Minutes of the 596th Minutes of the 596th I.pdf596th meeting of SEAC-Gujarat, dated 11.02.2020 Page...

596th meeting of SEAC-Gujarat, dated 11.02.2020

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Minutes of the 596th meeting of the State Level Expert Appraisal Committee (SEAC) held on

11/02/2020 at Committee Room, Gujarat Pollution Control Board, Sector 10A, Gandhinagar.

The 596th meeting of the State Level Expert Appraisal Committee (SEAC) was held on 11th February 2020

at Committee Room, Gujarat Pollution Control Board, Sector 10A, Gandhinagar. Following members

attended the meeting:

1. Dr. Dinesh Misra, Chairman, SEAC

2. Shri S. C. Srivastav, Vice Chairman, SEAC

3. Shri V. N. Patel, Member, SEAC

4. Shri. R. J. Shah, Member, SEAC

5. Dr. V. K. Jain, Member, SEAC

6. Shri A. K. Muley, Member, SEAC

The regular agenda of Appraisal, Screening & Scoping cases were taken up. The Committee considered the

applications made by project proponents, additional details submitted as required by the SEAC/SEIAA and

details furnished in the Form-1, PFR, EIA-EMP reports.

Proposal No. Name and Address of the Unit Remarks

7 SIA/GJ/IND2/47515/2019 M/s. Nexus Pharmachem Pvt. Ltd

Plot No- 25/1, Phase-III, GIDC Naroda,

Ahmedabad.

Appraisal

Category of the unit: 5(f)

Project status: Expansion

Project proponent (PP) has submitted online application vide no. SIA/GJ/IND2/47515/2019 on dated

18/01/2020 for obtaining Environmental Clearance.

The SEAC had recommended TOR to SEIAA and SEIAA issued TOR to PP vide their letter dated

04/11/2019.

Project proponent has submitted EIA Report prepared by Entech Laboratories, Ahmedabad based on the

TOR issued by SEIAA.

This expansion unit proposes for manufacturing of synthetic organic plant tabulated as below:

Sr.

no.

Name of the

Products

CAS

no. /

CI no.

Quantity

MT/Month

End-use of the products

Existing

Proposed Total


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1 Dexamethasone

Sodium Phosphate

2392-

39-4

0.4

-0.4 0 Corticosteroid to treat various

conditions such as severe

allergic

reactions, arthritis, treatment

for cancer, etc.

2 Betamethasone

Sodium Phosphate

151-73-

5

Corticosteroid used for a

number of diseases including

rheumatic disorders, skin

diseases, etc.

3 Prednisolone

Sodium Phosphate

302-25-

0

Corticosteroid used to treat

conditions such as arthritis,

immune system disorder,

hematologic disorder,

skin and eye conditions,

4 Betamethasone

Dipropionate

5593-

20-4

Corticosteroid used to treat a

variety of skin conditions

5 Betamethasone

Valerate

2152-

44-5



6 Clobetasole

Propionate

25122-

46-7



7 Clobetasole

Butyrate

25122-

57-0

treatment for a variety of

conditions such as eczema,

psoriasis, various forms of

dermatitis

8 Prednisolone

Acetate

52-21-1 Corticosteroid used to treat

certain eye conditions due

to inflammation or injury

9 Baclomethaneson

e Dipropionate

05534-

09-8

Corticosteroid used to prevent

and control symptoms caused

by asthma

10 Potassium Nitrate 7757-

79-1

0.25 0 0.25 Used in toothpastes

11 Potassium

Carbonate

584-08-

7

0.25 0 0.25 Raw material in

pharmaceutical industry

12 Magnesium 546-93- 0.25 0 0.25 High purity magnesium

https://www.webmd.com/arthritis/default.htm

https://www.webmd.com/skin-problems-and-treatments/picture-of-the-skin

https://www.webmd.com/eye-health/picture-of-the-eyes




https://www.webmd.com/eye-health/picture-of-the-eyes

https://www.webmd.com/arthritis/about-inflammation

https://www.webmd.com/asthma/default.htm


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Carbonate 0 carbonate is used as an

antacid

13 Magnesium

Hydroxide

1309-

42-8

0.25 0 0.25 Used as a laxative and

antacid

14 Deflazacort 14484-

47-0

0 2 2 Corticosteroid used as an

anti-inflammatory and

immunosuppressant

15 Methyl

Prednisolone

Acetate

53-36-1 Corticosteroid medication

used to treat pain and

swelling that occurs

with arthritis and other joint

disorders.

16 Hydrocortisone

Acetate

50-03-3 Corticosteroid that reduces

redness, itching, and swelling.

17 Methylprednisolon

e

83-43-2 Corticosteroid medication

used to suppress the immune

system and decrease

inflammation.

18 Hydroxyprogestero

ne Caproate

630-56-

8

Is a man-made progestin

hormone. It is used in

pregnant women to help lower

the risk of preterm birth.

Total 1.4 1.6 3.0

Note: Currently, project has CCA for production of 9 organic products of steroids with combined production

capacity as 0.4 MT/Month and 4 inorganic products each having production capacity of 0.25 MT/Month.

Existing organic products could not be manufactured without solvent, water, wastewater, emissions etc. but the

same was not mentioned earlier CCA. As unit was purchased by Nexus in 2017 and pollution load was not

mentioned in current CCA unit has decided to surrender all existing organic products. Unit was purchased by

Nexus in 2017; after these organic products are not manufactured by Nexus.

Products are/will be for sell purpose as well as for utilization in captive consumption.

The project falls under Category B of project activity 5(f) as per the schedule of EIA Notification 2006.


PP was called for presentation in the SEAC meeting dated 11/02/2020.

Salient features of the project are as under:

Sr. no. Particulars Details

https://www.webmd.com/arthritis/default.htm

https://www.webmd.com/pain-management/guide/joint-pain


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A Total cost of Proposed Project

(Rs. in Crores):

Existing: 4.5971

Proposed: 2.63

Total: 7.2271

Details of EMP

Sr.

No. Particulars

Capital

Cost

(Rs. in

Lacs)

Operating

Cost (Lacs/

Annum)

Maintenance

Cost (Lacs/

Annum)

Total

Recurring

Cost (Lacs/

Annum)

Remarks

1. Air Pollution

Control

2 0.75 0.25 1 New activated

carbon column

for process

stack.

Changing of

carbon.

2. Water Pollution

Control

1.5 0.35 0.10 0.45 Expansion of

ETP. Rain

water collection

& reuse.

Disposal of

additional

wastewater to

Common MEE.

3. Noise Pollution

Control

0.5 0.015 0.005 0.02 Vibration pads

to new

machinery.

4. Solid and

Hazardous Waste

Management

0.765 0.75 0.25 1 Disposal of

hazardous

waste to TSDF

& CHWIF.

5. Occupational

Health

2.53 0.2 0.4 0.6 PPE’s for new

staff. Fire

fighting

equipments in


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new building.

Medical

checkups of

new employee.

6. Ecology &

Biodiversity

0.705 0.1 0.2 0.3 Greenbelt

outside

premises &

conservation of

peacock

Total 8 2.165 1.205 3.37

Details of CER as per OM dated 01/05/2018

A total amount of Rs. 2.63 lacs would be utilized for CER programme for Three years as per OM no. 22-

65/2017 on 01.05.2018. Total 1.0% of the proposed additional project cost is Rs. 2.63 Crore and company

would to identify stake holders for the planning of CER activities and implementation of it.

B Total Plot area

( sq. meter)

Existing: 2009 Sq. m.

Proposed: 0.0 Sq. m.

Total: 2009 Sq. m.

Green belt area

( sq. meter)

Existing: 225 Sq. m.

Proposed: 380 Sq. m.*

Total: 225 Sq. m.

* Proposed greenbelt

area will be developed

within GIDC premises.

C Employment generation Existing: 15

Proposed: 10

Total: 25

D Water

i

Source of Water Supply

(GIDC Bore well, Surface water, Tanker supply etc...)

GIDC Bore well

Status of permission from the concern authority.

Permission has been

obtained from GIDC


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ii

Water consumption (KLD)

Existing

KLD

Revised

Existing (After

discontinued

products)

KLD

Proposed

(Additional)

KLD

Total after

Expansion

KLD

Remarks

(A) Domestic 0.829 -0.700 1.320 1.449

(B) Gardening

0.371 0.000 0.000 0.371 Sufficient

land is

not

available

to

develop

33%

greenbelt

hence

unit will

develop

380 m2

greenbelt

within

GIDC

(C) Industrial

Process 0.150 0.000 7.617 7.767 As RO

permeate

is used in

process

quantity

of

process

water is

not

consider

ed in

total


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water

consump

tion

Washing 0.250 0.000 0.100 0.350

Boiler

Cooling 0.055 -0.020 18.445 18.480

Others-scrubber 0.005 0.000 0.000 0.005

Others-RO Plant for

Process water

0.495 -0.495 11.095 11.095 Permeat

e to

reject of

existing

RO plant

ratio is

30% to

70%, i.e.

reject is

more

than

permeate

hence

existing

RO plant

will be

replaced.

Industrial Total 0.805 -0.515 29.640 29.930

Grand Total (A+B+C) 2.005 -1.215 30.960 31.750

1) Total water requirement for the project: 31.75 KLD

2) Quantity to be recycled: 0 KLD

3) Total fresh water requirement: 31.75 KLD

(Total water requirement = Fresh water + Recycled water)

iii

Waste water generation (KLD)

Category Existing

KLD

Revised

Existing (After

Proposed

(Additional)

Total

after

Remarks


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discontinued

products)

KLD

KLD Expa

nsion

KLD

(A) Domestic

0.805 -0.700 1.122 1.227

(B) Industrial

Process 0.000 0.000 8.573 8.573 High COD

wastewater

to common

incineration

facility

1.385 0.000 0.000 1.385 Actual low

COD

wastewater

generation

from

existing

products is

0.227 KL/d

and that

from

proposed

products is

0.922 KL/d

hence total

wastewater

generation

after

expansion

will be 1.138

KL/d which

less than

the existing

permission.


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Washing 0.250 0.000 0.100 0.350

Boiler

Cooling 0.000 0.000 6.160 6.160

Others-scrubber 0.020 0.000 0.000 0.020

Others-RO reject 0.345 -0.345 3.329 3.329 Permeate to

reject of

existing RO

plant ratio is

30% to

70%, i.e.

reject is

more than

permeate

hence

existing RO

plant will be

replaced

Total Industrial waste

water

2.000 -0.345 18.162 19.81

7

iv Treatment facility within premises with capacity

[In-house ETP (Primary, Secondary, Tertiary), MEE, Stripper, Spray Dryer, STP etc.

Primary

Treatment scheme including segregation at source. (Give Characteristics of each stream i.e.

COD, BOD, TDS etc.)

High COD wastewater shall be sent to Common incineration facility while Low COD to

common MEE/ spray dryer after treatment in in-house ETP

Note: (In case of CETP discharge) :

Management of waste water keeping in view direction under section 18 (1) (b) of the Water

(Prevention and Control of Pollution) act, 1974 issued by CPCB regarding compliance of

CETP.

Not applicable

Brief note on adequacy of ZLD (In case of Zero Liquid Discharge):

Not applicable


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v Mode of Disposal & Final meeting point

Domestic:

to Septic tank followed by soak pit

Industrial:

Low COD to to common MEE/ spray dryer

after treatment in in-house ETP.

High COD to common incineration facility.

vi In case of Common facility (CF) like CETP, Common Spray dryer, Common MEE, CHWIF etc.

Name of Common facility (CF)(For waste water treatment)

Spray dryer of NEPL

Sanand Eco Project

Membership of Common facility (CF)

(For waste water treatment)

NEPL vide letter dated 15.12.2017

SEPL vide letter no. SEPL/MBR/18-19 dated 02.05.18

vii Simplified water balance diagram with reuse / recycle of waste water


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vii Reuse/Recycle details (KLD)

[Source of reuse & application area]

Total reuse 0 KLD

-

Source of waste

water for reuse

with quantity in

KLD (From where it

is coming)

Application area

with quantity in

KLD (Where it is

used)

Characteristics of waste

water to be reused (COD,

BOD, TDS etc.)

Remarks

regarding

feasibility to

reuse i.e.

E Air

i Flue gas emission details


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No. of Boilers/TFH/Furnaces/DG sets etc. with capacities viz. TPH, Kcal/hr, MT/hr, KVA etc.

Existing & Proposed

-

Sr.

no.

Source of

emission

With

Capacity

Stack

Height

(meter)

Type

of

Fuel

Quantity

of Fuel

MT/Day

Type of

emissions

i.e. Air

Pollutants

Air

Pollution

Control

Measures

(APCM)

Remarks

Existing

1

D.G.Set

(20 kVA x

1 no.)

11 Diesel 0.1

PM

SO2

NOx

Adequate

Stack

Height

None in proposed

-

ii Process gas i.e. Type of pollutant gases (SO2, HCl, NH3, Cl2, NOx etc.)

Existing & Proposed

-

Sr.

no.

Specific Source of

emission

(Name of the Product

&Process)

Type of

emission

Stack/Vent

Height

(meter)

Air Pollution

Control

Measures

(APCM)

Remarks

Existing

1

Common stack attached

to reaction vessel of

Potassium carbonate &

magnesium carbonate

CO2 11 Water

scrubber

followed by

adequate

stack height

2



Potassium nitrate &

magnesium carbonate

VOC 11 Carbon

column

followed

by

adequate

APCM

mention

ed is wet

scrubber

for


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stack

height

scrubbin

g of PM.

Actual

pollutant

is VOC

due to

solvents

like

toluene

& IPA

hence

carbon

column

is

required

as

APCM.

Proposed

1



Deflazacort, Methyl

Prednisolone Acetate,

Hydrocortisone Acetate,

Methylprednisolone,

Hydroxyprogesterone

Caproate

VOC 11 Carbon

column

followed

by

adequate

stack

height

-

iii Fugitive emission details with its mitigation measures.

To control fugitive emissions in form of particulate matter following measures are being adopted

to ensure compliance and further reductions wherever possible, the same will be continued after

expansion:

The coverage of greenbelt around the plant consisting of air pollution capturing species.

The drums are being stored in separate storage area. Manual handling is avoided as far as

possible.

Proper ventilation is provided for dispersion.


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Good housekeeping is maintained in the plant.

The open area is covered with either greenbelt or paved surface to avoid dust during

transportation within plant.

F Hazardous waste

(As per the Hazardous and Other Wastes (Management and Transboundary Movement) Rules

2016.

Existing & Proposed

i

Sr

.

n

o.

Type/N

ame of

Hazard

ous

waste

Specific

Source of

generation

(Name of the

Activity,

Product etc.)

Categ

ory

and

Sche

dule

as per

HW

Rules

.

Quantity

(MT/Annum)

Manageme

nt of HW

Remarks

Exist

ing

Revised

Existing

(After

disconti

nued

product

s)

Propo

sed

Tota

l

1 ETP

Sludge

In-house ETP Sch.-I

& Cat.

-35.3

5.00

0

0.000 5.000 10.0

00

Collec

tion,

storag

e,

transp

ortatio

n and

dispo

sal to

TSDF

for

Land

filling

In existing

CCA, ETP

Sludge

quantity

mentioned

is 5

MT/Annum

but actual

quantity

generated

is 1.74

MT/Annum.


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2 Used

oil

Plant &

Machinery

Sch.-I

& Cat.

-5.1

0.00

9

-0.005 0.020 0.02

4

Collec

tion,

storag

e,

transp

ortatio

n and

dispo

sal by

selling

to

author

ized

recycl

er

3 Discard

ed bags

and

contain

ers

Raw material

storage area

Sch.-I

& Cat.

-33.1

75.0

0

-45.00 1896.

00

192

6.00

Collec

tion,

storag

e,

transp

ortatio

n and

dispo

sal to

author

ized

decon

tamin

ator


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4 Recove

red

Solvent

s

Distillation

column

attached with

reaction

vessel-1

(potassium

nitrate,

magnesium

carbonate)

and

Distillation

column

attached with

reaction

vessel-2, 3 &

4

(Deflazacort,

Methyl

Prednisolone

Acetate,

Hydrocortison

e Acetate,

Methyprednis

olone &

Hydroxproges

terone

Caproate)

- 5.68

5

0.000 1066.

581

107

2.26

6

Existi

ng

collect

ion,

storag

e,

transp

ortatio

n and

dispo

sal to

CHWI

F for

incine

ration

Propo

sed

collect

ion,

storag

e &

reuse

in

next

batch

In existing

CCA

recovered

solvents

(5.685

MT/Annum)

and

distillation

residue

(0.315

MT/Annum)

from

distillation

column

attached

with reactor

of

potassium

nitrate,

magnesium

carbonate

is

mentioned

under

distillation

residue.

Quantity is

now

bifurcated

in

appropriate

category.

5 Distillati

on

Residu

e

Distillation

column

attached with

reaction

Sch.-I

& Cat.

-36.1

0.31

5

0.000 15.16

2

15.4

77

Collec

tion,

storag

e,

In existing

CCA

recovered

solvents


of 174

vessel-1

(potassium

nitrate,

magnesium

carbonate);

and reaction

vessel-2, 3 &

4 (Methyl

Prednisolone

Acetate,

Hydrocortison

e Acetate)

transp

ortatio

n and

dispo

sal to

CHWI

F for

incine

ration

(5.685

MT/Annum)

and

distillation

residue

(0.315

MT/Annum)

from

distillation

column

attached

with reactor

of

potassium

nitrate,

magnesium

carbonate

is

mentioned

under

distillation

residue.

Quantity is

now

bifurcated

in

appropriate

category;

In existing

CCA total

quantity of

recovered

solvent and

distillation

residue is

mentioned


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as solvent

residue

under Sch.-

I category

28.6. Also

mode of

disposal in

TSDF

which is not

possible

hence

necessary

changes

have been

made.

6 Spent

Catalys

t &

carbon

Deflazacort,

Methyl

Prednisolone

Acetate,

Methylprednis

olone,

Hydroxyproge

sterone

Caproate

Sch.-I

& Cat.

-28.2

& 28.3

0.00 0.00 10.28

6

10.2

86

Collec

tion,

storag

e,

transp

ortatio

n and

dispo

sal to

CHWI

F for

incine

ration


of 174

7 Spent

carbon

or filter

medium

Carbon

scrubber

attached to

stack of

reaction

vessel-1 and

Carbon

scrubber

attached to

common

stack of

reaction

vessel-2, 3 &

4

Sch.-I

&

Cat.-

36.2

4.80 0.00 108.0

0

112.

800

Collec

tion,

storag

e,

transp

ortatio

n and

dispo

sal to

CHWI

F for

incine

ration

In existing

CCA this is

mentioned

as process

residue

under Sch.-

I category

28.1. Also

mode of

disposal in

TSDF

which is not

possible

hence

necessary

changes

have been

made in EC

application.

8 Scrubb

er

bleed

containi

ng

H2CO3

Water

scrubber

attached to

stack of

reaction

vessel-1

- 7.20 0.00 0.00 7.20 to

ETP

for

furthe

r

treatm

ent

-

ii Membership details of TSDF, CHWIF etc.

(For HW management)

Member of Eco-Care TSDF.

Membership no. ECIPL-1287

dated 19-02-19 valid till18-02-

2022.

Provisional Member of SEPPL

CHWIF.

Membership no.

SEPPL/1000100468/201-20/160

dated 25.01.2020 valid till


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25.06.2020

iii Details of Non-Hazardous waste & its disposal(MSW and

others)

None.

G Solvent management, VOC emissions etc.

i Types of solvents, Details of Solvent recovery, % recovery, reuse of recovered Solvents etc.

(Details in Table Format)

Name of the

Product

Name of the

Solvent

Solvent

consume

d in

process

(MT/

Month)

Recovere

d Solvent

(MT/

Month)

Distillati

on

Residue

(MT/Mont

h)

%

Recov

ery

Use of

Recove

red

Solvent E T E T E T

Potassium

Nitrate

Toluene 0.4

1

0.41 0.3

7

0.37 0.0

2

0.0

2

90.00% to

CHWIF

Magnesium

Carbonate

IPA 0.1

3

0.13 0.1

1

0.11 0.0

1

0.0

1

90.00%

Deflazacort Acetone - 39.4

3

- 35.4

9

- - 90.00% Reuse

in next

batch Methanol - 17.7

8

- 16 - - 90.00%

Methylene

Dichloride

- 11.8 - 10.6

2

- - 90.00%

Methyl

Prednisolone

Acetate

Methanol - 15.2

4

- 13.7

1

- 1.2

6

90.00%

Methylene

Dichloride

- 12.6

4

- 11.3

7

90.00%

Hydrocortison

e Acetate

Methanol - 4.52 - 4.29 - 0.2

2

95.00%

Methylprednis

olone

Methanol - 20 - 18 - - 90.00%

Methylene

Dichloride

- 13.2

7

- 11.9

4

- - 90.00%

Acetone - 65.4 - 58.9 - - 90.00%


of 174

9 4

Hydroxyproge

sterone

Caproate

Methylene

Dichloride

- 8.85 - 7.96 - - 90.00%

Di isopropyl ether - 2.42 - 2.18 - - 90.00%

ii VOC emission sources and its mitigation measures

Following measures are being followed to ensure compliance and further reductions wherever

possible; the same will be continued after expansion.

