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Enclosure: 1

Name of Products with its Quantity

Sr. No.

Product Name Quantity (MT/Month)

Group1. Intermediates 1. MUA (Meta Ureido Aniline) 2. PAABSA (Para aminoazobenzene 4 –Sulphonic

acid) 3. SPCP (Sulpho phenyl carboxy pyrazole) 4. N.W.Acid 5. Sodium Naphthionate 6. DASA (Diamino sulfanilamide) 7. FC Acid 8. Sulpho VS 9. OAVS (Ortho Anisidine Vinyl Sulphone) 10. K-Acid (1-Amino-8 Napthol)

75

Group 2. Dyes (Alternative Production) 1. Reactive Dyes

1. Reactive Black 8/HN 2. Reactive Black WNN/Black Mix 3. Reactive Black 5/B 4. Reactive Blue 222/BF 5. Reactive Blue 194/ Navy Blue ME2GL 6. Reactive Orange 12/Golden Yellow HR 7. Reactive Orange 13/H2R 8. Reactive Yellow 15/GR 9. Reactive Yellow 18/H4G 10. Reactive Yellow 42/FG 11. Reactive Yellow 145/Golden Yellow MERL 12. Reactive Yellow 160/ME4GL 13. Reactive Red 195/ ME4BL 14. Reactive Red 198/ RB

2. Direct Dyes 1. Direct Black 22/ VSF 2. Direct Red 31/ 12B 3. Direct Orange 39 4. Direct Yellow 86 5. Direct Yellow 11/ Paper Yellow R 6. Direct Violet 9/ BRILL Violet B 7. Direct Blue 86/ Turquoise Blue GL 8. Direct blue 1/ FF

3. Acid Dyes 1. Acid Blue 193/ Blue MTR 2. Acid Brown75/CR 3. Acid black 194/MSRL 4. Acid Blue 113 5. Acid green 68 6. Acid Red 131 7. Acid Yellow 36

4. Solvent Dyes: 1. Solvent Blue 36 2. Solvent Red 24 3. Solvent Yellow 33 4. Solvent Green 3

5. Food Colors: 1. Tartrazin 2. Sunset Yellow 3. Chocolate Brown 4. Ponceau 4R

120

1. Reactive Turquoise Blue 21/G 2. Reactive Orange 122/ ME2RL 3. Acid Violet 90/ Bordeaux MB 4. Acid Black 210/NT

75

6. Disperse Dyes: 1. Disperse Blue 366 2. Disperse Orange 25 3. Disperse Yellow 211 4. Disperse Blue 79

30

Enclosure: 2

Packing & Final Use of Products

Name of Product Type of Packing Final Application of Product

Intermediates 5, 10, 25, 50, 100, 500 kg Drums, Bags, Boxes, Jumbo Bags

Dye Industries

Reactive Dyes/Direct Dyes/ Acid Dyes/Solvent Dyes/food Colors (Alternative Production)

5, 10, 25, 50, 100, 500 kg Drums, Bags, Boxes, Jumbo Bags

Dying And Textile Industries

Disperse Dyes

Enclosure: 3 Name of Raw Materials with its Quantity

Group1. Dyes Intermediates

1. MUA: Sr.No. Name of Raw Material MT/MT MT/Month

1. MPD (Meta Phynelene diamine)

0.48 36

2. Hydrochloric Acid 1.24 93 3. Sodium Cynate 0.36 27

2. PAABSA:

Sr.No. Name of Raw Material MT/MT MT/Month 1. Aniline 0.13 9.7 2. Formaldehyde 0.08 6 3. Sodium Bi Sulphite 0.05 3.8 4. Sulphuric Acid 0.2 15 5. Hydrochloric Acid 0.17 12.8 6. Sodium Nitrite 0.08 6 7. Sodium Bi Carbonate 0.17 12.7

3. SPCP:

Sr.No. Name of Raw Material MT/MT MT/Month 1. Benzene 0.054 4.05 2. Di Ethyl Oxalate 1.05 78.0 3. Ethyl Acetate 0.67 50.25 4. PAPSA (4-Amino phenol 2

– sulphonic acid) 1.155 86.62

5. Caustic Lye 0.056 4.2 6. Sodium Metal 0.120 9

4. N.W Acid

Sr.No. Name of Raw Material MT/MT MT/Month 1 Sodium Napthoniate 1.3 97.5 2 Sodium Bi Sulphite 1.9 142 3 Sulphuric Acid 2.9 218 4 Caustic Lye 0.75 57 5 Hydrochloric Acid 1.25 94

5. Sodium Napthionate:

Sr.No. Name of Raw Material MT/MT MT/Month 1 ANA (Alpha Napthylamine) 0.52 39 2 Sulphuric Acid 0.36 27 3 Hydrochloric acid 0.16 12 4 Vaccum Salt 0.280 21

6. DASA:

Sr.No. Name of Raw Material MT/MT MT/Month 1 Para Nitro Aniline 0.525 40 2 Acetanilide 0.514 39 3 Chloro Sulphonic Acid 0.886 67 4 Iron Powder 0.425 32 5 Hydrochloric Acid 0.278 21 6 Sodium Hydroxide 0.15 11 7 Soda Ash 0.403 31 8 Spent Acid 1 75

7. F.C.Acid

Sr.No. Name of Raw Material MT/MT MT/Month 1 Para Nitro Aniline 0.495 37.1 2 PNCBOSA (Para Nitro

Chloro benzene ortho sulphonic acid)

0.851 64

3 Sulfuric Acid 0.351 27 4 Spent Sulfuric Acid 1 75 5 Soda Ash 0.76 57 6 Iron Powder 0.802 61 7 Hydrochloric Acid 0.262 19.65

8. Sulpho V.S

Sr.No. Name of Raw Material MT/MT MT/Month 1 Vinyl Sulphone 0.63 47.25 2 Oleum Acid 0.63 47.25 3 Sulphuric Acid 0.81 61 4 Ice 1.4 105 5 Pottasium Chloride 0.46 35

9. OAVS: Sr.No. Name of Raw Material MT/MT MT/Month

1 Acetyl Ortho Ansidine 0.71 54 2 Chloro Sulfonic Acid 3.04 228 3 Sodium Bi Sulfite 0.65 49 4 Caustic Lye 1.2 90 5 Ethylene Oxide 0.58 44 6 Sulphuric Acid 1.4 105

10. K-Acid:

Sr.No. Name of Raw Material MT/MT MT/Month 1. B- Naphthol 0.88 66.5 2. Oleum 3.78 283.5 3. Sulphuric Acid 2.2 165 4. Ice 1.1 82.5 5. Sodium Sulphate 2.9 217.5 6. Ammonia 4.5 337.5 7. Sodium Bicarbonate 0.61 45.75

Group2. Reactive Dyes:

1. Reactive Black HN: Sr.No. Name of Raw Material MT/MT MT/Month

1. Kieselher 0.025 3 2. Hydrochloric Acid 0.46 56 3. Acetic Acid 0.06 8 4. Sodium Sulphate 0.18 21 5. Caustic Lye 0.19 23 6. Cyanuric Chloride 0.19 23

2. Reactive Black WNN:

Sr.No. Name of Raw Material MT/MT MT/Month 1 SPVS (Sulpho Para Vinyl

Sulphone) 0.25 30

2 Hydrochloric Acid 0.05 6 3 Sodium Nitrite 0.05 6 4 J-Acid 0.08 10 5 MPDSA (Meta Phynelene

diamine sulphonic acid) 0.06 8

6 V.S.Diazo 0.23 28 7 Sodium Bi Carbonate 0.23 28 8 Reactive Black B 0.35 42 9 Salt 0.04 5

3. Reactive Black 5:

Sr.No. Name of Raw Material MT/MT MT/Month

1. Vinyl Sulphone 0.37 45 2. Hydrochloric Acid 0.25 30 3. Sodium Nitrite 0.09 11 4. H-Acid 0.21 26 5. Soda Ash 0.28 34

4. Reactive Blue 222/BF:

Sr.No. Name of Raw Material MT/MT MT/Month 1. MPDSA (Meta Phynelene


2. Soda 0.12 15 3. Ice 1.4 168 4. Cynuric Chloride 0.13 16 5. Cal. Oil 0.001 0.12 6. MBVS (Meta base vinyl

sulphone) 0.2 24

7. Sodium Bicarbonate 0.06 7.2 8. Hydrochloric Acid 0.34 41 9. Sodium Nitrite 0.1 12

10. H-Acid 0.21 25 11. Sulpho Tobias Acid 0.2 24

5. Reactive Navy Blue ME2GL:


1. Sulphanilic Acid 0.15 19 2. Cyanuric Chloride 0.16 20 3. Hydrochloric Acid 0.17 21 4. MPDSA (Meta Phynelene


5. Vinyl Sulphone 0.25 30

6. Reactive Golden Yellow HR:

Sr.No Name of Raw Material MT/MT MT/Month 1 K-Acid 0.4 48 2 Hydrochloric Acid 0.075 9 3 Sodium Nitrite 0.075 9 4 Meta Ureido Aniline 0.15 19 5 Cyanuric Chloride 0.19 23 6 Sodium Bi Carbonate 0.52 63 7 Ammonium Hydroxide 0.04 5

7. Reactive Orange H2R:

Sr.No. Name of Raw Material MT/MT MT/Month 1 NMJ Acid 0.3 36 2 Sodium Hydroxide 0.09 11 3 Acetic Anhydride 0.11 14 4 Sulpho Tobias Acid 0.35 42 5 Hydrochloric Acid 0.08 10 6 Sodium Bi Carbonate 0.2 24 7 Sodium Nitrite 0.08 10 8 Cyanuric Chloride 0.21 26 9 Ammoium Hydroxide 0.4 48

8. Reactive Yellow 15:


1. H-Acid 0.5 60 2. Caustic Lye 0.16 20 3. Acetic Anhydride 0.26 32 4. Soda Ash 0.9 105 5. Hydrochloric Acid 0.66 80 6. Disperging Agent-Tamol 0.02 2.4 7. Vinyl Sulphone 0.42 50 8. Sodium Nitrite 0.11 13 9. Sulfamic Acid 0.002 0.24

10. Octanol 0.02 2.4 11. Copper Sulphate 0.44 52 12. Sodium Acetate 1 120 13 Hydrogen Peroxide 0.542 65 14. Salt 0.5 60

9. Reactive Yellow 18/H4G:

Sr.No. Name of Raw Material MT/MT MT/Month 1. MPDSA (Meta Phynelene


2. Hydrochloric Acid 0.15 18 3. Sodium Nitrite 0.04 5 4. Cyanuric Chloride 0.11 14 5. Caustic Lye 0.05 6 6. Soda Ash 0.04 5 7. SPCP (Sulpho Phenyl Carbox

pyrazole) 0.17 21

8. DASDA (Diamino Stibene di sulphonic acid)

0.11 14

10. Reactive Yellow FG:

Sr.No. Name of Raw Material MT/MT Mt/Month

1 Vinyl Sulphone 0.44 53 2 Hydrochloric Acid 0.11 14 3 Sodium Nitrite 0.1 13 4 SPCP (Sulpho Phenyl

Carbox pyrazole) 0.45 54

5 Sodium Bi Carbonate 0.26 32

11. Reactive Golden Yellow MERL/ Yellow 145:

Sr.No. Name of Raw Material MT/MT MT/Month 1 K-Acid 0.3 37 2 Hydrochloric Acid 0.058 7 3 Sodium Nitrite 0.058 7 4 Meta Ureido Aniline 0.125 15 5 Cyanuric Chloride 0.15 18 6 Sodium Bi Carbonate 0.475 57 7 Vinyl Sulphone 0.225 27

12. Reactive Yellow ME4GL:

Sr.No. Name of Raw Material MT/MT MT/Month 1 Cyanuric Chloride 0.17 21 2 MPDSA (Meta Phynelene


3 Sodium Carbonate 0.1 12 4 Hydrochloric Acid 0.075 9 5 Sodium Nitrite 0.06 8 6 2-Pyridine 0.18 22 7 Sodium Bi Carbonate 0.24 29 8 Vinyl Sulphone 0.26 32

13. Reactive Red ME4BL/ Red 195:

Sr.No. Name of Product MT/MT MT/Month

1 Vinyl Sulphone 0.2 25 2 Sodium Bi Carbonate 0.43 52 3 Cyanuric Chloride 0.14 17 4 Sulpho Tobias Acid 0.22 27 5 Sodium Nitrite 0.05 6 6 H-Acid 0.05 7

14. Reactive Red RB/ Red 198:


1 Cyanuric Chloride 0.14 17 2 H-Acid 0.24 29 3 Sodium Bi Chloride 0.06 8 4 V.S. 0.42 51 5 Hydrochloric Acid 0.05 7 6 Sodium Nitrite 0.05 7 7 Sodium Carbonate 0.08 10

15. Reactive Orange ME2RL (75MT/Month):

Sr.No. Name of Raw Material MT/MT MT/Month 1 J-Acid 0.2 24 2 Caustic Lye 0.19 23 3 Acetic Anhydride 0.15 18 4 Hydrochloric Acid 0.31 38 5 Sulpho Tobias Acid 0.22 27 6 Cyanuric Chloride 0.14 17 7 Vinyl Sulphone 0.21 25

16. Reactive Blue G (75MT/Month):


1. Copper Phthalo Cyanine Blue

0.34 41

2. Chloro Sulfonic Acid 1.3 159 3. Phosphorus Tri Chloride 0.18 22 4. Vinyl Sulphone 0.32 39 5. Global Salt 0.08 10 6. Sodium Bi carbonate 0.22 27

Group3: Acid Dyes:

1. Acid Blue 193: Sr.No. Name of Raw Material MT/MT MT/Month

1 Beta Naphthol 0.3 37 2 Caustic Flakes 0.25 30 3 1:2:4 Diazo 0.5 60 4 Salicylic Acid 0.05 6 5 Basic Chrome Sulphate 0.35 42

2. Acid Brown 75:

Sr.No. Name of Raw Material MT/MT MT/Month 1 Sodium Nitrite 0.2 25 2 Hydrochloric Acid 0.24 29 3 H-Acid 0.32 39 4 Resourcinol 0.11 14 5 Napcramate 0.22 27 6 Para Nitro Aniline 0.14 17

3. Acid Black 194/MSRL:

Sr.No. Name of Raw Material MT/MT MT/Month 1. 6 Nitro 1:2:4 Diazo 0.5 60 2 Beta Naphthol 0.24 29 3 Caustic Flakes 0.36 44 4 Salicylic Acid 0.6 72 5 Basic Chrome Sulphate 0.23 28

4. Acid Blue 113:


1. Metanilic Acid 0.3 36 2 Hydrochloric Acid 0.24 29 3 Sodium Nitrite 0.25 30 4 Alpha Naphthyl Amine 0.23 28 5 Sulphuric Acid 0.25 30 6 Caustic Flakes 0.2 24 7 Phenyl Peri Acid 0.49 59 8 Soda Ash 0.2 24 9 Sodium Acetate 0.3 36

5. Acid Green 68:


1. Para Nitro Aniline 0.15 18 2 Hydrochloric Acid 0.25 30 3 Sodium Nitrite 0.2 25 4 H-Acid 0.31 38 5 Soda Ash 0.06 8 6 Diamino Sulphanilide 0.25 30 7 Caustic Flakes 0.21 26 8 Resorcinol 0.1 13

6. Acid Red 131 Sr.No. Name of Raw Material MT/MT MT/Month

1. H-Acid 0.4 48 2 Caustic Flakes 0.1 12 3 Soda Ash 0.1 12 4 Ether 0.226 27.2 5 Hydrochloric Acid 0.27 32.4 6 Sodium Nitrite 0.06 7.2 7 Caustic Flakes 0.07 8.4

7. Acid Yellow 36

Sr.No. Name of Raw Material MT/MT MT/Month 1. Metanilic Acid 0.48 57.6 2 Soda Ash 0.39 46.8 3 Sodium Nitrite 0.19 22.8 4 Diphenyl Amine 0.46 55.2 5 Caustic Flakes 0.25 30 6 Emulsifier 0.06 7.2 7 Salt 1.27 152.4

1. Acid Black 210 (75MT/Month):

Sr.No. Name of Raw Material MT/MT MT/Month 1 Hydrochloric Acid 0.36 44 2 Para nitro aniline 0.075 9 3 Sodium Nitrite 0.27 33 4 Caustic flackes 0.025 3 5 H-Acid 0.15 19 6 Diamino Sulphanilide 0.12 15 7 Meta Phynelene diamine 0.05 6

2. Acid Violet 90 (75MT/Month):

Sr.No. Name of Raw Material MT/MT MT/Month 1 1 Diazo 0.24 29 2 PMP (1 Phenyl 3 Methyl 5

Pyrazolone) 0.18 22

3 Caustic Flakes 0.1 12 4 Salicylic Acid 0.05 6 5 Basic Chrome Sulphate 0.17 21

Group 3. Direct Dyes:

1. Direct Black 22:

Sr.No. Name of Raw Material MT/MT MT/Month 1. F.C.Acid 0.18 22 2 Sodium Nitrite 0.47 57 3 Gamma Acid 0.29 35 4 Caustic 0.06 7 5 Soda Ash 0.29 35 6 Hydrochloric Acid 0.5 60

2. Direct Red 31:


1. Rhoduline Acid 0.14 17 2 Soda Ash 0.13 16 3 Hydrochloric Acid 0.08 10 4 Aniline 0.08 10 5 HMP 0.025 3 6 EDTA (Ethylene Diamine

tetra acetic acid) 0.002 0.24

3. Direct Orange 39:


1. PAPSA (4-Amino phenol 2 – sulphonic acid)

0.25 30


0.26 32

3. Caustic Flackes 0.1 12 4. Hydrochloric Acid 0.2 24

4. Direct Yellow 86:

Sr.No. Name of Raw Material MT/MT MT/Month 1. C-Acid 0.24 29 2. Hydrochloric Acid 0.15 18 3. Sodium Nitrite 0.05 7 4. Meta Toluidine 0.09 11 5. Soda Ash 0.09 11 6. Cyanuric Chloride 0.15 18 7. Caustic Lye 0.08 10 8. Diethyl aniline 0.1 12

5. Direct Yellow 11:


1. Pentothenic Acid 0.16 20 2. Caustic flackes 0.13 16 3. Tri-n-butyl amine 0.1 12 4. Diethyl Aniline 0.13 16

6. Direct Violet 9:


1. MXO 0.4 48 2. Soda ash 0.36 43.2 3. Nitrate 0.14 16.8 4. Polycabonate 0.3 36 5. Hydrochloric Acid 1.1 132 6. Phenyl J Acid 0.6 72

7. Direct Blue 86:


1. Chloro Sulphonic Acid 0.5 60 2. Copper Pthalocyamine 0.15 18 3. Salt 0.4 48 4. Sodium Hydroxide 0.1 12 5. Ice 1.5 180

8. Direct Blue FF:

Sr.No. Name of Raw Material MT/MT MT/Month 1. Blue B Base 0.13 16 2. Sodium Nitrite 0.1 12 3. H-Acid 0.4 48 4. Soda Ash 0.2 24

Group5. Solvent Dyes:

1. Solvent Blue 36:

Sr.No. Name of Raw Material MT/MT MT/Month 1. Quinizarine 0.75 90 2. Methanol 0.052 6.24 3. N-Isopropylamine 0.37 45

2. Solvent Red 24:


1 Fast Garnet GBC Base 0.16 20 2 Hydrochloric Acid 0.26 32 3 Sodium Nitrite 0.05 6

3. Solvent Yellow 33:


1. Quinaldine 0.54 65 2. Phthalic An hydride 0.58 70 3. Ortho Di Chloro Benzene 0.05 6.0 4. Methanol 0.04 4.8

4. Solvent Green 3:


1. Butanol 0.12 14.4 2. Quinizarint 0.66 80 3. P-Toluene 0.35 42

Group6. Food Colors:

1. Sunset Yellow:

Sr.No. Name of Raw Material MT/MT MT/Month 1 Sulphanic Acid 0.39 47 2 Hydrochloric Acid 0.16 20 3 Sodium Nitrite 0.15 19 4 Schaffer’s Acid 0.5 60 5 Sodium Carbonate 0.24 29

2. Chocolate Brown:


1 Sodium Naphthonate 0.35 42 2 Hydrochloric Acid 0.11 14 3 Sodium Nitrite 0.1 13 4 Resorcinol 0.17 21 5 Sodium Hydroxide 0.25 30 6 Formnaldehyde 0.05 6 7 Salt 0.11 14

3. Ponceau 4R:

Sr.No. Nmae of Raw Material MT/MT MT/Month

1 Sodium Napthonate 0.36 44 2 Hydrochloric Acid 0.12 15 3 Sodium Nitrite 0.11 14 4 G-Salt 0.51 61 5 Sodium Carbonate 0.35 43

4. Tartraine:


1 Suphanilic Acid 0.44 53 2 Hydrochloric Acid 0.19 23 3 Sodium Nitrite 0.016 21 4 DMAS (Di methyl

acetylsaccinate) 0.45 54

5 Sodium Carbonate 0.28 33

Group7. Disperse Dyes:

1. Disperse Blue 366:

Sr.No. Name of Raw Material MT/MT MT/Month 1 Hydrochloric Acid 2 60 2 PCONA (Para chloro ortho

nitro aniline) 1

30 3 Sodium Nitrite 0.4 12 4 Sodium Acetate 2.3 69 5 Aulfamic Acid 0.01 0.3 6 Catalytic Acid 0.02 0.6 7 Acetic Acid 0.1 3 8 Dytol DF 0.9 27 9 Kiri Mol 4 120

10 Ant Dusting Oil 0.02 0.6

2. Disperse Orange 25:

Sr.No. Nmae of Raw Material MT/MT MT/Month 1 Hydrochloric Acid 0.4 13.2 2 Para Nitro Aniline 0.20 6.0 3 Sodium Nitrite 0.106 3.18 4 CO 0.01 0.3 5 KD 0.25 7.7 6 Sulfuric Acid 0.006 0.2 7 Sodium Acetate 0.4 12 8 Acetic Acid 0.010 0.32 9 Dytol DF 0.24 7.2

10 Kiri Mol 0.9 29.3

3. Disperse Yellow 211:

Sr.No. Name of Raw Material MT/MT MT/Month 1. PCONA (Para chloro ortho

nitro aniline) 0.26

8 2. Hydrochloric Acid 0.38 12 3. Sodium Nitrite 0.11 4 4. EP 0.26 8 5. Sodium Acetate 0.59 18 6. Sulfamic Acid 0.005 0.2 7. Catalytic Agent 0.003 0.1 8. Acetic Acid 0.01 0.3 9. Dytol DF 0.23 7

10. Kiri Mol 0.89 27 11. Anti Dusting Oil 0.005 0.2

4. Disperse Blue 79:


1. DNBrPNA 0.35 10.5 2. Napthalene Sulphonic Acid 0.37 11.1 3. Meta amino acetanilide 0.39 11.7 4. Caustic Soda Lye 0.13 3.9 5. Dispersing Agent 0.7 21

Overall Raw Material Consumption:

Sr.No. Name of Raw Material CAS No. MT/Month

1. MPD (Meta Phynelene diamine) 107-41-5 42 2. Hydrochloric Acid(Hydrochloric Acid) 7647-01-0 330 3. Sodium Cyanate 917-61-3 27 4. Aniline 62-53-3 20 5. Formaldehyde 50-00-0 12 6. Sodium Bi Sulphite 7681-38-1 195 7. Sulphuric Acid 7664-93-9 248 8. Sodium Nitrite 7632-00-0 532 9. Benzene 71-43-2 4.05 10. Di Ethyl Oxalate 95-92-1 53 11. Ethyl Acetate 141-78-6 34 12. PAPSA (4- amino phenol-2- sulphonic

acid) 98-37-3 88

13. Caustic Lye/Flakes 1310-73-2 190 14. Sodium Metal 7440-23-5 6 15. ODCB(Ortho DiChloro Benzene) 95-50-1 6.0 16. ANA (Alpha Naphthyl Amine) 134-32-7 103 17. Soda Ash/Sodium Carbonate 497-19-8 655.8 18. Naphthenic Acid 1338-24-5 101 19. Para Nitro Aniline (PNA) 100-01-6 64.0 20. Acetanilide 1338-24-5 39 21. Chloro Sulphonic Acid (CSA) 7790-94-5 454 22. Iron Powder ------ 93 23. Sodium Hydroxide 1310-73-2 53 24. Spent Acid ------ 150 25. PNCBOSA (2- Chloro 5- Nitro Benzene

Sulfonic Acid) 96-73-1 64

26. Vinyl Sulphone 77-77-0 453 27. Oleum Acid 8014-95-7 283.5 28. Potassium Chloride 7447-40-7 35 29. Acetyl Ortho Ansidine 90-04-0 54 30. Ethylene Oxide 75-21-8 44 31. Beta Naphthol 135-19-3 66.5 32. Sodium Sulphate 7757-82-6 238.5 33. Ammonia 1336-21-6 337 34. Sodium Bicarbonate 144-55-8 357

Sr.No. Name of Raw Material CAS No. MT/Month 35. Acetic Acid 64-19-7 13 36. Cyanuric Chloride 108-77-0 230 37. SPVS (Sulpho Para Vinyl Sulphone) 42986-22-1 30 38. J-Acid 87-02-5 34 39. MPDSA (Meta Phynelene diamine

sulphonic acid) 88-63-1 81

40. Reactive Black B 17095-24-8 42 41. Salt 7647-14-5 210 42. H-Acid 5460-09-3 339 43. MBVS (Meta Base Vinyl Sulphone) ----- 24 44. Sulpho Tobias Acid 117-62-4 120 45. Sulphanilic Acid 121-57-3 72 46. K-Acid 130-23-4 85 47. Meta Ureido aniline) 73130-21-9 34 48. Ammonium Hydroxide 1336-21-6 48 49. Acetic Anhydride 108-24-7 64 50. NMJ Acid 22346-43-6 36 51. Sulphamic Acid 5329-14-9 48 52. Octanol 111-87-5 3 53. Copper Sulphate 7758-99-8 52 54. Sodium Acetate 127-09-3 303 55. Hydrogen Peroxide 7722-84-1 65 56. SPCP (Sulpho para carboxy pyrazole) 118-47-8 75 57. DASDA (Diamino Stibene di sulphonic

acid) 81-11-8 46

58. 2-Pyridine 1121-60-4 22 59. CPC Blue (Copper Phthalo Cyanine

blue) 147-14-8 84

60. Phosphorus Tri Chloride 7719-12-2 22 61. Salicylic Acid 69-72-7 84 62. Basic Chrome Sulphate 10101-53-8 91 63. Resorcinol 108-46-3 48 64. Metanilic Acid 121-47-1 93.6 65. Phenyl Peri Acid(PPA) 82-76-8 59 66. Diamino Sulphonic Acid 16803-97-7 45 67. Polymethylpentene 89-25-8 22 68. F.C. Acid 119-70-0 22

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Sr.No. Name of Raw Material CAS No. MT/Month 69. Gamma Acid 90-51-7 35 70. Rhoduline Acid 87-03-6 17 71. Ethylene diamine tetraacetic acid 10378-23-1 0.3 72. C-Acid (2 - Chloro 5 - Toludine 4 -

Sulphonic acid) 88-53-9 29

73. Meta Toludine 108-44-1 11 74. Di Ethyl Amine 109-89-7 28 75. Pentothenic Acid ----- 20 76. TNBA (Tri N-Butyl Amine) 129-66-8 12 77. MXO ----- 24 78. Phenyl J Acid 119-40-4 36 79. Blue B Base 101-64-4 16 80. Quinizarine 81-64-1 170 81. Methanol 67-56-1 6.24 82. N-Isopropylamine 75-31-0 45 83. Fast Garnate GBC Base 97-56-3 20 84. Quinaldine 91-63-4 65 85. Phthalic Anhydride 85-44-9 70 86. Butanol 71-36-3 14.4 87. P-Toludine 106-49-0 42 88. Schffer’s Acid 93-01-6 60 89. Sodium Naphthionate 130-13-2 86 90. DMAS (Dimethyl acetyl saccinate) 10420-33-4 54 91. PCONA (Para chloro ortho nitro

aniline) 89-63-4 38

92. Ether 7578-39-4 27.2 93. Di Phenyl Amine 122-39-4 55.2 94. Emulsifier --- 7.2 95. Napthalene Sulphonic acid 85-47-2 11.1 96. Meta Amino acetanilide 621-35-2 11.7

* We will maintain as minimum inventory as possible.

Enclosure: 4 Material Safety Data Sheets of Products & Raw Materials

(Attached)

Specification – 1,4 SPCP

Product Name : 1:4 SPCP

Chemical Name : 1-(4-Sulpho Phenyl)-3-Carboxy-5-Pyrazolone

Molecular Weight : 284.25 Grams/Mole

CAS NO. : 118-47-8

Empirical Formula : C10H8N2O4S

Structural Formula :

COOH

N O

N

SO3H Purity by NV : Min. 90%

Insoluble matters : Max. 0.20%

Solubility : Soluble in dilute Alkaline Solution

Other impurities : < 0.5%

Heavy Metal Contents : 1. Lead as Pb : Max. 10ppm 2. Iron as Fe: Max. 20ppm 3. Mercury as Hg: Max.1ppm 4. Arsenic as As: Max. 1ppm

Physical Appearance : White to Pale Yellow Colored Powder

Basis of Sale : On 100% Real basis

Packing : 25/50kgs HDPE bags with PE liners inside

p. 1

2 2 0

He a lt h

Fire

Re a c t iv it y

Pe rs o n a lPro t e c t io n

2

2

0

H

Material Safety Data Sheet2-Pyridinecarboxaldehyde MSDS

Section 1: Chemical Product and Company Identification

Product Name: 2-Pyridinecarboxaldehyde

Catalog Codes: SLP4234

CAS#: 1121-60-4

RTECS: Not available.

TSCA: TSCA 8(b) inventory: 2-Pyridinecarboxaldehyde

CI#: Not available.

Synonym: Pyridine-2-Carbaldehyde; Picolinaldehyde

Chemical Name: 2-Pyridinecarboxaldehyde

Chemical Formula: C6-H5-N-O

Contact Information:

Sciencelab.com, Inc.14025 Smith Rd.Houston, Texas 77396

US Sales: 1-800-901-7247International Sales: 1-281-441-4400

Order Online: ScienceLab.com

CHEMTREC (24HR Emergency Telephone), call:1-800-424-9300

International CHEMTREC, call: 1-703-527-3887

For non-emergency assistance, call: 1-281-441-4400

Section 2: Composition and Information on Ingredients

Composition:

Name CAS # % byWeight

{2-}Pyridinecarboxaldehyde 1121-60-4 100

Toxicological Data on Ingredients: 2-Pyridinecarboxaldehyde LD50: Not available. LC50: Not available.

Section 3: Hazards Identification

Potential Acute Health Effects:Hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, of inhalation (lung irritant). Slightly hazardousin case of skin contact (permeator).

Potential Chronic Health Effects:CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available.DEVELOPMENTAL TOXICITY: Not available. Repeated or prolonged exposure is not known to aggravate medical condition.

Section 4: First Aid Measures

Eye Contact:Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15minutes. Cold water may be used. Get medical attention.

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Skin Contact:In case of contact, immediately flush skin with plenty of water. Cover the irritated skin with an emollient. Remove contaminatedclothing and shoes. Cold water may be used.Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medicalattention.

Serious Skin Contact:Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek immediate medicalattention.

Inhalation:If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medicalattention.

Serious Inhalation:Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or waistband. Ifbreathing is difficult, administer oxygen. If the victim is not breathing, perform mouth-to-mouth resuscitation. Seek medicalattention.

Ingestion:Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconsciousperson. If large quantities of this material are swallowed, call a physician immediately. Loosen tight clothing such as a collar,tie, belt or waistband.

Serious Ingestion: Not available.

Section 5: Fire and Explosion Data

Flammability of the Product: Flammable.

Auto-Ignition Temperature: Not available.

Flash Points: CLOSED CUP: 54°C (129.2°F).

Flammable Limits: Not available.

Products of Combustion: These products are carbon oxides (CO, CO2), nitrogen oxides (NO, NO2...).

Fire Hazards in Presence of Various Substances: Flammable in presence of open flames and sparks, of heat.

Explosion Hazards in Presence of Various Substances:Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the product inpresence of static discharge: Not available.

Fire Fighting Media and Instructions:Flammable liquid, soluble or dispersed in water. SMALL FIRE: Use DRY chemical powder. LARGE FIRE: Use alcohol foam,water spray or fog. Cool containing vessels with water jet in order to prevent pressure build-up, autoignition or explosion.

Special Remarks on Fire Hazards: Not available.

Special Remarks on Explosion Hazards: Not available.

Section 6: Accidental Release Measures

Small Spill:Dilute with water and mop up, or absorb with an inert dry material and place in an appropriate waste disposal container.

Large Spill:Flammable liquid. Keep away from heat. Keep away from sources of ignition. Stop leak if without risk. Absorb with DRY earth,sand or other non-combustible material. Do not touch spilled material. Prevent entry into sewers, basements or confinedareas; dike if needed.

Section 7: Handling and Storage

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Precautions:Keep away from heat. Keep away from sources of ignition. Ground all equipment containing material. Do not ingest. Do notbreathe gas/fumes/ vapor/spray. Wear suitable protective clothing. In case of insufficient ventilation, wear suitable respiratoryequipment. If ingested, seek medical advice immediately and show the container or the label. Avoid contact with skin andeyes. Keep away from incompatibles such as oxidizing agents, reducing agents, acids, alkalis.

Storage:Store in a segregated and approved area. Keep container in a cool, well-ventilated area. Keep container tightly closed andsealed until ready for use. Avoid all possible sources of ignition (spark or flame).

Section 8: Exposure Controls/Personal Protection

Engineering Controls:Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respectivethreshold limit value. Ensure that eyewash stations and safety showers are proximal to the work-station location.

Personal Protection:Splash goggles. Lab coat. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Gloves.

Personal Protection in Case of a Large Spill:Splash goggles. Full suit. Vapor respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoidinhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling thisproduct.

Exposure Limits: Not available.

Section 9: Physical and Chemical Properties

Physical state and appearance: Liquid.

Odor: Not available.

Taste: Not available.

Molecular Weight: 107.11 g/mole

Color: Clear Brown.

pH (1% soln/water): Not available.

Boiling Point: 181°C (357.8°F) @ 760 mm Hg

Melting Point: -21°C (-5.8°F)

Critical Temperature: Not available.

Specific Gravity: Not available.

Vapor Pressure: Not available.

Vapor Density: Not available.

Volatility: Not available.

Odor Threshold: Not available.

Water/Oil Dist. Coeff.: Not available.

Ionicity (in Water): Not available.

Dispersion Properties: See solubility in water.

Solubility: Soluble in cold water, hot water.

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Section 10: Stability and Reactivity Data

Stability: The product is stable.

Instability Temperature: Not available.

Conditions of Instability: Heat, Ingition sources, incompatible materials

Incompatibility with various substances: Reactive with oxidizing agents, reducing agents, acids, alkalis.

Corrosivity: Not available.

Special Remarks on Reactivity: Not available.

Special Remarks on Corrosivity: Not available.

Polymerization: Not available.

Section 11: Toxicological Information

Routes of Entry: Absorbed through skin. Eye contact.

Toxicity to Animals:LD50: Not available. LC50: Not available.

Chronic Effects on Humans: Not available.

Other Toxic Effects on Humans:Hazardous in case of skin contact (irritant), of ingestion, of inhalation (lung irritant). Slightly hazardous in case of skin contact(permeator).

Special Remarks on Toxicity to Animals: Not available.

Special Remarks on Chronic Effects on Humans: Not available.

Special Remarks on other Toxic Effects on Humans:Acute Potential Health Effects: Skin: Causes skin irritation. Eyes: Causes eye irritation. Inhalation: Causes respiratorytract irritation. Ingestion: May be harmful if swallowed. The toxicological properties of this substance have not been fullyinvestigated.

Section 12: Ecological Information

Ecotoxicity: Not available.

BOD5 and COD: Not available.

Products of Biodegradation:Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.

Toxicity of the Products of Biodegradation: The products of degradation are less toxic than the product itself.

Special Remarks on the Products of Biodegradation: Not available.

Section 13: Disposal Considerations

Waste Disposal:Waste must be disposed of in accordance with federal, state and local environmental control regulations.

Section 14: Transport Information

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DOT Classification: CLASS 3: Flammable liquid.

Identification: : Aldehyde, n.o.s. (Picolinaldehyde) UNNA: 1989 PG: III

Special Provisions for Transport: Not available.

Section 15: Other Regulatory Information

Federal and State Regulations:TSCA 8(b) inventory: 2-Pyridinecarboxaldehyde TSCA 8(a) PAIR: 2-Pyridinecarboxaldehyde TSCA 8(d) H and S datareporting: 2-Pyridinecarboxaldehyde: Effective data: 9/30/91; Sunset date: 12/19/95

Other Regulations:OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200). EINECS: This product is on theEuropean Inventory of Existing Commercial Chemical Substances.

Other Classifications:

WHMIS (Canada):CLASS B-3: Combustible liquid with a flash point between 37.8°C (100°F) and 93.3°C (200°F). CLASS D-2B: Material causingother toxic effects (TOXIC).

DSCL (EEC):R10- Flammable. R22- Harmful if swallowed. R36/37/38- Irritating to eyes, respiratory system and skin. S16- Keep away fromsources of ignition - No smoking. S26- In case of contact with eyes, rinse immediately with plenty of water and seek medicaladvice. S36/39- Wear suitable protective clothing and eye/face protection.

HMIS (U.S.A.):

Health Hazard: 2

Fire Hazard: 2

Reactivity: 0

Personal Protection: h

National Fire Protection Association (U.S.A.):

Health: 2

Flammability: 2

Reactivity: 0

Specific hazard:

Protective Equipment:Gloves. Lab coat. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Wear appropriate respiratorwhen ventilation is inadequate. Splash goggles.

Section 16: Other Information

References: Not available.

Other Special Considerations: Not available.

Created: 10/09/2005 06:14 PM

Last Updated: 05/21/2013 12:00 PM

The information above is believed to be accurate and represents the best information currently available to us. However, wemake no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume

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no liability resulting from its use. Users should make their own investigations to determine the suitability of the information fortheir particular purposes. In no event shall ScienceLab.com be liable for any claims, losses, or damages of any third party or forlost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if ScienceLab.comhas been advised of the possibility of such damages.

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Material Safety Data SheetAcetic acid MSDS


Product Name: Acetic acid

Catalog Codes: SLA3784, SLA1438, SLA2101, SLA3604,SLA1258

CAS#: 64-19-7

RTECS: AF1225000

TSCA: TSCA 8(b) inventory: Acetic acid

CI#: Not applicable.

Synonym: Acetic acid; glacial acetic acid

Chemical Name: Acetic Acid, Glacial

Chemical Formula: C2-H4-O2









Composition:

Name CAS # % by Weight

Acetic acid 64-19-7 100

Toxicological Data on Ingredients: Acetic acid: ORAL (LD50): Acute: 3310 mg/kg [Rat]. 4960 mg/kg [Mouse]. 3530 mg/kg[Rat]. DERMAL (LD50): Acute: 1060 mg/kg [Rabbit]. VAPOR (LC50): Acute: 5620 ppm 1 hours [Mouse].


Potential Acute Health Effects:Very hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, of inhalation. Hazardous in case of skincontact (corrosive, permeator), of eye contact (corrosive). Liquid or spray mist may produce tissue damage particularly onmucous membranes of eyes, mouth and respiratory tract. Skin contact may produce burns. Inhalation of the spray mist mayproduce severe irritation of respiratory tract, characterized by coughing, choking, or shortness of breath. Inflammation of theeye is characterized by redness, watering, and itching. Skin inflammation is characterized by itching, scaling, reddening, or,occasionally, blistering.

Potential Chronic Health Effects:Hazardous in case of skin contact (irritant), of ingestion, of inhalation. CARCINOGENIC EFFECTS: Not available.MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells. Mutagenic for bacteria and/or yeast. TERATOGENICEFFECTS: Not available. DEVELOPMENTAL TOXICITY: Not available. The substance may be toxic to kidneys, mucousmembranes, skin, teeth. Repeated or prolonged exposure to the substance can produce target organs damage. Repeated


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or prolonged contact with spray mist may produce chronic eye irritation and severe skin irritation. Repeated or prolongedexposure to spray mist may produce respiratory tract irritation leading to frequent attacks of bronchial infection.


Eye Contact:Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15minutes. Cold water may be used. Get medical attention immediately.

Skin Contact:In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothingand shoes. Cover the irritated skin with an emollient. Cold water may be used.Wash clothing before reuse. Thoroughly cleanshoes before reuse. Get medical attention immediately.


Inhalation:If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medicalattention immediately.

Serious Inhalation:Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or waistband. Ifbreathing is difficult, administer oxygen. If the victim is not breathing, perform mouth-to-mouth resuscitation. WARNING: It maybe hazardous to the person providing aid to give mouth-to-mouth resuscitation when the inhaled material is toxic, infectious orcorrosive. Seek immediate medical attention.

Ingestion:Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconsciousperson. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention if symptoms appear.




Auto-Ignition Temperature: 463°C (865.4°F)

Flash Points: CLOSED CUP: 39°C (102.2°F). OPEN CUP: 43°C (109.4°F).

Flammable Limits: LOWER: 4% UPPER: 19.9%

Products of Combustion: These products are carbon oxides (CO, CO2).

Fire Hazards in Presence of Various Substances:Flammable in presence of open flames and sparks, of heat. Slightly flammable to flammable in presence of oxidizingmaterials, of metals.

Explosion Hazards in Presence of Various Substances:Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the product inpresence of static discharge: Not available. Slightly explosive in presence of oxidizing materials.


Special Remarks on Fire Hazards:Reacts with metals to produces flammable hydrogen gas. It will ignite on contact with potassium-tert-butoxide. A mixture ofammonium nitrate and acetic acid ignites when warmed, especially if warmed.

Special Remarks on Explosion Hazards:

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Acetic acid vapors may form explosive mixtures with air. Reactions between acetic acid and the following materialsare potentially explosive: 5-azidotetrazole, bromine pentafluoride, chromium trioxide, hydrogen peroxide, potassiumpermanganate, sodium peroxide, and phorphorus trichloride. Dilute acetic acid and dilute hydrogen can undergo anexothermic reaction if heated, forming peracetic acid which is explosive at 110 degrees C. Reaction between chlorinetrifluoride and acetic acid is very violent, sometimes explosive.


Small Spill:Dilute with water and mop up, or absorb with an inert dry material and place in an appropriate waste disposal container. Ifnecessary: Neutralize the residue with a dilute solution of sodium carbonate.

Large Spill:Flammable liquid. Corrosive liquid. Keep away from heat. Keep away from sources of ignition. Stop leak if without risk. If theproduct is in its solid form: Use a shovel to put the material into a convenient waste disposal container. If the product is inits liquid form: Absorb with DRY earth, sand or other non-combustible material. Do not get water inside container. Absorbwith an inert material and put the spilled material in an appropriate waste disposal. Do not touch spilled material. Use waterspray curtain to divert vapor drift. Prevent entry into sewers, basements or confined areas; dike if needed. Call for assistanceon disposal. Neutralize the residue with a dilute solution of sodium carbonate. Be careful that the product is not present at aconcentration level above TLV. Check TLV on the MSDS and with local authorities.


Precautions:\Keep away from heat. Keep away from sources of ignition. Ground all equipment containing material. Do not ingest. Do notbreathe gas/fumes/ vapor/spray. Never add water to this product. In case of insufficient ventilation, wear suitable respiratoryequipment. If ingested, seek medical advice immediately and show the container or the label. Avoid contact with skin andeyes. Keep away from incompatibles such as oxidizing agents, reducing agents, metals, acids, alkalis.




Personal Protection:Splash goggles. Synthetic apron. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Gloves(impervious).


Exposure Limits:TWA: 10 STEL: 15 (ppm) [Australia] TWA: 25 STEL: 27 (mg/m3) [Australia] TWA: 10 STEL: 15 (ppm) from NIOSH TWA: 25STEL: 37 (mg/m3) from NIOSH TWA: 10 STEL: 15 (ppm) [Canada] TWA: 26 STEL: 39 (mg/m3) [Canada] TWA: 25 STEL: 37(mg/m3) TWA: 10 STEL: 15 (ppm) from ACGIH (TLV) [United States] [1999] TWA: 10 (ppm) from OSHA (PEL) [United States]TWA: 25 (mg/m3) from OSHA (PEL) [United States]Consult local authorities for acceptable exposure limits.


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Odor: Pungent, vinegar-like, sour (Strong.)

Taste: Vinegar, sour (Strong.)


Color: Colorless. Clear (Light.)

pH (1% soln/water): 2 [Acidic.]

Boiling Point: 118.1°C (244.6°F)

Melting Point: 16.6°C (61.9°F)

Critical Temperature: 321.67°C (611°F)

Specific Gravity: 1.049 (Water = 1)

Vapor Pressure: 1.5 kPa (@ 20°C)

Vapor Density: 2.07 (Air = 1)


Odor Threshold: 0.48 ppm

Water/Oil Dist. Coeff.: The product is more soluble in water; log(oil/water) = -0.2


Dispersion Properties: See solubility in water, diethyl ether, acetone.

Solubility:Easily soluble in cold water, hot water. Soluble in diethyl ether, acetone. Miscible with Glycerol, alcohol, Benzene, CarbonTetrachloride. Practically insoluble in Carbon Disulfide.




Conditions of Instability: Heat, ignition sources, incompatible materials

Incompatibility with various substances: Reactive with oxidizing agents, reducing agents, metals, acids, alkalis.

Corrosivity:Highly corrosive in presence of stainless steel(304). Slightly corrosive in presence of aluminum, of copper. Non-corrosive inpresence of stainless steel(316).

Special Remarks on Reactivity:Reacts violently with strong oxidizing agents, acetaldehyde, and acetic anhydride. Material can react with metals, strongbases, amines, carbonates, hydroxides, phosphates, many oxides,cyanides, sulfides, chromic acid, nitric acid, hydrogenperoxide, carbonates. ammonium nitrate, ammonium thiosulfate, chlorine trifluoride, chlorosulfonic acid, perchloric acid,permanganates, xylene, oleum, potassium hydroxide, sodium hydroxide, phosphorus isocyanate, ethylenediamine, ethyleneimine.

Special Remarks on Corrosivity: Moderate corrosive effect on bronze. No corrosion data on brass

Polymerization: Will not occur.


Routes of Entry: Absorbed through skin. Dermal contact. Eye contact. Inhalation. Ingestion.

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Toxicity to Animals:WARNING: THE LC50 VALUES HEREUNDER ARE ESTIMATED ON THE BASIS OF A 4-HOUR EXPOSURE. Acute oraltoxicity (LD50): 3310 mg/kg [Rat]. Acute dermal toxicity (LD50): 1060 mg/kg [Rabbit]. Acute toxicity of the vapor (LC50): 56201 hours [Mouse].

Chronic Effects on Humans:MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells. Mutagenic for bacteria and/or yeast. May cause damage tothe following organs: kidneys, mucous membranes, skin, teeth.

Other Toxic Effects on Humans:Extremely hazardous in case of inhalation (lung corrosive). Very hazardous in case of skin contact (irritant), of ingestion, .Hazardous in case of skin contact (corrosive, permeator), of eye contact (corrosive).


Special Remarks on Chronic Effects on Humans: May affect genetic material and may cause reproductive effects based onanimal data. No human data found.

Special Remarks on other Toxic Effects on Humans:Acute Potential Health Effects: Skin: Extremely irritating and corrosive. Causes skin irritation (reddening and itching,inflammation). May cause blistering , tissue damage and burns. Eyes: Extremely irritating and corrosive. Causes eye irritation,lacrimation, redness, and pain. May cause burns, blurred vision, conjunctivitis, conjunctival and corneal destruction andpermanent injury. Inhalation: Causes severe respiratory tract irritation. Affects the sense organs (nose, ear, eye, taste),and blood. May cause chemical pneumonitis, bronchitis, and pulmonary edema. Severe exposure may result in lung tissuedamage and corrosion (ulceration) of the mucous membranes. Inhalation may also cause rhinitis, sneezing, coughing,oppressive feeling in the chest or chest pain, dyspnea, wheezing, tachypnea, cyanosis, salivation, nausea, giddiness,muscular weakness. Ingestion: Moderately toxic. Corrosive. Causes gastrointestinal tract irritation (burning and pain of themouth, throat, and abdomen, coughing, ulceration, bleeding, nausea, abdomial spasms, vomiting, hematemesis, diarrhea.May Also affect the liver (impaired liver function), behavior (convulsions, giddines, muscular weakness), and the urinarysystem - kidneys (Hematuria, Albuminuria, Nephrosis, acute renal failure, acute tubular necrosis). May also cause dyspneaor asphyxia. May also lead to shock, coma and death. Chronic Potential Health Effects: Chronic exposure via ingestion maycause blackening or erosion of the teeth and jaw necrosis, pharyngitis, and gastritis. It may also behavior (similar to acuteingestion), and metabolism (weight loss). Chronic exposure via inhalation may cause asthma and/or bronchitis with cough,phlegm, and/or shortness of breath . It may also affect the blood (decreased leukocyte count), and urinary system (kidneys).Repeated or prolonged skin contact may cause thickening, blackening, and cracking of the skin.


Ecotoxicity:Ecotoxicity in water (LC50): 423 mg/l 24 hours [Fish (Goldfish)]. 88 ppm 96 hours [Fish (fathead minnow)]. 75 ppm 96 hours[Fish (bluegill sunfish)]. >100 ppm 96 hours [Daphnia].

BOD5 and COD: BOD-5: 0.34-0.88 g oxygen/g







DOT Classification:

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CLASS 3: Flammable liquid. Class 8: Corrosive material

Identification: : Acetic Acid, Glacial UNNA: 2789 PG: II



Federal and State Regulations:New York release reporting list: Acetic acid Rhode Island RTK hazardous substances: Acetic acid Pennsylvania RTK: Aceticacid Florida: Acetic acid Minnesota: Acetic acid Massachusetts RTK: Acetic acid New Jersey: Acetic acid California Director'sList of Hazardous Subtances (8 CCR 339): Acetic acid TSCA 8(b) inventory: Acetic acid CERCLA: Hazardous substances.:Acetic acid: 5000 lbs. (2268 kg)



WHMIS (Canada):CLASS B-3: Combustible liquid with a flash point between 37.8°C (100°F) and 93.3°C (200°F). CLASS E: Corrosive liquid.

DSCL (EEC):R10- Flammable. R35- Causes severe burns. S23- Do not breathe gas/fumes/vapour/spray [***] S26- In case of contact witheyes, rinse immediately with plenty of water and seek medical advice. S45- In case of accident or if you feel unwell, seekmedical advice immediately (show the label where possible).

HMIS (U.S.A.):

Health Hazard: 3

Fire Hazard: 2

Reactivity: 0

Personal Protection: H


Health: 3

Flammability: 2

Reactivity: 0

Specific hazard:

Protective Equipment:Gloves (impervious). Synthetic apron. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Wearappropriate respirator when ventilation is inadequate. Splash goggles.




Created: 10/09/2005 03:35 PM

Last Updated: 05/21/2013 12:00 PM


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Material Safety Data SheetAcetic anhydride MSDS


Product Name: Acetic anhydride

Catalog Codes: SLA1693

CAS#: 108-24-7

RTECS: AK1925000

TSCA: TSCA 8(b) inventory: Acetic anhydride

CI#: Not available.

Synonym:

Chemical Formula: (CH3CO)2)









Composition:


Acetic anhydride 108-24-7 100

Toxicological Data on Ingredients: Acetic anhydride: ORAL (LD50): Acute: 1780 mg/kg [Rat]. DERMAL (LD50): Acute: 4000mg/kg [Rabbit].


Potential Acute Health Effects:Extremely hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, of inhalation. Very hazardous incase of skin contact (corrosive). Hazardous in case of skin contact (permeator). Liquid or spray mist may produce tissuedamage particularly on mucous membranes of eyes, mouth and respiratory tract. Skin contact may produce burns. Inhalationof the spray mist may produce severe irritation of respiratory tract, characterized by coughing, choking, or shortness of breath.Inflammation of the eye is characterized by redness, watering, and itching. Skin inflammation is characterized by itching,scaling, reddening, or, occasionally, blistering.

Potential Chronic Health Effects:CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available.DEVELOPMENTAL TOXICITY: Not available. The substance is toxic to lungs, mucous membranes. Repeated or prolongedexposure to the substance can produce target organs damage. Repeated or prolonged contact with spray mist may producechronic eye irritation and severe skin irritation. Repeated or prolonged exposure to spray mist may produce respiratory tractirritation leading to frequent attacks of bronchial infection.


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Eye Contact:Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15minutes. Get medical attention immediately.

Skin Contact:In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothingand shoes. Cover the irritated skin with an emollient. Wash clothing before reuse. Thoroughly clean shoes before reuse. Getmedical attention immediately.










Flammable Limits: LOWER: 2.7% UPPER: 10.3%


Fire Hazards in Presence of Various Substances: Flammable in presence of heat.


Fire Fighting Media and Instructions:Flammable liquid. SMALL FIRE: Use DRY chemical powder. LARGE FIRE: Use alcohol foam, water spray or fog. Coolcontaining vessels with water jet in order to prevent pressure build-up, autoignition or explosion.




Small Spill: Absorb with an inert material and put the spilled material in an appropriate waste disposal.

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Large Spill:Flammable liquid. Corrosive liquid. Keep away from heat. Keep away from sources of ignition. Stop leak if without risk. Absorbwith DRY earth, sand or other non-combustible material. Do not get water inside container. Do not touch spilled material.Use water spray curtain to divert vapor drift. Prevent entry into sewers, basements or confined areas; dike if needed. Callfor assistance on disposal. Be careful that the product is not present at a concentration level above TLV. Check TLV on theMSDS and with local authorities.


Precautions:Keep container dry. Keep away from heat. Keep away from sources of ignition. Ground all equipment containing material.Do not ingest. Do not breathe gas/fumes/ vapor/spray. Never add water to this product. In case of insufficient ventilation,wear suitable respiratory equipment. If ingested, seek medical advice immediately and show the container or the label. Avoidcontact with skin and eyes.




Personal Protection:Face shield. Full suit. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Gloves. Boots.


Exposure Limits:TWA: 5 TWA: 20 Consult local authorities for acceptable exposure limits.



Odor: Strong.

Taste: Strong.


Color: Light.



Melting Point: -73.1 (-99.6°F)





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Dispersion Properties: Not available.

Solubility: Not available.




Conditions of Instability: Not available.

Incompatibility with various substances: Not available.






Routes of Entry: Dermal contact. Eye contact. Inhalation. Ingestion.

Toxicity to Animals:WARNING: THE LC50 VALUES HEREUNDER ARE ESTIMATED ON THE BASIS OF A 4-HOUR EXPOSURE. Acute oraltoxicity (LD50): 1780 mg/kg [Rat]. Acute dermal toxicity (LD50): 4000 mg/kg [Rabbit]. Acute toxicity of the vapor (LC50): 10004 hours [Rat].

Chronic Effects on Humans: Causes damage to the following organs: lungs, mucous membranes.

Other Toxic Effects on Humans:Extremely hazardous in case of skin contact (irritant), of ingestion, . Very hazardous in case of skin contact (corrosive).Hazardous in case of skin contact (permeator), of eye contact (corrosive), of inhalation (lung corrosive).



Special Remarks on other Toxic Effects on Humans: Not available.







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Waste Disposal:


DOT Classification: Class 8: Corrosive material

Identification: : Acetic Anhydride UNNA: UN1715 PG: II



Federal and State Regulations:Pennsylvania RTK: Acetic anhydride Massachusetts RTK: Acetic anhydride TSCA 8(b) inventory: Acetic anhydride CERCLA:Hazardous substances.: Acetic anhydride

Other Regulations: OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).


WHMIS (Canada):CLASS B-3: Combustible liquid with a flash point between 37.8°C (100°F) and 93.3°C (200°F). CLASS E: Corrosive liquid.

DSCL (EEC):R10- Flammable. R20/22- Harmful by inhalation and if swallowed. R34- Causes burns.

HMIS (U.S.A.):

Health Hazard: 3

Fire Hazard: 2

Reactivity: 0

Personal Protection:


Health: 3

Flammability: 2

Reactivity: 1

Specific hazard:

Protective Equipment:Gloves. Full suit. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Wear appropriate respiratorwhen ventilation is inadequate. Face shield.




Created: 10/10/2005 08:13 PM

Last Updated: 05/21/2013 12:00 PM


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Material Safety Data SheetN,N-Dimethyl-1-naphthylamine MSDS


Product Name: N,N-Dimethyl-1-naphthylamine

Catalog Codes: SLD3067

CAS#: 86-56-6

RTECS: QM2825000

TSCA: TSCA 8(b) inventory: N,N-Dimethyl-1-naphthylamine

CI#: Not available.

Synonym: 1-Dimethylaminonaphthalene; 1-Naphthaleneamine; N,N-dimethyl-Paphthylamine; alpha-Dimethylnaphthylamine; Naphthylamine, N,N-dimethyl

Chemical Name: N,N-Dimethyl-1-naphthylamine

Chemical Formula: C12-H13-N









Composition:

Name CAS # % byWeight

{N,N}-Dimethyl-1-naphthylamine 86-56-6 100

Toxicological Data on Ingredients: N,N-Dimethyl-1-naphthylamine LD50: Not available. LC50: Not available.


Potential Acute Health Effects: Hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, of inhalation.



Eye Contact:


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Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15minutes. Get medical attention.

Skin Contact:In case of contact, immediately flush skin with plenty of water. Cover the irritated skin with an emollient. Remove contaminatedclothing and shoes. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention.



Serious Inhalation: Not available.




Flammability of the Product: May be combustible at high temperature.





Fire Hazards in Presence of Various Substances: Slightly flammable to flammable in presence of heat.


Fire Fighting Media and Instructions:SMALL FIRE: Use DRY chemical powder. LARGE FIRE: Use water spray, fog or foam. Do not use water jet.





Large Spill:Absorb with an inert material and put the spilled material in an appropriate waste disposal. Finish cleaning by spreading wateron the contaminated surface and allow to evacuate through the sanitary system.


Precautions:Keep away from heat. Keep away from sources of ignition. Empty containers pose a fire risk, evaporate the residue under afume hood. Ground all equipment containing material. Do not ingest. Do not breathe gas/fumes/ vapor/spray. Wear suitable

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protective clothing. In case of insufficient ventilation, wear suitable respiratory equipment. If ingested, seek medical adviceimmediately and show the container or the label. Avoid contact with skin and eyes. Keep away from incompatibles such asoxidizing agents, moisture.

Storage:MOISTURE SENSITIVE. Keep container tightly closed. Keep container in a cool, well-ventilated area. Do not store above23°C (73.4°F).







Physical state and appearance: Liquid. (Clear)

Odor: Aromatic.



Color: very light yellow. (Light.)

pH (1% soln/water): Not applicable.


Melting Point: Not available.










Solubility: Insoluble in cold water.


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Conditions of Instability: Excess heat, incompatible materials (strong oxidizers)

Incompatibility with various substances: Reactive with oxidizing agents, moisture.


Special Remarks on Reactivity: MOISTURE SENSITIVE







Other Toxic Effects on Humans: Hazardous in case of skin contact (irritant), of ingestion, of inhalation.


Special Remarks on Chronic Effects on Humans:May affect genetic material (mutagenicity) based on animal studies. (RTECS: DNA damage: Intraperitoneal, mouse = 50 mg/kg). No human data found.

Special Remarks on other Toxic Effects on Humans:Acute Potential Health Effects: Skin: May cause skin irritation. Eye: May cause eye irritation. Inhalation: May causerespiratory tract irritation. May cause irritatioin of the mucous membranes. Ingestion: May cause gastrointestinal tract irritationwith nausea, vomiting, and diarrhea. May be harmful if swallowed. Chronic Potential Health Effects: no data found. Thetoxicological properties of this substance have not been fully investigated.








Waste Disposal:


DOT Classification: Not a DOT controlled material (United States).

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Identification: Not applicable.

Special Provisions for Transport: Not applicable.


Federal and State Regulations: TSCA 8(b) inventory: N,N-Dimethyl-1-naphthylamine

Other Regulations: EINECS: This product is on the European Inventory of Existing Commercial Chemical Substances.


WHMIS (Canada): Not controlled under WHMIS (Canada).

DSCL (EEC):R22- Harmful if swallowed. S23- Do not breathe gas/fumes/vapour/spray [***] S24/25- Avoid contact with skin and eyes.

HMIS (U.S.A.):

Health Hazard: 2

Fire Hazard: 1

Reactivity: 0



Health: 1

Flammability: 0

Reactivity: 1

Specific hazard:

Protective Equipment:Gloves. Lab coat. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Splash goggles.




