyde
R C
O
R'ketone
![Page 18: New chm 152_unit_13_power_points-su13](https://reader035.fdocuments.net/reader035/viewer/2022062307/5550434db4c905b2788b4b05/html5/thumbnails/18.jpg)
15-18
Figure 15.20 Some common aldehydes and ketones.
Methanal (formaldehyde) Used to make resins in plywood, dishware, countertops; biological preservative
Ethanal (acetaldehyde) Narcotic product of ethanol metabolism; used to make perfumes, flavors, plastics, other chemicals
2-Propanone (acetone) Solvent for fat, rubber, plastic, varnish, lacquer; chemical feedstock
2-Butanone (methyl ethyl ketone) Important solvent
Benzaldehyde Artificial almond flavoring
![Page 19: New chm 152_unit_13_power_points-su13](https://reader035.fdocuments.net/reader035/viewer/2022062307/5550434db4c905b2788b4b05/html5/thumbnails/19.jpg)
15-19
Figure 15.21 The polar carbonyl group.
The C=O bond is electron rich and is also highly polar. It readily undergoes addition reactions, and the electron-poor C atom attracts electron-rich groups.
![Page 20: New chm 152_unit_13_power_points-su13](https://reader035.fdocuments.net/reader035/viewer/2022062307/5550434db4c905b2788b4b05/html5/thumbnails/20.jpg)
15-20
Reactions of Aldehydes and Ketones
Reduction to alcohols is an example of an addition reaction:
O
reduction
OH
cyclobutanone cyclobutanol
Organometallic compounds, which have a metal atom covalently bonded to C, add to the electron-poor carbonyl C:
R C
O
H + R' Li+-
+
-
R CH
OH
R' + LiOH
![Page 21: New chm 152_unit_13_power_points-su13](https://reader035.fdocuments.net/reader035/viewer/2022062307/5550434db4c905b2788b4b05/html5/thumbnails/21.jpg)
15-21
Sample Problem 15.5 Predicting the Steps in a Reaction Sequence
PLAN: For each step we examine the functional group of the reactant and the reagent above the yield arrow to decide on the most likely product.
PROBLEM: Fill in the blanks in the following reaction sequence:
CH3 CH2 CH
Br
CH3OH- Cr2O7
2-
H2SO4
CH3-Li H2O
SOLUTION: The first step involves an alkyl halide reacting with OH-, so this is probably a substitution reaction, which yields an alcohol. In the next step the alcohol is oxidized to a ketone and finally the organometallic reagent adds to the ketone to give an alcohol with one more C in its skeleton:
![Page 22: New chm 152_unit_13_power_points-su13](https://reader035.fdocuments.net/reader035/viewer/2022062307/5550434db4c905b2788b4b05/html5/thumbnails/22.jpg)
15-22
Sample Problem 15.5
CH3 CH2 CH
Br
CH3OH- Cr2O7
2-
H2SO4
CH3-Li
H2O
CH3 CH2 CH
OH
CH3
substitution oxidation(elimination)
CH3 CH2 C
O
CH3
addition
CH3 CH2 C
OH
CH3
CH3
![Page 23: New chm 152_unit_13_power_points-su13](https://reader035.fdocuments.net/reader035/viewer/2022062307/5550434db4c905b2788b4b05/html5/thumbnails/23.jpg)
15-23
Aldehydes
• Nomenclature• IUPAC
TRIVIAL• HCHO• CH3CHO
• CH3CH2CHO
• CH3CH2CH2CHO
![Page 24: New chm 152_unit_13_power_points-su13](https://reader035.fdocuments.net/reader035/viewer/2022062307/5550434db4c905b2788b4b05/html5/thumbnails/24.jpg)
15-24