The fugitive emissions in terms of handling losses are reduced by proper storage and

handling.

Hazardous chemicals are stored as per standard criteria.

Periodically monitoring is carried out as per the existing monitoring plan.

Proper ventilation in storage & production area is provided and all materials are being stored

in suitable packing to prevent contamination of air due to particulates & volatile emissions

from storage container & area.

Enclosed system & efficient procedures for materials charging is provided.

SOP’s for start-up, shut down, operation & maintenance are established & maintained in all

relevant area of works.

Brine chilled condensers are provided in solvent recovery units (SRU). These SRU are closed

system.

H Details regarding storage of Hazardous chemicals

Storage details Name of major Hazardous chemicals Remarks

Storage tanks None

Drum/Barrel storage

17 Alpha Hydroxy Progesterone, Acetic Acid

Acetic Anhydride, Acetone, D-5 Intermediate,

Di isopropyl ether, Dimethyl Formamide,

Hydrocortisone Base, Methanol,

Methylprednisolone base, Methylene

Dichloride, N-Caproic Anhydride, Nitric Acid

(20%), P-1 Intermediate, Pyridine, Toluene,

Tri Ethyl Amine

PVC, Corrugated

Fiber or HDPE

drums of 10, 25,

150, 200, 250 lit

capacity

bags

Activated Carbon, Alumina oxide, Calcium

Chloride lump anhydrous, Calcium Oxide,

Hyflo, Iodine, Magnesium Hydroxide,

Magnesium Sulphate, Potassium Acetate,

Potassium Chloride, Potassium hydroxide

PP/ HDPE bags of

25, 40, 50 kg

capacity

Cylinder Ammonia gas & Carbon Dioxide SS or MS cylinder


of 174

of 7 & 50 kg

capacity

Can Isopropyl Alcohol HDPE can of 40 kg

capacity

Applicability of PESO :

Permission from PESO will be obtained

During the meeting dated 11/02/2020, technical presentation made by project proponent.

The baseline environmental quality has been assessed for various components of the environment viz. air,

noise, water, biological and socioeconomic aspect. The baseline environmental study has been conducted for

the study area of 10 km radial distance from project site for the period March to May 2019. Ambient Air

Quality monitoring was carried out for PM10, PM2.5, SO2, NOx, CO & VOC at eight locations, including the

project site. Values conform to the prescribed standards for Ambient Air Quality. The incremental Ground

Level Concentration (GLC) has been computed using ISCST3. The resultant concentrations are within the

NAAQS.

Risk assessment including prediction of the worst-case scenario and maximum credible accident scenarios

has been carried out. The detail proposed safeguard measures including On-Site / Off-Site Emergency Plan

has been covered in the RA report.

During SEAC meeting on 11/02/2020, committee noted that the proposal is for expansion. This unit has valid

CC&A for existing unit. Copy of CC&A, its compliance report is submitted. PP ensured that there are no

court cases pending and no public complaints against the project. Source of water is GIDC. PP mentioned

that high COD effluent generated from process will be sent common spray dryer of Sanand Eco Project,

Sanad while Low COD effluent generated from process, washing, boiler blow down, cooling tower blow

down & scrubber will be treated in ETP consisting of primary treatment and treated effluent will be sent to

common MEE/Spray Dryer of Naroda Enviro Projects Ltd, Naroda. Committee noted that PP has not

submitted membership certificate of common facility in-line with the direction given by GPCB vide Letter No.

GPCB/P-1/8-G (5)/550706 dated 08/01/2020 and asked to submit the same. PP mentioned that there is no

fuel requirement in the proposed project. Committee noted that PP has not address LDAR satisfactorily.

Committee noted that PP has addressed Hazardous Waste as per HWR – 2016.

After detailed discussion, it was decided to consider the proposal only after submission of the

following documents:

1. Membership Certificate from Common Facility (mentioning total capacity, consented quantity, occupied

capacity and spare capacity and norms of acceptance of effluent from member units) in-line with the

direction given by GPCB vide Letter No. GPCB/P-1/8-G (5)/550706 dated 08/01/2020.

2. Leak Detection and Repairing Programme (LDAR) for all the solvents/volatile organic chemicals proposed

with detailed chemical properties including vapor pressure. LDAR with all mitigation measures shall endeavor


of 174

prevention of losses of solvents/Volatile organic compounds to the best minimum extent.

8 SIA/GJ/IND2/35602/2014 M/s. Vithal Castor Polyols Pvt Ltd

PLOT No. 26/A, GIDC Jhagadia, Bharuch.

Appraisal






23/08/2019.

Project proponent has submitted EIA Report prepared by M/s. Siddhi Green Excellence Pvt Ltd, Ankleshwar

based on the TOR issued by SEIAA.


Sr.

No

Name of the Product CAS No. /

HSN code

Quantity (MT/Annum) End-use of the

Products Existing Proposed Total

Group -A

1. Various Polyester

Polyols e.g. EBT -

500, 501, 509 & 320

29161950 4320 9625 13945 As Polyols in

Automobiles, furniture,

mattresses, etc.

2. EST-2408/2070/650 39079990


Polyols like AK7001

39079990 0 2600 2600


Polyols like ES257

39079990


Polyols like ES258

39079990


Polyols like GP400

39079990


Polyols like PES295

39079990

Group -B


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8. Fatty Acid 38231900 1680 1129 2809 Intermediate,

Cosmetics, lubricants

Group -C

9. Trimethylolpropane

trihepatanoate-

(Jagrolubes-13)

78-16-0 1380 19245 20625 Intermediate,

Plasticizers,

Lubricants, Cosmetics,

Coatings, Inks, textiles 10. Poly(Pentaerythritol

adipate,

ethylhexanoate-

(Jagrolubes-26)

Polymer

HS 39079990

11. Pentaerythritol

tetrapelargonate-

(Jagrolubes-32)

14450-05-6

12. Poly(Trimethylolpropa

ne adipate,

pelargonate)-

(Jagrolubes-220)

Polymer

HS 39079990

13. Poly(Glycerol

dimerate, 2-

octanoate)-

Jagrolubes-ODE and

isomers

Polymer HS

3909990

14. 2-octyl

poly(ricinoleate) -

Jagrolubes-OPR and

isomers

HS 3909990

15. 2-ethylhexyl

poly(ricinoleate) -

Jagrolubes-EPR and

isomers

HS 3909990

16. 2-ethylhexyl

poly(hydroxy

29710-25-6


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stearate) -

Jagrolubes-RH and

isomers

17. Capryl Benzoate-

(Jagroplast-CB) and

isomers

6938-51-8

18. Dicapryl Phthalate -

(Jagroplast- DCP)

and isomers

2917 39 20

CAS

131-15-7

19. Dicapryl Sebacate-

(Jagroplast-DCS) and

isomers

10340-41-7 or

122-62-3 or

2432-87-3

20. Dicapryl Adipate-

(Jagroplast DCA) and

isomers

2917 12 00

CAS

108-63-4 or

103-23-1

Or

123-79-5

21. Dicapryl terephthalate

and isomers

6422-86-2 or

4654-26-6

0 20625

22. Dicapryl cyclohexane

dicarboxylate ester

and isomers

84731-70-4 or

1140919-37-4

or

519054-50-3

or 53807-

76-4

23. Capryl fatty acid 135800-37-2


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esters e.g. Jagrolube

8F and isomers

24. Dicapryl furan

dicarboxylate esters

and isomers

3319-31-1 or

89-04-3

25. Calcium Ricinoleate 6865-33-4

26. Dicapryl Itaconate 2287-83-4

27. 2-octyl Glycidyl Ether 2461-15-6

28. Sodium Ricinoleate 5323-95-5

29. Sodium Sebacate 17265-14-4

30. Tricapryl Trimellitate 27251-75-8

31. Zinc Ricinoleate 13040-19-2

Group -D

32. Dimethyl Sebacate 106-79-6 900 3812 4712 Plasticizer/intermediate

33. Dibutyl Sebacate 109-43-3 Plasticiser

Group -E

34. 2-Octyl Ricinoleate

(Jagrocos-OR)

HS 3909990

93980-66-6

5400 10165 15565 Emollient/Plasticiser/lu

bricant

35. Cetyl Ricinoleate

(Jagrocos-CR)

10401-55-5 Emollient/Plasticiser/lu

bricant

36. 2-Ethyl Hexyl

Ricinoleate

(Jagrocos-ER)

HS 3909990 Emollient/Plasticiser/lu

bricant

37. 2-Octyl

Hydroxystearate

(Jagrocos-OHS)

29710-25-6 Intermediate,

Plasticizers,


Coatings, Inks, textiles

38. Cetyl HSN 29157040 Intermediate,


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Hydroxystearate

(Jagrocos-CHS)

Plasticizers,



39. 2-Ethyl Hexyl

Hydroxystearate

29383-26-4 Intermediate,

Plasticizers,



40. Methyl Ricinoleate 141-24-2 0 15565 Emollient/Plasticiser/lu

bricant/ Intermediate

41. Zinc, Calcium and

Sodium salts of

Ricinoleates,

sebacates and fatty

acids

13040-19-

2/6865-33-

4/5323-95-

5/17265-14-4

Stabilizer/Corrosion

inhibitors/ Emulsifiers /

lubricants/

intermediates

42. Vegetable oil based

glycidyl ethers e.g.

Jagroxy - 505 etc.

74398-71-3 0 2469 2469 Epoxy Diluents &

modifiers / Plasticizers

/ intermediates

Group –E (Total) 5400 18034

43. Methanol 67-56-1 0 1214

(generated

from Sr.34 to

39)

1214 Used as antifreeze,

solvent, and as a

denaturant for ethanol.

44. Glycerine Lye 56-81-5 0 3057

(generated

from Sr.

no.40)

3057 Used in Cosmetics

TOTAL 13680 66996

Note: High Potash Organic Ash (consented quantity: 50 MT/M) is removed from the product list and considered

in Hazardous Waste/Non- Hazardous Waste table.





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Sr.

no

.

Particulars Details


(Rs. in Crores):

Existing: 30

Proposed: 102.18

Total: 132.18

Details of EMP

COMPONENT ADDITIONAL CAPITAL COST

OF EMP

RECURRING COST OF EMP

(per month)

TOTAL COST Rs. 89 Lakh Rs. 22.76 Lakh

Bifurcation of EMP Cost

Sr.

No. Particulars Capacity

Additional

Capital

Cost (Rs.

in Lakh)

Operating

Cost (Lakh

/ month)

Maintenance

Cost (Lakh /

month)

Total

Recurring

Cost (Lakh

/ month)

1

Effluent

Treatment

Plant

Effluent drainage

network,

drains around

plants and

storages, RO

plant

augmentation,

recycle effluent

storage facility,

sewage effluent

drainages

65 4.5 0.5 5

2 APCM

Multicyclone

separators,

bagfilters, water

scrubber,

Installation of

stacks with

platform and

sampling

arrangements,

7 0.378 0.042 0.42


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local exhaust

and dust

collector systems

3

Hazardous

waste

management

91 sq. m. (0.36

% of total plot

area)

4 14.22 1.58 15.8

4

AWH

Monitoring Cost

+ Noise

Pollution

control + Green

belt

Enhancement

& maintenance

+ occupational

health & safety

-- 13 1.35 0.15 1.5


As per OM no. 22-65/2017 on dated 01/05/2018 regarding “Corporate Environment Responsibility” (CER),

Brownfield projects having investment > 100 crore have to contribute 0.75% of Capital Investment.

Accordingly proponent has committed to allocate Rs. 77 lakh for CER activities to be conducted after the

project is operational .

Component As per Norms Allocation

CER 76.2 lakh 77 Lakh

Activities to be carried out under CER:

Health : maintenance, repair and replacement of RO plants

Environment : plantation along village periphery and schools

Solar Electrification through Solar Street Lights and solar heating systems

Sanitation : Up-gradation of sanitation facility- Toilet blocks & infrastructure development

Infrastructure development : construction of approach roads and pucca internal roads

B Total Plot area

( sq. meter)

Existing: 25200

Proposed: NIL

Total: 25200

Green belt area

( sq. meter)

Existing: ~ 8500

Proposed: NIL


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Total: ~ 8500

C Employment generation Existing: 32 Nos. company

employees + 30 Nos. on

Contract basis

Proposed: 91 Nos. company


Contract basis

Total: 123 Nos. company


Contract basis

Locally employed manpower

shall be utilized.

D Water

i



GIDC supply

Status of permission from the concern authority. Consented Quantity

Domestic: 10 KLD

Industrial: 110 KLD

ii Water consumption (KLD)

Existing

KLD

Proposed

(Additional)

KLD

Total after

expansion

KLD

Remarks

(A) Domestic 10 10 20 GIDC water supply

(B) Gardening 10 5 15 GIDC water supply

(C) Industrial

Process 0 18 18 GIDC water supply

Boiler 0 96 96 GIDC water supply

Cooling 90 500 590 Fresh water (GIDC): 546

KLD + Recycled water from

RO: 44 KLD


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Washing 10 54 64 10 KLD existing Fresh water

requirement + 54 KLD

recycled

(Boiler blow down of 9 KLD &

Cooling tower blow down of

45 KLD after proposed

expansion shall be passed

through cartridge filter & then

shall be used for washing

purpose.)

Others 0 0 0 --

Industrial Total 100 668 768 Fresh water (GIDC): 670

KLD + Recycled water: 98

KLD

Grand Total

(A+B+C)

120 683 803 Fresh water (GIDC): 705

KLD + Recycled water: 98

KLD

4) Total water requirement for the project: 803 KLD


6) Total fresh water requirement: 705 KLD


iii Waste water generation (KLD)

Category

Existing

KLD

Proposed

(Additional)

KLD

Total after

expansion

KLD

Remarks (Disposal Scenario

after proposed expansion)

(A) Domestic 5 4 9 To soak pit via septic tank

(B) Industrial


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Process 2 28 30 To ETP (Capacity: 50 KLD)

having primary, secondary &

tertiary treatment. Final treated

effluent conforming to discharge

norms of Jhagadia pipeline

project (JPP) shall be discharged

into aboveground pipeline

connected to Jhagadia pipeline

project (JPP) of M/s. Narmada

Clean Tech (NCT) for final

disposal into marine water

Boiler 0 9 9 Recycled water: 54 KLD

Blow down from boiler & cooling

tower (9 + 45 = 54 KLD) shall be

passed through cartridge filter &

then shall be used for washing

purpose.

Cooling 20 25 45

Washing 10 54 64 10 KLD existing waste water + 54

KLD recycled water.

Total 64 KLD shall be subjected

to RO(Overall Capacity after

expansion: 100 KLD) from which

44 KLD RO Permeate shall be

reused in Cooling Tower and 20

KLD of RO Reject shall be further

treated in ETP (Capacity: 50

KLD) along with process effluent.

Others 0 0 0 --

Recycled

water

0 (-98) (-98) 44 KLD RO Permeate + 54 KLD

recycled water from utilities


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Total

Industrial

waste water

to be

discharged

32 18 50 --

Total Waste

water [A+B]

37 22 59 --


[In-house ETP (Primary, Secondary, Tertiary), MEE, Stripper, Spray Dryer, STP etc..

Existing ETP of 50 KLD capacity

Treatment scheme including segregation at source. (Give Characteristics of each stream i.e. COD,

BOD, TDS etc.)

As the pipeline project was not completed and operational at the time of CTO application, unit has

opted for zero liquid discharge (ZLD) by treating existing industrial effluent in own ETP (capacity: 50

KLD), two stage MEE (Capacity: 10 KLD) & RO (Capacity: 50 KLD).

After proposed expansion, total industrial effluent shall be 94 KLD out of which 30 KLD of process

effluent shall be treated in ETP (Primary + Secondary + Tertiary Treatment) and 64 KLD effluent

from utilities and washing shall be subjected to RO (Overall Capacity after expansion: 100 KLD)

44 KLD RO Permeate shall be reused in Cooling Tower and 20 KLD of RO Reject shall be further

treated in ETP (Capacity: 50 KLD) along with process effluent.

Jhagadia pipeline project (JPP) is now operational and hence proponent intends to discharge 50

KLD Treated effluent conforming to discharge norms obtained from ETP into aboveground pipeline

connected to Jhagadia pipeline project (JPP) of M/s. Narmada Clean Tech (NCT) for final disposal

into marine water.

Unit has membership of Jhagadia pipeline project (JPP) of M/s. Narmada Clean Tech (NCT) for final

disposal of treated effluent into deep sea upto 50 KLD.

Low COD, low TDS effluent (from washing)

SN Particulars Unit Feed to RO

(Washing effluent)

RO permeate used

in cooling tower

1 pH -- 6.5-7.5 7.0-7.5

2 Total Dissolved Solids mg/l ~1600 <200

3 COD mg/l 250 <100

4 Suspended Solids mg/l <10 NIL


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5 Oil & Grease mg/l NIL NIL

6 Ammonical Nitrogen mg/l <10 <10

Process and RO reject effluent

SN Particulars Unit

Inlet to ETP

(Process effluent &

RO Reject)

Final Treated

Effluent from ETP to

JPP of M/s. NCT

1 pH -- 6.5-8.5 6.5-8.5

2 Total Dissolved Solids mg/l 4500-5000 5000-7000

3 COD mg/l 2000-3500 <250

4 Suspended Solids mg/l <100 <10

5 Oil & Grease mg/l <10 <1

6 Ammonical Nitrogen mg/l <10 <10



(Prevention and Control of Pollution) act, 1974 issued by CPCB regarding compliance of CETP.

Not applicable as Treated effluent conforming to discharge norms of Jhagadia pipeline project

(JPP) shall be discharged into aboveground pipeline connected to Jhagadia pipeline project (JPP)

of M/s. Narmada Clean Tech (NCT) for final disposal into marine water.


Not applicable as Treated effluent conforming to discharge norms of Jhagadia pipeline project

(JPP) shall be discharged into aboveground pipeline connected to Jhagadia pipeline project (JPP)

of M/s. Narmada Clean Tech (NCT) for final disposal into marine water.


Domestic: Sewage shall be disposed to soak pit via septic

tank.

Industrial:

Treated effluent from ETP conforming to

discharge norms of Jhagadia pipeline project

(JPP) shall be discharged into aboveground

pipeline connected to Jhagadia pipeline project

(JPP) of M/s. Narmada Clean Tech (NCT) for

final disposal into marine water


Name of Common facility (CF)(For waste water treatment)

Name of Common facility:


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Jhagadia pipeline project (JPP) of M/s. Narmada Clean Tech (NCT), Ankleshwar

Membership of Common facility (CF) --


Unit is member of M/s. Narmada Clean Tech (NCT), Ankleshwar




Total reuse/recycle 98 KLD

Source of waste

water for reuse with

quantity in KLD

(From where it is

coming)

Application area with

quantity in KLD (Where it

is used)

Characteristics of

waste water to be

reused (COD, BOD,

TDS etc.)

Remarks regarding

feasibility to reuse i.e.

RO Permeate: 44 KLD RO Permeate of 44 KLD

shall be reused in Cooling

Tower

COD: <100

BOD: <30

TDS: <200

As per the given

characteristics

it is feasible.


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Boiler blowdown: 9

KLD

Boiler blowdown of 9 KLD

& Cooling tower blowdown

of 45 KLD shall be used for

washing purpose.

COD: <100

BOD: <30

TDS: <500

Blow down will be used

only after passing

through cartridge filter.

Thus, parameters will

remain within

permissible limit

and feasible to use for

washing purpose.

Cooling tower

blowdown: 45 KLD

E Air



Existing & Proposed

Sr.

No.

Source of

emission with

Capacity

Stack

Height

From G.L.

(m)

Type of

Fuel

Quantity of

Fuel

Type of

emissions

i.e. Air

pollutants

Air Pollution Control

Measures (APCM)

Existing

1

Thermic Fluid

Heater-

2 nos. (10 lac

kcal/h & 2 lac

kcal/h)

30

De-oiled

cake (Agro

waste)/

Briquettes

(Agro

waste)

25 MT/day PM

SO2

NOX

Multicyclone + Bag filter

2

D.G. Set

1 no. (250 KVA)

(Stand-by)

11 Diesel 100 L/h Adequate Stack Height is

provided

Proposed

3

Boiler

2 nos. (10 TPH

each)

30

De-oiled

cake (Agro

waste)/

Briquettes

110 MT/day

PM

SO2

Multicyclone + Bag filter

+ Water scrubber


of 174

(Agro

waste)

NOX

4

Thermic Fluid

Heater-

3 nos. (20 lac

kcal/h each)

30

(each)

De-oiled

cake (Agro

waste)/

Briquettes

(Agro

waste)

60 MT/day Multicyclone + Bag filter

+ Water scrubber

5

D.G. Set

2 nos. (600 KVA

each) (Both Stand-

by)

11 Diesel 180 L/h Adequate Stack Height

shall be provided


Existing & Proposed

There is no process gas emission from existing manufacturing process and there shall be no process gas

emission from manufacturing of proposed new products also.