Created: 10/09/2005 05:12 PM

Last Updated: 05/21/2013 12:00 PM

The information above is believed to be accurate and represents the best information currently available to us. However, wemake no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assumeno liability resulting from its use. Users should make their own investigations to determine the suitability of the information fortheir particular purposes. In no event shall ScienceLab.com be liable for any claims, losses, or damages of any third party or forlost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if ScienceLab.comhas been advised of the possibility of such damages.

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Material Safety Data Sheet

Aqua Ammonia (19 – 30% NH3)

MSDS Number 2050 (Revised July 1, 2003) 8 Pages 1. CHEMICAL PRODUCT and EMERGENCY TELEPHONE CONTACT

Product Name:............................................ Aqua Ammonia (19 – 30% NH3) Chemical Family: ....................................... Inorganic Nitrogen Compound Synonyms:.................................................. Ammonium Hydroxide; Ammonia Solution,

Aqueous Solution; Ammonia Monohydrate; Ammonia Water; Ammonia Liquor

Formula: ..................................................... NH4OH in H2O Product Use:……………………………… Fertilizers; Pharmaceuticals; Lubricants;

Household Cleaners; SCR NOx Control EMERGENCY TELEPHONE NUMBERS CHEMTREC (U.S.): .................................. 800-424-9300 CANUTEC (Canada): ………………… .. 613-996-6666

2. COMPOSITION/INFORMATION ON INGREDIENTS

Ingredient Name/CAS Number Concentration Exposure Limits (NH3)

Ammonium Hydroxide / 1336-21-6 39-62% 25 ppm TWA Water / 7732-18-5 38-61% 35 ppm STEL 50 ppm PEL Contains between 19 and 30% ammonia as NH3 300 ppm IDLH

3. HAZARDS IDENTIFICATION

Terra Industries Inc. Terra Centre – 600 Fourth Street Sioux City, Iowa 51101

EMERGENCY OVERVIEW Corrosive liquid! May be fatal if swallowed. Vapor is toxic and irritating to eyes, nose, throat and skin. Liquid will burn skin and eyes. Vapor is flammable under limited conditions. Use water to control fire and disperse vapors.

POTENTIAL HEALTH EFFECTS

Primary Routes of Entry: Inhalation, skin contact/absorption and eye contact.

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General Acute Exposure: Aqua ammonia may cause caustic injury. The severity of injury depends upon the concentration and duration of exposure. The extent of injury ranges from mild skin irritation or cough to severe burns or laryngeal edema and life- threatening pulmonary edema. Inhalation: Corrosive! Ammonia vapor is toxic and a severe irritant of the respiratory tract. It may cause a running nose, coughing, chest pain, cessation of respiration and death. It may cause severe breathing difficulties, which may be delayed in onset. ADDITIONAL MEDICAL INFORMATION: Bronchospasm, laryngitis, tracheitis, wheezing, dyspnea, and laryngeal stridor may be noted. Mucosal burns to the tracheobronchial tree, Pulmonary Edema, and associated hypoxemia frequently occur following exposure to concentrated ammonia. Skin Contact: Corrosive! Aqua ammonia is a severe irritant of the skin. Skin exposure to high concentrations may cause pain and deep and severe burns to the skin. ADDITIONAL MEDICAL INFORMATION: Corrosive effects on the skin and other tissues may be delayed, and damage may occur without the sensation or onset of pain. Strict adherence to first aid measures following exposure is essential. Eye Contact: Corrosive! Vapors cause irritation. Effects as a result of direct contact with aqua ammonia may range from irritation and lacrimation to severe injury and blindness. ADDITIONAL MEDICAL INFORMATION: Eye exposure may result in conjunctivitis, lacrimation and/or corneal irritation. Total corneal epithelial loss may occur. Ingestion: Toxic! May cause corrosion to the esophagus and stomach with perforation and peritonitis. Symptoms may include pain in the mouth, chest, and abdomen, with coughing, vomiting and collapse. Ingestion of as little as 3-4 ml of ammonium hydroxide may be fatal.

Note to the Physician: Pneumonitis should be anticipated after severe inhalation or ingestion. If severe exposure is suspected, observe for 48-72 hours for delayed pulmonary edema.

Carcinogenicity: NTP:.................................................. Not Listed

IARC:................................................ Not Listed OSHA:............................................... Not Regulated Medical Conditions Aggravated by Exposure: Chronic respiratory or skin disease.

4. FIRST AID MEASURES

First Aid for Eyes: Immediately flush eyes with copious amounts of tepid water for at least 15 minutes. If irritation, pain, swelling, excessive tearing, or light sensitivity persists,

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the patient should be seen in a health care facility and referral to an ophthalmologist considered. First Aid for Skin: Immediately flush exposed area with copious amounts of tepid water for at least 15 minutes followed by washing area thoroughly with soap and water. The patient should be seen in a health care facility if irritation or pain persists. First Aid for Inhalation: Move patient to fresh air. Monitor for respiratory distress. If cough or difficulty in breathing develops, evaluate for respiratory tract irritation, bronchitis, or pneumonitis. If trained to do so administer supplemental oxygen with assisted ventilation as required. Administer artificial respiration if patient is not breathing. First Aid for Ingestion: Call a physician. If conscious, give the patient 4 to 8 ounces of milk or water to drink immediately. Do not induce vomiting.

5. FIRE FIGHTING MEASURES Flash Point: ................................................. Not Applicable Lower Flammable Limit:............................ 15.5 % Volume in Air (for NH3) Upper Flammable Limit: ............................ 27.0 % Volume in Air (for NH3) Autoignition Temperature .......................... 1204o F (651o C) (for NH3) Extinguishing Media: Stopping the flow of gas rather than extinguishing the fire is usually the best procedure to follow when escaping gas is burning. Small Fire: .........................................Dry chemical or CO2 Large Fire: .........................................Water spray, fog or foam Special Fire Fighting Procedures: Use water to keep fire exposed containers cool. Use water fog or foam to reduce vapor concentrations if necessary. Full protective equipment including a self-contained breathing apparatus should be worn in a fire involving the material.

6. ACCIDENTAL RELEASE MEASURES Spill or Leak Measures: Stop leak if you can do so without risk. Keep unnecessary people away, isolate hazard area and deny entry. Stay upwind, out of low areas, and ventilate closed spaces before entering. Evaluate the affected area to determine whether to evacuate or shelter- in-place by taping windows and doors, shutting off outside air intake (attic fans, etc.), and placing a wet towel or cloth over the face (if needed). Self-contained breathing apparatus (SCBA) and structural firefighter’s protective clothing used in conjunction with water spray will provide limited protection in outdoor releases for short-term exposure. Fully encapsulating, vapor-protective clothing should be worn for spills and leaks with no fire. Use water spray to control vapors.

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CAUTION: Runoff from vapor control or dilution of spilled product may cause pollution.

Determining Spill Size: Generally, a small spill is one that involves a single, small Package (i.e. up to a 55 gallon drum), small cylinder, or a small (non-continuing) leak from a large container. Small Spill: a. Flush area with flooding amounts of water. b. First isolate 100 feet in all directions and then protect persons downwind 0.1 miles

during daylight and 0.1 miles at night (recommended for ammonia vapor).

Large Spill: a. Dike far ahead of liquid spill for later disposal. b. Follow local emergency protocol for handling. c. First isolate 200 feet in all directions, than protect persons downwind 0.3 miles

during daylight and 0.7 miles at night (recommended for ammonia vapor).

7. HANDLING AND STORAGE Handling: Avoid contact with either liquid or vapors. Direct contact with mercury must be avoided. Use proper PPE when working with or around aqua ammonia (See section 8). Storage: Ambient temperature. Store in dry, well-ventilated area away from incompatible materials. Protect against physical damage. Keep out of direct sunlight and away from heat sources.

8. EXPOSURE CONTROLS, PERSONAL PROTECTION Respiratory Protection Requirements: (for NH3) <25 ppm: No protection required. 25 to 35 ppm: Protection required if the daily TWA is exceeded. 35 to 50 ppm: Protection required if exposed for more than 15 minutes. 50 to 250 ppm: Minimum of an air-purifying respirator equipped with

ammonia canister(s) or cartridge(s). 250 to 300 ppm: Minimum of a full- face air-purifying respirator

equipped with ammonia canister(s) or cartridge(s). >300 ppm: A fresh air supply system must be used (i.e. SCBA)

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9. PHYSICAL AND CHEMICAL PROPERTIES

Typical for 30% Aqua Ammonia Physical Form:............................................... Liquid Color:............................................................. Colorless Odor:.............................................................. Strong pungent penetrating odor, ammonia. Boiling Point: ................................................ 27o C pH:................................................................. 12.0 (neat) Specific Gravity: ........................................... 0.8974 (@ 15.5o C) Vapor Density: .............................................. 0.60 (@ 15.5o C) for NH3 Vapor Pressure: ............................................. 475 mm Hg (@ 15.5o C) Molecular Weight:......................................... 35.05 Relative Density: ........................................... 7.48 lb. per gallon (@ 15.5o C)

Skin Protection Requirements: Nitrile rubber, neoprene, or PVC gloves and protective clothing should be used. Eye Protection Requirements: Use chemical (indirectly vented) goggles when there is a potential for eye contact. A full- face shield is recommended in addition to goggles for added protection. Other Protective Equipment: Safety shower and eyewash fountain should be provided in the aqua ammonia handling area. When transporting, provide at least 5 gallons of readily accessible, clean water and personal protective equipment. Engineering Controls: Maintain adequate ventilation to keep ammonia concentrations below applicable standards. NOTE: See Section 2 for regulatory exposure limits.

10. REACTIVITY Stability:.........................................................This is a stable material. Hazardous Polymerization:............................Will not occur. Decomposition: Will liberate ammonia if heated. Hydrogen is released on heating ammonia above 850o F (454o C). The decomposition temperature may be lowered to 575o F (300o C) by contact with certain metals such as nickel. At 12900 F (6900 C) or in the presence of electric spark ammonia decomposes into nitrogen and hydrogen gases, which may form a flammable mixture in the air. Conditions to avoid: Excessive heat. Materials to avoid: Contact with calcium hypochlorite, bleaches, gold, mercury, and silver may form highly explosive products. Contact with iodine, bromine or chlorine may cause violent spattering.

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11. TOXICOLOGICAL INFORMATION Toxicity Acute Oral Toxicity LD50 Rat:..................................................350 mg/kg bw LD50 Cat:………………………………...750 mg/kg bw

Acute Toxicity, Other Routes LDLO Rabbit:……………………………..10 mg/kg bw Skin Irritation / Corrosion Rabbit:……………………………………….Corrosive at 20% but not 10% Eye Irritation / Corrosion Rabbit:……………………………………….Irritating Genetic Toxicity in vitro Gene Mutation E. Coli:..................................Negative Genetic Toxicity in vivo Gene Mutation Drosophila melanogaster: ....No evidence for mutagenicity Ecotoxicity Acute Toxicity to Fish LC50 Cyprinus carpio: .............................1.34 – 1.70 mg un- ionized NH3/L (48 hr

semi-static) Acute Toxicity to Aquatic Invertebrates LC50 Daphnia magna: .............................32 mg NH4OH/L (48 hr static) Chronic Toxicity to Fish LC50 Ictalurus punctatus: ........................37.5 ppm (8 days) Source: TFI Product Testing Program April 2003

12. ECOLOGICAL INFORMATION

a. Ammonia is harmful to aquatic life in very low concentrations and may be

hazardous if it enters water intakes. b. Local health and wildlife authorities, as well as operators of water intakes in the

vicinity, should be notified of water releases. c. Waterfowl toxicity may occur at elevated concentrations. d. Ammonia does not concentrate in the food chain. e. The conversion of ammonia to nitrites/nitrates by bacteria in aquatic systems can

reduce the concentration of dissolved oxygen (referred to as nitrogenous oxygen demand).

Effect on water treatment process: Chlorination will produce chloramines, which are more readily detected by taste and odor. Note: See Ecotoxicity information in section 11.

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14. TRANSPORTATION INFORMATION

U.S. DOT and Canadian TDG Act Shipping Name:............................................. Ammonia solutions, (more than 10% but not

more than 35 % ammonia) Shipping Class/Division:............................... 8 Hazard Class:................................................. Corrosive Liquid Product Identification Number (PIN):........... UN2672 Packing Group ............................................... III OSHA Label Required:................................. Yes RQ (Reportable Quantity):............................ 1000 pounds (as NH4OH) TDG Reporting Quantity:.............................. 5 kg or 5 liters

15. REGULATORY INFORMATION Controlled Products Regulations Classification: D-1B: Toxic (Acute Lethality); E: Corrosive OSHA: This product is considered a hazardous material under criteria of the Federal OSHA Hazard Communication Standard 29 CFR 1910.1200 (Toxic; Corrosive). CAA Chemical Accident Prevention: Ammonia solution with a concentration of 20% or greater is considered a regulated substance, subject to the Chemical Accident Prevention provisions of 40 CFR Part 68. The threshold quantity for this substance is 20,000 lbs. Ammonia solution with a concentration less than 20% is not subject to the provisions of 40 CFR Part 68. CERCLA Hazardous Substances List:

a. RQ (Reportable Quantity): 1000 pounds (as NH4OH) b. Regulation: “Designation, Reportable Quantities, Notification” - 40 CFR Part 302

SARA TITLE III: Ammonia (including ammonia solution) is subject to the reporting requirements of Section 313 “Specific Toxic Chemical Listings” 40 CFR Part 372. Terra is required by 40 CFR Part 372.45 to notify certain customers as to which of its mixture or trade name products contain those chemicals. The purpose of that notification is to ensure that facilities that may be subject to the reporting requirements of Section 313 and that use products of unknown formulation will have knowledge that they are receiving products that contain chemicals subject to those reporting requirements.

13. DISPOSAL CONSIDERATIONS

Reclaim as fertilizer if possible. Otherwise, waste must be disposed of in accordance with federal, state, and local environmental control regulations.

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16. OTHER INFORMATION

May 5, 2003: This MSDS was written to comply with ANSI Standard Z400.1-1993. July 1, 2003: Added toxicity information from the TFI Product Testing Program April 2003.

The information and recommendations herein are taken from data contained in independent, industry-recognized references including but not limited to NIOSH, OSHA, ANSI, NFPA, DOT ERG, the TFI Product Testing Program, Global Engineering Documents, MEDITEXT, HAZARDTEXT, SARATEXT, CHRIS, OHM/TADS, and IRIS. Terra Industries Inc. makes no guarantee, warranty or other representation concerning this substance, since conditions of its use are beyond the control of the company. Terra Industries Inc. disclaims any liability for loss or damage incurred in connection with the use of this substance.

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Material Safety Data SheetAmmonium hydroxide MSDS


Product Name: Ammonium hydroxide

Catalog Codes: SLA3667, SLA3490, SLA1144

CAS#: 1336-21-6

RTECS: BQ9625000

TSCA: TSCA 8(b) inventory: Ammonium hydroxide


Synonym: Aqueous Ammonia; Strong Ammonia Solution;Stronger Ammonia Water

Chemical Name: Not applicable.

Chemical Formula: Not applicable.









Composition:


Ammonia, anhydrous 7664-41-7 27-31

Water 7732-18-5 69-73

Toxicological Data on Ingredients: Ammonia, anhydrous: GAS (LC50): Acute: 2000 ppm 4 hours [Rat]. 4230 ppm 1 hours[Mouse].


Potential Acute Health Effects:Very hazardous in case of skin contact (corrosive, irritant, permeator), of eye contact (irritant), of ingestion, . Non-corrosiveto the eyes. Non-corrosive for lungs. Liquid or spray mist may produce tissue damage particularly on mucous membranes ofeyes, mouth and respiratory tract. Skin contact may produce burns. Inhalation of the spray mist may produce severe irritationof respiratory tract, characterized by coughing, choking, or shortness of breath. Severe over-exposure can result in death.Inflammation of the eye is characterized by redness, watering, and itching. Skin inflammation is characterized by itching,scaling, reddening, or, occasionally, blistering.

Potential Chronic Health Effects:CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Mutagenic for bacteria and/or yeast. [Ammonia,anhydrous]. TERATOGENIC EFFECTS: Not available. DEVELOPMENTAL TOXICITY: Not available. The substance is toxic


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to upper respiratory tract, skin, eyes. Repeated or prolonged exposure to the substance can produce target organs damage.Repeated or prolonged contact with spray mist may produce chronic eye irritation and severe skin irritation. Repeated orprolonged exposure to spray mist may produce respiratory tract irritation leading to frequent attacks of bronchial infection.Repeated exposure to a highly toxic material may produce general deterioration of health by an accumulation in one or manyhuman organs.


Eye Contact:Check for and remove any contact lenses. Immediately flush eyes with running water for at least 15 minutes, keeping eyelidsopen. Cold water may be used. Get medical attention immediately. Finish by rinsing thoroughly with running water to avoid apossible infection.




Serious Inhalation:Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or waistband. Ifbreathing is difficult, administer oxygen. If the victim is not breathing, perform mouth-to-mouth resuscitation. WARNING: It maybe hazardous to the person providing aid to give mouth-to-mouth resuscitation when the inhaled material is toxic, infectious orcorrosive. Seek medical attention.

Ingestion:If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to anunconscious person. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention immediately.



Flammability of the Product: Non-flammable.

Auto-Ignition Temperature: Not applicable.

Flash Points: Not applicable.

Flammable Limits: Not applicable.

Products of Combustion: Hazardous decomposition include Nitric oxide, and ammonia fumes

Fire Hazards in Presence of Various Substances: Not applicable.

Explosion Hazards in Presence of Various Substances: Non-explosive in presence of open flames and sparks, of shocks.

Fire Fighting Media and Instructions: Not applicable.


Special Remarks on Explosion Hazards:Forms explosive compounds with many heavy metals such as silver, lead, zinc and their halide salts. It can form shocksensitive compounds with halogens, mercury oxide, and siliver oxide.

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Small Spill:Dilute with water and mop up, or absorb with an inert dry material and place in an appropriate waste disposal container. Ifnecessary: Neutralize the residue with a dilute solution of acetic acid.

Large Spill:Corrosive liquid. Poisonous liquid. Stop leak if without risk. Absorb with DRY earth, sand or other non-combustible material.Do not get water inside container. Do not touch spilled material. Use water spray curtain to divert vapor drift. Use water sprayto reduce vapors. Prevent entry into sewers, basements or confined areas; dike if needed. Call for assistance on disposal.Neutralize the residue with a dilute solution of acetic acid. Be careful that the product is not present at a concentration levelabove TLV. Check TLV on the MSDS and with local authorities.


Precautions:Keep locked up.. Keep container dry. Do not ingest. Do not breathe gas/fumes/ vapor/spray. Never add water to this product.In case of insufficient ventilation, wear suitable respiratory equipment. If ingested, seek medical advice immediately and showthe container or the label. Avoid contact with skin and eyes. Keep away from incompatibles such as metals, acids.

Storage: Keep container tightly closed. Keep container in a cool, well-ventilated area. Do not store above 25°C (77°F).





Exposure Limits:TWA: 25 (ppm) from ACGIH (TLV) [United States] TWA: 50 STEL: 35 (ppm) from OSHA (PEL) [United States] TWA: 25 STEL:35 from NIOSH Consult local authorities for acceptable exposure limits.



Odor: Ammonia-like (Strong.)

Taste: Acrid.

Molecular Weight: 35.05

Color: Colorless.

pH (1% soln/water): 11.6 [Basic.] This is the actual pH in a 1 N solution.

Boiling Point: Not available

Melting Point: -69.2°C (-92.6°F)


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Vapor Density: Not available


Odor Threshold: 5 - 50 ppm as ammonia



Dispersion Properties: See solubility in water

Solubility: Easily soluble in cold water.




Conditions of Instability: Incompatible materials, high temperatures

Incompatibility with various substances:Highly reactive with metals. Reactive with acids. Slightly reactive to reactive with oxidizing agents.

Corrosivity:Extremely corrosive in presence of zinc, of copper. Corrosive in presence of aluminum. Non-corrosive in presence of glass, ofstainless steel(304), of stainless steel(316).

Special Remarks on Reactivity:Incompatible with the following: Organic acids, amides, organic anhydrides, isocyanates, vinyl acetate, epichlorhydrin,aldehydes, Acrolein, Acrylic acid, chlorosulfonic acid, dimethyl sulfate, fluorine, gold + aqua regia, hydrochloric acid,hydrofluoric acid, hydrogen peroxide, iodine, nitric acid, olelum, propiolactone, propylene oxide, silver nitrate, silver oxide,silver oxide + ethyl alcohol, nitromethane, silver permanganate, sulfuric acid, halogens. Forms explosive compounds withmany heavy metals (silver, lead, zinc) and halide salts.

Special Remarks on Corrosivity:Dissolves copper and zinc. Corrosive to aluminum and its alloys. Corrosive to galvanized surfaces. Severe corrosive effect onbrass and bronze




Toxicity to Animals: Acute oral toxicity (LD50): 350 mg/kg [Rat].

Chronic Effects on Humans:MUTAGENIC EFFECTS: Mutagenic for bacteria and/or yeast. [Ammonium hydroxide]. May cause damage to the followingorgans: mucous membranes, skin, eyes.

Other Toxic Effects on Humans:Very hazardous in case of skin contact (corrosive, irritant, permeator), of ingestion, . Hazardous in case of eye contact(corrosive), of inhalation (lung corrosive).

Special Remarks on Toxicity to Animals: Highly toxic to aquatic organisms

Special Remarks on Chronic Effects on Humans:May affect genetic material based on tests with microorganisms and animals. May cause cancer (tumorigenic) based onanimal data. No human data found at this time. (Ammonia, anhydrous)

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Special Remarks on other Toxic Effects on Humans:Acute Potential Health Effects: Skin: Causes severe irritation. Causes skin burns. May cause deep, penetrating ulcers of theskin. Contact with skin may cause staining, inflammation, and thickening of the skin. Eye: Contact with liquid or vapor causessevere burns and possible irreversible eye damage including corneal injury and cataracts. Inhalation: Causes severe irritationof the upper respiratory tract with coughing, burns, breathing difficulty. May cause acute pulmonary edema, pneumoconiosis,fibrosis, and even coma. It is a respiratory stimulant when inhaled at lower concentrations. It may also affect behavior/central nervous system (convulsions, seizures, ataxia, tremor), cardiovascular system (increase in blood pressure and pulserate). Ingestion: Harmful if swallowed. Affects the Gastrointestinal tract (burns, swelling of the lips, mouth, and larynx, throatconstriction, nausea, vomiting, convulsions, shock, and may cause severe and permanent damage), liver, and urinary system(kidneys) May affect behavior (convulsions, seizures, ataxia, excitement). Chronic Potential Health Effects: Ingestion: Maycause effects similar to those of acute ingestion. Inhalation: Repeated exposure to low concentrations may cause bronchitiswith cough, phlegm, and/or shortness of breath. May also cause liver and kidney damage, and affect the brain, and blood.Eye: May cause corneal damage and the development of cataracts and glaucoma. Skin: Repeated skin contact to lowconcentrations may cause dryness, itching, and redness (dermatitis)


Ecotoxicity:Ecotoxicity in water (LC50): 0.1 ppm 24 hours [Rainbow trout]. 8.2mg/l 96 hours [Fathead minnow]. 0.1 ppm 48 hours[Bluegill].









Identification: : Ammonia Solution UNNA: 2672 PG: III



Federal and State Regulations:Connecticut hazardous material survey.: Ammonium hydroxide Illinois toxic substances disclosure to employee act:Ammonium hydroxide Illinois chemical safety act: Ammonium hydroxide New York release reporting list: Ammoniumhydroxide Pennsylvania RTK: Ammonium hydroxide Massachusetts RTK: Ammonium hydroxide Massachusetts spill list:Ammonium hydroxide New Jersey: Ammonium hydroxide New Jersey spill list: Ammonium hydroxide New Jersey toxiccatastrophe prevention act: Ammonium hydroxide Louisiana spill reporting: Ammonium hydroxide California Director's List ofHazardous Substances (8 CCR 339): Ammonium hydroxide TSCA 8(b) inventory: Ammonium hydroxide CERCLA: Hazardoussubstances.: Ammonium hydroxide: 1000 lbs. (453.6 kg)

Other Regulations:

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OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200). EINECS: This product is on theEuropean Inventory of Existing Commercial Chemical Substances.


WHMIS (Canada):CLASS D-1B: Material causing immediate and serious toxic effects (TOXIC). CLASS E: Corrosive liquid.

DSCL (EEC):

HMIS (U.S.A.):

Health Hazard: 3

Fire Hazard: 0

Reactivity: 0



Health: 2

Flammability: 0

Reactivity: 0

Specific hazard:





Created: 10/09/2005 03:55 PM

Last Updated: 05/21/2013 12:00 PM


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Material Safety Data SheetAniline MSDS


Product Name: Aniline

Catalog Codes: SLA1735

CAS#: 62-53-3

RTECS: BW6650000

TSCA: TSCA 8(b) inventory: Aniline


Synonym: Aminobenzene; Benzenamine; Aminophen

Chemical Name: Aniline

Chemical Formula: C6H5NH2









Composition:


Aniline 62-53-3 100

Toxicological Data on Ingredients: Aniline: ORAL (LD50): Acute: 250 mg/kg [Rat.]. 464 mg/kg [Mouse]. DERMAL (LD50):Acute: 820 mg/kg [Rabbit.]. 1400 mg/kg [Rat].


Potential Acute Health Effects:Hazardous in case of skin contact (irritant, permeator), of eye contact (irritant), of ingestion, of inhalation. Severe over-exposure can result in death.

Potential Chronic Health Effects:Slightly hazardous in case of skin contact (sensitizer). CARCINOGENIC EFFECTS: Classified A3 (Proven for animal.) byACGIH. 3 (Not classifiable for human.) by IARC. MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells. Mutagenicfor bacteria and/or yeast. TERATOGENIC EFFECTS: Not available. DEVELOPMENTAL TOXICITY: Not available. Thesubstance may be toxic to blood, kidneys, liver, bladder, spleen, cardiovascular system, central nervous system (CNS).Repeated or prolonged exposure to the substance can produce target organs damage. Repeated exposure to a



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Eye Contact:Check for and remove any contact lenses. Immediately flush eyes with running water for at least 15 minutes, keeping eyelidsopen. Cold water may be used. Get medical attention. Finish by rinsing thoroughly with running water to avoid a possibleinfection.








Flammability of the Product: Combustible.

Auto-Ignition Temperature: 615°C (1139°F)

Flash Points: CLOSED CUP: 70°C (158°F).

Flammable Limits: LOWER: 1.3% UPPER: 23%


Fire Hazards in Presence of Various Substances:Flammable in presence of open flames and sparks, of heat. Non-flammable in presence of shocks.



Special Remarks on Fire Hazards:Ignites on contact with sodium peroxide + water. Aniline ignites spontaneously in presence of red fuming nitric acid. Sodiumperoxide or potassium peroxide is spontaneouly flammable with aniline. When heated to decomposition it emits toxic fumes.

Special Remarks on Explosion Hazards:Spontaneously explosive reactions occur with benzenediazonium -2-carboxylate, dibenzoyl peroxide, fluorine nitrate, nitrosylperchlorate, red fuming nitric acid, peroxodisulfuric acid, and tetranitromethane. Addition of a drop of aniline to 1 gram ofdibenzoyl peroxide leads to mildly explosive decompostion after a short delay. Addition of aniline to nitromethane renders itsusceptible to initiation by a detonator. Anililne reacts with perchloric acid, and then formaldehyde to produce explosive andcombustible condensed resin.

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Large Spill:Combustible material. Keep away from heat. Keep away from sources of ignition. Stop leak if without risk. Neutralize theresidue with a dilute solution of acetic acid. Be careful that the product is not present at a concentration level above TLV.Check TLV on the MSDS and with local authorities.


Precautions:Keep locked up.. Keep away from heat. Keep away from sources of ignition. Ground all equipment containing material. Donot ingest. Do not breathe gas/fumes/ vapor/spray. Wear suitable protective clothing. In case of insufficient ventilation, wearsuitable respiratory equipment. If ingested, seek medical advice immediately and show the container or the label. Avoidcontact with skin and eyes. Keep away from incompatibles such as oxidizing agents, metals, acids, alkalis.

Storage:Air and light sensitive. Store in light-resistance container. Keep container in a cool, well-ventilated area. Keep container tightlyclosed and sealed until ready for use. Avoid all possible sources of ignition (spark or flame).





Exposure Limits:TWA: 7.6 (mg/m3) from ACGIH (TLV) [United States] SKIN TWA: 2 (ppm) from ACGIH (TLV) [United States] SKIN TWA: 2[Canada] TWA: 7.6 (mg/m3) [Canada] TWA: 5 (ppm) from OSHA (PEL) [United States] TWA: 19 (mg/m3) from OSHA (PEL)[United States] TWA: 1 (ppm) [United Kingdom (UK)] TWA: 4 (mg/m3) [United Kingdom (UK)]Consult local authorities foracceptable exposure limits.


Physical state and appearance: Liquid. (Oily liquid.)

Odor: Aromatic. Amine like.

Taste: Burning.


Color: Colorless.

pH (1% soln/water): Basic.


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Melting Point: -6°C (21.2°F)

Critical Temperature: 425.6°C (798.1°F)






Water/Oil Dist. Coeff.: The product is more soluble in oil; log(oil/water) = 0.9


Dispersion Properties: See solubility in water, methanol, diethyl ether.

Solubility: Soluble in cold water, hot water, methanol, diethyl ether.





Incompatibility with various substances: Reactive with oxidizing agents, metals, acids, alkalis.

Corrosivity: Non-corrosive in presence of glass.

Special Remarks on Reactivity:Air and light sensitive. May darken on exposure to light or air. Incompatible with strong oxidizing agents , strong acids, bases,aluminum, fluorine, formaldehyde, iron, nitric acid, silver perchlorate, sodium peroxide, sulfuric acid, zinc, hydrogen peroxide,benzenediazonium-2-carboxylate, boron trichloride, tetranitromethane, trichloronitromethane, diisopropyl peroxydicarbonate,hexachloromelamine, peroxomonosulfuric acid, albumin, iron salts, perchloric acid, nitrobenzene, alkalis, potassiumperoxide, glycerine , fuming nitric acid, peroxydisulfuric acid, N-chloro compounds, N-bromides (e.g. n-bromosuccinimide),nitrosyl fluroide, toluene diisocyanate, performic acid. Formaldehyde + aniline reacts violently with 90% performic acid,acetic anhyride. Aniline + trichloronitromethane can produce a violent reaction. Aniline can react vigorously with oxidizingmaterials. Violent reactions can occur with peroxyformic acid, diisopropyl peroxydicarbonate, fluorine, trichloronitromethane,chlorosulfonic acid, peroxydisulfuric acid, FO3Cl, nitric acid + N2O4 + sulfuric acid, b-propiolactone, AgClO4.





Toxicity to Animals:WARNING: THE LC50 VALUES HEREUNDER ARE ESTIMATED ON THE BASIS OF A 4-HOUR EXPOSURE. Acute oraltoxicity (LD50): 250 mg/kg [Rat.]. Acute dermal toxicity (LD50): 820 mg/kg [Rabbit.]. Acute toxicity of the vapor (LC50): 175 7hours [Mouse].

Chronic Effects on Humans:CARCINOGENIC EFFECTS: Classified A3 (Proven for animal.) by ACGIH. 3 (Not classifiable for human.) by IARC.MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells. Mutagenic for bacteria and/or yeast. May cause damage tothe following organs: blood, kidneys, liver, bladder, spleen, cardiovascular system, central nervous system (CNS).

Other Toxic Effects on Humans: Hazardous in case of skin contact (irritant, permeator), of ingestion, of inhalation.

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Special Remarks on Chronic Effects on Humans:May affect genetic materials. May cause adverse reproductive effects. It may cause cancer. However, IARC has foundinadequate evidence in humans. Human: passes through the placenta.

Special Remarks on other Toxic Effects on Humans:










DOT Classification: CLASS 6.1: Poisonous material.

Identification: : Aniline UNNA: 1547 PG: II



Federal and State Regulations:California prop. 65: This product contains the following ingredients for which the State of California has found to cause cancer,birth defects or other reproductive harm, which would require a warning under the statute: Aniline California prop. 65 (nosignificant risk level): Aniline: 0.1 mg/day (value) California prop. 65: This product contains the following ingredients forwhich the State of California has found to cause cancer which would require a warning under the statute: Aniline Connecticuthazardous material survey.: Aniline Illinois toxic substances disclosure to employee act: Aniline Illinois chemical safetyact: Aniline New York release reporting list: Aniline Rhode Island RTK hazardous substances: Aniline Pennsylvania RTK:Aniline Minnesota: Aniline Massachusetts RTK: Aniline Massachusetts spill list: Aniline New Jersey: Aniline New Jerseyspill list: Aniline Louisiana RTK reporting list: Aniline Louisiana spill reporting: Aniline California Director's List of HazardousSubstances: Aniline TSCA 8(b) inventory: Aniline TSCA 8(a) IUR: Aniline TSCA 8(d) H and S data reporting: Aniline: 10/4/92SARA 302/304/311/312 extremely hazardous substances: Aniline SARA 313 toxic chemical notification and release reporting:Aniline CERCLA: Hazardous substances.: Aniline: 5000 lbs. (2268 kg)



WHMIS (Canada):CLASS B-3: Combustible liquid with a flash point between 37.8°C (100°F) and 93.3°C (200°F). CLASS D-1A: Material causingimmediate and serious toxic effects (VERY TOXIC). CLASS D-2B: Material causing other toxic effects (TOXIC).

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DSCL (EEC):R23/24/25- Toxic by inhalation, in contact with skin and if swallowed. R36/38- Irritating to eyes and skin. R40- Possible risksof irreversible effects. S2- Keep out of the reach of children. S28- After contact with skin, wash immediately with plenty ofwater. S36/37- Wear suitable protective clothing and gloves. S46- If swallowed, seek medical advice immediately and showthis container or label.

HMIS (U.S.A.):

Health Hazard: 2

Fire Hazard: 2

Reactivity: 0



Health: 3

Flammability: 2

Reactivity: 0

Specific hazard:



References:-Hawley, G.G.. The Condensed Chemical Dictionary, 11e ed., New York N.Y., Van Nostrand Reinold, 1987. -Material safetydata sheet emitted by: la Commission de la SantÃ© et de la SÃ©curitÃ© du Travail du QuÃ©bec. -SAX, N.I. DangerousProperties of Indutrial Materials. Toronto, Van Nostrand Reinold, 6e ed. 1984. -The Sigma-Aldrich Library of Chemical SafetyData, Edition II. -Guide de la loi et du rÃ¨glement sur le transport des marchandises dangeureuses au canada. Centre deconformitÃ© internatinal LtÃ©e. 1986. Registery of Toxic Effects of Chemical Substances (RTECS) database, REPROTEXTdata base, Ariel Global View database.


Created: 10/11/2005 11:19 AM

Last Updated: 05/21/2013 12:00 PM


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Material Safety Data SheetBenzene MSDS


Product Name: Benzene

Catalog Codes: SLB1564, SLB3055, SLB2881

CAS#: 71-43-2

RTECS: CY1400000

TSCA: TSCA 8(b) inventory: Benzene

CI#: Not available.

Synonym: Benzol; Benzine

Chemical Name: Benzene

Chemical Formula: C6-H6









Composition:


Benzene 71-43-2 100

Toxicological Data on Ingredients: Benzene: ORAL (LD50): Acute: 930 mg/kg [Rat]. 4700 mg/kg [Mouse]. DERMAL (LD50):Acute: >9400 mg/kg [Rabbit]. VAPOR (LC50): Acute: 10000 ppm 7 hours [Rat].


Potential Acute Health Effects:Very hazardous in case of eye contact (irritant), of inhalation. Hazardous in case of skin contact (irritant, permeator), ofingestion. Inflammation of the eye is characterized by redness, watering, and itching.

Potential Chronic Health Effects:CARCINOGENIC EFFECTS: Classified A1 (Confirmed for human.) by ACGIH, 1 (Proven for human.) by IARC. MUTAGENICEFFECTS: Classified POSSIBLE for human. Mutagenic for mammalian somatic cells. Mutagenic for bacteria and/or yeast.TERATOGENIC EFFECTS: Not available. DEVELOPMENTAL TOXICITY: Classified Reproductive system/toxin/female[POSSIBLE]. The substance is toxic to blood, bone marrow, central nervous system (CNS). The substance may be toxic toliver, Urinary System. Repeated or prolonged exposure to the substance can produce target organs damage.



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Eye Contact:Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15minutes. Cold water may be used. WARM water MUST be used. Get medical attention immediately.



Inhalation:If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medicalattention if symptoms appear.






Auto-Ignition Temperature: 497.78°C (928°F)

Flash Points: CLOSED CUP: -11.1°C (12°F). (Setaflash)



Fire Hazards in Presence of Various Substances:Highly flammable in presence of open flames and sparks, of heat. Slightly flammable to flammable in presence of oxidizingmaterials. Non-flammable in presence of shocks.

Explosion Hazards in Presence of Various Substances:Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the product inpresence of static discharge: Not available. Explosive in presence of oxidizing materials, of acids.

Fire Fighting Media and Instructions:Flammable liquid, soluble or dispersed in water. SMALL FIRE: Use DRY chemical powder. LARGE FIRE: Use alcohol foam,water spray or fog.

Special Remarks on Fire Hazards:Extremely flammable liquid and vapor. Vapor may cause flash fire. Reacts on contact with iodine heptafluoride gas.Dioxygenyl tetrafluoroborate is as very powferful oxidant. The addition of a small particle to small samples of benzene, atambient temperature, causes ignition. Contact with sodium peroxide with benzene causes ignition. Benzene ignites in contactwith powdered chromic anhydride. Virgorous or incandescent reaction with hydrogen + Raney nickel (above 210 C) andbromine trifluoride.

Special Remarks on Explosion Hazards:Benzene vapors + chlorine and light causes explosion. Reacts explosively with bromine pentafluoride, chlorine, chlorinetrifluoride, diborane, nitric acid, nitryl perchlorate, liquid oxygen, ozone, silver perchlorate. Benzene + pentafluoride andmethoxide (from arsenic pentafluoride and potassium methoxide) in trichlorotrifluoroethane causes explosion. Interaction

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of nitryl perchlorate with benzene gave a slight explosion and flash. The solution of permanganic acid ( or its explosiveanhydride, dimaganese heptoxide) produced by interaction of permanganates and sulfuric acid will explode on contact withbenzene. Peroxodisulfuric acid is a very powferful oxidant. Uncontrolled contact with benzene may cause explosion. Mixturesof peroxomonsulfuric acid with benzene explodes.



Large Spill:Flammable liquid. Keep away from heat. Keep away from sources of ignition. Stop leak if without risk. Absorb with DRY earth,sand or other non-combustible material. Do not touch spilled material. Prevent entry into sewers, basements or confinedareas; dike if needed. Be careful that the product is not present at a concentration level above TLV. Check TLV on the MSDSand with local authorities.


Precautions:Keep locked up.. Keep away from heat. Keep away from sources of ignition. Ground all equipment containing material. Donot ingest. Do not breathe gas/fumes/ vapor/spray. In case of insufficient ventilation, wear suitable respiratory equipment. Ifingested, seek medical advice immediately and show the container or the label. Avoid contact with skin and eyes. Keep awayfrom incompatibles such as oxidizing agents, acids.






Exposure Limits:TWA: 0.5 STEL: 2.5 (ppm) from ACGIH (TLV) [United States] TWA: 1.6 STEL: 8 (mg/m3) from ACGIH (TLV) [United States]TWA: 0.1 STEL: 1 from NIOSH TWA: 1 STEL: 5 (ppm) from OSHA (PEL) [United States] TWA: 10 (ppm) from OSHA (PEL)[United States] TWA: 3 (ppm) [United Kingdom (UK)] TWA: 1.6 (mg/m3) [United Kingdom (UK)] TWA: 1 (ppm) [Canada] TWA:3.2 (mg/m3) [Canada] TWA: 0.5 (ppm) [Canada]Consult local authorities for acceptable exposure limits.



Odor:Aromatic. Gasoline-like, rather pleasant. (Strong.)



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Color: Clear Colorless. Colorless to light yellow.


Boiling Point: 80.1 (176.2°F)

Melting Point: 5.5°C (41.9°F)

Critical Temperature: 288.9°C (552°F)

Specific Gravity: 0.8787 @ 15 C (Water = 1)

Vapor Pressure: 10 kPa (@ 20°C)







Solubility:Miscible in alcohol, chloroform, carbon disulfide oils, carbon tetrachloride, glacial acetic acid, diethyl ether, acetone. Veryslightly soluble in cold water.




Conditions of Instability: Heat, ignition sources, incompatibles.

Incompatibility with various substances: Highly reactive with oxidizing agents, acids.


Special Remarks on Reactivity:Benzene vapors + chlorine and light causes explosion. Reacts explosively with bromine pentafluoride, chlorine, chlorinetrifluoride, diborane, nitric acid, nitryl perchlorate, liquid oxygen, ozone, silver perchlorate. Benzene + pentafluoride andmethoxide (from arsenic pentafluoride and potassium methoxide) in trichlorotrifluoroethane causes explosion. Interactionof nitryl perchlorate with benzene gave a slight explosion and flash. The solution of permanganic acid ( or its explosiveanhydride, dimaganese heptoxide) produced by interaction of permanganates and sulfuric acid will explode on contact withbenzene. Peroxodisulfuric acid is a very powferful oxidant. Uncontrolled contact with benzene may cause explosion. Mixturesof peroxomonsulfuric acid with benzene explodes.




Routes of Entry: Absorbed through skin. Dermal contact. Eye contact. Inhalation.

Toxicity to Animals:WARNING: THE LC50 VALUES HEREUNDER ARE ESTIMATED ON THE BASIS OF A 4-HOUR EXPOSURE. Acute oraltoxicity (LD50): 930 mg/kg [Rat]. Acute dermal toxicity (LD50): >9400 mg/kg [Rabbit]. Acute toxicity of the vapor (LC50): 100007 hours [Rat].

Chronic Effects on Humans:

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CARCINOGENIC EFFECTS: Classified A1 (Confirmed for human.) by ACGIH, 1 (Proven for human.) by IARC. MUTAGENICEFFECTS: Classified POSSIBLE for human. Mutagenic for mammalian somatic cells. Mutagenic for bacteria and/or yeast.DEVELOPMENTAL TOXICITY: Classified Reproductive system/toxin/female [POSSIBLE]. Causes damage to the followingorgans: blood, bone marrow, central nervous system (CNS). May cause damage to the following organs: liver, Urinary System.

Other Toxic Effects on Humans:Very hazardous in case of inhalation. Hazardous in case of skin contact (irritant, permeator), of ingestion.


Special Remarks on Chronic Effects on Humans:May cause adverse reproductive effects (female fertility, Embryotoxic and/or foetotoxic in animal) and birth defects. May affectgenetic material (mutagenic). May cause cancer (tumorigenic, leukemia)) Human: passes the placental barrier, detected inmaternal milk.

Special Remarks on other Toxic Effects on Humans:Acute Potential Health Effects: Skin: Causes skin irritation. It can be absorbed through intact skin and affect the liver, blood,metabolism,and urinary system. Eyes: Causes eye irritation. Inhalation: Causes respiratory tract and mucous membraneirritation. Can be absorbed through the lungs. May affect behavior/Central and Peripheral nervous systems (somnolence,muscle weakness, general anesthetic, and other symptoms similar to ingestion), gastrointestinal tract (nausea), bloodmetabolism, urinary system. Ingestion: May be harmful if swallowed. May cause gastrointestinal tract irritation includingvomiting. May affect behavior/Central and Peripheral nervous systems (convulsions, seizures, tremor, irritability, initialCNS stimulation followed by depression, loss of coordination, dizziness, headache, weakness, pallor, flushing), respiration(breathlessness and chest constriction), cardiovascular system, (shallow/rapid pulse), and blood.











Identification: : Benzene UNNA: 1114 PG: II



Federal and State Regulations:California prop. 65: This product contains the following ingredients for which the State of California has found to cause cancer,birth defects or other reproductive harm, which would require a warning under the statute: Benzene California prop. 65 (nosignificant risk level): Benzene: 0.007 mg/day (value) California prop. 65: This product contains the following ingredients

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for which the State of California has found to cause cancer which would require a warning under the statute: BenzeneConnecticut carcinogen reporting list.: Benzene Connecticut hazardous material survey.: Benzene Illinois toxic substancesdisclosure to employee act: Benzene Illinois chemical safety act: Benzene New York release reporting list: Benzene RhodeIsland RTK hazardous substances: Benzene Pennsylvania RTK: Benzene Minnesota: Benzene Michigan critical material:Benzene Massachusetts RTK: Benzene Massachusetts spill list: Benzene New Jersey: Benzene New Jersey spill list:Benzene Louisiana spill reporting: Benzene California Director's list of Hazardous Substances: Benzene TSCA 8(b) inventory:Benzene SARA 313 toxic chemical notification and release reporting: Benzene CERCLA: Hazardous substances.: Benzene:10 lbs. (4.536 kg)



WHMIS (Canada):CLASS B-2: Flammable liquid with a flash point lower than 37.8°C (100°F). CLASS D-2A: Material causing other toxic effects(VERY TOXIC).

DSCL (EEC):R11- Highly flammable. R22- Harmful if swallowed. R38- Irritating to skin. R41- Risk of serious damage to eyes. R45- Maycause cancer. R62- Possible risk of impaired fertility. S2- Keep out of the reach of children. S26- In case of contact with eyes,rinse immediately with plenty of water and seek medical advice. S39- Wear eye/face protection. S46- If swallowed, seekmedical advice immediately and show this container or label. S53- Avoid exposure - obtain special instructions before use.

HMIS (U.S.A.):

Health Hazard: 2

Fire Hazard: 3

Reactivity: 0



Health: 2

Flammability: 3

Reactivity: 0

Specific hazard:





Created: 10/10/2005 08:35 PM

Last Updated: 05/21/2013 12:00 PM


Material Safety Data Sheet (Beta Naphthol)

Page 1 of 6

415 Huguenot Street New Rochelle, NY 10801 Phone:(914) 654-6800 Fax: (914) 654-6899

DATE PREPARED:6/23/2009 REVISION NUMBER: 6/23/2009 EMERGENCY NUMBER: CHEMTREC: 1-800-424-9300

SECTION 1 – PRODUCT AND COMPANY INFORMATION

PRODUCT NAME Beta Naphthol SYNONYM 2-Naphthol, 2-Hydroxynaphthalene FORMULA C10H8O CAS NUMBER 135-19-3

SECTION 2 – COMPOSITON/INFORMATION ON INGREDIENTS

PRODUCT NAME CAS NUMBER PURITY Beta Naphthol 135-19-3 100%

SECTION 3- HAZARDS IDENTIFICATION

Emergency Overview OSHA Hazards Target Organ Effect, Harmful by ingestion., Irritant Target Organs Damage to the eyes.

HMIS Classification

Health Hazard: 2 Chronic Health Hazard: * Flammability: 1 Physical hazards: 0

NFPA Rating

Health Hazard: 2 Fire: 1 Reactivity Hazard: 0

Potential Health Effects

Inhalation May be harmful if inhaled. Causes respiratory tract irritation. Skin May be harmful if absorbed through skin. Causes skin irritation. Eyes Causes eye irritation. Ingestion Harmful if swallowed.

SECTION 4 – FIRST AID MEASURES

General advice Consult a physician. Show this safety data sheet to the doctor in attendance.Move out of dangerous area.


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If inhaled If breathed in, move person into fresh air. If not breathing give artificial respiration Consult a physician. In case of skin contact Wash off with soap and plenty of water. Consult a physician. In case of eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. If swallowed Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

SECTION 5 – FIRE FIGHTING MEASURES

Flammable properties Flash point 153 °C (307 °F) - closed cup Ignition temperature no data available

Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Special protective equipment for fire-fighters Wear self contained breathing apparatus for fire fighting if necessary.

SECTION 6 – ACCIDENTAL RELEASE MEASURES

Personal precautions Use personal protective equipment. Avoid dust formation. Avoid breathing dust. Ensure adequate ventilation. Environmental precautions Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided. Methods for cleaning up Pick up and arrange disposal without creating dust. Keep in suitable, closed containers for disposal.

SECTION 7- HANDLING AND STORAGE

Handling Avoid formation of dust and aerosols. Provide appropriate exhaust ventilation at places where dust is formed. Normal measures for preventive fire protection. Storage Keep container tightly closed in a dry and well-ventilated place. Light sensitive.

SECTION 8 - EXPOSURE CONTROLS/ PERSONAL PROTECTION

Contains no substances with occupational exposure limit values. Personal protective equipment


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Respiratory protection Where risk assessment shows air-purifying respirators are appropriate use a dust mask type N95 (US) or type P1 (EN 143) respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).

Hand protection Handle with gloves.

Eye protection Safety glasses

Skin and body protection Choose body protection according to the amount and concentration of the dangerous substance at the work place.

Hygiene measures Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.

SECTION 9 – PHYSICAL AND CHEMICAL PROPERTIES

Appearance Form solid

Safety data

pH no data available Melting point 120 - 122 °C (248 - 252 °F) Boiling point 285 - 286 °C (545 - 547 °F) Flash point 153 °C (307 °F) - closed cup Ignition temperature no data available Lower explosion limit no data available Upper explosion limit no data available Vapour pressure 13 hPa (10 mmHg) at 145.5 °C (293.9 °F) Water solubility no data available

SECTION 10 – STABILITY AND REACTIVITY DATA

Storage stability Stable under recommended storage conditions. Materials to avoid Strong oxidizing agents, Strong bases Hazardous decomposition products Hazardous decomposition products formed under fire conditions. - Carbon oxides

SECTION 11 – TOXICOLOGICAL INFORMATION

Acute toxicity LD50 Oral - rat - 1,960 mg/kg LD50 Oral - rat - 1,960 mg/kg LD50 Dermal - rabbit - > 10,000 mg/kg


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LD50 Dermal - rabbit - > 10,000 mg/kg Irritation and corrosion Skin - rabbit - Mild skin irritation - 24 h Eyes - rabbit - Moderate eye irritation Sensitisation no data available Chronic exposure IARC: No component of this product present at levels greater than or equal to 0.1% is identified

as probable, possible or confirmed human carcinogen by IARC. ACGIH: No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by ACGIH. NTP: No component of this product present at levels greater than or equal to 0.1% is identified

as a known or anticipated carcinogen by NTP. OSHA: No component of this product present at levels greater than or equal to 0.1% is identified

as a carcinogen or potential carcinogen by OSHA. Signs and Symptoms of Exposure Depending on the intensity and duration of exposure, effects may vary from mild irritation to severe destruction of tissue., Damage to the eyes., To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Potential Health Effects

Inhalation May be harmful if inhaled. Causes respiratory tract irritation. Skin May be harmful if absorbed through skin. Causes skin irritation. Eyes Causes eye irritation. Ingestion Harmful if swallowed. Target Organs Damage to the eyes.,

Additional Information RTECS: QL2975000

SECTION 12 – ECOLOGICAL INFORMATION

Elimination information (persistence and degradability) Biodegradability Zahn-Wellens Test

Result: 92 % - Readily biodegradable. Ecotoxicity effects

Toxicity to fish LC50 - Pimephales promelas (fathead minnow) - 3.46 mg/l - 96 h Further information on ecology An environmental hazard cannot be excluded in the event of unprofessional handling or disposal. Very toxic to aquatic organisms.

SECTION 13 – DISPOSAL CONSIDERATION

Product Observe all federal, state, and local environmental regulations. Contact a licensed professional waste disposal service to dispose of this material.


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Contaminated packaging Dispose of as unused product.

SECTION 14 - TRANSPORTATION DATA

DOT (US) Not dangerous goods IMDG UN-Number: 3077 Class: 9 Packing group: III EMS-No: F-A, S-F Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (2-Naphthol) Marine pollutant: No IATA UN-Number: 3077 Class: 9 Packing group: III Proper shipping name: Environmentally hazardous substance, solid n.o.s. (2-Naphthol)

SECTION 15 – REGULATORY INFORMATION

OSHA Hazards Target Organ Effect, Harmful by ingestion., Irritant DSL Status All components of this product are on the Canadian DSL list. SARA 302 Components SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302. SARA 313 Components SARA 313: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. SARA 311/312 Hazards Acute Health Hazard, Chronic Health Hazard Massachusetts Right To Know Components No components are subject to the Massachusetts Right to Know Act. Pennsylvania Right To Know Components

2-Naphthol CAS-No. 135-19-3 Revision Date New Jersey Right To Know Components

2-Naphthol CAS-No. 135-19-3 Revision Date California Prop. 65 Components This product does not contain any chemicals known to State of California to cause cancer, birth, or any other reproductive defects.


Page 6 of 6

SECTION 16 – OTHER INFORMATION

Disclaimer The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product.

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Material Safety Data SheetNaphthol-2 MSDS


Product Name: Naphthol-2

Catalog Codes: SLN1498, SLN2110

CAS#: 135-19-3

RTECS: QL2975000

TSCA: TSCA 8(b) inventory: Naphthol-2

CI#: Not available.

Synonym: Beta-Naphthol

Chemical Name: 2-Naphthol

Chemical Formula: C10H7Oh









Composition:


Naphthol-2 135-19-3 100

Toxicological Data on Ingredients: Naphthol-2: ORAL (LD50): Acute: 1960 mg/kg [Rat].


Potential Acute Health Effects:Very hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion. Hazardous in case of skin contact(permeator), of inhalation. Slightly hazardous in case of skin contact (corrosive). Inflammation of the eye is characterized byredness, watering, and itching. Skin inflammation is characterized by itching, scaling, reddening, or, occasionally, blistering.

Potential Chronic Health Effects:CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available.DEVELOPMENTAL TOXICITY: Not available. The substance is toxic to lungs, mucous membranes. Repeated or prolongedexposure to the substance can produce target organs damage.


Eye Contact:

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Check for and remove any contact lenses. Immediately flush eyes with running water for at least 15 minutes, keeping eyelidsopen. Cold water may be used. Do not use an eye ointment. Seek medical attention.

Skin Contact:After contact with skin, wash immediately with plenty of water. Gently and thoroughly wash the contaminated skin with runningwater and non-abrasive soap. Be particularly careful to clean folds, crevices, creases and groin. Cover the irritated skin with anemollient. If irritation persists, seek medical attention. Wash contaminated clothing before reusing.


Inhalation: Allow the victim to rest in a well ventilated area. Seek immediate medical attention.


Ingestion:Do not induce vomiting. Examine the lips and mouth to ascertain whether the tissues are damaged, a possible indication thatthe toxic material was ingested; the absence of such signs, however, is not conclusive. Loosen tight clothing such as a collar,tie, belt or waistband. If the victim is not breathing, perform mouth-to-mouth resuscitation. Seek immediate medical attention.








Fire Hazards in Presence of Various Substances: Not available.






Small Spill:Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water onthe contaminated surface and dispose of according to local and regional authority requirements.

Large Spill:Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on thecontaminated surface and allow to evacuate through the sanitary system.


Precautions:

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Keep container dry. Keep away from heat. Keep away from sources of ignition. Empty containers pose a fire risk, evaporatethe residue under a fume hood. Ground all equipment containing material. Do not ingest. Do not breathe dust. Never addwater to this product In case of insufficient ventilation, wear suitable respiratory equipment If ingested, seek medical adviceimmediately and show the container or the label. Avoid contact with skin and eyes

Storage:Keep container dry. Keep in a cool place. Ground all equipment containing material. Keep container tightly closed. Keep in acool, well-ventilated place. Combustible materials should be stored away from extreme heat and away from strong oxidizingagents.


Engineering Controls:Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommendedexposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminantsbelow the exposure limit.

Personal Protection:Splash goggles. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Gloves.

Personal Protection in Case of a Large Spill:Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoidinhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling thisproduct.



Physical state and appearance: Solid.




Color: Not available.



Melting Point: 122°C (251.6°F)



Vapor Pressure: Not applicable.







Solubility: Very slightly soluble in cold water.

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Polymerization: No.




Chronic Effects on Humans: The substance is toxic to lungs, mucous membranes.

Other Toxic Effects on Humans:Very hazardous in case of skin contact (irritant), of ingestion. Hazardous in case of skin contact (permeator), of inhalation.Slightly hazardous in case of skin contact (corrosive).








Toxicity of the Products of Biodegradation: The products of degradation are more toxic.



Waste Disposal:





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Federal and State Regulations: TSCA 8(b) inventory: Naphthol-2



WHMIS (Canada): CLASS D-2A: Material causing other toxic effects (VERY TOXIC).

DSCL (EEC):R38- Irritating to skin. R41- Risk of serious damage to eyes.

HMIS (U.S.A.):

Health Hazard: 2

Fire Hazard: 1

Reactivity: 0

Personal Protection: E


Health: 2

Flammability: 1

Reactivity: 0

Specific hazard:

Protective Equipment:Gloves. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Wear appropriate respiratorwhen ventilation is inadequate. Splash goggles.




Created: 10/10/2005 10:54 AM

Last Updated: 05/21/2013 12:00 PM


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Material Safety Data Sheet1-Butanol MSDS


Product Name: 1-Butanol

Catalog Codes: SLB3157, SLB1489

CAS#: 71-36-3

RTECS: EO1400000

TSCA: TSCA 8(b) inventory: 1-Butanol


Synonym: Propylcarbinol

Chemical Name: N-Butyl alcohol

Chemical Formula: CH3(CH2)2CH2OH









Composition:


{1-}Butanol 71-36-3 100

Toxicological Data on Ingredients: 1-Butanol: ORAL (LD50): Acute: 790 mg/kg [Rat.]. DERMAL (LD50): Acute: 3400 mg/kg[Rabbit.].


Potential Acute Health Effects:Very hazardous in case of skin contact (irritant, permeator), of eye contact (irritant), of ingestion, of inhalation. Slightlyhazardous in case of skin contact (sensitizer). Inflammation of the eye is characterized by redness, watering, and itching. Skininflammation is characterized by itching, scaling, reddening, or, occasionally, blistering.



Eye Contact:


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Check for and remove any contact lenses. Immediately flush eyes with running water for at least 15 minutes, keeping eyelidsopen. Cold water may be used. Get medical attention immediately.










Flash Points: CLOSED CUP: 28.9°C (84°F). OPEN CUP: 36.1°C (97°F) (Cleveland).



Fire Hazards in Presence of Various Substances:Highly flammable in presence of open flames and sparks. Flammable in presence of heat, of oxidizing materials, of reducingmaterials, of combustible materials.



Special Remarks on Fire Hazards: May form explosive mixtures with air. CAUTION: MAY BURN WITH NEAR INVISIBLEFLAME




Large Spill:

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Flammable liquid. Keep away from heat. Keep away from sources of ignition. Stop leak if without risk. Absorb with DRY earth,sand or other non-combustible material. Do not touch spilled material. Prevent entry into sewers, basements or confinedareas; dike if needed. Be careful that the product is not present at a concentration level above TLV. Check TLV on the MSDSand with local authorities.


Precautions:Keep away from heat. Keep away from sources of ignition. Ground all equipment containing material. Do not ingest. Donot breathe gas/fumes/ vapor/spray. In case of insufficient ventilation, wear suitable respiratory equipment. If ingested,seek medical advice immediately and show the container or the label. Avoid contact with skin and eyes. Keep away fromincompatibles such as oxidizing agents, reducing agents.






Exposure Limits:CEIL: 152 (mg/m3) Consult local authorities for acceptable exposure limits.


Physical state and appearance: Liquid. (Z)

Odor: Vinous. (Slight.)


Molecular Weight: 74.12g/mole

Color: Colorless.





Specific Gravity: 0.81(Water = 1)




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Dispersion Properties: See solubility in water, methanol, diethyl ether, n-octanol.

Solubility:Easily soluble in methanol, diethyl ether. Partially soluble in cold water, hot water, n-octanol.





Incompatibility with various substances:Highly reactive with oxidizing agents, reducing agents. Slightly reactive to reactive with organic materials, acids, alkalis.







Toxicity to Animals:WARNING: THE LC50 VALUES HEREUNDER ARE ESTIMATED ON THE BASIS OF A 4-HOUR EXPOSURE. Acute oraltoxicity (LD50): 790 mg/kg [Rat.]. Acute dermal toxicity (LD50): 3400 mg/kg [Rabbit.]. Acute toxicity of the vapor (LC50): 80004 hours [Rat.].


Other Toxic Effects on Humans:Very hazardous in case of skin contact (irritant, permeator), of ingestion, of inhalation. Slightly hazardous in case of skincontact (sensitizer).


Special Remarks on Chronic Effects on Humans: Can cause gastrointestinal disturbances.

Special Remarks on other Toxic Effects on Humans: Exposure can cause nausea, headache and vomiting.







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Waste Disposal:



Identification: : Butanol UNNA: UN1120 PG: III



Federal and State Regulations:Pennsylvania RTK: 1-Butanol Massachusetts RTK: 1-Butanol TSCA 8(b) inventory: 1-Butanol



WHMIS (Canada):CLASS B-2: Flammable liquid with a flash point lower than 37.8°C (100°F). CLASS D-2B: Material causing other toxic effects(TOXIC).