O
methanalO
ethanal
O
propanal
O
butanal
![Page 25: New chm 152_unit_13_power_points-su13](https://reader035.fdocuments.net/reader035/viewer/2022062307/5550434db4c905b2788b4b05/html5/thumbnails/25.jpg)
15-25
![Page 26: New chm 152_unit_13_power_points-su13](https://reader035.fdocuments.net/reader035/viewer/2022062307/5550434db4c905b2788b4b05/html5/thumbnails/26.jpg)
15-26
Aldehydes
• Preparation– RCH2OH + [O] ---> RCHO
– CH3CH2OH + [O] ---> CH3CHO
– Prepare• 3-methylpentanal• 2,4-dimethylhexanal
![Page 27: New chm 152_unit_13_power_points-su13](https://reader035.fdocuments.net/reader035/viewer/2022062307/5550434db4c905b2788b4b05/html5/thumbnails/27.jpg)
15-27
![Page 28: New chm 152_unit_13_power_points-su13](https://reader035.fdocuments.net/reader035/viewer/2022062307/5550434db4c905b2788b4b05/html5/thumbnails/28.jpg)
15-28
![Page 29: New chm 152_unit_13_power_points-su13](https://reader035.fdocuments.net/reader035/viewer/2022062307/5550434db4c905b2788b4b05/html5/thumbnails/29.jpg)
15-29
Ketones, RCOR’
• Nomenclature• IUPAC
TRIVIAL• CH3COCH3
• CH3COCH2CH3
• CH3COCH2CH2CH3
![Page 30: New chm 152_unit_13_power_points-su13](https://reader035.fdocuments.net/reader035/viewer/2022062307/5550434db4c905b2788b4b05/html5/thumbnails/30.jpg)
15-30
O
propanone
O
2-butanone
O
2-pentanone
![Page 31: New chm 152_unit_13_power_points-su13](https://reader035.fdocuments.net/reader035/viewer/2022062307/5550434db4c905b2788b4b05/html5/thumbnails/31.jpg)
15-31
![Page 32: New chm 152_unit_13_power_points-su13](https://reader035.fdocuments.net/reader035/viewer/2022062307/5550434db4c905b2788b4b05/html5/thumbnails/32.jpg)
15-32
Ketones
• Preparation– OH– RCHR’ + [O] ---> RCOR’– OH– CH3CHCH3 + [O] ---> CH3COCH3
• Prepare:– 3-hexanone– 2-methyl-3-pentanone
![Page 33: New chm 152_unit_13_power_points-su13](https://reader035.fdocuments.net/reader035/viewer/2022062307/5550434db4c905b2788b4b05/html5/thumbnails/33.jpg)
15-33
![Page 34: New chm 152_unit_13_power_points-su13](https://reader035.fdocuments.net/reader035/viewer/2022062307/5550434db4c905b2788b4b05/html5/thumbnails/34.jpg)
15-34
![Page 35: New chm 152_unit_13_power_points-su13](https://reader035.fdocuments.net/reader035/viewer/2022062307/5550434db4c905b2788b4b05/html5/thumbnails/35.jpg)
15-35
![Page 36: New chm 152_unit_13_power_points-su13](https://reader035.fdocuments.net/reader035/viewer/2022062307/5550434db4c905b2788b4b05/html5/thumbnails/36.jpg)
15-36
Carboxylic Acids
Carboxylic acids are named by replacing the –e of the alkane with the suffix –oic acid.
Carboxylic acids contain the functional group –COOH, or
Carboxylic acids are weak acids in water, and react with strong bases:
C
O
OH
CH3 C
O
OH (l) + NaOH (aq) CH3 C
O
O- (aq) + Na+ (aq) + H2O (l)
methanoic acid methanoate anion
![Page 37: New chm 152_unit_13_power_points-su13](https://reader035.fdocuments.net/reader035/viewer/2022062307/5550434db4c905b2788b4b05/html5/thumbnails/37.jpg)
15-37
Figure 15.22 Some molecules with the carboxylic acid functional group.