Sr.

No. Probable sources Control measures

1) Pump glands and

seals

All pumps handling HAP chemicals with low V.Ps are

provided mechanical seals which are presently best for

preventing emissions.

2) Emissions from Bulk

Storage Tanks during

storage, loading and

unloading

Storage tanks storing low V.Ps chemicals are provided

with Breather valve assembly. Set pressure of

breather valves is kept above the vapor pressures of

stored material to avoid fugitive emission.

Tank Pressure equalization is applied wherever

required.

Use of ISO tankers for Hazardous Chemicals and

Closed transfer system.

3) During reactions & Charging of raw materials is carried out in closed


of 174

Solvent recovery

systems

systems

All reactors shall be closed and provided with

condenser with cooling water circulation and vent

condensers with chilled water circulation for maximum

vapor recovery

Solvent recovery of minimum 95% shall be achieved

Temperature and pressure conditions shall be

stringently controlled as per the process requirement

and optimized with low temperature and vacuum

conditions wherever feasible.

4) Pressure Relief Valve

Emissions from

pipelines

For highly pressurized lines, pressure equalization is

followed with return lines so that the pipelines as well

as connected equipment do not get pressurized

unduly.

5) Release from

Sampling Lines

Shall be carried out using a closed loop sampling

system.

6) Valves, Flanges,

plugs and instrument

connections

Welded pipes to be used wherever feasible

Suitable gasket material to be used

Suitable gland packing to be used in valves

LDAR shall be planned and implemented for periodic

inspection and maintenance of pipes and pipe fittings.

7) Chemical vapors

during filtration and

drying process

Covered filtration, closed movement of solid material

are adopted to best possible extent, workers are

provided PPEs, fume extraction system to be provided

wherever required

8) Drum filling machinery Covered transfer systems are adopted with minimum

manual operations, workers are provided PPEs, area

is well -ventilated, facilitated with local exhausts and

roof top ventilators

9) Warehouse storing Spillages shall be strictly prevented by providing drip

pans; proper handling equipment, Spill control


of 174

drums and bags procedures and equipment are available.

F Hazardous waste

(As per the Hazardous and Other Wastes (Management and Transboundary Movement) Rules 2016.

Existing & Proposed

i

Sr.

no

.

Type/Nam

e of

Hazardou

s waste

Specific

Source

of

generati

on

(Name of

the

Activity,

Product

etc.)

Catego

ry and

Schedu

le as

per HW

Rules.

Quantity

(MT/Annum)

Management

of HW

Existing

Propos

ed

Tota

l

Authorizati

on

available

Actual

generated

(Authorizati

on

requested)

1.

Used or

Spent Oil

From

Machiner

y

Cat.:

5.1 &

Sch: I

3.5 -- 12 15.5

Collection,

Stored in

drums in H.W.

storage area

(shed with

RCC flooring),

Transportation

& Will be used

for lubricating

purposes as

required and

then sell to

MoEF&CC

authorized

registered re-

refiners.

2.

Empty

barrels /

containers

Raw

material

container

Cat:

33.1 &

Sch: I

50 -- 168 218

Collection,

Storage,

Decontaminati


of 174

/ liners

contaminat

ed with

hazardous

chemicals /

wastes

s / bags on, reused

and sell to

authorized

recyclers

3.

Chemical

sludge

from waste

water

treatment

From

ETP

Cat.:

35.3 &

Sch: I

100 -- 300 400

Collection,

Stored in

Bags in

separate

place (shed

with RCC

flooring),

Transportation

& sent to

TSDF of M/s.

BEIL,

Ankleshwar

4.

Spent

Solvent

During

productio

n:

Distillatio

n

process

of Sr. No.

17 to 20,

32,33,40

products

in

product

list

Categor

y: 20.2

& Sch: I

0 78* 804* 882*

Reused

continuously

in production

through

distillation

columns

having

Primary and

secondary

condensers

inbuilt with

reactors

without any

storage in the

premises

5. Process

Waste

During

productioCategor 0 -- 24 24

Collection,

Stored in


of 174

Sludge

(Inorganic)

n: From

Filtration

process

of Sr. No.

34 to 39

products

in

product

list

y: 26.1

& Sch: I

Bags in

separate

place (shed

with RCC

flooring),

Transportation

& sent to

TSDF of M/s.

BEIL,

Ankleshwar

6.

Spent

Filter cloth

Filtration

Process

Categor

y: 36.2

& Sch: I

0 -- 12 12

Collection,

Stored in

Bags in

separate

place (shed

with RCC

flooring),

Transportation

& sent to M/s.

RSPL

7.

Bottom

product

after

distillation

During

productio

n:

Distillatio

n

process

of Sr. No.

32, 33 &

Sr. no.

40

products

in

product

list

Categor

y: 20.3

& Sch: I

0 -- 84 84

Collection,

Stored in

drums/bags in

separate

place (shed

with RCC

flooring),

Transportation

and sent for

Co-processing

*We have received TOR vide letter no. SEIAA/GUJ/TOR/5(f)/1183/2019 dated 23-08-2019 for existing


of 174

spent solvent quantity generated from manufacturing process about 1656 MTA, proposed additional about

15024 MTA and total after expansion about 16680 MTA. As per the recent suggestions given by the

committee for updating actual spent solvent quantity rather than showing the recovered quantity. Hence,

here we have incorporated all the suggestions and updated the Hazardous waste matrix and mentioned

the actual spent solvent quantity.


(For HW management)

For existing Hazardous

waste quantity, unit is

having membership of

TSDF of M/s. BEIL,

Ankleshwar.

For proposed additional

Hazardous waste, unit has

obtained NOC from M/s.

BEIL, Ankleshwar.

iii Details of Non-Hazardous waste & its disposal(MSW and others)

Sr.

no.

Type/Name

of

Hazardous

waste

Specific

Source of

generation

(Name of

the Activity,

Product

etc.)

Category

and

Schedule

as per HW

Rules.

Quantity

(MT/Annum)

Management of

Non Hazardous

Waste Existing Proposed Total

1. High Potash

Organic Ash

OR

From De

oiled cake

combustion -- 600 3108 3708

Collection,

Storage,

Transportation,

Sale as

Agricultural

manure

2. Ash From

Briquette

combustion

-- 900 9312 10212

Collection,

Storage,

Transportation,

Sale to brick

manufacturers

or

manufacturers of


of 174

Cement articles

or products


i Types of solvents, Details of Solvent recovery, % recovery, reuse of recovered Solvents etc. (Details in

Table Format)

Solvent recovery is done by distillation assembly provided on reaction vessels. After the reaction the un -

reacted solvent is recovered by distillation and reused in next batch. Capryl alcohol is recovered upto 96%

and during distillation of Capryl alcohol 3% of octene is generated which shall be reused within the

premises. New production units shall also have same facility. Solvent recovery system shall consist of

packed columns and primary condenser having cooling water circulation and secondary condenser

having chilled water or chilled brine circulation. Distillation is to be carried out at atmospheric as well as

vacuum conditions to obtain min. 95% recovery.

Product

Sr. No.

Product Solvent Solvent

charged

kg per

1000 kg

batch

Subject to

recovery

kg per

batch

Recovered Solvent

Per batch

(kg)

%

Recover

y

17 Capryl Benzoate-

(Jagroplast-CB) and

isomers

Capryl

Alcohol

1056 495.16 480.3 96.0

18 Dicapryl Phthalate -

(Jagroplast-DCP) and

isomers

Capryl

Alcohol

1167 494.50 480.3 96.2

19 Dicapryl Sebacate-

(Jagroplast-DCS) and

isomers

Capryl

Alcohol

1110 494.12 480.3 96.2

20 Dicapryl Adipate-

(Jagroplast DCA) and

isomers

Capryl

Alcohol

1203 493.99 480.3 96.3

32 Dimethyl Sebacate Methanol 1000 677 650.00 95.1

33 Dibutyl Sebacate Butanol 943 443 425.00 95.0

40 Methyl Ricinoleate Methanol 200 96 92.20 95.1


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Handling of chemicals will be in closed system. Primary and secondary condensers are proposed.



Storage tanks

Pelargonic Acid, Heptanoic Acid, Capryl alcohol, Butanol, 2-

Octanol

Tanks

Drum/

Barrel/Carboys

storage

Tetra Isopropyl Titanate(TIPT)/tetra-n-butyl titanate(TnBT)

Catalyst, Methanol, Hydrogen Peroxide (50%), Catalyst

(Titanium (IV) Butoxide, Titanium (IV) Isopropoxide etc.), 2-

ethyl hexanol, Epichlorohydrin, Ethyl Acetate, Octene.

HDPE OR MS

Drums/ Carboys

Bags Trimethylol propane, Terephthalic acid, Sodium Hydroxide,

Phthalic anhydride, Sodium Methoxide (NaOCH3) Catalyst,

Adipic Acid

--

Applicability of PESO: Yes, applicable




the study area of 10 km radial distance from project site for the period October to December 2017. Ambient

Air Quality monitoring was carried out for PM10, PM2.5, SO2, NOx, Benzene, NH3, CO & VOC at nine

locations, including the project site. Values conform to the prescribed standards for Ambient Air Quality. The

incremental Ground Level Concentration (GLC) has been computed using AERMOD. The resultant

concentrations are within the NAAQS.




During SEAC meeting on 11/02/2020, Committee noted that the proposal is for expansion. Committee noted

that unit has obtained earlier EC from SEIAA, Gujarat vide Letter No. SEIAA/GUJ/EC/5(f)/1203/2015 dated

31/03/2015 however, not submitted Certified Compliance Report from RO – Bhopal as a part of compliance of

ToR and asked to submit the same.

After detailed discussion, Committee decided to defer the project and consider the same only after

submission of Certified Compliance Report (CCR) from RO – Bhopal as a part of Compliance of ToR

granted by SEIAA, Gujarat.

9 SIA/GJ/IND2/46850/2019 M/s. Turtle Pharma Pvt. Ltd.

SPS99, Sterling SEZ, Sarod, Jambusar,

Dist. Bharuch

Appraisal

Category of the unit : 5(f)


of 174

Project status: New




04/11/2019.

Project proponent has submitted EIA Report prepared by M/s. Enpro Enviro Tech & Engineer Pvt Ltd, Surat

based on the TOR issued by SEIAA.

This is new unit proposes for manufacturing of synthetic organic chemical as tabulated below:

Sr.

No. Name of the Products

CAS no. /CI

no.

Quantity

MT/Month

End-use of the

products

1 GROUP - I

1.1 Canagliflozin and/or 842133-18-0

58

MT/Month

Active

Pharmaceutical

Ingredients

1.2 Bimatoprost and/or 155206-00-1

1.3 Dapagliflozin and/or 461432-26-8

1.4 Apixaban and/or 503612-47-3

1.5 Deferasirox and/or 201530-41-8

1.6 Apremilast and/or 608141-41-9

1.7 Danofloxacin Mesylate and/or 119478-55-6

1.8 Droxidopa and/or 3916-18-5


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1.9 Treprostinil and/or 81846-19-7

1.10 Olopatadine Hydrochloride USP and/or 140462-76-6

II GROUP - II

2.1 Lomefloxacin Hydrochloride and/or 98079-52-8

59

MT/Month

Active

Pharmaceutical

Ingredients

2.2 Marbofloxacin BP and/or 115550-35-1

2.3 Ciprofloxacin Lactate and/or 96186-80-0

2.4 Paracetamol and/or 103-90-2

2.5 Ofloxacin USP and/or 82419-36-1

2.6 Levofloxacin Hemihydrate USP and/or 138199-71-0

2.7 Difloxacin Hydrochloride EP/BP and/or 91296-86-5

2.8 Moxifloxacin Hydrochloride BP and/or 151096-09-2

2.9 Efinaconazole and/or 164650-44-6

2.10 Ciprofloxacin USP and/or 93594-39-9


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III GROUP - III

3.1 Ciprofloxacin Hydrochloride USP and/or 86393-32-0

59

MT/Month

Active

Pharmaceutical

Ingredients

3.2 Dabigatran Etexilate and/or 211915-06-9

3.3 Rivaroxaban and/or 366789-02-8

3.4 Enrofloxacin USP and/or 93106-60-6

3.5 Sarafloxacin Hydrochloride 91296-87-6

3.6 Nadifloxacin and/or 124858-35-1

3.7 Azelastine Hydrochloride USP and/or 79307-93-0

3.8 Norfloxacin BP and/or 70458-96-7

3.9 Ranolazine and/or 95635-55-5

3.10 Metformin Hydrochloride and/or 1115-70-4

Total 176

MT/Month



Salient feature of the project including air, water and hazardous waste management as below:


of 174

Sr.

no. Particulars Details

A


(Rs. in Crores): 15 Crores

Details of EMP Rs. 3.40 Crores

Details of CER as per OM dated 01/05/2018 Rs. 30 Lacs

B Total Plot area ( sq. meter) 4050 Sq. m.

Green belt area

( sq. meter)

1335 Sq. m.

(33 % of Total Area)

C Employment generation 100 (Direct and Indirect)

D Water

i


(GIDC Bore well, Surface water, Tanker supply etc...) Sterling SEZ water supply


Necessary permission has been

taken from concerned authority for

consumption of water.

ii

Category Quantity

KLD Remarks

(D) Domestic 6 -


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(E) Gardening 6.6 -

(F) Industrial -

Process 18.43 -

Washing 4 -

Boiler 12 -

Cooling 8 -

Others (Scrubber) 3.5 -

Industrial Total 45.93 -

Total (A + B + C) 58.53 -

-

-

In case of effluent sent to common MEE facility of M/s. BEIL




In case of use of inhouse MEE plant*





Note * - Unit will use in-house MEE plant only during shutdown or maintenance of Common MEE facility.

In that case only, fresh water requirement will be reduced to 35.53 KLD as 23 KLD water will be recycled

back from MEE.


of 174


-

Category Waste water

KLD Remarks

(C) Domestic 5.4

(D) Industrial

Process 16.58

Washing 4

Boiler 1.5

Cooling 1

Others (Scrubber) 3.0

Total Industrial waste water 26.08

Total [A + B] 31.48

-

Iv

Treatment facility within premises with capacity


Unit shall Neutralize the Effluent and then sent to Common MEE Facility of BEIL. However, Unit has also

proposed to install inhouse MEE plant followed by biological treatment and RO plant for the treatment of

waste water. Unit will use inhouse MEE plant only in case of maintenance or breakdown of common

MEE facility of BEIL. In that case only unit will recycle 23 KL/Day water from RO plant. Domestic effluent

shall be disposed through septic tank/soak pit.

Treatment scheme including segregation at source.


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There shall be only one stream generated from industrial activities. Which shall be sent to common MEE

facility of M/s. BEIL Infrastructure Ltd.

Note: (In case of CETP discharge) : Common MEE facility of M/s. BEIL



Unit has proposed to send waste water to common MEE facility of M/s. BEIL after neutralization.

However, unit will install stand by inhouse MEE plant followed by Biological treatment and RO

plant, which shall be operated during maintenance or break down of common MEE facility.


Unit is not ZLD based. Waste water generated from industrial activities shall be sent to common

MEE facility of M/s. BEIL. However, Unit has proposed Inhouse MEE plant followed by biological

treatment and RO Plant for the treatment of waste water generated from industrial activities. Unit

will use inhouse MEE plant only in case of break down or maintenance of common MEE facility of

M/s. BEIL.

v

Mode of Disposal & Final meeting point

Domestic: 5.4 KL/Day Disposed through Septic Tank / Soak Pit System

Industrial:

26.08 KL/day of concentrated effluent stream, shall be sent to M/s. BEIL

Infrastructure Ltd. for the Evaporation-crystallization / MEE treatment. However, unit

has proposed inhouse MEE plant followed by biological treatment and RO plant. RO

permeate water shall be reused into process & other utilities. Unit will use inhouse

only in case of break down or shutdown of common MEE facility of M/s.BEIL.

vi

In case of Common facility (CF) like CETP, Common Spray dryer, Common MEE etc. Name of CF

M/s. BEIL Infrastructure Ltd.


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Unit has obtained NOC from M/s. BEIL for treatment of waste water.


Water Balance Diagram: (In case of Effluent will be send to Common MEE facility.)

-

-

Water Balance Diagram: (In case of use of inhouse MEE)

-


of 174

-

Characteristics of Waste water (In case of use of inhouse MEE plant)

Parameter Unit Concentrated

stream

characteristics

After MEE

treatment

After

biological

treatment

After RO

treatment

pH - 4-5 6.5-8.5 6.5-8.5 6.5-8.5

COD mg/L 25000-30000 5000-6000 1000-1200 <100

TDS mg/L 30000-35000 3000-3500 3000-3500 <250

SS mg/L 500-600 50-60 50-60 <30

Source- Sterling SEZ and Infrastructure Limited.

Note * - Unit will use in-house MEE plant only during shutdown or maintenance of Common MEE facility. In that

case only, fresh water requirement will be reduced to 35.53 KLD as 23 KLD water will be recycled back from

MEE. RO permeate water shall be reused in process & other utilities.

viii Reuse/Recycle details (KLD)


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Total reuse 23 KLD

-

Source of waste water

for reuse with quantity

in KLD (From where it

is coming)

Application area

with quantity in

KLD (Where it is

used)



BOD, TDS etc.)

Remarks

regarding

feasibility to

reuse i.e.

23 KLD from MEE plant

followed by RO plant

Within plant

premises

pH - 6.5-8.5

COD - <100

TDS - <250

SS - <30

-

Note: Unit will use in-house MEE plant only during shutdown or maintenance of Common MEE facility of

BEIL.

E Air

i

Flue gas emission details


-

Sr.

no.

Source of

emission

With Capacity

Stack

Height

(meter)

Type of

Fuel

Quantity of

Fuel

MT/Day

Type of

emissions i.e.

Air Pollutants

Air Pollution

Control

Measures

(APCM)

1.

Boiler – I

(Capacity:

3 MT/hr)

Height: 30

m

Dia: 400

mm

LDO 250 L/hr

PM,

SO2,

NOX

As LDO is used

as a fuel. Stack

Height of 30 m

is provided.

2.

Boiler – II

(Capacity:

2 MT/hr)

(Standby)

Height: 30

m

Dia: 350

mm

LDO 175 L/hr

PM,

SO2,

NOX

As LDO is used

as a fuel. Stack

Height of 30 m

is provided.


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3.

Thermopack

(Capacity:

300 U)

Height: 30

m

Dia: 300

mm

LDO 50

L/hr

PM,

SO2,

NOX

As LDO is used

as a fuel. Stack

Height of 30 m

is provided.

4.

D.G. Set – I & II

(Capacity:

160 KVA)

(Stand by)

Height: 10

m

Dia: 150

mm

HSD 30

L/hr (Each)

PM,

SO2,

NOX

Stack Height

will be provided

as per CPCB

norms..

-

ii Process gas emission details i.e. Type of pollutant gases (SO2, HCl, NH3, Cl2, NOx etc.)

-

Sr.

no.

Specific Source of

emission

(Name of the Product &

Process)

Type of

emission

Stack/Vent

Height (meter)


Measures

(APCM)

1. Reaction Vessel – I HCl, HF Height: 13 m

Dia: 100 mm

Two Stage Alkali

Scrubber

2. Reaction Vessel - II HCl, HI Height: 13 m

Dia: 100 mm

Two Stage Alkali

Scrubber

3. Reaction Vessel – III HF, HI Height: 13 m

Dia: 100 mm

Two Stage Alkali

Scrubber


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4. Reaction Vessel - IV NH3 Height: 13 m

Dia: 100 mm

Single Stage water

Scrubber

-

iii Fugitive emission details with its mitigation measures:

As below:

Not Applicable

F Hazardous wastes

(as per the Hazardous and Other Wastes (Management and Transboundary Movement) Rules 2016.

i

-

Sr.

no.

Type/Name of

Hazardous

waste

Specific Source

of generation

(Name of the

Activity, Product

etc.)

Category

and

Schedule as

per HW

Rules.

Quantity

(MT/

Annum)

Management of HW

1 ETP Sludge From ETP 35.3 30 MT/Year

Collection / Storage /

Transportation / send

to CHWTSDF Site of

M/s. BEIL-Dahej for

Landfill.