DSCL (EEC):R10- Flammable. R22- Harmful if swallowed. R38- Irritating to skin. R41- Risk of serious damage to eyes.

HMIS (U.S.A.):

Health Hazard: 1

Fire Hazard: 3

Reactivity: 0



Health: 1

Flammability: 3

Reactivity: 0

Specific hazard:



References: -Manufacturer's Material Safety Data Sheet.


Created: 10/10/2005 08:15 PM

Last Updated: 05/21/2013 12:00 PM


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Material Safety Data SheetSodium Hydroxide, 50% MSDS


Product Name: Sodium Hydroxide, 50%

Catalog Codes: SLS3127, SLS4549

CAS#: Mixture.

RTECS: Not applicable.

TSCA: TSCA 8(b) inventory: Sodium hydroxide; Water


Synonym: Sodium Hydroxide, 50% Solution











Composition:


Sodium hydroxide 1310-73-2 50

Water 7732-18-5 50

Toxicological Data on Ingredients: Sodium hydroxide LD50: Not available. LC50: Not available.


Potential Acute Health Effects:Very hazardous in case of skin contact (corrosive, irritant, permeator), of eye contact (irritant, corrosive), of ingestion, . Slightlyhazardous in case of inhalation (lung sensitizer). Liquid or spray mist may produce tissue damage particularly on mucousmembranes of eyes, mouth and respiratory tract. Skin contact may produce burns. Inhalation of the spray mist may producesevere irritation of respiratory tract, characterized by coughing, choking, or shortness of breath. Severe over-exposure canresult in death. Inflammation of the eye is characterized by redness, watering, and itching. Skin inflammation is characterizedby itching, scaling, reddening, or, occasionally, blistering.

Potential Chronic Health Effects:CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available.DEVELOPMENTAL TOXICITY: Not available. The substance is toxic to lungs. Repeated or prolonged exposure to thesubstance can produce target organs damage. Repeated or prolonged contact with spray mist may produce chronic eyeirritation and severe skin irritation. Repeated or prolonged exposure to spray mist may produce respiratory tract irritation


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leading to frequent attacks of bronchial infection. Repeated exposure to a highly toxic material may produce generaldeterioration of health by an accumulation in one or many human organs.


Eye Contact:Check for and remove any contact lenses. Immediately flush eyes with running water for at least 15 minutes, keeping eyelidsopen. Cold water may be used. Get medical attention immediately. Finish by rinsing thoroughly with running water to avoid apossible infection.












Products of Combustion: Not available.





Special Remarks on Explosion Hazards:Sodium hydroxide reacts to form explosive products with ammonia + silver nitrate. Benzene extract of allyl benzenesulfonateprepared from allyl alcohol, and benzene sulfonyl chloride in presence of aquesous sodium hydroxide, under vacuumdistillation, residue darkened and exploded. Sodium Hydroxde + impure tetrahydrofuran, which can contain peroxides, cancause serious explosions. Dry mixtures of sodium hydroxide and sodium tetrahydroborate liberate hydrogen explosively at230-270 deg. C. Sodium Hydroxide reacts with sodium salt of trichlorophenol + methyl alcohol + trichlorobenzene + heat tocause an explosion. (Sodium hydroxide)

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Large Spill:Corrosive liquid. Poisonous liquid. Stop leak if without risk. Absorb with DRY earth, sand or other non-combustible material.Do not get water inside container. Do not touch spilled material. Use water spray curtain to divert vapor drift. Use water sprayto reduce vapors. Prevent entry into sewers, basements or confined areas; dike if needed. Call for assistance on disposal.Neutralize the residue with a dilute solution of acetic acid. Be careful that the product is not present at a concentration levelabove TLV. Check TLV on the MSDS and with local authorities.


Precautions:Do not ingest. Do not breathe gas/fumes/ vapor/spray. Never add water to this product. In case of insufficient ventilation,wear suitable respiratory equipment. If ingested, seek medical advice immediately and show the container or the label. Avoidcontact with skin and eyes. Keep away from incompatibles such as oxidizing agents, reducing agents, metals, acids, alkalis,moisture.

Storage: Keep container tightly closed. Keep container in a cool, well-ventilated area.


Engineering Controls:Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respectivethreshold limit value.



Exposure Limits:Sodium hydroxide STEL: 2 (mg/m3) from ACGIH (TLV) [United States] TWA: 2 CEIL: 2 (mg/m3) from OSHA (PEL) [UnitedStates] CEIL: 2 (mg/m3) from NIOSHConsult local authorities for acceptable exposure limits.



Odor: Odorless.

Taste: Alkaline. Bitter. (Strong.)

Molecular Weight: Not applicable.

Color: Clear Colorless.

pH (1% soln/water): Basic.

Boiling Point: 140°C (284°F)



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Vapor Pressure: The highest known value is 2.3 kPa (@ 20°C) (Water).

Vapor Density: The highest known value is 0.62 (Air = 1) (Water).






Solubility: Easily soluble in cold water.




Conditions of Instability: Excess heat, incompatible materials, water/moisture

Incompatibility with various substances:Reactive with oxidizing agents, reducing agents, metals, acids, alkalis. Slightly reactive with water

Corrosivity:Extremely corrosive in presence of aluminum, brass. Corrosive in presence of copper, of stainless steel(304), of stainlesssteel(316). Non-corrosive in presence of glass.

Special Remarks on Reactivity:Hygroscopic. Much heat is evolved when solid material is dissolved in water. Therefore cold water and caution must beused for this process. Generates considerable heat when a sodium hydroxide solution is mixed with an acid Sodiumhydroxide solution and octanol + diborane during a work-up of a reaction mixture of oxime and diborane in tetrahyrofuranis very exothermic, a mild explosion being noted on one occassion. Reactive with water, acids (mineral, non-oxidizing, e.g.hydrochloric, hydrofluoric acid, muriatic acid, phosphoric), acids (mineral, oxidizing e.g. chromic acid, hypochlorous acid, nitricacid, sulfuric acid), acids (organic e.g. acetic acid, benzoic acid, formic acid, methanoic acid, oxalic acid), aldehydes (e.g.acetaldehyde, acrolein, chloral hydrate, foraldehyde), carbamates (e.g. carbanolate, carbofuran), esters (e.g. butyl acetate,ethyl acetate, propyl formate), halogenated organics (dibromoethane, hexachlorobenzene, methyl chloride, trichloroethylene),isocyanates (e.g. methyl isocyanate), ketones (acetone, acetophenone, MEK, MIBK), acid chlorides, strong bases, strongoxidizing agents, strong reducing agents, flammable liquids, powdered metals and metals (i.e aluminum, tin, zinc, hafnium,raney nickel), metals (alkali and alkaline e.g. cesium, potassium, sodium), metal compounds (toxic e.g. berylium, leadacetate, nickel carbonyl, tetraethyl lead), mitrides (e.g. potassium nitride, sodium nitride), nitriles (e.g. acetonitrile, methylcyanide), nitro compounds (organic e.g. nitrobenzene, nitromethane), acetic anhydride, hydroquinone, chlorohydrin,chlorosulfonic acid, ethylene cyanohydrin, glyoxal, hydrosulfuric acid, oleum, propiolactone, acylonitrile, phorosous pentoxide,chloroethanol, chloroform-methanol, tetrahydroborate, cyanogen azide, 1,2,4,5 tetrachlorobenzene, cinnamaldehyde. Reactswith formaldehyde hydroxide to yield formic acid, and hydrogen. (Sodium hydroxide)

Special Remarks on Corrosivity: Very caustic to aluminum and other metals in presence of moisture.






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Other Toxic Effects on Humans:Extremely hazardous in case of inhalation (lung corrosive). Very hazardous in case of skin contact (corrosive, irritant,permeator), of eye contact (corrosive), of ingestion, .


Special Remarks on Chronic Effects on Humans: Investigation as a mutagen (cytogenetic analysis), but no data available.(Sodium hydroxide)

Special Remarks on other Toxic Effects on Humans:Acute Potential Health Effects: Skin: May be harmful if absorbed through skin. Causes severe skin irritation and burns. Maycause deep penetrating ulcers of the skin. Eyes: Causes severe eye irritation and burns. May cause chemical conjunctivitisand corneal damage. Inhalation: Harmful if inhaled. Causes severe irritation of the respiratory tract and mucous membraneswith coughing, burns, breathing difficulty, and possible coma. Irritation may lead the chemical pneumonitis and pulmonaryedema. Causes chemical burns to the respiratory tract and mucous membranes. Ingestion: May be fatal if swallowed. Maycause severe and permanent damage to the digestive tract. Causes











Identification: : Sodium hydroxide, solution (Sodium hydroxide) UNNA: UN1824 PG: II



Federal and State Regulations:Illinois toxic substances disclosure to employee act: Sodium hydroxide Illinois chemical safety act: Sodium hydroxide NewYork release reporting list: Sodium hydroxide Rhode Island RTK hazardous substances: Sodium hydroxide PennsylvaniaRTK: Sodium hydroxide Minnesota: Sodium hydroxide Massachusetts RTK: Sodium hydroxide New Jersey: Sodium hydroxideLouisiana spill reporting: Sodium hydroxide TSCA 8(b) inventory: Sodium hydroxide; Water CERCLA: Hazardous substances.:Sodium hydroxide: 1000 lbs. (453.6 kg);



WHMIS (Canada):

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CLASS D-2A: Material causing other toxic effects (VERY TOXIC). CLASS E: Corrosive liquid.

DSCL (EEC):

HMIS (U.S.A.):

Health Hazard: 3

Fire Hazard: 0

Reactivity: 1



Health: 3

Flammability: 0

Reactivity: 1

Specific hazard:





Created: 10/09/2005 06:32 PM

Last Updated: 05/21/2013 12:00 PM


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Material Safety Data SheetChromium sulfate MSDS


Product Name: Chromium sulfate

Catalog Codes: SLC4861

CAS#: 10101-53-8

RTECS: GB7200000

TSCA: TSCA 8(b) inventory: Chromium sulfate

CI#: Not available.

Synonym:

Chemical Name: Not available.

Chemical Formula: Cr2(SO4)3.xH2O









Composition:


Chromium sulfate 10101-53-8 100

Toxicological Data on Ingredients: Chromium sulfate LD50: Not available. LC50: Not available.


Potential Acute Health Effects:Very hazardous in case of ingestion. Hazardous in case of skin contact (irritant), of eye contact (irritant), of inhalation.

Potential Chronic Health Effects:Very hazardous in case of ingestion. Hazardous in case of skin contact (irritant), of eye contact (irritant), of inhalation.CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available.DEVELOPMENTAL TOXICITY: Not available. The substance is toxic to lungs, mucous membranes. Repeated or prolongedexposure to the substance can produce target organs damage.


Eye Contact:Check for and remove any contact lenses. Immediately flush eyes with running water for at least 15 minutes, keeping eyelidsopen. Cold water may be used. Do not use an eye ointment. Seek medical attention.


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Skin Contact:After contact with skin, wash immediately with plenty of water. Gently and thoroughly wash the contaminated skin with runningwater and non-abrasive soap. Be particularly careful to clean folds, crevices, creases and groin. Cold water may be used.Cover the irritated skin with an emollient. If irritation persists, seek medical attention.

Serious Skin Contact:Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek medical attention.



Ingestion:Do not induce vomiting. Loosen tight clothing such as a collar, tie, belt or waistband. If the victim is not breathing, performmouth-to-mouth resuscitation. Seek immediate medical attention.















Large Spill:Use a shovel to put the material into a convenient waste disposal container. Be careful that the product is not present at aconcentration level above TLV. Check TLV on the MSDS and with local authorities.


Precautions:Do not breathe dust. Wear suitable protective clothing In case of insufficient ventilation, wear suitable respiratory equipment Ifyou feel unwell, seek medical attention and show the label when possible. Avoid contact with skin and eyes

Storage:No specific storage is required. Use shelves or cabinets sturdy enough to bear the weight of the chemicals. Be sure that it isnot necessary to strain to reach materials, and that shelves are not overloaded.

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Exposure Limits:TWA: 0.5 (mg/m3) Consult local authorities for acceptable exposure limits.


Physical state and appearance: Solid. (Crystals solid.)






Boiling Point: Not available.

Melting Point: Decomposes.









Dispersion Properties: See solubility in water, methanol.

Solubility:Soluble in cold water. Partially soluble in methanol.





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Polymerization: No.


Routes of Entry: Eye contact. Inhalation. Ingestion.



Other Toxic Effects on Humans:Very hazardous in case of ingestion. Hazardous in case of skin contact (irritant), of inhalation.











Waste Disposal:


DOT Classification: CLASS 9: Miscellaneous hazardous material.

Identification: : Not available. : NA9100 PG: III



Federal and State Regulations:Pennsylvania RTK: Chromium sulfate Massachusetts RTK: Chromium sulfate TSCA 8(b) inventory: Chromium sulfate SARA313 toxic chemical notification and release reporting: Chromium sulfate CERCLA: Hazardous substances.: Chromium sulfate

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DSCL (EEC): R36/38- Irritating to eyes and skin.

HMIS (U.S.A.):

Health Hazard: 2

Fire Hazard: 0

Reactivity: 0



Health: 2

Flammability: 0

Reactivity: 0

Specific hazard:





Created: 10/09/2005 04:55 PM

Last Updated: 05/21/2013 12:00 PM


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Material Safety Data SheetCopper Sulfate solution MSDS


Product Name: Copper Sulfate solution


CAS#: Mixture.

RTECS: Not applicable.

TSCA: TSCA 8(b) inventory: No products were found.


Synonym: Copper Sulfate Solution











Composition:


Water 7732-18-5 91.8

Copper sulfate pentahydrate 7758-99-8 8.23

Toxicological Data on Ingredients: Copper sulfate pentahydrate: ORAL (LD50): Acute: 300 mg/kg [Rat.]. DERMAL (LD50):Acute: >2000 mg/kg [Rat].


Potential Acute Health Effects:Hazardous in case of skin contact (irritant), of eye contact (irritant). Slightly hazardous in case of ingestion, . Non-corrosive forskin.

Potential Chronic Health Effects:CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells. [Copper sulfatepentahydrate]. TERATOGENIC EFFECTS: Not available. DEVELOPMENTAL TOXICITY: Not available. The substance maybe toxic to kidneys, liver. Repeated or prolonged exposure to the substance can produce target organs damage. Repeatedexposure to a highly toxic material may produce general deterioration of health by an accumulation in one or many humanorgans.



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Explosion Hazards in Presence of Various Substances: Non-explosive in presence of open flames and sparks, of shocks,of heat.



Special Remarks on Explosion Hazards: Nitromethanes and copper salts spontaneously form explosive materials (Coppersulfate pentahydrate)


Small Spill:Dilute with water and mop up, or absorb with an inert dry material and place in an appropriate waste disposal container.Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authorityrequirements.

Large Spill:Absorb with an inert material and put the spilled material in an appropriate waste disposal. Finish cleaning by spreading wateron the contaminated surface and allow to evacuate through the sanitary system. Be careful that the product is not present at aconcentration level above TLV. Check TLV on the MSDS and with local authorities.


p. 3

Precautions:Do not ingest. Do not breathe gas/fumes/ vapor/spray. Wear suitable protective clothing. In case of insufficient ventilation,wear suitable respiratory equipment. If ingested, seek medical advice immediately and show the container or the label. Avoidcontact with skin and eyes.



Engineering Controls:Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respectivethreshold limit value.



Exposure Limits:Copper sulfate pentahydrate TWA: 1 (mg/m3) from ACGIH (TLV) [United States] Inhalation TWA: 0.1 (mg/m3) from OSHA(PEL) [United States] Inhalation TWA: 1 (mg/m3) from NIOSH InhalationConsult local authorities for acceptable exposurelimits.





Molecular Weight: Not applicable.

Color: Blue.

pH (1% soln/water): Not available

Boiling Point: The lowest known value is 100°C (212°F) (Water).




Vapor Pressure: The highest known value is 2.3 kPa (@ 20°C) (Water).

Vapor Density: The highest known value is 0.62 (Air = 1) (Water).






Solubility:Easily soluble in cold water, hot water. Partially soluble in methanol.

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Conditions of Instability: Incompatible materials

Incompatibility with various substances: Slightly reactive to reactive with metals, alkalis.

Corrosivity: Corrosive in presence of steel.

Special Remarks on Reactivity:Air Sensitive. Solutions of hyprobromite are decomposed by powerful catalytic action of cupric ions, even as impurities.Incompatible with finely powdered metals. (Copper sulfate pentahydrate)





Toxicity to Animals:Acute oral toxicity (LD50): 3641 mg/kg (Rat.) (Calculated value for the mixture). Acute dermal toxicity (LD50): 25485 mg/kg(Rat) (Calculated value for the mixture).

Chronic Effects on Humans:MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells. [Copper sulfate pentahydrate]. Contains material which maycause damage to the following organs: kidneys, liver.

Other Toxic Effects on Humans:Hazardous in case of skin contact (irritant). Slightly hazardous in case of ingestion, of inhalation.

Special Remarks on Toxicity to Animals:Lowest Published Lethal Dose: LDL [Human] - Route: Oral; Dose: 1088 mg/kg (Copper sulfate pentahydrate)

Special Remarks on Chronic Effects on Humans: May affect genetic material based on animal data (Copper sulfatepentahydrate)

Special Remarks on other Toxic Effects on Humans:Acute Potential Health Effects: Skin: Causes skin irritation. Eyes: Causes eye irritation. Inhalation: May cause respiratory tractirritation. Ingestion: May be harmful if swallowed. May cause gastrointestinal tract irritation with nausea, vomiting, diarrhea.May affect metabolism, liver (jaundice), blood (Methemoglobin, hemalytic anemia), urinary system (kidneys), behavior/nervoussystems (somnolence, coma), cardiovascular system (lowering of blood pressure)






Special Remarks on the Products of Biodegradation:If released to soil, copper sulfate may leach to groundwater, be partly oxidized, or bind to humic materials, clay, or hydrousof iron and manganese. In water, it will bind to carbonates as well as humic materials, clay and hydrous oxides of iron andmanganese. Copper is accumulated by plants and animals, but it does not appear to biomagnify from plants to animals. This

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lack of biomagnification appears common with heavy metals. In air, copper aerosols (in general) have a residence time of 2 to10 days in an unpolluted atmosphere and 0.1 to >4 in a polluted, urban areas. (Copper sulfate pentahydrate)








Federal and State Regulations:TSCA 8(b) inventory: Water SARA 313 toxic chemical notification and release reporting: Copper compounds CERCLA:Hazardous substances.: Copper sulfate pentahydrate: 10 lbs. (4.536 kg);




DSCL (EEC):This product is not classified according to the EU regulations. Not applicable.

HMIS (U.S.A.):

Health Hazard: 2

Fire Hazard: 0

Reactivity: 0



Health: 2

Flammability: 0

Reactivity: 0

Specific hazard:

Protective Equipment:Gloves. Lab coat. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Splash goggles.




Created: 10/10/2005 01:00 AM

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Material Safety Data SheetCyanuric Chloride MSDS


Product Name: Cyanuric Chloride


CAS#: 108-77-0

RTECS: XZ1400000

TSCA: TSCA 8(b) inventory: Cyanuric Chloride

Synonym: 2, 4, 6-Trichloro-1, 3, 5-triazine

Chemical Name: Cyanuric Chloride

Chemical Formula: C3Cl3N3









Composition:


Cyanuric Chloride 108-77-0 100

Toxicological Data on Ingredients: Cyanuric Chloride: ORAL (LD50): Acute: 485 mg/kg [Rat]. 350 mg/kg [Mouse]. DUST(LC50): Acute: 2.7 ppm 4 hour(s) [Mouse].


Potential Acute Health Effects:Extremely hazardous in case of skin contact (irritant), of eye contact (irritant). Hazardous in case of skin contact (corrosive),of eye contact (corrosive). Slightly hazardous in case of inhalation (lung irritant, lung corrosive). The amount of tissue damagedepends on length of contact. Eye contact can result in corneal damage or blindness. Skin contact can produce inflammationand blistering. Severe over-exposure can produce lung damage, choking, unconsciousness or death. Inflammation of theeye is characterized by redness, watering, and itching. Skin inflammation is characterized by itching, scaling, reddening, or,occasionally, blistering.

Potential Chronic Health Effects:Very hazardous in case of skin contact (corrosive, irritant), of eye contact (irritant). Hazardous in case of inhalation (lungirritant). CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Notavailable. DEVELOPMENTAL TOXICITY: Not available. The substance is toxic to blood, the nervous system, liver, brain,bones, central nervous system (CNS). Repeated or prolonged exposure to the substance can produce target organs damage.Repeated exposure of the eyes to a low level of dust can produce eye irritation. Repeated skin exposure can produce local


p. 2

skin destruction, or dermatitis. Repeated inhalation of dust can produce varying degree of respiratory irritation or lung damage.Repeated exposure to an highly toxic material may produce general deterioration of health by an accumulation in one or manyhuman organs. Repeated or prolonged inhalation of dust may lead to chronic respiratory irritation.


Eye Contact: Check for and remove any contact lenses. Do not use an eye ointment. Seek medical attention.

Skin Contact:If the chemical got onto the clothed portion of the body, remove the contaminated clothes as quickly as possible, protectingyour own hands and body. Place the victim under a deluge shower. If the chemical got on the victim's exposed skin, suchas the hands : Gently and thoroughly wash the contaminated skin with running water and non-abrasive soap. Be particularlycareful to clean folds, crevices, creases and groin. If irritation persists, seek medical attention. Wash contaminated clothingbefore reusing.









Flash Points: Not available.









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Small Spill: Use appropriate tools to put the spilled solid in a convenient waste disposal container.

Large Spill:Corrosive solid. Stop leak if without risk. Do not get water inside container. Do not touch spilled material. Use water spray toreduce vapors. Prevent entry into sewers, basements or confined areas; dike if needed. Eliminate all ignition sources. Call forassistance on disposal.


Precautions:Keep locked up Keep container dry. Keep away from heat. Keep away from sources of ignition. Empty containers pose afire risk, evaporate the residue under a fume hood. Ground all equipment containing material. Do not ingest. Do not breathedust. Never add water to this product If ingested, seek medical advice immediately and show the container or the label. Avoidcontact with skin and eyes Keep away from incompatibles such as moisture.

Storage:Keep container dry. Keep in a cool place. Ground all equipment containing material. Corrosive materials should be stored in aseparate safety storage cabinet or room.



Personal Protection:Splash goggles. Synthetic apron. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Gloves.





Odor: Strong.



Color: Colorless

pH (1% soln/water): <7 [Neutral.]

Boiling Point: 194°C (381.2°F)

Melting Point: 150°C (302°F)

Critical Temperature: 147.7°C (297.9°F)




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Dispersion Properties: See solubility in water, methanol, diethyl ether, acetone.

Solubility:Soluble in diethyl ether, acetone. Partially soluble in methanol. Insoluble in cold water.





Incompatibility with various substances: Highly reactive with moisture.


Special Remarks on Reactivity: Readily hydrolyzed by moisture, with the liberation of hydrochloric acid.


Polymerization: No.



Toxicity to Animals:WARNING: THE LC50 VALUES HEREUNDER ARE ESTIMATED ON THE BASIS OF A 4-HOUR EXPOSURE. Acute oraltoxicity (LD50): 350 mg/kg [Mouse]. Acute toxicity of the dust (LC50): 20 mg/m3 4 hour(s) [Mouse].

Chronic Effects on Humans: The substance is toxic to blood, the nervous system, liver, brain, bones, central nervous system(CNS).

Other Toxic Effects on Humans:Extremely hazardous in case of skin contact (irritant). Hazardous in case of skin contact (corrosive), of eye contact (corrosive).Slightly hazardous in case of inhalation (lung irritant, lung corrosive).










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Waste Disposal:


DOT Classification: CLASS 8: Corrosive solid.

Identification: : Cyanuric Chloride : UN2670 PG: II



Federal and State Regulations:New Jersey: Cyanuric Chloride TSCA 8(b) inventory: Cyanuric Chloride



WHMIS (Canada):CLASS D-1B: Material causing immediate and serious toxic effects (TOXIC). CLASS E: Corrosive solid.

DSCL (EEC):R37/38- Irritating to respiratory system and skin. R41- Risk of serious damage to eyes. R48/22- Harmful: danger of seriousdamage to health by prolonged exposure if swallowed.

HMIS (U.S.A.):

Health Hazard: 3

Fire Hazard: 1

Reactivity: 1



Health: 3

Flammability: 1

Reactivity: 1

Specific hazard:

Protective Equipment:Gloves. Synthetic apron. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Wear appropriaterespirator when ventilation is inadequate. Splash goggles.




Created: 10/09/2005 05:02 PM

Last Updated: 05/21/2013 12:00 PM

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Material Safety Data SheetDiethyl oxalate MSDS


Product Name: Diethyl oxalate


CAS#: 95-92-1

RTECS: Not available.

TSCA: TSCA 8(b) inventory: Diethyl oxalate

CI#: Not available.

Synonym:

Chemical Formula: C6H10O4









Composition:


Diethyl oxalate 95-92-1 100

Toxicological Data on Ingredients: Diethyl oxalate: ORAL (LD50): Acute: 2000 mg/kg [Mouse].


Potential Acute Health Effects: Hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, of inhalation(lung irritant).






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Flash Points: CLOSED CUP: 75°C (167°F). OPEN CUP: 76°C (168.8°F).










Large Spill:Combustible material. Keep away from heat. Keep away from sources of ignition. Stop leak if without risk.


Precautions:Keep away from heat. Keep away from sources of ignition. Ground all equipment containing material. Do not ingest. Do notbreathe gas/fumes/ vapour/spray. Wear suitable protective clothing If ingested, seek medical advice immediately and show thecontainer or the label. Avoid contact with skin and eyes

Storage:Flammable materials should be stored in a separate safety storage cabinet or room. Keep away from heat. Keep away fromsources of ignition. Keep container tightly closed. Keep in a cool, well-ventilated place. Ground all equipment containingmaterial. Keep container dry. Keep in a cool place.

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Solubility: Not available.







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Polymerization: No.


Routes of Entry: Eye contact. Ingestion.

Toxicity to Animals: Acute oral toxicity (LD50): 2000 mg/kg [Mouse].


Other Toxic Effects on Humans: Hazardous in case of skin contact (irritant), of ingestion, of inhalation (lung irritant).











Waste Disposal:



Identification: : Ethyl Oxalate : UN2525 PG: III



Federal and State Regulations:Florida: Diethyl oxalate New Jersey: Diethyl oxalate TSCA 8(b) inventory: Diethyl oxalate



WHMIS (Canada):CLASS B-3: Combustible liquid with a flash point between 37.8°C (100°F) and 93.3°C (200°F). CLASS D-1B: Material causingimmediate and serious toxic effects (TOXIC).

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DSCL (EEC):R36/37/38- Irritating to eyes, respiratory system and skin.

HMIS (U.S.A.):

Health Hazard: 2

Fire Hazard: 2

Reactivity: 0



Health: 2

Flammability: 2

Reactivity: 0

Specific hazard:





Created: 10/09/2005 05:09 PM

Last Updated: 05/21/2013 12:00 PM


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Material Safety Data SheetEthylenediamine tetraacetic acid MSDS


Product Name: Ethylenediamine tetraacetic acid

Catalog Codes: SLE1045

CAS#: 60-00-4

RTECS: AH4025000

TSCA: TSCA 8(b) inventory: Ethylenediamine tetraaceticacid

CI#: Not available.

Synonym: EDTA; Edetic acid

Chemical Name: Ethylenediamine tetraacetic acid

Chemical Formula: C10H16N2O8









Composition:


Ethylenediamine tetraacetic acid 60-00-4 100

Toxicological Data on Ingredients: Ethylenediamine tetraacetic acid: ORAL (LD50): Acute: 30 mg/kg [Mouse].


Potential Acute Health Effects:Slightly hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, of inhalation. Severe over-exposurecan result in death.

Potential Chronic Health Effects:CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells.TERATOGENIC EFFECTS: Classified POSSIBLE for human. DEVELOPMENTAL TOXICITY: Not available. The substancemay be toxic to kidneys. Repeated or prolonged exposure to the substance can produce target organs damage. Repeatedexposure to a highly toxic material may produce general deterioration of health by an accumulation in one or many humanorgans.



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Eye Contact:Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15minutes. Cold water may be used. WARM water MUST be used. Get medical attention if irritation occurs.

Skin Contact: Wash with soap and water. Cover the irritated skin with an emollient. Get medical attention if irritation develops.

Serious Skin Contact: Not available.











Fire Hazards in Presence of Various Substances:Slightly flammable to flammable in presence of open flames and sparks, of heat. Non-flammable in presence of shocks.

Explosion Hazards in Presence of Various Substances:Risks of explosion of the product in presence of mechanical impact: Not available. Slightly explosive in presence of openflames and sparks, of heat.






Large Spill:Poisonous solid. Stop leak if without risk. Do not get water inside container. Do not touch spilled material. Use water spray toreduce vapors. Prevent entry into sewers, basements or confined areas; dike if needed. Eliminate all ignition sources. Call forassistance on disposal.


Precautions:

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Keep locked up.. Keep away from heat. Keep away from sources of ignition. Empty containers pose a fire risk, evaporatethe residue under a fume hood. Ground all equipment containing material. Do not ingest. Do not breathe dust. Wear suitableprotective clothing. If ingested, seek medical advice immediately and show the container or the label.

Storage: Keep container tightly closed. Keep container in a cool, well-ventilated area. Do not store above 24°C (75.2°F).



Personal Protection: Safety glasses. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent.Gloves.




Physical state and appearance: Solid. (crystalline powder.)




Color: White.



Melting Point: Decomposition temperature: 220-240°C (464°F)










Solubility:Very slightly soluble in cold water. Insoluble in common organic solvents.


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Conditions of Instability: Excess heat, incompatible materials



Special Remarks on Reactivity:Neutralized by alkali metal hydroxides to form a series of water-soluble salts containing from one to four alkali metal cations.No other information at this time.




Routes of Entry: Inhalation. Ingestion.


Chronic Effects on Humans:MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells. TERATOGENIC EFFECTS: Classified POSSIBLE forhuman. May cause damage to the following organs: kidneys.

Other Toxic Effects on Humans: Slightly hazardous in case of skin contact (irritant), of ingestion, of inhalation.


Special Remarks on Chronic Effects on Humans:May cause adverse reproductive effects (fertility and fetotoxicity) and birth defects based on animal data. May affect geneticmaterial based on animal data.

Special Remarks on other Toxic Effects on Humans:Acute Potential Health Effects: Skin: Can cause skin irritation. Eyes: Can cause eye irritation. Inhalation: Can irritate the nose,throat/respiratory tract, and mucous membranes. Ingestion: May cause gastrointestinal tract irritation. May affect behavior.Chronic Potential Health Effects: Long term exposure via inhalation or ingestion may damage the kidneys.










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Identification: : Not available. UNNA: NA9117 PG: III



Federal and State Regulations:Connecticut carcinogen reporting list.: Ethylenediamine tetraacetic acid Illinois toxic substances disclosure to employee act:Ethylenediamine tetraacetic acid Illinois chemical safety act: Ethylenediamine tetraacetic acid New York release reporting list:Ethylenediamine tetraacetic acid Pennsylvania RTK: Ethylenediamine tetraacetic acid Massachusetts RTK: Ethylenediaminetetraacetic acid Massachusetts spill list: Ethylenediamine tetraacetic acid New Jersey: Ethylenediamine tetraacetic acidNew Jersey spill list: Ethylenediamine tetraacetic acid California Director's List of Hazardous Substances: Ethylenediaminetetraacetic acid TSCA 8(b) inventory: Ethylenediamine tetraacetic acid CERCLA: Hazardous substances.: Ethylenediaminetetraacetic acid: 5000 lbs. (2268 kg)




DSCL (EEC):R40- Possible risks of irreversible effects. R63- Possible risk of harm to the unborn child. S2- Keep out of the reach of children.S36/37- Wear suitable protective clothing and gloves.

HMIS (U.S.A.):

Health Hazard: 1

Fire Hazard: 1

Reactivity: 0



Health: 1

Flammability: 1

Reactivity: 0

Specific hazard:

Protective Equipment:Gloves. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Safety glasses.




Created: 10/10/2005 08:18 PM

Last Updated: 05/21/2013 12:00 PM


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Material Safety Data SheetEthyl acetate MSDS


Product Name: Ethyl acetate

Catalog Codes: SLE2452, SLE2317

CAS#: 141-78-6

RTECS: AH5425000

TSCA: TSCA 8(b) inventory: Ethyl acetate

CI#: Not available.

Synonym: Acetic Acid, Ethyl Ester Acetic Ether

Chemical Name: Ethyl Acetate










Composition:


Ethyl acetate 141-78-6 100

Toxicological Data on Ingredients: Ethyl acetate: ORAL (LD50): Acute: 5620 mg/kg [Rat]. 4100 mg/kg [Mouse]. 4935 mg/kg[Rabbit]. VAPOR (LC50): Acute: 45000 mg/m 3 hours [Mouse]. 16000 ppm 6 hours [Rat].


Potential Acute Health Effects:Hazardous in case of ingestion, of inhalation. Slightly hazardous in case of skin contact (irritant, permeator), of eye contact(irritant).

Potential Chronic Health Effects:CARCINOGENIC EFFECTS: A4 (Not classifiable for human or animal.) by ACGIH. MUTAGENIC EFFECTS: Not available.TERATOGENIC EFFECTS: Not available. DEVELOPMENTAL TOXICITY: Not available. The substance is toxic to mucousmembranes, upper respiratory tract. The substance may be toxic to blood, kidneys, liver, central nervous system (CNS).Repeated or prolonged exposure to the substance can produce target organs damage.



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Skin Contact:Wash with soap and water. Cover the irritated skin with an emollient. Get medical attention if irritation develops. Cold watermay be used.









Flash Points: CLOSED CUP: -4.4°C (24.1°F). (TAG) OPEN CUP: 7.2°C (45°F) (Cleveland).

Flammable Limits: LOWER: 2.2% UPPER: 9%


Fire Hazards in Presence of Various Substances:Highly flammable in presence of open flames and sparks, of heat. Slightly flammable to flammable in presence of oxidizingmaterials, of acids, of alkalis. Non-flammable in presence of shocks.

Explosion Hazards in Presence of Various Substances:Risks of explosion of the product in presence of static discharge: Not available. Slightly explosive in presence of heat. Non-explosive in presence of shocks.


Special Remarks on Fire Hazards:Vapor may travel considerable distance to source of ignition and flash back. When heated to decomposition it emits acridsmoke and irritating fumes.

Special Remarks on Explosion Hazards:The liquid produces a vapor that forms explosive mixtures with air at normal temperatures. Explosive reaction with lithiumtetrahydroaluminate.



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Large Spill:Flammable liquid. Keep away from heat. Keep away from sources of ignition. Stop leak if without risk. Absorb with DRY earth,sand or other non-combustible material. Do not touch spilled material. Prevent entry into sewers, basements or confinedareas; dike if needed. Be careful that the product is not present at a concentration level above TLV. Check TLV on the MSDSand with local authorities.


Precautions:Keep away from heat. Keep away from sources of ignition. Ground all equipment containing material. Do not ingest. Do notbreathe gas/fumes/ vapor/spray. Wear suitable protective clothing. In case of insufficient ventilation, wear suitable respiratoryequipment. If ingested, seek medical advice immediately and show the container or the label. Keep away from incompatiblessuch as oxidizing agents, acids, alkalis.

Storage:Store in a segregated and approved area. Keep container in a cool, well-ventilated area. Keep container tightly closed andsealed until ready for use. Avoid all possible sources of ignition (spark or flame). Moisture sensitive.



Personal Protection:Safety glasses. Lab coat. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Gloves.


Exposure Limits:TWA: 400 (ppm) from OSHA (PEL) [United States] TWA: 400 from ACGIH (TLV) [United States] TWA: 1400 (mg/m3) fromNIOSH [United States] TWA: 400 (ppm) from NIOSH [United States] TWA: 400 (ppm) [Canada] TWA: 1440 (mg/m3) [Canada]TWA: 1400 (mg/m3) from OSHA (PEL) [United States]3 Consult local authorities for acceptable exposure limits.



Odor: Ethereal. Fruity. (Slight.)

Taste: Bittersweet, wine-like burning taste


Color: Colorless.




Critical Temperature: 250°C (482°F)



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Solubility: Soluble in cold water, hot water, diethyl ether, acetone, alcohol, benzene.




Conditions of Instability: Heat, ignition sources (flames, sparks, static), incompatible materials

Incompatibility with various substances: Reactive with oxidizing agents, acids, alkalis.


Special Remarks on Reactivity:Also incompatible with nitrates, chlorosulfonic acid, oleum, potassium-tert-butoxide, and lithium tetrahydroaluminate. Moisturesensitive. On storage, it is slowly decomposed by water.




Routes of Entry: Absorbed through skin. Eye contact. Inhalation. Ingestion.

Toxicity to Animals:WARNING: THE LC50 VALUES HEREUNDER ARE ESTIMATED ON THE BASIS OF A 4-HOUR EXPOSURE. Acute oraltoxicity (LD50): 4100 mg/kg [Mouse]. Acute toxicity of the vapor (LC50): 45000 mg/m3 3 hours [Mouse].

Chronic Effects on Humans:CARCINOGENIC EFFECTS: A4 (Not classifiable for human or animal.) by ACGIH. Causes damage to the following organs:mucous membranes, upper respiratory tract. May cause damage to the following organs: blood, kidneys, liver, central nervoussystem (CNS).

Other Toxic Effects on Humans:Hazardous in case of ingestion, of inhalation. Slightly hazardous in case of skin contact (irritant, permeator).

Special Remarks on Toxicity to Animals: LD50 [Rabbit] - Route: skin; Dose >20,000 ml/kg

Special Remarks on Chronic Effects on Humans:May affect genetic material (mutagenic). May cause adverse reproductive effects. based on animal test data. No human datafound at this time.

Special Remarks on other Toxic Effects on Humans:Acute Potential Health Effects: Skin: May cause skin irritation. Eyes: Causes eye irritation. May cause irritation of theconjunctivia. Inhalation: May cause respiratory tract and mucous membrane irritation. May affect respiration and may causeacute pulmonary edema. May affect gastrointestinal tract (nausea, vomiting). May affect behavior/central nervous system(mild central nervous system depression - exhilaration, talkativeness, boastfulness, belligerancy, vertigo, diplopia, drowsiness,slurred speech, slowed reaction time, dizziness, lightheadedness, somnolence, ataxia, unconciousness, irritability, fatigue,sleep disturbances, reduced memory and concentration, stupor, coma), cardiovascular system (peripheral vascular collapse(shock) - rapid pulse, hypotension, cold pale skin, hypothermia). Other symptoms may include: flushing of face and sweating.

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Ingestion: May cause gastrointestinal tract irritation with nausea and vomiting. May affect blood, behavior/central nervoussystem (CNS depression - effects may be similar to that of inhalation). Chronic Potential Health Effects: Skin: Repeated orprolonged skin contact may cause drying and cracking of the skin. IngestIon: Prolonged or repeated ingestion may affectthe liver. Inhalation: Prolonged inhalation may affect behavior/central nervous system (symptoms similar to those of acuteinhalation), and cause liver, kidney, lung, and heart damage. It may also affect metabolism, and blood (anemia, leukocytosis).


Ecotoxicity:Ecotoxicity in water (LC50): 220 mg/l 96 hours [Fish (Fathead minnow)]. 212.5 ppm 96 hours [Fish (Indian catfish)].



Toxicity of the Products of Biodegradation: The product itself and its products of degradation are not toxic.






Identification: : Ethyl Acetate UNNA: 1173 PG: II



Federal and State Regulations:Connecticut hazardous material survey.: Ethyl acetate Illinois toxic substances disclosure to employee act: Ethyl acetateIllinois chemical safety act: Ethyl acetate New York release reporting list: Ethyl acetate Rhode Island RTK hazardoussubstances: Ethyl acetate Pennsylvania RTK: Ethyl acetate Florida: Ethyl acetate Minnesota: Ethyl acetate MassachusettsRTK: Ethyl acetate Massachusetts spill list: Ethyl acetate New Jersey: Ethyl acetate New Jersey spill list: Ethyl acetateLouisiana spill reporting: Ethyl acetate California Director's list of Hazardous Substances: Ethyl acetate TSCA 8(b) inventory:Ethyl acetate TSCA 4(a) final test rules: Ethyl acetate TSCA 8(a) IUR: Ethyl acetate TSCA 12(b) annual export notification:Ethyl acetate CERCLA: Hazardous substances.: Ethyl acetate: 5000 lbs. (2268 kg)



WHMIS (Canada): CLASS B-2: Flammable liquid with a flash point lower than 37.8°C (100°F).

DSCL (EEC):R11- Highly flammable. R36- Irritating to eyes. S2- Keep out of the reach of children. S16- Keep away from sources of ignition- No smoking. S26- In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S33-Take precautionary measures against static discharges. S46- If swallowed, seek medical advice immediately and show thiscontainer or label.

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HMIS (U.S.A.):

Health Hazard: 2

Fire Hazard: 3

Reactivity: 0

Personal Protection: g


Health: 1

Flammability: 3

Reactivity: 0

Specific hazard:

Protective Equipment:Gloves. Lab coat. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Wear appropriate respiratorwhen ventilation is inadequate. Safety glasses.




Created: 10/10/2005 08:18 PM

Last Updated: 05/21/2013 12:00 PM


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Material Safety Data SheetFormaldehyde 37% solution MSDS


Product Name: Formaldehyde 37% solution

Catalog Codes: SLF1426

CAS#: Mixture.

RTECS: LP8925000

TSCA: TSCA 8(b) inventory: Formaldehyde; Methylalcohol; Water


Synonym: Formalin

Chemical Name: Formaldehyde

Chemical Formula: HCHO









Composition:


Formaldehyde 50-00-0 36.5-38

Methyl alcohol 67-56-1 10-15

Water 7732-18-5 47-53.5

Toxicological Data on Ingredients: Formaldehyde: ORAL (LD50): Acute: 100 mg/kg [Rat]. 42 mg/kg [Mouse]. 260 mg/kg[Guinea pig]. MIST (LC50): Acute: 454000 mg/m 4 hours [Mouse]. Methyl alcohol: ORAL (LD50): Acute: 5628 mg/kg [Rat].DERMAL (LD50): Acute: 15800 mg/kg [Rabbit]. VAPOR (LC50): Acute: 64000 ppm 4 hours [Rat].


Potential Acute Health Effects:Very hazardous in case of eye contact (irritant), of ingestion, . Hazardous in case of skin contact (irritant, sensitizer,permeator), of eye contact (corrosive). Slightly hazardous in case of skin contact (corrosive). Severe over-exposure can resultin death. Inflammation of the eye is characterized by redness, watering, and itching.

Potential Chronic Health Effects:Hazardous in case of skin contact (sensitizer). CARCINOGENIC EFFECTS: Classified A2 (Suspected for human.) by ACGIH,2A (Probable for human.) by IARC [Formaldehyde]. MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells.[Formaldehyde]. Mutagenic for bacteria and/or yeast. [Formaldehyde]. Mutagenic for mammalian somatic cells. [Methyl


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alcohol]. Mutagenic for bacteria and/or yeast. [Methyl alcohol]. TERATOGENIC EFFECTS: Classified POSSIBLE for human[Methyl alcohol]. DEVELOPMENTAL TOXICITY: Not available The substance may be toxic to kidneys, liver, skin, centralnervous system (CNS). Repeated or prolonged exposure to the substance can produce target organs damage. Repeatedexposure to a highly toxic material may produce general deterioration of health by an accumulation in one or many humanorgans.


Eye Contact:Check for and remove any contact lenses. Immediately flush eyes with running water for at least 15 minutes, keeping eyelidsopen. Cold water may be used. Get medical attention immediately.










Flash Points: CLOSED CUP: 50°C (122°F). OPEN CUP: 60°C (140°F).

Flammable Limits: The greatest known range is LOWER: 6% UPPER: 36.5% (Methyl alcohol)


Fire Hazards in Presence of Various Substances:Flammable in presence of open flames and sparks, of heat. Non-flammable in presence of shocks, of oxidizing materials, ofreducing materials, of combustible materials, of organic materials, of metals, of acids, of alkalis.



Special Remarks on Fire Hazards:Explosive in the form of vapor when exposed to heat or flame. Vapor may travel considerable distance to source of ignitionand flash back. When heated to decomposition, it emits acrid smoke and irritating fumes. CAUTION: MAY BURN WITH NEARINVISIBLE FLAME (Methyl alcohol)

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Special Remarks on Explosion Hazards:Reaction with peroxide, nitrogen dioxide, and permformic acid can cause an explosion. (Formaldehyde gas)



Large Spill:Flammable liquid. Poisonous liquid. Keep away from heat. Keep away from sources of ignition. Stop leak if without risk.Absorb with DRY earth, sand or other non-combustible material. Do not get water inside container. Do not touch spilledmaterial. Use water spray to reduce vapors. Prevent entry into sewers, basements or confined areas; dike if needed. Call forassistance on disposal. Neutralize the residue with a dilute solution of sodium carbonate. Be careful that the product is notpresent at a concentration level above TLV. Check TLV on the MSDS and with local authorities.


Precautions:Keep away from heat. Keep away from sources of ignition. Ground all equipment containing material. Do not ingest. Donot breathe gas/fumes/ vapor/spray. In case of insufficient ventilation, wear suitable respiratory equipment. If ingested,seek medical advice immediately and show the container or the label. Avoid contact with skin and eyes. Keep away fromincompatibles such as oxidizing agents, reducing agents, acids, alkalis, moisture.




Personal Protection:Safety glasses. Lab coat. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Gloves (impervious).


Exposure Limits:Formaldehyde gas STEL: 0.3 (ppm) from ACGIH (TLV) [United States] STEL: 0.37 (mg/m3) from ACGIH (TLV) [United States]TWA: 0.75 STEL: 2 (ppm) from OSHA (PEL) [United States] TWA: 2 STEL: 2 (ppm) [United Kingdom (UK)] TWA: 2.5 STEL:2.5 (mg/m3) [United Kingdom (UK)] Methyl alcohol TWA: 200 from OSHA (PEL) [United States] TWA: 200 STEL: 250 (ppm)from ACGIH (TLV) [United States] [1999] STEL: 250 from NIOSH [United States] TWA: 200 STEL: 250 (ppm) from NIOSHSKIN TWA: 200 STEL: 250 (ppm) [Canada] Consult local authorities for acceptable exposure limits.



Odor: Pungent. Suffocating. (Strong.)


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Color: Clear Colorless.

pH (1% soln/water): 3 [Acidic.] pH of the solution as is.


Melting Point: -15°C (5°F)

Critical Temperature: The lowest known value is 240°C (464°F) (Methyl alcohol).




Volatility: 100% (w/w).

Odor Threshold: The highest known value is 100 ppm (Methyl alcohol)


Ionicity (in Water): Non-ionic.


Solubility:Easily soluble in cold water, hot water. Soluble in diethyl ether, acetone, alcohol




Conditions of Instability: Heat, ignition sources (flames, sparks), incompatible materials

Incompatibility with various substances:Reactive with oxidizing agents, reducing agents, acids, alkalis. Slightly reactive to reactive with metals.


Special Remarks on Reactivity:Also incompatible with urea, phenol, isocyanates, anhydrides, amines, AZO compounds, carbonyl compounds, oxides(e.g.nitrogen dioxide), performic acid, dithiocarbmates, or peroxides. Polymerization can be inhibited by the addition of methanol orstabilizers such as hydorxypropyl methyl cellulose, methyl ethyl celluloses, or isophthalobisguanamine.





Toxicity to Animals:Acute oral toxicity (LD50): 42 mg/kg [Mouse]. (Formaldehyde) Acute dermal toxicity (LD50): 15800 mg/kg [Rabbit]. (Methylalcohol). Acute toxicity of the mist(LC50): 454000 mg/m 4 hours [Mouse]. (Formaldehyde) 3

Chronic Effects on Humans:CARCINOGENIC EFFECTS: Classified A2 (Suspected for human.) by ACGIH, 2A (Probable for human.) by IARC[Formaldehyde]. MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells. [Formaldehyde]. Mutagenic for bacteriaand/or yeast. [Formaldehyde]. Mutagenic for mammalian somatic cells. [Methyl alcohol]. Mutagenic for bacteria and/oryeast. [Methyl alcohol]. TERATOGENIC EFFECTS: Classified POSSIBLE for human [Methyl alcohol]. DEVELOPMENTALTOXICITY: Not available May cause damage to the following organs: kidneys, liver, central nervous system (CNS).

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Other Toxic Effects on Humans:Very hazardous in case of ingestion, . Hazardous in case of skin contact (irritant, sensitizer, permeator), of eye contact(corrosive), of inhalation (lung corrosive). Slightly hazardous in case of skin contact (corrosive).

Special Remarks on Toxicity to Animals:Formaldehyde: LD50 [Rabbit] - Route: Skin; Dose: 270 ul/kg

Special Remarks on Chronic Effects on Humans:Exposure to Formaldehyde and Methanol may affect genetic material (mutagenic). Exposure to Formaldehyde and Methanolmay cause adverse reproductive effects and birth defects(teratogenic). Adverse reproductive effects of Formaldehyde as wellas Methanol are primarily based on animal studies. Very few human studies have been done on the adverse reproductiveeffects from exposure to Formaldehyde. Studies produced a weak association (limited evidence) between advese humanfemale reproductive effects and occupational exposure. Furthermore, no human data could be found on adverse reproductiveeffects from occupational exposure to Methanol. Exposure to Formaldehyde may cause cancer.

Special Remarks on other Toxic Effects on Humans:Acute Potential Health Effects: Skin: Corrosive. Causes skin irritation which may range from mild to severe with possible burnsdepending on the extent of exposure and concentration of solution. Other symptoms may include brownish discoloration of theskin, urticaria, and pustulovesicffular eruptions. May be absorbed through skin with symptoms paralleling those of ingestion.Eyes: Corrosive. Contact with liquid causes severe eye irritation and burns. It may cause irreversible eye damage (severecorneal Solutions containing low formaldehyde concentrations may produce transient discomfort and irritation. Inhalation:Causes irrititation of the respiratory tract (nose, throat, airways). Symptoms may include dry and sore mouth and throat,thirst, and sleep disturbances, difficulty breathing, shortness of breath, coughing, sneezing, wheezing rhinitis, chest tightness,pulmonary edema, bronchitis, tracheitis, laryngospasm, pneumonia, palpitations. It may also affect metabolism weightloss, metabolic acidosis), behavior/central nervous system (excitement, central nervous system depression, somnolence,convulsions, stupor, aggression, headache, weakness, dizziness, drowsiness, coma), peripheral nervous system, and blood.Ingestion: Harmful if swallowed. May be fatal. Causes gastrointestinal irritation with nausea, vomiting (possibly with blood),diarrhea, severe pain in mouth, throat and stomach, and possible corrosive injury to the gastrointestinal mucosa/ulcerationor bleeding from stomach. May also affect the liver(jaundice), urinary system/kidneys (difficulty urinating, albuminuria,hematuria, anuria), blood, endocrine system, respiration (respiratory obstruction, pulmonary edema, bronchiolar obstruction),cardiovascular system (hypotension), metabolism (metabolic acidosis), eyes (retinal changes, visual field changes), andbehavior/central nervous system (symptoms similar to those for inhalation). Contains Methanol which may cause blindness ifswallowed. Chronic Potential Health Effects: Skin: Prolonged or repeated exposure may cause contact dermatits both irritantand allergic. It may also cause skin discoloration. Inhalation: Although there is no clear evidence, prolonged or repeatedexposure may induce allergic asthma. Other effects are similar to that of acute exposure. Ingestion: Prolonged or repeatedingestion may cause gastrointestinal tract irritation and ulceration or bleeding from the stomach. Other effects may be similarto that of acute ingestion.






Special Remarks on the Products of Biodegradation:Methanol in water is rapidly biodegraded and volatilized. Aquatic hydrolysis, oxidation, photolysis, adsorption to sediment, andbioconcentration are not significant fate processes. The half-life of methanol in surfact water ranges from 24 hrs. to 168 hrs.Based on its vapor pressure, methanol exists almost entirely in the vapor phase in the ambient atmosphere. It is degraded byreaction with photochemically produced hydroxyl radicals and has an estimated half-life of 17.8 days. Methanol is physicallyremoved from air by rain due to its solubility. Methanol can react with NO2 in pollulted to form methyl nitrate. The half-life ofmethanol in air ranges from 71 hrs. (3 days) to 713 hrs. (29.7 days) based on photooxidation half-life in air. (Methyl alcohol)


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DOT Classification:CLASS 3: Flammable liquid. Class 8: Corrosive material

Identification: : Formaldehyde Solution, flammable (Methyl alcohol) UNNA: 1198 PG: III



Federal and State Regulations:California prop. 65: This product contains the following ingredients for which the State of California has found to cause cancer,birth defects or other reproductive harm, which would require a warning under the statute: Formaldehyde California prop.65 (no significant risk level): Formaldehyde: 0.04 mg/day (inhalation) California prop. 65: This product contains the followingingredients for which the State of California has found to cause cancer which would require a warning under the statute:Formaldehyde Solution Connecticut hazardous material survey.: Formaldehyde; Methyl alcohol Illinois toxic substancesdisclosure to employee act: Formaldehyde; Methyl alcohol Illinois chemical safety act: Formaldehyde; Methyl alcohol NewYork release reporting list: Formaldehyde; Methyl alcohol Rhode Island RTK hazardous substances: Formaldehyde; Methylalcohol Pennsylvania RTK: Formaldehyde; Methyl alcohol Minnesota: Formaldehyde gas; Methyl alcohol MassachusettsRTK: Formaldehyde; Methyl alcohol Massachusetts spill list: Formaldehyde; Methyl alcohol New Jersey: Formaldehyde;Methyl alcohol New Jersey spill list: Formaldehyde; Methyl alcohol Louisiana RTK reporting list: Formaldehyde Louisiana spillreporting: Formaldehyde; Methyl alcohol California Director's List of Hazardous Substances: Formaldehyde; Methyl alcoholTSCA 8(b) inventory: Formaldehyde gas; Methyl alcohol; Water TSCA 4(f) priority risk review: Formaldehyde, Reagnt, ACSSARA 302/304/311/312 extremely hazardous substances: Formaldehyde SARA 313 toxic chemical notification and releasereporting: Formaldehyde; Methyl alcohol CERCLA: Hazardous substances.: Formaldehyde: 100 lbs. (45.36 kg); Methylalcohol: 5000 lbs. (2268 kg);



WHMIS (Canada):CLASS B-3: Combustible liquid with a flash point between 37.8°C (100°F) and 93.3°C (200°F). CLASS D-1A: Material causingimmediate and serious toxic effects (VERY TOXIC). CLASS D-2A: Material causing other toxic effects (VERY TOXIC).

DSCL (EEC):

HMIS (U.S.A.):

Health Hazard: 3

Fire Hazard: 2

Reactivity: 0

Personal Protection: G


Health: 3

Flammability: 2

Reactivity: 0

Specific hazard:

p. 7

Protective Equipment:Gloves (impervious). Lab coat. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Wearappropriate respirator when ventilation is inadequate. Safety glasses.




Created: 10/09/2005 05:35 PM

Last Updated: 05/21/2013 12:00 PM


**** MATERIAL SAFETY DATA SHEET ****

2-AMINO-8-NAPHTHOL-6-SULFONIC ACID(GAMMA ACID)

**** SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION ****

MSDS Name: 2-AMINO-8-NAPHTHOL-6-SULFONIC ACID(GAMMA ACID)

**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****

+----------------+--------------------------------------+----------+-

----------+-----------+---------------+

| CAS# | Chemical Name | % |

EINECS# |Haz Symbols| Risk Phrases |

|----------------|--------------------------------------|----------|-

----------|-----------|---------------+

| 90-51-7 |2-AMINO-8-NAPHTHOL-6-SULFONIC ACID| | |

| | (GAMMA ACID)| | |

|

| | | |

| |

+----------------+--------------------------------------+----------+-

----------+-----------+---------------+

Hazard Symbols: None Listed.

Risk Phrases: None Listed.

**** SECTION 3 - HAZARDS IDENTIFICATION ****

EMERGENCY OVERVIEW

Not available.


The toxicological properties of this material have not been

investigated. Use appropriate procedures to prevent opportunities

for direct contact with the skin or eyes and to prevent inhalation.

**** SECTION 4 - FIRST AID MEASURES ****

Eyes:

Flush eyes with plenty of water for at least 15 minutes,

occasionally lifting the upper and lower eyelids. Get medical

aid

immediately.

Skin:

Get medical aid. Flush skin with plenty of water for at least

15

minutes while removing contaminated clothing and shoes. Remove

contaminated clothing and shoes.

Ingestion:

If victim is conscious and alert, give 2-4 cupfuls of milk or

water.

Get medical aid immediately.

Inhalation:

Get medical aid immediately. Remove from exposure and move to

fresh

air immediately. If not breathing, give artificial respiration.

If

breathing is difficult, give oxygen.

Notes to Physician:

**** SECTION 5 - FIRE FIGHTING MEASURES ****

General Information:

As in any fire, wear a self-contained breathing apparatus in

pressure-demand, MSHA/NIOSH (approved or equivalent), and full

protective gear. During a fire, irritating and highly toxic

gases

may be generated by thermal decomposition or combustion.

Extinguishing Media:

Use agent most appropriate to extinguish fire.

**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****

General Information: Use proper personal protective equipment as

indicated

in Section 8.

Spills/Leaks:

Clean up spills immediately, observing precautions in the

Protective

Equipment section.

**** SECTION 7 - HANDLING and STORAGE ****

Handling:

Wash thoroughly after handling. Remove contaminated clothing

and

wash before reuse. Avoid contact with eyes, skin, and clothing.

Avoid

ingestion and inhalation.

Storage:

Store in a cool, dry place. Keep container closed when not in

use.

**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****

Engineering Controls:

Use process enclosure, local exhaust ventilation, or other

engineering controls to control airborne levels.

Personal Protective Equipment

Eyes:

Wear chemical goggles.

Skin:

Wear appropriate protective gloves to prevent

skin

exposure.

Clothing:

Wear appropriate protective clothing to minimize

contact with skin.

Respirators:

A respiratory protection program that meets

OSHA's 29

CFR 1910.134 and ANSI Z88.2 requirements or

European

Standard EN 149 must be followed whenever

workplace

conditions warrant a respirator's use.

**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****

Physical State: Powder

Color: Gray powder


pH: Not available.


Viscosity: Not available.


Freezing/Melting Point: 0 deg C

Autoignition Temperature: 340 deg C ( 644.00 deg F)

Flash Point: Not available.

Explosion Limits, lower: Not available.

Explosion Limits, upper: Not available.

Decomposition Temperature:

Solubility in water: slightly soluble

Specific Gravity/Density:

Molecular Formula: C10H9NO4SMolecular Weight: 239

**** SECTION 10 - STABILITY AND REACTIVITY ****

Chemical Stability:

Stable under normal temperatures and pressures.

Conditions to Avoid:

Incompatible materials, strong oxidants.

Incompatibilities with Other Materials:

Not available.

Hazardous Decomposition Products:

Irritating and toxic fumes and gases.

Hazardous Polymerization: Not available.

**** SECTION 11 - TOXICOLOGICAL INFORMATION ****

RTECS#:

CAS# 90-51-7 unlisted.

LD50/LC50:

Not available.

Carcinogenicity:

2-AMINO-8-NAPHTHOL-6-SULFONIC ACID(GAMMA ACID)

Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.

See actual entry in RTECS for complete information.

**** SECTION 12 - ECOLOGICAL INFORMATION ****

**** SECTION 13 - DISPOSAL CONSIDERATIONS ****

Dispose of in a manner consistent with federal, state, and local

regulations.

**** SECTION 14 - TRANSPORT INFORMATION ****

IATA

No information available.

IMO


RID/ADR


**** SECTION 15 - REGULATORY INFORMATION ****

European/International Regulations

European Labeling in Accordance with EC Directives

Hazard Symbols: Not available.

Risk Phrases:

Safety Phrases:

S 24/25 Avoid contact with skin and eyes.

WGK (Water Danger/Protection)

CAS# 90-51-7

United Kingdom Occupational Exposure Limits

United Kingdom Maximum Exposure Limits

Canada

CAS# 90-51-7 is listed on Canada's DSL List.

CAS# 90-51-7 is not listed on Canada's Ingredient Disclosure

List.

Exposure Limits

US FEDERAL

TSCA

CAS# 90-51-7 is listed on the TSCA inventory.

**** SECTION 16 - ADDITIONAL INFORMATION ****

MSDS Creation Date: 7/16/1996 Revision #0 Date: Original.

The information above is believed to be accurate and represents the

best

information currently available to us. However, we make no warranty

of

merchantability or any other warranty, express or implied, with

respect to

such information, and we assume no liability resulting from its use.