Methanoic acid (formic acid) An irritating component of ant and bee stings
Butanoic acid (butyric acid) Odor of rancid butter; suspected component of monkey sex attractant
Octadecanoic acid (stearic acid) Found in animal fats; used in making candles and soaps
Benzoic acid Calorimetric standard; used in preserving food, dyeing fabric, curing tobacco
![Page 38: New chm 152_unit_13_power_points-su13](https://reader035.fdocuments.net/reader035/viewer/2022062307/5550434db4c905b2788b4b05/html5/thumbnails/38.jpg)
15-38
Carboxylic Acids, RCOOH
• Nomenclature• IUPAC TRIVIAL• HCOOH• CH3COOH
• CH3CH2COOH
• CH3CH2CH2COOH
![Page 39: New chm 152_unit_13_power_points-su13](https://reader035.fdocuments.net/reader035/viewer/2022062307/5550434db4c905b2788b4b05/html5/thumbnails/39.jpg)
15-39
OHO
methanoic acid
O
OH
ethanoic acid
O
OH
propanoic acid
O
OH
butanoic acid
![Page 40: New chm 152_unit_13_power_points-su13](https://reader035.fdocuments.net/reader035/viewer/2022062307/5550434db4c905b2788b4b05/html5/thumbnails/40.jpg)
15-40
![Page 41: New chm 152_unit_13_power_points-su13](https://reader035.fdocuments.net/reader035/viewer/2022062307/5550434db4c905b2788b4b05/html5/thumbnails/41.jpg)
15-41
Carboxylic Acids, RCOOH
• Preparation– RCH2OH + xs[O] ----> RCOOH
– CH3CH2OH + xs[O] ----> CH3COOH
• Reaction--as acid– RCOOH + NaOH ----> RCOONa– CH3COOH + NaOH ----> CH3COONa
– sodium acetate
![Page 42: New chm 152_unit_13_power_points-su13](https://reader035.fdocuments.net/reader035/viewer/2022062307/5550434db4c905b2788b4b05/html5/thumbnails/42.jpg)
15-42
Derivatives of Carboxylic Acids
• Acid Chlorides, RCOCl– Nomenclature
• “oic acid” becomes ‘yl chloride”• CH3CH2COCl
– Preparatio• RCOOH + PCl3 ----> RCOCl
![Page 43: New chm 152_unit_13_power_points-su13](https://reader035.fdocuments.net/reader035/viewer/2022062307/5550434db4c905b2788b4b05/html5/thumbnails/43.jpg)
15-43
![Page 44: New chm 152_unit_13_power_points-su13](https://reader035.fdocuments.net/reader035/viewer/2022062307/5550434db4c905b2788b4b05/html5/thumbnails/44.jpg)
15-44
Esters
The ester group is formed by the reaction of an alcohol and a carboxylic acid.
Ester groups occur commonly in lipids, which are formed by the esterification of fatty acids.
CH3 C
O
OH O CH3H+ CH3 C
O
O CH3 + HOH
ethanoic acid methanol methyl ethanoate
Esterification is a dehydration-condensation reaction.
![Page 45: New chm 152_unit_13_power_points-su13](https://reader035.fdocuments.net/reader035/viewer/2022062307/5550434db4c905b2788b4b05/html5/thumbnails/45.jpg)
15-45
Figure 15.23 Some lipid molecules with the ester functional group.
Cetyl palmitate The most common lipid in whale blubber
Lecithin Phospholipid found in all cell membranes
Tristearin Typical dietary fat used as an energy store in animals
![Page 46: New chm 152_unit_13_power_points-su13](https://reader035.fdocuments.net/reader035/viewer/2022062307/5550434db4c905b2788b4b05/html5/thumbnails/46.jpg)
15-46
Derivatives of Carboxylic Acids
• Esters, RCOOR’– Preparation and Nomenclature– RCOCl + R’OH ----> RCOOR’ + HCl– CH3COCl + CH3CH2OHCH3COOCH2CH3
– ethyl acetate
– or ethyl ethanoate
![Page 47: New chm 152_unit_13_power_points-su13](https://reader035.fdocuments.net/reader035/viewer/2022062307/5550434db4c905b2788b4b05/html5/thumbnails/47.jpg)
15-47
Table 1. Names, Structures, and Fruit and Flower Aromas of Some Common Natural EstersEster Name Aroma
3-Methylbutyl acetate Bananas n-Butyl acetate Pears
n-Octyl acetate Oranges
Benzyl acetate Peaches
Benzyl butyrate Flowers*
Ethyl butyrate Pineapples
![Page 48: New chm 152_unit_13_power_points-su13](https://reader035.fdocuments.net/reader035/viewer/2022062307/5550434db4c905b2788b4b05/html5/thumbnails/48.jpg)
15-48
O
O
3-Methylbutyl acetate
O
O
n-Butyl acetate
O
O
n-Octyl acetate
![Page 49: New chm 152_unit_13_power_points-su13](https://reader035.fdocuments.net/reader035/viewer/2022062307/5550434db4c905b2788b4b05/html5/thumbnails/49.jpg)
15-49
O
O
Benzyl acetate
O
O
Benzyl butyrate
O
O
Ethyl butyrate
![Page 50: New chm 152_unit_13_power_points-su13](https://reader035.fdocuments.net/reader035/viewer/2022062307/5550434db4c905b2788b4b05/html5/thumbnails/50.jpg)
15-50
Saponification
Ester hydrolysis can be carried out using either aqueous acid or aqueous base. When base is used the process is called saponification.This is the process used to make soaps from lipids.