2 Used Oil From Plant &

Machineries 5.1

0.033

MT/Year



to registered recycler.

3 Discarded

Containers

From Raw

material and

Packaging

33.1 20 MT/Year


Transportation /

Supplier / send to

registered recycler.

4 Process Sludge From Process of

Droxidopa 28.1

487

MT/Year



to CHWTSDF Site for

incineration.


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5 Spent Carbon

From Process of

Droxidopa,

Paracetamol and

Ciproflaxacin USP

28.3 38.4

MT/Year



to CHWTSDF Site for

incineration.

6 Process

Residue From Distillation 28.1

2820

MT/Year



for Co- Processing

based on feasibility.

7 Spent Solvents

7.1 Acetone

From Process of

Apremilast,

Olopatadine

Hydrochloride

USP

28.6 1309

MT/Year


Transportation /

Distillation / reuse in

to same process.

7.2 Acetonitrile

From Process of

Apixaban,

Efinaconazole,

Nadifloxacin,

Azelastine

Hydrochloride

USP

28.6 5816

MT/Year


Transportation /


to same process.

7.3 Dichloro

methene

From Process of

Marbofloxacin BP 28.6

1662

MT/Year


Transportation /


to same process.

7.4 Dimethyl

Formamide

From Process of

Apixaban,

Deferasirox

28.6 1634

MT/Year


Transportation /


to same process.

7.5 Dimethyl

Sulphoxide

From Process of

Ciprofloxacin

Lactate, Ofloxacin

USP, Levofloxacin

Hemihydrate USP,

Ciprofloxacin

USP,

28.6 3339

MT/Year


Transportation /


to same process.


of 174

Ciprofloxacin

Hydrochloride

USP, Enrofloxacin

USP

7.6 Ethanol

From Process of

Apixaban,

Apremilast,

Danofloxacin

Mesylate,

Droxidopa

28.6 2533

MT/Year


Transportation /


to same process.

7.7 Ether From Process of

Bimatoprost 28.6

2479

MT/Year


Transportation /


to same process.

7.8 Ethyl Acetate

From Process of

Canagliflozin,

Bimatoprost,

Dapagliflozin,

Apixaban,

Apremilast,

Treprostinil,

Dabigatran

Etexilate

28.6 5024

MT/Year


Transportation /


to same process.

7.9 Iso Propyl

Alcohol

From Process of

Ciprofloxacin

Lactate, Ofloxacin

USP, Levofloxacin

Hemihydrate USP,

Efinaconazole,

Ciprofloxacin

USP,

Ciprofloxacin

Hydrochloride

USP, Enrofloxacin

USP, Sarafloxacin

Hydrochloride

28.6 6736

MT/Year


Transportation /


to same process.


of 174

7.10 Methanol

From Process of

Canagliflozin,

Dapagliflozin,

Droxidopa,

Treprostinil,

Lomefloxacin

Hydrochloride,

Moxifloxacin

Hydrochloride BP,

Norfloxacin BP,

Ranolazine,

Metformin HCl

28.6 6722

MT/Year


Transportation /


to same process.

7.11 N Heptane From Process of

Efinaconazole 28.6

1184

MT/Year


Transportation /


to same process.

7.12 Pyridine

From Process of

Danofloxacin

Mesylate,

Difloxacin

Hydrochloride

EP/BP

28.6 2348

MT/Year


Transportation /


to same process.

7.13 THF

From Process of

Canagliflozin,

Olopatadine

Hydrochloride

USP, Moxifloxacin

Hydrochloride BP,

Dabigatran

Etexilate

28.6 5797

MT/Year


Transportation /


to same process.

7.14 Toluene

From Process of

Bimatoprost,

Ranolazine

28.6 3087

MT/Year


Transportation /


to same process.

8 Bleed from

Scrubber From Scrubber 35.1

1260

kL/Year




of 174

to Common MEE

facility of BEIL-Dahej.

9 MEE Salt* From MEE 35.3 228

MT/Year



to CHWTSDF Site of

M/s. BEIL-Dahej for

Landfill.

10 Off specification

product From Process 28.4 6.0 MT/Year



to CHWTSDF Site for

Landfill or Incineration

based on

characteristics.

11 Date expired

product From Process 28.5 6.0 MT/Year



to CHWTSDF Site for

Landfill or Incineration

based on

characteristics.

-

*Note: MEE salt will be generated only during operation of in-house MEE facility.


(For HW management)

Unit has obtained NOC letter from

BEIL.

iii Details of Non-Hazardous waste & its disposal

(MSW and others) Not Applicable



of 174

i

Types of solvents, Details of Solvent recovery, % recovery, reuse of recovered Solvents etc. (Details in

Table Format)

Spent solvent shall be Collect / reuse in to Process.

-

Name of solvent Requirement in

MT/Year

Recycled

within a

process

in MT/Year

Loss

in

MT/Year

Recovery

(%) Loss (%)

Acetone 1491.4 1309.1 182.3 87.8 12.2

Acetonitrile 6563.8 5816.7 747.1 88.6 11.4

Chloroform 1770.0 1593.0 177.0 90.0 10.0

Dichloro methene 1847.0 1662.3 184.7 90.0 10.0

Dimethyl Sulphoxide 3777.9 3339.9 438.0 88.4 11.6

Ethanol 2784.0 2533.4 250.6 91.0 9.0

Ether 2610.0 2479.5 130.5 95.0 5.0

Ethyl Acetate 5797.6 5024.5 773.1 86.7 13.3

IPA 7594.9 6736.7 858.2 88.7 11.3

Methanol 7232.4 6722.1 510.3 92.9 7.1

N Heptane 1287.3 1184.3 103.0 92.0 8.0

Pyridine 2719.1 2348.5 370.6 86.4 13.6

THF 6385.8 5797.4 588.4 90.8 9.2

Toluene 3414.0 3087.1 326.9 90.4 9.6

-


of 174

ii

VOC emission sources and its mitigation measures

The entire manufacturing activities & distillation process will be carried out in a totally closed system.

All the pumps shall be mechanical seal type to avoid any leakage of solvent.

For solvent handling fire proof electrical motors and components shall be used.

Firefighting systems shall be provided with alarm system.

All the storage tanks and day tanks shall be connected to a vent system through two-stage chilled

water condensers to prevent loss of solvents in the atmosphere.

All the reactor condenser vents are connected with two-stage chilled water condensers for maximum

possible recovery of the solvents and minimum loss.

H

Details regarding storage of Hazardous chemicals

-


Storage tanks with adequate

capacity will be provided.

Acetone, Acetonitrile, Chloroform,

Dichloro methene, Dimethyl Sulphoxide,

Ethanol, Ether, Ethyl Acetate, IPA.

Tank farm is

proposed to be

provided for the

hazardous

chemicals.

-

More details will be provided in EIA report.

Applicability of PESO : Not Applicable




the study area of 10 km radial distance from project site for the March to May 2019. Ambient Air Quality

monitoring was carried out for PM2.5, PM10, SO2, NOx, CO, NH3, HC, VOC & PAH at six locations, including

the project site. Values conform to the prescribed standards for Ambient Air Quality. The incremental Ground

Level Concentration (GLC) has been computed using AERMOD. The resultant concentrations are within the

NAAQS.




Committee noted that this proposal is new in Sterling SEZ. PP mentioned that source of water is SEZ

(Sterling). PP mentioned that effluent generated from process, washing, boiler blow down, colling tower blow

down & scrubbing will be treated in proposed in-house ETP consisting of primary treatment and treated


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effluent will be sent to common MEE of BEIL, Dahej. Committee noted that PP has not submitted Membership

Certificate from Common Facility in-line with the direction given by GPCB vide Letter No. GPCB/P-1/8-G

(5)/550706 dated 08/01/2020 and asked to submit the same. PP has proposed two boiler and one

Thermopack. Fuel used will be LDO. Committee noted that PP has not addressed adequate APCM in process

gas emission and LDAR. Committee noted that PP has not addressed Hazardous Waste as per HWR – 2016.

Committee noted that EMP & CER addressed by PP is not satisfactory.

After detailed discussion, it was decided to consider the proposal only after submission of the

following documents:

1. Membership Certificate from Common Facility in-line with the direction given by GPCB vide Letter No.

GPCB/P-1/8-G (5)/550706 dated 08/01/2020.Membership Certificate from Common Facility (mentioning

total capacity, consented quantity, occupied capacity and spare capacity and norms of acceptance of

effluent from member units) in-line with the direction given by GPCB vide Letter No. GPCB/P-1/8-G

(5)/550706 dated 08/01/2020.

2. Leak Detection and Repairing Programme (LDAR) for all the solvents/volatile organic chemicals proposed

with detailed chemical properties including vapor pressure. LDAR with all mitigation measures shall

endeavor prevention of losses of solvents/Volatile organic compounds to the best minimum extent.

3. Revised Hazardous Waste Matrix as per HWR – 2016 considering disposal of Incinerable & Co-

processing Waste outside CEPI Area keeping in view NGT order dated 10/07/2019 in Original Application

No. 1038.

4. Adequate APCM for Process gas emission considering type of emission.

5. Revised Need Based CER & EMP along with Fixed Capital Cost and Recurring Cost as per OM dated

01/05/2018 of MoEF&CC.

10 SIA/GJ/IND2/30567/2018 M/s. Ecofine Colourchem Pvt. Ltd.

Plot no. DP: 42 & 43, Saykha GIDC,

Saykha, Vagra, Bharuch.

Appraisal






27/03/2018.

Project proponent has submitted EIA Report prepared by M/s. Jyoti Om Chemical Research Center Pvt Ltd,

Surat based on the TOR issued by SEIAA.



of 174

Sr.

no.

Name of the

Products

CAS no. /

CI no.

Quantity

MT/Month

End Use of the

products

Existing Proposed Total

Existing Products as per CTE - 88975

A Formulation and standardization

acrylic Dyes; some representative

dyes

400 0 400 Colouring of wool and

acrylic fibres

1. Golden Yellow

AND/OR

--

2. Blue AND/OR --

3. Violet Red AND/OR --

4. Yellow AND/OR --

5. Orange --

B Formulation and Standardization

Azo&Anthra Quinone Disperse

Dyes :Some Representative

Colouring of Polyester

fabrics / Mix fabrics

1. Disperse oranges:-

1,3,25,31,44 & 228

and/or

11080,

11005,

61968-38-5

2. Disperse yellow:-

1,3,7,23,27,42,54,64,

114,119 & 221 and/or

11855,

26090,

26070,

61968-66-9,

57308-41-5

3. Disperse red:-

1,5,13,17,19,50,54,73

,74,167,202 & 343

and/or

11110,

11215,

11115,

11210,

11130,

11226,

11116,

99031-78-6

4. Disperse Blue:-

3,14,60,79,94 & 291

AND/OR

61505,

61500,

61104,


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11345,

12235-96-0,

56548-64-2

5. Disperse violet:-

26,28,33,57,63,93 &

99 and/or

61102,

52697-38-8

6. Disperse brown:-1 &

26

23355-64-8

C Mixtures Made Out of about

Products: Some Representative

Dyes

Colouring of Polyester

fabrics / Mix fabrics

1. Disperse Green 2G

and/or

--

2. Disperse Green 2B

and/or

--

3. Disperse Brown 3

REL AND/OR

52623-75-3

4. Disperse Brown 3BS

AND/OR

--

5. Disperse Yellow 5RX

AND/OR

--

6. Disperse Black RL

AND/OR

--

7. Disperse Black CCR

AND/OR

--

Total 400 0 400

Proposed

Sr.

no.

Name of Product CAS No. Quantity

MT/Month

End Use


Acid dyes (Azo) 0 75 75 Colouring of wool /

Nylon / Leather 1 Acid Yellow 11 18820

2 Acid Yellow 17 18965



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4 Acid Yellow 29 6359-91-7





9 Acid Orange 3 6373-74-6

10 Acid Orange 19 14690




14 Acid Red 1 18050

15 Acid Red 37 17045

16 Acid Red 57 17053

17 Acid Red 114 23653

18 Acid Red 119 12220-20-1

19 Acid Red 138 18073

20 Acid Red 249 18134

21 Acid Blue 92 13390

22 Acid Blue 113 26360

23 Acid Black 10 --

24 Acid Black 210 99576-15-5

25 Acid Black 60 18165

26 Acid Violet 7 18055




Acid Dyes (Anthraquinones/

Condensed)

0 25 25

1 Acid Green 25 61570

2 Acid Green 27 61580



5 Acid Blue 25 62055




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8 Acid Blue 129 62058

Basic Dyes 0 200 200 Colouring of paper /

acrylics 1 Basic Yellow 2 41000

2 Basic Yellow 51 83949-75-1

3 Basic Orange 2 11270

4 Basic Orange 14 10127-02-3

5 Basic Red 1 989-38-8

6 Basic Red 2 477-73-6

7 Basic Red 9 569-61-9

8 Basic Blue 7 2390-60-5

9 Basic Blue 9 52015

10 Basic Blue 11 2185-86-6

11 Basic Blue 17 92-32-9

13 Basic Blue 26 53126

14 Basic Blue 54 15000-59-6

15 Basic Violet 1 42535




19 Basic Violet 11 2390-63-8

20 Basic Violet 26 --

21 Basic Green 1 42040

22 Basic Green 4 42000

23 Basic Green 5 224967-52-6

24 Basic Brown 1 10114-58-6

25 Basic Brown 4 21010

Disperse Dyes (Azo) 0 350 350 Colouring of Polyester

fabrics / Mix fabrics 1 Disperse Yellow 3 11855

2 Disperse Yellow 5 12790




6 Disperse Yellow 56 54077-16-6




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13 Disperse Orange 1 11080







20 Disperse Orange 31 61968-38-5






26 Disperse Orange 288 --

27 Disperse Red 1 11110








35 Disperse Red 52 --



38 Disperse Red 74 61703-11-5


40 Disperse Red 114 --


42 Disperse Red 152 78564-86-0

43 Disperse Red 153 78564-87-1


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45 Disperse Red 279 72827-94-2

46 Disperse Red 311 77907-28-9

47 Disperse Red 338 87714-25-8

48 Disperse Red 343 99031-78-6

49 Disperse Red 362 158129-94-3

50 Disperse Brown 1 23355-64-8

51 Disperse Brown 3 11190

52 Disperse Brown 19 71872-49-6

53 Disperse Violet 7 11410



56 Disperse Violet 43 12223-81-3



59 Disperse Blue 79 11345


61 Disperse Blue 90 12222-88-7


63 Disperse Blue 106 12223-01-7



66 Disperse Blue 281 22578-86-5

67 Disperse Blue 284 71872-43-0

68 Disperse Blue 291 56548-64-2

Disperse Dyes

(Anthraquinones/Condensed)

0 150 150






6 Disperse Yellow 22 --




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24 Disperse Red 277 70294-19-8


26 Disperse Violet8 62030










36 Disperse Blue 354 104137-27-1

Reactive Dyes (Azo) 200 200 Dye printing of cotton

1 Reactive Yellow 42 12226-63-0




5 Reactive Yellow 135 24925



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7 Reactive Orange 4 18260



10 Reactive Orange 122 12220-12-1

11 Reactive Red 35 12226-12-9

12 Reactive Red 141 61931-52-0

13 Reactive Red 152 71870-80-5

14 Reactive Red 195 93050-79-4

15 Reactive Red 198 18221

16 Reactive Blue 13 12236-84-9



19 Reactive Blue 109 61951-76-6

20 Reactive Blue 171 77907-32-5

21 Reactive Black 5 14095-24-8

22 Reactive Black WNN --

Reactive Dyes (Anthraquinones/

Condensed)

100 100

1 Reactive Blue 4 61205




Total 0 1100 1100

TOTAL (Existing +

Proposed)

400 1100 1500




Sr.

no.

Particulars Details


(Rs. in Crores):

Existing: 10

Proposed: 70

Total: 80


of 174

Details of EMP

EMP Cost: (I) Capital cost for EMS (Environmental Management System): Rs. 14.0 Crores.

(II) Recurring cost towards the environmental protection measures: Rs. 4.8 Crores per

Annum.


CER Cost: Rs. 1.6 Crores

Activities to be carried out under CER:

Unit will allocate fund to Gram Vikas Trust, Bharuch for Corporate Environment Responsibility.

Letter for above CER activity from Gram Vikas Trust, Bharuch is attached as annexure- XVI.

B Total Plot area

( sq. meter)

Existing: 8905.6 Sq. m.


Total: 22053.54 Sq. m.

Green belt area

( sq. meter)

Existing: 0 Sq. m.

Proposed: 6616 Sq. m.

Total: 6616 Sq. m.

C Employment generation Existing: 13

Proposed: 50

Total: 63

D Water

i


(GIDC Bore well, Surface water, Tanker supply

etc...)

GIDC

Status of permission from the concern authority. Water consumption letter is attached as

annexure – VI in EIA report.


Existing Proposed Total after Remarks


of 174

KLD (Additional)

KLD

Expansion

KLD

(G) Domestic 5

10 15 Fresh

(H) Gardening

5 20 25 (Fresh 14 +

Recycle 11)

Fresh 14 +

Recycle 11

(I) Industrial

Process 3 314 317(Recycle

263** + Reuse

54*)

Recycle 263** +

Reuse 54*

Washing 4

10 14 Fresh

Boiler 2

73 75 Fresh

Cooling 2

40 42 Fresh

Others 1

110 111 (Fresh 49 +

Recycle 62**)

Scrubber-11 +

Chilling Plant-100

Industrial Total

12 547 559 (Fresh 180 +

Recycle 379)

Fresh 180 +

Recycle 379

Grand Total (A+B+C)

22 577 599 (Fresh 209 +

Recycle 390)

Fresh 209 +

Recycle 390

Note: Unit will achieve Zero Liquid Discharge.

Domestic waste water will be treated in STP plant and recycle (11 KLD) it for gardening purpose.

Ice from chilling plant reuse in the process.

* 54 KLD boiler live steam reuse in process.

** RO permeate and MEE condensate total 325 KLD water recycle (263 KLD in process and 62 KLD

in chilling plant).






of 174

Category Existing

KLD

Proposed

(Additional)

KLD

Total after

Expansion

KLD

Remarks

(E) Domestic

3.5 7.5 11 Recycle in

Gardening

(F) Industrial

Process 0 310 310

Washing 4 10 14

Boiler 0.1 10.9 11

Cooling 0.2 10.8 11

Others 1 10 11 Scrubber


water

5.3 351.7 357


Domestic waste water will be treated in STP plant and recycle (11 KLD) it for gardening purpose. Ice

from chilling plant reuse in the process.

* 54 KLD boiler live steam reuse in process.

** RO permeate and MEE condensate total 325 KLD water recycle (263 KLD in process and 62 KLD in

chilling plant).


[In-house ETP (Primary, Secondary, Tertiary), MEE, Spray Dryer, STP etc..

ETP: 360 KLD

STP: 15 KLD

MEE: 240 KLD



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Not Applicable.


Unit will achieve Zero Liquid Discharge. For this unit will install RO and MEE.

RO permeate and MEE condensate total 325 KLD water recycle (263 KLD in process and 62 KLD

in chilling plant).

54 KLD boiler live steam reuse in process.

Domestic waste water will be treated in STP plant and recycle (11 KLD) it for gardening purpose.


Domestic: Domestic waste water will be treated in STP plant

and recycle for gardening purpose

Industrial: The effluent generation form plant will be treated

in ETP treatment system, RO system and MEE

PROPOSED FLOW DIAGRAM OF EFFLUENT TREATMENT PLANT


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plant. RO permeate and MEE condensate will be

recycle in the process.

In case of Common facility (CF) like CETP, Common Spray dryer, Common MEE, CHWIF etc.

Name of Common facility (CF) (For waste water treatment)

--




Proposed Water Balance Diagram


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Domestic waste water will be treated in STP plant and recycle it for gardening purpose.

* 54 KLD boiler live steam will be reuse in process.

** RO permeate and MEE condensate total 325 KLD water recycle (263 KLD in process and 62 KLD in

Chilling plant).

Note: Boiler (10 KLD) include water scrubber loss, Boiler steam loss and coal handling.


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Total reuse 390 KLD

Source of waste

water for reuse

with quantity in KLD

(From where it is

coming)

Application area

with quantity in

KLD (Where it is

used)


water to be reused

(COD, BOD, TDS etc.)

Remarks

regarding

feasibility to

reuse i.e.

Domestic: 11 Gardening : 11 pH: 6.5-7.5

TDS: 300-400 mg/l

COD: <50 mg/l

BOD: <20 mg/l

It meets surface

discharge norms

RO permeate: 250 Process: 263

Chilling Plant: 62

pH: 7.0-7.5

TDS: <275mg/l

COD: <25 mg/l

BOD: <10 mg/l

TSS: 10-20 mg/l

Oil & Grease: Nil

It could be use

for process and

chilling plant.