Users

should make their own investigations to determine the suitability

of the

information for their particular purposes. In no way shall the

company be

liable for any claims, losses, or damages of any third party or for

lost

profits or any special, indirect, incidental, consequential or

exemplary

damages, howsoever arising, even if the company has been advised of

the possibility of such damages.

---------------------------------------------------------------------

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Material Safety Data SheetPotassium chloride MSDS


Product Name: Potassium chloride

Catalog Codes: SLP3334, SLP5143, SLP2317, SLP4126

CAS#: 7447-40-7

RTECS: TS8050000

TSCA: TSCA 8(b) inventory: Potassium chloride

CI#: Not available.

Synonym:

Chemical Name: Potassium Chloride

Chemical Formula: KCl









Composition:


Potassium chloride 7447-40-7 100

Toxicological Data on Ingredients: Potassium chloride: ORAL (LD50): Acute: 2500 mg/kg [Guinea pig]. 2600 mg/kg [Rat].1500 mg/kg [Mouse].


Potential Acute Health Effects: Slightly hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, ofinhalation.

Potential Chronic Health Effects:CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells. Mutagenic forbacteria and/or yeast. TERATOGENIC EFFECTS: Not available. DEVELOPMENTAL TOXICITY: Not available. The substancemay be toxic to blood, cardiovascular system. Repeated or prolonged exposure to the substance can produce target organsdamage.


Eye Contact:


p. 2

Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15minutes. Cold water may be used. Get medical attention.

















Special Remarks on Explosion Hazards: May result in explosion with potassium permanganate and sulfuric acid.





Precautions:Do not ingest. Do not breathe dust. If ingested, seek medical advice immediately and show the container or the label. Keepaway from incompatibles such as oxidizing agents, acids, moisture.

Storage: Keep container tightly closed. Keep container in a cool, well-ventilated area. Hygroscopic

p. 3








Odor: Odorless.

Taste: Saline. (Strong.)


Color: White.













Solubility:Soluble in cold water, hot water. Very slightly soluble in methanol, n-octanol.





Incompatibility with various substances: Reactive with oxidizing agents, acids.

p. 4


Special Remarks on Reactivity:Hygroscopic. Incompatible with KMnO4, H2SO4, BrF3, and BrCl3. May react violently with BrF3.






Chronic Effects on Humans: May cause damage to the following organs: blood, cardiovascular system.



Special Remarks on Chronic Effects on Humans:May affect genetic material. Passes through the placental barrier in animal.

Special Remarks on other Toxic Effects on Humans:Actute Potential Health Effects: Skin: May cause skin irritation Eye: Dust may cause eye irritation. Inhalation: Dust may causerespiratory tract irritation. Low hazard for usual industrial handling Ingestion: May affect behavior (coma, change in motoractivity, listlessness, vertigo, mental confusion, paresthesias, general weakness, flaccid paralysis), metabolism, blood (changein clotting factor, electrolytic imbalance), cardiovascular (hypotension, circulatory disturbances, cardiac arrhythmias, heartblock), and respiratory, gastrointestinal (irritation of GI tract, nausea, vomiting, diarrhea, abdominal discomfort, purging), andurinary(impairment of renal function) systems. Acute potassium intoxication by mouth is rare because large single dosesusually induce vomiting, and because in the absence of pre-existing kidney damage potassium is rapidly excreted. Maximalnontoxic oral dose of KCl in man varies from 0.2g to 1 g of potassium/kg/day depending upon efficiency of individual excretorymechanism; lower doses sometimes cause impairment of renal function as shown by reduced inulin, and urea clearance.Chronic Potential Health Effects: May affect blood and cardiovascular system.












p. 5



Federal and State Regulations: TSCA 8(b) inventory: Potassium chloride




DSCL (EEC):R36- Irritating to eyes. S26- In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S39-Wear eye/face protection.

HMIS (U.S.A.):

Health Hazard: 1

Fire Hazard: 0

Reactivity: 0



Health: 1

Flammability: 0

Reactivity: 0

Specific hazard:





Created: 10/10/2005 08:49 PM

Last Updated: 05/21/2013 12:00 PM


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Material Safety Data Sheetm-Toluidine MSDS


Product Name: m-Toluidine

Catalog Codes: SLT4096

CAS#: 108-44-1

RTECS: XU2800000

TSCA: TSCA 8(b) inventory: m-Toluidine

CI#: Not available.

Synonym: 3-Aminotoluene; 3-Methylaniline; 3-Amino-1-methylbenzene; 3-Aminophenylmethane; 3-Methylbenzenamine; 3-Toluidine; Aniline, 3-methyl-;Benzenamine, 3-methyl-; m-Aminotoluene; m-Methylaniline; m-Methylbenzenamine; M-Tolylamine

Chemical Name: m-Toluidine










Composition:


{m-}Toluidine 108-44-1 100

Toxicological Data on Ingredients: m-Toluidine: ORAL (LD50): Acute: 450 mg/kg [Rat]. 740 mg/kg [Mouse]. 750 mg/kg[Rabbit]. DERMAL (LD50): Acute: 3250 mg/kg [Rabbit].


Potential Acute Health Effects:Hazardous in case of eye contact (irritant), of ingestion, of inhalation. Slightly hazardous in case of skin contact (irritant,permeator). Severe over-exposure can result in death.

Potential Chronic Health Effects:CARCINOGENIC EFFECTS: A4 (Not classifiable for human or animal.) by ACGIH. MUTAGENIC EFFECTS: Not available.TERATOGENIC EFFECTS: Not available. DEVELOPMENTAL TOXICITY: Not available. The substance may be toxicto blood, kidneys, the nervous system, skin, eyes, central nervous system (CNS). Repeated or prolonged exposure tothe substance can produce target organs damage. Repeated exposure to a highly toxic material may produce generaldeterioration of health by an accumulation in one or many human organs.


p. 2


Eye Contact:Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15minutes. Cold water may be used. WARM water MUST be used. Get medical attention.










Flash Points: CLOSED CUP: 86.111°C (187°F).




Explosion Hazards in Presence of Various Substances:Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the product inpresence of static discharge: Not available. Slightly explosive in presence of heat.


Special Remarks on Fire Hazards:Toluidine in Triethylamine solution are ignited rapidly by fuming Nitric acid at tempertures of minus 76 deg. C or lower.

Special Remarks on Explosion Hazards:When heated vapors may form explosive mixtures with air. Containers may explode then heated.



Large Spill:Combustible material. Poisonous liquid. Keep away from heat. Keep away from sources of ignition. Stop leak if without risk.Do not get water inside container. Do not touch spilled material. Use water spray to reduce vapors. Prevent entry into sewers,basements or confined areas; dike if needed. Call for assistance on disposal.

p. 3


Precautions:Keep locked up.. Keep away from heat. Keep away from sources of ignition. Ground all equipment containing material. Donot ingest. Do not breathe gas/fumes/ vapor/spray. Avoid contact with eyes. Wear suitable protective clothing. In case ofinsufficient ventilation, wear suitable respiratory equipment. If ingested, seek medical advice immediately and show thecontainer or the label. Keep away from incompatibles such as oxidizing agents, acids.

Storage:Keep container in a cool, well-ventilated area. Keep container tightly closed and sealed until ready for use. Avoid all possiblesources of ignition (spark or flame).





Exposure Limits:TWA: 2 (ppm) from ACGIH (TLV) [United States] SKIN TWA: 2 (ppm) from OSHA (PEL) [United States] SKIN TWA: 9 (mg/m3) from OSHA (PEL) [United States] SKIN TWA: 2 (ppm) [Canada] SKIN TWA: 8.8 (mg/m3) [Canada] SKIN Consult localauthorities for acceptable exposure limits.



Odor: Aromatic. Amine like.



Color: Colorless to light yellow.












p. 4


Solubility:Soluble in diethyl ether, acetone. Very slightly soluble in cold water. Very soluble in ethanol, benzene. Infinitely soluble inCarbon Tetrachloride, Heptane. Solubility in water: 1.5X10+4 mg/l












Toxicity to Animals:Acute oral toxicity (LD50): 450 mg/kg [Rat]. Acute dermal toxicity (LD50): 3250 mg/kg [Rabbit].

Chronic Effects on Humans:CARCINOGENIC EFFECTS: A4 (Not classifiable for human or animal.) by ACGIH. May cause damage to the followingorgans: blood, kidneys, the nervous system, skin, eyes, central nervous system (CNS).

Other Toxic Effects on Humans:Hazardous in case of ingestion, of inhalation. Slightly hazardous in case of skin contact (irritant, permeator).



Special Remarks on other Toxic Effects on Humans:Acute Potential Health Effects: Skin: Causes skin irritation. It may be absorbed through the skin and affect behavior/centralnervous system (CNS) causing CNS depression. Absorption into the body can also lead to Methemoglobinemia (interferencewith the ability of the blood to carry oxygen) which causes cyanosis, a bluish discoloration the skin and lips due to defficientoxygenation of the blood. Eyes: Causes eye irritation. Inhalation: It may cause anoxia characterized by CNS depression(nausea, weakness, headache, dizziness, drowsiness, convulsions, unconciousness, confusion), methemoglobinemia(interference with the ability of the blood to carry oxygen) which causes cyanosis (a bluish discoloration of the skin and lips),shortness of breath, rapid heart rate, and chocolate-brown colored blood. It may even cause coma and death. Ingestion:Harmful if swallowed. May cause nausea, vomiting, diarrhea, and loss of appetite, Methemoglobinemia. Symptoms mayinclude weakness, headache, drowsiness, dyspnea, cyanosis, chocolate-brown colored blood, hypotension, rapid heart rate,and jaundice, and other symptoms similar to that of inhalation. Chronic Potential Health Effects: Skin: Prolonged or repeatedskin contact may cause defatting dermatitis. Inhalation and Ingestion: Prolonge or repeated ingestion and inhalation maycause anorexia, and kidney and bladder damage causing painful bloody urine. May damage the nervous system causingsymptoms similar to acute inhalation and ingestion. It may also affect the blood causing Methemoglobinemia, cyanosis, andanemia.



p. 5









Identification: : Toluidine UNNA: 1708 PG: II



Federal and State Regulations:Illinois toxic substances disclosure to employee act: m-Toluidine Pennsylvania RTK: m-Toluidine Minnesota: m-ToluidineMassachusetts RTK: m-Toluidine New Jersey: m-Toluidine California Director's List of Hazardous Substances: m-ToluidineTSCA 8(b) inventory: m-Toluidine TSCA 8(a) PAIR: m-Toluidine TSCA 8(d) H and S data reporting: m-Toluidine: effectivedate: 3/11/94; Sunset date: 6/30/98



WHMIS (Canada):CLASS B-3: Combustible liquid with a flash point between 37.8°C (100°F) and 93.3°C (200°F). CLASS D-1A: Material causingimmediate and serious toxic effects (VERY TOXIC).

DSCL (EEC):

HMIS (U.S.A.):

Health Hazard: 2

Fire Hazard: 2

Reactivity: 0



Health: 2

Flammability: 2

Reactivity: 0

Specific hazard:

Protective Equipment:

p. 6

Gloves. Lab coat. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Wear appropriate respiratorwhen ventilation is inadequate. Splash goggles.




Created: 10/11/2005 12:47 PM

Last Updated: 05/21/2013 12:00 PM


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Material Safety Data SheetMethyl alcohol MSDS


Product Name: Methyl alcohol

Catalog Codes: SLM3064, SLM3952

CAS#: 67-56-1

RTECS: PC1400000

TSCA: TSCA 8(b) inventory: Methyl alcohol


Synonym: Wood alcohol, Methanol; Methylol; WoodSpirit; Carbinol

Chemical Name: Methanol

Chemical Formula: CH3OH









Composition:


Methyl alcohol 67-56-1 100

Toxicological Data on Ingredients: Methyl alcohol: ORAL (LD50): Acute: 5628 mg/kg [Rat]. DERMAL (LD50): Acute: 15800mg/kg [Rabbit]. VAPOR (LC50): Acute: 64000 ppm 4 hours [Rat].


Potential Acute Health Effects:Hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, of inhalation. Slightly hazardous in case ofskin contact (permeator). Severe over-exposure can result in death.

Potential Chronic Health Effects:Slightly hazardous in case of skin contact (sensitizer). CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS:Mutagenic for mammalian somatic cells. Mutagenic for bacteria and/or yeast. TERATOGENIC EFFECTS: ClassifiedPOSSIBLE for human. DEVELOPMENTAL TOXICITY: Not available. The substance is toxic to eyes. The substance may betoxic to blood, kidneys, liver, brain, peripheral nervous system, upper respiratory tract, skin, central nervous system (CNS),optic nerve. Repeated or prolonged exposure to the substance can produce target organs damage. Repeated exposure to ahighly toxic material may produce general deterioration of health by an accumulation in one or many human organs.



p. 2

Eye Contact:Check for and remove any contact lenses. Immediately flush eyes with running water for at least 15 minutes, keeping eyelidsopen. Cold water may be used. Get medical attention.











Flammable Limits: LOWER: 6% UPPER: 36.5%


Fire Hazards in Presence of Various Substances:Highly flammable in presence of open flames and sparks, of heat. Non-flammable in presence of shocks.

Explosion Hazards in Presence of Various Substances:Risks of explosion of the product in presence of mechanical impact: Not available. Explosive in presence of open flames andsparks, of heat.


Special Remarks on Fire Hazards:Explosive in the form of vapor when exposed to heat or flame. Vapor may travel considerable distance to source of ignitionand flash back. When heated to decomposition, it emits acrid smoke and irritating fumes. CAUTION: MAY BURN WITH NEARINVISIBLE FLAME

Special Remarks on Explosion Hazards:Forms an explosive mixture with air due to its low flash point. Explosive when mixed with Choroform + sodium methoxide anddiethyl zinc. It boils violently and explodes.


p. 3


Large Spill:Flammable liquid. Poisonous liquid. Keep away from heat. Keep away from sources of ignition. Stop leak if without risk.Absorb with DRY earth, sand or other non-combustible material. Do not get water inside container. Do not touch spilledmaterial. Use water spray to reduce vapors. Prevent entry into sewers, basements or confined areas; dike if needed. Callfor assistance on disposal. Be careful that the product is not present at a concentration level above TLV. Check TLV on theMSDS and with local authorities.


Precautions:Keep locked up.. Keep away from heat. Keep away from sources of ignition. Ground all equipment containing material. Donot ingest. Do not breathe gas/fumes/ vapor/spray. Wear suitable protective clothing. In case of insufficient ventilation, wearsuitable respiratory equipment. If ingested, seek medical advice immediately and show the container or the label. Avoidcontact with skin and eyes. Keep away from incompatibles such as oxidizing agents, metals, acids.






Exposure Limits:TWA: 200 from OSHA (PEL) [United States] TWA: 200 STEL: 250 (ppm) from ACGIH (TLV) [United States] [1999] STEL: 250from NIOSH [United States] TWA: 200 STEL: 250 (ppm) from NIOSH SKIN TWA: 200 STEL: 250 (ppm) [Canada] Consultlocal authorities for acceptable exposure limits.



Odor: Alcohol like. Pungent when crude.



Color: Colorless.



Melting Point: -97.8°C (-144°F)

Critical Temperature: 240°C (464°F)

p. 4





Odor Threshold: 100 ppm

Water/Oil Dist. Coeff.: The product is more soluble in water; log(oil/water) = -0.8

Ionicity (in Water): Non-ionic.


Solubility: Easily soluble in cold water, hot water.




Conditions of Instability: Heat, ingnition sources, incompatible materials

Incompatibility with various substances: Reactive with oxidizing agents, metals, acids.


Special Remarks on Reactivity:Can react vigorously with oxidizers. Violent reaction with alkyl aluminum salts, acetyl bromide, chloroform + sodium methoxide,chromic anhydride, cyanuirc chlorite, lead perchlorate, phosphorous trioxide, nitric acid. Exothermic reaction with sodiumhydroxide + chloroform. Incompatible with beryllium dihydride, metals (potassium and magnesium), oxidants (bariumperchlorate, bromine, sodium hypochlorite, chlorine, hydrogen peroxide), potassium tert-butoxide, carbon tetrachloride, alkalimetals, metals (aluminum, potassium magnesium, zinc), and dichlormethane. Rapid autocatalytic dissolution of aluminum,magnesium or zinc in 9:1 methanol + carbon tetrachloride - sufficiently vigorous to be rated as potentially hazardous. Mayattack some plastics, rubber, and coatings.





Toxicity to Animals:WARNING: THE LC50 VALUES HEREUNDER ARE ESTIMATED ON THE BASIS OF A 4-HOUR EXPOSURE. Acute oraltoxicity (LD50): 5628 mg/kg [Rat]. Acute dermal toxicity (LD50): 15800 mg/kg [Rabbit]. Acute toxicity of the vapor (LC50):64000 4 hours [Rat].

Chronic Effects on Humans:MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells. Mutagenic for bacteria and/or yeast. TERATOGENICEFFECTS: Classified POSSIBLE for human. Causes damage to the following organs: eyes. May cause damage to thefollowing organs: blood, kidneys, liver, brain, peripheral nervous system, upper respiratory tract, skin, central nervous system(CNS), optic nerve.

Other Toxic Effects on Humans:Hazardous in case of skin contact (irritant), of ingestion, of inhalation. Slightly hazardous in case of skin contact (permeator).


Special Remarks on Chronic Effects on Humans:

p. 5

Passes through the placental barrier. May affect genetic material. May cause birth defects and adverse reproductiveeffects(paternal and maternal effects and fetotoxicity ) based on animal studies.

Special Remarks on other Toxic Effects on Humans:


Ecotoxicity: Ecotoxicity in water (LC50): 29400 mg/l 96 hours [Fathead Minnow].




Special Remarks on the Products of Biodegradation:Methanol in water is rapidly biodegraded and volatilized. Aquatic hydrolysis, oxidation, photolysis, adsorption to sediment, andbioconcentration are not significant fate processes. The half-life of methanol in surfact water ranges from 24 hrs. to 168 hrs.Based on its vapor pressure, methanol exists almost entirely in the vapor phase in the ambient atmosphere. It is degraded byreaction with photochemically produced hydroxyl radicals and has an estimated half-life of 17.8 days. Methanol is physicallyremoved from air by rain due to its solubility. Methanol can react with NO2 in pollulted to form methyl nitrate. The half-life ofmethanol in air ranges from 71 hrs. (3 days) to 713 hrs. (29.7 days) based on photooxidation half-life in air.





Identification: : Methyl alcohol UNNA: 1230 PG: II



Federal and State Regulations:Connecticut hazardous material survey.: Methyl alcohol Illinois toxic substances disclosure to employee act: Methyl alcoholIllinois chemical safety act: Methyl alcohol New York release reporting list: Methyl alcohol Rhode Island RTK hazardoussubstances: Methyl alcohol Pennsylvania RTK: Methyl alcohol Minnesota: Methyl alcohol Massachusetts RTK: Methylalcohol Massachusetts spill list: Methyl alcohol New Jersey: Methyl alcohol New Jersey spill list: Methyl alcohol Louisianaspill reporting: Methyl alcohol California Directors List of Hazardous Substances (8CCR 339): Methyl alcohol TennesseHazardous Right to Know : Methyl alcohol TSCA 8(b) inventory: Methyl alcohol SARA 313 toxic chemical notification andrelease reporting: Methyl alcohol CERCLA: Hazardous substances.: Methyl alcohol: 5000 lbs. (2268 kg)



WHMIS (Canada):CLASS B-2: Flammable liquid with a flash point lower than 37.8°C (100°F). CLASS D-1B: Material causing immediate andserious toxic effects (TOXIC). CLASS D-2A: Material causing other toxic effects (VERY TOXIC). Class D-2B: Material causingother toxic effects (TOXIC).

p. 6

DSCL (EEC):R11- Highly flammable. R23/24/25- Toxic by inhalation, in contact with skin and if swallowed. R39- Danger of very seriousirreversible effects. R39/23/24/25- Toxic: danger of very serious irreversible effects through inhalation, in contact with skin andif swallowed. S7- Keep container tightly closed. S16- Keep away from sources of ignition - No smoking. S36/37- Wear suitableprotective clothing and gloves. S45- In case of accident or if you feel unwell, seek medical advice immediately (show the labelwhere possible).

HMIS (U.S.A.):

Health Hazard: 2

Fire Hazard: 3

Reactivity: 0



Health: 1

Flammability: 3

Reactivity: 0

Specific hazard:



References:-SAX, N.I. Dangerous Properties of Indutrial Materials. Toronto, Van Nostrand Reinold, 6e ed. 1984. -Material safetydata sheet emitted by: la Commission de la SantÃ© et de la SÃ©curitÃ© du Travail du QuÃ©bec. -Hawley, G.G.. TheCondensed Chemical Dictionary, 11e ed., New York N.Y., Van Nostrand Reinold, 1987. LOLI, HSDB, RTECS, HAZARDTEXT,REPROTOX databases


Created: 10/10/2005 08:23 PM

Last Updated: 05/21/2013 12:00 PM


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Material Safety Data SheetCopper phthalocyanine MSDS


Product Name: Copper phthalocyanine


CAS#: 147-14-8

RTECS: GL8510000

TSCA: TSCA 8(b) inventory: Copper phthalocyanine

CI#: 74160

Synonym: Phthalocyanine Blue Pigment Blue 15;


Chemical Formula: C32H16CuN8









Composition:


Copper phthalocyanine 147-14-8 100

Toxicological Data on Ingredients: Copper phthalocyanine LD50: Not available. LC50: Not available.


Potential Acute Health Effects: Hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, of inhalation.

Potential Chronic Health Effects:Hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, of inhalation. CARCINOGENIC EFFECTS:Not available. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available. DEVELOPMENTALTOXICITY: Not available. The substance is toxic to kidneys, liver. Repeated or prolonged exposure to the substance canproduce target organs damage.





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Products of Combustion: These products are carbon oxides (CO, CO2), nitrogen oxides (NO, NO2...). Some metallic oxides.




Special Remarks on Fire Hazards: Material in powder form, capable of creating a dust explosion.






Precautions:Keep away from heat. Keep away from sources of ignition. Empty containers pose a fire risk, evaporate the residue undera fume hood. Ground all equipment containing material. Do not breathe dust. Wear suitable protective clothing In case ofinsufficient ventilation, wear suitable respiratory equipment If you feel unwell, seek medical attention and show the label whenpossible. Avoid contact with skin and eyes


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Physical state and appearance: Solid. (Microcrystalline solid powder.)




Color: Blue.




















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Polymerization: No.




Chronic Effects on Humans: The substance is toxic to kidneys, liver.

Other Toxic Effects on Humans: Hazardous in case of skin contact (irritant), of ingestion, of inhalation.











Waste Disposal:






Federal and State Regulations:Pennsylvania RTK: Copper phthalocyanine Massachusetts RTK: Copper phthalocyanine TSCA 8(b) inventory: Copperphthalocyanine SARA 313 toxic chemical notification and release reporting: Copper phthalocyanine CERCLA: Hazardoussubstances.: Copper phthalocyanine



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HMIS (U.S.A.):

Health Hazard: 2

Fire Hazard: 1

Reactivity: 0



Health: 2

Flammability: 1

Reactivity: 0

Specific hazard:

Protective Equipment:Gloves. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Splash goggles.




Created: 10/09/2005 04:59 PM

Last Updated: 05/21/2013 12:00 PM


MSDS-HCL PAGE 9A-1 Issued 8/5/1999 Revised 10/27/06

Material Safety Data Sheet(MSDS-HCL)

PRODUCT IDENTIFICATION Product Name Hydrochloric Acid Solution 20 Deg. Be – 31.5%

22 Deg. Be – 35.2% Trade Names and Synonyms Hydrogen Chloride (Aqueous)

Muriatic Acid Manufacturer/Distributor Trans Chem, Inc.

1259 Safe Energy Dr. Port Allen, Louisiana 70767 (225) 389-9133 Various others

Transportation Emergency 800-255-3924 (24 hrs -- CHEM • TEL)

HAZARDOUS COMPONENTS Material or Component CAS No. TLV PEL Hydrochloric Acid 7647-01-0 7mg/m3 5PPM N/A = Not assigned NE = Not established

PHYSICAL DATA Boiling Point 127° F Vapor Pressure 24mm Hg – 20 Deg. Be

100mm Hg – 22 Deg. Be Solubility in Water Complete Specific Gravity 1.16 @ 15.5° C 20 Deg. Be

1.1789 @ 15.5° C 22 Deg. Be Melting Point N/A Vapor Density Similar to Water Evaporation Rate Not Applicable Appearance and Odor Clear Colorless to Yellowish Fuming Liquid, Pungent and Irritating

HAZARDOUS REACTIVITY Stable under ordinary conditions of use and storage. Does not polymerize. Incompatible with aluminum and aluminum alloys, carbon steel, copper and copper alloys, and nylon. Hydrogen gas will be formed if acid contacts metal.

FIRE AND EXPLOSION DATA Flashpoint Not Flammable Extinguishing Media Use any means suitable for extinguishing surrounding fire. Decomposition Products Contact with most metals may produce Hydrogen gas to potentially explosive limits. Unusnal Explosion Containers may explode when heated. Consult the 2000 Emergency Response

Guidebook, Guide 157 for further details.


HEALTH HAZARDS / FIRST AID Inhalation Inhalation causes severe irritation of upper respiratory tract. FA: Remove person to to

fresh air. If not breathing, give artificial respiration. Call physician. Ingestion CORROSIVE ! Ingestion of Hydrochloric Acid can cause burns of the mouth, throat,

esophagus and gastrointestinal tract. FA: DO NOT INDUCE VOMITING. Give large quantities of water or milk of magnesia. Never give anything by mouth to an unconscious person. Get immediate medical attention.

Skin Contact CORROSIVE ! Can cause redness, pain and skin burns. Can cause some tissue destruction. FA: Immediately flush with water.

Eye Contact CORROSIVE ! FA: Continuously flush eyes with large amounts of water for at least 20 minutes. If irritation continues, seek medical attention.

SPILL OR LEAK PROCEDURES Spill/leak In the event of a spill or leak, keep upwind. Ventilate enclosed areas until spill or leak is

contained, neutralized and prepared for removal. Waste disposal Disposal of waste material or residue may be subject to federal, state, or local

regulation. Before transporting waste material see 49 CFR 172.

SPECIAL PROTECTION INFORMATION Ventilation Use only in areas with adequate ventilation. Eye Protection Use chemical safety goggles, plus a safety shield is recommended. Contact lenses

should not be worn when working with this material. Skin Protection Wear impervious protective clothing; i.e., Boots, Gloves, Lab Coat, Apron or Coveralls to

prevent skin contact. Other If working in an area of potential exposure, use an NIOSH approved respirator when

material is fuming and exceeds the TLV.

STORAGE CONDITIONS Store and handle only in containers suitably lined with or constructed of materials specified, by the manufacturer, for the product. Protect against physical damage. Keep separated from incompatible materials.

REGULATORY INFORMATION Proper shipping name Hydrochloric acid Hazard class 8 UN Number UN1789 DOT Label & Placard Corrosive NFPA / HMIS Ratings Health – 3; Flammability – 0; Reactivity – 0 SARA Title III Reporting Sections 302, 311 & 313


The information contained in this Material Safety Data Sheet is based upon available data and believed to be correct; however, as such has been obtained from various sources, including the manufacturer and independent laboratories, it is given without warranty or representation that it is complete, accurate, and can be relied upon. OWEN COMPLIANCE SERVICES, INC. has not attempted to conceal in any manner the deleterious aspects of the product listed herein, but makes no warranty as to such. Further, OWEN COMPLIANCE SERVICES, INC. cannot anticipate nor control the many situations in which the product or this information may be used; there is no guarantee that the health and safety precautions suggested will be proper under all conditions. It is the sole responsibility of each user of the product to determine and comply with the requirements of all applicable laws and regulations regarding its use. This information is given solely for the purposes of safety to persons and property. Any other use of this information is expressly prohibited.

For further information contact: David W. Boston, President OWEN COMPLIANCE SERVICES, INC. 12001 County Road 1000 P.O. Box 765 Godley, TX 76044

Telephone number: 817-551-0660 FAX number: 817-396-4584

MSDS prepared by: Allen M. Sweeney Original publication date: 8/5/1999 Revision date 10/27/06

Safety data for 2,4-diamino-benzenesulphonic acid

Glossary of terms on this data sheet.

The information on this web page is provided to help you to work safely, but it is intended to be an overview of hazards, not a replacement for a full Material Safety Data Sheet (MSDS). MSDS forms can be downloaded from the

web sites of many chemical suppliers.

General Synonyms: 2,4-diaminobenzenesulphonic acid, 2,4-diaminobenzenesulfonic acid, 1,3-phenylenediamine-4-sulphonic acid, o-aminosulfanilic acid, m-phenylenediamine-4-sulphonic acid, 1,3-diaminobenzene-4-sulphonic acid, 1,3-phenylenediamine-4-sulfonic acid, m-phenylenediamine-4-sulfonic acid, 1,3-diaminobenzene-4-sulfonic acid, Molecular formula: C6H8N2O3S CAS No: 88-63-1 EC No: 201-846-5

Physical data Appearance: brownish powder Melting point: Boiling point: Vapour density: Vapour pressure: Specific gravity: Flash point: Explosion limits: Autoignition temperature:

Stability Stable. Incompatible with strong oxidizing agents.

Toxicology Eye and skin irritant. May cause sensitization by skin contact.

http://ptcl.chem.ox.ac.uk/MSDS/glossary/GLOSSARY.html

Toxicity data (The meaning of any toxicological abbreviations which appear in this section is given here.) ORL-RAT LD50 3480 mg kg-1

Risk phrases (The meaning of any risk phrases which appear in this section is given here.) R36 R38 R43.

Transport information (The meaning of any UN hazard codes which appear in this section is given here.) Non-hazardous for air, sea and road freight.

Personal protection Safety glasses, adequate ventilation.

Safety phrases (The meaning of any safety phrases which appear in this section is given here.) S26 S36 S39.

http://ptcl.chem.ox.ac.uk/MSDS/toxicity_abbreviations.html

http://ptcl.chem.ox.ac.uk/MSDS/risk_phrases.html

http://ptcl.chem.ox.ac.uk/MSDS/glossary/un_hazard_codes.html

http://ptcl.chem.ox.ac.uk/MSDS/safety_phrases.html

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Material Safety Data SheetPhosphorus trichloride MSDS


Product Name: Phosphorus trichloride

Catalog Codes: SLP5299

CAS#: 7719-12-2

RTECS: TH3675000

TSCA: TSCA 8(b) inventory: Phosphorus trichloride

CI#: Not available.

Synonym: Phosphine, Trichloro-; Phosphorus Chloride

Chemical Name: Phosphorus Trichloride

Chemical Formula: PCl3









Composition:


Phosphorus trichloride 7719-12-2 100

Toxicological Data on Ingredients: Phosphorus trichloride: ORAL (LD50): Acute: 18 mg/kg [Rat]. VAPOR (LC50): Acute: 50ppm 4 hours [Guinea pig].


Potential Acute Health Effects:Very hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, of inhalation. Hazardous in case ofskin contact (corrosive, permeator), of eye contact (corrosive). Slightly hazardous in case of skin contact (sensitizer). Liquidor spray mist may produce tissue damage particularly on mucous membranes of eyes, mouth and respiratory tract. Skincontact may produce burns. Inhalation of the spray mist may produce severe irritation of respiratory tract, characterized bycoughing, choking, or shortness of breath. Severe over-exposure can result in death. Inflammation of the eye is characterizedby redness, watering, and itching. Skin inflammation is characterized by itching, scaling, reddening, or, occasionally, blistering.

Potential Chronic Health Effects:CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available.DEVELOPMENTAL TOXICITY: Not available. The substance may be toxic to blood, kidneys, lungs, liver, upper respiratorytract. Repeated or prolonged exposure to the substance can produce target organs damage. Repeated or prolonged contactwith spray mist may produce chronic eye irritation and severe skin irritation. Repeated or prolonged exposure to spray mistmay produce respiratory tract irritation leading to frequent attacks of bronchial infection. Repeated exposure to a highly toxicmaterial may produce general deterioration of health by an accumulation in one or many human organs.


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Eye Contact:Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15minutes. Get medical attention immediately.














Explosion Hazards in Presence of Various Substances:Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the product inpresence of static discharge: Not available. Slightly explosive in presence of heat, of moisture.


Special Remarks on Fire Hazards:It may burn, but does not ignite readily. May ignite combustibles (wood, paper, oil, clothing, etc.). Flammable hydrogen gasmay be produced on prolonged contact with metals such as aluminum, tin, lead and zinc.




Large Spill:

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Corrosive liquid. Poisonous liquid. Stop leak if without risk. Absorb with DRY earth, sand or other non-combustible material.Do not get water inside container. Do not touch spilled material. Use water spray curtain to divert vapor drift. Use water sprayto reduce vapors. Prevent entry into sewers, basements or confined areas; dike if needed. Call for assistance on disposal. Becareful that the product is not present at a concentration level above TLV. Check TLV on the MSDS and with local authorities.


Precautions:Keep locked up.. Keep container dry. Keep away from heat. Keep away from sources of ignition. Keep away from directsunlight or strong incandescent light. Do not ingest. Do not breathe gas/fumes/ vapor/spray. Never add water to this product.Avoid shock and friction. In case of insufficient ventilation, wear suitable respiratory equipment. If ingested, seek medicaladvice immediately and show the container or the label. Avoid contact with skin and eyes. Keep away from incompatibles suchas combustible materials, organic materials, metals, acids, moisture.






Exposure Limits:TWA: 0.5 (ppm) from OSHA (PEL) [United States] TWA: 0.2 STEL: 0.5 (ppm) from ACGIH (TLV) [United States] STEL: 0.5(ppm) from NIOSH [United States] STEL: 3 (mg/m3) from NIOSH [United States] TWA: 3 (mg/m3) from OSHA (PEL) [UnitedStates] Consult local authorities for acceptable exposure limits.


Physical state and appearance: Liquid. (Fuming liquid.)

Odor: Pungent. Irritant. Like Hydrochloric acid



Color: Colorless to light yellow. Clear








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Dispersion Properties: See solubility in water, diethyl ether.

Solubility: Soluble in diethyl ether, chloroform, benzene, carbon disulfide, carbon tetrachloride




Conditions of Instability: Incompatible materials, moisture, water.

Incompatibility with various substances:Reactive with combustible materials, organic materials, metals, acids, moisture. The product may undergo hazardousdecomposition, condensation or polymerization, it may react violently with water to emit toxic gases or it may become self-reactive under conditions of shock or increase in temperature or pressure.


Special Remarks on Reactivity:It has a violent reaction with water producing hydrochloric and phosphoric acid Will react with water releasing toxic and/or corrosive gases. Incompatible with acetic acid, aluminum, chromyl chloride, diallyl phophite and allyl alcohol, fluorine,hydroxylamine, iodine monochloride, lead dioxide, nitric acid, nitrous acid, organic matter, potassium, sodium, water,combustible materials, alcohol.

Special Remarks on Corrosivity: Corrodes most common construction material




Toxicity to Animals:WARNING: THE LC50 VALUES HEREUNDER ARE ESTIMATED ON THE BASIS OF A 4-HOUR EXPOSURE. Acute oraltoxicity (LD50): 18 mg/kg [Rat]. Acute toxicity of the vapor (LC50): 50 4 hours [Guinea pig].

Chronic Effects on Humans: May cause damage to the following organs: blood, kidneys, lungs, liver, upper respiratory tract.

Other Toxic Effects on Humans:Extremely hazardous in case of inhalation (lung corrosive). Very hazardous in case of skin contact (irritant), of ingestion, .Hazardous in case of skin contact (corrosive, permeator), of eye contact (corrosive). Slightly hazardous in case of skin contact(sensitizer).

Special Remarks on Toxicity to Animals:Lowest Published Lethal Dose: LDL [Rabbit] - Route: Skin; Dose: 1260 mg/kg


Special Remarks on other Toxic Effects on Humans:Acute Potential Health Effects: Skin: Causes severe skin irritation and burns. It may be absorbed through the skin in harmfulamounts. When absorbed through the skin, it may affect behavior/central nervous system (symptoms similar to that ofinhalation and ingestion). May cause dermatitis. Inhalation: Harmful if inhaled. Causes severe irritation and chemical burns ofthe respiratory tract (nose and throat) with sore throat, coughing, bronchitis, pneumonitis, necrosis of the nostrils, shortnessof breath, dyspnea and delayed lung edema. It may also affect behavior/central nervous system (muscle weakness, vertigo,

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headache, dizziness). Eyes: Causes lacrimation, severe irritation and burns. May cause conjunctivitis, and photophobia.Ingestion: May be fatal if swallowed. Causes severe digestive tract irritation and burns with immediate pain, peritonitis,swelling of the throat, convulsions, and possible coma. It may also affect behavior (symtoms similar to that of inhalation), andrespiration and cause chronic pulmonary edema. Other symptoms of exposure may included nausea, vomiting, anorexia (lossof appetite). Chronic Potential health effects: Repeated or prolonged exposure may cause kidney damage (nephritis) and mayaffect the liver (hepatic function










DOT Classification:Class 8: Corrosive material CLASS 6.1: Poisonous material.

Identification: : Phosphorous trichloride UNNA: 1809 PG: I

Special Provisions for Transport: Poison, Inhalation Hazard Zone B


Federal and State Regulations:Connecticut hazardous material survey.: Phosphorus trichloride Illinois toxic substances disclosure to employee act:Phosphorus trichloride Illinois chemical safety act: Phosphorus trichloride New York release reporting list: Phosphorustrichloride Rhode Island RTK hazardous substances: Phosphorus trichloride Pennsylvania RTK: Phosphorus trichlorideMinnesota: Phosphorus trichloride Massachusetts RTK: Phosphorus trichloride Massachusetts spill list: Phosphorus trichlorideNew Jersey: Phosphorus trichloride New Jersey spill list: Phosphorus trichloride Louisiana RTK reporting list: Phosphorustrichloride Louisiana spill reporting: Phosphorus trichloride California Director's List of Hazardous Substances: Phosphorustrichloride TSCA 8(b) inventory: Phosphorus trichloride SARA 302/304/311/312 extremely hazardous substances: Phosphorustrichloride CERCLA: Hazardous substances.: Phosphorus trichloride: 1000 lbs. (453.6 kg)

Other Regulations:


WHMIS (Canada):CLASS D-1A: Material causing immediate and serious toxic effects (VERY TOXIC). CLASS E: Corrosive liquid. CLASS F:Dangerously reactive material.

DSCL (EEC):R14- Reacts violently with water. R26/28- Very toxic by inhalation and if swallowed. R35- Causes severe burns. S7/8- Keepcontainer tightly closed and dry. S26- In case of contact with eyes, rinse immediately with plenty of water and seek medical

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advice. S36/37/39- Wear suitable protective clothing, gloves and eye/face protection. S45- In case of accident or if you feelunwell, seek medical advice immediately (show the label where possible).

HMIS (U.S.A.):

Health Hazard: 3

Fire Hazard: 0

Reactivity: 2



Health: 4

Flammability: 0

Reactivity: 2

Specific hazard:





Created: 10/11/2005 01:44 PM

Last Updated: 05/21/2013 12:00 PM


www.Lagunaclay.com 800-452-4862 [email protected]

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Material Safety Data SheetSodium nitrite MSDS


Product Name: Sodium nitrite

Catalog Codes: SLS2356, SLS3778, SLS1558

CAS#: 7632-00-0

RTECS: RA1225000

TSCA: TSCA 8(b) inventory: Sodium nitrite

CI#: Not available.

Synonym:

Chemical Name: Sodium Nitrite

Chemical Formula: NaNO2









Composition:


Sodium nitrite 7632-00-0 100

Toxicological Data on Ingredients: Sodium nitrite: ORAL (LD50): Acute: 180 mg/kg [Rat]. 175 mg/kg [Mouse].


Potential Acute Health Effects:Very hazardous in case of eye contact (irritant), of ingestion, of inhalation. Hazardous in case of skin contact (irritant).Slightly hazardous in case of skin contact (permeator). Prolonged exposure may result in skin burns and ulcerations. Over-exposure by inhalation may cause respiratory irritation. Severe over-exposure can result in death. Inflammation of the eye ischaracterized by redness, watering, and itching.

Potential Chronic Health Effects:CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells. Mutagenicfor bacteria and/or yeast. TERATOGENIC EFFECTS: Classified POSSIBLE for human. DEVELOPMENTAL TOXICITY:Classified Reproductive system/toxin/female, Reproductive system/toxin/male [POSSIBLE]. The substance may be toxic toblood, cardiovascular system, Smooth Muscle. Repeated or prolonged exposure to the substance can produce target organsdamage. Repeated exposure to a highly toxic material may produce general deterioration of health by an accumulation in oneor many human organs.



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Explosion Hazards in Presence of Various Substances:Risks of explosion of the product in presence of static discharge: Not available. Slightly explosive in presence of shocks, ofheat.


Special Remarks on Fire Hazards:When in contact with organic matter, it will ignite by friction. May ignite combustibles.

Special Remarks on Explosion Hazards:Explodes when heated over 1000 F (538 C). Sodium Nitrite + thiocyanate explodes on heating. A mixture of sodium nitrite andvarious cyanides explodes on contact. Mixture of sodium nitrite and phthalic acid or anhydride explode violently on heating.Fusion of urea with sodium nitrite Interaction of nitrites when heated with metal amidosulfates (sulfamates) may becomeexplosively violent owing to liberation of nitrogen and steam mixed with ammonium sulfamate form. Violent explosion occursif an ammonium salt is is melted with nitrite salt. Shock may explode nitrites. must be carried out exactly as described to avoidirsk of explosion.


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Large Spill:Oxidizing material. Poisonous solid. Stop leak if without risk. Do not get water inside container. Avoid contact with acombustible material (wood, paper, oil, clothing...). Keep substance damp using water spray. Do not touch spilled material.Use water spray to reduce vapors. Prevent entry into sewers, basements or confined areas; dike if needed. Call for assistanceon disposal.


Precautions:Keep locked up.. Keep away from heat. Keep away from sources of ignition. Keep away from combustible material.. Do notingest. Do not breathe dust. In case of insufficient ventilation, wear suitable respiratory equipment. If ingested, seek medicaladvice immediately and show the container or the label. Avoid contact with skin and eyes. Keep away from incompatibles suchas reducing agents, combustible materials, organic materials, metals, acids.

Storage:Oxidizer. Hygroscopic. Air sensitive. Keep container tightly closed. Keep container in a cool, well-ventilated area. Separatefrom acids, alkalies, reducing agents and combustibles. See NFPA 43A, Code for the Storage of Liquid and Solid Oxidizers.Do not store above 23°C (73.4°F).



Personal Protection: Safety glasses. Synthetic apron. Gloves (impervious).

Personal Protection in Case of a Large Spill:Splash goggles. Full suit. Boots. Gloves. Suggested protective clothing might not be sufficient; consult a specialist BEFOREhandling this product.



Physical state and appearance: Solid. (Powdered solid.)

Odor: Odorless.

Taste: Saline. (Slight.)

Molecular Weight: 69 g/mole

Color: White to slightly yellowish.

pH (1% soln/water): 9 [Basic.]







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Solubility:Easily soluble in hot water. Soluble in cold water. Partially soluble in methanol. Very slightly soluble in diethyl ether.




Conditions of Instability:Excess heat, dust generation, ignition sources, exposure to air, combustible materials, incompatible materials, exposure tomoist air or water.

Incompatibility with various substances:Highly reactive with combustible materials, organic materials. Reactive with reducing agents, metals, acids. Slightly reactive toreactive with moisture.


Special Remarks on Reactivity:Hygroscopic. Strong oxidizer. Slowly oxidizes to nitrate in air. Reacts vigorously with reducing materials. Sodium nitrite isa strong oxidizer and is incompatible with the following: acetanilide, metals as powders, ammonium salts, aminoguanidinesalts, anitpyrine, Butadiene, chlorates, hypophosphites, activated carbon, iodides, mercury salts, permanganate, phthalic acid,phthalic anydride, sodium amide, sodium disulphite, cyanides (e.g. potassium cyanide, sodium cyanide), sodium thiocyanate,lithium, sulfites, tannic acid, urea, wood, vegetable astringent decoctions, infusions, or tinctures.




Routes of Entry: Absorbed through skin. Inhalation. Ingestion.

Toxicity to Animals:WARNING: THE LC50 VALUES HEREUNDER ARE ESTIMATED ON THE BASIS OF A 4-HOUR EXPOSURE. Acute oraltoxicity (LD50): 175 mg/kg [Mouse]. Acute toxicity of the dust (LC50): 5.5 4 hours [Rat].

Chronic Effects on Humans:MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells. Mutagenic for bacteria and/or yeast. TERATOGENICEFFECTS: Classified POSSIBLE for human. DEVELOPMENTAL TOXICITY: Classified Reproductive system/toxin/female,Reproductive system/toxin/male [POSSIBLE]. May cause damage to the following organs: blood, cardiovascular system,Smooth Muscle.

Other Toxic Effects on Humans:Very hazardous in case of ingestion, of inhalation. Hazardous in case of skin contact (irritant). Slightly hazardous in case ofskin contact (permeator).


Special Remarks on Chronic Effects on Humans:May cause cancer (tumorigen), affect gentic material (mutagen), cause adverse reproductive effects (fertility, fetotoxicity) andbirth defects based on animal data. Passes through the placental barrier in animal.

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Special Remarks on other Toxic Effects on Humans:Acute Potential Health Effects: Skin: Causes skin irritation. May be absorbed through skin. Eyes: Causes eye irritation. Maycause conjunctivitis. May cause permanent corneal opacification. Ingestion: Harmful if swallowed. Causes gastrointestinaltract irritation with nausea. May affect behavior, brain, nervous system (change in motor activity, muscular incoordination,loss of reflexes, convulsions, coma), blood (methemoglobinemia), liver, metabolism, cardiovasular system (decrease inblood pressure, rapid pulse) and urinary system. May also cause weakness. Inhalation: May be fatal if inhaled. May causerespiratory tract irritation, cyanosis, dyspena, pulmonary edema, asphyxia, chemical pneumonitis, upper airway obstructioncaused by edema and possible death. May cause biochemical changes. May affect the blood (methemoglobinemia), and thecardiovascular system (tachycardia).










DOT Classification:CLASS 5.1: Oxidizing material. CLASS 6.1: Poisonous material.

Identification: : Sodium nitrite UNNA: 1500 PG: III

Special Provisions for Transport: Marine Pollutant


Federal and State Regulations:New York release reporting list: Sodium nitrite Pennsylvania RTK: Sodium nitrite Massachusetts RTK: Sodium nitrite NewJersey: Sodium nitrite California Director's List of Hazardous Substances: Sodium nitrite TSCA 8(b) inventory: Sodiumnitrite TSCA 12(b) one time export: Sodium nitrite SARA 313 toxic chemical notification and release reporting: Sodium nitriteCERCLA: Hazardous substances.: Sodium nitrite: 100 lbs. (45.36 kg)



WHMIS (Canada):CLASS C: Oxidizing material. CLASS D-1A: Material causing immediate and serious toxic effects (VERY TOXIC). CLASSD-2A: Material causing other toxic effects (VERY TOXIC).

DSCL (EEC):

HMIS (U.S.A.):

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Health Hazard: 3

Fire Hazard: 0

Reactivity: 0

Personal Protection: C


Health: 3

Flammability: 0

Reactivity: 1

Specific hazard:

Protective Equipment:Gloves (impervious). Synthetic apron. Wear appropriate respirator when ventilation is inadequate. Safety glasses.




Created: 10/10/2005 08:27 PM

Last Updated: 05/21/2013 12:00 PM


Material Safety Data SheetVinyl Sulfone MSDS


Product Name: Vinyl Sulfone

Catalog Codes: SLV1171

CAS#: 77-77-0

RTECS: KM7175000


CI#: Not available.

Synonym: Bis(ethenyl)sulfone; Divinyl sulfone

Chemical Name: Ethene, 1,1'-sulfonylbis-

Chemical Formula: C4-H6-O2-S








Section 2: Composition and Information on IngredientsComposition:


Vinyl Sulfone 77-77-0 100

Toxicological Data on Ingredients: Vinyl Sulfone: ORAL (LD50): Acute: 32 mg/kg [Rat].


Potential Acute Health Effects:Very hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, of inhalation. Hazardous incase of skin contact (corrosive), of eye contact (corrosive). Liquid or spray mist may produce tissue damageparticularly on mucous membranes of eyes, mouth and respiratory tract. Skin contact may produce burns.Inhalation of the spray mist may produce severe irritation of respiratory tract, characterized by coughing, choking,or shortness of breath. Severe over-exposure can result in death. Inflammation of the eye is characterized byredness, watering, and itching. Skin inflammation is characterized by itching, scaling, reddening, or, occasionally,blistering.

Potential Chronic Health Effects:CARCINOGENIC EFFECTS: Not available.MUTAGENIC EFFECTS: Not available.TERATOGENIC EFFECTS: Not available.DEVELOPMENTAL TOXICITY: Not available.Repeated or prolonged contact with spray mist may produce chronic eye irritation and severe skin irritation.

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Repeated or prolonged exposure to spray mist may produce respiratory tract irritation leading to frequent attacksof bronchial infection. Repeated exposure to a highly toxic material may produce general deterioration of health byan accumulation in one or many human organs.


Eye Contact:Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for atleast 15 minutes. Cold water may be used. Get medical attention immediately.

Skin Contact:In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminatedclothing and shoes. Cover the irritated skin with an emollient. Cold water may be used.Wash clothing beforereuse. Thoroughly clean shoes before reuse. Get medical attention immediately.

Serious Skin Contact:Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek immediatemedical attention.

Inhalation:If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Getmedical attention immediately.

Serious Inhalation:Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt orwaistband. If breathing is difficult, administer oxygen. If the victim is not breathing, perform mouth-to-mouthresuscitation. WARNING: It may be hazardous to the person providing aid to give mouth-to-mouth resuscitationwhen the inhaled material is toxic, infectious or corrosive. Seek immediate medical attention.

Ingestion:If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give anything bymouth to an unconscious person. Loosen tight clothing such as a collar, tie, belt or waistband. Get medicalattention immediately.








Fire Hazards in Presence of Various Substances: Slightly flammable to flammable in presence of open flames and sparks,of heat.

Explosion Hazards in Presence of Various Substances:Risks of explosion of the product in presence of mechanical impact: Not available.Risks of explosion of the product in presence of static discharge: Not available.

Fire Fighting Media and Instructions:SMALL FIRE: Use DRY chemical powder.LARGE FIRE: Use water spray, fog or foam. Do not use water jet.

Special Remarks on Fire Hazards: When heated to decomposition it emits highly toxic fumes of sulfur oxides..

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Small Spill:Dilute with water and mop up, or absorb with an inert dry material and place in an appropriate waste disposalcontainer.

Large Spill:Corrosive liquid. Poisonous liquid.Stop leak if without risk. Absorb with DRY earth, sand or other non-combustible material. Do not get water insidecontainer. Do not touch spilled material. Use water spray curtain to divert vapor drift. Use water spray to reducevapors. Prevent entry into sewers, basements or confined areas; dike if needed. Eliminate all ignition sources.Call for assistance on disposal.


Precautions:Keep away from heat. Keep away from sources of ignition. Ground all equipment containing material. Do notingest. Do not breathe gas/fumes/ vapor/spray. Never add water to this product. In case of insufficientventilation, wear suitable respiratory equipment. If ingested, seek medical advice immediately and show thecontainer or the label. Avoid contact with skin and eyes. Keep away from incompatibles such as acids.

Storage: Keep container tightly closed. Keep container in a cool, well-ventilated area. Refrigerate


Engineering Controls:Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below theirrespective threshold limit value. Ensure that eyewash stations and safety showers are proximal to thework-station location.

Personal Protection:Face shield. Full suit. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Gloves.Boots.

Personal Protection in Case of a Large Spill:Splash goggles. Full suit. Vapor respirator. Boots. Gloves. A self contained breathing apparatus should beused to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialistBEFORE handling this product.









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Solubility: Soluble in cold water.





Incompatibility with various substances: Reactive with acids.


Special Remarks on Reactivity:High reactivity with compounds having active hydrogens.On contact with acid or acid fumes, highly toxic fumes of sulfur oxides are emitted







Other Toxic Effects on Humans:Very hazardous in case of skin contact (irritant), of ingestion, .Hazardous in case of skin contact (corrosive), of eye contact (corrosive), of inhalation (lung corrosive).

Special Remarks on Toxicity to Animals:Lethal Dose/Conc 50% Kill:LD50 [Rabbit] - Route: Skin; Dose 22 uL/kg

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Special Remarks on other Toxic Effects on Humans:Acute Potential Health Effects:Skin: Corrosive. Causes skin burns. It can be absorbed through the skin. May be fatal if absorbed throurghskin.Eyes: Corrosive. Causes eye (corneal) burns. Exposure to vapors causes lacrimation.Inhalation: It may cause respiratory tract irritation with coughing, wheezing laryngitis, burning sensation,shortness of breath, headache. It may cause chemical burns to the upper respiratory tract. Inhalation may resultin spasm, inflammation and edema. It may also affect behavior with symptoms similar to that of ingestion.Ingestion: May be fatal if swallowed. May affect behavior (headache, somnolence, tremor, convulsions,appearance of intoxication, drowsiness, mental confusion). It may cause renal impairment (nephrotoxicity). It cancause gastrointestinal tract irritation with nausea, vomiting, stomach pain, and cause fluid shifts or fluid losses intothe peritoneal cavity from local irritation, producing hemoconcentration.




Products of Biodegradation:Possibly hazardous short term degradation products are not likely. However, long term degradation products mayarise.




Waste Disposal:Waste must be disposed of in accordance with federal, state and local environmentalcontrol regulations.


DOT Classification:Class 8: Corrosive materialCLASS 6.1: Poisonous material.

Identification: : Toxic Liquid, Corrosive, Organic, n.o.s (Vinyl Sulfone) UNNA: 2927 PG: I



Federal and State Regulations: No products were found.

Other Regulations:OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).EINECS: This product is on the European Inventory of Existing Commercial Chemical Substances.


WHMIS (Canada):CLASS D-1A: Material causing immediate and serious toxic effects (VERY TOXIC).

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CLASS E: Corrosive liquid.

DSCL (EEC):R25- Toxic if swallowed.R27- Very toxic in contact with skin.R34- Causes burns.S26- In case of contact with eyes, rinseimmediately with plenty of water and seekmedical advice.S28- After contact with skin, wash immediatelywith plenty of water.S36/37/39- Wear suitable protective clothing,gloves and eye/face protection.S45- In case of accident or if you feel unwell,seek medical advice immediately (show thelabel where possible).

HMIS (U.S.A.):

Health Hazard: 3

Fire Hazard: 1

Reactivity: 0



Health: 3

Flammability: 1

Reactivity: 0

Specific hazard:

Protective Equipment:Gloves.Full suit.Vapor respirator. Be sure to use anapproved/certified respirator orequivalent. Wear appropriate respiratorwhen ventilation is inadequate.Face shield.




Created: 10/10/2005 12:15 AM

Last Updated: 10/10/2005 12:15 AM

The information above is believed to be accurate and represents the best information currently available to us. However, wemake no warranty of merchantability or any other warranty, express or implied, with respect to such information, and weassume no liability resulting from its use. Users should make their own investigations to determine the suitability of theinformation for their particular purposes. In no event shall ScienceLab.com be liable for any claims, losses, or damages of any

p. 6

third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, evenif ScienceLab.com has been advised of the possibility of such damages.

p. 7

Material Safety Data SheetChlorosulfonic acid MSDS


Product Name: Chlorosulfonic acid


CAS#: 7790-94-5

RTECS: FX5730000

TSCA: TSCA 8(b) inventory: Chlorosulfonic acid


Synonym: Sulfuric Chlorohydrin, Chlorosulfuric acid

Chemical Name: Chlorosulfonic Acid

Chemical Formula: ClSO3H








Section 2: Composition and Information on IngredientsComposition:


Chlorosulfonic acid 7790-94-5 100

Toxicological Data on Ingredients: Chlorosulfonic acid LD50: Not available. LC50: Not available.


Potential Acute Health Effects:Extremely hazardous in case of skin contact (irritant), of ingestion. Very hazardous in case of skin contact(corrosive), of eye contact (irritant), of inhalation. Hazardous in case of skin contact (permeator). Liquid or spraymist may produce tissue damage particularly on mucous membranes of eyes, mouth and respiratory tract. Skincontact may produce burns. Inhalation of the spray mist may produce severe irritation of respiratory tract,characterized by coughing, choking, or shortness of breath. Inflammation of the eye is characterized by redness,watering, and itching. Skin inflammation is characterized by itching, scaling, reddening, or, occasionally,blistering.

Potential Chronic Health Effects:CARCINOGENIC EFFECTS: Not available.MUTAGENIC EFFECTS: Not available.TERATOGENIC EFFECTS: Not available.DEVELOPMENTAL TOXICITY: Not available.The substance is toxic to lungs, mucous membranes.

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Repeated or prolonged exposure to the substance can produce target organs damage. Repeated or prolongedcontact with spray mist may produce chronic eye irritation and severe skin irritation. Repeated or prolongedexposure to spray mist may produce respiratory tract irritation leading to frequent attacks of bronchial infection.


Eye Contact:Check for and remove any contact lenses. Immediately flush eyes with running water for at least 15 minutes,keeping eyelids open. Cold water may be used. Do not use an eye ointment. Seek medical attention.

Skin Contact:If the chemical got onto the clothed portion of the body, remove the contaminated clothes as quickly as possible,protecting your own hands and body. Place the victim under a deluge shower. If the chemical got on the victim'sexposed skin, such as the hands : Gently and thoroughly wash the contaminated skin with running water andnon-abrasive soap. Be particularly careful to clean folds, crevices, creases and groin. Cold water may be used.If irritation persists, seek medical attention. Wash contaminated clothing before reusing.

Serious Skin Contact:Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek medicalattention.


Serious Inhalation:Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt orwaistband. If breathing is difficult, administer oxygen. If the victim is not breathing, perform mouth-to-mouthresuscitation. WARNING: It may be hazardous to the person providing aid to give mouth-to-mouth resuscitationwhen the inhaled material is toxic, infectious or corrosive. Seek immediate medical attention.

Ingestion:Do not induce vomiting. Loosen tight clothing such as a collar, tie, belt or waistband. If the victim is notbreathing, perform mouth-to-mouth resuscitation. Seek immediate medical attention.









Explosion Hazards in Presence of Various Substances:Explosive in presence of reducing materials.Non-explosive in presence of open flames and sparks, of shocks, of heat, of oxidizing materials, of combustiblematerials, of organic materials, of metals, of acids, of alkalis, of moisture.




p. 2


Small Spill:Dilute with water and mop up, or absorb with an inert dry material and place in an appropriate waste disposalcontainer. If necessary: Neutralize the residue with a dilute solution of sodium carbonate.

Large Spill:Corrosive liquid.Stop leak if without risk. Absorb with DRY earth, sand or other non-combustible material. Do not get water insidecontainer. Do not touch spilled material. Use water spray curtain to divert vapor drift. Prevent entry into sewers,basements or confined areas; dike if needed. Call for assistance on disposal. Neutralize the residue with adilute solution of sodium carbonate.


Precautions:Keep container dry. Do not breathe gas/fumes/ vapour/spray. Never add water to this product In case ofinsufficient ventilation, wear suitable respiratory equipment If ingested, seek medical advice immediately andshow the container or the label. Avoid contact with skin and eyes Keep away from incompatibles such asreducing agents, organic materials, metals, alkalis, moisture.May corrode metallic surfaces. Store in a metallic or coated fiberboard drum using a strong polyethylene innerpackage.

Storage:May corrode metallic surfaces. Store in a metallic or coated fiberboard drum using a strong polyethylene innerpackage. Corrosive materials should be stored in a separate safety storage cabinet or room.


Engineering Controls:Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below theirrespective threshold limit value.

Personal Protection:Splash goggles. Lab coat. Vapor respirator. Be sure to use an approved/certified respirator or equivalent.Gloves.

Personal Protection in Case of a Large Spill:Splash goggles. Full suit. Vapor respirator. Boots. Gloves. A self contained breathing apparatus should beused to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialistBEFORE handling this product.




Odor: Strong.

Taste: Strong.


Color: Light.

pH (1% soln/water): 1 [Acidic.]


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Melting Point: -80°C (-112°F)



Vapor Pressure: 1 mm of Hg (@ 20°C)










Instability Temperature: 158°C (316.4°F)


Incompatibility with various substances:Extremely reactive or incompatible with alkalis, moisture.Reactive with reducing agents, organic materials, metals.

Corrosivity:Highly corrosive in presence of aluminum, of zinc.Corrosive in presence of steel, of copper.Slightly corrosive to corrosive in presence of stainless steel(304), of stainless steel(316).Non-corrosive in presence of glass.



Polymerization: No.



Toxicity to Animals:LD50: Not available.LC50: Not available.


Other Toxic Effects on Humans:Extremely hazardous in case of skin contact (irritant), of ingestion.Very hazardous in case of skin contact (corrosive), of inhalation.

p. 4

Hazardous in case of skin contact (permeator).







