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ELECTRONIC SUPPLEMENTARY INFORMATION

Small molecule-based photocrosslinkable fluorescent materials toward

multilayered and high-resolution emissive patterning

Simon Olivier,ab Lionel Derue,c Bernard Geffroy,c Tony Maindron,b Eléna Ishow*a

aCEISAM–UMR CNRS 6230, Université de Nantes, 2 rue de la Houssinière, 44322 Nantes,

France. bCEA LETI, LETI/DOPT/SCOOP/LCV, Minatech Campus, 17 rue des Martyrs, 38054

Grenoble, France. cCEA Saclay, IRAMIS (UMR CNRS 3685), LICSEN, F-91191 Gif-sur-Yvette,

France. LPICM-UMR CNRS 7647, Ecole Polytechnique, Route de Saclay, 91128 Palaiseau,

France.

CONTENT

1. Diffential Scanning Calorimetry thermograms

Electronic Supplementary Material (ESI) for Journal of Materials Chemistry C.This journal is © The Royal Society of Chemistry 2015

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Figure S1. DSC thermograms for compounds 7 and 8 on the [-30; 140] °C temperature range

using a 30 °C.min-1 thermal gradient.

2. AFM imaging of stacked photopatterns

a)

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b)

Figure S2. AFM images of thin films 7 (a) and 8 (b) containing 3 mol. % TPO before irradiation,

after irradiation (exc = 365 nm with a 6.3 J.cm-2 exposure dose), and after development. A) Phase

contrast, and B) topography images.

Figure S3 AFM images of a stacked bilayer obtained after successive deposition,

photoirradiation and development of solution of red emitter 8 and green emitter 7 containing 3

mol. % TPO (exc = 365 nm with a 0.026 J.cm-2.cm-2 exposure dose).