MEE condensate: 75 pH: 6.5-7.5

TDS: 150-200 mg/l

COD: 100-200 mg/l

TSS: 10-15 mg/l

E Air



Existing & Proposed

Sr.

no.

Source of

emission

With

Capacity

Stack

Height

(meter)

Type of

Fuel

Quantity of

Fuel

MT/Day

Type of

emissions i.e.

Air Pollutants

Air Pollution

Control

Measures

(APCM)

Existing


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1 Boiler (1000

kg/hr)

20

Bio coal

1.67

PM-150

mg/NM3

SO2- 100 PPM

NOx- 50 PPM

Multi Cyclone

Separator, Bag

filter & Scrubber

2

Hot air

generator-

Nos. 6(Cap of

each is 1 lac

kcal/hr)

3

D.G Set

(400 KWH)

(Stand by) 11

Diesel

16.67 lit/day

Adequate stack

height and

acoustic

enclosure

Proposed

1 Boiler

(4 TPH) 30

Coal 29.8 MT/day

PM-150

mg/NM3

SO2- 100 PPM

NOx- 50 PPM

Multi Cyclone

Separator, Bag

filter & Scrubber 2

Boiler

(4 TPH)

3

Hot air

generator-

Nos. 3(Cap of

each is 2 lac

kcal/hr)

30

Dust Collector &

Scrubber

4

D.G Set (400

KWH) (Stand

by) 11 Diesel

16.67 lit/day PM-150

mg/NM3

SO2- 100 PPM

NOx- 50 PPM

Adequate stack

height and

acoustic

enclosure


Existing & Proposed

Sr.

no.

Specific Source

of emission

(Name of the

Product &

Process)

Type of emission

Stack/Vent

Height

(meter)


Measures

(APCM)

Existing

1 Spray Dryer – 4

Particulate Matter: 150 11 Scrubber & Dust


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Nos.

(Cap: 1000 Lit/Hr

Each)

mg/Nm3 Collector

2

Tray Dryer Total

No. 4 Each

Capacity 400

Trays

11

Scrubber & Dust

Collector

Proposed

1

Tray Dryer Total

No. 4 Each

Capacity 200

Trays

Particulate Matter: 150

mg/Nm3 11

Scrubber & Dust

Collector

2 Reactors -4 Nos. --- 11 Water Scrubber

-


FUGITIVE EMISSION

Sr.

No.

Source Probable

Pollutant

Emission

Control Measures/ APCM

1 Solvent storage

tank

Air pollutant

(VOC)

Carry out work place area monitoring to find out

concentration level in ambient air

Close handling system

Provision of breather valve cum flame arrester.

2. Solvent recovery

system

Air pollutant

(VOC)

Solvent recovery system with steam condensation

system.

Pumps & motors are mechanical seal type.

3 Handling of raw

material bags in

storage area

Air pollutant

(PM)

Provision of exhaust ventilation

Provision of PPE

Provision of Job rotation to reduce exposure

4 Flange joints of

pipeline, pump &

motors

Air pollutant

(VOC)

Routine & periodic inspection to check leakage

Preventive maintenance, Follow SOP for

maintenance

Pumps & motors will be mechanical seal type

LDAR program will be followed.


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5 Solid raw

material

transferring to

reactor

Air pollutant

(PM)

Hopper will be provided with powder transfer system

6 Liquid raw

material

transferring to

reactor

Air pollutant

(VOC)

Feeding of liquid raw material will be carried out by

closed pipeline and mechanical seal pump.

7 Loading

/unloading at

storage area

Air pollutant

(VOC)

Unloading through pipeline to tank in a close system.

F Hazardous waste


Existing & Proposed

i Sr.

no

.

Type/Name

of Hazardous

waste

Specific

Source of

generation

(Name of the

Activity,

Product etc.)

Categor

y and

Schedul

e as per

HW

Rules.

Quantity

(MT/Year)

Management of

HW

Existi

ng

Propos

ed

Total

1 Used Oil Maintenance 5.1 3.6 30 33.6 Collection,

storage,

transportation,

Disposal by selling

to Registered

refineries.

2 Discarded

containers/Ba

gs/Linears

Packing

Materials

33.1 48 48 96 Collection,

Storage,

Decontamination,

Reuse & sell to

authorized vendor.

3 ETP Sludge ETP 35.3 -- 1200 1200 Collection,

Storage,

Transportation

and sent to TSDF


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site for secured

land filling.

4 Distillation

Residue

Production

Process: Acid

Dyes

(A.Q./Condens

ed), Disperse

Dyes(A.Q.

/Condensed)

20.3 -- 30 30 Collection,

Storage,

Transportation

and disposal for

co-processing

facility.

5 Process

waste

Process 28.1 -- 360 360 Collection,

Storage,

Transportation

and disposal for

co-processing.

6 MEE salt MEE plant 35.3 -- 2780 2780 Collection,

Storage,

transportation and

Disposal at TSDF

Site- for secured

landfill.

7 Scrubber

Solution

Scrubber

(Spray Dryer)

-- 360 3600 3960 Collection,

Storage and

recovery of

blended Dyes-

Black and Brown.

8 Recovered

Solvent

Production

Process: Acid

Dyes (A.Q./

Condensed),

Disperse Dyes

(A.Q./

Condensed).

28.6 -- 4132.5 4132.5 Collection,

Storage & recover

and reuse

internally.

9 Spent

Carbon

From Effluent

Treatment

plant

26.1 -- 18 18 Collection,

Storage,

Transportation

and disposal at


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CHWIF for co-

processing.


(For HW management)

Membership letter from

BEIL is attached as

annexure - VII

iii Details of Non-Hazardous waste & its disposal(MSW and others) Fly ash (430 MT/Year):

Collection, Storage,

Transportation and sell to

brick manufacturer.


i Types of solvents, Details of Solvent recovery, % recovery, reuse of recovered Solvents etc.

Sr.

No. Name of Product Name of Solvent

Total Quantity

of solvent in

MT/Month

Quantity of

solvent

recovered in

MT/Month

%

Recover

y

1. Acid Dyes

(A.Q./Condense)

Xylene / Dimethyl

Formamide 2.5 2.375 95

2. Disperse Dyes

(A.Q./Condense)

Dimethyl Formamide

/ Xylene / Toluene 2.0 1.9 95

3. Disperse Violet 26 Dimethyl Formamide 655.98 629.74 96.0

4. Disperse Yellow 82 Methanol 405 390 96.3

5. Disperse Red 60 Methanol 91.5 87 95.0

6. Disperse Blue 354 Dimethyl Formamide 61.02 58.47 95.8

Methanol 63.56 62.29 98.0

7. Disperse Yellow 184 Methanol 122.23 119.3 97.6


Solvent/ Chemical handling: The VOC emission in terms of handling losses will be reduced by

storing solvents in a drum and handling solvent/raw material feeding will be carried out by

pumps.


Storage details Name of major Hazardous

chemicals

Remarks


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Storage tanks

Acetic Acid, H2SO4, HCl,

Methanol, Dimethyl

Formamide, Xylene,

Drum/Barrel storage Toluene

Applicability of PESO: Unit will take the permission after getting CCA.




the study area of 10 km radial distance from project site for the period March to May 2018. Ambient Air

Quality monitoring was carried out for PM10, PM2.5, SO2, NOx, CO & VOC at eight locations, including the

project site. Values conform to the prescribed standards for Ambient Air Quality. The incremental Ground

Level Concentration (GLC) has been computed using ISCST3. The resultant concentrations are within the

NAAQS.




During SEAC meeting on 11/02/2020, Committee noted that the proposal is for expansion. This unit has valid

CC&A for existing unit. Copy of CC&A, its compliance report is submitted. PP ensured that there are no court

cases pending and no public complaints against the project. Source of water is GIDC. PP mentioned that high

COD/TDS effluent generated from process and washing will be treated in ETP – 1 consisting of primary ETP

followed By MEE – 1, condensate of MEE – 1 will be sent to ETP – 2 consisting of primary, secondary &

tertiary treatment followed by RO, RO – Permeate will be reused/recycled back while RO – Reject will be

treated in MEE – 2, condensate from MEE – 2 will be reused/recycled back while salt generated will be

disposed at approved TSDF, while Low COD/TDS effluent generated from process, washing, boiler blow

down, cooling tower blow down and scrubber will be treated in ETP – 2 followed by RO & MEE – 2 and

permeate of RO and condensate of MEE – 2 will be reused/recycled back, hence unit will maintain complete

ZLD.

Committee deliberated on the water balance diagram presented by PP along with its treatability and noted

that the salt generation in MEE – 1 is 1.5 % and loss is 1.5 % and 97 % is condensate while in MEE – 2 the

loss is 20 – 21 % condensate is 75 % and salt generation is 4 to 5 % and asked PP to clarify the same along

with its characteristic however PP was not able to reply for the same satisfactorily.

PP has proposed two boiler and one HAG. Fuel used will be Coal.

Committee noted that PP has shown disposal of Spent Carbon in Hazardous Waste Matrix in CHWIF of

Ankleshwar and asked to clarify the same w.r.to NGT order date 10/07/2019 in Original Application No.

1038/2019 however PP could not reply for the same satisfactorily.


of 174

After detailed discussion, Committee unanimously decided to consider the proposal only after

submission of the following documents.

1. Technical Justification for 97 % condensate output in MEE – 1 against 75 % in MEE – 2 along with its

respective loss and salt generation incorporating its characteristic.

2. Revised Hazardous Waste Matrix Incorporating the Membership Certificate of CHWIF outside CPA Area

in-line with NGT order date 10/07/2019 in Original Application No. 1038/2019.

11 SIA/GJ/MIS/17797/2016 M/S. Commissioner of Fisheries

Development of Porbandar Fishery Harbour

Phase II (FH), Porbandar.

EC – Reconsideration

Category of the unit: 7(e)


Project proponent (PP) submitted online application vide no. SIA/GJ/MIS/17797/2016 dated 30/12/2019 for

obtaining Environmental Clearance.

SEIAA issued TOR to PP vide their letter dated 18/02/2017.

Public Hearing of the Project was carried out by Gujarat Pollution Control Board on 20/11/2018 at Shree

Vindyavasini Maher Samaj Vadi, Village: Kuchhadi, Ta & Dist: Porbandar.

Project proponent has submitted EIA Report prepared by M/s ULTRA-TECH, Environmental Consultancy &

Laboratory, Thane based on the TOR issued by SEIAA.

This is new project for Development of Porbandar Fishing harbor Phase II (FH), Porbandar, Dist: Porbandar

as tabulated below.

Sr. no. Type of activity Capacity

1 Fish handling capacity >88000 TPA

The project falls under Category B of project activity 7(e) as per the schedule of EIA Notification 2006.



Sr. no. Particulars Details

A


(Rs. in Crores):

392.6 Crores

Details on EMP: 4.30 Crores on EMP

Environmental Aspect Capital Expenditure

in Lakhs

Annual Recurring

Expenditure in Lakhs

Emission control measures 3.00 0.50


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Wastewater Management

(ETP/STP) 400.00 20.00

Solid Waste Management 25.00 2.00

Greenbelt 2.00 0.50

Monitoring -- 5.00

Housekeeping -- 12.00

Total 430.00 40.00

Details on CER:

As per MOEF&CC OM no 22-65/2017-IA.III dated 01/05/2018 greenfield project having investment of > 100 cr.

to ≤500 Cr shall expend 1.5 % under Corporate Environment Responsibility (CER). Total project cost is 392.6

Cr. Hence 5.88 Cr. (approx. 6 Cr) will be spent on CER as listed below. Villages Kuchhadi, Kantela and Degam

which are in proximity of fishing harbour phase II are selected for CER activity.

CER Budget as per Guidelines

S. No Description Cost in Crores

1 Health Hygiene and Sanitation – Swacchh Bharat Abhiyan 2.00

2 Education in villages around the project site 2.00

3 Solar Power/Renewable energy in villages 1.00

4 Rainwater Harvesting 1.00

Total 6.00

Details of Proposed CER Activities

CER Activity Total duration of the project: 4 years

20-21 21-22 22-23 23-24 In Lakhs

Health Hygiene and Sanitation 80 80 20 20 200

Education – School 50 50 50 50 200

Renewable Energy 40 40 10 10 100

Rainwater Harvesting 40 40 10 10 100

Total Amount in Lakhs 210 210 90 90 600

B Total Plot area ( sq. meter)

Reclaimed Area: 192380 m2

Greenbelt Area ( sq. meter) Greenbelt along boundary

45540 m2

Greenbelt on reclaimed area

18600 m2

Total Greenbelt 64140 m2


of 174

C Employment generation 26070 Nos

D Water

i

Source of Water Supply 3.7 MLD of water

requirement will be fulfilled by

Porbandar Nagarpalika. The

permission is under process

Status of permission from the concern authority. The permission is under

process


Category Quantity KLD Remarks

(J) Domestic 140

(K) Gardening

(L) Industrial

Process Ice Manufacturing 2400

Washing

Boiler

Cooling

Others: Fish Washing 1160

Industrial Total

Total (A + B + C) 3700

1) Total water requirement for the project: 3700 .KLD

2) Quantity to be recycled:40 KLD sewage and 950 KLD fish washing effluent



iii



KLD

Remarks

(G) Domestic 40 100 KLD STP will be provided

(H) Industrial

Process

Washing

Boiler

Cooling


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Others

Waste water from fish

washing/ auction hall

cleaning/ fish box cleaning

950

1000 KLD ETP will be provided


water

Total [A + B] 990

-



ETP: 1000 KLD

STP: 100 KLD


MBBR Technology


Treated water will be fully used for floor washing and fish box washing


Domestic:

Will be used for Green belt plantation

Industrial:

Will be recycled and reused

vi In case of Common facility (CF) like CETP, Common Spray dryer, Common MEE etc.

Name of CF

Not applicable



Not applicable



of 174


Total reuse KLD

Source of waste

water for reuse

with quantity in

KLD (From where

it is coming)

Application

area with

quantity in

KLD (Where it

is used)

Characteristics of

waste water to be

reused (COD, BOD, and

TDS etc.)

Remarks

regarding

feasibility to

reuse i.e.

1000 KLD ETP Reused within

fishing harbour

BOD: < 10mg/lit

Suspended solids: NIL

COD: <20 mg/lit

pH : 7.1 to 7.3

Oil & grease: < 10mg/lit

-

100 KLD STP:

MBBR - Moving

Bed Bio Reactor

technology

Green belt BOD: < 10mg/lit

Suspended solids: NIL

COD: <20 mg/lit

pH : 7.1 to 7.3

Oil & grease: < 10mg/lit

-

E Air


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No. of Boilers/TFH/Furnaces/DG sets etc. with capacities viz. TPH, Kcal/hr, MT/hr, KVA

etc. Not applicable

Sr.

no.

Source of

emission

With

Capacity

Stack

Height

(meter)

Type

of Fuel

Quantity

of Fuel

MT/Day

Type of

emissions

i.e. Air

Pollutants

Air Pollution

Control

Measures

(APCM)

1


Not applicable


Not applicable

F Hazardous wastes

(as per the Hazardous and Other Wastes (Management and Transboundary Movement)

Rules 2016.

i Sr. No. Type of Waste Quantity Mode of Disposal

Hazardous Waste

1 Used Oil (HW Cat. 5.1) 45 MT/Annum GPCB authorized

recyclers


(For HW management)

Will be obtained

iii Details of Non-Hazardous waste & its disposal (MSW and others)

Non Hazardous and Organic Waste

1 Fish Waste 9000 kg/day Fish meal and poultry

feed production

factories in GIDC 2

ETP sludge (only fish

washing) 30 kg/day

3 Scrap Metal ~12 MT/Annum Authorized recyclers

4 Discarded Nets ~10 MT/Annum Authorized recyclers

5 STP sludge ~1.5 kg/day Used as manure in

greenbelt





of 174

the study area of 5 km radial distance from project site for the October to December 2016. Ambient Air Quality

monitoring was carried out for PM2.5, PM10, SO2, NOx and CO at eight locations, including the project site.

Values conform to the prescribed standards for Ambient Air Quality. The incremental Ground Level

Concentration (GLC) has been computed using AERMOD. The resultant concentrations are within the

NAAQS.




During the meeting on 09/01/2020, Committee noted that proposal is for development of Porbandar fishing

harbor phase II (FH), Porbandar. Committee deliberated on the plant layout by PP in which phase – II is

proposed in adjacent area of Super Gas installation compound wall and asked PP to justify their site w.r.to

source of ignition and air vapour. PP clarified that the proposed site is as per the guidelines of OSD – 144 and

is located @ 500 m from their proposed phase – II project. Committee asked PP to explore the possibility of

increasing the height of compound wall w.r.to LPG super gas station location within the periphery of 500 m.

Committee asked PP to show layout map of the sensitive area located in the periphery of 10 KMs. PP

mentioned that Flamingo Habitats is located @ 6 Kms, Mangroves in Porbandar Creek is located @ 3.2 KMs,

Porbandar Bird Sanctuary is located @ 5.5 KMs, Turtle Nesting Site is located @ 4 KMs. Committee asked

PP to show conservation plan for the schedule – I species viz Flamingo & Turtle Nesting located within 10

KMs area along with Mangroves Conservation. PP mentioned that they have not prepared the plan however

there are no turtles or marine mammals were observed during study period.

PP explained in detail regarding trawlers & gillnetters in the proposed facility along with its description.

Committee noted that PP has not satisfactorily addressed all the issued raised during Public Hearing and

were asked to submit the same in tabular form along with their comments and compliance status of

commitments made to Public during Public Hearing.

Committee asked PP to justify the difference in water consumption & generation along with reuse/recycle

from the ToR granted by SEIAA, Gujarat. PP was not able to reply satisfactorily for the same. Further

Committee asked PP to justify the concentration PM10 (Max) – 105 ug/m3 in AAQ1 which is more than the

prescribed NAAQ norms. PP was not able to satisfactorily reply for the same.

Committee asked PP regarding capital dredging of 1,50,000 m3 along with its mathematical modeling for

dredging however PP was not able to satisfactorily address the same. Committee also noted that due to

proposed project activity there will be permanent loss of benthic diversity in reclamation area.

After detailed discussion, Committee unanimously decided to defer the proposal and consider the

proposal only after satisfactory submission of the following details.

1. Explore the possibility of increasing the height of compound wall w.r.to LPG super gas station location

within the periphery of 500 m to avoid any source of ignition.

2. Conservation Plan for Schedule – I species viz (1) Flamingo & (2) Sea Turtle along with Mangroves


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Conservation Plan.

3. Issues raised during Public Hearing in Tabular Form along with their comments and current Status of

commitments made to Public during Public Hearing.

4. Technical Justification Regarding Change in Water Consumption & Waste Water Generation along with

Reuse/Recycle from ToR granted by SEIAA, Gujarat.

5. Justification Regarding Higher value of PM10 (Max) – 105 ug/m3 in AAQ1 location as compared to NAAQ

norms.

6. Mathematical Modeling regarding dredging of 1,50,000 m3 and its anticipated Environmental Impacts &

Mitigation Measures for the same.

7. Hazardous Waste Matrix as per HWR – 2016 along with Other Solid Waste with their Quantity and Final

Disposal for the same.

8. Revised Need based CER along with EMP with Fixed Capital Cost and Recurring Cost.

Project proponent made presentation for the above mentioned query dated 09/01/2019 for the above

mentioned points.

PP presented replied as below:

1. PP presented that boundary wall of 2.4 m will be provided as per standards prescribed for industrial

buildings by National Building Code of India, 2005.

2. PP presented conservation plan for schedule – I species viz (1) Flamingo & (2) Sea Turtle along with

Mangroves Conservation Plan.

3. PP presented point wise compliance of Issues raised during Public Hearing in Tabular Form along with

their comments and current status.

4. PP presented technical justification Regarding Change in Water Consumption & Waste Water Generation

along with Reuse/Recycle from ToR granted by SEIAA, Gujarat mentioning that during pre-feasibility

studies total boats considered for fishing harbor design were 2922 and as per CICEF recommendations,

final fishing harbor design with European standards was approved for 4500 boats. Hence, final water

requirement was increased to 3.7 MLD and EIA report was prepared considering revised higher water

requirement.

5. PP presented Justification Regarding Higher value of PM10 (Max) – 105 ug/m3 in AAQ1 location as

compared to NAAQ norms mentioning that it could be attributed due to strong winds during coal handling

at jetty as Porbandar port handles coal, bauxite, limestone, cement, LPG etc.

6. PP presented Mathematical Modeling regarding dredging of 1,50,000 m3 and its anticipated

Environmental Impacts & Mitigation Measures for the same.

7. PP presented Hazardous Waste Matrix as per HWR – 2016 along with Other Solid Waste with their

Quantity and Final Disposal for the same.