Products of Biodegradation:Possibly hazardous short term degradation products are not likely. However, long term degradation products mayarise.




Waste Disposal:


DOT Classification: CLASS 8: Corrosive liquid.

Identification: : Chlorosulfonic acid : UN1754 PG: I

Special Provisions for Transport: Poison inhalation hazard zone B


Federal and State Regulations:Pennsylvania RTK: Chlorosulfonic acidMassachusetts RTK: Chlorosulfonic acidTSCA 8(b) inventory: Chlorosulfonic acidCERCLA: Hazardous substances.: Chlorosulfonic acid



WHMIS (Canada):CLASS D-2A: Material causing other toxic effects (VERY TOXIC).CLASS E: Corrosive liquid.

DSCL (EEC):R14- Reacts violently with water.R34- Causes burns.

HMIS (U.S.A.):

Health Hazard: 3

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Fire Hazard: 0

Reactivity: 2



Health: 3

Flammability: 0

Reactivity: 2

Specific hazard:

Protective Equipment:Gloves.Lab coat.Vapor respirator. Be sure to use anapproved/certified respirator orequivalent. Wear appropriate respiratorwhen ventilation is inadequate.Splash goggles.




Created: 10/11/2005 11:38 AM

Last Updated: 10/11/2005 11:38 AM

The information above is believed to be accurate and represents the best information currently available to us. However, wemake no warranty of merchantability or any other warranty, express or implied, with respect to such information, and weassume no liability resulting from its use. Users should make their own investigations to determine the suitability of theinformation for their particular purposes. In no event shall ScienceLab.com be liable for any claims, losses, or damages of anythird party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, evenif ScienceLab.com has been advised of the possibility of such damages.

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Material Safety Data SheetSodium bicarbonate MSDS


Product Name: Sodium bicarbonate


CAS#: 144-55-8

RTECS: VZ0950000

TSCA: TSCA 8(b) inventory: Sodium bicarbonate

CI#: Not available.

Synonym: Baking Soda; Bicarbonate of soda; Sodiumacid carbonate; Monosodium carbonate; Sodium hydrogencarbonate; Carbonic acid monosodium salt

Chemical Name: Sodium Bicarbonate

Chemical Formula: NaHCO3









Composition:


Sodium bicarbonate 144-55-8 100

Toxicological Data on Ingredients: Not applicable.





Eye Contact:Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15minutes. Cold water may be used. Get medical attention if irritation occurs.


p. 2
















Special Remarks on Fire Hazards: When heated to decomposition it emits acrid smoke and irritating fumes.






Precautions:Do not ingest. Do not breathe dust. If ingested, seek medical advice immediately and show the container or the label. Keepaway from incompatibles such as acids.



p. 3







Odor: Odorless.

Taste: Saline. Alkaline.

Molecular Weight: 84.01g/mole

Color: White.





Specific Gravity: Density: 2.159 (Water = 1)








Solubility:Soluble in cold water. Slightly soluble in alcohol. Solubility in Water: 6.4, 7.6, 8.7, 10.0, 11.3, 12.7, 14.2, 16.5, 19.1 g/100solution at 0, 10, 20, 30, 40, 50, 60, 80, adn 100 deg. C, respectively. Solubility in Water: 6.9, 8,2, 9.6, 11.1, 12.7, 14.5, 16.5,19.7, and 23.6 g/100g water at 0, 10, 20, 30, 40, 50, 60, 80, 100 deg. C, respectively.




Conditions of Instability: Incompatible materials, Moisture. Stable in dry air, but slowly decomposes in moist air.

Incompatibility with various substances: Reactive with acids.

p. 4


Special Remarks on Reactivity:Reacts with acids to form carbon dioxide. Dangerous reaction with monoammonium phosphate or a sodium-potassium alloy.









Special Remarks on Chronic Effects on Humans:Sodium Bicarbonate as produced genetic effects in rats (unscheduled DNA synthesis). However, no affects have been foundin humans.

Special Remarks on other Toxic Effects on Humans:Acute Potential Health Effects: Skin: May cause mild skin irritation. Eyes: May cause mild eye irritation. Inhalation: Maycause respiratory tract irritation. Symptoms may include coughing and sneezing. Ingestion: Symptoms of overexposure toSodium Bicarbonate include thirst, abdominal pain, gastroenteritis, and inflammation of the digestive tract. Chronic PotentialHealth Effects: Skin: Repeated or prolonged skin contact may cause irritation, drying or cracking of the skin. Ingestion andInhalation: Chronic toxicity usually occurs within 4 to 10 days following ingestion of very large amounts. Repeated or prolongedingestion or inhalation of large amounts may cause metabolic abnormalities, and sodium retention. Metabolic abnormalitiessuch as acidosis, hypernatremia, hypochloremia, alkalosis, hypocalcemia, or sodium retention may affect the blood, kidneys,respiration (cyanosis, apnea secondary to metabolic acidosis or pulmonary edema), and cardiovascular system (tachycardia,hypotension). Severe toxicity may also affect behavior/central nervous system/nervous system. Neurological changes mayresult from metabolic abnormalities. These may include fatigue, irritability, dizziness, mental confusion, paresthesia, seizures,tetany, cerebral edema Medical Conditions Aggravated by Exposure: Persons with pre-existing skin conditions might haveincreased sensitivity. Predisposing conditions that contribute to a mild alkali syndrome include, renal disease, dehydration, adnelectrolyte imbalance, hypertension, sarcoidosis, congestive heart failure, edema, or other sodium retaining conditions.










p. 5





Federal and State Regulations: TSCA 8(b) inventory: Sodium bicarbonate

Other Regulations: Not available.




HMIS (U.S.A.):

Health Hazard: 1

Fire Hazard: 0

Reactivity: 0



Health: 1

Flammability: 0

Reactivity: 0

Specific hazard:





Created: 10/10/2005 08:26 PM

Last Updated: 05/21/2013 12:00 PM


Product Specification

Product Number: 450561CAS Number: 71310-21-9MDL: MFCD00022096Formula: C11H22O2SFormula Weight: 218.36 g/mol

TEST Specification________________________________________________________________________

Appearance (Color) White to Light Yellow

Appearance (Form) Powder

Infrared spectrum Conforms to Structure

Proton NMR spectra Conforms to Structure

GC (area %) > 94.0 %_

Sigma-Aldrich warrants, that at the time of the quality release or subsequent retest date this product conformed to the information contained in

this publication. The current Specification sheet may be available at Sigma-Aldrich.com. For further inquiries, please contact Technical Service.

Purchaser must determine the suitability of the product for its particular use. See reverse side of invoice or packing slip for additional terms

and conditions of sale.

1 of 1

3050 Spruce Street, Saint Louis, MO 63103, USA

Website: www.sigmaaldrich.com

Email USA: [email protected]

Outside USA: [email protected]

Product Name:

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Material Safety Data Sheet1-Octanol MSDS


Product Name: 1-Octanol

Catalog Codes: SLO1090

CAS#: 111-87-5

RTECS: RH6550000

TSCA: TSCA 8(b) inventory: 1-Octanol

CI#: Not available.

Synonym:

Chemical Formula: C8H17OH









Composition:


{1-}Octanol 111-87-5 100

Toxicological Data on Ingredients: 1-Octanol: ORAL (LD50): Acute: 1790 mg/kg [Mouse].


Potential Acute Health Effects:Very hazardous in case of eye contact (irritant), of ingestion. Hazardous in case of skin contact (irritant), of inhalation.Inflammation of the eye is characterized by redness, watering, and itching.






p. 2









Flash Points: CLOSED CUP: 81.1°C (178°F). (TAG)










Large Spill:Combustible material. Keep away from heat. Keep away from sources of ignition. Stop leak if without risk. Finish cleaning byspreading water on the contaminated surface and allow to evacuate through the sanitary system.


Precautions:Keep away from heat. Keep away from sources of ignition. Ground all equipment containing material. Do not ingest. Do notbreathe gas/fumes/ vapour/spray. In case of insufficient ventilation, wear suitable respiratory equipment If ingested, seekmedical advice immediately and show the container or the label. Avoid contact with skin and eyes


p. 3














Melting Point: -16.5°C (2.3°F)

















p. 4



Polymerization: No.
















Waste Disposal:






Federal and State Regulations:Pennsylvania RTK: 1-Octanol TSCA 8(b) inventory: 1-Octanol



WHMIS (Canada):

p. 5

CLASS B-3: Combustible liquid with a flash point between 37.8°C (100°F) and 93.3°C (200°F). CLASS D-2B: Material causingother toxic effects (TOXIC).


HMIS (U.S.A.):

Health Hazard: 2

Fire Hazard: 2

Reactivity: 0



Health: 1

Flammability: 2

Reactivity: 0

Specific hazard:





Created: 10/11/2005 01:35 PM

Last Updated: 05/21/2013 12:00 PM


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Material Safety Data Sheet1,2-Dichlorobenzene MSDS


Product Name: 1,2-Dichlorobenzene


CAS#: 95-50-1

RTECS: CZ4500000

TSCA: TSCA 8(b) inventory: 1,2-Dichlorobenzene

CI#: Not available.

Synonym:


Chemical Formula: C6H4Cl2









Composition:


{1,2-}Dichlorobenzene 95-50-1 100

Toxicological Data on Ingredients: 1,2-Dichlorobenzene: ORAL (LD50): Acute: 500 mg/kg [Rat]. 500 mg/kg [Rabbit].


Potential Acute Health Effects:Very hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion. Hazardous in case of skin contact(permeator), of inhalation. Inflammation of the eye is characterized by redness, watering, and itching. Skin inflammation ischaracterized by itching, scaling, reddening, or, occasionally, blistering.

Potential Chronic Health Effects:Very hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion. Hazardous in case of skincontact (permeator), of inhalation. CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Not available.TERATOGENIC EFFECTS: Not available. DEVELOPMENTAL TOXICITY: Not available. The substance is toxic to kidneys,liver, mucous membranes. Repeated or prolonged exposure to the substance can produce target organs damage. Repeatedor prolonged inhalation of vapors may lead to chronic respiratory irritation.



p. 2













Products of Combustion: These products are carbon oxides (CO, CO2), halogenated compounds.

Fire Hazards in Presence of Various Substances: Slightly flammable to flammable in presence of oxidizing materials.

Explosion Hazards in Presence of Various Substances:Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the product inpresence of static discharge: Not available. Slightly explosive to explosive in presence of oxidizing materials.






Large Spill:Combustible material. Keep away from heat. Keep away from sources of ignition. Stop leak if without risk. Be careful that theproduct is not present at a concentration level above TLV. Check TLV on the MSDS and with local authorities.


p. 3

Precautions:Keep away from heat. Keep away from sources of ignition. Ground all equipment containing material. Do not ingest. Do notbreathe gas/fumes/ vapour/spray. In case of insufficient ventilation, wear suitable respiratory equipment If ingested, seekmedical advice immediately and show the container or the label. Avoid contact with skin and eyes






Exposure Limits:TWA: 50 (ppm) TWA: 300 (mg/m3)Consult local authorities for acceptable exposure limits.



Odor: Pleasant.


Molecular Weight: 147 g/mole




Melting Point: -17.6°C (0.3°F)



Vapor Pressure: 1.2 mm of Hg (@ 20°C)



Odor Threshold: 2 ppm

Water/Oil Dist. Coeff.: The product is equally soluble in oil and water; log(oil/water) = 0



Solubility: Very slightly soluble in cold water.

p. 4









Polymerization: No.



Toxicity to Animals: Acute oral toxicity (LD50): 500 mg/kg [Rabbit].

Chronic Effects on Humans: The substance is toxic to kidneys, liver, mucous membranes.

Other Toxic Effects on Humans:Very hazardous in case of skin contact (irritant), of ingestion. Hazardous in case of skin contact (permeator), of inhalation.











Waste Disposal:



Identification: : o-Dichlorobenzene : UN1591 PG: III


p. 5


Federal and State Regulations:Pennsylvania RTK: 1,2-Dichlorobenzene Massachusetts RTK: 1,2-Dichlorobenzene TSCA 8(b) inventory: 1,2-Dichlorobenzene SARA 313 toxic chemical notification and release reporting: 1,2-Dichlorobenzene CERCLA: Hazardoussubstances.: 1,2-Dichlorobenzene



WHMIS (Canada):CLASS B-3: Combustible liquid with a flash point between 37.8°C (100°F) and 93.3°C (200°F). CLASS D-1B: Material causingimmediate and serious toxic effects (TOXIC). CLASS D-2B: Material causing other toxic effects (TOXIC).


HMIS (U.S.A.):

Health Hazard: 2

Fire Hazard: 2

Reactivity: 0



Health: 2

Flammability: 2

Reactivity: 0

Specific hazard:





Created: 10/09/2005 05:07 PM

Last Updated: 05/21/2013 12:00 PM


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Material Safety Data SheetSulfuric acid, fuming, 20% MSDS


Product Name: Sulfuric acid, fuming, 20%

Catalog Codes: SLS1405

CAS#: 8014-95-7

RTECS: WS5605000

TSCA: TSCA 8(b) inventory: Sulfuric acid; Sulfur trioxide


Synonym: Oleum; Sulfuric Acid mixture with sulfurtrioxde; Fuming Sulfuric Acid


Chemical Formula: H2SO4 + 20% SO3









Composition:


Sulfuric acid 7664-93-9 76-82

Sulfur trioxide 7446-11-9 18-24

Toxicological Data on Ingredients: Sulfuric acid: ORAL (LD50): Acute: 2140 mg/kg [Rat.]. VAPOR (LC50): Acute: 510 mg/m2 hours [Rat]. 320 mg/m 2 hours [Mouse]. Sulfur trioxide LD50: Not available. LC50: Not available.


Potential Acute Health Effects:Very hazardous in case of skin contact (corrosive, irritant, permeator), of eye contact (irritant, corrosive), of ingestion, . Slightlyhazardous in case of inhalation (lung sensitizer). Liquid or spray mist may produce tissue damage particularly on mucousmembranes of eyes, mouth and respiratory tract. Skin contact may produce burns. Inhalation of the spray mist may producesevere irritation of respiratory tract, characterized by coughing, choking, or shortness of breath. Severe over-exposure canresult in death. Inflammation of the eye is characterized by redness, watering, and itching. Skin inflammation is characterizedby itching, scaling, reddening, or, occasionally, blistering.

Potential Chronic Health Effects:Slightly hazardous in case of skin contact (sensitizer). CARCINOGENIC EFFECTS: Classified 1 (Proven for human.) by IARC[Sulfuric acid, fuming]. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available. DEVELOPMENTAL


p. 2

TOXICITY: Not available. The substance may be toxic to kidneys, lungs, heart, cardiovascular system, upper respiratory tract,eyes, teeth. Repeated or prolonged exposure to the substance can produce target organs damage. Repeated or prolongedcontact with spray mist may produce chronic eye irritation and severe skin irritation. Repeated or prolonged exposure to spraymist may produce respiratory tract irritation leading to frequent attacks of bronchial infection. Repeated exposure to a highlytoxic material may produce general deterioration of health by an accumulation in one or many human organs.
















Explosion Hazards in Presence of Various Substances:Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the product inpresence of static discharge: Not available. Slightly explosive in presence of heat, of oxidizing materials.


Special Remarks on Fire Hazards:When heated to decomposition it emits highly toxic fumes. May ignite other combustible materials.

Special Remarks on Explosion Hazards:M i x t u r e s o f s u l f u r i c a c i d a n d a n y o f t h e f o l l o w i n g c a n e x p l o d e : p - n i t r o t o l u e n e , p e n t a s il v e r trihydroxydiaminophosphate, perchlorates, alcohols with strong hydrogen peroxide, ammonium tetraperoxychromate,

p. 3

mercuric nitrite, potassium chlorate, potassium permanganate with potassium chloride. Nitramide decomposes explosivelyon contact with concentrated sulfuric acid. 1,3,5-Trinitrosohexahydro-1,3,5-triazine + sulfuric acid causes explosivedecompositon.



Large Spill:Corrosive liquid. Poisonous liquid. Stop leak if without risk. Absorb with DRY earth, sand or other non-combustible material.Do not get water inside container. Do not touch spilled material. Use water spray curtain to divert vapor drift. Use water sprayto reduce vapors. Prevent entry into sewers, basements or confined areas; dike if needed. Call for assistance on disposal.Neutralize the residue with a dilute solution of sodium carbonate. Be careful that the product is not present at a concentrationlevel above TLV. Check TLV on the MSDS and with local authorities.


Precautions:Keep locked up.. Keep container dry. Keep away from heat. Keep away from sources of ignition. Keep away from directsunlight or strong incandescent light. Do not ingest. Do not breathe gas/fumes/ vapor/spray. Never add water to this product.Avoid shock and friction. In case of insufficient ventilation, wear suitable respiratory equipment. If ingested, seek medicaladvice immediately and show the container or the label. Avoid contact with skin and eyes. Keep away from incompatibles suchas oxidizing agents, reducing agents, combustible materials, organic materials, metals, acids, alkalis, moisture. May corrodemetallic surfaces. Store in a metallic or coated fiberboard drum using a strong polyethylene inner package.

Storage:Keep container tightly closed. Keep container in a cool, well-ventilated area. Hygroscopic; keep container tightly closed. Willreact with water or steam to produce heat and toxic fumes.





Exposure Limits:TWA: 1 (mg/m3) from NIOSH Consult local authorities for acceptable exposure limits.


Physical state and appearance: Liquid. (Fuming oily liquid.)

Odor: sharp, penetrating, choking.



p. 4

Color: Colorless to slight yellow/brown

pH (1% soln/water): Acidic.

Boiling Point: The lowest known value is 45°C (113°F) (Sulfur trioxide). Weighted average: 254.47°C (490°F)

Melting Point: May start to solidify at 16.8°C (62.2°F) based on data for: Sulfur trioxide. Weighted average: 11.29°C (52.3°F)

Critical Temperature: The lowest known value is 217.8°C (424°F) (Sulfur trioxide).



Vapor Density: The highest known value is 3.4 (Air = 1) (Sulfuric acid). Weighted average: 3.31 (Air = 1)






Solubility:Easily soluble in cold water. Sulfuric is soluble in water with liberation of much heat. Reacts violently with water.




Conditions of Instability: Moist air, water, excess heat, incompatible materials

Incompatibility with various substances:Reactive with oxidizing agents, reducing agents, combustible materials, organic materials, metals, acids, alkalis, moisture. Theproduct may undergo hazardous decomposition, condensation or polymerization, it may react violently with water to emit toxicgases or it may become self-reactive under conditions of shock or increase in temperature or pressure.

Corrosivity:Extremely corrosive in presence of copper. Highly corrosive in presence of steel, of aluminum, of stainless steel(304), ofstainless steel(316). Non-corrosive in presence of glass.

Special Remarks on Reactivity:Hygroscopic; keep container tightly closed. Will react with water or steam to produce heat and toxic fumes. Incompatiblewith ACETIC ACID, ACRYLIC ACID, AMMONIUM HYDROXIDE, CRESOL, CUMENE, D I C H L O R O E T H Y L E TH E R , E T H Y L E N E C Y A N O H Y D R I N , E T H Y L E N E I M I N E , N I T R I C A C I D , 2-NITROPROPANE,PROPYLENE OXIDE, SULFOLANE, VINYLIDENE CHLORIDE, DIETHYLENE GLYCOL MONOMETHYL ETHER, ETHYLACETATE, ETHYLENE CYANOHYDRIN, ETHYLENE GLYCOL MONOETHYL ETHER ACETATE, GLYOXAL, METHYLETHYL KETONE, dehydrating agents, organic materials, moisture, Acetic anhydride, Acetone, cyanohydrin, Acetone+nitric acid, Acetone + potassium dichromate, Acetonitrile, Acrolein, Acrylonitrile, Acrylonitrile+water, Alcohols + hydrogenperoxide, Allyl alcohol, Allyl Chloride, 2-Aminoethanol, Ammonium hydroxide, Ammonium triperchromate, Aniline, Bromate+ metals, Bromine pentafluoride, n-Butyraldehyde, Carbides, Cesium acetylene carbide, Chlorates, Cyclopentanone oxime,chlorinates, Chlorated + metals, Chlorine trifluoride, Chlorosulfonic acid, 2-cyano-4-nitrobenzenediazonium hydrogensulfate, Cuprous nitride, p-chloronitrobenzene, 1,5-Dinitronaphthlene + sulfur, Diisobutylene, p-dimethylaminobenzaldehyde,1,3-Diazidobenzene, Dimethylbenzylcarbinol + hydrogen peroxide, Epichlorohydrin, Ethyl alcohol + hydrogen peroxide,Ethylene diamine, Ethylene glycol, Ethylenimine, Fulminates, hydrogen peroxide, Hydrochloric acid, Hydrofluoric acid, Iodineheptafluoride, Indane + nitric acid, Iron, Isoprene, Lithium silicide, Mercuric nitride, Mesityl oxide, Mercury nitride, Metals(powdered), Nitromethane, Nitric acid + glycerides, p-Nitrotoluene, Pentasilver trihydroxydiaminophosphate Perchlorates,Perchloric acid, Permanganates + benzene, 1-Phenyl-2-methylpropyl alcohol + hydrogen peroxide, Phosphorus, Phosphorusisocyanate, Picrates, Potassium tert-butoxide, Potassium chlorate, Potassium Permanganate, Potassium Permanganate +Potassium chloride, Potassium Permanganate + water, Propiolactone (beta)-, Pyridine, Rubidium aceteylene carbide, Silver

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permanganate, Sodium, Sodium carbonate, sodium hydroxide, Steel, styrene monomer, toluene + nitric acid, Vinyl acetate,Thalium (I) azidodithiocarbonate, Zinc chlorate, Zinc Iodide.

Special Remarks on Corrosivity:Minor corrosive effect on bronze. No corrosion data for brass or zinc.




Toxicity to Animals:WARNING: THE LC50 VALUES HEREUNDER ARE ESTIMATED ON THE BASIS OF A 4-HOUR EXPOSURE. Acute oraltoxicity (LD50): 2140 mg/kg [Rat.]. (Sulfuric acid). Acute toxicity of the vapor (LC50): 347 1 hours [Rat]. (Sulfuric Acid, fuming)

Chronic Effects on Humans:CARCINOGENIC EFFECTS: Classified 1 (Proven for human.) by IARC [Sulfuric acid, fuming]. May cause damage to thefollowing organs: kidneys, lungs, heart, cardiovascular system, upper respiratory tract, eyes, teeth.


Special Remarks on Toxicity to Animals:Lowest Published Lethal Dose: LCL [Guinea Pig]- Route: Inhalation; Dose 30 mg/m3/6H (Sulfur trioxide)

Special Remarks on Chronic Effects on Humans:Mutagenicity: Cytogenetic Analysis: Hamster, ovary = 4mmol/L Reproductive effects: May cause adverse reproductive effectsbased on animal data. Developmental abnormalities (musculoskeletal) in rabbits at a dose of 20 mg/m3 for 7 hrs.(RTECS)Teratogenecity: neither embryotoxic, fetoxic, nor teratogenetic in mice or rabbits at inhaled doses producing some maternaltoxicity (Sulfuric acid)

Special Remarks on other Toxic Effects on Humans:Acute Potential Health Effects: Skin: Causes severe skin irritation and burns. Continued contact can cause tissue necrosis.Eye: Causes severe eye irritation and burns. May cause irreversible eye injury. Ingestion: Harmful if swallowed. May causepermanent damage to the digestive tract. Causes gastrointestial tract burns. May cause perforation of the stomach, GIbleeding, edema of the glottis, necrosis and scarring, and sudden circulatory collapse(similar to acute inhalation). It mayalso cause systemic toxicity with acidosis. Inhalation: May cause severe irritation of the respiratory tract and mucousmembranes with sore throat, coughing, shortness of breath, and delayed lung edema. Causes chemical burns to the repiratorytract. Inhalation may be fatal as a result of spasm, inflammation, edema of the larynx and bronchi, chemical pneumonitis,and pulmonary edema. Cause corrosive action on mucous membranes. May affect cardiovascular system (hypotension,depressed cardiac output, bradycardia). Circulatory collapse with clammy skin, weak and rapid pulse, shallow respiration, andscanty urine may follow. Circulatory shock is often the immediate cause of death. May also affect teeth(changes in teeth andsupporting structures - erosion, discoloration). Chronic Potential Health Effects: Inhalation: Prolonged or repeated inhalationmay affect behavior (muscle contraction or spasticity), urinary system (kidney damage), and cardiovascular system, heart(ischemic heart leisons), and respiratory system/lungs(pulmonary edema, lung damage), teeth (dental discoloration, erosion).Skin: Prolonged or repeated skin contact may cause dermatitis, an allergic skin reaction.







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Identification: : Sulfuric acid, fuming (Sulfuric acid) UNNA: 1831 PG: I

Special Provisions for Transport: Poison inhalation hazard zone B (Sulfur trioxide)


Federal and State Regulations:Connecticut hazardous material survey.: Sulfur trioxide Illinois toxic substances disclosure to employee act: Sulfuric acidIllinois chemical safety act: Sulfur trioxide New York release reporting list: Sulfuric acid; Sulfur trioxide Rhode Island RTKhazardous substances: Sulfuric acid Pennsylvania RTK: Sulfuric acid; Sulfur trioxide Minnesota: Sulfuric acid MassachusettsRTK: Sulfuric acid; Sulfur trioxide Massachusetts spill list: Sulfur trioxide New Jersey: Sulfuric acid; Sulfur trioxide New Jerseyspill list: Sulfur trioxide New Jersey toxic catastrophe prevention act: Sulfur trioxide Louisiana RTK reporting list: Sulfur trioxideTSCA 8(b) inventory: Sulfuric acid; Sulfur trioxide SARA 302/304/311/312 extremely hazardous substances: Sulfuric acid;Sulfur trioxide SARA 313 toxic chemical notification and release reporting: Sulfuric acid CERCLA: Hazardous substances.:Sulfuric acid: 1000 lbs. (453.6 kg); Sulfur trioxide: 100 lbs. (45.36 kg);



WHMIS (Canada):CLASS E: Corrosive liquid. CLASS F: Dangerously reactive material.

DSCL (EEC):R14- Reacts violently with water. R35- Causes severe burns. S26- In case of contact with eyes, rinse immediately with plentyof water and seek medical advice. S30- Never add water to this product. S45- In case of accident or if you feel unwell, seekmedical advice immediately (show the label where possible).

HMIS (U.S.A.):

Health Hazard: 3

Fire Hazard: 0

Reactivity: 2



Health: 3

Flammability: 0

Reactivity: 2

Specific hazard:



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Created: 10/09/2005 11:59 PM

Last Updated: 05/21/2013 12:00 PM


Deepak Nitrite Limited

Effective Date: 05.07.2012 p-Toluidine 1 of 7

Material Safety Data Sheet p-Toluidine

1 Product And Company Identification :

Product Name : p-Toluidine

Other/Generic Names : 4-Aminotoluene, 4-Methylaniline

CAS No. : 106-49-0 Product use : It can be used to manufacture pigment, dyestuffs,

photographic chemicals, antioxidants, agricultural, pharmaceutical and rubber chemicals.

Supplier Deepak Nitrite Ltd. Aaditya-I, National Highway No. 8, Chhani Road, Vadodara - 390 024, India Manufacturing facilities at : Vadodara, Roha, Taloja & Hyderabad. Contact no. : +91-9904406400

For Chemical Emergency

Spill, Leak, Fire, Exposure, or Accident, Call CHEMTREC Within USA and Canada: 1-800-424-9300 Outside USA and Canada: +1 703-527-3887

2 Hazard Identification :

GHS classification (Classification according to Regulation (EC) No 1272/2008)

Hazard statement (s)

Health Hazards Category 3, Inhalation Category 3, Dermal Carcinogenicity Category 2 Flammability: Physical hazards: Eye irritation, Category 2 Skin sensitization, Category 1

H301: Toxic if swallowed. H311: Toxic in contact with skin. H331: Toxic if inhaled. H351: Suspected of causing cancer. H319: Causes serious eye irritation. H317: May cause an allergic skin reaction. H400: Very toxic to aquatic life.

EC classification (Classification according to Directive 67/548/EEC)

T: R23/24/25 Xi; R36 Carc.Cat.3; R40 R43 N : R50 Acute aquatic toxicity, Category 1

Toxic by inhalation, in contact with skin and if swallowed Irritating to eyes. Limited evidence of a carcinogenic effect. May cause sensitization by skin contact. Very toxic to aquatic organisms.

Hazard pictograms



Signal word Warning

3 Composition / Information On Ingredients :

Chemical formula : CH3C6H4NH2

Common Name : p-Toluidine

Synonyms : 4-Aminotoluene, 4-Methylaniline

Molecular weight : 107.15 g/mol

CAS No. : 106-49-0

Index No. : 612-160-00-4

UN No. : 3451

EINECS No. : 203-403-1

4 First Aid Measures :

General advice First aider needs to protect himself.

If inhaled Fresh air. If breathing stops: immediately apply mechanical ventilation, if necessary oxygen mask. Immediately call in physician.

In case of skin contact Wash off with plenty of water. Dab with polyethylene glycol 400. Immediately remove contaminated clothing. Call a physician immediately.

In case of eye contact Rinse out with plenty of water. Call in ophthalmologist. If swallowed Give water to drink (two glasses at the most). Seek medical advice immediately. In exceptional cases only, if medical care is not available within one hour, induce vomiting (only in persons who are wide awake and fully conscious), administer activated charcoal (20 - 40 g in a 10% slurry) and consult a doctor as quickly as possible



5 Fire Fighting Measures: Suitable extinguishing media Water, Carbon dioxide (CO2), Foam, Dry powder Special protective equipment for fire-fighters Do not stay in dangerous zone without self-contained breathing apparatus. In order to avoid contact with skin, keep a safety distance and wear suitable protective clothing. Fire may cause evolution of: nitrogen oxides Combustible material, Vapours are heavier than air and may spread along floors. Forms explosive mixtures with air on intense heating. Development of hazardous combustion gases or vapours possible in the event of fire. Further information Suppress (knock down) gases/vapours/mists with a water spray jet. Prevent fire extinguishing water from contaminating surface water or the ground water system.

6 Accidental Release Measures :

Personal precautions Avoid substance contact. Avoid inhalation of dusts in all circumstances. Ensure adequate ventilation. Environmental precautions Do not empty into drains. Methods and materials for containment and cleaning up Take up dry. Forward for disposal. Clean up affected area. Avoid generation of dusts.

7 Handling & Storage :

Handling Advice on safe handling Observe label precautions. Work under hood. Do not inhale substance. Storage Further information on storage conditions Protected from light. Dry. Tightly closed. Keep in a well-ventilated place. Keep locked up or in an area accessible only to qualified or authorised persons. Store at +15°C to +25°C.



8 Exposure Control / Personal Protection :

Personal protective equipment Protective clothing should be selected specifically for the working place, depending on concentration and quantity of the hazardous substances handled. The resistance of the protective clothing to chemicals should be ascertained with the respective supplier. Respiratory protection required when dusts are generated. Recommended Filter type: Filter A-(P3) Hand protection full contact: Hand protection Glove material: Nitrile rubber Glove thickness: 0,11 mm Break through time: > 480 min Eye protection Safety glasses Protective suit Protective measures Hygiene measures Immediately change contaminated clothing. Apply skin- protective barrier cream. Wash handsand face after working with substance. Work under hood. Do not inhale substance.

9 Physical And Chemical Properties :

Appearance : solid

Colour : white

Odour : alcoholic

pH ( 1% Solution) : (H2O, 20 °C) alkaline

Boiling Point/range : 200 °C

Melting point : 43 °C

Flash Point : 87 °C

Autoignition temperature : 480 °C

Lower explosion limit : No data avilable

Upper explosion limit : No data avilable

Vapour Pressure : 1.3 hPa (50 °C)

Density : 1.05 g/cm3 (20 °C)

Solubility water : 7.5 g/l (20 °C)

Relative vapour density : 3.9



10 Stability And Reactivity : Materials to avoid

Nitrosing agents, nitrous acid, nitrites

Condition to avoid

Strong heating. A range from approx. 15 Kelvin below the flash point is to be rated as critical.

Hazardous decomposition products

Fire may cause evolution of: nitrogen oxides Combustible material, Vapours are heavier than air and may spread along floors. Forms explosive mixtures with air on intense heating. Development of hazardous combustion gases or vapours possible in the event of fire.

Further information Sensitivity to light Sensitive to air. Heat-sensitive Forms explosive mixtures with air on intense heating.

11 Toxicological Information :

Acute toxicity : LD 50 oral LD50 rat 336 mg/kg LD 50 dermal LD50 rabbit 890 mg/kg

RTECS# : XU3150000

Category of danger : Toxic, irritant, carcinogenic, sensitizing, dangerous for the environment

Health Warnings : Liver, Kidney Effect potentiated by: ethanol

Target organs : Liver, Kidney

Potential health effects

: Toxic by inhalation, in contact with skin and if swallowed Irritating to eyes.

12 Ecological Information :

Acute fish toxicity LC50

Acute toxicity to aquatic invertebrates EC50

: :

Species: Brachydanio rerio (zebra fish) Dose: 137 mg/l Exposure time: 48 h Method: OECD Test Guideline 203 Species: Daphnia magna (Water flea) Dose: 0,12 mg/l Exposure time: 48 h (ECOTOX Database) Toxicity to bacteria MICROTOX-TEST EC50 Species: Photobacterium phosphoreum Dose: 4,27 mg/l Exposure time: 30 min (Lit.) WGK 2 water endangering



13 Disposal Considerations : Product Chemicals must be disposed of in compliance with the respective national regulations Packaging Product packaging must be disposed of in compliance with the country-specific regulations or must be passed to a packaging return system.

14 Transport Information :

UN No. : 3451 Hazard Class : 6.1 Packing Group : II Declaration (railroad and road) ADR, RID UN 3451 Toluidine, fest, 6.1, II Declaration (transport by sea) IMDG-Code UN 3451 TOLUIDINES, SOLID, 6.1, II Declaration (transport by air) IATA-DGR UN 3451 TOLUIDINES, SOLID, 6.1, II

15 Regulatory Information :

Safety Information according to GHS

Hazard Statement (s) H301: Toxic if swallowed. H311: Toxic in contact with skin. H331: Toxic if inhaled. H351: Suspected of causing cancer. H319: Causes serious eye irritation. H317: May cause an allergic skin reaction. H400: Very toxic to aquatic life.

Precautionary Statement (s) P273: Avoid release to the environment. P280: Wear protective gloves/ protective clothing. P302 + P352: IF ON SKIN: Wash with plenty of soap and water. P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Signal Word Danger

Hazard Pictogram(s):

RTECS# : XU3150000



Labeling according to EC directives

Hazard symbols : Risk phrases : R 23/24/25-36-40-43-50

Toxic by inhalation, in contact with skin and if swallowed. Irritating to eyes .Limited evidence of a carcinogenic effect. May cause sensitization by skin contact. Very toxic to aquatic organisms.

Safety phrases : S 28-36/37-45-61 After contact with skin, wash immediately with plenty of soap and water. Wear suitable protective clothing and gloves. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).Avoid release to the environment. Refer to special instructions/ Safety data sheets.

OSHA Hazards Combustible Liquid DSL Status All components of this product are on the Canadian DSL list. SARA 302 Components SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302. SARA 313 Components SARA 313: This material does not contain any chemical components with known CAS numbers that exceed the threshold reporting levels established by SARA Title III, Section 313. SARA 311/312 Hazards Fire Hazard Massachusetts Right To Know Components No components are subject to the Massachusetts Right to Know Act. Pennsylvania Right To Know Components 2-Ethylhexyl nitrate CAS-No. 27247-96-7 New Jersey Right To Know Components 2-Ethylhexyl nitrate CAS-No. 27247-96-7 California Prop. 65 Components This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm

16 Other Information:

-

DISCLAIMER : Deepak Nitrite Ltd. provides the information contained herein in good faith but makes no representation as to comprehensiveness or accuracy. This document is only as a guide to a properly trained person, for the appropriate precautions and handling of the material. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose. The data does not signify any warranty with regard to the product’s properties.

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Material Safety Data SheetPhthalic anhydride MSDS


Product Name: Phthalic anhydride

Catalog Codes: SLP4651, SLP1825

CAS#: 85-44-9

RTECS: TI3150000

TSCA: TSCA 8(b) inventory: Phthalic anhydride

CI#: Not available.

Synonym: 1,3-Isobenzofurandione

Chemical Name: Phthalic Anydride










Composition:


Phthalic anhydride 85-44-9 100

Toxicological Data on Ingredients: Phthalic anhydride: ORAL (LD50): Acute: 1530 mg/kg [Rat]. 1500 mg/kg [Mouse].DERMAL (LD50): Acute: >10000 mg/kg [Rabbit]. DUST (LC50): Acute: >210 mg/m 1 hours [Rat].


Potential Acute Health Effects:Very hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, of inhalation. Hazardous in case of skincontact (corrosive, permeator), of eye contact (corrosive). The amount of tissue damage depends on length of contact. Eyecontact can result in corneal damage or blindness. Skin contact can produce inflammation and blistering. Inhalation of dustwill produce irritation to gastro-intestinal or respiratory tract, characterized by burning, sneezing and coughing. Severe over-exposure can produce lung damage, choking, unconsciousness or death. Inflammation of the eye is characterized by redness,watering, and itching. Skin inflammation is characterized by itching, scaling, reddening, or, occasionally, blistering.

Potential Chronic Health Effects:Slightly hazardous in case of skin contact (sensitizer). CARCINOGENIC EFFECTS: A4 (Not classifiable for human or animal.)by ACGIH. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available. DEVELOPMENTAL TOXICITY:Not available. Repeated exposure of the eyes to a low level of dust can produce eye irritation. Repeated skin exposure canproduce local skin destruction, or dermatitis. Repeated inhalation of dust can produce varying degree of respiratory irritation orlung damage. Repeated exposure to a highly toxic material may produce general deterioration of health by an accumulation inone or many human organs.


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Eye Contact:Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15minutes. Cold water may be used. WARM water MUST be used. Get medical attention immediately.










Flash Points: CLOSED CUP: 151.67°C (305°F). OPEN CUP: 165°C (329°F).



Fire Hazards in Presence of Various Substances:Slightly flammable to flammable in presence of heat. Non-flammable in presence of shocks.







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Large Spill:Corrosive solid. Poisonous solid. Stop leak if without risk. Do not get water inside container. Do not touch spilled material. Usewater spray to reduce vapors. Prevent entry into sewers, basements or confined areas; dike if needed. Eliminate all ignitionsources. Call for assistance on disposal. Be careful that the product is not present at a concentration level above TLV. CheckTLV on the MSDS and with local authorities.


Precautions:Keep locked up.. Keep container dry. Keep away from heat. Keep away from sources of ignition. Empty containers pose afire risk, evaporate the residue under a fume hood. Ground all equipment containing material. Do not ingest. Do not breathedust. Never add water to this product. In case of insufficient ventilation, wear suitable respiratory equipment. If ingested,seek medical advice immediately and show the container or the label. Avoid contact with skin and eyes. Keep away fromincompatibles such as oxidizing agents.

Storage: Keep container tightly closed. Keep container in a cool, well-ventilated area. Do not store above 25°C (77°F).



Personal Protection:Splash goggles. Synthetic apron. Vapor and dust respirator. Be sure to use an approved/certified respirator or equivalent.Gloves.

Personal Protection in Case of a Large Spill:Splash goggles. Full suit. Vapor and dust respirator. Boots. Gloves. A self contained breathing apparatus should be used toavoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handlingthis product.

Exposure Limits:TWA: 6.1 (mg/m3) from ACGIH (TLV) [United States] TWA: 6 from ACGIH (TLV) [United States]Consult local authorities foracceptable exposure limits.


Physical state and appearance: Solid. (Crystals solid.)

Odor: Characteristic acrid, choking



Color: White.







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Solubility: Very slightly soluble in cold water, diethyl ether.




Conditions of Instability: Excess heat, dust generation, moisture, incompatible matrerials.

Incompatibility with various substances:Reactive with oxidizing agents. Slightly reactive to reactive with moisture.


Special Remarks on Reactivity: Also incompatible with Nitric Acid, Sodium Nitrite, and Copper Oxide.





Toxicity to Animals:WARNING: THE LC50 VALUES HEREUNDER ARE ESTIMATED ON THE BASIS OF A 4-HOUR EXPOSURE. Acute oraltoxicity (LD50): 1500 mg/kg [Mouse]. Acute dermal toxicity (LD50): >10000 mg/kg [Rabbit]. Acute toxicity of the dust (LC50):>210 mg/m 1 hours [Rat]. 3

Chronic Effects on Humans: CARCINOGENIC EFFECTS: A4 (Not classifiable for human or animal.) by ACGIH.

Other Toxic Effects on Humans:Very hazardous in case of skin contact (irritant), of ingestion, of inhalation. Hazardous in case of skin contact (corrosive,permeator), of eye contact (corrosive).


Special Remarks on Chronic Effects on Humans:May affect genetic material. May cause adverse reproductive effects (paternal effects) based on animal data.

Special Remarks on other Toxic Effects on Humans:Acute Potential Health Effects: Corrosive! If the solid materials is permitted to remain in contact with moist tissues, superficialburns may result. Skin: May cause severe skin irritation witn possible skin burns. If the skin is moist the irritant effects will begreater due to hydrolysis of phthalic acid. Eyes: May cause severe eye irritation with possible eye burns. May cause chemicalconjunctivitis and corneal damage. Inhalation: Causes severe respiratory tract irritation with possible chemical burns to therespiratory tract. May cause asthmatic attacks due to allergic sensitization of respiratory tract. May also affect respiration,and liver. Symptoms may include Rhinorrhea, blaody nasal disharge, hoarseness of voice, cough, bronchospasm Ingestion:Causes severe digestive tract irritation iwth possible burns. May cause severe and permanent damage to the digestivetract. Mah cause perforation of the digestive tract. May affect behavior. Chronic Potential Health Effects: Skin: Prolonged orrepeated skin contact may cause allergic skin reaction. I

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Identification: : Phthalic anhydride UNNA: 2214 PG: III



Federal and State Regulations:Connecticut hazardous material survey.: Phthalic anhydride Illinois toxic substances disclosure to employee act: Phthalicanhydride Illinois chemical safety act: Phthalic anhydride New York release reporting list: Phthalic anhydride Rhode IslandRTK hazardous substances: Phthalic anhydride Pennsylvania RTK: Phthalic anhydride Minnesota: Phthalic anhydrideMichigan critical material: Phthalic anhydride Massachusetts RTK: Phthalic anhydride Massachusetts spill list: Phthalicanhydride New Jersey: Phthalic anhydride New Jersey spill list: Phthalic anhydride Louisiana spill reporting: Phthalicanhydride California Director's List of Hazardous Substances: Phthalic anhydride TSCA 8(b) inventory: Phthalic anhydrideTSCA 8(a) IUR: Phthalic anhydride SARA 313 toxic chemical notification and release reporting: Phthalic anhydride CERCLA:Hazardous substances.: Phthalic anhydride: 5000 lbs. (2268 kg)



WHMIS (Canada):CLASS D-2A: Material causing other toxic effects (VERY TOXIC). CLASS E: Corrosive solid.

DSCL (EEC):R22- Harmful if swallowed. R26- Very toxic by inhalation. R38- Irritating to skin. R41- Risk of serious damage to eyes. S1/2-Keep locked up and out of the reach of children. S26- In case of contact with eyes, rinse immediately with plenty of waterand seek medical advice. S28- After contact with skin, wash immediately with plenty of [***] S36/37- Wear suitable protectiveclothing and gloves. S39- Wear eye/face protection. S45- In case of accident or if you feel unwell,

HMIS (U.S.A.):

Health Hazard: 3

Fire Hazard: 1

Reactivity: 1

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Personal Protection: j


Health: 3

Flammability: 1

Reactivity: 0

Specific hazard:

Protective Equipment:Gloves. Synthetic apron. Vapor and dust respirator. Be sure to use an approved/certified respirator or equivalent. Wearappropriate respirator when ventilation is inadequate. Splash goggles.




Created: 10/10/2005 11:26 AM

Last Updated: 05/21/2013 12:00 PM


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Material Safety Data SheetQuinaldine MSDS


Product Name: Quinaldine

Catalog Codes: SLQ1060

CAS#: 91-63-4

RTECS: UZ9625000

TSCA: TSCA 8(b) inventory: Quinaldine

CI#: Not available.

Synonym: 2-Methylquinoline

Chemical Name: Quinaldine










Composition:


Quinaldine 91-63-4 100

Toxicological Data on Ingredients: Quinaldine: ORAL (LD50): Acute: 1230 mg/kg [Rat]. DERMAL (LD50): Acute: 1978.5mg/kg [Rabbit (converted from the actual figure of 1870 ul/kg reported in RTECS)].


Potential Acute Health Effects:Hazardous in case of eye contact (irritant), of ingestion, of inhalation (lung irritant). Slightly hazardous in case of skin contact(irritant, permeator).

Potential Chronic Health Effects:CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Mutagenic for bacteria and/or yeast. TERATOGENICEFFECTS: Not available. DEVELOPMENTAL TOXICITY: Not available. The substance may be toxic to central nervoussystem (CNS). Repeated or prolonged exposure to the substance can produce target organs damage.


Eye Contact:


p. 2

Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15minutes. Cold water may be used. Get medical attention immediately.










Flash Points: CLOSED CUP: 79.4°C (174.9°F).



Fire Hazards in Presence of Various Substances:Flammable in presence of open flames and sparks, of heat. Non-flammable in presence of shocks.






Small Spill:Dilute with water and mop up, or absorb with an inert dry material and place in an appropriate waste disposal container.Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authorityrequirements.

Large Spill:Combustible material. Keep away from heat. Keep away from sources of ignition. Stop leak if without risk. Finish cleaning byspreading water on the contaminated surface and allow to evacuate through the sanitary system.


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Precautions:Keep locked up.. Keep away from heat. Keep away from sources of ignition. Ground all equipment containing material. Donot ingest. Do not breathe gas/fumes/ vapor/spray. Avoid contact with eyes. Wear suitable protective clothing. In case ofinsufficient ventilation, wear suitable respiratory equipment. If ingested, seek medical advice immediately and show thecontainer or the label. Keep away from incompatibles such as oxidizing agents, acids.

Storage:Air and Moisture Sensitive. Light Sensitive. Store in light-resistant container. Keep container in a cool, well-ventilated area.Keep container tightly closed and sealed until ready for use. Avoid all possible sources of ignition (spark or flame). Do notstore above 24°C (75.2°F).







Physical state and appearance: Liquid. (Oily liquid.)

















Solubility: Partially soluble in cold water.

p. 4




Conditions of Instability: Ignition Sources, excess heat, incompatibles, moisture, air.

Incompatibility with various substances:Reactive with oxidizing agents, acids. Slightly reactive to reactive with moisture.


Special Remarks on Reactivity:Air and Moisture Sensitive. Light Sensitive. Incompatible with strong oxidizing, agents, acids, and acid chlorides, and acidanhydrides.





Toxicity to Animals:Acute oral toxicity (LD50): 1230 mg/kg [Rat]. Acute dermal toxicity (LD50): 1978.5 mg/kg [Rabbit (converted from the actualfigure of 1870 ul/kg reported in RTECS)].

Chronic Effects on Humans:MUTAGENIC EFFECTS: Mutagenic for bacteria and/or yeast. May cause damage to the following organs: central nervoussystem (CNS).

Other Toxic Effects on Humans:Hazardous in case of ingestion, of inhalation (lung irritant). Slightly hazardous in case of skin contact (irritant, permeator).



Special Remarks on other Toxic Effects on Humans:Acute Potential Health Effects: Skin: May cause skin irritation. May be harmful if absorbed through skin. Eyes: Causes eyeirritation. Ingestion: May be harmful if swallowed. Causes gastrointestinal tract irritation. Inhalation: Causes respiratory tractand mucous membrane irritation. May affect Central Nervous System. Inhalation may have an anesthetic effect on the centralnervous system which is characterized by loss of sensation. Preliminary excitement is the initial effect followed by relaxation,dizziness, stupor or sleep. Chronic Potential Health Effects: no information found at this time.








p. 5







Federal and State Regulations: TSCA 8(b) inventory: Quinaldine



WHMIS (Canada):CLASS B-3: Combustible liquid with a flash point between 37.8°C (100°F) and 93.3°C (200°F).

DSCL (EEC):R20/21/22- Harmful by inhalation, in contact with skin and if swallowed. R37/38- Irritating to respiratory system and skin. R40-Possible risks of irreversible effects. R41- Risk of serious damage to eyes. S23- Do not breathe gas/fumes/vapour/spray [***]S24/25- Avoid contact with skin and eyes. S26- In case of contact with eyes, rinse immediately with plenty of water and seekmedical advice. S36- Wear suitable protective clothing.

HMIS (U.S.A.):

Health Hazard: 2

Fire Hazard: 2

Reactivity: 0



Health: 2

Flammability: 2

Reactivity: 0

Specific hazard:





Created: 10/09/2005 06:20 PM

p. 6

Last Updated: 05/21/2013 12:00 PM



Reactive Black 5

sc-215793

Hazard Alert Code Key: EXTREME HIGH MODERATE LOW

Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAMEReactive Black 5

STATEMENT OF HAZARDOUS NATURE

CONSIDERED A HAZARDOUS SUBSTANCE ACCORDING TO OSHA 29 CFR 1910.1200.

NFPA

SUPPLIERSanta Cruz Biotechnology, Inc.

2145 Delaware Avenue

Santa Cruz, California 95060

800.457.3801 or 831.457.3800

EMERGENCY:

ChemWatch

Within the US & Canada: 877-715-9305

Outside the US & Canada: +800 2436 2255

(1-800-CHEMCALL) or call +613 9573 3112

SYNONYMSC26-H25-N5-O19-S6.4Na, "4-amino-5-hydroxy-3, 6-bis[[4-[[2-(sulfoxy)ethyl]sulfonyl]azo]-", "2, 7-naphthalenedisulfonic acid, tetrasodium

salt", "Remazol Black B"

Section 2 - HAZARDS IDENTIFICATION

CHEMWATCH HAZARD RATINGS

Min Max

Flammability: 1

Toxicity: 0

Body Contact: 0

Reactivity: 1

Chronic: 2

Min/Nil=0

Low=1

Moderate=2

High=3

Extreme=4

CANADIAN WHMIS SYMBOLS

FLAMMABILITY1HEALTH HAZARD0 INSTABILITY0

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EMERGENCY OVERVIEW

RISKMay cause SENSITISATION by inhalation.

POTENTIAL HEALTH EFFECTS

ACUTE HEALTH EFFECTS

SWALLOWED! The material has NOT been classified as "harmful by ingestion". This is because of the lack of corroborating animal or human evidence.

<\p>.

EYE! Although the material is not thought to be an irritant, direct contact with the eye may cause transient discomfort characterized by tearing or

conjunctival redness (as with windburn). Slight abrasive damage may also result.

<\p>.

SKIN! The material is not thought to produce adverse health effects or skin irritation following contact (as classified using animal models).

Nevertheless, good hygiene practice requires that exposure be kept to a minimum and that suitable gloves be used in an occupational

setting.

! Open cuts, abraded or irritated skin should not be exposed to this material.

! Entry into the blood-stream, through, for example, cuts, abrasions or lesions, may produce systemic injury with harmful effects. Examine

the skin prior to the use of the material and ensure that any external damage is suitably protected.

INHALED! The material is not thought to produce adverse health effects or irritation of the respiratory tract (as classified using animal models).

Nevertheless, good hygiene practice requires that exposure be kept to a minimum and that suitable control measures be used in an

occupational setting.

! Persons with impaired respiratory function, airway diseases and conditions such as emphysema or chronic bronchitis, may incur further

disability if excessive concentrations of particulate are inhaled.

CHRONIC HEALTH EFFECTS! Inhaling this product is more likely to cause a sensitization reaction in some persons compared to the general population.

Limited evidence suggests that repeated or long-term occupational exposure may produce cumulative health effects involving organs or

biochemical systems.

There is limited evidence that, skin contact with this product is more likely to cause a sensitization reaction in some persons compared to the

general population.

Long term exposure to high dust concentrations may cause changes in lung function i.e. pneumoconiosis; caused by particles less than 0.5

micron penetrating and remaining in the lung.

<\p>.

Some azo dyes may be able to cause mutations and be associated with thedevelopment of bladder cancer.

Respiratory sensitization may result in allergic/asthma like responses; from coughing and minor breathing difficulties to bronchitis with

wheezing, gasping.

Occupational exposure to reactive dyes may result in irritation of the respiratory tract, when inhaled in the dust form.

Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS

NAME CAS RN %

C.I. Reactive Black 5 17095-24-8 >98

Section 4 - FIRST AID MEASURES

SWALLOWED" Immediately give a glass of water. " First aid is not generally required. If in doubt, contact a Poisons Information Center or a doctor.

EYE! If this product comes in contact with eyes: " Wash out immediately with water. " If irritation continues, seek medical attention.

SKIN! If skin contact occurs: " Immediately remove all contaminated clothing, including footwear " Flush skin and hair with running water (and

soap if available).

INHALED" If fumes or combustion products are inhaled remove from contaminated area. " Other measures are usually unnecessary.

NOTES TO PHYSICIAN! Treat symptomatically.

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Periodic medical surveillance should be carried out on persons in occupations exposed to the manufacture or bulk handling of the product

and this should include hepatic function tests and urinalysis examination. [ILO Encyclopaedia].

Section 5 - FIRE FIGHTING MEASURES

Vapour Pressure (mmHG): Negligible

Upper Explosive Limit (%): Not available

Specific Gravity (water=1): Not available.

Lower Explosive Limit (%): Not available

EXTINGUISHING MEDIA" Water spray or fog.

" Foam.

FIRE FIGHTING" Alert Emergency Responders and tell them location and nature of hazard.

" Wear breathing apparatus plus protective gloves.

GENERAL FIRE HAZARDS/HAZARDOUS COMBUSTIBLE PRODUCTS" Combustible solid which burns but propagates flame with difficulty.

" Avoid generating dust, particularly clouds of dust in a confined or unventilated space as dusts may form an explosive mixture with air, and

any source of ignition, i.e. flame or spark, will cause fire or explosion. Dust clouds generated by the fine grinding of the solid are a particular

hazard; accumulations of fine dust may burn rapidly and fiercely if ignited.

Combustion products include: carbon monoxide (CO), carbon dioxide (CO2), nitrogen oxides (NOx), sulfur oxides (SOx), other pyrolysis

products typical of burning organic material.

May emit poisonous fumes.

May emit corrosive fumes.

FIRE INCOMPATIBILITY! Avoid contamination with oxidizing agents i.e. nitrates, oxidizing acids,chlorine bleaches, pool chlorine etc. as ignition may result.

PERSONAL PROTECTIONGlasses:

Chemical goggles.

Gloves:

Respirator:

Particulate

Section 6 - ACCIDENTAL RELEASE MEASURES

MINOR SPILLS

" Clean up all spills immediately.

" Avoid breathing dust and contact with skin and eyes.

MAJOR SPILLS

! Moderate hazard.

" CAUTION: Advise personnel in area.

" Alert Emergency Responders and tell them location and nature of hazard.

Section 7 - HANDLING AND STORAGE

PROCEDURE FOR HANDLING" Avoid all personal contact, including inhalation.

" Wear protective clothing when risk of exposure occurs.

Empty containers may contain residual dust which has the potential to accumulate following settling. Such dusts may explode in the presence

of an appropriate ignition source.

" Do NOT cut, drill, grind or weld such containers.

" In addition ensure such activity is not performed near full, partially empty or empty containers without appropriate workplace safety

authorisation or permit.

RECOMMENDED STORAGE METHODS" Polyethylene or polypropylene container.

" Check all containers are clearly labelled and free from leaks.

STORAGE REQUIREMENTS" Store in original containers.

" Keep containers securely sealed.

Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION

EXPOSURE CONTROLS

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Source Material TWA ppmTWA

mg/m#STEL ppm

STEL

mg/m#Peak ppm

Peak

mg/m#TWA F/CC Notes

___________ ___________ _______ _______ _______ _______ _______ _______ _______ _______

US - California

Permissible

Exposure Limits

for Chemical

Contaminants

C.I. Reactive

Black 5

(Particulates not

otherwise

regulated

Respirable

fraction)

5 (n)

US - Tennessee

Occupational

Exposure Limits -

Limits For Air

Contaminants

C.I. Reactive

Black 5

(Particulates not

otherwise

regulated

Respirable

fraction)

5

US - Wyoming

Toxic and

Hazardous

Substances Table

Z1 Limits for Air

Contaminants

C.I. Reactive

Black 5

(Particulates not

otherwise

regulated

(PNOR)(f)-

Respirable

fraction)

5

US - Michigan

Exposure Limits

for Air

Contaminants

C.I. Reactive

Black 5

(Particulates not

otherwise

regulated,

Respirable dust)

5

Canada - Prince

Edward Island

Occupational

Exposure Limits

C.I. Reactive

Black 5 (Particles

(Insoluble or

Poorly Soluble)

[NOS] Inhalable

particles)

10

See

Appendix B

current

TLV/BEI

Book

ENDOELTABLE

PERSONAL PROTECTION

RESPIRATORParticulate

Consult your EHS staff for recommendations

EYE" Safety glasses with side shields.

" Chemical goggles.

HANDS/FEET! NOTE: The material may produce skin sensitization in predisposed individuals. Care must be taken, when removing gloves and other

protective equipment, to avoid all possible skin contact.

Suitability and durability of glove type is dependent on usage. Important factors in the selection of gloves include: such as:

" frequency and duration of contact,

" chemical resistance of glove material,

" glove thickness and

" dexterity

Select gloves tested to a relevant standard (e.g. Europe EN 374, US F739).

" When prolonged or frequently repeated contact may occur, a glove with a protection class of 5 or higher (breakthrough time greater than

240 minutes according to EN 374) is recommended.

" When only brief contact is expected, a glove with a protection class of 3 or higher (breakthrough time greater than 60 minutes according to

EN 374) is recommended.

" Contaminated gloves should be replaced.

Gloves must only be worn on clean hands. After using gloves, hands should be washed and dried thoroughly. Application of a non-perfumed

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moisturiser is recommended.

Experience indicates that the following polymers are suitable as glove materials for protection against undissolved, dry solids, where abrasive

particles are not present.

" polychloroprene

" nitrile rubber

" butyl rubber

" fluorocaoutchouc

" polyvinyl chloride

Gloves should be examined for wear and/ or degradation constantly.

OTHER" Overalls.

" P.V.C. apron.

" Barrier cream.

" Skin cleansing cream.

" Eye wash unit.

ENGINEERING CONTROLS" Local exhaust ventilation is required where solids are handled as powders or crystals; even when particulates are relatively large, a certain

proportion will be powdered by mutual friction.

" Exhaust ventilation should be designed to prevent accumulation and recirculation of particulates in the workplace.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

PHYSICAL PROPERTIES

Solid.

Mixes with water.

State Divided solid Molecular Weight 991.82

Melting Range (°F) >572 Viscosity Not Applicable

Boiling Range (°F) Not available Solubility in water (g/L) Miscible

Flash Point (°F) Not available pH (1% solution) Not available

Decomposition Temp (°F) Not available pH (as supplied) Not applicable

Autoignition Temp (°F) Not available Vapour Pressure (mmHG) Negligible

Upper Explosive Limit (%) Not available Specific Gravity (water=1) Not available.

Lower Explosive Limit (%) Not available Relative Vapor Density (air=1) Not applicable.

Volatile Component (%vol) Negligible Evaporation Rate Not applicable

APPEARANCEBlack powder; mixes with water.

Section 10 - CHEMICAL STABILITY

CONDITIONS CONTRIBUTING TO INSTABILITY" Presence of incompatible materials.

" Product is considered stable.

STORAGE INCOMPATIBILITY" Toxic gases are formed by mixing azo and azido compounds with acids, aldehydes, amides, carbamates, cyanides, inorganic fluorides,

halogenated organics, isocyanates, ketones, metals, nitrides, peroxides, phenols, epoxides, acyl halides, and strong oxidizing or reducing

agents.

" Flammable gases are formed by mixing azo and azido compounds with alkali metals.

Avoid reaction with oxidizing agents, bases and strong reducing agents.

For incompatible materials - refer to Section 7 - Handling and Storage.

Section 11 - TOXICOLOGICAL INFORMATION

C.I. REACTIVE BLACK 5

TOXICITY AND IRRITATION

C.I. REACTIVE BLACK 5:! unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances.

! Allergic reactions involving the respiratory tract are usually due to interactions between IgE antibodies and allergens and occur rapidly.

Allergic potential of the allergen and period of exposure often determine the severity of symptoms.

<\p>.

Attention should be paid to atopic diathesis, characterized by increased susceptibility to nasal inflammation, asthma and eczema.

Exogenous allergic alveolitis is induced essentially by allergen specific immune-complexes of the IgG type; cell-mediated reactions (T

5 of 7

lymphocytes) may be involved. Such allergy is of the delayed type with onset up to four hours following exposure.