R C
O
O CH2
CH
CH2O
O
C
O
R"
C
O
R'
a triglyceride
3NaOH
HO CH2
CH
CH2HO
HO
R C
O
O- Na+
R' C
O
O- Na+
R" C
O
O- Na+
3 soaps(salts of fatty acids)
glycerol
![Page 51: New chm 152_unit_13_power_points-su13](https://reader035.fdocuments.net/reader035/viewer/2022062307/5550434db4c905b2788b4b05/html5/thumbnails/51.jpg)
15-51
Amides
An amide contains the functional group:
C
O
N
Amides, like esters, can be hydrolyzed to give a carboxylic acid and an amine.
The peptide bond, which links amino acids in a protein, is an amide group.
![Page 52: New chm 152_unit_13_power_points-su13](https://reader035.fdocuments.net/reader035/viewer/2022062307/5550434db4c905b2788b4b05/html5/thumbnails/52.jpg)
15-52
Lysergic acid diethylamide (LSD-25)A potent hallucinogen
Figure 15.24 Some molecules with the amide functional group.
N,N-Dimethylmethanamide (dimethylformamide)Major organic solvent; used in production of synthetic fibers
AcetaminophenActive ingredient in nonaspirin pain relievers; used to make dyes and photographic chemicals
![Page 53: New chm 152_unit_13_power_points-su13](https://reader035.fdocuments.net/reader035/viewer/2022062307/5550434db4c905b2788b4b05/html5/thumbnails/53.jpg)
15-53
Derivatives of Carboxylic Acids
• Amides, RCONH2
– Preparation and Nomenclature– RCOCl + NH3 ----> RCONH2 + HCl
– CH3COCl + NH3 ----> CH3CONH2
– ethanamide– acetamide
![Page 54: New chm 152_unit_13_power_points-su13](https://reader035.fdocuments.net/reader035/viewer/2022062307/5550434db4c905b2788b4b05/html5/thumbnails/54.jpg)
15-54
Sample Problem 15.6 Predicting the Reactions of the Carboxylic Acid Family
PROBLEM: Predict the product(s) of the following reactions:
(a) CH3 CH2 CH2 C
O
OH CH3 CH
OH
CH3+H+
(b) CH CH2 CH2 C
O
NH
CH3
CH3 CH2CH3
NaOH
H2O
PLAN: We identify the functional groups in the reactant(s) and see how they change. In (a), a carboxylic acid reacts with an alcohol, so the reaction must be a substitution to form an ester. In (b), an amide reacts with aqueous base, so hydrolysis occurs.