8. PP presented revised Need based CER along with EMP with Fixed Capital Cost and Recurring Cost.

Committee deliberated on the reply submitted by PP and noted that PP has complied to all the queries


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satisfactorily except Conservation Plan for Schedule – I species and Mathematical Modeling regarding

dredging of 1,50,000 m3 and asked to address the same again.

After detailed discussion, Committee unanimously decided to consider the proposal only after

submission of the following documents.

1. Revised Conservation Plan for Schedule – I species viz (1) Flamingo & (2) Sea Turtle along with

Mangroves Conservation Plan.

2. Mathematical Modeling regarding dredging of 1, 50, 000 m3 and its anticipated Environmental Impacts &

Mitigation Measures for the same.

12 SIA/GJ/IND2/45912/2019 M/S. Pooja Enterprise

Plot No. DP: 42 & 43, Saykha GIDC,


Screening & Scoping



This office has received an application vide their online proposal no. SIA/GJ/IND2/45912/2019 dated

02/12/2019 made by project proponent (PP) regarding grant of Terms of Reference [ToR] for preparation of

EIA/EMP report.

Project proponent (PP) has submitted Form-1, PFR and relevant details/information.

This is expansion of existing unit proposes for manufacturing of synthetic organic product as tabulated below:

SR.

NO PRODUCT NAME CAS No.

Exiting

MT/Month

Additional

MT/Month

Total

proposed

Product

MT/Month

Non EC Product

1 Cuprous Chloride Anhydrous 7447-39-4 20

NIL

20

2 Magnesium Hydroxide IP (Pharma

grade) 1309-42-8 30 30

3 Magnesium Sulphate 7487-88-9 15 15

4 Sodium Hypo Chloride 7681-52-9 25 25

5 Zinc Sulphate 7733-02-0 20 20

EC Product

1 4- Chloro Resorsinol 95-88-5

NIL

20 20

2 Para Chloro Meta Xylenol 88-04-0 25 25

3 N-N Bis, (2-Chloro Ethyl) Amine

Hydrochloride 821-48-7 50 50


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Salient features of the project including Water, Air and Hazardous waste management:

Sr.

no.

Particulars Details


(Rs. in Crores):

1.28 Crores

B Total Plot area ( sq. meter) 2186.11 Sq. m.

Green belt area

( sq. meter)

500 Sq. m.

C Employment generation

D Water

i



GIDC water Supply



Sr

No Category

Existing

KLD

Additional

KLD

Total

KLD

4 1-(2,3 Di hloro Phenyl) Piperazine

hydrochloride (ARIP-INT) 119532-26-2 12 12

5 1-(4-Methoy Phenyl) Piperazine Di

hydrochloride 38869-47-5 15 15

6 Cetyl Chloride 6004-24-6 40 40

7 Palmitoyl Chloride 112-67-4 15 15

8 Cetyl Pyridium Chloride 6004-24-6 30 30

9 Anthranilic Acid 118-92-3 30 30

10 Meta Amino Acetanilide 103-84-4 35 35

11 Chloro Phthalic Acid 21739-92-4 50 50

12 4-Methyl 3 Nitro Aniline 119-32-4 50 50

13 4-Hydroxy N-Methyl Quinoline 607-67-0 15 15

TOTAL 110 387 497


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1. Domestic Purpose 1.5 1.5 3.0

2.

INDUSTRIAL

Process 1.6 4.0 5.6

Boiler NIL 3.0 3.0

Cooling NIL 3.0 3.0

Scrubber NIL 19.0 19.0

Total Water Consumption and

Generation (Domestic) 1.5 1.5 3.0

Total water Consumption and

Generation (Industrial ) 1.6 29.0 30.6


2) Quantity to be recycle: NIL



Sr

No Category

Existing

KLD

Additional

KLD

Total

KLD

1. Domestic Purpose 1.2 1.2 2.4

2.

INDUSTRIAL

Process NIL 11.5 11.5

Boiler

NIL

0.5 0.5


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Cooling NIL

1.0 1.0

Scrubber NIL

*33.6 *33.6

Total Water Consumption and

Generation (Domestic) 1.2 1.2 2.4

Total water Consumption and

Generation (Industrial ) NIL 13.0 13.0

Note; The scrubber water includes the daily quantity of Spent HCl, Sodium Bi Sulphite. The management

of the same is tabulated in Hazardous Waste Management part.


[In-house ETP (Primary, Secondary), MEE, Stripper, Spray Dryer, STP etc..

Sr. no Name of Equipment Capacity Nos.

1 Collection Tank 15.00 KL 1

2 Primary Settling Tank 5 m3 1

3 Filter Press 900*900*24 1

4 Holding Tank 25.00 KL 1


of 174





Total 13.0 KLD Industrial wastewater generation from Manufacturing Process and Other ancillary

Operation, which is treated primary Effluent Treatment Plant and Discharge though common

Facility.


Not applicable


Domestic:

Domestic 2.4 KLD sewage generated will be disposed through soak pit/septic

tank.

Industrial:

Total 13.0 KLD Industrial wastewater generation from Manufacturing Process

and Other ancillary Operation, which is treated primary Effluent Treatment

Plant and Discharge though common Facility.

vi In case of Common facility (CF) like CETP, Common Spray dryer, Common MEE etc. , Name of CF

No required Common Facility



Common Spray Dryer of Chhatral Environment Management System Pvt Ltd


Collection cum Neutralizer tank

Primary tretmet Filter Press Common Facility


of 174

viii Reuse/Recycle details (NIL KLD)

Total reuse NIL KLD

Source of waste

water for reuse

with quantity in

KLD (From where it

is coming)

Application area

with quantity in

KLD (Where it is

used)



BOD, TDS etc.)

Remarks

regarding

feasibility to

reuse i.e.

- - -

E Air



Sr

no Stack attached to

Stack

height in

meter

Fuel Consumptio

n APCM Remark


of 174

1

Thermic Fluid

Heater (3 Lac

Kcal/hr)

15.0

Diesel (E)

Or

Agro waste

(P)

0.150

MT/Day or

2 MT/Day

Cyclone

Separator + Bag

Filter

Existing

2 Boiler (1 TPH) 15.0

Diesel

Or

Agro waste

0.80 MT/Day

or

2 MT/Day

Multi cyclone +

Bag filter Proposed


Sr

no Vent Attached To

Stack

height in

meter

APCM Emission Remark

1 Reaction Vessel 05

Two stage alkali scrubber

followed by water

scrubber

HCl, SO2 Existing

2 Reaction Vessel 05


followed by water

scrubber

HCl, SO2 Proposed

3 Chlorination 05


followed by water

scrubber

HCl, SO2 Proposed


As below:

The entire manufacturing activities will be carried out in the closed reactors and regular checking and

maintenance of reactors will be carried out to avoid any leakages.

The tank vents will be equipped with either a carbon filter or an oil trap to prevent water vapor from

entering the tank as it breathes.

All the motors of pumps for the handling of hazardous chemicals will be flame proof and provided with

suitable mechanical seal with stand-by arrangement

Control of all parameters on a continuous basis will be done by adequate control valves, pressure

release valves and safety valves etc.

All the flange joints of the pipe lines will be covered with flange guards.

All the raw materials will be stored in isolated storage area and containers tightly closed.


of 174

There will also be provision of adequate ventilation system in process plant and hazardous chemical

storage area.

A regular preventive maintenance will be planned to replace or rectify all gaskets, joints etc.

The unit will also develop green belt within the factory premises to control the fugitive emission from

spreading into surrounding environment

F Hazardous wastes


i

Sr.

No

Types of

Hazardous

Waste

Sources Category Existing

MT/Year

Addition

MT/Year

Ultimate

MT/Year Disposal

1 ETP Sludge ETP Area 35.3 NIL 8 8

Collection,

storage,

Transportation

and Dispose to

Active TSDF

Site

2 Used Oil Plant

Machinery 5.1 NIL 1 1

Collection,

storage, Reuse

within

premises.

3

Discarded

Container/

Bags

Material

Storage

and

Handling

33.1 0.5 9.5 10.00

Collection,

storage,

Transportation

and Dispose to

Registered

Recycler

4 HCL 30% Scrubbing

Media 26.1 NIL 2880 2880

Collection,

storage,

Transportation

and Send to

Rule-9

Authorized

parties


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5 Sodium Bi

Sulphite

Scrubbing

Media 26.1 NIL 7200 7200

Collection,

storage,

Transportation

and Send to

Rule-9

Authorized

parties

6 Spent

Solvent

Manufacturi

ng Process 26.3 NIL 6800 6800

Collection,

storage, and

reuse in next

betch after in

house

distillation

7 Solvent

Residue

Distillation

Unit 26.3 NIL 611 611

Collection,

storage,

transportation

and send to

CHWIF

8 Sodium

Acetate

Meta Amino

Acetanilide,

Chloro

Phthalic

Acid, 4-

Hydroxy N-

Methyl

Quinoline

26.1 NIL 1961 1961

Collection,

storage,

Transportation

and Send to

Rule-9

Authorized

parties

9

Spent

Sulphuric

Acid

4-Methyl 3

Nitro

Aniline

26.1 NIL 4529 4529

Collection,

storage,

Transportation

and Send to

Rule-9

Authorized


of 174

parties

10 Acetic Acid

4-Methyl 3

Nitro

Aniline, 4-

Hydroxy N-

Methyl

Quinoline

26.1 NIL 1050 1050

Collection,

storage, in

which 810

MT/Year reuse

in 4-Hydroxy N-

Methyl

Quinoline

process and

remaining 240

MT/Year sell to

Rule-9

Authorized

parties


(For HW management)

We will obtained after getting NOC

from GPCB


of 174


(MSW and others)

Not applicable


i Types of solvents, Details of Solvent recovery, % recovery. reuse of recovered Solvents

Sr.

No

Name of

Product Solvent

Total

Solvent

Input (Kg)

Qty of

Solvent

Recycled

(Kg)

Qty of

Losses

(Kg)

% recovery %

Losses

1. Para Chloro

Meta Xylenol

Parachlor

o ethylene 3906 3711 195 95 5

2.

N-N Bis, (2-

Chloro Ethyl)

Amine

Hydrochloride

EDC 1875 1719 156 92 8

3.

1-(2,3 Di

hloro Phenyl)

Piperazine

hydrochloride

(ARIP-INT)

Acetone 5091 4741 350 93.2 6.8

Methanol 1818 1738 80 95.6 4.4


of 174

4

1-(4-Methoy

Phenyl)

Piperazine Di

hydrochloride

Mix xylene 4483 4138 345 92 8

N butanol 4483 4138 345 92 8

5

Cetyl

Pyridinium

Chloride

Methyl &

Ethyl

Ketone

4000 3700 300 93 8

Acetone 2000 1900 100 95.0 5.0


Sources of fugitive emissions include storage of chemicals, solvents storage, loading and

unloading section, raw material handling and, hazardous waste storage area Measures:

The fugitive emissions in terms of handling losses will get reduced by proper storage and handling.

Hazardous chemicals will be stored as per standard criteria. • Periodically monitoring will be

carried out as per the post project monitoring plan.

Proper ventilation in storage & production area shall be ensured

All materials must be stored in suitable packing to prevent contamination of air

Enclosed system & efficient procedures for materials charging shall be ensured.

Procedures for start-up shut down, operation & maintenance procedures shall be established &

maintained.

The coverage of greenbelt around the plant also acts as natural barrier to stop carrying of dust


of 174

along with the wind current.


Storage details Name of major Hazardous

chemicals

Remarks

Storage tanks Methanol

EDC

Mix Xylene

Acetone

Drum/Barrel storage Anthraniliic Acid

Acetic Acid

Nitric Acid 60%

Cylinder Chlorine Tonner


Technical presentation was made by the project proponent with consultant/expert Satva Environment

Consultancy, Ahmedabad during SEAC meeting dated 11/02/2020.

Committee noted that this proposal is for expansion of project located in GIDC - Talod. PP has submitted

compliance of earlier CC&A. PP mentioned that there are no any court case or public complaints pending

against this unit. Source of water is GIDC. PP mentioned that effluent generated from process, cooling blow

down & boiler blow down will be treated in ETP and treated effluent will be sent to Common Spray Dryer of

Chhatral Environment Management System Pvt Ltd for final treatment and disposal. PP has proposed one

steam boiler. Fuel used will Diesel. PP has addressed Hazardous Waste as per HWR – 2016.

After detailed discussion, it was decided to recommend the project to SEIAA Gujarat for grant of

Terms of Reference.

Considering the above project details, after detailed discussion, the terms of reference (ToR) were prescribed


of 174

as below and as per the standard TOR for the Synthetic Organic Chemical projects recommended by SEAC

vide letter no. EIA-10-GEN-21/1480 dated 14/09/2017 and approved by SEIAA in its 12th meeting dated

16/09/2017 for the EIA study to be done covering 10 Km radial distance from the project boundary.

1. Details with respect to justification for proposed expansion: (1) To address proportionate

availability of space for production plant. (2) To address proportionate availability of storage area

for raw materials finished goods, utilities considering fire-safety norms & PESO standards and

goods carrier movement within premises. (3) To address proportionate captive/common

infrastructure available to accommodate additional load due to proposed expansion. (4)

Environment impact and its mitigation measures for common/ captive infrastructure due to

proposed production.

2. Compliance of MoEFCC’s OM dated 01/05/2018 regarding “Corporate Environment Responsibility”

(CER). Fund allocation for Corporate Environment Responsibility (CER) shall be made as per

MoEFCC’s O.M. No. 22-65/2017-IA.III dated 01/05/2018 for various activities therein. The details

of fund allocation and activities for CER shall be incorporated in EIA/EMP report.

3. Explore the use of renewable energy to the maximum extent possible. Details of provisions to

make the project energy-efficient through energy efficient devices and adoption of modes of

alternative eco-friendly sources of energy like solar water heater, solar lighting etc. Measures

proposed for energy conservation.

4. Leak Detection and Repairing Programme (LDAR) for all the volatile organic solvent proposed for

use in-house with detailed chemical properties including vapor pressure. LDAR shall endeavor

prevention of losses of solvents to the best minimum extent.

5. Safety precautions including flame proof electric fittings to be taken to avoid fire hazard during

unloading, storage, transportation, handling and processing of Solvents.

6. Status of all the applicable Rules, Acts, Regulation, Clearances in a tabular form.

7. Characteristic of effluent to be sent to Common Spray Dryer Facility of Chhatral Environment

Management System Pvt Ltd.

8. MoU for all the Hazardous Waste to be disposed under Rule – 9 as per HWR – 2016.

9. Membership Certificate from Common Facility (mentioning total capacity, consented quantity,

occupied capacity and spare capacity and norms of acceptance of effluent from member units) in-

line with the direction given by GPCB vide Letter No. GPCB/P-1/8-G (5)/550706 dated 08/01/2020.

10. Details of Nitration process Safety along with its SOP [Standard Operating Procedure].

The TOR prescribed as above and as per the standard TOR approved by SEIAA and the model ToRs

available in the MoEFCC’s sector specific EIA Manual for ‘Synthetic Organic Chemical Industry’ shall be

considered as generic TORs for preparation of the EIA report in addition to all the relevant information as per

the generic structure of EIA given in Appendix III in the EIA Notification, 2006.

Further Project Proponent may be advised to submit final EIA Report with EC application within 100 days


of 174

from the date of issuance of this ToR to expedite processing of Environment Clearance application.

The project proponent shall have to apply for Environmental clearance through online portal

http://environmentclearance.nic.in/ along with final EIA report.

13 SIA/GJ/IND2/47233/2019 M/S. Mohan Polyfab Private Limited

Plot No. C-42, Saykha Industrial Estate,


Screening & Scoping


Project status: New



EIA/EMP report.


This is new unit proposes for manufacturing of synthetic organic product as tabulated below:

SR.

NO.

NAME OF THE PRODUCTS CAS NO. QUANTITY

MT/MONTH

END-USE OF PRODUCT

1 Bronner's Acid 68189-32-2 Dyes

2 Aniline 2:4 Disulphonic Acid 137-51-9 Dyes

3 Aniline 2:5 Disulphonic Acid 98-44-2 Dyes

4 K - Acid 118-03-6 Dyes

5 Bromamine Acid 116-81-4 Dyes

6 PNTOSA 121-03-9 Dyes

7 G - Salt 842-18-2 Dyes

8 4 Sulpho Hydrozone 118969-29-2 Dyes

9 5 Sulpho Hydrozone 68645-45-4 Dyes

10 4 Sulpho Anttanilic Acid 98-43-1 Dyes

11 Sodium Napthoniate 130-13-2 Dyes

12 Copper Formazone / 4 Sulpho F

Base

77840-01-8 Dyes

13 HEGN 124448-55-1 Dyes

14 Blue HEGN-III -- Dyes

15 Blue 49 Base 12236-92-9 Dyes

16 4 Nitro 4 Amino Diphyniline

amine 2 Sulfonic Acid (4

NADPSA)

91-29-2 Dyes

http://environmentclearance.nic.in/


of 174

17 Mesitylen Acid (M Acid) 108-67-8 Dyes

18 Dichlone (2:3 Dichloro 1:4

neptha Quinone) 117-80-6

Dyes

19 3,3 Dichloro Benzidine

Dihydrochloride 612-83-9

Dyes

20 4 Chloro 2 Amino Phenol 95-85-2 Dyes

21 4-Aminotoluene 3-Sulphonic

Acid (4 B Acid) 88-44-8

Dyes

22 4 Nitro 2 Amino Phenol 99-57-0 Dyes

23 Benzoyl H Acid 117-46-4 Dyes

24 2 Chloro 5 Toludine 4 Sulphonic

Acid 516-02-1

Dyes

25 3,3 Dimethyl 4,4 Diamino

Diphenyl 838-88-0

Dyes

26 Fast Brodeaux GP Base 96-96-8 Dyes

27 Fast Red B Base & Fast Scarlet

R Base 27165-17-9

Dyes

28 Blue B Base 119-90-4 Dyes

29 Chloranil 118-75-2 Dyes

30 2-Chloro 4 Aminotoluene 5

Sulphonic Acid (2 B Acid)

88-51-7 Dyes

31 Ethyl C Acid 541-41-3 Dyes

32 MNPT 119-32-4 Dyes

TOTAL

400 MT/MONTH




Sr.

no.

Particulars Details

A


(Rs. in Crores):

23.0 Crores

B Total Plot area ( sq. meter) 5000.0 Sq. m.


of 174

Green belt area

( sq. meter)

1650.0 Sq. m.

C Employment generation

Direct : 50

Indirect : 25

D Water

i



GIDC water Supply


GIDC/DEE(WS)/BRH/748

Dated: 02/11/2018

ii


Category

Quantity

KLD

Remarks

(M) Domestic 10.0

(N) Gardening 2.0

(O) Industrial

Process 122.3

Washing 5.0

Boiler 20.0

Cooling 4.0

Others/Scrubber 3.0

Industrial Total

154.3

Total (A + B + C)

166.3


of 174

1) Total water requirement for the project: 163.3.KLD

2) Quantity to be recycled: 50.0 KLD


(Total water requirement: 163.3 KLD = 116.3 KLD Fresh water + 50.0 KLD Recycled water)

iii



KLD

Remarks

(I) Domestic 8.0

(J) Industrial

Process 228.0

Washing 5.0

Boiler 0.7

Cooling 0.3

Others/Scrubber 3.75

Total Industrial

waste water

237.75

Total [A + B] 245.75

-



ETP -1 : 166.0 KLD

ETP-2 : with MEE Plant : 68.0 KLD

DETAILS OF EFFLUENT TREATMENT PLANT

First all non-toxic and biodegradable streams (low & medium COD& TDS) of wastewater shall pass

through Oil & Grease Removal Tank (OGRT-01) where floating O & G shall be removed manual from

top and collected in O & G Collection Tank (OGCT-01). Then effluent shall be collected in Equalization

cum Neutralization tank-01 (ENT-01) where the continuous addition and stirring of Lime solution is


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pumped to maintain neutral pH of wastewater from Lime Dosing Tank (LDT-01). Mixer is provided at

bottom of the ENT-01 to keep all suspended solids in suspension and for proper mixing.

Then after, neutralized wastewater shall be pumped to Flash Mixer-01 (FM-01). Alum and

Polyelectrolyte shall be dosed from Alum Dosing Tank (ADT-01) and Polyelectrolyte Dosing Tank

(PEDT-01) respectively by gravity into FM-01 to carry out coagulation by using a Flash Mixer.

Then after, coagulated wastewater shall be settled in Primary Settling Tank-01 (PST-01). Clear

supernatant from PST-01 shall be passed in Aeration Tank (AT-01). Here, biodegradation of organic

matter of the wastewater shall be carried out by bacteria (suspended growth) in the AT-1 and for that

oxygen shall be supplied by 2 nos. of air blowers (B-01) through diffusers. Air blowers also keep MLSS

in suspension. Nutrients will be added from NDT-01 to Aeration Tank for growth of Bacteria.