No significant acute toxicological data identified in literature search.

Section 12 - ECOLOGICAL INFORMATION

No data

Ecotoxicity

IngredientPersistence:

Water/SoilPersistence: Air Bioaccumulation Mobility

C.I. Reactive

Black 5LOW

GESAMP/EHS COMPOSITE LIST - GESAMP Hazard Profiles

Name / EHS TRN A1a A1b A1 A2 B1 B2 C1 C2 C3 D1 D2 D3 E1 E2 E3 Cas No / RTECS No _________ ___ ___ ___ ___ ___ ___ ___ ___

___ ___ ___ ___ ___ ___ ___ ___ ___ Poly(2+)c 224 574 4 4 4 NR (4) NI (1) (1) (2) (1) (1) CM S 3 yclic 6 aromatics / CAS:17095 - 24- 8 /

Legend: EHS=EHS Number (EHS=GESAMP Working Group on the Evaluation of the Hazards of Harmful Substances Carried by Ships)

NRT=Net Register Tonnage, A1a=Bioaccumulation log Pow, A1b=Bioaccumulation BCF, A1=Bioaccumulation, A2=Biodegradation,

B1=Acuteaquatic toxicity LC/ECIC50 (mg/l), B2=Chronic aquatic toxicity NOEC (mg/l), C1=Acute mammalian oral toxicity LD50 (mg/kg),

C2=Acutemammalian dermal toxicity LD50 (mg/kg), C3=Acute mammalian inhalation toxicity LC50 (mg/kg), D1=Skin irritation & corrosion,

D2=Eye irritation& corrosion, D3=Long-term health effects, E1=Tainting, E2=Physical effects on wildlife & benthic habitats, E3=Interference

with coastal amenities, For column A2: R=Readily biodegradable, NR=Not readily biodegradable. For column D3: C=Carcinogen,

M=Mutagenic, R=Reprotoxic, S=Sensitising, A=Aspiration hazard, T=Target organ systemic toxicity, L=Lunginjury, N=Neurotoxic,

I=Immunotoxic. For column E1: NT=Not tainting (tested), T=Tainting test positive. For column E2: Fp=Persistent floater, F=Floater, S=Sinking

substances. The numerical scales start from 0 (no hazard), while higher numbers reflect increasing hazard. (GESAMP/EHS Composite List

of Hazard Profiles - Hazard evaluation of substances transported by ships)

Section 13 - DISPOSAL CONSIDERATIONS

Disposal InstructionsAll waste must be handled in accordance with local, state and federal regulations.

$ Puncture containers to prevent re-use and bury at an authorized landfill.

Legislation addressing waste disposal requirements may differ by country, state and/ or territory. Each user must refer to laws operating in

their area. In some areas, certain wastes must be tracked.

A Hierarchy of Controls seems to be common - the user should investigate:

" Reduction

" Reuse

" Recycling

" Disposal (if all else fails)

This material may be recycled if unused, or if it has not been contaminated so as to make it unsuitable for its intended use. Shelf life

considerations should also be applied in making decisions of this type. Note that properties of a material may change in use, and recycling or

reuse may not always be appropriate.

DO NOT allow wash water from cleaning equipment to enter drains. Collect all wash water for treatment before disposal.

" Recycle wherever possible.

" Consult manufacturer for recycling options or consult Waste Management Authority for disposal if no suitable treatment or disposal facility

can be identified.

Section 14 - TRANSPORTATION INFORMATION

NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS: DOT, IATA, IMDG

Section 15 - REGULATORY INFORMATION

C.I. Reactive Black 5 (CAS: 17095-24-8) is found on the following regulatory lists;"Canada Domestic Substances List (DSL)","Canada Toxicological Index Service - Workplace Hazardous Materials Information System -

WHMIS (English)","OECD Representative List of High Production Volume (HPV) Chemicals","US EPA High Production Volume Program

Chemical List","US Toxic Substances Control Act (TSCA) - Inventory"

Section 16 - OTHER INFORMATION

LIMITED EVIDENCE! Cumulative effects may result following exposure*.

! Possible skin sensitiser*.

* (limited evidence).

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Reasonable care has been taken in the preparation of this information, but the author makes no warranty of

merchantability or any other warranty, expressed or implied, with respect to this information. The author makes no

representations and assumes no liability for any direct, incidental or consequential damages resulting from its use.

For additional technical information please call our toxicology department on +800 CHEMCALL.

! Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent

review by the Chemwatch Classification committee using available literature references.

A list of reference resources used to assist the committee may be found at:

www.chemwatch.net/references.

! The (M)SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the

reported Hazards are Risks in the workplace or other settings. Risks may be determined by reference to Exposures Scenarios. Scale of use,

frequency of use and current or available engineering controls must be considered.

This document is copyright. Apart from any fair dealing for the purposes of private study, research, review or

criticism, as permitted under the Copyright Act, no part may be reproduced by any process without written

permission from CHEMWATCH. TEL (+61 3) 9572 4700.

Issue Date: Sep-15-2009

Print Date:Nov-23-2010

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Material Safety Data SheetResorcinol MSDS


Product Name: Resorcinol

Catalog Codes: SLR1486, SLR1159, SLR1483

CAS#: 108-46-3

RTECS: VG9625000

TSCA: TSCA 8(b) inventory: Resorcinol

CI#: Not available.

Synonym: Resorcin; 1,3-Benzenediol; m-dihydroxybenzene

Chemical Name: Resorcinol










Composition:


Resorcinol 108-46-3 100

Toxicological Data on Ingredients: Resorcinol: ORAL (LD50): Acute: 301 mg/kg [Rat]. 200 mg/kg [Mouse]. DERMAL(LD50): Acute: 3360 mg/kg [Rabbit].


Potential Acute Health Effects:Hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, of inhalation. Slightly hazardous in case ofskin contact (permeator).

Potential Chronic Health Effects:CARCINOGENIC EFFECTS: Classified 4 (No evidence.) by NTP. A4 (Not classifiable for human or animal.) by ACGIH, 3 (Notclassifiable for human.) by IARC. MUTAGENIC EFFECTS: Mutagenic for bacteria and/or yeast. TERATOGENIC EFFECTS:Not available. DEVELOPMENTAL TOXICITY: Not available. The substance may be toxic to liver, cardiovascular system,endocrine. Repeated or prolonged exposure to the substance can produce target organs damage.



p. 2














Fire Hazards in Presence of Various Substances: Slightly flammable to flammable in presence of open flames and sparks,of heat.




Special Remarks on Explosion Hazards: Potentially explosive reaction with nitric acid.



Large Spill:Use a shovel to put the material into a convenient waste disposal container. Be careful that the product is not present at aconcentration level above TLV. Check TLV on the MSDS and with local authorities.

p. 3


Precautions:Keep locked up.. Keep away from heat. Keep away from sources of ignition. Empty containers pose a fire risk, evaporatethe residue under a fume hood. Ground all equipment containing material. Do not ingest. Do not breathe dust. Wear suitableprotective clothing. In case of insufficient ventilation, wear suitable respiratory equipment. If ingested, seek medical adviceimmediately and show the container or the label. Avoid contact with skin and eyes. Keep away from incompatibles such asoxidizing agents, acids.






Exposure Limits:TWA: 45 STEL: 90 (mg/m3) from ACGIH (TLV) [United States] TWA: 10 STEL: 20 (ppm) from ACGIH (TLV) [United States]TWA: 10 STEL: 20 from NIOSH [United States] TWA: 45 STEL: 90 (mg/m3) from NIOSH [United States] TWA: 10 STEL: 20(ppm) from OSHA (PEL) [United States] TWA: 45 STEL: 90 (mg/m3) from OSHA (PEL) [United States] TWA: 10 STEL: 20(ppm) [United Kingdom (UK)] TWA: 46 STEL: 92 (mg/m3) [United Kingdom (UK)]3 Consult local authorities for acceptableexposure limits.


Physical state and appearance: Solid. (Crystals solid. Powdered solid.)

Odor: Characteristic. (Slight.)

Taste: Sweetish followed by bitter.


Color: White.










p. 4



Dispersion Properties: See solubility in water, diethyl ether.

Solubility: Easily soluble in cold water, diethyl ether.




Conditions of Instability: Excess heat, incompatible materials



Special Remarks on Reactivity:Incompatible with acetanilide, albumin, alkalies, antipyrine, camphor, ferri salts, menthol, spirit nitrous ether, urethane,periodate. When heated to decompostion, it emits acrid smoke and irritating fumes.




Routes of Entry: Absorbed through skin. Dermal contact. Inhalation. Ingestion.

Toxicity to Animals:Acute oral toxicity (LD50): 200 mg/kg [Mouse]. Acute dermal toxicity (LD50): 3360 mg/kg [Rabbit].

Chronic Effects on Humans:CARCINOGENIC EFFECTS: Classified 4 (No evidence.) by NTP. A4 (Not classifiable for human or animal.) by ACGIH, 3 (Notclassifiable for human.) by IARC. MUTAGENIC EFFECTS: Mutagenic for bacteria and/or yeast. May cause damage to thefollowing organs: liver, cardiovascular system, endocrine.

Other Toxic Effects on Humans:Hazardous in case of skin contact (irritant), of ingestion, of inhalation. Slightly hazardous in case of skin contact (permeator).


Special Remarks on Chronic Effects on Humans:May cause cancer based on animal data. No human data found May affect genetic material.

Special Remarks on other Toxic Effects on Humans:Acute Potential Health Effects: Skin: Causes skin irritation. It may be absorbed through the skin and affect metabolism.Eyes: Causes eye irritation. Inhalation: Causes respiratory tract and mucous membrane irritation. Ingestion: May causegastrointestinal tract irritation. It may affect the blood (methemoglobinemia), respiration(cyanosis. dyspnea), behavior/nervoussystem(convulsions, excitement, tetany, coma, spastic paralysis), cardiovascular system(hypotension), liver, and kidneys.Chronic Potential Health Effects: Skin: Prolonged or repeated skin contact may cause dermatitis, an allergic skin reaction.Ingestion: Prolonged or repeated ingestion may affect the endocrine system (adrenal gland, thymus), liver, kidneys, andmetabolism.




p. 5








Identification: : Resorcinol UNNA: 2876 PG: III



Federal and State Regulations:Connecticut hazardous material survey.: Resorcinol Illinois toxic substances disclosure to employee act: Resorcinol Illinoischemical safety act: Resorcinol New York release reporting list: Resorcinol Rhode Island RTK hazardous substances:Resorcinol Pennsylvania RTK: Resorcinol Minnesota: Resorcinol Massachusetts RTK: Resorcinol Massachusetts spill list:Resorcinol New Jersey: Resorcinol New Jersey spill list: Resorcinol Louisiana spill reporting: Resorcinol California Director'sList of Hazardous Substances: Resorcinol TSCA 8(b) inventory: Resorcinol CERCLA: Hazardous substances.: Resorcinol:5000 lbs. (2268 kg)



WHMIS (Canada):CLASS D-1B: Material causing immediate and serious toxic effects (TOXIC). CLASS D-2B: Material causing other toxic effects(TOXIC).

DSCL (EEC):R22- Harmful if swallowed. R36/38- Irritating to eyes and skin. R50- Very toxic to aquatic organisms. S2- Keep out of thereach of children. S26- In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S46- Ifswallowed, seek medical advice immediately and show this container or label. S61- Avoid release to the environment. Refer tospecial instructions/Safety data sheets.

HMIS (U.S.A.):

Health Hazard: 2

Fire Hazard: 1

Reactivity: 0



Health: 2

Flammability: 1

p. 6

Reactivity: 0

Specific hazard:





Created: 10/10/2005 08:25 PM

Last Updated: 05/21/2013 12:00 PM


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Material Safety Data SheetSalicylic acid MSDS


Product Name: Salicylic acid


CAS#: 69-72-7

RTECS: VO0525000


CI#: Not available.

Synonym: 2-hydroxybenzoic acid

Chemical Name: Salicylic Acid










Composition:


Salicylic acid 69-72-7 100

Toxicological Data on Ingredients: Salicylic acid: ORAL (LD50): Acute: 891 mg/kg [Rat]. 480 mg/kg [Mouse]. 1300 mg/kg[Rabbit].


Potential Acute Health Effects:Hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, of inhalation (lung irritant). Slightly hazardousin case of skin contact (permeator). Severe over-exposure can result in death.

Potential Chronic Health Effects:CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Mutagenic for bacteria and/or yeast. TERATOGENICEFFECTS: Not available. DEVELOPMENTAL TOXICITY: Classified Reproductive system/toxin/female, Development toxin[POSSIBLE]. Repeated exposure to a highly toxic material may produce general deterioration of health by an accumulation inone or many human organs.


Eye Contact:


p. 2

Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15minutes. Cold water may be used. Get medical attention immediately.











Flammable Limits: LOWER: 1.1%


Fire Hazards in Presence of Various Substances: Slightly flammable to flammable in presence of heat.




Special Remarks on Explosion Hazards: Dust-Air mixtures may pose an explosion hazard.



Large Spill:Poisonous solid. Stop leak if without risk. Do not get water inside container. Do not touch spilled material. Use water spray toreduce vapors. Prevent entry into sewers, basements or confined areas; dike if needed. Eliminate all ignition sources. Call forassistance on disposal. Finish cleaning by spreading water on the contaminated surface and allow to evacuate through thesanitary system.


p. 3

Precautions:Keep locked up.. Keep away from heat. Keep away from sources of ignition. Empty containers pose a fire risk, evaporatethe residue under a fume hood. Ground all equipment containing material. Do not ingest. Do not breathe dust. Wear suitableprotective clothing. In case of insufficient ventilation, wear suitable respiratory equipment. If ingested, seek medical adviceimmediately and show the container or the label. Avoid contact with skin and eyes. Keep away from incompatibles such asoxidizing agents, moisture.

Storage:LIGHT SENSITIVE. MOISTURE SENSITIVE. Store in light resistant containers. Keep container tightly closed. Keep containerin a cool, well-ventilated area. Do not store above 23°C (73.4°F).







Physical state and appearance: Solid. (Crystalline granules )

Odor: Odorless.

Taste: sweetish , afterward acrid


Color: White.


Boiling Point: Decomposition temperature: 211°C (411.8°F)










Dispersion Properties: See solubility in water, acetone.

p. 4

Solubility:Soluble in acetone. Partially soluble in cold water. Very slightly soluble in hot water.




Conditions of Instability:Excessive heat, excessive dust generation, Incompatible materials. Dust-Air mixtures

Incompatibility with various substances: Reactive with oxidizing agents, moisture.


Special Remarks on Reactivity: Light, moisture, Iron salts, spirt nitrous ether, lead acetate, iodine




Routes of Entry: Absorbed through skin. Inhalation. Ingestion.

Toxicity to Animals:WARNING: THE LC50 VALUES HEREUNDER ARE ESTIMATED ON THE BASIS OF A 4-HOUR EXPOSURE. Acute oraltoxicity (LD50): 480 mg/kg [Mouse]. Acute toxicity of the dust (LC50): 900 mg/m3 1 hours [Rat].

Chronic Effects on Humans:MUTAGENIC EFFECTS: Mutagenic for bacteria and/or yeast. DEVELOPMENTAL TOXICITY: Classified Reproductivesystem/toxin/female, Development toxin [POSSIBLE].

Other Toxic Effects on Humans:Hazardous in case of skin contact (irritant), of ingestion, of inhalation (lung irritant). Slightly hazardous in case of skin contact(permeator).


Special Remarks on Chronic Effects on Humans:May affect genetic material (mutagenicity) based on animal studies. May cause adverse reproductive effects. Teratorgenic,Embryotoxic and/or foetotoxic in animal studies. Human: Transferred into maternal breast milk.

Special Remarks on other Toxic Effects on Humans:Acute Potential Health Efffects: Skin: May be harmful through skin absorption, May cause skin irritation. May affect thecardiovascular system (increase in blood pressure), and metabolism (body temperature increase) if absorbe through skinEye: Causes eye irritation, tempory injury. Inhalation: Causes irritation of the respiratory system (coughing, difficult breathing),ringing in the ears, confusion, rapid pulse, headache, dizziness, nausea, and vomiting. Ingestion: May be harmful if swallowedin large amounts. Causes irritation of the gastrointestinal tract (nausea, vomiting abdominal pains). May affect behavior(muscle weakness and general depressed activity, confusion). May cause ringing in the ears, rapid breathing, sweatingand possible kidney damage. Sever overexposure may result in central nervous system stimulation followed by depression.Chronic Potential Heath Effects: Possible hypersensitization.




Products of Biodegradation:

p. 5

Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.




Waste Disposal:






Federal and State Regulations: TSCA 8(b) inventory: Salicylic acid




DSCL (EEC):R22- Harmful if swallowed. R37/38- Irritating to respiratory system and skin. R41- Risk of serious damage to eyes. S26- Incase of contact with eyes, rinse immediately with plenty of water and seek medical advice. S37/39- Wear suitable gloves andeye/face protection.

HMIS (U.S.A.):

Health Hazard: 2

Fire Hazard: 1

Reactivity: 0



Health: 0

Flammability: 1

Reactivity: 0

Specific hazard:





p. 6

Created: 10/10/2005 08:25 PM

Last Updated: 05/21/2013 12:00 PM


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Material Safety Data SheetSodium acetate anhydrous MSDS


Product Name: Sodium acetate anhydrous


CAS#: 127-09-3

RTECS: AJ4300010

TSCA: TSCA 8(b) inventory: Sodium acetate anhydrous


Synonym: Acetic acid, sodium salt

Chemical Name: Sodium acetate

Chemical Formula: CH3COONa









Composition:


Sodium acetate anhydrous 127-09-3 100

Toxicological Data on Ingredients: Not applicable.


Potential Acute Health Effects:Hazardous in case of ingestion, of inhalation. Slightly hazardous in case of skin contact (irritant), of eye contact (irritant).



Eye Contact:Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15minutes. Cold water may be used. Get medical attention if irritation occurs.

Skin Contact:


p. 2

Wash with soap and water. Cover the irritated skin with an emollient. Get medical attention if irritation develops. Cold watermay be used.












Fire Hazards in Presence of Various Substances:Slightly flammable to flammable in presence of open flames and sparks, of heat. Non-flammable in presence of shocks.



Special Remarks on Fire Hazards: Combustible when exposed to heat or flame.



Small Spill:Use appropriate tools to put the spilled solid in a convenient waste disposal container. If necessary: Neutralize the residue witha dilute solution of acetic acid. Finish cleaning by spreading water on the contaminated surface and dispose of according tolocal and regional authority requirements.

Large Spill:Use a shovel to put the material into a convenient waste disposal container. Neutralize the residue with a dilute solutionof acetic acid. Finish cleaning by spreading water on the contaminated surface and allow to evacuate through the sanitarysystem.


Precautions:Keep away from heat. Keep away from sources of ignition. Empty containers pose a fire risk, evaporate the residue under afume hood. Ground all equipment containing material. Do not ingest. Do not breathe dust. Wear suitable protective clothing. In

p. 3

case of insufficient ventilation, wear suitable respiratory equipment. If ingested, seek medical advice immediately and show thecontainer or the label. Keep away from incompatibles such as oxidizing agents, acids.








Physical state and appearance: Solid. (Granular, crystalline powder.)

Odor: Odorless to acetic (Slight.)



Color: Colorless. White.

pH (1% soln/water): 11 [Basic.]















p. 4


Conditions of Instability: Excess heat, incompatible materials, moisture.



Special Remarks on Reactivity:Hygroscopic; keep container tightly closed. Incompatible (violent reaction) with fluorine diketene, potassium nitrate. Alsoincompatible wth nitric acid. Emits fumes of acetic acid upon heating and on contact with strong acids.





Toxicity to Animals:WARNING: THE LC50 VALUES HEREUNDER ARE ESTIMATED ON THE BASIS OF A 4-HOUR EXPOSURE. Acute oraltoxicity (LD50): 3530 mg/kg [Rat]. Acute dermal toxicity (LD50): >10000 mg/kg [Rabbit]. Acute toxicity of the dust (LC50):>30000 mg/m 1 hours [Rat]. 3


Other Toxic Effects on Humans:Hazardous in case of ingestion, of inhalation. Slightly hazardous in case of skin contact (irritant).



Special Remarks on other Toxic Effects on Humans:Acute Potential Health Effects: Skin: May cause skin irritation. Eyes: May cause eye irritation. Ingestion: May cause digestivetract irritation with abdominal pain, nausea, and vomiting. May affect behavior, and urinary system. Inhalation: May causerespiratory tract irritation. Symptoms may include coughing, sore throat, labored breathing, and chest pain.











p. 5




Federal and State Regulations: TSCA 8(b) inventory: Sodium acetate anhydrous





HMIS (U.S.A.):

Health Hazard: 2

Fire Hazard: 1

Reactivity: 0



Health: 2

Flammability: 1

Reactivity: 0

Specific hazard:



References:-Hawley, G.G.. The Condensed Chemical Dictionary, 11e ed., New York N.Y., Van Nostrand Reinold, 1987. -SAX, N.I.Dangerous Properties of Indutrial Materials. Toronto, Van Nostrand Reinold, 6e ed. 1984. -The Sigma-Aldrich Library ofChemical Safety Data, Edition II. Registery of Toxic Effects of Chemical Substances. Hazardous Substance Data Bank.


Created: 10/09/2005 06:28 PM

Last Updated: 05/21/2013 12:00 PM


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Material Safety Data SheetSodium bisulfate MSDS


Product Name: Sodium bisulfate

Catalog Codes: SLS2104, SLS4258

CAS#: 7681-38-1

RTECS: VZ1860000

TSCA: TSCA 8(b) inventory: Sodium bisulfate

CI#: Not available.

Synonym: GBS; Nitre cake; Sodium acid sulfate; Sodiumpyrosulfate; Sodium hydrogen sulfate; Sulfuric acid,monosodium salt.

Chemical Name: Sodium Bisulfate

Chemical Formula: NaHSO4









Composition:


Sodium bisulfate 7681-38-1 100

Toxicological Data on Ingredients: Sodium bisulfate: ORAL (LD50): Acute: 2800 mg/kg [Rat].


Potential Acute Health Effects:Very hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, of inhalation. Hazardous in case of skincontact (corrosive, permeator). The amount of tissue damage depends on length of contact. Eye contact can result in cornealdamage or blindness. Skin contact can produce inflammation and blistering. Inhalation of dust will produce irritation to gastro-intestinal or respiratory tract, characterized by burning, sneezing and coughing. Severe over-exposure can produce lungdamage, choking, unconsciousness or death. Inflammation of the eye is characterized by redness, watering, and itching. Skininflammation is characterized by itching, scaling, reddening, or, occasionally, blistering.

Potential Chronic Health Effects:CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Mutagenic for bacteria and/or yeast. TERATOGENICEFFECTS: Not available. DEVELOPMENTAL TOXICITY: Not available. Repeated exposure of the eyes to a low level of dustcan produce eye irritation. Repeated skin exposure can produce local skin destruction, or dermatitis. Repeated inhalation ofdust can produce varying degree of respiratory irritation or lung damage.


p. 2






















Large Spill:Corrosive solid. Stop leak if without risk. Do not get water inside container. Do not touch spilled material. Use water spray toreduce vapors. Prevent entry into sewers, basements or confined areas; dike if needed. Call for assistance on disposal.

p. 3


Precautions:Keep locked up.. Keep container dry. Do not ingest. Do not breathe dust. Never add water to this product. In case ofinsufficient ventilation, wear suitable respiratory equipment. If ingested, seek medical advice immediately and show thecontainer or the label. Avoid contact with skin and eyes. Keep away from incompatibles such as oxidizing agents, alkalis.




Personal Protection:Splash goggles. Synthetic apron. Vapor and dust respirator. Be sure to use an approved/certified respirator or equivalent.Gloves.

Personal Protection in Case of a Large Spill:Splash goggles. Full suit. Vapor and dust respirator. Boots. Gloves. A self contained breathing apparatus should be used toavoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handlingthis product.



Physical state and appearance: Solid. (Granular solid.)




Color: Off-white.



Melting Point: 157.22°C (315°F)










Solubility:

p. 4

Easily soluble in hot water. Soluble in cold water. Soluble in 2 parts cold water. Soluble in 1 part boiling water. Decomposed byalcohol into sodium sulfate and free H2SO4.




Conditions of Instability: Incompatible materials, moisture

Incompatibility with various substances: Reactive with oxidizing agents, alkalis.


Special Remarks on Reactivity:Do not mix with liquid chlorine bleach (hypochlorites), ammonia cleansers or similar products, or alcohols. Hygroscopic; keepcontainer tightly closed.




Routes of Entry: Absorbed through skin. Dermal contact. Inhalation. Ingestion.


Chronic Effects on Humans: MUTAGENIC EFFECTS: Mutagenic for bacteria and/or yeast.

Other Toxic Effects on Humans:Very hazardous in case of skin contact (irritant), of ingestion, of inhalation. Hazardous in case of skin contact (corrosive,permeator).


Special Remarks on Chronic Effects on Humans: May affect genetic material (mutagenic)

Special Remarks on other Toxic Effects on Humans:Acute Potential Health Effects: Skin: Can cause severe skin irritation or burns. Eyes: Can cause severe irritation or burnsof the eyes. Inhalation: It is destructive to the mucous membranes of the upper respiratory tract. Causes irritation andchemical burns to the respiratory tract with burning pain in the nose and throat, coughing , wheezing, shortness of breath,and pulmonary edema. Inhalation may be fatal as a result of spasm, inflammation, edema of the larynx and bronchi, chemicalpneumonitis, and pulmonary edema. Ingestion: Causes gastrointestinal tract irritation and burns. Symptoms may includenausea and vomiting. May cause severe and permanent damage to the digestive tract. Chronic Potential Health Effects:Repeated exposure may cause erosion of teeth, lung irritation, bronchitis, persistant coughing,








p. 5




Identification: : Corrosive Solid, n.o.s.(Sodium Bisulfate) UNNA: 1759 PG: III



Federal and State Regulations:Connecticut hazardous material survey.: Sodium bisulfate New Jersey: Sodium bisulfate TSCA 8(b) inventory: Sodiumbisulfate



WHMIS (Canada): CLASS E: Corrosive solid.

DSCL (EEC):R34- Causes burns. R41- Risk of serious damage to eyes. S24/25- Avoid contact with skin and eyes. S26- In case of contactwith eyes, rinse immediately with plenty of water and seek medical advice. S36/37/39- Wear suitable protective clothing,gloves and eye/face protection.

HMIS (U.S.A.):

Health Hazard: 3

Fire Hazard: 0

Reactivity: 0

Personal Protection: j


Health: 3

Flammability: 0

Reactivity: 0

Specific hazard:

Protective Equipment:Gloves. Synthetic apron. Vapor and dust respirator. Be sure to use an approved/certified respirator or equivalent. Wearappropriate respirator when ventilation is inadequate. Splash goggles.




Created: 10/10/2005 08:27 PM

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Material Safety Data SheetSodium carbonate MSDS


Product Name: Sodium carbonate

Catalog Codes: SLS3481, SLS1264, SLS4105, SLS1894,SLS3316

CAS#: 497-19-8

RTECS: VZ4050000

TSCA: TSCA 8(b) inventory: Sodium carbonate

CI#: Not available.

Synonym: Crystal Carbonate, Disodium Carbonate, SalSoda, Soda Asha, Washing Soda

Chemical Name: Sodium Carbonate, Anhydrous

Chemical Formula: Na2-C-O3









Composition:


Sodium carbonate 497-19-8 100

Toxicological Data on Ingredients: Sodium carbonate: ORAL (LD50): Acute: 4090 mg/kg [Rat]. 6600 mg/kg [Mouse]. DUST(LC50): Acute: 2300 mg/m 2 hours [Rat]. 1200 mg/m 2 hours [Mouse].


Potential Acute Health Effects: Hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, of inhalation(lung irritant).

Potential Chronic Health Effects:Slightly hazardous in case of skin contact (sensitizer). CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS:Not available. TERATOGENIC EFFECTS: Not available. DEVELOPMENTAL TOXICITY: Not available. The substance maybe toxic to upper respiratory tract, skin, eyes. Repeated or prolonged exposure to the substance can produce target organsdamage.



p. 2













Products of Combustion: Emits Na2O fumes when heated to decompositon.




Special Remarks on Fire Hazards:Sodium carbonate can ignite and burn fiercely in contact with fluoride. Sodium Carbonate in contact with fluorine decomposedat ordinary temperature with incandescence.

Special Remarks on Explosion Hazards:Reacts explosively with red-hot aluminum metal. Sodium carbonate + ammonia in arabic gum solution will explode.


Small Spill:Use appropriate tools to put the spilled solid in a convenient waste disposal container. If necessary: Neutralize the residue witha dilute solution of acetic acid. Finish cleaning by spreading water on the contaminated surface and dispose of according tolocal and regional authority requirements.

Large Spill:Use a shovel to put the material into a convenient waste disposal container. Neutralize the residue with a dilute solutionof acetic acid. Finish cleaning by spreading water on the contaminated surface and allow to evacuate through the sanitarysystem.

p. 3


Precautions:Do not ingest. Do not breathe dust. Wear suitable protective clothing. In case of insufficient ventilation, wear suitablerespiratory equipment. If ingested, seek medical advice immediately and show the container or the label. Avoid contact withskin and eyes. Keep away from incompatibles such as acids.

Storage:Hygroscopic. Keep container tightly closed. Keep container in a cool, well-ventilated area. Do not store above 24°C (75.2°F).Hygroscopic







Physical state and appearance: Solid. (Solid powder.)

Odor: Odorless.

Taste: Alkaline.


Color: White.

pH (1% soln/water): 11.5 [Basic.]












Solubility:

p. 4

Soluble in hot water, glycerol. Partially soluble in cold water. Insoluble in acetone, alcohol.




Conditions of Instability: Incompatible materials, moisture

Incompatibility with various substances:Reactive with acids. Slightly reactive to reactive with moisture.


Special Remarks on Reactivity:Hygroscopic. Combines with water with evolution of heat. Incompatible with phosphorus pentoxide, lithium, fluorine, fluoride,ammonia + silver nitrate, 2,4,6-trinitrotoluene, ammonia, acids, sodium sulfide + water, hydrogen peroxide, red hot alumiummetal, sodium sulfide, zinc, calcium hydroxide. Sodium Carbonate is decomposed by acids with effervescence. Reactsviolently with F2, Lithium, and 2,4,6-trinitrotoluene. Sodium begins to decompose at 400 C to evolve CO2.

Special Remarks on Corrosivity: Hot concentrated solutions of sodium carbonate are mildly corrosive to steel.




Toxicity to Animals:WARNING: THE LC50 VALUES HEREUNDER ARE ESTIMATED ON THE BASIS OF A 4-HOUR EXPOSURE. Acute oraltoxicity (LD50): 4090 mg/kg [Rat]. Acute toxicity of the dust (LC50): 1200 mg/m3 2 hours [Mouse].

Chronic Effects on Humans: May cause damage to the following organs: upper respiratory tract, skin, eyes.

Other Toxic Effects on Humans: Hazardous in case of skin contact (irritant), of ingestion, of inhalation (lung irritant).

Special Remarks on Toxicity to Animals: LDL (Lowest Published Lethal Dose) [Man] - Route: Oral; Dose: 714 mg/kg

Special Remarks on Chronic Effects on Humans: May cause adverse reproductive effects based on animal test data

Special Remarks on other Toxic Effects on Humans:Acute Potential Health Effects: Skin: Causes skin irritation with possible burns depending on the concentration, site (abradedor intact skin), and duration of exposure. Eyes: Causes eye irritation and possible burns. Concentrated solutions may causepermanent corneal injury (permanent corneal opacity). Ingestion: Sodium carbonate ingestion may cause irritation of thedigestive tract resulting in nausea, vomiting, diarrhea, thirst, abdominal pain depending on concentration and amount ingested.May also affect the cardiovascular system . Inhalation: Dust may cause respiratory tract and mucous membrane irritationwith coughing and shortness of breath (dyspnea), pulmonary edema. Chronic Potential Health Effects: Chronic inhalationmay result in decreased pulmonary function, nasal congestion, nosebleeds, perforation of the nasal septum. Other effectsof chronic exposure are skin (dermatitis and ulceration), and gastrointestinal complaints. However, the effects of chronicexposure seem to be reversible if exposure is decreased.





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Federal and State Regulations: TSCA 8(b) inventory: Sodium carbonate



WHMIS (Canada): CLASS D-2B: Material causing other toxic effects (TOXIC).

DSCL (EEC):R36/37/38- Irritating to eyes, respiratory system and skin. S22- Do not breathe dust. S26- In case of contact with eyes, rinseimmediately with plenty of water and seek medical advice.

HMIS (U.S.A.):

Health Hazard: 2

Fire Hazard: 0

Reactivity: 1



Health: 2

Flammability: 0

Reactivity: 1

Specific hazard:





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Created: 10/10/2005 08:26 PM

Last Updated: 05/21/2013 12:00 PM


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Material Safety Data SheetSodium chloride MSDS


Product Name: Sodium chloride


CAS#: 7647-14-5

RTECS: VZ4725000

TSCA: TSCA 8(b) inventory: Sodium chloride


Synonym: Salt; Sea Salt

Chemical Name: Sodium chloride

Chemical Formula: NaCl









Composition:


Sodium chloride 7647-14-5 100

Toxicological Data on Ingredients: Sodium chloride: ORAL (LD50): Acute: 3000 mg/kg [Rat.]. 4000 mg/kg [Mouse].DERMAL (LD50): Acute: >10000 mg/kg [Rabbit]. DUST (LC50): Acute: >42000 mg/m 1 hours [Rat].



Potential Chronic Health Effects:CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells. Mutagenic forbacteria and/or yeast. TERATOGENIC EFFECTS: Not available. DEVELOPMENTAL TOXICITY: Not available. Repeated orprolonged exposure is not known to aggravate medical condition.


Eye Contact:


p. 2

Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15minutes. Cold water may be used. Get medical attention.
















Special Remarks on Fire Hazards: When heated to decomposition it emits toxic fumes.

Special Remarks on Explosion Hazards:Electrolysis of sodium chloride in presence of nitrogenous compounds to produce chlorine may lead to formation of explosivenitrogen trichloride. Potentially explosive reaction with dichloromaleic anhydride + urea.





Precautions:Keep locked up.. Do not ingest. Do not breathe dust. Avoid contact with eyes. Wear suitable protective clothing. If ingested,seek medical advice immediately and show the container or the label. Keep away from incompatibles such as oxidizingagents, acids.

p. 3








Physical state and appearance: Solid. (Solid crystalline powder.)

Odor: Slight.

Taste: Saline.


Color: White.

pH (1% soln/water): 7 [Neutral.]












Solubility:Easily soluble in cold water, hot water. Soluble in glycerol, and ammonia. Very slightly soluble in alcohol. Insoluble inHydrochloric Acid.



p. 4


Conditions of Instability: Incompatible materials, high temperatures.

Incompatibility with various substances: Reactive with oxidizing agents, metals, acids.

Corrosivity: Not considered to be corrosive for metals and glass.

Special Remarks on Reactivity:Hygroscopic. Reacts with most nonnoble metals such as iron or steel, building materials (such as cement) Sodium chloride israpidly attacked by bromine trifluoride. Violent reaction with lithium.





Toxicity to Animals:WARNING: THE LC50 VALUES HEREUNDER ARE ESTIMATED ON THE BASIS OF A 4-HOUR EXPOSURE. Acute oraltoxicity (LD50): 3000 mg/kg [Rat.]. Acute dermal toxicity (LD50): >10000 mg/kg [Rabbit]. Acute toxicity of the dust (LC50):>42000 mg/m3 1 hours [Rat].

Chronic Effects on Humans: MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells. Mutagenic for bacteria and/or yeast.


Special Remarks on Toxicity to Animals: Lowest Published Lethal Dose (LDL) [Man] - Route: Oral; Dose: 1000 mg/kg

Special Remarks on Chronic Effects on Humans:Causes adverse reproductive effects in humans (fetotoxicity, abortion, ) by intraplacental route. High intake of sodium chloride,whether from occupational exposure or in the diet, may increase risk of TOXEMIA OF PREGNANCY in susceptible women(Bishop, 1978). Hypertonic sodium chloride solutions have been used to induce abortion in late pregnancy by direct infusioninto the uterus (Brown et al, 1972), but this route of administration is not relevant to occupational exposures. May causeadverse reproductive effects and birth defects in animals, particularly rats and mice (fetotoxicity, abortion, musculoskeletalabnormalities, and maternal effects (effects on ovaries, fallopian tubes) by oral, intraperitoneal, intraplacental, intrauterine,parenteral, and subcutaneous routes. While sodium chloride has been used as a negative control n some reproductivestudies, it has also been used as an example that almost any chemical can cause birth defects in experimental animalsif studied under the right conditions (Nishimura & Miyamoto, 1969). In experimental animals, sodium chloride has causeddelayed effects on newborns, has been fetotoxic, and has caused birth defects and abortions in rats and mice (RTECS, 1997).May affect genetic material (mutagenic)

Special Remarks on other Toxic Effects on Humans:Acute Potential Health Effects: Skin: May cause skin irritation. Eyes: Causes eye irritation. Ingestion: Ingestion of largequantities can irritate the stomach (as in overuse of salt tablets) with nausea and vomiting. May affect behavior (musclespasicity/contraction, somnolence), sense organs, metabolism, and cardiovascular system. Continued exposure mayproduce dehydration, internal organ congestion, and coma. Inhalation: Material is irritating to mucous membranes and upperrespiratory tract.






p. 5









Federal and State Regulations: TSCA 8(b) inventory: Sodium chloride




DSCL (EEC):R40- Possible risks of irreversible effects. S24/25- Avoid contact with skin and eyes.

HMIS (U.S.A.):

Health Hazard: 1

Fire Hazard: 0

Reactivity: 0



Health: 1

Flammability: 0

Reactivity: 0

Specific hazard:



References:-Hawley, G.G.. The Condensed Chemical Dictionary, 11e ed., New York N.Y., Van Nostrand Reinold, 1987. -SAX, N.I.Dangerous Properties of Indutrial Materials. Toronto, Van Nostrand Reinold, 6e ed. 1984. -The Sigma-Aldrich Library ofChemical Safety Data, Edition II.


Created: 10/11/2005 12:33 PM

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Sodium Metal

MSDS# 20850

Section 1 - Chemical Product and Company Identification

MSDS Name: Sodium Metal

Catalog Numbers: 61114-4540, S135-1LB, S206-1LB

Synonyms: Natrium; Sodium dry stick; Sodium dry powder.

Company Identification:

Fisher Scientific

One Reagent Lane

Fair Lawn, NJ 07410

For information in the US, call: 201-796-7100

Emergency Number US: 201-796-7100

CHEMTREC Phone Number, US: 800-424-9300

Section 2 - Composition, Information on Ingredients

----------------------------------------

CAS#: 7440-23-5

Chemical Name: Sodium

%: 100

EINECS#: 231-132-9

----------------------------------------

Hazard Symbols: F C

Risk Phrases: 14/15 34

Section 3 - Hazards Identification

EMERGENCY OVERVIEW

Danger! Causes burns by all exposure routes. Contact with water or steam may cause a fire/explosion hazard. Liberates

flammable hydrogen gas. Reacts violently and/or explosively with water, steam or moisture. Target Organs: Respiratory

system, gastrointestinal system, eyes, skin, mucous membranes.


Eye: Causes eye burns.

Skin: Causes skin burns. May be harmful if absorbed through the skin.

Ingestion: Causes gastrointestinal tract burns. May be harmful if swallowed.

Inhalation:Causes chemical burns to the respiratory tract. Inhalation may be fatal as a result of spasm, inflammation, edema

of the larynx and bronchi, chemical pneumonitis and pulmonary edema.

Chronic: Chronic inhalation and ingestion may cause effects similar to those of acute inhalation and ingestion.

Section 4 - First Aid Measures

Eyes:Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower

eyelids. Get medical aid immediately.

Skin:Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing

contaminated clothing and shoes.

Ingestion: Do not induce vomiting. Get medical aid immediately. Call a poison control center.

Inhalation:

Get medical aid immediately. Remove from exposure and move to fresh air immediately. If breathing is

difficult, give oxygen. Do not use mouth-to-mouth resuscitation if victim ingested or inhaled the substance;

induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper

respiratory medical device.

Notes to

Physician:

Section 5 - Fire Fighting Measures

General

Information:

As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH

(approved or equivalent), and full protective gear. Reacts violently with water giving off flammable gas

which may explode. May re-ignite after fire is extinguished.

Extinguishing

Media:

DO NOT USE WATER! Do NOT use CO2 or halogenated extinguishing agents. Smother with dry

sand, dry clay, dry ground limestone (CaCO3), or use approved Class D extinguishers.

Autoignition

Temperature:115 deg C ( 239.00 deg F)

Flash Point: Not applicable.

Explosion Limits:

Lower:Not available

Explosion Limits:

Upper:Not available

NFPA Rating: ; Special Hazard: -W-

Section 6 - Accidental Release Measures

General

Information:Use proper personal protective equipment as indicated in Section 8.

Spills/Leaks:

Wear a self contained breathing apparatus and appropriate personal protection. (See Exposure Controls,

Personal Protection section). Avoid generating dusty conditions. Cover with sand, dry lime or soda ash and

place in a closed container for disposal. Provide ventilation. Do not expose spill to water. Do not let this

chemical enter the environment.

Section 7 - Handling and Storage

Handling:Minimize dust generation and accumulation. Do not get in eyes, on skin, or on clothing. Do not ingest or inhale.

Handle under an inert atmosphere. Do not allow contact with water. Use only in a chemical fume hood.

Storage:Store in a cool, dry place. Store in a tightly closed container. Flammables-area. Water free area. Store under an

inert atmosphere.

Section 8 - Exposure Controls, Personal Protection

+-------------------- +------------------- +------------------- +----------------- +

| Chemical Name | ACGIH | NIOSH |OSHA - Final PELs|

|-------------------- |------------------- |------------------- |----------------- |

| Sodium |none listed |none listed |none listed |

+-------------------- +------------------- +------------------- +----------------- +

OSHA Vacated PELs: Sodium: None listed


Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use only

under a chemical fume hood.

Exposure Limits


Eyes:Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face

protection regulations in 29 CFR 1910.133 or European Standard EN166.

Skin: Wear appropriate protective gloves to prevent skin exposure.

Clothing: Wear appropriate protective clothing to prevent skin exposure.

Respirators:

Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a

NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if

irritation or other symptoms are experienced.

Section 9 - Physical and Chemical Properties

Physical State: Solid

Color: light gray - silver white

Odor: odorless

pH: Not applicable

Vapor Pressure: 1 mm Hg @ 440 deg C

Vapor Density: Not available

Evaporation Rate: Not available

Viscosity: 0.680cp @ 100C

Boiling Point: 883 deg C ( 1,621.40°F)

Freezing/Melting Point: 98 deg C ( 208.40°F)

Decomposition Temperature: Not available

Solubility in water: Reacts violently with water

Specific Gravity/Density: 0.9684 @ 20°C

Molecular Formula: Na


Section 10 - Stability and Reactivity

Chemical Stability: Reacts violently with water.

Conditions to Avoid: Incompatible materials, dust generation, excess heat, exposure to moist air or water.

Incompatibilities with Other Materials Water, oxidizing agents, acids.

Hazardous Decomposition Products Hydrogen gas, sodium oxide.

Hazardous Polymerization Will not occur.

Section 11 - Toxicological Information

RTECS#: CAS# 7440-23-5: VY0686000

LD50/LC50: RTECS: Not available.

Carcinogenicity: Sodium - Not listed as a carcinogen by ACGIH, IARC, NTP, or CA Prop 65.

Other: See actual entry in RTECS for complete information.

Section 12 - Ecological Information

Other: Do not empty into drains.

Section 13 - Disposal Considerations

Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - Transport Information

US DOT

Shipping Name: SODIUM

Hazard Class: 4.3

UN Number: UN1428

Packing Group: I

Canada TDG

Shipping Name: SODIUM

Hazard Class: 4.3

UN Number: UN1428

Packing Group: I

USA RQ: CAS# 7440-23-5: 10 lb final RQ; 4.54 kg final RQ

Section 15 - Regulatory Information



Hazard Symbols: F C

Risk Phrases:

R 14/15 Reacts violently with water liberating extremely flammable gases.

R 34 Causes burns.

Safety Phrases:

S 6A Keep under nitrogen.

S 8 Keep container dry.

S 43D In case of fire, use sodium carbonate or dry sand (never use water).

S 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where

possible).


CAS# 7440-23-5: 2

Canada

CAS# 7440-23-5 is listed on Canada's DSL List

Canadian WHMIS Classifications: B6, E, F

This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations

and the MSDS contains all of the information required by those regulations.

CAS# 7440-23-5 is not listed on Canada's Ingredient Disclosure List.

US Federal

TSCA

CAS# 7440-23-5 is listed on the TSCA

Inventory.

Section 16 - Other Information

MSDS Creation Date: 10/13/1998

Revision #7 Date 7/20/2009

The information above is believed to be accurate and represents the best information currently available

to us. However, we make no warranty of merchantibility or any other warranty, express or implied,

with respect to such information, and we assume no liability resulting from its use. Users should make

their own investigations to determine the suitability of the information for their particular purposes. In no

event shall the company be liable for any claims, losses, or damages of any third party or for lost profits

or any special, indirect, incidental, consequential, or exemplary damages howsoever arising, even if the

company has been advised of the possibility of such damages.

--------------------------------------------------------------------------------

- 1 -


1. Composition/information on ingredients

Product Name: Sodium Naphthionate

Synonyms:

Company Identification: Shanghai IS Chemicals Technology LTD.

Address: 2nd floor,Chemical Building,No.1000 Xuefu Road, Jinshan

District, Shanghai China, Zip, 201512

Telephone Number: 86-21-52685808

Fax Number: 86-21-52685809

2. Identification of the substance

Catalog Number: I14-6805

CAS #: 130-13-2

Purity: 98%

EINECS#

3. Hazards identification

EMERGENCY OVERVIEW Irritating to eyes, respiratory system and skin.

Potential Health Effects Eye:

Causes eye irritation. May cause chemical conjunctivitis.

Skin:

Causes skin irritation.

Ingestion:

May cause gastrointestinal irritation with nausea, vomiting and diarrhea. The toxicological properties of

this substance have not been fully investigated.

Inhalation:

Causes respiratory tract irritation. The toxicological properties of this substance have not been fully

investigated. Can produce delayed pulmonary edema.

Chronic:

Effects may be delayed.

4. First aid measures

Eyes:

Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and

lower eyelids. Get medical aid.

Skin:

Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated

clothing and shoes. Wash clothing before reuse.

Ingestion:

- 2 -

Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If

conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. Wash mouth out with water.

Inhalation:

Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If

breathing is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth resuscitation.

Notes to Physician:

Treat symptomatically and supportively.

5. Fire fighting measures


As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved

or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated

by thermal decomposition or combustion.


Use water spray, dry chemical, carbon dioxide, or chemical foam.

6. Accidental release measures

General Information: Use proper personal protective equipment as indicated in Section 8.

Spills/Leaks:

Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately,

observing precautions in the Protective Equipment section. Avoid generating dusty conditions. Provide

ventilation.

7. Handling and storage

Handling:

Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container

tightly closed. Use with adequate ventilation. Wash clothing before reuse. Avoid breathing dust.

Storage:

Store in a cool, dry place. Store in a tightly closed container.

8. Exposure Controls / PPE


Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety

shower. Use adequate ventilation to keep airborne concentrations low.

Exposure Limits CAS# 130-13-2:

Personal Protective Equipment Eyes:

Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and

face protection regulations in 29 CFR 1910.133 or European Standard EN166.

Skin:

Wear appropriate protective gloves to prevent skin exposure.

Clothing:

Wear appropriate protective clothing to prevent skin exposure.

Respirators:

Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a

- 3 -

NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if

irritation or other symptoms are experienced.

9. Physical and chemical properties

Physical State: Powder.

Color: Light gray to light brown.


pH: Not available.




Freezing/Melting Point: Not available

Autoignition Temperature: Not available.




Decomposition Temperature: Not available

Specific Gravity/Density: Not available

Molecular Formula: C10H8NO3S.Na


10. Stability and reactivity

Chemical Stability:



Dust generation.


Acids, bases, reducing agents, strong oxidizing agents.


Carbon monoxide, carbon dioxide, hydrogen bromide.

Hazardous Polymerization: Has not been reported.

11. Toxicological information

RTECS#:

CAS#：130-13-2 unlisted.

LD50/LC50:

Not available.

Carcinogenicity:

Sodium Naphthionate

Not listed by ACGIH, IARC, or NTP.

12. Ecological information

Not available.

- 4 -

13. Disposal consideration

Dispose of in a manner consistent with federal, state, and local regulations.

14. Transportation information

IATA

Shipping Name: Not available.

Hazard Class: Not available.

UN Number: Not available.

Packing Group: Not available.

IMO




Packing Group: Not available.

RID/ADR




Packing group: Not available.

15. Regulatory information

European/International Regulations European Labeling in Accordance with EC Directives Hazard

Symbols: XI Risk Phrases:

R 36/37/38 Irritating to eyes, respiratory system and skin.

Safety Phrases:

S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

S 37/39 Wear suitable gloves and eye/face protection.

WGK (Water Danger/Protection) CAS# 130-13-2: No information available.

Canada

None of the chemicals in this product are listed on the DSL/NDSL list.

CAS# 130-13-2 is not listed on Canada's Ingredient Disclosure List.

US FEDERAL TSCA CAS# 130-13-2 is not listed on the TSCA inventory.

It is for research and development use only.

16. Other information

The information above is believed to be accurate and represents the best information currently available

to us. However, we make no warranty of merchantability or any other warranty, express or implied, with

respect to such information, and we assume no liability resulting from its use. Users should make their

own investigations to determine the suitability of the information for their particular purposes. In no way

shall the company be liable for any claims, losses, or damages of any third party or for lost profits or any

special, indirect, incidental, consequential or exemplary

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Material Safety Data SheetSodium nitrate MSDS


Product Name: Sodium nitrate


CAS#: 7631-99-4

RTECS: WC5600000

TSCA: TSCA 8(b) inventory: Sodium nitrate

CI#: Not available.

Synonym: Chile saltpeter; soda niter; Sodium saltpeter;Nitric acid, sodium salt; Nitratine

Chemical Name: Sodium Nitrate

Chemical Formula: NaNO3









Composition:


Sodium nitrate 7631-99-4 100

Toxicological Data on Ingredients: Sodium nitrate: ORAL (LD50): Acute: 1267 mg/kg [Rat]. 2680 mg/kg [Rabbit].


Potential Acute Health Effects:Hazardous in case of ingestion. Slightly hazardous in case of skin contact (irritant), of eye contact (irritant), of inhalation.Prolonged exposure may result in skin burns and ulcerations. Over-exposure by inhalation may cause respiratory irritation.

Potential Chronic Health Effects:CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Mutagenic for bacteria and/or yeast. TERATOGENICEFFECTS: Not available. DEVELOPMENTAL TOXICITY: Not available. The substance may be toxic to blood. Repeated orprolonged exposure to the substance can produce target organs damage.


Eye Contact:


p. 2

Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15minutes. Cold water may be used. Get medical attention if irritation occurs.













Fire Hazards in Presence of Various Substances: organic materials, combustible materials

Explosion Hazards in Presence of Various Substances:Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the product inpresence of static discharge: Not available. Slightly explosive in presence of heat.


Special Remarks on Fire Hazards:It may accelerate burning when involved in a fire. Increases the flammability of any combustible material May ignitecombustibles (wood, paper, clothing, etc.). Flames up when heated to 540 deg. C. Mixture with charcoal ignites on heating.Contact with combustible or organic materials may cause fire.

Special Remarks on Explosion Hazards:It will react explosively with hydrocarbons. Interaction of nitrates when heated with amidosulfates(sulfamates) may becomeexplosively violent owing to liberation of dinitrogen oxide and steam. Mixtures of sodium nitrate with powdered aluminum orits oxide were reported to be explosive. Mixtures of sodium nitrate and barium thiocyanate may explode. Mixture with sodiumnitrate and powdered antimony explode. Mixture of sodium nitrate and sodium thiosulfate or sodium phosphinate explode.



Large Spill:Oxidizing material. Stop leak if without risk. Avoid contact with a combustible material (wood, paper, oil, clothing...). Keepsubstance damp using water spray. Do not touch spilled material. Prevent entry into sewers, basements or confined areas;dike if needed. Call for assistance on disposal.

p. 3


Precautions:Keep away from heat. Keep away from sources of ignition. Keep away from combustible material. Do not ingest. Do notbreathe dust. Wear suitable protective clothing. If ingested, seek medical advice immediately and show the container or thelabel. Keep away from incompatibles such as reducing agents, combustible materials, organic materials, acids.

Storage:Keep container tightly closed. Keep container in a cool, well-ventilated area. Separate from acids, alkalies, reducing agentsand combustibles. See NFPA 43A, Code for the Storage of Liquid and Solid Oxidizers.







Physical state and appearance: Solid. (Granular solid. Powdered solid.)


Taste: Bitter. Saline.


Color: White.


Boiling Point: Decomposition temperature: 380°C (716°F)











Solubility:

p. 4

Easily soluble in hot water. Soluble in cold water. Partially soluble in methanol. Very slightly soluble in acetone. Very slightlysoluble in glycerol. Very soluble in liquid Ammonia. Solubility in water: 92.1g/100 ml @ 25 deg. C.; 180 g/100 ml @ 100 deg.C. Solubility in Methanol: 1 g dissolves in 300 ml Methanol 1 gram dissolves in 125 ml Alcohol, 52 ml boiling Alcohol, 3470 mlabsolute Alcohol.





Incompatibility with various substances:Highly reactive with combustible materials, organic materials. Reactive with reducing agents, acids.


Special Remarks on Reactivity:Fibrous organic material is oxidized in contact with sodium nitrate above 160 deg. C and will ignite below 220 C. Woodand similar cellulosic materials are rendered highly combustible by nitrate imgregnation. Reacts with acids to emit toxicfumes of nitrogen dioxide. Also incompatible with boron phosphide, barium rhodanide, cyanides, sodium thiosulfate,hypophosphites such as sodium hypophosphite, sulfur plus charcoal, antimony, chlorides, aluminum and stannous chloride,esters, powdered metals such as zinc or aluminum or aluminum oxide, isothiocyanates, thiocyanates, phosphorus, organicmaterials, combustible materials, acids, pyrosulfites, sulfides, amides, bisulfites, hydrazine, ammonium sulfate, amides,amines, phospham. Sodium nitrate + amines may for nitroasmines which have been proven to be carcinogenic in aminal tests.






Chronic Effects on Humans:MUTAGENIC EFFECTS: Mutagenic for bacteria and/or yeast. May cause damage to the following organs: blood.

Other Toxic Effects on Humans:Hazardous in case of ingestion. Slightly hazardous in case of skin contact (irritant), of inhalation.


Special Remarks on Chronic Effects on Humans:May affect genetic material (mutagenic). May cause adverse reproductive effects based on animal test data. May causecancer based on animal test data.

Special Remarks on other Toxic Effects on Humans:Acute Potential Health Effects: Skin: Causes skin irritation with redness, itching, and pain Eyes: Causes eye irritaton withredness, itching, and pain. Inhalation: Causes respiratory tract and mucous membrane irritation. Symptoms may includecoughing, shortness of breath. Ingestion: May be harmful if swallowed. Clinical signs associated with nitrate poisoning include:Gastroenteritis, abdominal pain, nausea, vomiting, diarrhea, metabolis acidosis, muscular weakness, dizziness, fatigue,headache, mental impairment, incoordination, convulsions, accelerated heart rate, orthostatic hypotension, dyspnea, and insevere cases, methemoglobinemia due to inadequate oxygenation of the blood leading to progressive cyanosis, and coma.Cyanosis is first visible as a bluish discoloration of the mucous membranes and unpigmented areas of the body. Purging anddiuresis can be expected. Rare cases of nitrates being converted into more toxic nitrites


p. 5









DOT Classification: CLASS 5.1: Oxidizing material.

Identification: : Sodium nitrate UNNA: 1498 PG: III



Federal and State Regulations:Connecticut hazardous material survey.: Sodium nitrate Rhode Island RTK hazardous substances: Sodium nitratePennsylvania RTK: Sodium nitrate Massachusetts RTK: Sodium nitrate New Jersey: Sodium nitrate TSCA 8(b) inventory:Sodium nitrate



WHMIS (Canada):CLASS C: Oxidizing material. CLASS D-2B: Material causing other toxic effects (TOXIC).

DSCL (EEC):R8- Contact with combustible material may cause fire. R22- Harmful if swallowed. S17- Keep away from combustible material.S36- Wear suitable protective clothing.

HMIS (U.S.A.):

Health Hazard: 2

Fire Hazard: 0

Reactivity: 0



Health: 2

Flammability: 0

Reactivity: 0

p. 6

Specific hazard:

Protective Equipment:Gloves. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Wear appropriate respiratorwhen ventilation is inadequate. Safety glasses.




Created: 10/10/2005 08:27 PM

Last Updated: 05/21/2013 12:00 PM


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Material Safety Data SheetSodium sulfate anhydrous MSDS


Product Name: Sodium sulfate anhydrous


CAS#: 7757-82-6

RTECS: WE1650000

TSCA: TSCA 8(b) inventory: Sodium sulfate anhydrous

CI#: Not available.

Synonym:

Chemical Name: Sodium Sulfate Anhydrous

Chemical Formula: Na2SO4









Composition:


Sodium sulfate anhydrous 7757-82-6 100

Toxicological Data on Ingredients: Sodium sulfate anhydrous: ORAL (LD50): Acute: 5989 mg/kg [Mouse].


Potential Acute Health Effects:Hazardous in case of eye contact (irritant). Slightly hazardous in case of skin contact (irritant), of ingestion, of inhalation.





p. 2

















Special Remarks on Explosion Hazards: At a temperature of 800 C, sodium sulfate and aluminum will explode.





Precautions:Do not ingest. Do not breathe dust. Avoid contact with eyes. Wear suitable protective clothing. If ingested, seek medical adviceimmediately and show the container or the label. Keep away from incompatibles such as oxidizing agents, metals.



p. 3






Physical state and appearance:Solid. (Crystals solid. Crystalline powder. Granular solid. Powdered solid.)

Odor: Odorless.

Taste: Bitter. Saline.


Color: White.













Solubility:Soluble in cold water, hydrogen iodide, and glycerol.. Insoluble in alcohol.




Conditions of Instability: Excess dust generation, incompatible materials

Incompatibility with various substances: Reactive with oxidizing agents, metals.

p. 4


Special Remarks on Reactivity:Hygroscopic. Sodium sulfate reacts violently with magnesium. Also incompatible with aluminum, potassium, mercury, lead,calcium, silver, barium, ammonium ions, and strontium. Sulfates give precipitates with salts of lead, barium, strontium, andcalcium. Silver and mercury form slightly soluble salts. Alcohol preciptates most sulfates out of solution.

Special Remarks on Corrosivity:The rates of corrosion of iron and steel in water are a function of the specific mineral quality as well as the alkalinity and pHvalues. Sodium sulfate ... is a strong contributor to the rate of corrosion. For example, in water with 400 mg/l of alkalinity (asCaCO3) at pH 7, the corrosion rate will be zero at 200 mg/l of Na2SO4, but when the concentration of sodium sulfate is 400mg/l, the corrosion rate will be about 100 mg per square cm per day.








Special Remarks on Chronic Effects on Humans:May cause adverse reproductive effects (fetotoxicity) based on animal studies. Human human data found May cause cancer(tumorigenic) based on animal studies. No human data found. Placental absorption of sulfate ion has been characterized.Sulfate ion levels at term are somewhat higher in fetal than in maternal blood.

Special Remarks on other Toxic Effects on Humans:Acute Potential Health Effects: Skin: May cause irritation, although it is not known to be an irritant. Eyes: May cause eyeirritation. Ingestion: Saline cathartics (laxitives) are poorly absorbed from the gastrointestinal tract; hence, systemic toxicityis unlikely unless massive amounts have been ingested. Ingestion of large amounts may cause gastrointestinal (digestive)tract irritation with abdominal pain, nausea, vomiting, diarrhea. Low hazard for usual industrial handling. Inhalation: May causerespiratory tract irritation. Low hazard for usual industrial handling.










p. 5





Federal and State Regulations:Pennsylvania RTK: Sodium sulfate anhydrous Massachusetts RTK: Sodium sulfate anhydrous TSCA 8(b) inventory: Sodiumsulfate anhydrous




DSCL (EEC):R36- Irritating to eyes. S36- Wear suitable protective clothing. S46- If swallowed, seek medical advice immediately and showthis container or label.