![Page 55: New chm 152_unit_13_power_points-su13](https://reader035.fdocuments.net/reader035/viewer/2022062307/5550434db4c905b2788b4b05/html5/thumbnails/55.jpg)
15-55
Sample Problem 15.6
SOLUTION:
(a) CH3 CH2 CH2 C
O
OH CH3 CH
OH
CH3+H+
CH3 CH2 CH2 C
O
O CH
CH3
CH3
+ H2O
(b) CH CH2 CH2 C
O
NH
CH3
CH3 CH2CH3
NaOH
H2OCH CH2 CH2 C
OCH3
CH3 O- Na+
CH2CH3
+NH2
![Page 56: New chm 152_unit_13_power_points-su13](https://reader035.fdocuments.net/reader035/viewer/2022062307/5550434db4c905b2788b4b05/html5/thumbnails/56.jpg)
15-56
Ethers, ROR’
• HOH ROH ROR’• water alcohol ether
![Page 57: New chm 152_unit_13_power_points-su13](https://reader035.fdocuments.net/reader035/viewer/2022062307/5550434db4c905b2788b4b05/html5/thumbnails/57.jpg)
15-57
Ethers, ROR’
• Nomenclature• Use common names• CH3OCH3
• CH3OCH2CH3
• CH3OCH2CH2CH2CH3
![Page 58: New chm 152_unit_13_power_points-su13](https://reader035.fdocuments.net/reader035/viewer/2022062307/5550434db4c905b2788b4b05/html5/thumbnails/58.jpg)
15-58
O
methoxymethane
O
methoxyethane
O
methoxybutane
![Page 59: New chm 152_unit_13_power_points-su13](https://reader035.fdocuments.net/reader035/viewer/2022062307/5550434db4c905b2788b4b05/html5/thumbnails/59.jpg)
15-59
Alexander Williamson
• Alexander William Williamson (May 1, 1824 – May 6, 1904), an English chemist, was born at Wandsworth, London. Williamson is remembered for his research on the formation of ether. For his work on etherification, Williamson received a Royal medal from the Royal Society in 1862.
![Page 60: New chm 152_unit_13_power_points-su13](https://reader035.fdocuments.net/reader035/viewer/2022062307/5550434db4c905b2788b4b05/html5/thumbnails/60.jpg)
15-60
Ethers, ROR’
• Preparation (Williamson synthesis)• RONa + R’I ---> ROR’ + NaI• Outline a synthesis of each of the
following:• ethylmethyl ether• ethoxybutane
![Page 61: New chm 152_unit_13_power_points-su13](https://reader035.fdocuments.net/reader035/viewer/2022062307/5550434db4c905b2788b4b05/html5/thumbnails/61.jpg)
15-61
![Page 62: New chm 152_unit_13_power_points-su13](https://reader035.fdocuments.net/reader035/viewer/2022062307/5550434db4c905b2788b4b05/html5/thumbnails/62.jpg)
15-62
![Page 63: New chm 152_unit_13_power_points-su13](https://reader035.fdocuments.net/reader035/viewer/2022062307/5550434db4c905b2788b4b05/html5/thumbnails/63.jpg)
15-63
Polymers
Addition polymers, also called chain-growth polymers form when monomers undergo an addition reaction with each other.The monomers of most addition polymers contain an alkene group.
Condensation polymers are formed when monomers link by a dehydration-condensation type reaction.The monomers of condensation polymers have two functional groups, and each monomer can link to two others.
![Page 64: New chm 152_unit_13_power_points-su13](https://reader035.fdocuments.net/reader035/viewer/2022062307/5550434db4c905b2788b4b05/html5/thumbnails/64.jpg)
15-64
Figure 15.27 Steps in the free-radical polymerization of ethylene.
![Page 65: New chm 152_unit_13_power_points-su13](https://reader035.fdocuments.net/reader035/viewer/2022062307/5550434db4c905b2788b4b05/html5/thumbnails/65.jpg)
15-65
Table 15.6 Some Major Addition Polymers
![Page 66: New chm 152_unit_13_power_points-su13](https://reader035.fdocuments.net/reader035/viewer/2022062307/5550434db4c905b2788b4b05/html5/thumbnails/66.jpg)
15-66
Table 15.6 Some Major Addition Polymers
![Page 67: New chm 152_unit_13_power_points-su13](https://reader035.fdocuments.net/reader035/viewer/2022062307/5550434db4c905b2788b4b05/html5/thumbnails/67.jpg)
15-67
Figure 15.28 The formation of nylon-66.
Nylon-66 is a condensation polymer, made by reacting a diacid with a diamine. The polyamide forms between the two liquid phases.
HO C
O
(CH2)4 C
O
OH + nH2N (CH2)6 NH2
HO C
O
(CH2)4 C
O
NH (CH2)6 NH Hn