Then after, wastewater shall go to Secondary Settling Tank (SST-01). Here, the suspended solids shall

be settled. Sludge shall be removed from bottom of SST-01 and pumped to AT-1 to maintain MLSS and

excess activated sludge shall be sent to Sludge Sump (SS-01-A/B).Clear effluent is the collected in

Intermediate Sump (IS-01) by gravity.

Thereafter, the wastewater shall be passed through Pressure Sand Filter (PSF-01) to remove left out

TSS and Activated Carbon Filter (ACF-01) for final effluent polishing. After tertiary treatment, effluent

shall be collected in Treated Effluent Sump (TES-01) before sent to RO-01 for further treatment. RO-01

permeate water shall be collected in RO Permeate Water Tank (ROPWT-01) before reuse in plant. RO-

01 reject shall be sent to MEE Feed tank (MFT-01) for further treatment.

Sludge settled in PST-01 and excess sludge from SST-01 shall be collected in Sludge Sumps (SSs-01-

A/B) then sludge shall be pumped to Centrifuge (CFs-01) where poly shall be mixed from poly Dosing

Tank-2 (PDT-02) with sludge to increase efficiency of centrifuge sludge dewatering. Then, dewatered

sludge shall be stored in in HWSA and then ultimate disposal to TSDF. Leachate from CFs-01 and

backwash from MGF-01 and ACF-01 shall be collected in Drain Pit and pumped back to ENT-01-A/B for

further treatment.

Treatment of high TDS effluent.

Stream II

All High TDS streams of wastewater shall be collected in Collection cum Equalization Tanks-01 (CETs-

01-A/B).Mixer is provided in CETs-01-A/B to keep all suspended solids in suspension and to provide

proper mixing. Then effluent shall be pumped to Neutralization Tank (NT-01) where Lime shall be added

from Lime Dosing tank with help of Dosing Pumps. Then after, effluent shall have sent to Flash Mixer-2

(FM-02) where Alum and poly shall be added from ADT-01 and PEDT-01 respectively. Then after,

coagulated wastewater shall be settled in Primary Clarifier (PCL-01).

Clear effluent from PCL-01 shall be collected in MEE Feed Tank (MFT-01). Then effluent shall be sent

to Multiple Effect Evaporator (MEE-01) for further treatment followed by Agitated Thin Film Dryer (ATFD-


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01) for solids dewatering. Condensate from MEE & ATFD shall collect in ME Condensate Tank (MECT-

01) and reuse for further treatment. Solids from ATFD-01 shall be collected and stored in HWSA for

disposal in TSDF.

ETP-1 : LOW COD Stream

Sr.

No. Name of Unit Tag No.

Size in Meters

(L X B X (LD+FB) Nos. MOC

Inlet Units

1. Collection cum

Equalization Tank CET-01 7.0 x 4.0 x (3.0+0.5) 1

RCC M30+

A/A Bk. Lining

Primary Treatment

2. Neutralization Tank NT-01 1.7 x 1.7 x (2.0 + 0.5) 1 RCC M30

3. Flash Mixer-1 FM-01 2.0 x 2.0 x (1.8 + 0.5) 1 RCC M30

4. Flocculator FL-01 2.0 x 2.0 x (1.6 + 0.5) 1 RCC M30

5. Primary Clarifier PCL-01 4.3 Dia x (3.0 SWD +

0.5) 1

RCC M30

Secondary Treatment

6. Aeration Tank-1 AT-01 8.0 x 4.0 (5.0 + 0.5) 1 RCC M30

7. Secondary Clarifier-1 SCL-01 4.8 Dia x (3.0 SWD +

0.5) 1

RCC M30

8. Aeration Tank-2 AT-02 7.0 x 3.5 (5.0 + 0.5) 1 RCC M30

9. Secondary Clarifier-2 SCL-02 4.3 Dia x (3.0 SWD +

0.5) 1 RCC M30

Tertiary Treatment

10. Intermediate Sump IS-01 4.0 x 4.0 (3.0+0.5) 1 RCC M30

11. Multi Grade Filter MGF-01 8.5 m3/D 1 MSEP

12. Active Carbon Filter ACF-01 8.5 m3/D 1 MSEP

13. Treated Effluent Sump TES-01 8.0 x 5.0 (4.0 + 0.3) 1 RCC M30

14. Sludge Sump SS-01 3.0 x 3.0 x (2.0+0.5) 1 RCC M30

15. Centrifuge CFG-01/02 33 m3/D 1 SS304

16. Drain Pit DP-01 3.0 x 3.0 x (3.0+0.3) 1 RCC M30

17. Lime Dosing Tanks LDTs-01-A/B 3000 Lit. 2 HDPE/PP

18. Alum Dosing Tank ADT-01 2500 Lit 1 HDPE/PP

19. Poly Dosing Tanks PDT-01/02 1000 Lit 2 HDPE

20. Nutrient Dosing Tanks NDTs-01 1000 Lit 2 HDPE


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ETP : 2 : DETAILS OF UNITS: (FOR HIGH COD & TDS STREAMS) (68 KLD Process)

Sr.

No. Name of Unit Tag No.

Size in Meters

(L X B X (LD+FB) Nos. MOC

Inlet Units

1. Collection cum

Equalization Tank-02 CET-02 5.0 x 2.5 x (3.0+0.5) 1

RCC M25+A/A

Bk. Lining

Primary Treatment

2. Neutralization Tank-2 NT-02 1.0 x 1.0 x (2.0 + 0.5) 1 RCC M25+A/A

Bk. Lining

3. Flash Mixer-2 FM-02 1.0 x 1.0 x (2.0 + 0.5) 1 RCC M25

4. Primary Clarifier -2 PCL-02 2.7 Dia x (3.0 SWD + 0.5) 1 RCC M25

Advance Treatment

5. Holding Tank HT-01 2.0 x 2.0 x (2.0+0.5) 1 RCC M25

6. Stripper ST-01 68 m3/hr 1 SS316L

7. MEE Feed Tank MFT-01 3.0 x 3.0 x (2.0+0.5) 1 RCC M25

8.

Multi Effect Evaporator

(MEE-01) with Agitated

Thin Film Dryer (ATFD-

01)

MEE-01/

ATFD-01 68 m3/hr 1 SS316L

9. Condensate Storage

Tank CST-01 2.0 x 2.0 x (2.0+0.5) 1 RCC M30


of 174


The wastewater generation will be 245.75 KL/Day. The industrial effluent (237.75 KL/Day)

generation.

Low Concentrate 166.0 KLD consist of primary, Secondary & tertiary treatment send to deep

sea discharge through GIDC pipeline.

High Concentrate from process 68.0 KLD be treated in In-house MEE plant. 50.0 KLD MEE

Condensate will be reuse in Plant premises.

Scrubber waste water will be send to end users shaving rule-9 permission.

Domestic waste water (8.0 KL/Day) will be disposed by septic tank & soak pit.




CETP Saykha, GIDC/BRH/DEE/(DRG)/324 Dated: 10/06/2019


The wastewater generation will be 245.75 KL/Day. The industrial effluent (237.75 KL/Day)

generation.

Low Concentrate 166.0 KLD consist of primary, Secondary & tertiary treatment send to deep

sea discharge through GIDC pipeline.


of 174

High Concentrate from process 68.0 KLD be treated in In-house MEE plant. 50.0 KLD MEE

Condensate will be reuse in Plant premises.




Domestic:


Industrial:

The wastewater generation will be 245.75 KL/Day. The industrial effluent

(237.75 KL/Day) generation.

Low Concentrate 166.0 KLD consist of primary, Secondary & tertiary

treatment send to deep sea discharge through GIDC pipeline.

High Concentrate from process 68.0 KLD be treated in In-house MEE plant.

50.0 KLD MEE Condensate will be reuse in Plant premises.


vi In case of Common facility (CF) like CETP, Common Spray dryer, Common MEE etc. Name of CF

CETP Saykha,


(For waste water treatment) CETP Saykha, GIDC/BRH/DEE/(DRG)/324 Dated: 10/06/2019



of 174

Low COD Stream

Sr

.

N

o.

Paramet

ers

Untreated

Effluent

Characteri

stic

Primary

Treated

Effluent

Characteristic

Secondary Treated

Effluent Characteristic

Tertiary

Treated

Effluent

Characteristic

Deep sea

discharge

Norms

First Stage

Aeration

Second

Stage

Aeration

1 pH 3.5-5.5 6.5-8.5 6.5-8.5 6.5-8.5 6.5-8.5 6.5-9.0

2 TSS 500 <100 <100 <100 <50 100

3 COD

(mg/L)

3200 2400 1080 540 <250 250

4 BOD3

(mg/L)

1060 816 368 185 <100 100

5 NH3-N <30 <30 <30 <30 <30 50


of 174

High COD Stream

Sr. No. Parameters Untreated Effluent

Characteristic

MEE Condensate

1 pH 6.0-8.0 6.5-8.5

2 COD (mg/L) 20000-22000 150.0

3 BOD3 (mg/L) 5000-6000 50.0

4 TDS (mg/L) 200000-250000 100.0


Total reuse…….KLD

Source of waste

water for reuse

with quantity in

KLD (From

where it is

coming)

Application

area with

quantity in

KLD (Where it

is used)

Characteristics of

waste water to be

reused (COD, BOD,

TDS etc.)

Remarks

regarding

feasibility

to reuse i.e.

MEE condensate Process pH: 6.5-8.5

COD :<100

BOD : <50

TDS: <150

--

E Air



-

Sr.

no.

Source

of

emission

With

Capacity

Stack

Height

(meter)

Type of

Fuel

Quantity

of Fuel

MT/Day

Type of

emissions

i.e. Air

Pollutants

Air

Pollution

Control

Measures

(APCM)

1

Steam

boiler

2 TPH

30 Natural

gas

800

nm3/Day

SPM-150

mg/Nm3

SO2-100

ppm

Adequate

Stack

height

2 Steam

boiler

30 Briquettes

/ I.Coal

8.0

MT/Day

Multi-

cyclone


of 174

2 TPH or 5.0

MT/Day

NOX-50

ppm

Separator

+ bag filter,

Water

Scrubber

3

Steam

boiler

5 TPH

30 Briquettes

/ I.Coal

15.0

MT/Day

or 12

MT/Day

Multi-

cyclone

Separator

+ bag filter,

Water

Scrubber

4

D.G set

(500)KVA

X 2

11 Diesel 100

Lit/Hr

Adequate

Stack

height

-


-

Sr. no.

Specific Source of

emission

(Name of the

Product &

Process)

Type of

emission

Stack/Vent

Height (meter)


Measures

(APCM)

1

Process Vent -1

(Reactor Vessel)

HCL < 20.0

mg/Nm3

Cl2 < 9.0 mg/Nm3

15

Two Stage Water

Scrubber

2

Process Vent -2

(Reactor Vessel)

SO2 < 40.0

mg/Nm3

15

Two Stage Water + Alkali

Scrubber

3 Process Vent -3

(Reactor Vessel-3)

NO2 < 175.0

mg/Nm3 15

Two Stage Water + Alkali

Scrubber

-


As below:

1. Airborne dust at all transfers operations/ points will be controlled either by spraying water or

providing enclosures.

2. Care will be taken to store construction material properly to prevent fugitive emissions, if any.


of 174

3. Regular maintenance of valves, pumps, flanges, joints and other equipment will be done to

prevent leakages and thus minimizing the fugitive emissions of VOCs.

4. Entire process will be carried out in the closed reactors with proper maintenance of pressure and

temperature.

5. Periodic monitoring of work area will be carried out to check the fugitive emission.

6. Breather valves will be provided on solvent tanks.

7. Solvent tank vents will be connected to vent chillers.

8. To eliminate chances of leakages from glands of pumps, mechanical seal will be provided at all

solvent pumps.

9. Close feeding system will be provided for centrifuges. Centrifuge and filtrate tank vents will be

connected to vent chillers.

10. Minimum number of flanges, joints and valves in pipelines.

11. Enclosures to chemical storage area, collection of emission from loading of raw materials in

particular solvents through hoods and ducts by induced draft, and control by scrubber / dust

collector to be ensured..

F Hazardous wastes


i

Sr.

no.

Name of Hazardous

waste

Source of

generation

Category

No. and

Schedule

Quantity

(MT/

Month)

Management of HW

1 Discarded

Containers/Barrels

/liner

Process, Storage

and Handling

Sch -I

33.1

2500

Nos/Year


Transportation,

Decontamination &

given registered

vendors.

2 Used Oil Equipment and

Maintenance

Sch -I

5.1

1000

Ltr/Year


Transportation and

Sale to authorized

traders.

3 Spent Solvent Mfg. Process Sch -I

28.6

22536

MT/Year


recovered through in

house distillation or

sent for distillation

job work to


of 174

authorized recycler

then reuse in

process.

4 Distillation Residue From Distillation Sch -I

(36.1)

1125.0

MT/Year


Transportation & co-

processing in

cement industries or

sent to CHWIF site.

5 Spent Carbon From mfg. process

(4 Chloro 2 Amino

Phenol)

Sch -I

28.1

159.96

MT/Year



processing in


sent to CHWIF site.

6 ETP Sludge From ETP Sch -I

35.3

1800.0

MT/Year


Transportation and

sent to co-

processing in


common TSDF of

BEIL.

7 Iron Sludge From mfg. Process

(Mesitylene Acid (M

Acid)

Sch -I

28.1

19200

MT/Year


Transportation and

sent to co-

processing in


common TSDF of

BEIL.

8 Process Waste

(Organic)

From mfg. process

(Copper Formazone

/ 4 Sulpho F Base)

Sch -I

28.1

2847.0

MT/Year



processing for

Agriculture industries

or Disposal to TSDF

site

9 Sodium Acetate From mfg. process

(Fast Brodeaux GP

Base)

Sch -I

28.1

9890.0

MT/Year


Transportation & Sell

to End users having


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rule-9 permission.

10 Ammonium Sulphate From mfg. process

of product . 2

Chloro, 5 Toludine 4

Sulphonic Acid

Sch -I

28.1

48000.0

MT/Year



to End users having

rule-9 permission.

11 Dil. HCL 30 % Scrubber

From mfg. process

of product no.

Ethyl C Acid

Chloranil, 2 Chloro,

5 Toludine 4

Sulphonic Acid,

Sch -I

28.1

24800.0

MT/Year


Reuse in product

Chloranil Required

Quantity 24000

MT/Annum +

product Ethyl C Acid

Required Quantity

24000 MT/Annum &

remaining quantity

800 MT/Year send to

end user having

Rule-9 permission.

12 Spent Sulphuric Acid From mfg. process

Product No. 4

sulphoanthanilic

acid

Sch -I

28.1

35586.0

MT/Year



to End users having

rule-9 permission.

13 Dil. Nitric Acid

(15 %)

Scrubber Sch -I

28.1

414.0

MT/Year



to End users having

rule-9 permission.

14 Sodium bisulfite (30%) Scrubber Sch -I

(28.1)

468

MT/Year



to End users having

rule-9 permission.

15 MEE Salt MEE Sch -I

(28.1)

7200

MT/Year


Transportation and

sent to co-

processing in

cement industries ,

agro by product or


of 174

common TSDF of

BEIL.

-


(For HW management)

BEIL /ANK/2018

Dated: 01 Sep 2018


(MSW and others)

--


Atmospheric Distillation of Solvents:

Primary Condenser HE-01: Cooling Tower water will be used to condense the solvents and the

non condensed vapors will be condensed in a Secondary Condenser.

Secondary Condenser HE-02: Chilled water at 6 0C will be used to condense the non condensed

vapors in the Secondary Condenser.

VOC Trap Condenser HE-03: Chilled Brine at -35 0C will be used to trap any traces of Solvent

which is slipped from Secondary condenser.

Vacuum distillation of Solvent:

Primary Condenser HE-01: Cooling Tower water or Chilled water will be used to condense the

solvents depend on the vapor pressure at its operating conditions and the non condensed vapors

will be condensed in a Secondary Condenser.

Secondary Condenser HE-02: Chilled Brine at -17 0C will be used to condense the non condensed

vapors in the Secondary Condenser.

VOC Trap Condenser HE-03: Chilled Brine at -35 0C will be used to trap any traces of Solvent which is

slipped from Secondary condenser.

min. 95.00 % of Spent Solvent will be recovered by In-house distillation of Solvent.


Table Format)

Solvent Boiling

Point

(0C)

Vapor

Pressure

Input

(MT)

Output

(MT)

Loss %

Recovery

%

Loss

ODCB 180.0 1 mm hg 338.12 321.12 35.84 94.97 5.03

DCM 39.60 0.13 kpa 1510.0 1446.14 64.19 95.77 4.23


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Toluene 111 22 mm

Hg @

200C

1033 966.67 66.67 93.58 6.42

Methanol 64.7 96 mm

Hg @

200C

1758.24 1696.70 61.54 96.50 3.50


All the solvents are directly distillate from product mix and purified in packed column with the

help of reflux and therefore there is no generation of any distillation residue from the solvent

distillation.

The solvent distillation system is designed so as to achieve minimum 95% recovery of solvent.

Pure solvent, crude solvent and distilled (recovered) solvent shall be stored only in storage tanks

and we shall not be using drums at any stage in the Solvent Management System.

Wherever required, the solvents shall be directly pumped into day tanks from the storage tanks

and shall be charged into the reactors without involving any manual handling.

All the pumps shall be mechanical seal type to avoid any leakage of solvent.

All necessary fire fighting systems shall be provided with alarm system. Flame proof wiring and

flame proof electrical accessories shall be provided to avoid any mishap.

All the storage tank and day tank shall be connected to a vent system through chilled water

condensers to prevent loss of solvents in the atmosphere.

All the distillation column vents are also connected to chilled water condensers for maximum possible

recovery of the solvents.


Storage details Name of major

Hazardous chemicals

Remarks

Storage tanks

HCL, Sulphuric Acid,

Formaldehyde, Liq.

Ammonia, Toluene,

Methanol, Acetic Acid

--

Drum/Barrel storage

Acetic Acid , Soda Ash,

Iron Powder

--

Tonner Chlorine --

Applicability of PESO : All raw material as per PESO standards

Technical presentation was made by the project proponent with consultant/expert M/s. Aqua Air

Environmental Engineers Pvt Ltd, Surat during SEAC meeting dated 11/02/2020.


of 174

Committee noted that this proposal is for new unit located in GIDC Saykha. Source of water is GIDC. PP

mentioned that high COD effluent generated from process will be treated in Primary ETP – 2 followed by

MEE, Condensate from MEE will be reused/recycle while salt generated will be disposed at approved TSDF

while Low COD effluent generated from process, washing boiler blow down and cooling blow down will be

treated in proposed in-house ETP – 1 consisting of Primary, Secondary & Tertiary ETP and treated effluent

will be discharged into deep sea via GIDC pipeline after meeting its norms. PP has proposed three steam

boilers. Fuel used will be Natural Gas/Briquettes/Coal. PP has addressed Hazardous Waste as per HWR –

2016.


Terms of Reference.



















6. Characteristic of effluent to be treated in proposed ETP – 1 & 2 consisting of Primary, Secondary &

Tertiary treatment along with its Adequacy.

7. Provision of separate ETP – 1 & 2 for low concentration and high concentration waste water

streams ensuring proper segregation and no intermixing of the streams.

8. Characteristic of effluent to be discharged into deep sea via GIDC pipeline along with its control

mechanism and provision of online monitoring system.

9. Membership of GIDC for disposal into deep sea via GIDC pipeline clearly mentioning the

characteristic of effluent to be discharged along with its quantity.


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10. Details of in-house MEE along with characteristic of effluent to be treated and quality and quantity

of effluent to be reused back into process along with its feasibility.

11. MoU for all the Hazardous Waste to be disposed into Rule – 9 as per HWR – 2016.









14 SIA/GJ/IND2/48757/2019 M/S. Darshan Pharmachem Pvt. Ltd

Plot No. D2/CH/8, GIDC Dahej-II, Vagra

Bharuch.

Screening & Scoping


Project status: New



EIA/EMP report.


This is new unit proposes for manufacturing of synthetic organic product as tabulated below:

Sr.

No. Name of Product CAS No.