HMIS (U.S.A.):

Health Hazard: 2

Fire Hazard: 0

Reactivity: 0



Health: 2

Flammability: 0

Reactivity: 0

Specific hazard:





Created: 10/10/2005 08:28 PM

Last Updated: 05/21/2013 12:00 PM


SULFO PARA BASE VINYL SULFONE

Chemical Name2-Amino -5-{ { 2-(Sulfoxy) Ethyl} Sulfonyl } Benzene Sulfonic Acid

Molecular Weight 361

Cas No. #42986-22-1

Appearance Beige Colored Powder

Purity by N.V. 68% (Min)

Purity by HPLC 93.5% (Min)

Hydrolysed 2.0% (Max)

Insolubles <0.2%

NH2

SO2 CH2 CH2 OSO3H

SO3H

ASSOCIATED DYESTUFF PVT. LTD.ISO 9001- ISO 14001 CERTIFIEDDYE - INTERMEDIATES

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Material Safety Data SheetSulfanilic acid MSDS


Product Name: Sulfanilic acid

Catalog Codes: SLS1108

CAS#: 121-57-3

RTECS: WP3895500

TSCA: TSCA 8(b) inventory: Sulfanilic acid

CI#: Not available.

Synonym: 4-Aminobenzenesulfonic acid

Chemical Formula: C6H7NO3S









Composition:


Sulfanilic acid 121-57-3 100

Toxicological Data on Ingredients: Sulfanilic acid: ORAL (LD50): Acute: 12300 mg/kg [Rat].


Potential Acute Health Effects:Very hazardous in case of ingestion. Hazardous in case of skin contact (irritant), of eye contact (irritant), of inhalation.

Potential Chronic Health Effects:Very hazardous in case of ingestion. Hazardous in case of skin contact (irritant), of eye contact (irritant), of inhalation.CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available.DEVELOPMENTAL TOXICITY: Not available. The substance is toxic to blood, the nervous system, liver. Repeated orprolonged exposure to the substance can produce target organs damage.




p. 2

Skin Contact:After contact with skin, wash immediately with plenty of water. Gently and thoroughly wash the contaminated skin with runningwater and non-abrasive soap. Be particularly careful to clean folds, crevices, creases and groin. Cold water may be used.Cover the irritated skin with an emollient. If irritation persists, seek medical attention. Wash contaminated clothing beforereusing.





















Precautions:Keep away from heat. Keep away from sources of ignition. Empty containers pose a fire risk, evaporate the residue under afume hood. Ground all equipment containing material. Do not ingest. Do not breathe dust. Wear suitable protective clothing Incase of insufficient ventilation, wear suitable respiratory equipment If ingested, seek medical advice immediately and show thecontainer or the label. Avoid contact with skin and eyes

p. 3








Physical state and appearance: Solid. (Crystalline solid.)




Color: Colorless.



Melting Point: Decomposes. (288°C or 550.4°F)










Solubility:Partially soluble in cold water. Insoluble in methanol, diethyl ether.


p. 4








Polymerization: No.




Chronic Effects on Humans: The substance is toxic to blood, the nervous system, liver.












Waste Disposal:






p. 5

Federal and State Regulations: TSCA 8(b) inventory: Sulfanilic acid



WHMIS (Canada): CLASS D-2B: Material causing other toxic effects (TOXIC).


HMIS (U.S.A.):

Health Hazard: 2

Fire Hazard: 1

Reactivity: 0



Health: 2

Flammability: 1

Reactivity: 0

Specific hazard:





Created: 10/10/2005 08:29 PM

Last Updated: 05/21/2013 12:00 PM


**** MATERIAL SAFETY DATA SHEET ****

SULPHO TOBIAS ACID（STA）**** SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION ****

MSDS Name: SULPHO TOBIAS ACID (STA)

Catalog Numbers:

Company Identification (Europe): hangzhou dingsheng chemical co。，ltd

For information in : 0571-85284775

For emergencies , call ： 0571-85284775

**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****

+----------------+--------------------------------------+----------+-

----------+-----------+---------------+

| CAS# | Chemical Name | % |

EINECS# |Haz Symbols| Risk Phrases |

|----------------|--------------------------------------|----------|-

----------|-----------|---------------+

| 117-62-4 | SULPHO TOBIAS ACID| |

+----------------+--------------------------------------+----------+-

----------+-----------+---------------+

Hazard Symbols: Risk Phrases:

**** SECTION 3 - HAZARDS IDENTIFICATION ****

EMERGENCY OVERVIEW

Harmful by inhalation, in contact with skin and if swallowed.


Eye:

May cause eye irritation.

Skin:

Harmful if absorbed through the skin.

Ingestion:

Harmful if swallowed. The toxicological properties of this

substance

have not been fully investigated.

Inhalation:

Harmful if inhaled. The toxicological properties of this

substance

have not been fully investigated.

Chronic:

Not available.

**** SECTION 4 - FIRST AID MEASURES ****

Eyes:

Flush eyes with plenty of water for at least 15 minutes,

occasionally lifting the upper and lower eyelids. Get medical

aid.

Skin:

Get medical aid. Flush skin with plenty of water for at least

15

minutes while removing contaminated clothing and shoes.

Ingestion:

Get medical aid. Wash mouth out with water.

Inhalation:

Remove from exposure and move to fresh air immediately. If not

breathing, give artificial respiration. If breathing is

difficult,

give oxygen. Get medical aid.

Notes to Physician:

**** SECTION 5 - FIRE FIGHTING MEASURES ****


As in any fire, wear a self-contained breathing apparatus in

pressure-demand, MSHA/NIOSH (approved or equivalent), and full

protective gear.


In case of fire, use water, dry chemical, chemical foam, or

alcohol-resistant foam.

**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****

General Information: Use proper personal protective equipment as

indicated

in Section 8.

Spills/Leaks:

Vacuum or sweep up material and place into a suitable disposal

container.

**** SECTION 7 - HANDLING and STORAGE ****

Handling:

Avoid breathing dust, vapor, mist, or gas. Avoid contact with

skin

and eyes.

Storage:

Store in a cool, dry place. Store in a tightly closed container.

**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****


Use adequate ventilation to keep airborne concentrations low.


Eyes:

Wear appropriate protective eyeglasses or

chemical

safety goggles as described by OSHA's eye and face

protection regulations in 29 CFR 1910.133 or

European

Standard EN166.

Skin:

Wear appropriate protective gloves and clothing

to

prevent skin exposure.

Clothing:

Wear appropriate protective clothing to prevent

skin

exposure.

Respirators:

Follow the OSHA respirator regulations found in

29

CFR 1910.134 or European Standard EN 149. Always

use

a NIOSH or European Standard EN 149 approved

respirator when necessary.

**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****

Physical State: powder

Color: white


pH: Not available.




Freezing/Melting Point: Not available

Autoignition Temperature: Not available.




Decomposition Temperature:

Solubility in water:

Specific Gravity/Density:

Molecular Formula: C10H9NO6S2Molecular Weight: 303.30

**** SECTION 10 - STABILITY AND REACTIVITY ****

Chemical Stability:



Incompatible materials.


Strong oxidizing agents, strong acids, strong bases.


Nitrogen oxides, carbon monoxide, carbon dioxide.

Hazardous Polymerization: Has not been reported.

**** SECTION 11 - TOXICOLOGICAL INFORMATION ****

RTECS#:

CAS# 117-62-4: ME9950000

LD50/LC50:

CAS# 117-62-4: Oral, mouse: LD50 = >10 gm/kg.

Carcinogenicity:

Salicylic 99%-

Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.

See actual entry in RTECS for complete information.

**** SECTION 12 - ECOLOGICAL INFORMATION ****

**** SECTION 13 - DISPOSAL CONSIDERATIONS ****

Dispose of in a manner consistent with federal, state, and local

regulations.

**** SECTION 14 - TRANSPORT INFORMATION ****

IATA


IMO


RID/ADR


**** SECTION 15 - REGULATORY INFORMATION ****



R 20/21/22 Harmful by inhalation, in contact

with

skin and if swallowed.

Safety Phrases:

S 24/25 Avoid contact with skin and eyes.


CAS# 117-62-4: 1

United Kingdom Occupational Exposure Limits

United Kingdom Maximum Exposure Limits

Canada

CAS# 117-62-4 is listed on Canada's DSL List.

CAS# 117-62-4is not listed on Canada's Ingredient Disclosure

List.

Exposure Limits

US FEDERAL

TSCA

CAS# 117-62-4 is listed on the TSCA inventory.

**** SECTION 16 - ADDITIONAL INFORMATION ****

MSDS Creation Date: 5/31/2009 Revision #0 Date: Original.

The information above is believed to be accurate and represents the

best

information currently available to us. However, we make no warranty

of

merchantability or any other warranty, express or implied, with

respect to

such information, and we assume no liability resulting from its use.

Users

should make their own investigations to determine the suitability

of the

information for their particular purposes. In no way shall the

company be

liable for any claims, losses, or damages of any third party or for

lost

profits or any special, indirect, incidental, consequential or

exemplary

damages, howsoever arising, even if the company has been advised of

the possibility of such damages.-----------------------------------------------------------------------------------

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Material Safety Data SheetSulfuric acid MSDS


Product Name: Sulfuric acid


CAS#: 7664-93-9

RTECS: WS5600000

TSCA: TSCA 8(b) inventory: Sulfuric acid


Synonym: Oil of Vitriol; Sulfuric Acid

Chemical Name: Hydrogen sulfate

Chemical Formula: H2-SO4









Composition:


Sulfuric acid 7664-93-9 95 - 98

Toxicological Data on Ingredients: Sulfuric acid: ORAL (LD50): Acute: 2140 mg/kg [Rat.]. VAPOR (LC50): Acute: 510 mg/m2 hours [Rat]. 320 mg/m 2 hours [Mouse].


Potential Acute Health Effects:Very hazardous in case of skin contact (corrosive, irritant, permeator), of eye contact (irritant, corrosive), of ingestion,of inhalation. Liquid or spray mist may produce tissue damage particularly on mucous membranes of eyes, mouth andrespiratory tract. Skin contact may produce burns. Inhalation of the spray mist may produce severe irritation of respiratorytract, characterized by coughing, choking, or shortness of breath. Severe over-exposure can result in death. Inflammation ofthe eye is characterized by redness, watering, and itching. Skin inflammation is characterized by itching, scaling, reddening,or, occasionally, blistering.

Potential Chronic Health Effects:CARCINOGENIC EFFECTS: Classified 1 (Proven for human.) by IARC, + (Proven.) by OSHA. Classified A2 (Suspected forhuman.) by ACGIH. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available. DEVELOPMENTALTOXICITY: Not available. The substance may be toxic to kidneys, lungs, heart, cardiovascular system, upper respiratory tract,eyes, teeth. Repeated or prolonged exposure to the substance can produce target organs damage. Repeated or prolonged


p. 2

contact with spray mist may produce chronic eye irritation and severe skin irritation. Repeated or prolonged exposure to spraymist may produce respiratory tract irritation leading to frequent attacks of bronchial infection. Repeated exposure to a highlytoxic material may produce general deterioration of health by an accumulation in one or many human organs.














Products of Combustion:Products of combustion are not available since material is non-flammable. However, products of decompostion include fumesof oxides of sulfur. Will react with water or steam to produce toxic and corrosive fumes. Reacts with carbonates to generatecarbon dioxide gas. Reacts with cyanides and sulfides to form poisonous hydrogen cyanide and hydrogen sulfide respectively.

Fire Hazards in Presence of Various Substances: Combustible materials



Special Remarks on Fire Hazards:Metal acetylides (Monocesium and Monorubidium), and carbides ignite with concentrated sulfuric acid. White Phosphorous +boiling Sulfuric acid or its vapor ignites on contact. May ignite other combustible materials. May cause fire when sulfuric acidis mixed with Cyclopentadiene, cyclopentanone oxime, nitroaryl amines, hexalithium disilicide, phorphorous (III) oxide, andoxidizing agents such as chlorates, halogens, permanganates.

p. 3

Special Remarks on Explosion Hazards:M i x t u r e s o f s u l f u r i c a c i d a n d a n y o f t h e f o l l o w i n g c a n e x p l o d e : p - n i t r o t o l u e n e , p e n t a s il v e r trihydroxydiaminophosphate, perchlorates, alcohols with strong hydrogen peroxide, ammonium tetraperoxychromate,mercuric nitrite, potassium chlorate, potassium permanganate with potassium chloride, carbides, nitro compounds, nitrates,carbides, phosphorous, iodides, picratres, fulminats, dienes, alcohols (when heated) Nitramide decomposes explosivelyon contact with concentrated sulfuric acid. 1,3,5-Trinitrosohexahydro-1,3,5-triazine + sulfuric acid causes explosivedecompositon.



Large Spill:Corrosive liquid. Poisonous liquid. Stop leak if without risk. Absorb with DRY earth, sand or other non-combustible material.Do not get water inside container. Do not touch spilled material. Use water spray curtain to divert vapor drift. Use water sprayto reduce vapors. Prevent entry into sewers, basements or confined areas; dike if needed. Call for assistance on disposal.Neutralize the residue with a dilute solution of sodium carbonate. Be careful that the product is not present at a concentrationlevel above TLV. Check TLV on the MSDS and with local authorities.


Precautions:Keep locked up.. Keep container dry. Do not ingest. Do not breathe gas/fumes/ vapor/spray. Never add water to this product.In case of insufficient ventilation, wear suitable respiratory equipment. If ingested, seek medical advice immediately and showthe container or the label. Avoid contact with skin and eyes. Keep away from incompatibles such as oxidizing agents, reducingagents, combustible materials, organic materials, metals, acids, alkalis, moisture. May corrode metallic surfaces. Store in ametallic or coated fiberboard drum using a strong polyethylene inner package.

Storage:Hygroscopic. Reacts. violently with water. Keep container tightly closed. Keep container in a cool, well-ventilated area. Do notstore above 23°C (73.4°F).





Exposure Limits:TWA: 1 STEL: 3 (mg/m3) [Australia] Inhalation TWA: 1 (mg/m3) from OSHA (PEL) [United States] Inhalation TWA: 1 STEL: 3(mg/m3) from ACGIH (TLV) [United States] [1999] Inhalation TWA: 1 (mg/m3) from NIOSH [United States] Inhalation TWA: 1(mg/m3) [United Kingdom (UK)]Consult local authorities for acceptable exposure limits.


p. 4

Physical state and appearance: Liquid. (Thick oily liquid.)

Odor: Odorless, but has a choking odor when hot.

Taste: Marked acid taste. (Strong.)


Color: Colorless.

pH (1% soln/water): Acidic.

Boiling Point:270°C (518°F) - 340 deg. C Decomposes at 340 deg. C

Melting Point: -35°C (-31°F) to 10.36 deg. C (93% to 100% purity)










Solubility:Easily soluble in cold water. Sulfuric is soluble in water with liberation of much heat. Soluble in ethyl alcohol.




Conditions of Instability:Conditions to Avoid: Incompatible materials, excess heat, combustible material materials, organic materials, exposure to moistair or water, oxidizers, amines, bases. Always add the acid to water, never the reverse.

Incompatibility with various substances:Reactive with oxidizing agents, reducing agents, combustible materials, organic materials, metals, acids, alkalis, moisture.

Corrosivity:Extremely corrosive in presence of aluminum, of copper, of stainless steel(316). Highly corrosive in presence of stainlesssteel(304). Non-corrosive in presence of glass.

Special Remarks on Reactivity:Hygroscopic. Strong oxidizer. Reacts violently with water and alcohol especially when water is added to the product.Incompatible (can react explosively or dangerously) with the following: ACETIC ACID, ACRYLIC ACID, AMMONIUMHYDROXIDE, CRESOL, CUMENE, DICHLOROETHYL ETHER, ETHYLENE CYANOHYDRIN, ETHYLENEIMINE, NITRICACID, 2-NITROPROPANE, PROPYLENE OXIDE, SULFOLANE, VINYLIDENE CHLORIDE, DIETHYLENE GLYCOLMONOMETHYL ETHER, ETHYL ACETATE, ETHYLENE CYANOHYDRIN, ETHYLENE GLYCOL MONOETHYL ETHERACETATE, GLYOXAL, METHYL ETHYL KETONE, dehydrating agents, organic materials, moisture (water), Acetic anhydride,Acetone, cyanohydrin, Acetone+nitric acid, Acetone + potassium dichromate, Acetonitrile, Acrolein, Acrylonitrile, Acrylonitrile+water, Alcohols + hydrogen peroxide, ally compounds such as Allyl alcohol, and Allyl Chloride, 2-Aminoethanol, Ammoniumhydroxide, Ammonium triperchromate, Aniline, Bromate + metals, Bromine pentafluoride, n-Butyraldehyde, Carbides, Cesiumacetylene carbide, Chlorates, Cyclopentanone oxime, chlorinates, Chlorates + metals, Chlorine trifluoride, Chlorosulfonicacid, 2-cyano-4-nitrobenzenediazonium hydrogen sulfate, Cuprous nitride, p-chloronitrobenzene, 1,5-Dinitronaphthlene +

p. 5

sulfur, Diisobutylene, p-dimethylaminobenzaldehyde, 1,3-Diazidobenzene, Dimethylbenzylcarbinol + hydrogen peroxide,Epichlorohydrin, Ethyl alcohol + hydrogen peroxide, Ethylene diamine, Ethylene glycol and other glycols, , Ethylenimine,Fulminates, hydrogen peroxide, Hydrochloric acid, Hydrofluoric acid, Iodine heptafluoride, Indane + nitric acid, Iron, Isoprene,Lithium silicide, Mercuric nitride, Mesityl oxide, Mercury nitride, Metals (powdered), Nitromethane, Nitric acid + glycerides,p-Nitrotoluene, Pentasilver trihydroxydiaminophosphate, Perchlorates, Perchloric acid, Permanganates + benzene, 1-Phenyl-2-methylpropyl alcohol + hydrogen peroxide, Phosphorus, Phosphorus isocyanate, Picrates, Potassium tert-butoxide,Potassium chlorate, Potassium Permanganate and other permanganates, halogens, amines, Potassium Permanganate +Potassium chloride, Potassium Permanganate + water, Propiolactone (beta)-, Pyridine, Rubidium aceteylene carbide, Silverpermanganate, Sodium, Sodium carbonate, sodium hydroxide, Steel, styrene monomer, toluene + nitric acid, Vinyl acetate,Thalium (I) azidodithiocarbonate, Zinc chlorate, Zinc Iodide, azides, carbonates, cyanides, sulfides, sulfites, alkali hydrides,carboxylic acid anhydrides, nitriles, olefinic organics, aqueous acids, cyclopentadiene, cyano-alcohols, metal acetylides,Hydrogen gas is generated by the action of the acid on most metals (i.e. lead, copper, tin, zinc, aluminum, etc.). Concentratedsulfuric acid oxidizes, dehydrates, or sulfonates most organic compounds.

Special Remarks on Corrosivity:Non-corrosive to lead and mild steel, but dillute acid attacks most metals. Attacks many metals releasing hydrogen. Minorcorrosive effect on bronze. No corrosion data on brass or zinc.




Toxicity to Animals:WARNING: THE LC50 VALUES HEREUNDER ARE ESTIMATED ON THE BASIS OF A 4-HOUR EXPOSURE. Acute oraltoxicity (LD50): 2140 mg/kg [Rat.]. Acute toxicity of the vapor (LC50): 320 mg/m3 2 hours [Mouse].

Chronic Effects on Humans:CARCINOGENIC EFFECTS: Classified 1 (Proven for human.) by IARC, + (Proven.) by OSHA. Classified A2 (Suspectedfor human.) by ACGIH. May cause damage to the following organs: kidneys, lungs, heart, cardiovascular system, upperrespiratory tract, eyes, teeth.



Special Remarks on Chronic Effects on Humans:Mutagenicity: Cytogenetic Analysis: Hamster, ovary = 4mmol/L Reproductive effects: May cause adverse reproductive effectsbased on animal data. Developmental abnormalities (musculoskeletal) in rabbits at a dose of 20 mg/m3 for 7 hrs.(RTECS)Teratogenecity: neither embryotoxic, fetoxic, nor teratogenetic in mice or rabbits at inhaled doses producing some maternaltoxicity

Special Remarks on other Toxic Effects on Humans:Acute Potential Health Effects: Skin: Causes severe skin irritation and burns. Continued contact can cause tissue necrosis.Eye: Causes severe eye irritation and burns. May cause irreversible eye injury. Ingestion: Harmful if swallowed. May causepermanent damage to the digestive tract. Causes gastrointestial tract burns. May cause perforation of the stomach, GIbleeding, edema of the glottis, necrosis and scarring, and sudden circulatory collapse(similar to acute inhalation). It mayalso cause systemic toxicity with acidosis. Inhalation: May cause severe irritation of the respiratory tract and mucousmembranes with sore throat, coughing, shortness of breath, and delayed lung edema. Causes chemical burns to the repiratorytract. Inhalation may be fatal as a result of spasm, inflammation, edema of the larynx and bronchi, chemical pneumonitis,and pulmonary edema. Cause corrosive action on mucous membranes. May affect cardiovascular system (hypotension,depressed cardiac output, bradycardia). Circulatory collapse with clammy skin, weak and rapid pulse, shallow respiration, andscanty urine may follow. Circulatory shock is often the immediate cause of death. May also affect teeth(changes in teeth andsupporting structures - erosion, discoloration). Chronic Potential Health Effects: Inhalation: Prolonged or repeated inhalationmay affect behavior (muscle contraction or spasticity), urinary system (kidney damage), and cardiovascular system, heart(ischemic heart leisons), and respiratory system/lungs(pulmonary edema, lung damage), teeth (dental discoloration, erosion).Skin: Prolonged or repeated skin contact may cause dermatitis, an allergic skin reaction.

p. 6


Ecotoxicity: Ecotoxicity in water (LC50): 49 mg/l 48 hours [bluegill/sunfish].






Waste Disposal:Sulfuric acid may be placed in sealed container or absorbed in vermiculite, dry sand, earth, or a similar material. It may alsobe diluted and neutralized. Be sure to consult with local or regional authorities (waste regulators) prior to any disposal. Wastemust be disposed of in accordance with federal, state and local environmental control regulations.



Identification: : Sulfuric acid UNNA: 1830 PG: II



Federal and State Regulations:Illinois toxic substances disclosure to employee act: Sulfuric acid New York release reporting list: Sulfuric acid RhodeIsland RTK hazardous substances: Sulfuric acid Pennsylvania RTK: Sulfuric acid Minnesota: Sulfuric acid MassachusettsRTK: Sulfuric acid New Jersey: Sulfuric acid California Director's List of Hazardous Substances (8 CCR 339): Sulfuric acidTennessee RTK: Sulfuric acid TSCA 8(b) inventory: Sulfuric acid SARA 302/304/311/312 extremely hazardous substances:Sulfuric acid SARA 313 toxic chemical notification and release reporting: Sulfuric acid CERCLA: Hazardous substances.:Sulfuric acid: 1000 lbs. (453.6 kg)



WHMIS (Canada):CLASS D-1A: Material causing immediate and serious toxic effects (VERY TOXIC). CLASS E: Corrosive liquid.

DSCL (EEC):R35- Causes severe burns. S2- Keep out of the reach of children. S26- In case of contact with eyes, rinse immediately withplenty of water and seek medical advice. S30- Never add water to this product. S45- In case of accident or if you feel unwell,seek medical advice immediately (show the label where possible).

HMIS (U.S.A.):

Health Hazard: 3

Fire Hazard: 0

Reactivity: 2

p. 7



Health: 3

Flammability: 0

Reactivity: 2

Specific hazard:



References:-Material safety data sheet emitted by: la Commission de la Santé et de la Sécurité du Travail du Québec. -The Sigma-AldrichLibrary of Chemical Safety Data, Edition II. -Hawley, G.G.. The Condensed Chemical Dictionary, 11e ed., New York N.Y., VanNostrand Reinold, 1987.


Created: 10/09/2005 11:58 PM

Last Updated: 05/21/2013 12:00 PM


Chemical Name : Trinitrobenzoic acid

Synonyms: TNBA, 2,4,6 Trinitrobenzoic acid, Trinitrobenzoic acid, wetted with not less than 30% water, 1-Carboxy-2,4,6-trinitrobenzene, sym-Trinitrobenzoic acid

Formula : C7H3N3O8

Toxic, Explosive

1. CHEMICAL IDENTITY

Chemical Classification: Trade Name :

CAS No: 129-66-8 UN No: 0215 / 1355Regulated Identification Shipping Name :Codes / Label : Hazardous Waste ID No :

Hazchem Code :Trinitrobenzoic acidClass 1.1D / 4.1, Toxic, Explosive

161W

HAZARDOUS INGREDIENTS C.A.S. No. HAZARDOUS INGREDIENTS C.A.S. No.12

34

Trinitrobenzoic acid 129-66-8

2. PHYSICAL / CHEMICAL DATASolid Crystals (dry / wet)

228.7

Very soluble

1.785 g/cm3

Soluble in alcohol, ether, methanol & slightly soluble in benzene.

Boiling Pt. °C:

Physical State:

Vapour Pressure @ 35°C mmHg:

Appearance:

Odour:

Vapour Density(Air =1):

Solubility inwater at 30°C g/100ml:

Others:

Specific Gravity (Water =1 ): pH :

Melting Pt °C:

3. FIRE / EXPLOSION HAZARD DATAYesFlammability :

TDG Flammability:LEL:UEL:

Flash Point °C in OC:Flash Point °C in CC:

Autoignition Temperature °C :Explosion sensitivity to impact: ExplodesExplosion sensitivity to static Electricity: ExplodesHazardous Combustion Products : Emits toxic fumes of NOx.Hazardous Polymerization : Will not occur.

YesYesNo

YesNoNo

NoCombustible Liquid:Flammable Material:Pyrophoric Material:

Explosive Material:Oxidiser :Organic Peroxide :

Corrosive MaterialOthers:

MATERIAL SAFETY DATA SHEETSTrinitrobenzoic acid659

Stable.If mixed with reducing agents, including hydrides, sulfides and nitrides, they may begin a vigorous reaction that culminates in a detonation.Extremely explosive.

Chemical Stability Incompatibility with other materialReactivity

4. REACTIVITY DATA::

:Page 1 of 3Trinitrobenzoic acid

Reacts with heavy metals to form heat or impact-sensitive explosive salts.

Hazardous Reaction Products5. HEALTH HAZARD DATA

Skin & Eyes.

Inhalation & ingestion: May be toxic if inhaled, igestioned or on contact.. Skin: Can be absorbed through the skin. May cause burns. Eyes: May cause burns

Move patient to fresh air. Monitor for respiratory distress. Administer oxygen and assist ventilation as required. Treat bronchospasm with beta2 agonist and corticosteroid aerosols.

Routes of entry:Effects of Exposure / Symptoms:

Emergency Treatment :

1 3

LD50 (oral-rat) mg/kg:

Permissible Exposure Limit:

TLV (ACGIH) :

STEL:Odour Threshold:

Health Flammability Reactivity SpecialNFPA HazardSignals

Inhalation:

Remove and isolate contaminated clothing and shoes. Flush with running water for at least 20 minutes.

Skin:

Irrigate exposed eyes with copious amounts of tepid water for at least 15 minutes. If irritation, pain, swelling, lacrimation, or photophobia persist, the patient should be seen in a health care facility.

Eyes:

Activated charcoal: administer charcoal as a slurry (240 ml water/30 g charcoal). Usual dose: 25 to 100 g in adults/adolescents.

Ingestion:

LC50 (rat) mg/kg:

6. PREVENTIVE MEASURESAvoid contact with solid or dust / vapours. Provide complete protective equipments such as thick protective overclothing, face shield I safety goggles, safety Provide complete protective equipments such as thick protective overclothing, face shield I safety goggles, safety All chemicals should be considered hazardous. Avoid direct physical contact. Use appropriate, approved safety equipment. Untrained individuals should not handle this chemical or its container. Handling should occur in a chemical fume hood.

Personal ProtectiveEquipment

Handling

:

:

Precautions :Keep in cool, dry place. Protect from heat, light and open flames.Storage :

First Aid Measures:EXPOSURE:

7. EMERGENCY / FIRST AID MEASURES

Water, CO2, dry chemical powder.Keep the containers cool by spraying water if exposed to heat or flame.

Fire Extinguishing MediaSpecial Procedure

Unusual Hazards

FIRE:::

:

Move patient to fresh air. Monitor for respiratory distress. Administer oxygen and assist ventilation as required. Treat bronchospasm with beta2 agonist and corticosteroid aerosols.

Inhalation:

Remove and isolate contaminated clothing and shoes. Flush with running water for at least 20 minutes.

Skin:

:

Page 2 of 3Trinitrobenzoic acid

Sweep and collect without making dust. Wash the place with soap and water.Seal all the waste in vapour tight plastic bags for eventual disposal

Antidotes / Dosages:

Steps To Be Taken

Waste Disposal Method:

SPILLS :

Irrigate exposed eyes with copious amounts of tepid water for at least 15 minutes. If irritation, pain, swelling, lacrimation, or photophobia persist, the patient should be seen in a health care facility.

Eyes:

Activated charcoal: administer charcoal as a slurry (240 ml water/30 g charcoal). Usual dose: 25 to 100 g in adults/adolescents.

Ingestion:

8. ADDITIONAL INFORMATION / REFERENCESFlammble and explosive. A hazard in preparations. Wet Trinitrobenzoic acid contains at least 10% water.9. MANUFACTURERS / SUPPLIERS DATA

Information contained in this material data sheet is believed to be reliable but no representation, guarantee or warranties of any kind are made as to its accuracy, suitability for a particular application or results to be obtained from them. It is up to the manufacturer/ seller to ensure that the information contained in the material safety data sheet is relevant to the product manufactured / handled or sold by him as the case may be. The Government makes no warranties expressed or implied in the respect of the adequacy of this document for any particular purpose.

NAME OF FIRM :MAILING ADDRESS :TELEPHONE / TELEX NOS :TELEGRAPHIC ADDRESS :

Contact personin Emergency :Local Bodies involved :Standard Packing :Trem Card Details / Ref :

10. DISCLAIMER

End of documentTotal No. of Pages: 3

:

OTHERS :

Page 3 of 3Trinitrobenzoic acid

Enclosure: 5

Sr. No.

Raw Material Physical Form

Container Type

M.O.C. Maximum Storage at a time

(MT) 1. MPD (Meta phenelyne

diamine) Solid Bag HDPE 12

2. Sodium Cyanate Solid Bag HDPE 8 3. Sodium Bi Sulphite Solid Bag HDPE 50 4. Sodium Nitrite Solid Bag HDPE 100 5. Sodium Bi Carbonate Solid Bag HDPE 90 6. PAPSA (4- amino phenol-2-

sulphonic acid) Solid Bag HDPE 20

7. Sodium Metal Solid Bag HDPE 2 8. ANA (Alpha Naphthyl

Amine) Solid Bag HDPE 25

9. Soda Ash/ Sodium Carbonate

Solid Bag HDPE 150

10. Para Nitro Aniline(PNA) Solid Bag HDPE 16 11. Acetanilide Solid Bag HDPE 10 12. PNCBOSA (2- Chloro 5-

Nitro Benzene Sulfonic Acid)

Solid Bag HDPE 15

13. Vinyl Sulphone(V.S) Solid Bag HDPE 110 14. Potassium Chloride Solid Bag HDPE 10 15. Acetyl Ortho Ansidine Solid Bag HDPE 15 16. B-Naphthol Solid Bag HDPE 15 17. Sodium Sulphate Solid Bag HDPE 60 18. Cyanuric Chloride Solid Bag HDPE 60 19. Sulpho Para Vinyl

Sulphone Solid Bag HDPE 8

20. J-Acid Solid Bag HDPE 10 21. MPDSA (Meta Phenylene

Diamine 4 Sulfonic Acid) Solid Bag HDPE 20

22. Reactive Black B Solid Bag HDPE 10 23. Salt Solid Bag HDPE 52 24. H-Acid Solid Bag HDPE 85

Chemical Name and Physical form of Raw Material with its Storage Capacity

Sr. No.


Container Type


(MT) 25. Meta Base Vinyl

Sulphone Solid Bag HDPE 6

26. Sulpho Tobias Acid Solid Bag HDPE 30 27. Sulphanilic Acid Solid Bag HDPE 20 28. K-Acid Solid Bag HDPE 20 29. Meta Uriedo Aniline Solid Bag HDPE 10 30. NMJ Acid Solid Bag HDPE 10 31. Sulphamic Acid Solid Bag HDPE 15 32. Copper Sulphate Solid Bag HDPE 15 33. Sodium Acetate Solid Bad HDPE 75 34. Sulpho para carboxy

pyrazole Solid Bag HDPE 20


Solid Bag HDPE 12

36. CPC Blue (Copper Phthalo Cyanine blue)

Solid Bag HDPE 20

37. Salicylic Acid Solid Bag HDPE 20 38. Basic Chrome Sulphate Solid Bag HDPE 25 39. Resorcinol Solid Bag HDPE 12 40. DASA (Diamino

Sulphanilide) Solid Bag HDPE 12

41. F.C. Acid Solid Bag HDPE 5 42. Gamma Acid Solid Bag HDPE 10 43. Rhoduline Acid Solid Bag HDPE 5 44. C-Acid Solid Bag HDPE 8 45. Phenyl J Acid Solid Bag HDPE 10 46. Blue B Base Solid Bag HDPE 5 47. Quinizarine Solid Bag HDPE 45 48. Fast Garnate GBC Base Solid Bag HDPE 5 49. Phthalic Anhydride Solid Bag HDPE 20 50. P-Toludine Solid Bag HDPE 10 51. Schaeffer’s Acid Solid Bag HDPE 15 52. Sodium Naphthionate Solid Bag HDPE 21 53. DMAS (Dimethyl acetyl

saccinate) Solid Bag HDPE 15

Sr. No.


Container Type


(MT) 54. PCONA (4-Chloro-2-

Nitroaniline) Solid Bag HDPE 10

55. Hydrochloric Acid Liquid Tank MS 80 56. Aniline Liquid Drum MS/HDPE 5 57. Formaldehyde Liquid Drum MS/HDPE 5 58. Sulphuric Acid Liquid Tank MS 60 59. Benzene Liquid Drum/

Carboy HDPE 5

60. Di Ethyl Oxalate Liquid Drum HDPE 15 61. Ethyl Acetate Liquid Drum HDPE 10 62. ODCB (Ortho Di Chloro

Benzene) Liquid Drum/

Tank HDPE/

MS 5

63. Naphthenic Acid Liquid Drum HDPE 25 64. Chloro Sulphonic Acid Liquid Drum HDPE 110 65. Sodium Hydroxide Soln. Liquid Carboy HDPE 15 66. Oleum Acid Liquid Drum HDPE 70 67. Acetic Acid Liquid Drum/

Tank HDPE/

MS 5

68. Ammonium Hydroxide Liquid Drum HDPE 12 69. Acetic Anhydride Liquid Drum HDPE 16 70. Octanol Liquid Drum HDPE 1 71. Hydrogen Peroxide Liquid Drum HDPE 15 72. 2-Pyridine Liquid Carboy/

Drum HDPE 5

73. Phosphorus Tri Chloride Liquid Drum HDPE 5 74. PMP

(Polymethylpentene) Liquid Drum/

Carboy HDPE 5

75. Meta Toludine Liquid Drum HDPE 5 76. D.E.A (Di Ethyl Amine) Liquid Drum HDPE 10 77. Pentothenic Acid Liquid Drum HDPE 5 78. TNBA (Tri N-Butyl

Amine) Liquid Drum/

Carboy HDPE 3

79. Methanol Liquid Drum/ Tank

HDPE/ MS

5

https://www.google.co.in/url?sa=t&rct=j&q=&esrc=s&source=web&cd=4&cad=rja&uact=8&ved=0ahUKEwj87r2GvojVAhVEv48KHZ44CIsQFggtMAM&url=https%3A%2F%2Fpubchem.ncbi.nlm.nih.gov%2Fcompound%2F4-chloro-2-nitroaniline&usg=AFQjCNHR8aOANtTsSYBQcw4a9mO3CetOng

https://www.google.co.in/url?sa=t&rct=j&q=&esrc=s&source=web&cd=4&cad=rja&uact=8&ved=0ahUKEwj87r2GvojVAhVEv48KHZ44CIsQFggtMAM&url=https%3A%2F%2Fpubchem.ncbi.nlm.nih.gov%2Fcompound%2F4-chloro-2-nitroaniline&usg=AFQjCNHR8aOANtTsSYBQcw4a9mO3CetOng

https://www.google.co.in/url?sa=t&rct=j&q=&esrc=s&source=web&cd=2&ved=0ahUKEwimoOumqIjVAhVEtY8KHXkZAYMQFggrMAE&url=https%3A%2F%2Fen.wikipedia.org%2Fwiki%2FPolymethylpentene&usg=AFQjCNF1Q4MkBl24x0DLyh7kfAl-qRi4LA&cad=rja

Sr. No.


Container Type


(MT) 80. N-Isopropylamine Liquid Drum/

Carboy HDPE 12

81. Butanol Liquid Drum HDPE 5 82. Quinaldine Colorless

oil Carboy HDPE 45

83. Ethylene Oxide Gas Cylinder/ Tank

MS 10

84. Ammonia Gas Cylinder MS 80

Enclosure: 6

Physical and Chemical Properties of the Raw Material

Chemical Formula

State M.W. ˚C ˚C ppm or mg/Nm3

ppm or mg/Nm3

1 B‐Naphthol C10H7OH Solid 144.17 285.5 153 NA NA 1960 1.22 4.98 NA Slightly Soluble in cold Water2 Oleum H2SO4+20% SO3 Liquid 178.14 45 NA NA NA 2140 1.92 3.4 NA Easily Soluble in Cold Water3 Sulphuric Acid H2SO4 Liquid 98.08 270‐340 NA NA 1 2140 1.84 3.4 NA Easily Soluble in Cold Water4 Sodium Sulphate Na2SO4 Solid 142.06 1100 NA NA NA 5989 2.671 NA NA Soluble in Cold Water5 Ammonia NH3 Liquid 17 ‐33.4 NA 15 NA 2000 0.59 21.1 20 0.8486 Sodium Bicarbonate NaHCO3 Solid 84.01 NA NA NA NA 3360 2.159 NA NA Soluble in Cold Water7 Benzene C6H6 Liquid 78.11 80.1 ‐11.1 NA 1.6 930 0.8787 2.8 4.68 Very Slightly Soluble In cold Water8 Diethyl Oxalate C6H10O4 Liquid 146.15 185.7 75 NA NA 2000 1.076 5.04 NA NA9 Ethyl Acetate C4H8O2 Liquid 88.11 77 ‐4.4 2.2 400 5620 0.902 3.04 3.9 Soluble

10 Sodium Metal Na Solid 22.99 883 NA NA NA NA 0.9684 NA NA Reacts violently with water12 Caustic Lye NaOH Liquid NA 140 NA NA 2 NA 1.53 0.62 NA Easily Soluble in Cold Water13 Vinyl Sulphone C4H6O2S Solid 118.15 234.5 102.8 NA NA 22 1.177 NA NA Soluble in Cold Water14 KCl KCl Solid 74.55 1420 Na NA NA 1500 1.987 NA NA Soluble15 Sodium Nitrite NaNO2 Solid 69 320 NA NA NA 180 2.2 NA NA solule16 Sodium Bisulphate NaHSO4 Solid 120.6 NA NA NA NA 2800 2.435 NA NA Soluble17 HCl HCl Liquid 36.46 52.77 NA 5 7 NA 1.16 1 NA Soluble18 Aniline C6H5NH2 Liquid 93.13 184.1 70 NA 7.6 250 1.0216 3.22 2.4 Soluble19 Formaldehyde HCHO Liquid 30.02 98 50 NA 0.3 100 1.08 1.03 100 Soluble21 Acetic Acid C2H4O2 Liquid 60.05 118.1 39 NA NA 3310 1.049 2.07 0.48 Soluble22 Cyanuric Chloride C3Cl3N3 Solid 184.41 194 NA NA NA 350 1.32 6.3 NA Insoluble in Cold Water23 K‐Acid C10H9NO7S2 Solid 320025 Ammonium Hydroxide NA Liquid 35.05 NA NA NA NA 350

898NA 5‐50 As AmEasily Soluble in Cold Water

27 Sodium Hydroxide NaOH Liquid NA 140 NA NA 2 NA 1.53 0.62 NA Easily Soluble in Cold Water28 Acetic Anhydride (CH3CO)2 Liquid 102.09 139.9 49 NA NA 1780 1.08 3.52 0.1 NA31 MPDSA C6H8N2O3S Solid 188 NA NA NA NA NA NA NA NA Soluble32 Sodium Carbonate Na2CO3 Solid 106 NA NA NA NA 4090 2.532 NA NA Soluble33 SPCP C10H8N2O4S Solid 284 NA NA NA NA NA NA NA NA Soluble34 SPVS C8 H11 NO9 S3 Solid 361 NA NA NA NA NA NA NA NA

No. Sulphanilic Acid C6H7NO3S Solid NA NA NA NA NA 12300 1.485 NA NA Partially Soluble in Cold Water37 H‐Acid C10H8NNaO7S2 Solid 341.29 NA NA NA NA 300 NA NA NA NA38 J‐Acid C10H9NO4S Solid 239.25 NA NA NA NA NA NA NA NA slightly soluble39 2‐Pyridine C6H5NO Liquid 107.11 181 54 NA NA NA NA NA NA Soluble

Solubility in WaterF.P. TLVPhysical and Chemical Composition B.P. Odour Threshold

V.D. at (Air=1)

No. Product LEL LD50 mg/Kg

Sp.Gr. At (Water=1)

40 Reactive Black B 26H25N5O19S6.4NSOlid 991.82 NA NA NA NA NA NA NA NA Miscible42 Copper Phthalo

Cyanine BlueC32H16CuN8 Solid 576.05 NA NA NA NA 1.5 NA NA NA Insoluble in Cold Water

43 Chloro Sulphonic Acid ClSO3H Liquid 116.52 158 NA NA NA NA1.76 4.02

NA Soluble

44 Phosphorous TriChloride

PCl3 Liquid 137.35 76 NA NA 0.5 18 1.574 4.75 NA Soluble

50 Salicylic Acid C7H6O3 Solid 138.12 211 157 NA NA 891 1.443 4.8 NA Slightly Soluble in Hot Water51 Chrome Sulphate Cr2(SO4)3.xH2O Solid 392.17 NA Na NA NA NA 3.012 NA NA Soluble52 Beta Naphthol C10H8O Solid 144.7 285.5 153 NA NA 1960 1.22 4.98 NA Very Slightly Soluble In cold Water54 Resourcinol C6H6O2 Solid 110.11 281 127.2 90 NA 301 1.272 3.8 NA Easily Soluble in Cold Water57 Sodium acetate CH3COONa Solid 82.03 NA NA NA NA 3530 1.528 NA NA Easily Soluble in Cold Water59 Alpha Naphthyl Amine C12H13N Liquid 171.24 139.5 112 NA NA NA

1.04 5.9NA Insoluble in Cold Water

61 Gamma Acid C10H9NO4S 239 NA NA NA NA NA NA NA NA NA Slightly Soluble63 HMP C9H10O4 Solid 182 NA NA NA NA NA NA NA NA NA64 EDTA C10H16N2O8 Solid 292.28 NA NA NA NA 30 0.72 NA NA Very Slightly Soluble In cold Water65 Meta Toludine C7H9N 107.16 203.3 86.111 2 NA 450 0.99 3.7 NA Very Slightly Soluble In cold Water67 TNBA C7H3N3O8 Solid 257 NA NA NA NA NA 1.785 NA NA Soluble68 Blue B Base C13H14N2O Solid 214 NA NA NA NA NA NA NA NA NA69 Sodium Nitrate NaNO2 Solid 84.99 380 NA NA NA 1267 2.26 NA NA Easily Soluble in Hot Water71 Methanol CH3OH Liquid 32.04 64.5 12 NA NA 15800 0.7915 1.11 100 Easily Soluble74 Sodium Bi Chloride NaHCO3 Solid 84.01 NA NA NA NA 3360 2.159 NA NA Soluble in Cold Water76 Octanol C8H17OH Liquid 130.23 194.5 81.1 NA NA 1790 0.827 4.5 0.1 Insoluble in Cold Water77 Copper Sulphate CuSO4 Liquid 159.61 100 NA 1 NA 300 1.053 0.62 NA Easily Soluble in Cold Water79 ODCB C6H4Cl2 Liquid 147 180 66 NA NA 500 1.309 5.07 2 Very Slightly Soluble In cold Water80 Phthalic Anhydried C8H4O3 Solid 148.13 295 151.7 6.1 NA 1530 1.53 6.6 NA Very Slightly Soluble In cold Water81 Quinaldine C10H9N Liquid 143.19 248.5 79.4 NA NA 1230 1.058 NA NA Partially Soluble in Cold Water82 Butanol CH3(CH2)2CH2OH Liquid 74.12 117.7 28.9 NA NA 790 0.81 2.55 1.2 Soluble83 P‐Toluediline CH3C6H4OH Solid 107.15 200 87 NA NA 336 NA 3.9 NA Soluble84 DMAS C8H12O5 Liquid 188.18 213.8 138 NA NA NA NA 1.3146 NA86 Sodium Naphthonate C10H8NO3SNa Solid 245.01 NA NA NA NA NA NA NA NA NA

Enclosure: 7 Details of Hazardous Chemicals

The Raw Materials, which are termed as Hazardous Chemicals as per the "Manufacturing, Storage and Import of Hazardous Chemicals Rules, 1989", are as listed in below:

Hazardous Chemicals

Reference The Manufacturer, storage & Import of Hazardous chemical Rules 1989

Maximum quantity that can be stored at a time (MT)

Threshold Quantity in MT

Chloro Sulfonic Acid

Sr.No. 136(Part II,Sch 1 of MSCIR, 1989)

110 Not Listed

Hydrochloric Acid Sr.No. 313(Part II,Sch 1 of MSCIR, 1989)

80 Not Listed

Sulphuric Acid Sr.No. 591(Part II,Sch 1 of MSCIR, 1989)

60 Not Listed

Ammonia Sr.No. 31(Part II,Sch 1 of MSCIR, 1989)

80 50

Acetic Anhydride Sr.No. 3(Part II,Sch 1 of MSCIR, 1989)

16 Not Listed

Ethylene Oxide Sr.No. 269(Part II,Sch 1 of MSCIR, 1989)

10 5

Oleum Sr.No. 444(Part II,Sch 1 of MSCIR, 1989)

70 Not Listed

Sodium Hydroxide Sr.No. 571(Part II,Sch 1 of MSCIR, 1989)

15 Not Listed

Aniline Sr.No. 37(Part II,Sch 1 of MSCIR, 1989)

5 Not Listed

Acetic Acid Sr.No. 2(Part II,Sch 1 of MSCIR, 1989)

5

Hydrogen Peroxide


15 Not Listed

Alpha Naphthylamine


25 0.001

Methyl Alcohol Sr.No. 377(Part II,Sch 1 of MSCIR, 1989)

5 Not Listed

Formaldehyde Sr.No. 285(Part II,Sch 1 of MSCIR, 1989)

5 Not Listed

Enclosure: 8 Manufacturing Process, Chemical Reacction and Mass Balance

Group1: Intermediate

1. MUA:

MPD: 720 HCl: 1860 NaOCN: 540 Water: 1200 Total: 4320

Reaction Vessel

Filtration Effluent will send to ETP: 2820

Finished Product 1500Kg of: MUA

2. PAABSA:

Omega Reactor Aniline: 200 Kg Formaldehyde: 120 Kg Sodium Bi Sulphite: 80 Kg Total: 400 Kg

Diazotization Sulphuric Acid: 300 Kg HCl: 250 Kg Nano: 120 Kg Water: 1500 L Ice: 1350 Kg Total: 3170 Kg

Coupling NaHCO3: 250 Kg

Filtration Spent Acid: 250 L

Centrifuge Effluent: 1200 L

Dryer Drying Loss: 1089 Kg

Pulverising

Finished Product 1500Kg Of PAABSA

CO2 Liberate: 131 Kg

3. SPCP In a MS Jacketed Sulphonator take Benzene. Check moisture test and charge Di Ethyl Oxalate. Check moisture test and charge Ethyl Acetate. Heat to 45oC and then charge Sodium Metal in 4-parts. After metal charging again heat for 3hours. In another reactor take water and charge real PHPSA the charge Caustic Lye. Then heating is started and get temperature 95-100 oC and maintain for 4hrs. Filter above solution in filter press and Nutch filter and take into MS/RL/BL vessel and charge Sulfanilic Acid. Drawn this solution into Nutch filter and then centrifuge it.

Chemical Reaction for SPCP:

SO3H

HCl

NaNO2

SO3HNa

NaHSO3

Na2CO3

+H2O

NH-NH2

+NaCl

SO3HNa

SO3HNa

SO3 + H2 O +

N

N

O

CH2 SO3H

H2 O +CH3OH

Benzene: 2650 Direthyl oxalate: 1050 Ethyl Acetate: 675 Total: 4375

Water: 5000 PAPSA: 1155 Caustic lye: 56 Total: 6211

Sulphonator Reaction Vessel

Sodium Metal: 120

Diazotization 10706

Condensation 10706

Water: 2000 Benzene recover: 2596

Filtration Effluent: 7170 L

Centrifuge Effluent: 1940 L

Finished Product 1000Kg of SPCP

4. N.W Acid:

1. :-Process Description:- Sodium Naphthionate is condensed with sodium Bisulphite at reflux temp for 48 hrs.Followed by

Hydrolysis with sulphuric acid to remove SO2.SO 2 is scrubbed in soda ash solution and reuse for further batch.Hydrolysed mass is neutralize and alkaline with sodium Hydroxide(Caustic Lye) boile for removal of Ammonia.Cool it remove isolated salt.Than Isolate N.W.acid with dil sulphuric acid/Hydrochloric acid.Filter it.Collect W/C and than dry the mass as N.W.Acid.

+ NaHSO3

NH2 OH

H2SO

NaOH

SO3H SO3H

3. Chemicals Reaction:-

SBS 3650 Water 16000

Reflux 2700

Filter

25300 28300

1500 1500

27860

15860

13360

15860

Drying

w/c 3200 kg 1200

2000 Dry

1680 Real

Filter Salt 2500

Hydrochloric Acid 2500 Isolation

Filter/Cf w/w 12660

140 NH3+300 water Scrubber700kg 20%(NH3)

Caustic Lye 48% Expel of NH3 Reuse Water

Concentration Water 12000

Water+Soda 8000+2200kg

Separation Reuse

SN SN 50kg

22250kg

SO2 Scrubber Reuse

H2SO4 (38%)5800 Hydrolysis 11970 25350kg

2. Process Flow Diagram And Mass Balance:--

S.N

SN(2600kg)1950Real SS Vessel

CO2 930kg

5. Sodium Naphthionate: Manufacturing Process: Stage-I In a ball mill, take sulfuric acid and alpha-Naphthol amine and heat for several hours .after that take the material down in cooling trays. Stage-II In a reaction mix the above material in water to get clear solution and filter the solution add some HCl(30%) in it and add vacuum salt to make sodium naphtheonate filter the material. Dry and pack. Chemical Reaction:

Material Balance:

6. DASA: Sulphonation of Acetanilide Acetanilide is sulphonated with chloro sulphonic acid at 50oc in M.S. vessel. The Sulpho mass is dumped in ice at 5-10OC temperature and filtered into Nutch. The filtrate is spent acid and wet cake is ASC slurry. Reduction of PNA PNA is reduced with iron powder and Hydrochloric Acid at 95 C in MSRL/BL vessel. The reduction mass is neutralized with soda ash and filtered in filter press. The filtrate is PPD Solution. PPD Solution is condensed with ASC at 30-40 oC using soda ash in MSRL/BL vessel. The isolated slurry is filtered in Nutch and washed with water. Wet cake is obtained. Hydrolysis Wet cake is charged in water and caustic soda flakes is added and heated. The hydrolyzed solution is clarified in filter press and clarified solution is neutralized using spent acid to isolate DASA. The isolated slurry of DASA is filtered in Nutch at 55ºC and washed with water, centrifuged it and dry it in dryer. The dried product is DASA.

Chemical Reaction for DASA (A) SULPHONATION OF ACETANILIDE (ASC): (B) REDUCTION OF PNA TO PPD: (C) CONDENSATION OF PPD WITH ASC:

+ 2ClSO3H

NHCOCH3 NHCOCH3

0 - 5°C

(M.W. 233.5) (M.W. 135) SO2Cl

NH2

NH2

(M.W. 138)

NH2

+ 2Fe + 2HCl + H2O

NO2

(M.W. 108)

NH2

NH2

+

NHCOCH3

SO2Cl

(M.W. 233.5) ASC Slurry

(M.W. 108) PPD

(M.W. 233)

M.W. 112 M.W. 73 M.W.18

+ 2HCl M.W. 73

(Goes with Product)

+ Fe2O3 M.W. 160

(Iron Sludge)

+ 2HCl (Goes with Product)

+ H2SO4 M.W. 98

Spent Acid

+ HCl M.W. 36.5

Goes to scrubber

Na2CO3 M.W. 106

(D) HYDROLYSIS OF CONDENSED MASS:

NHSO2 H2N NHCOCH3

(M.W. 305)

NHSO2 H2N NHCOCH3 + NaOH M W 40

(M.W. 305)

NHSO2 H2N NH2 + CH3COONa M.W. 82

+ 2NaCl M.W. 117

+ H2O M.W. 18

+ CO2 M.W. 44

+ HCl M.W. 36.5

+ 2NaCl M.W. 117

+ H2O M.W. 18

+ HCl M.W. 36.5

DASA (M.W. 263)

+ 2NaCl M.W. 117

+ H2O M.W. 18

+ HCl M.W. 36.5

Goes to Effluent

DASA

Acetanilide: 770 Kg ClSO3H: 1330 Kg Total: 2100 Kg

Sulphonation 2100 Kg

HCl: 210 Lit To Scrubber (Get Dilute HCl 30%- 700 Lit.)

Ice: 2000 Kg Dumping In Vessel 3890 Kg

Filter Nutch Spent Acid: 1250 Kg

PNA: 788 Kg HCl: 417 Kg Water: 1800 Kg Fe: 637 Kg Total: 3642 Kg

Reduction 3642 Kg

Filter Nutch 3642 Kg

Fe2O3:1200 Kg

Condensation 5687 Kg

PPD (2442 Kg)

Soda: 605 Kg

CO2 Generation: 252 Kg

Water: 750 Kg NaOH: 225 Kg Total: 975 Kg

Hydrolysis 6410 Kg

Spent Acid: 1500

Isolation 7910 Kg

Water: 1500 Kg Filter Nutch 9410 Kg

Waste Water: 6860 Lit. To Evaporator

Centrifuge 2550 Kg

ML: 600 Lit To Evaporator

Tray Drying 1950 kg

Moisture Loss: 450 Lit.

DASA: 1500 Kg

7. F.C.Acid: Reduction of PNA PNA is reduced with Iron Powder and hydrochloric acid is added at 95ºC in MSRL/BL vessel. The reduction mass is neutralized with Soda ash and Filtered in filter press, the filterate is PPD Solution. Condensation PPD Solution is condensed with PNCBSA at 102ºC using Soda ash and salt in MSRL/BL vessel. After condensation the slurry is isolated by spent acid and filtered into neutch and then it is centrifuged. The cake is 4- NADPSA. Reduction of 4-NADPSA 4- NADPSA is reduced with Iron powder and Hydrochloric Acid at 98oC in MSRL/BL vessel. The reduction mass is dissolved in Soda ash at 10.8 pH. The filtrate material is isolated by spent acid and filtered in to Nutch. Then washed it with water, then centrifuged and dried in drier. The dried product is F C Acid.

Chemical Reaction for FC Acid:

NO2

Fe + HCl

NH2

Reduction

Condensation

Cl NH2

NH2 NH2

+

NH2

So3H

NO2

Salt

Soda ash

NH

So3H

NO2

NH

NH2

NO2

Fe + HCl

Spent acid NH2 NH NH2

So3H

So3H

F C acid

NH2

FC Acid

PNA: 742 Kg HCl: 393 Kg Fe: 602 Kg Water: 1500 Kg Total: 3237 Kg

Reduction 3237 Kg

Filter Nutch 3237 Kg

Fe2O3: 1200 Kg With Moisture

PPD Solution 2037 Kg

Soda: 570 Kg PNCBOSA: 1276 Kg Total: 1846 Kg


Water: 1500 Kg

Filtration 5225 Kg

CO2 Generation: 158 Kg

Waste Water: 2700 Lit To Evaporator

Water: 1500 Kg H2SO4: 526 Kg Fe: 602 Kg Soda: 570 Kg Total: 3198 Kg

Reduction 5723 Kg

Fe2O3: 1300 Kg With Moisture

Filtration 5723 Kg

Spent Acid: 1500 Kg

Isolation 5923 Kg

Co2 Generation: 337 Kg

Water: 1500 Kg Filtration 7086 Kg

Waste Water: 4500 Kg To Evaporator

Centrifuge 2586 Kg

ML: 557 Lit. To Evaporator

Spin Flash Drying 2029 Kg

Moisture Loss: 529 Lit.

FC Acid: 1500 Kg

8. Sulpho VS Manufacturing Process:

Vinyl Sulphone Ester is charged in to sulphuric acid below 30oC. Then charge Oleum 65% in it & dumps this sulpho mass in ice and water & salted out by potassium chloride. Then filter it and centrifuge it. The final product is packed as a Sulpho VS.

Sulphonation V.S.: 944 Oleum Acid: 944 Sulphuric Acid: 1215 Total: 3103

Drying Ice: 2094 KCl: 692 Total: 2786

Centrifuge Filtrate: 4389

Finished Product 1500kg of Sulpho V.S.

9. OAVS: Acetyl ortho anisidine is charged in to chloro sulphonic acid below 30°C. After the addition the temperature is raised to 50-55°C and maintained for 4 hours. It is cooled and drowned over ice and filtered. The Sulphachloride is charged in to slurry of sodium bi sulphate and made neutral with caustic and the pH is maintained at 7 Ethylene oxide is passed in to the solution maintaining pH 7 by adding H2S04. When the reaction is complete, it is filtered and dried. It is further clarified by heating with calculated quantity of H2S04 and then pulverized.

Chemical Reaction for OAVS:

Material Balance

OAVS

Acetyl Ortho Anisidine: 1073 Kg Chloro Sulphonic Acid: 4550 Kg Total: 5623 Kg

Sulphonation 5623 Kg

HCl: 234 Kg To Scrubber (Get Dilute HCl 30%- 780 Lit.)

Dumping 6314 Kg Ice: 925 Kg

Sodium Bisulphite: 975 Kg Caustic Lye: 1787 Kg Total: 2762 Kg

Reduction 4671 Kg

Ethylene Oxide: 878 Kg Sulphuric Acid: 1603 Kg Total: 2481 Kg

Ethoxylation 7152 Kg

Effluent for Glauber Salt Recovery Glauber Salt: 1160 Kg Effluent to ETP: 4652 L

Sulphuric Acid: 475 Kg Esterification 1815 Kg

Acetic Acid: 315 Kg

Pulverization

OAVS: 1500 Kg

Filtration

Water: 2000 Spent Acid: 6405

10. K-Acid

B-Naphthol is sulphonated by 98% Sulphuric acid and 65% Oleum. Then sulpho mass dump in ice & water. Then salted out with Sodium Sulphate. Then filter it and get cake then amidation by 24% Ammonia & Sodium bisulphite. Then isolate the material with 98% Sulfuric acid. Filter it and centrifuge it & the final product is known as K-acid.

Chemical Reaction for K-Acid:

Sulphonation Β-Napthol: 1330 Sulphuric Acid: 2270 Oleum: 5675

Drowings Ice: 1670 Water: 1000

Isolation Sodium Sulphate: 4450

Filtration Wash Water: 2500

Centrifuge

Spent Acid: 12990 (Reuse/Re sale)

Spent Acid: 2750 (Reuse/ resale)

Amidatiion 24% Ammonia: 6830 Sodium Bi Carbonate: 920

NH3: 450 (To Water Scrubber & get 1050 Kg Amonium Hydroxide Solution)

Isolation Sulphuric Acid: 1165 SO2: 1650 (To Alkali Scrubber & get 2850 Kg Sodium Bisulphite)

Filtration & Nutch Wash Water: 840 ML: 7685

Centrifuge ML: 950

Product Loss: 675

Finished Product 1500Kg of K-Acid

Group2. Reactive Dyes:

1. Reactive Black 8/HN: 4 Nap Is diacotized and coupled with H-Acid solution in alkaline medium. Coupling mass obtained is then chrominated and cobalting is done.The resultant mass is then cyanurated and hot brandings done with liquid ammonia. The final product spray dried to get dry powder.

Chemical Reaction for Reactive Black HN:

Kieselgher : 27 Hcl: 475 Water: 1390 Ice: 1819 Total: 3711

Vessel 3711

Coupling 4024

Hcl: 223 Acetic Acid: 90 Total: 313

CO2 Liberate: 517

Reaction With Sodium Sulphate

Cyanuration 4324

Sodium Sulphate: 257 Caustic Lye: 279 Total: 536

Cyanuic Chloride: 281

Spray Dryer Spray Drying Loss: 2824

Reactive Black HN 1500 Kgs

2. Reactive Black WNN:

Vinyl Sulfone Diazo: Charge water and Vinyl Sulfone in MSRL vessel. Stir for good slurry. Charge HYDROCHLORIC ACID and Ice followed by Sodium Nitrite gradually till diazotization completed, which can confirmed by starch iodide paper. Any access nitrite will be removed by adding sulfamic acid just before coupling. First Coupling: Charge H.Acid into the Vinyl sulfone diazo and Ice. Second Coupling: Charge J. Acid into the first couple mass. And add soda bi carb/Soda Ash to adjust pH. Add Ice. Stir the couple mass for some time. Third Coupling: Increase pH by adding Soda Bi Carb / Soda Ash. Then charge MPDSA. Stir it for dissolved. Spray Drying: The liquid transferred to the spray drying holding tank and spray dry. Standardization: The spray dried powder is then charged to the Blender and de-dusted by antidusting oil if necessary. Packing: The final product is then packed in HDPE bags / M.S. Drums / Plastic Carboys / Paper Carton Boxes for ready to dispatch.

Chemical Reaction for Reactive Black WNN:

Diazotization:

Temp. 0–30C + 2.5 HCl + NaNO2+H2O + NaCl + H2O

Coupling: N=N-C l

+ + +

N=N

(Re. Black-5)

N=N

(Orange)

N=N =

NH2 N=N-Cl

SO2CH2 CH2OSO3H (V.S)

SO2CH2 CH2OSO3H (Diazo)

5

SO2CH2 CH2OSO3H

HO3S SO3H

OH NH2 HO3S NH

OH

NH2

NH2

SO3Na

Temp. -0-50C , pH=5.5,

NaO3SOH2CH2C O2S

OH NH2

NaO3S SO3Na

N=N SO2CH2 CH2OSO3Na

NaO3SOn2 CH2C O2S

NH2

NaO3S SO3Na

N=

SO2CH2 CH2OSO3Na NaO3S

NH2

SO2CH2 CH2OSO3Na

NH2

NaO3S

VESSEL: 1 (Diazo of S.P.V.S.)

Water: 1044 Lit S.P.V.S: 376 Kgs

Ice: 783 Kgs HCl: 76 Kgs

Sodium Nitrite: 72 Kgs

Total: 2351 Kgs

VESSEL: 1 (Coupling)

3266

J Acid: 124 Kgs MPDSA: 98 Kgs

VS Diazo: 343 Kgs Sodium Bi Carbonate: 350 Kgs

Total: 915 Kgs

Spray Drying

1500 Kgs Finished Product Reactive Black WNN/R/G

Spray drying Loss 2906 Kgs Including Ice & water qty. with product loss

CO2 Liberate: 183 Kg

VESSEL: 1 (Mixing with Reactive Black-B)

4406 Kgs

Reactive Black B: 517 Kgs Salt: 61 Kgs

Water: 417 liter Ice: 328 Kgs

Total: 1323 Kgs

3. Reactive Black B:

First Diazotization: VS charged to a MSRL reaction vessel along with water and ice to maintain temperature between 0 ºC to 5ºC. Then Hydrochloric Acid will be added followed by Sodium Nitrite powder gradually till diazotization completed, which can be confirmed by starch iodide paper. Any excess nitrite will be removed by adding Sulfamic Acid just before coupling. Keep temperature between 0 ºC to 5ºC throughout the diazotization reaction. First Coupling: Charged H-Acid to the diazotized BNTS and stir it keeping the temperature between 0 ºC to 5ºC by adding ice. Second Coupling: OAVS charged to a MSRL reaction vessel along with water and ice to maintain temperature between 0 ºC to 5ºC. Then Hydrochloric Acid will be added followed by Sodium Nitrite powder gradually till diazotization completed, which can be confirmed by starch iodide paper. Any excess nitrite will be removed by adding Sulfamic Acid just before coupling. Keep temperature between 0 ºC to 5ºC throughout the diazotization reaction. Spray Drying The Standardized dye liquid will be transfer to the spray drying holding tank and spray dried. Standardization The Spray dried powder is then charged to the ball-mill and standardization. Packing The Final product is then packed in HDPE bags / MS Drums / Plastic Carboys / Paper carton boxes.

Chemical Reaction for Reactive Black B:

Water: 3000 V.S.: 563 Ice: 3000 Hcl: 375 Sodium Nitrite: 135 Total: 7073

Reaction Vessel

Coupling

Water: 1200 H-Acid: 323 Soda Ash: 420 Ice: 1950 Live Steam: 450 Total: 4343

R.O. R.O. rejected: 6075

Spray Drying

Spray Drying Loss: 3841

Finished Product of 1500 Kg: Reactive Black 5

4. Reactive Blue 222/BF Manufacturing Process: MPDSA is condensed with Cynuric chloride and which is further condensed with MBVS Ester and then the product obtained is diazotized and coupled with H-Acid to get Coupling Mass-1. S.T A is diazotized and further coupled with coupling mass-1 to get coupling Mass-2, which is spray dried and dry PDR is obtained.

Reactive Blue BF (Blue 222)

Water: 1500 Kg Cyanuric Chloride: 150 Kg V.S: 225 Kg S.B.C:150 Kg Ice: 450 Kg Total : 2475 Kg

Cynuration 2475 Kg

MPDSA: 150 Kg S.B.C: 60 Kg Total: 210 Kg


VS: 225 Kg HCl: 300 Kg Sodium Nitrite : 111 Kg Ice: 1500 Kg Total: 2136 Kg

Diazotization 4821

H-Acid: 255 Kg C- Flax: 35 Kg Water: 1500 Kg Ice: 150 Kg Total: 1940 Kg

Coupler 6761 Kg

Spray Drying 3761 Kg Evaporation:

5261 Kg

Reactive Blue BF: 1500 Kg

5. Reactive Blue 194/ Navy Blue ME2GL: MPDSA is condensed with cycle and condensed product is again 2nd condensed with Sulfamic acid, which is then diazotized and coupled with H-Acid to give coupling mass-1. V.S. Ester Diazo is prepared and then condensed with coupling mass-1 to give coupling mass-2, which then spray dried and dry powder is obtained.

Chemical Reaction for Reactive Blue 194/Navy Blue ME2GL:

Sulphanilic Acid:237 Cyanuric Chloride: 250 Hcl: 212 Water: 1250 Ice: 1250 Total: 3199 Kg

Spray Drying Loss 4831

6331

Reactive Blue M2GL 1500Kg

Spray Dryer

Coupling

M.P.D.S.A: 257 Vinyl Sulphone: 375 Water: 1250 Ice: 1250 Total: 3132 Kg

6. Reactive Orange 12/ Golden Yellow HR: K-Acid is diazotized and coupled with Meta uriedo aniline. The coupled mass is cyanurated with Cyanuric chloride. The Cyanuration mass is hot branded with liquid ammonia to get final product, which is then isolated, filtrated and wet cake is obtained. The wet cake solution is prepared and then spray dried to get dry powder.

Chemical Reaction for Reactive Blue G/ 21:

Water: 1237 K-Acid: 592 Ice: 1082 HCl: 112 Sodium Nitrite: 106 Total: 3129

Vessel: 1 Diazo of K-Acid

Vessel: 2 Couping with MUA MUA: 233

Vessel: 3 Cyanuration

Cyanuration Chloride: 285 Sodium Bicarbonate: 649 Total: 934

CO2 Liberate: 339Kg

Vessel: 4 Hot Branch with

Ammonia

NH4OH: 54 Sodium Bicarbonate: 129 Total: 934

CO2Liberate: 67Kg

Spray Drying Spray Drying loss: 2573Kg

Reactive Golden Yellow HR 1500 Kg Produce

7. Reactive Orange 13/ H2R:

First Acetylation N Methyl J-Acid Charge to a MSRL reaction vessel along with water and ICE to maintain Temperature between 0 oC to 5ºC. Then Acetic Anhydride will be added followed by Caustic Flacks powder gradually till reaction completed, which can be confirmed by Congo Red paper. Keep Temperature between 20 oC to 25ºC throughout the Acetylation. First Diazotization ST Acid charged to a MSRL vessel along with water and ICE to maintain temperature between 0 oC to 5ºC. Then Hydrochloric Acid will be added followed by sodium Nitrite powder gradually till diazotization completed, which can be confirm by starch iodide paper. Any excess nitrite will be removed by adding Sulfamic Acid just before coupling. Keep temperature 0 oC to 5ºC throughout the diazotization reaction. First Coupling Charge Acetylation mass to the first diazotization BNTS and stir it keeping the temperature between 0 oC to 5ºC by adding Ice. Hydrolysis Charge caustic Flacks gradually keeping Temperature 85ºC throughout the Hydrolysis. Cyanuration In Hydrolysis mass charge ICE to maintain temperature 5ºC. Then Cynuric Chloride will be added followed by Soda Ash powder gradually till reaction Completed. Condensation Charge VS Powder gradually keeping Temperature 55ºC throughout the Reaction Completed. Spray Drying The Standardized dye liquid will be transfer to the spray drying holding tank and spray dried. Standardization The Spray dried powder is then charged to the ball-mill and standardization. Packing The Final product is then packed in HDPE bags / MS Drums / Plastic Carboys / Paper Carton boxes.

Chemical Reaction for Reactive Orange H2R:

Water: 1726 NMJ Acid: 436 Sodium Hydroxide: 69 Acetic Anhydride: 176 Total: 2407

Water: 863 Sulpho Tobias Acid: 523 HCl: 126 Sodium Nitrite: 119 Ice: 726 Total: 2357

Vessel: 1 Acetylation of NMJ Acid

Vessel: 2 Preparation of STA Diazo

Coupling NaHCO3: 289 CO2 Liberate: 151Kg

Hydrolysis NaOH: 69

Filtration Filtrate: 2881

Cyanuration

Cyanuric Chloride: 318 Water: 3178 Ice: 1726 Total: 5222

Isolation

NH4OH: 60 Spray Drying Spray Drying loss: 5872

Reactive Orange H2R 1500Kg

8. Reactive Yellow 15/ Yellow GR: PCVS is Diazo id coupled with SPMP and spray dried.

Chemical Reaction for Reactive Yellow 15/ Violet 5R:

Water: 1875 H-Acid: 720 Ice: 1750 Caustic Lye: 250 Acetic Anhydride: 394 Soda Ash: 750 HCl: 750 Total: 6489

Water: 2250 HCl: 250 Dispersing Agent- Tamol: 32 V.S.: 625 Sodium Nitrite: 157 Sulfamic Acid: 3 Ice: 2500 Total: 5817

Diazotization

Coupling 12882 Soda Ash Solution: 563

Octanol: 13 Total: 576

Coppering Ice: 500 Copper Sulphate: 648 Sodium Acetate: 1500 Hydrogen Peroxide: 813 Octanol: 13 Total: 3474

Heating Steam: 3125

Salting NaCl: 750

Filtration Wash Water: 1250 Effluent: 14000

Spray Drying Spray Drying Loss: 5981

Finished Product of 1500 Kg:

Reactive Yellow 15

9. Reactive Yellow 18:

First Cyanuration & Diazotization MPDSA Charge in MSRL reaction Vessel along with water and ICE to maintain Temperature between 0 ºC to 5ºC. Then add Cyanuric Chloride in the mass. Then Hydrochloric Acid will be added followed by Sodium Nitrite powder gradually till diazotization completed, which can be confirmed by starch iodide paper. Any excess nitrite will be removed by adding Sulfamic Acid just before coupling. Keep temperature between 0 ºC to 5ºC throughout the diazotization reaction. First Coupling Charge SPCP Powder to the diazotization BNTS and stir keeping the temperature between 0 ºC t o 5ºC by adding ICE. Condensation Charge Metanilic Acid Powder with soda ash for condensation purpose to the coupler mass and stir it keeping the temperature between 45ºC to 50 ºC. Spray Drying The Standardized dye liquid will be transfer to the spray drying holding tank and spray dried. Standardization The Spray dried powder is then charged to the ball-mill and standardization. Packing The Final product is then packed in HDPE bags / MS Drums / Plastic Carboys / Paper carton boxes.

Chemical Reaction for Reactive Yellow H4G:

Reaction Vessel

Water: 2000 MPDSA: 170 Ice: 1700 HCl: 219 Sodium Nitrite: 63 Total: 4152

Cynurarion

Water: 1350 Cynuration Chloride: 165 Caustic Lye: 75 Ice: 1500 Soda Ash: 93 Total: 3183

Coupling Water: 1050 SPCP: 255

Condensation Live Steam: 525 DASDA: 165

Spray Drying Spray Drying Los: 7830

Finished Product of 1500Kg of Reactive Yellow 18/ H4G

10. Reactive Yellow 42/ FG: Diazotization of Vinyl Sulphone by Hydro Chloric Acid, Sodium Nitrite, Ice & water. This mixture is known as diazotization of VS. Make solution of SPCP with water. Coupling of Diazo -1 with SPCP solution. This is known as coupler 1. Then add caustic soda up to required pH. Send the liquefied material of coupler I for spray drying activity. Finally the powder material is packed into bags.

Chemical Reaction for Reactive Yellow FG/42:

(1) VINYL SULPHONE DIAZOTIZATION:- + 2Hydrochloric Acid + NaNO2 + NaCl + 2H2O

(2) COUPLING I WITH SPCP:-

+

NH2

SO2CH2CH2OSO3H

(M.W. 281)

N=N-Cl

SO2CH2CH2OSO3H

(M.W. 328.5)

N=N-Cl

SO2CH2CH2OSO3H

S.P.C.P. (M.W. 284)

(M.W. 328.5)

Reactive Yellow FG

(M.W. 576)

+ HCl.

(M.W. 36.5)

Water: 1406 V.S.: 658 Ice: 1171 HCl: 171 Sodium Niterite: 161 Total: 3567

Vessel: 1 Diazo of vinyl sulphone

Vessel: 2 Coupling with SPCP

SPCP: 665 SBC: 393 Total: 1058

CO2 Liberate: 217Kg

Spray Drying Spray Drying loss: 2908

Reactive Yellow FG 1500Kg

11. Reactive Golden Yellow MERL/145:

First Diazotization K-Acid Charge in MSRL reaction Vessel along with water and ice to maintain temperature between 0ºC to 5ºC C. Then Hydrochloric Acid will be added followed by Sodium Nitrite powder gradually till diazotization completed, which can be confirmed by starch iodide paper. Any excess nitrite will be removed by adding Sulfamic Acid just before coupling. Keep temperature between 0ºC to 5ºC throughout the diazotization reaction. First Coupling Charge MUA Powder to the diazotization BNTS and stir keeping the temperature between 0ºC to 5ºC C by adding ice. 1st Cyanuration Charge Cyanuric Chloride to maintain Temperature between 0ºC to 5ºC C. Then Charge Soda Ash powder gradually till Cyanuration completed which can be confirmed by PC. Condensation Charge VS Powder with soda ash for condensation purpose to the coupler mass and stir it keeping the temperature between 45ºC to 50ºC Spray Drying The Standardized dye liquid will be transfer to the spray drying holding tank and spray dried. Standardization The Spray dried powder is then charged to the ball-mill and standardization. Packing The Final product is then packed in HDPE bags/MS Drums/Plastic Carboys/Paper carton boxes.

Chemical Reaction for Reactive Yellow 145/Golden Yellow MERL:

Water: 1795 K-Acid: 460 Ice: 957 HCl: 87 Sodium Nitrite: 83 Total: 3382

Vessel: 1 (Diazo of K-Acid)

MUA: 180 Vessel: 2 Coupling with MUA

Cyanurnatio

Cyanuric Chloride: 221 SBC: 201 Total: 422

Coupling with Vinyl Sulphone

Vinyl Sulphone: 336 SBC: 201 Total: 537

Co2 liberate: 263 Kg

Co2 liberate: 105 Kg


Reactive Golden Yellow MERL/145 1500Kg Production

12. Reactive Yellow 160/ ME4GL: MPDSA is condensed with Cyanuric chloridr and condensed product is diazotized and coupled with 2-Pyridone. The coupling mass obtained is further condensed with Vinyl Sulfone Ester to give final product, which is spraying dried to give dry powder.

Chemical Reaction for Reactive Yellow 160/ ME4GL:

Water: 1417 Cyanuric Chloride: 261 MPDSA: 266 Sodium Carbonate: 150 Ice: 1417 Total: 3511

Vessel: 1 Cyanuration of MPDSA CO2 Liberate: 62Kg

Vessel: 2 Diazotization

HCl: 103 Sodium Nitrite: 97 Total: 200

Vessel: 3 Coupling with 2Pyridone

2-Pyridone: 275 SBC: 119 Total: 394

CO2 Liberate: 62Kg

Vessel: 4 Coupling with Vuinyl Sulphone

V.S.: 398 SBC: 238 Total: 636

Spray Drying Spray drying loss: 3117Kg

Reactive YellowME4GL 1500Kg


Reactive YellowME4GL 1500Kg

13. Reactive Red ME4BL:

First Cyanuration ACVS Charge to a MSRL reaction vessel along with water and ICE to maintain Temperature between 0 ºC to 5ºC. Then Cyanuric Chloride will be added followed by Soda Bicarbonate powder gradually till reaction completed, which can be confirmed by Congo red paper. Keep Temperature between 0 ºC to 5ºC throughout the Cyanuration. Second Cyanuration Charge H-Acid Powder to the first Cyanuration BNTS and stir it keeping the temperature between 0 ºC to 5ºC by adding Ice. First Diazotization ST Acid charged to a MSRL vessel along with water and ICE to maintain temperature between 0 ºC to 5ºC. Then Hydrochloric Acid will be added followed by sodium Nitrite powder gradually till diazotization completed, which can be confirm by starch iodide paper. Any excess nitrite will be removed by adding Sulfamic Acid just before coupling. Keep temperature 0 ºC to 5ºC throughout the diazotization reaction. First Coupling Charge second Cyanuration to the first diazotization BNTS and stir it keeping the temperature between 0 ºC to 5ºC by adding ICE. Spray Drying The Standardized dye liquid will be transfer to the spray drying holding tank and spray dried. Standardization The Spray dried powder is then charged to the ball-mill and standardization. Packing The Final product is then packed in HDPE bags / MS Drums / Plastic Carboys / Paper carton boxes

Chemical Reaction for Reactive Red ME4BL:

Water: 550 V.S.: 310 Sodium Bicarbonate: 185 Cyanuric Chloride: 200 Ice: 550 Total: 1795

Water: 550 Sulpho Tobiac Acid: 330 HCl: 80 Sodium Nitrite: 75 SodiumBicarbonate: 185 Ice: 550 Total: 1770

Vessel: 1 Cyanuation

CO2 Liberate: 96Kg

Vessel: 2 Preparation of STA

Diazo

CO2 Liberarte: 96 Kg

Vessel: 3 Coupling of H-Acid

NaHCO3: 90 H-Acid: 350 Total: 440

CO2 Liberate: 48Kg

Coupling NaHCO3: 277

Spray Drying Spray Drying loss: 2494Kg

Reactive Red ME4BL

CO2 Liberate: 48Kg

14. Reactive Red 198/RB:

First Cyanuration ACVS Charge to a MSRL reaction vessel along with water and Ice to maintain temperature between 0ºC to 5ºC. Then Cyanuric Chloride will add followed by Sodium Bicarbonate powder gradually till reaction completed, which can be confirmed by Congo red paper. Keep Temperature between 0ºC to 5ºC throughout the Cyanuration. Second Cyanuration Charge H-Acid Powder to the first Cyanuration BNTS and stir it keeping the temperature between 0ºC to 5ºC by adding ice. First Diazotization ST Acid charged to a MSRL vessel along with water and Ice to maintain temperature between 0ºC to 5ºC. Then Hydrochloric Acid will be added followed by sodium Nitrite powder gradually till diazotization completed, which can be confirm by starch iodide paper. Any excess nitrite will be removed by adding Sulfamic Acid just before coupling. Keep temperature 0ºC to 5ºC throughout the diazotization reaction. First Coupling Charge second Cyanuration to the first diazotization BNTS and stir it keeping the temperature between 0ºC to 5ºC by adding ice. Spray Drying The Standardized dye liquid will be transfer to the spray drying holding tank and spray dried. Standardization The Spray dried powder is then charged to the ball-mill and standardization. Packing The Final product is then packed in HDPE bags / MS Drums / Plastic Carboys / Paper carton boxes.

Chemical Reaction for Reactive Red 198/RB:

Water: 1136 Cyanuric Chloride: 210 H-Acid: 362 Sodium Bicarbonate: 95 Ice: 568 Total: 2371

Water: 568 V.S: 320 HCl: 82 Sodium Nitrite: 78 Ice: 568 Total: 1616

Vessel: 1 Cyanuration of H-Acid Vessel: 2 V.S. Diazo

Vessel: 1 Coupling

NaHCO3: 380 CO2 Liberate:200 Kg

Vessel: 4 Condensation with V.S.

Na2CO3: 120 V.S.: 320 Total: 440 CO2 Liberate: 50 Kg

Spray Drying Spray Drying Loss: 3057Kg

Reactive Red RB 1500Kg

15. Reactive Blue G/21:

Charge Chloro Sulphonic Acid in MS Reactor plus charge CPC Blue gradually, heat up this mixture by boiler by 120 C -130 C and maintain this temperature for 3Hrs and cool it down to 40 C- 45 C. After that dump this mixture in to dumping vessel with ice. Then filter this mixture into filter press and was it off with water. Then add VS Solution and maintain the pH by adding material. Sprays dry this material in spray dryer.

Chemical Reaction for Reactive Blue G/ 21:

Vessel CPC: - 510Kgs CSA: - 1980Kgs PCl3:-270Kgs Total: 2760

SO2, HCl Scrubbed out in Scrubber System: 360Kgs

Dumping Vessel Ice: -2010 Kgs

Filtration Water: -2450 Kgs Filtrte: 5260Kgs

Condensation

Ice:-330 Kgs V.S.:- 480Kgs Global Salt; - 120 Kgs Total: 930 Kgs

Neutralization Sodium Bi Carbonate: - 330Kgs

Spray Drying M/c Removal 1360 Kgs

Product 1500Kgs

2860 Kgs

2530 Kgs

1600 Kgs

4410Kgs

2400Kgs HCl As Byproduct:1500 Kg

16. Reactive Orange ME2RL:

First Acetylation J-Acid Charge to a MSRL reaction vessel along with water and ICE to maintain Temperature between 0 oC to 5ºC. Then Acetic Anhydride will be added followed by Caustic Flacks powder gradually till reaction completed, which can be confirmed by Congo red paper. Keep Temperature between 20 ºC to 25ºC throughout the Acetylation. First Diazotization ST Acid charged to a MSRL vessel along with water and iceto maintain temperature between 0 ºC to 5ºC. Then Hydrochloric Acid will be added followed by sodium Nitrite powder gradually till diazotization completed, which can be confirm by starch iodide paper. Any excess nitrite will be removed by adding Sulfamic Acid just before coupling. Keep temperature 0 ºC to 5ºC throughout the diazotization reaction. First Coupling Charge Acetylation mass to the first diazotization BNTS and stir it keeping the temperature between 0 ºC to 5ºC by adding ice. Hydrolysis Charge caustic Flacks gradually keeping Temperature 85ºC throughout the Hydrolysis. Cyanuration In Hydrolysis mass charge ICE to maintain temperature 5ºC. Then Cynuric Chloride will be added followed by Soda Ash powder gradually till reaction Completed. Condensation Charge VS Powder gradually keeping Temperature 55ºC throughout the Reaction completed. Spray Drying The Standardized dye liquid will be transfer to the spray drying holding tank and spray dried. Standardization The Spray dried powder is then charged to the ball-mill and standardization.

Chemical Reaction for Reactive Orange 122/ME2RL:

Water: 1415 J Acid: 297 Caustic Lye: 141 Acetic Anydride: 226 Total: 2079

Water: 2132 HCL: 466 Sulpho Tobias Acid: 339 ICE: 2490 Total: 10427

Vessel Vessel

Coupling & Hydrolysis 7647

Filtration 7647

Cynuration 8107

Caustic Lye: 141

Vessel

Cyanuric Chloride: 212 Water: 2415 Ice: 3075 Total: 5702

Effluent: 5242

2079 5427

Vinyl Sulphone: 308 Water: 283

Spray Drying

8698


Reactive Orange ME2RL: 1500 kg

Group2. Direct Dyes:

1. Direct Black VSF/22:

Diazotization: F C Acid charged to a reaction vessel along with water. Then Hydrochloric Acid will be added followed by stirring. Charge ice then charge Sodium Nitrite. Maintain it for some time. Remove excess Nitrite by adding sulphamic acid Keep temperature between 0 to 50C throughout the diazotization reaction. Gamma acid clear solution: Charge Gamma Acid with water. Raise the pH of the mass by addition soda ash and caustic flakes up to the 6.5 – 7.0. Stir it for 30 minutes. Add ice to drop temp around 00C. First coupling: Transfer Gamma Acid clear solution in to F C Diazo slowly with temp 5 to 100C. Stirr for 2 hr. Diazo of coupler mass: Charge ice with HYDROCHLORIC ACID in coupler mass. Then dump sodium nitrite. Stir the solution for 0.5 hr. Add ice to set temp 0C. Remove excess nitrite by adding sulphamic acid. MPD clear solution: Charge water and heat it up to 500C. Then charge MPD and stir for 30 minutes. Second coupling: Transfer first coupled mass in to MPD clear solution. After completion of addition adjust pH 8.5 by charging Soda ash solution. Stir the solution for 8 hrs. Do the filtration of coupling solution after raising the temp up to 400C. Then Charge with water to make slurry. Spray Drying: The liquid transferred to the spray drying holding tank and spray dry.

Chemical Reaction for Direct Black 22/VSF:

F.C.Acid: 270 kg Ice: 540 kg HCl: 487 kg Sodium Nitrite: 135 kg Water: 600 Lit. Gamma Acid Coupling

1334 Lit

Ice: 150 kg Water: 675 Lit. Gamma Acid: 427 kg Caustic:82 kg

Coupling – I 4626 Lit.

F.C. Diazo 2032 Lit.

Ice: 450 Soda Ash: 435 kg Water: 375 Lit.

Diazo

Diazotization

Coupling – III 6628 Lit.

DIRECT BLACK 22 1500 kgs

Liquefied Material to Spray Drying

HCl: 750 Lit NaNO2: 135 kg Ice: 750 kg

Water Evaporates: 5128 Liter

Water: 150 Lit. MPD: 217 kg

2. Direct Red 31

Rhoduline Acid: 213 Water: 1500 Ice: 750 Soda Ash: 195 Total: 2658

Rhodulline Solution

Diazo tab Water: 600 HCl: 114 Aniline: 126 Ice: 750 Sodium Nitrite: 46 Total: 1636

Aniline Diazotizatio

Coupling HMP: 37 EDTA: 3 Total: 40


Tray Drying Drying Loss: 1035

Direct Red 31: 1500Kg

3. Direct Orange 39:

Water: 2600 Kg PAPSA: 375 Kg Total: 2975 Kg

Vessel 8525 Kg

Water: 2000 Kg HCl: 300 Kg Ice: 1000 Kg Total: 3300 Kg

Dumping Vessel 8825 Kg

Caustic: 150 Kg DASDA: 400 Kg Water: 2000 Kg Total: 2550 Kg

Isolation

Filtration

Spray Drying

Final Product: 1500 Kg

Filtrate: 4000 Kg

Spray Drying Loss: 3325 Kg

4. Direct Yellow 86: First Diazotization C-Acid charge to a MSRL reaction vessel along with water and ICE to maintain temperature between 00C to 50C. Then Hydrochloric Acid will be added followed by Sodium Nitrite powder gradually till diazotization completed, which can be confirmed by starch iodide paper. Any excess nitrite will be removed by adding sulfamic acid just before coupling. Keep temperature between 00C to 50C throughout the diazotization reaction. First Coupling Charge Meta Toluidine Hydrochloride to the diazotization BNTS and stir keeping the temperature between 00C to 50C by adding ICE. Isolation & Filteration Charge Refined Salt and stir keeping temperature 50C to 100C by adding ICE till good spot. Filter in Filter Press. W/C Charge in Water & Proceed for Cynuration. 1st Cynuration Cynuric Chloride Charge in MSRL reaction Vessel along with water and ICE to maintain Temperature between 00C to 50C. Then Cyanuric Chloride in the mass. Then Base solution will be added followed by Sodium Carbonate powder gradually till Reaction completed, which can be confirmed by Paper Chromatogram. Any excess Base will be removed by adding Cynuric Chloride. Keeping temperature between 00C to 50C throughout the 1st cyanuration reaction completed. 2nd Condensation Raise temperature between 400C to 450C by adding Soda Carbonate powder gradually till reaction completed, which can be confirmed by paper chromatogram. Any excess Base will be removed by adding Cynuric Chloride keeping temperature 400C to 450C temperature through the 2nd condensation reaction completed. 3rd Condensation Raise Temperature between 900C to 950C Temperature by adding Mono Ethyl Amine liquid. Spray Drying The Standardized dye liquid will be transfer to the spray drying holding tank and spray dried. Standardization The Spray dried powder is then charged to the ball-mill and standardization. Packing The Final product is then packed in HDPE bags / MS Drums / Plastic Carboys / Paper carton boxes.

Chemical Reaction for Direct Yellow 86:

Reaction Vessel

Meta Toluidine: 129 Kg Water: 1575 Kg Ice: 1700 Kg Soda Ash: 128 Kg Total: 3532 Kg

1St Coupling

Cynuric Chloride: 221 Kg Ice: 650 Kg Water: 1050 Kg Caustic Lye: 113 Kg Total: 2034 Kg

Cynuration

Live Steam: 600 Kg DEA: 146 Kg

Condensation

R/O

Spray Drying

Final Product 1500 Kg

5376 Kg Use For Washing

4682 Kg

Water: 2575 Kg C-Acid: 363 Kg Ice: 2000 Kg HCl: 225 Kg Sodium Nitrite: 83 Kg Total: 5246 Kg

5. Direct yellow 11:

Direct Yellow 11

REACTION VESAL

TNBA: 150 Kg DEA: 200 Kg

LIQUIDIFICATION

SOLVENT SEPRATION

Distillation

FINAL LIQUID SLURY: 1500 Kg

PAN Acid: 250 Lit. Caustic: 200 Kg Water: 2000 Kg Total: 2450 Kg

D E A: 130 KG ( DYE ETHENOL AEMINE )

Solvent recovery: 1430

6. Direct Violet 9:

Vessel

MXO 200 KG SODA 80 LTR WATER 1500 LTR NAITRATE 72 KG

RIVERS DIZOTIZETION HCL 400 KG

VESAL PC 150 KG WATER 1000 LTR HCL 150 LTR

FILTER

WATECAKE DUMPING 980 Kg

PTO RIVERS DYZOTIZETION

DUMPING VESAL PHYNIAL J 300 KG SODA 100 LTR WATER 2000 LTR

FILTERATION

WATECAKE DUMPING

DRYING

CUPPLER

MASS BALANCE


DRYING LOSS 780 Kg

Effluent: 2100 L

Effluent: 2572 L

7. Direct Blue 86: Charge Oleum into reactor vessel. Slowly add CPC powder into the reactor. Maintain temperature during this reaction. Dump Sulpho mass into salted ice and filter it. Make liquid of w/c by addition of Caustic flakes. This liquid is dried by direct spraying.

Chemical Reaction for Direct Blue 86:

Material Balance

8. Direct Blue FF:

DIRECT Blue FF

Blue B Base: 200 Kg HCl: 100 Kg Ice: 2000 Kg Nitrate: 150 Kg Water: 2000 Kg Total: 4450 Kg

Diazotization 4450 Kg

H-Acid: 600 Kg Soda Ash: 300 Kg Water: 1500 Kg Total: 2400 Kg

Dumping Vessel 6850 Kg

Isolation

Filtration

Drying

Filtrate: 3500 Kg

M/C Removal: 1850 Kg


Group3. Acid Dyes:

1. Acid Blue 193/ Dark Blue MTR:

1-Diazo 2-Naphthol 4 Sulphuric Acid coupling with Beta Naphthol. Clear Sold at 50ºC temp. in alkaline medium in presence of catalyst. Stir for 3 hours after 3 hours Chromination with Salicylic Acid & B.C.S at 95ºC temp. PHP maintain so for 4 hours. After 4 hours check test completion of Chromination. If o then spray dry it.

Chemical Reaction for Acid Blue 193/ Dark Blue MTR:

Water: 2750 Beta Naphthol: 460 Caustic Flakes: 262 Total: 4472 Beta Solution

1st Coupling Water: 1500 1:2:4: diazo: 750 Total: 2250

Chromination Salicylic Acid: 75 B.C.S.: 525(Basic Chrome Sulphate) Caustic Flakes: 112 Total: 712


Acid Blue 193: 1500Kg

2. Acid Brown 75/ CR:

H-Acid Diazotized with HYDROCHLORIC ACID & Nitrite at 0ºC temp. Stir 1-1/2" hours after 1-1/2 hours coupling with resorcinol in alkaline medium and stir. After 2hours Na picramate diazo coupling with first coupling in alkaline medium. Stir for 2 hours. After 2 hours PNA Diazo coupled with second coupling at 6.5 pH, stir 6 hours then RO and spray dryer it.

Chemical Reaction for Acid Brown75/CR:

Water: 1750 H-Acid: 480 HCl: 102 Sodium Nitrite: 103 Ice: 2500 Total: 4935

Diazotization

1st Coupling Resourcinol: 165 Caustic Flakes: 360 Total: 525

2nd Coupling

Water: 1750 Napacramate: 330 HCl: 130 Sodium Nitrite: 105 Ice: 1750 Total: 4065

3rd Coupling

Water: 1750 PNA: 207 HCl: 130 Sodium Nitrite: 103 Ice: 1000 Total: 3190

RO R/O rejected: 6700

Spray Dryer Spray Drying loss: 4515

Acid Brown 75: 1500Kg

3. Acid Black 194: Manufacturing Process:

• Preparation of Diazotization: Charge 6-Nitro in the MSRL vessel. Add water and ice in it. • Preparation of coupling component: Charge B-Naphthol in the MSRL vessel with kg caustic. • Coupling: Charge 6- Nitro slurry ti the B-Naphthol slurry. Keep the temperature between 0°C to

5°C by adding ice. • Chromination: Add basic Chromium Sulphate in coupler mass and give steam for the heating

purpose. • Heating: Heat is coupler mass by giving steam. • Spray Drying: Sand the total mass for the drying purpose

6-Nitro: 738 Water: 1200 Ice: 1200 Total: 3138

Diazotization 3138

B-naphthol: 354 Caustic: 531 Total: 885

1st Coupling 4023

Ice: 600

2nd Coupling 4623

Chromination

BCS: 225

Steam: 840 Salicylic Acid: 885 Total: 1725

Heating

Spray Drying Spray Drying Loss 5073


4. Acid Blue 113: Manufacturing Process:

• Metanilic acid diazotized with Hydrochloric Acid, Nitrite and with ice at 0°C temperature stir for 1 hour. Alpha Naphthyl Amine coupled with Metanilic acid in acidic medium. Stir for 8 hours. After 8 hours ANA diazo with Hydrochloric Acid & Nitrite at 18 °C temp. Stirrer 3 hours and then coupled with Phenyl Peril Acid. At neutral pH, stir for 3 hours, then isolated & spray dryer it.

Water: 1500 Kg Metanilic Acid: 450 Kg HCl: 135 Kg Sodium Nitrite: 180 Kg Ice: 1750 Kg Total: 6015 Kg


Water: 1500 Kg HCl: 225 kg Alpha Naphthyl Amine: 350 Kg Total: 2075 Kg

1st Coupling 6090 Kg

Ice: 1250 Kg Nitrite: 180 Kg H2SO4: 375 Kg Caustic Flakes: 300 Kg Total: 2105 Kg

2nd Diazotization 8195 Kg

Water: 1500 Kg Phenyl Peri Acid: 735 Kg Soda Ash: 300 Kg Sodium Acetate: 450 Kg Total: 2985 Kg

2nd Coupling 11180 Kg

RO 5500 Water Recycle for Washing

Spray Drying 6680 Kg

Acid Blue 113: 1500 Kg

4180 Water Evaporate

5. Acid Green 68: Manufacturing Process:

• PNA (Para Nitro Aniline) Diazotized with Hydrochloric Acid, Nitrite at 50°C temp, Stir for 2 hour. H- Acid Clear Solution coupled with PNA Diazo in Acidic Medium at 100°C temperature. Stir 8 hours DASA Tetrazosited and with first coupling in alkaline medium coupled at 70°C temperature. Stir 2 hour third coupling resorcinol with second coupling in alkaline medium at 100°C temperature. Stir for 6 hours. After 6 hours heat 50V clarify/ RO, Spray Drying it.

Water: 2050 Kg PNA: 213 Kg HCl: 133 Kg Nitrite: 107 Kg Ice: 2000 Kg Total: 4503 Kg


Water: 900 Kg H-Acid: 468 Kg Soda Ash: 90 Kg Total: 1458 Kg

1st Coupling 5961 Kg CO2:30 Kg

Water: 1500 Kg DASA: 365 Kg HCl: 230 Kg Nitrite: 190 Kg Ice: 2250 Kg Caustic Flakes: 315 Kg Total: 4850 Kg

2nd Coupling 10781 Kg

Water: 750 Kg Resourcinol: 162 Kg Total: 912 Kg

3rd coupling 14693 Kg

R/O 5500 Water Recycle for Washing


4693 Kg Water Evaporate

Acid Green 68: 1500 Kg

6. Acid Red 131:

Water: 2750 Kg H-Acid: 600 Kg C-Flakes: 150 Kg Ice: 1500 Kg Soda Ash: 150 Kg Total: 5150 Kg

Diazotization 5150 kg

Ether: 340 Kg HCl: 405 Kg Water: 2750 Kg Ice: 2000 Kg Sodium Nitrite: 90 Total: 5585 Kg

Coupler Solution 10735 Kg

Caustic Flakes: 105

Coupling 10840 Kg

Clarifier 9740 Kg

Waste: 1100 Kg

Evaporation: 5015 kg




7. Acid Yellow 36: Manufacturing Process: Metanilic Acid, Soda Ash, Caustic Flakes and NaNO2 are diazotised in presence of water and Ice. Diphenyl Amine, Caustic, Emulsifier and Soda Ash are dissolved in presence of Ice & water.above both diazotised and dissolved mass are coupled in coupling vessel. The mass is than Isolated and filtered followed by drying and pulverisation to obtain finished product. Chemical reaction:

Acid Yellow 36

Metanilic Acid: 720 Kg Soda Ash: 300 Kg Caustic Flakes: 75 Kg NaNO2: 285 Kg Water: 3000 Kg Ice: 1500 Kg Total: 5880 Kg

Diphenyl Amine: 690 Kg Caustic: 300 Kg Emulsifier: 90 Kg Soda Ash: 285 Kg Ice: 1500 Kg Water: 1500 Kg Total: 4365 Kg

Diazotization Diazotization

Coupling 12150 Kg

Salt: 1905 Kg

Filter

Waste Water: 8100 Kg

Drying 4050 Kg

Loss: 2550 Kg

Finished Product: 1500 Kg

1. Acid Violet 90/Bordeaux MB:

1 Diazo 2 Naphthol 4 Sulphonite Acid coupling with PMP. Diazoxide is coupled in near Alkaline medium with Parazolone and the coupling product converted into 1:2 metal complexes with Basic Chrome Sulphate.

Chemical Reaction for Acid Violet 90/ Bordeaux MB:

Water: 4500 1 diazo: 576 Total: 5076

Diazo Solution

1st Coupling

Water: 3000 PMP: 426 Caustic Flakes: 150 Total: 3576

Chromination

Salicylic Acid: 103 B.C.S.: 412 Caustic Flakes: 79 Total: 594


Wet Cake Water: 1200

Spray Drying Spray drying loss: 5250

Acid Violet 90: 1500Kg

2. Acid Black 210/NT:

First make PNA Diazo coupled with H Acid in acidic medium at 5ºC stir foe hour then DASA Tetrazo coupled with first coupling in alkaline medium at 10ºC stir for 2 hour & then last above coupling with make Phenyl Diamine in alkaline pH at 10º then clarify & RO and spray dry it.

Chemical Reaction for Acid Black 210/NT:

PNA: 165 Ice: 1500 HCl: 270 Sodium Nitrite: 487 Water: 522 Total: 2947

Ice: 225 Water: 1200 H-Acid: 381 Caustic: 48 Total: 1854

PNA Diazo Coupling-1

Ice: 450

Coupling-2

DASA: 300 Ice: 1500 HCl: 600 Sodium Nitrite: 165 Water: 600 NaOH: 240 Total: 3165

Coupling-3

Water: 300 MPD: 120 Steam: 600 Total: 420

Filter press Filtrate: 7955

Tray Dryer Loss: 221

Acid Black Product 1500Kg

Group4. Solvent Dyes:

1. Solvent Blue 36:

In clean reaction charge methanol, quinizerene, leuco quinizerene and propan-2-amine. Heat the reaction mass to reflux temp. And maintain for 8 hrs. Cool the reaction mass to Room temp, for isolation. Filter the reaction mass and wash with water. Dry the wet cake And pulverize and sent for packing.

Chemical Reaction for Solvent Blue 36:

Solvent blue 36

Quinizarine: 1125 kg MeOH : 3515 kg N-Isopropylamine : 558 kg

Filtrate

Solvent

Filtrate

S.S Reactor 5198 kg

Maintain reflux Heating Water distilled out 168 kg

5030 kg

Nutch

Washing MeOH: 468 lit

Solvent recovery: 3797 kg

Drying

1701 kg

Evaporation loss : 201 kg

1500 kg

Pulverize Final Yield: 1500 kg

Quinizarine: 1125 Kg MeOH: 3515 Kg N-Isopropylamine: 558 Kg Total: 5198 Kg

2. Solvent Red 24:

Diazotization:- Take approximate water in vessel. Take Garnet GBC and Stirrfor15minures.Add Hydrochloric Acid. Add Ice to bring temperature 0-5ºC. Add Sodium Nitrite under stirring Maintain temperature 0-5ºC. Coupler:- In another vessel take approximate water. Charge B-Naphthol and stir solution for 15minutes. Add Caustic Flakes and stir the solution for 30minutes. Clear the solution and Ice to bring temperature 0-5ºC. Coupling:- Receive diazo solution to coupler solution. Stir over night. Maintain pH 7.0 Next day heat to 40ºC. Filter in filter press. Unload and dry the wet cake at 80-90ºC.

Chemical Reaction for Solvent Red 24:

Solvent Red -24

Vessel: 1 (Stirring 15 min) 440 Kg

Water: 200Kg Fast Garnet GBC Base: 240Kg Total: 440

Vessel: 1 (stirring) 1500Kg

HCl: 390 Kg Ice: 597 Kg Total: 987

Diazo solution 1500Kg

Vessel: 1 Temp 5 0C 1427Kg

Sodium Nitrite Solution: 73 Kg

3. Solvent Yellow 33: In vessel take O.D.C.B and add Quinaldine, Phthalic Anhydride. Close the vessel. Heat to 175oC. Separate the water from receiver and maintain this temperature for 5hours. Cool to room temperature and dump to Nutch filter. Wash with Methanol. Dry wet cake at 100oC.

Chemical Reaction for Solvent Yellow 33:

Solvent Yellow 33

ODBC: 1258 Kg Phthalic Anhydride: 817 Kg Quinaldine: 791 Kg Total: 2866 Kg

Reaction 2866 Kg

Methanol: 3333 Kg Isolation 6199 Kg

Wash Water: 4166 Kg Filtration 10365 Kg

ODCB Recovery: 1187 Kg Methanol Recovery: 3000 Kg Aqueous ML: 2428 kg Total: 6615

Drying 3750 Kg Drying Loss: 2250 Kg

Pulverisation 1500 Kg

Packing


4. Solvent Green 3: A mixture of Quinizarine & Leuco Quinizarine is reacted with Para Toluidine using Butanol as a solvent. The product is isolated by distilling off the Butanol; it is then filtered and washed with Hydrochloric Acid. The wet cake is dried, pulverized and sieved to get the finished product.

Chemical Reaction for Solvent Green 3:

Solvent green 3

Butanol: 3711 Kg Quinizarine: 996 Kg P-Toluedine: 520 Kg Total: 5227 Kg

Reaction 5227 Kg

Water: 3711 Kg Distillation 8938 Kg

Filtration 8505 Kg

Water Wash: 3092 Kg

Butanol Recovery: 3525 Kg

Aqueous ML: 4763 Kg

Drying 3742 Kg

Drying Loss: 2242Kg

Pulverisation 1500 Kg

Packing

Final product: 1500 Kg

Group5. Food Colors:

1. Tatrazine:

STAGE 01: Take water in reaction vessel 01.Now charge Sulfanilic Acid in it. Then stir it. Add Ice to maintain temperature. Add Hydrochloric Acid and Sodium Nitrite. STAGE 02: Couple vessel 01 mass with DMAS in reaction vessel 02. Charge Sodium Carbonate and water in it. Then stir it. SPRAY DRYING: Sent the liquor for spray drying. Pack the Final product.

Water: 1200 Sulphanilic Acid: 658 HCl: 277 Sodium Nitrite: 262 Total: 2397

Vessel-1

Vessel-2 DMAS: 670 Sodium Carbonate: 403 Water: 1350 Total: 2423

CO2 Liberate: 167

Clarifier Process Waste: 40Kg

Filteration Effluent to ETP: 1649 L


Tartrazine : 1500Kg Production

2. Sunset Yellow:

STAGE 01: Take water in reaction vessel 01.Now charge Sulfanilic Acid in it. Then stir it. Add Ice to maintain temperature. Add Hydrochloric Acid and Sodium Nitrite STAGE 02: Couple vessel 01 mass with Schaffer’s Acid in reaction vessel 02.Charge Sodium Carbonate and water in it. Then stir it. SPRAY DRYING: Sent the liquor for spray drying. Pack the Final product.

Water: 1350 Sulphanic Acid: 576 Ice: 750 HCl: 243 Sodium Nitrite: 229 Total: 3148

Vessel: 1

Vessel: 2 Coupling with

Schffer’s Acoid

Schaffer’s Acid: 742 Sodium Carbonate: 351 Water: 1050 Total: 2143

CO2 Liberate: 146

Clarifier Process Waste: 36


Sunset Yellow Production: 1500Kg

3. Chocolate Brown:

Stage 1: Take Water in a reaction vessel. Now charge Sodium Naphthonate in it. Then stir it,Add ice to maintain the temperature. Add Hydrochloric Acid and Sodium Nitrite. Stage 2: Couple vessel 1 mass with Resorcinol in Reaction Vessel 2. Charge Sodium Hydroxide and Formaldehyde and stir it. Stage 3: Then clarifying the mass and add salt to it. Again filtrate it and then Spray drying it. Pack the final product.

Water: 1500 Sodium Naphthonate: 513 Ice: 2700 HCl: 168 Sodium Nitrite: 159 Total: 5040

Vessel: 1 Diazo of Sodium

Napthonate

Vessel: 2 Coupling with

Resorcinol

Resorcinol: 253 Sodium Hydroxide: 369 Formaldehyde: 69 Total: 691


Salling

NaCl: 165

Filtratiion Filtrate: 3795

Making Soln. of Wet Cake Water: 3750

Chocolate Brown Production: 1500Kg


4. Ponceau 4R:

STAGE 01: Take water in reaction vessel 01.Now charge Sodium Sulphonate in it. Then stir it. Add Ice to maintain temperature. Add Hydrochloric Acid and Sodium Nitrite STAGE 02: Couple vessel 01 mass with G-Salt in reaction vessel 02.Charge Sodium Carbonate and water in it.Then stir it. SPRAY DRYING: Sent the liquor for spray drying. Pack the Final product.

Water: 1650 Sodium Napthonate: 541 Ice: 1800 HCl: 181 Sodium Nitrite: 171 Total: 4343

Vessel: 1 Diazo of Sodium Napthonate

Vessel: 2 Coupling with G-Salt

G-Salt: 754 Sodium Carbonate: 526 Water: 1350 Total: 2630

CO2 Liberate: 217


Filteration Effluent goes to ETP:1657


Ponceau 4R Production: 1500Kg

Group: 6 Disperse Dyes

1. Disperse Blue 366

8

Diazotization & Clarification

Water: 750

HCl: 764

PCONA: 380

Ice: 7500

Sodium Nitrite: 157

Coupling EP: 393

Water: 1500

Sodium Acetate: 873

Aulfamic Acid: 7

Catalytic aAcid: 4

Ice: 5250

Volume Adjustment

Water: 15000

Filtration Washing Water: 10920

Sand Mill

Waste Water to ETP: 41000

Acetic Acid: 15

Dytol DF: 333

Harmonizer Kiri Mol: 1333

Anti Dusting Oil: 8

Spray Dryer Spray Drying Loss: 2690

Finished Product 1500 Kg of

Disperse Blue 366

2. Disperse Orange 25:

3. Disperse Yellow 211

Water: 750 Kg HCl: 763 Kg PCONA: 380 Kg Ice: 7500 Kg Sodium Nitrite: 157 Kg Total: 9550 Kg

Diazotization and Clarification

9550 Kg

EP: 393 Kg Water: 1500 Kg Sodium Acetate: 873 Kg Sulphamic Acid: 7 Kg Catalytic Agent: 4 Kg Ice: 5250 Kg Total: 8027 Kg

Coupling 17577 Kg

Water: 15000 Kg Volume Adjustment 32577 Kg

Washing Water: 10920 Kg Filtration 43497 Kg

Waste Water Stream to ETP: 40997 Kg

Wet Cake: 2500 Kg

Acetic Acid: 15 Kg Dytol DF: 333 Kg Total: 348 Kg

Wet Cake: 2848 Kg

Sand Mill

Kiri Mol: 1333 Kg Anti Dusting Oil: 7 Kg Total: 1340 Kg

Harmonizer: 4188 Kg

Spray Dryer Evaporation Loss: 2688 Kg

Disperse Yellow 211: 1500 Kg

4. Disperse Blue 79

Manufacturing Process: DNBrPNA is diazotized & coupled with M-5A.Then Coupled mass is Filtered. Wet cake is washed by water & make slurry in dispersing agent & water Then is grinded & standardized in sand mills, Then Slurry is dried in spray dried for powder product. Then Directly Packed. Chemical Reaction:

Disperse Blue 79

Water: 3750 Kg DNBrPNA: 525 Kg NSA: 555 Kg Ice: 1050 Kg Total: 5880 Kg


M- 5A: 585 Kg Caustic Lye: 188 Kg Water for Washing: 2250 Kg Total: 3023 Kg

Coupling with Filtration 8903 Kg

Water: 900 Kg Dispersing Agent: 1050 Kg Total: 1950 Kg

Slurry, Sand millig, Grinding, Formulation & Spray Drying

3150 Kg

ML to ETP: 7703 Kg

Water Evaporative In spray drying: 1650

Product: 1500 Kg

Enclosure: 9 Details of Water Consumption and Waste Water Generation

Application Water Consumption

(KL/Day)

Waste water generation

(KL/Day) Domestic 5 4 Gardening 30 0 Industrial Process 109.4 135.10 Washing 60 60 Boiler 50 5 Cooling 50 5 Scrubber 10 10 Total 314.4 219.10

Total Water consumption should be 314.4 KLPD. From which 5 KLPD for Domestic Purpose, 30 KLPD for Gardening purpose & 279.40 KLPD for Industrial Purpose. Total Waste water generation should be 219.10 KLPD. From which 4 KLPD domestic waste water will be goes to soak pit via septic tank. 215.10 KLPD waste water will generate from industrial purpose activity.

Product wise water consumption and waste water generation for Process only

Name of Product Batch Size (MT)

Monthly Production

(MT)

Nos of Batches

per month

Water Consumption

(KL/Batch)

Effluent Genreation (KL/Batch)

Water Consumption

(KL/Day)

Effluent Genreation

(KL/Day)

MUA 1.5

75

50 1.2 2.82 2.4 5.6 PAABSA 1.5 50 1.5 1.2 3.0 2.4 SPCP 1 75 7 9.11 21.0 27.3 N.W. Acid 2 38 17.5 27.66 26.3 41.5 Sodium Napthoniate 1.25 60 2 2.4 4.8 5.8

DASA 1.5 50 4.05 7.46 8.1 14.9 FC Acid 1.5 50 6 7.757 12.0 15.5 Sulpho VS 1.5 50 0 4.389 0.0 8.8 OAVS 1.5 50 2 5.812 4.0 11.6 K Acid 1.5 50 4.34 8.635 8.7 17.3 Reactive Black HN 1.5

120

80 1.39 0 4.4 0.0 Reactive Black WNN/R/G 1.5 80 1.461 0 4.7 0.0

Reactive Black 5 1.5 80 4.2 6.075 13.4 19.4 Reactive Blue BF 1.5 80 3 0 9.6 0.0 Reactive Blue M2GL 1.5 80 2.5 0 8.0 0.0

Reactive Golden Yellow HR 1.5 80 1.237 0 4.0 0.0

Reactive Orange H2R 1.5 80 5.767 2.881 18.5 9.2

Reactive Yellow 15 1.5 80 5.375 14 17.2 44.8 Reactive Yellow 18 1.5 80 4.4 0 14.1 0.0 Reactive Yellow FG 1.5 80 1.406 0 4.5 0.0 Reactive Golden Yellow MERL 1.5 80 1.795 0 5.7 0.0

Reactive Yellow ME4GL 1.5 80 1.417 0 4.5 0.0

Reactive Red ME4BL 1.5 80 1.1 0 3.5 0.0

Reactive Red RB 1.5 80 1.704 0 5.5 0.0 Direct Black 22 1.5 80 1.8 0 5.8 0.0 Direct Red 31 1.5 80 2.1 1.799 6.7 5.8

Direct Orange 39 1.5

80 6.6 4 21.1 12.8 Direct Yellow 86 1.5 80 5.2 5.376 16.6 17.2 Direct Yellow 11 1.5 80 2 0 6.4 0.0 Direct Violet 9 0.5 240 4.5 4.672 43.2 44.9 Direct Blue 86 1 120 2.2 2.65 10.6 12.7 Direct Blue FF 1.5 80 3.5 3.5 11.2 11.2 Acid Blue 193 1.5 80 4.25 0 13.6 0.0 Acid Brown 75 1.5 80 5.25 6.7 16.8 21.4 Acid Black 194 1.5 80 1.2 0 3.8 0.0 Acid Blue 113 1.5 80 4.5 5.5 14.4 17.6 Acid Green 68 1.5 80 5.2 5.5 16.6 17.6 Acid Red 131 1.5 80 5.5 0 17.6 0.0 Acid Yellow 36 1.5 80 4.5 8.1 14.4 25.9 Solvent Blue 36 1.5 80 0 0.168 0.0 0.5 Solvent Red 24 1.5 80 0.2 0 0.6 0.0 Solvent Yellow 33 1.5 80 4.166 2.428 13.3 7.8 Solvent Green 3 1.5 80 6.803 4.763 21.8 15.2 Tatrazine 1.5 80 2.55 1.649 8.2 5.3 Sunset Yellow 1.5 80 2.4 0 7.7 0.0 Chocolate Brown 1.5 80 5.25 3.795 16.8 12.1 Ponceau 4R 1.5 80 3 1.657 9.6 5.3 Acid Violet 90 1.5

75

50 8.7 6.696 17.4 13.4 Acid Black 210 1.5 50 2.622 7.955 5.2 15.9 Reactive Blue G 1.5 50 2.45 5.26 4.9 10.5 Reactive Oranage ME2RL 1.5 50 6.245 5.242 12.5 10.5

Disperse Blue 366 1.5

30

20 28.17 41 22.5 32.8 Disperse Orange 25 1.5 20 19.651 29.257 15.7 23.4

Disperse Yellow 211 1.5 20 28.17 40.997 22.5 32.8

Disperse Blue 79 1.5 20 6.9 7.703 5.5 6.2

Total Water Consumption: 109.4 KLPD Total Waste Water Generation: 135.10 KLPD

Water Balance Diagram

All Units are in KL/Day

Water 314.4

Domestic 5

Goes To Soak Pit via Septic Tank: 4

Gardening 30

Industrial 279.40

Process 109.4

W/w 135.10

Washing 60

W/w 60

Boiler 50

W/w 5

Scrubbing 10

Total Industrial effluent 215.1 goes to ETP &then finally discharged to MEE for Evaporation

W/w 10

Cooling 50

W/w 5

Enclosure: 10

Details of Effluent Treatment Plant

Sr.No. Name of Unit Quantity Nos. Capacity 1. Collection Tank 2 50 2. Neutralization Tank 2 50 3. Hoper Bottom Settling Tank 1 35 4. Sludge Drying Bed 4 ---- 5. Final Collection Tank 1 100

Enclosure: 11 Details of Flue Gas Emission and Process Gas emission system with APC System

Details of Flue Gas Emission

Details of Process Emission

Sr. No.

Stack attached To APCD System Stack

Height Pollutants

1 Reaction vessel Two Stage Scrubber system 11 m Hydrochloric Acid <= 20 mg/NM3

Cl2 <= 09 mg/NM3

2 Reaction vessel Two Stage Scrubber system 11 m NH3 <= 175 mg/NM3

3 Reaction vessel Two Stage Scrubber system 11 m SO2 <= 40 mg/NM3

4 Reaction vessel Scrubber system 11 m Hydrochloric Acid <= 20 mg/NM3

5 Reaction vessel Scrubber system 11 m SO2 <= 40 mg/NM3

6 Spray dryer Wet scrubber 11 m SPM <= 150 mg/NM3

Sr. No.

Stack attached To

Stack Height

In Meter APC System

Pollutants SPM

mg/NM3 SO2 ppm

NOX ppm

1. Steam Boiler – 1 (For Group1) (Capacity: 3 MT)

30 Multi Cyclone Dust

collector Followed By Bag Filter

< 150 mg/NM3

< 100 ppm < 50 ppm

2. Steam Boiler – 2 (For Group2) (Capacity: 3 MT)

30 Multi Cyclone Dust

collector Followed By Bag Filter

< 150 mg/NM3

< 100 ppm < 50 ppm

3. Hot Air Generator (10 lacs Kcal) 30

Multi Cyclone Dust collector Followed By

Bag Filter

< 150 mg/NM3

< 100 ppm < 50 ppm

4. DG Set 11 --- < 150 mg/NM3

< 100 ppm < 50 ppm

Fuel Requirement

Sr. No. Stack attached To Stack Height In Meter Type of Fuel Quantity APC System

1. Steam Boiler - 1 (Capacity: 3 MT) 30

Coal/ lignite/ wood/ agro

waste/ 7 MT/Day

Multi Cyclone Dust collector

Followed By Bag Filter

2. Steam Boiler - 2 (Capacity: 3 MT) 30


waste/ 7 MT/Day



3. Hot Air Generator - 1 (10 lacs Kcal) 30


waste/ 4.8 MT/Day



4. DG Set 11 Diesel 20 Liter/hr. ---

Enclosure: 12

Details of Hazardous Waste Generation with its Management

Sr. No Type of Hazardous Waste

Cat. No. Quantity Management

1.

ETP Sludge

35.3

600 MT/Year

Collection, Storage, Transportation, Disposal to TSDF site

2.

Iron Sludge

B1

1530

MT/Year

Collection, Storage, Transportation, Disposal to TSDF site or Actual recycler.

3 Spent Acid 26.3 787.5 MT/Month

Collection, Storage, Transportation, Disposal to Spent Acid management site or sell to Actual recycler.

4. Process waste 26.1 3.6 MT/Month

Collection, Storage, Transportation, Disposal by selling to actual users

5.

Discarded Bags/Containers/Drums

33.1

10000-15000

Nos./Year

Used for packing of ETP waste or return back to supplier.

6.

Used Oil

5.1

20 Liter/Year

Storage into carboys and ultimately Reuse or sell to registered re refiners

Enclosure: 13

Name and Address of Partners

Sr. No. Name of Partners Residential Address

1. Jignesh Jayesh Bhimani D-1/2, Kailash Tower, Stadium Road, Navarangpura, Ahmedabad-380009

2. Bhavin Jayesh Bhimani D-1/2, Kailash Tower, Stadium Road, Navarangpura, Ahmedabad-380009

3. Parin Jayesh Bhimani D-1/2, Kailash Tower, Stadium Road, Navarangpura, Ahmedabad-380009

Enclosure: 14

Land Supporting Document

(Attached)

Enclosure: 15

Site Plan and Layout Plan

(Attached)

Bhimani Dyechem industries Office : 507 Mahakant, Opp. V. S. Hospital, Ellisbridge, Ahmedabad – 380006, INDIA

Factory : Plot # 2, Survey # 316, B/H Virat Industrial Estate, Village – Dhanot, Kalol, Gandhinagar, INDIA

Phone : +91 - 79 – 26575474 ● E-Mail : [email protected] ● Web : www.bhimanigroup.com

PLANT LAYOUT

Enclosure: 16

Valuation Certificate

(Attached)

Enclosure: 17

MSME Copy

(Attached)

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