Quantity

(Mt/Month)

End Use of

Products

1 Ketoconazole 65277-42-1

150

Antifungal

1a Cis-Tosylate 154003-23-3 Ketaconazole

1b Para-Hydroxylphenyl-n-acetyl

piperazine 67914-60-7 Ketaconazole

1c Cis-bromobenzoate 61397-56-6 Ketaconazole

2 Itraconazole & Its Intermediates 84625-61-6 Antifungal

2a

2,4-Dihydro-4-[4-[4-4(-hydroxy phenyl)-

1-piperazinyl ]phenyl]-2 -(1-

methylpropyl)-3H-1,2,4-tri azol-3-one

106461-41-0 Itraconazole

2b Cis-mesylate 67914-86-7 Itraconazole



of 174

2c 1-(4-Aminophenyl)-4-(4-

Hydroxyphenyl)piperazine 74853-08-0 Itraconazole

2d 1-(4-Methoxyphenyl)-4-(4-

nitrophenyl)piperazine 74852-61-2 Itraconazole

3 2-Chloro Ethylamine HCl 870-24-6 Ifasamide

4 Fluconazole And Its Intermediates 86386-73-4 Antifungal

4a 1-(2,4-Difluorophenyl)-1-(1H-1,2,4-

triazole-1yl)-ethanone (DFTA) 86404-63-9 Fluconazole

4b

2-(2,4-Difluorophenyl)-1-(1H-1,2,4-

triazole-1yl) 2,3 Epoxy propane-

Methane sulphonate

86386-77-8 Fluconazole

5 Trazodone Hydrochloride & Its

intermediates 25332-39-2 Antidepression

5a 1-(3-chlorophenyl) piperazine 6640-24-0 Trazodone

Hydrochloride

5b 1-(3-chlorophenyl)-4-(3-chloropropyl)

piperazine hydrochloride 52605-52-4

Trazodone

Hydrochloride

6 Aripiprazole & Its Intermediates 129722-12-9 Schizophrenia

6a 1-(2,3- Dichlorophenyl) piperazine

hydrochloride 119532-26-2 Aripiprazole

6b 7-(4-bromobutoxy)-3 4-dihydro-2(1h)-

quinolinone 129722-34-5 Aripiprazole

7 Teneligliptin & Its Intermediates 760937-92-6 Antidiabetic

7a 1-(3-Methyl-1-phenyl-5-

pyrazolyl)Piperazine 401566-79-8 Teneligliptin

7b Tert-butyl 4-oxo-2-(1,3-thiazolidin- 3-yl

carbonyl) pyrrolidine-1-carboxylate 401564-36-1 Teneligliptin

8 Rivaroxaban & Its Intermediates 366789-02-8 Anticoagulant

8a 4-(4-Aminophenyl)morpholin-3-one Rivaroxaban

9 Meloxicam & Its Intermediates 71125-38-7 Painkiller

9a 2-Amino-5-Methylthiazole 7305-71-7 Meloxicam

9b

Methyl 4-Hydroxy-2H-1,2-

Benzothiazine-3-Carboxylate 1,1-

Dioxide

35511-15-0 Meloxicam

10 Moxifloxacin Hydrochloride & Its

Intermediate 354812-41-2 Antibiotic

http://www.sigmaaldrich.com/catalog/product/aldrich/679135

http://darshanpharmaindia.in/1-(3-Methyl-1-phenyl-5-pyrazolyl)Piperazine.html

http://darshanpharmaindia.in/1-(3-Methyl-1-phenyl-5-pyrazolyl)Piperazine.html

http://darshanpharmaindia.in/4-(4-Aminophenyl)morpholin-3-one.html


of 174

10a

7-[(4aS,7aS)-1,2,3,4,4a,5,7,7a-

octahydropyrrolo[3,4-b]pyridin-6-yl]-1-

cyclopropyl-6-fluoro-8-methoxy-4-

oxoquinoline-3-carboxylic acid

151096-09-2 Moxifloxacin

11 Fingolimod & Its Intermediate 162359-55-9 Sclerosis

11a N-(1-Hydroxy-2-(hydroxymethyl)-4-(4-

octylphenyl) butan-2-yl) acetamide 249289-10-9 Fingolimod

12 Roflumilast & Its Intermediate 162401-32-3 Anti-Inflammatory

12a 3-(cyclopropyl methoxy)-4- (difluoro

methoxy) benzoyl chloride 672883-68-0 Roflumilast

13 Fesoterodine Fumrate & Its Intermediate 286930-02-7 Antimuscarinic

13a FESOTERODINE NDMF 286930-02-7 Fesoterodine

Fumrate

13b FESOTERODINE DMF 286930-02-7 Fesoterodine

Fumrate

14 Pramipexole & Its Intermediate 104632-26-0 Parkinson’s disease

14a N-(trans)-4-hydroxycyclohexyl)

acetamide 27489-60-7 Pramipexole

14b N-(trans)-4-oxocyclohexyl) acetamide 27514-08-5 Pramipexole

14c (-/+)2,6-Diamino-4,5,6,7-

tetrahydrobenzothiozole 106092-09-5 Pramipexole

14d (+)2,6-Diamino-4,5,6,7-

tetrahydrobenzothiozole 106092-09-5 Pramipexole

15 Tamsulosin & Its Intermediate 106133-20-4 benign prostatic

hyperplasia

15a Tamsulosin Base 106138-88-9 Tamsulosin

16 Bimatoprost And Its Intermediate 155206-00-1 Glucoma

16a

Cyclopentane methyl heptenoate ,5-cis-

2-(3-hydroxy-5-phenyl-1-trans-

pentenyl)-3,5 -dihydroxy[1 ,2,3,5]

- Bimatoprost

17 Desvenlafaxine & Its Intermediate 93413-62-8 Antidepressant

17a Desvenlafexine base dry 93413-62-8 Desvenlafaxine

18 Sitagliptin & Its Intermediate 486460-32-6 Antidiatetic

18a Sitaglimptin base 486460-32-6 Sitagliptin

19 Atorvastatin & Its Intermediate 134523-00-5 dyslipidemia

http://www.commonchemistry.org/ChemicalDetail.aspx?ref=162401-32-3




https://en.wikipedia.org/wiki/Benign_prostatic_hyperplasia

https://en.wikipedia.org/wiki/Benign_prostatic_hyperplasia







of 174

19a Tert-butyl 2-((4R, 6R)-6-(2-aminoethyl)-

2, 2-dimethyl-1,3-Dioxane-4-yl)acetate 125995-13-3 Atorvastatin

19b

(3R, 5R)-tert butyl 7-(2-(4-flurophenyl)-

5-isopropyl-3-phenyl-4-

(phenylcarbamoyl)-1H-pyrrol-1-yl)-3,5-

dihydroxyheptanoate

134395-00-9 Atorvastatin

20 Febuxostat & Its Intermediate 144060-53-7 Hyperuticemia

20a Ethyl 2-[3-Formyl-4-(2-methylpropoxy)

phenyl]-4-methyl-5-thiazole carboxylate 161798-03-4 Febuxostat

20b Ethyl 2-[3-Cyano-4-(2-methylpropoxy)

phenyl]-4-methyl-5-thiazole carboxylate 160844-75-7 Febuxostat

20c

2-[3-Cyano-4-(2-methylpropoxy)

phenyl]-4-methyl-5-thiazole carboxylic

Acid

160844-75-7 Febuxostat

21 Carbazepamine 298-46-4 Anticonvulsant

22 Metoprolo & Its Intermediate 51384-51-1 Hypertension

22a 2-((4-(2-methoxyethyl) phenoxy) methyl)

oxirane 56718-70-8 Metoprolo

23 Levocitrizine DIHCL& Its Intermediate 130018-77-8 Antihistamine

23a C-(4-Chloro-phenyl)-C-phenyl

methylamine

24 Finofibrate 49562-28-9 hypercholesterolemi

a

25 Levatiracetam & Its Intermediate 102767-28-2 Epilepsy

25a

(R)-2-(2-(4-((4-

chlorophenyl)(phenyl)methyl) piperazin-

1-yl)ethoxy) acetamide

909779-33-5 Levatiracetam

26 2-Chloro Ethyl Amine Hydrochloride 870-24-6 Ifasamine

27 N,N, Bis (2-Chloro Ethyl) Amine

Hydrochloride 821-48-7

Piperazine

derivatives

28 Di Ethyl Amino Ethyl Chloride

Hydrochloride 869-24-9 Antibacterial

29 Di Methyl Amino Ethyl Chloride

Hydrochloride 4584-46-7 Antibacterial

30 4-Sulphanamido Phenyl Hydrazine

Hydrochloride 17852-52-7 Anti-inflammatory






of 174

31 1-[2-(2-Hydroxyethoxy)Ethyl]Piperazine 13349-82-1 Quetiapine

32 1 – Methyl– 3–Phenyl Piperazine 5271-27-2 Mirtazapine

33 4-(2-Chloroethyl)Morpholine

Hydrochloride 3647-69-6 Floredil

34

5-(4-(4-(5-Cyano1H-Indol-3-Yl)- Butyl)-

Piperazin-1- Yl)Benzofuran-2-

Carboxamide

163521-19-5 Vilazodone HCl

35 3-(Cyclopropylmethoxy)-4-

(Difluoromethoxy) Benzoylchloride 672883-68-0 Anti-inflammatory

36 (R)-5-(2-Aminopropyl)-2-Methoxy

Benzene Sulfonamide 112101-81-2 Tamsulosine

37

(E)-7-((1R,2R,3R,5S)-3,5-Dihydroxy-2-

((E)-3-Hydroxy-5-Phenylpent-1-En-1-

Yl)Cyclopentl)Hept-5-Enoic Acid

38344-08-0 Bimatoprost Acid

38 (S)-4-(4-(5-Aminomethyl)-2oxooxa

Zolidin-3-Yl) Phenyl)Phorpholin-3-One 446292-10-0 Rivaroxaban

39

(3R,5R)-Tert-Butyl 7-(2-(4-Fluoro

Phenyl)-5-Isopropyl-3-Phenyl- 4-(Phenyl

Carbonyl)4-Pyrol-1-Yl)-3,5-Dihydroxy

Heptanoate

134523-00-5 Atorvastatin

40 2-((4-(2-Methoxyethyl)Phenoxy)Methyl) 56718-70-8 Metropolol

41

(R)-2-(2-(4-((4-Chlorophenyl) Oxirane

(Phenyl)Methyl) Piperazin- 1-Yl)Ethoxy)

Acetamide

83881-37-2 Cetrizine Amide

42 2-(4-(4-Chlorobenzoyl) Phenoxy-2-

Methylpropanoic Acid 42017-89-0 Fenofibric Acid

43 2,2’-Azanediylbis(1-(6-Fluorochroman-2-

Yl) Ethanol) 169293-50-9 Nebivolol HCl

R & D * -- 10 kg/Month

Total 150 MT/Month




Sr.

no.

Particulars Details


of 174

A


(Rs. in Crores):

8.5 Crores

B Total Plot area ( sq. meter) 10068.75

Green belt area

( sq. meter)

3778.48 (Approx.37.52%)

C Employment generation Direct = 20 Employees

Indirect = 10 Employees

D Water

i



GIDC Water Supply Letter

Status of permission from the concern authority. No. GIDC/DEE(WS)/BRH/870


Sr. No. Category

Water Consumption Remarks

(KL/Day) Source

1 Domestic 7.0 GIDC Water Supply

Authority 2 Gardening 15.0

3 Industrial

Process 192.0 Mfg. Process

(Febuxostat)

Boiler 10.0

Cooling 3.0

Washing 10.0

Scrubbing 7.0

3 Total Industrial 222.0

Total (1+2+3) 244.0


5) Quantity to be recycled: Nil KLD





of 174

-

Sr. No. Category

Waste Water

generation Remarks

(KL/Day) Mode of discharge

1 Domestic 6.0 Septic Tank & Soak pit

2 Gardening Nill

3 Industrial

Process 150.0

Mfg. Process

(5-(4-(4-(5-Cyano1H-Indol-3-Yl)-

Butyl)-Piperazin-1- Yl)

Benzofuran-2- Carboxamide

Boiler 2.5

Cooling 1.0

Washing 8.5

Scrubbing

(10% NaCl Salt) 1.0 1.0 KLD NaCl Salt in ETP

Scrubbing Solution

(30-35 % NaBr/HBr) 2.0 To End User

Scrubbing Solution

( 20-22% Na2SO3 ) 2.0 To End User

Scrubbing Solution

(Liq. Ammonia) 2.0 Reused within premises.

3 Total Industrial 169.0

Total (1+2+3) 175.0

NOTE:-

Total Industrial Waste Water Generation will be 169.0 KLD. Out of which 163 KLD will be treated in

Primary ETP 1 & 2, In-house MEE, Secondary & Tertiary ETP and then send to common facility

(CETP, Dahej). 4.0 KLD Scrubber Solution will be send to End User Under Rule-9. 2.0 KLD Scrubber

Solution will be reused within the premises.


[In-house ETP 1 (Primary, Secondary, Tertiary), MEE, Stripper etc and ETP 2 (Primary).

1. Hydraulic Load – ETP 1: 13 KLD & ETP 2: 150.0 KLD

In-house ETP 1 Capacity – 18 KLD & ETP 2 Capacity – 180 KLD

2. Hydraulic Load – Secondary & Tertiary ETP: 153 KLD


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Capacity: 200 KLD

3. Hydraulic load of In House MEE – 147.7 KLD

In- House MEE Capacity – 190 KLD

1. Hydraulic load of Solvent Stripper – 150 KLD

Capacity – 180 KLD


150.0 KLD from Process is subjected to solvent stripper & shall be treated in Primary ETP - 2

and from there wastewater @ 147.7 KLD will be sent to In-house MEE.

Dilute Stream, which comes @ 2.5 KLD from Boiler, 1 KLD from cooling, 8.5 KLD from

Washing and 1 KLD from Scrubbing, Totally 13 KLD will be subjected to Primary ETP-1 and

then will be mixed with MEE Condensate of Process stream @ 140 KLD and then is sent to for

secondary and tertiary treatment, then final treated Waste Water @ 153 KLD will be sent to

common CETP, Dahej.

High COD range from 42760 mg/L (Febuxostat) to 73565 mg/l (Trazodone Hydrochloride)

Low COD range from Boiler Blowdown 100 mg/L to Washing Section 2500 mg/L.


Management of wastewater keeping in view direction under section 18 (1) (b) of the Water


Treated Effluent 153.0 KLD will be sent to Common CETP, Dahej.


Not Applicable, Treated Effluent 153.0 KLD will be sent to Common CETP, Dahej.


Domestic: Septic Tank & Soak Pit

Industrial:

Total Industrial Effluent 169.0 KLD, (Boiler Outlet 2.5 KLD, Washing 8.5

KLD, Cooling 1.0 KLD, 1.0 KLD Scrubbing(1.0 KLD NaCl Salt in ETP and

other @ 4 KLD Sell to End User, 2 KLD reused within Premises) Total

Effluent @ 150.00 KLD subjected to solvent stripper & then wastewater @

147.7 KLD is sent to Primary ETP 2, then it is sent to In-house MEE.

The MEE condensate @ 140 KLD is combined with dilute stream @ 13 KLD

and sent to Secondary and Tertiary ETP and Final effluent @ 153 KLD will

be sent to Common CETP, Dahej.

vi In case of Common facility (CF) like CETP, Common Spray dryer, Common MEE etc.

Name of CF

Common CETP, Dahej




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Common CETP, Dahej ( Letter No. – GIDC/DEE/DRG/BRH/681)



Total reuse:- KLD

Source of waste

water for reuse

with quantity in

KLD (From

where it is

coming)

Application

area with

quantity in

KLD (Where

it is used)

Characteristics of

wastewater to be

reused (COD, BOD,

and TDS etc.)

Remarks regarding

feasibility to reuse i.e.

- - - -

No water reuse

Characteristic wastewater dilute & Concentrate stream

SR.

No. Para Unit

Concentrate

Stream from

process (Worst

Case)

After

Solvent

Stripper

After Primary

Treatment

MEE

Condensate

Quantity (KLD) 150 147.7 147.7 140

1 pH pH Unit 8-10 8-10 7.5 6-8

2 TSS mg/L 250 <100 <50 <30


of 174

3 TDS mg/L 18260 18260 20086 <1000

4 BOD mg/L 19935 10365 8472 4236

5 COD mg/L 66453 33226 28242 5648

6 Ammo.

Nitrogen mg/L 30 Nil Nil Nil

SR. No. Para Unit Dilute Stream

Combined Effluent

Dilute stream after

Primary Treatment

Quantity (KLD)

13.0 (Boiler: 2.5 +

Cooling: 1.0 + washing:

8.5 + Scrubbing: 1.0)

13.0

1 pH pH Unit 6-8 7-7.5

2 TSS mg/L 133 50

3 TDS mg/L 1126 957

4 BOD mg/L 551 468

5 COD mg/L 1776 1509

6 Ammo. Nitrogen mg/L Nil Nil

SR.

No. Para Unit

Combine effluent

(MEE Condensate +

Dilute stream after

Primary Treatment )

After Secondary

Treatment

After Tertiary

Treatment

Stage I Stage II PSF + Carbon

Filter

Quantity (KLD)

153.0 (MEE

Condensate: 140.0 +

Dilute after primary

treatment: 13.0)

153 153 153

1 pH pH

Unit 7-7.5 7.5 7.5 7.5

2 TSS mg/L 32 <30 <30 <30

3 TDS mg/L <1000 <1000 <1000 <1000

4 BOD mg/L 3841 461 <100 <90

5 COD mg/L 5322 1597 479 <250

6 Ammo.

Nitrogen mg/L

Nil Nil Nil Nil

E Air


of 174



Sr.

No.

Stack

attached to

Stack

Height/Dia.

(Meter)

Fuel Fuel Qty. APCM Permissible limit

1.

Steam Boiler

(2.0 TPH)

(2 nos.)

30/0.5

Bio Coal/

Briquette/

Agro

Waste/Coal

OR

Natural Gas

12 MT/Day

OR

6400

SCM/Day

MCS +

Water

Scrubber

PM < 150 mg/Nm3

SO2 < 100 ppm

NOX < 50 ppm

2.

Thermic

Fluid Heater

(10 Lac

KCal/Hr.)

30/0.5

Bio Coal/

Briquette/

Agro

Waste/Coal

OR

Natural Gas

6.5

MT/Day

OR

2800

SCM/Day

MCS +

Water

Scrubber

PM < 150 mg/Nm3

SO2 < 100 ppm

NOX < 50 ppm

3.

Hot Air

Generator (9

Lac Kcal/Hr.)

30/0.5

Coal

OR

Natural Gas

5 MT/Day

OR

2300

SCM/Day

MCS +

Water

Scrubber

PM < 150 mg/Nm3

SO2 < 100 ppm

NOX < 50 ppm

4. D.G. Set

(125 KVA) 11/0.25 Diesel 15 lit/Hr.

Adequate

Stack

Height

PM < 150 mg/Nm3

SO2 < 100 ppm

NOX < 50 ppm

ii Process gas emission details i.e. Type of pollutant gases (SO2, PM, NOx etc.)

-

Sr.

No. Vent attached to

Height

(Meter) APCM

Permissible

limit

1.

Reaction Vessel of

(3-(cyclopropylmethoxy)-4-

(difluoromethoxy) benzoylchloride)

Height: 11

Meters

Dia: 0.2

Meters

Two Stage

Alkali Scrubber

SO2: 40

mg/Nm3

2.

Reaction Vessel of (3-

(cyclopropylmethoxy)-4-

(difluoromethoxy) benzoylchloride)

Height: 11

Meters

Dia: 0.2

Two Stage

Alkali Scrubber

HCl: 20

mg/Nm3


of 174

Meters

3.

Reaction Vessel of [(3R,5R)-tert-

butyl 7-(2-(4-fluoro phenyl)-5-

isopropyl-3-phenyl- 4-(phenyl

carbonyl)4-pyrol-1-yl)-3,5-

dihydroxy heptanoate]

Height: 11

Meters

Dia: 0.2

Meters

Two Stage

Alkali Scrubber

NH3: 175

mg/Nm3

4. Reaction Vessel of Ketoconazole

(Bromination)

Height: 11

Meters

Dia: 0.2

Meters

Two Stage

Alkali Scrubber

HBr: 20

mg/Nm3

-

Iii Fugitive emission details with its mitigation measures:

As below:

Whole process will be carried out in close loop.

Pipe line will be having minimum flange.

Pump with double mechanical seals

Proper ventilation.

F Hazardous wastes


S

r.

N

o

.

Type of

Hazardou

s Waste

Hazardou

s Waste

Category

&

Schedule

Source

Qty.

(MT/

Year)

Management

of HW

1 ETP

Sludge

35.3/SCH

-I ETP 1810.0

Collection,

Storage,

Transportatio

n, disposal at

nearest TSDF

site. (M/s.

BEIL, Dahej)

2 MEE Salt - From MEE 1100.0

3 Used Oil 5.1/SCH-I Maintenance

activity 2.0

Collection,

Storage,

Transportatio


of 174

n & Reuse or

sale to

authorized re-

processors.

4

Discarded

Container

s/ Bags /

Liners

33.1/SCH-I Raw Material

Supplier

30.0

(1850

container

s, 12000

bags)

Collection,

Storage,

Transportatio

n & Reuse/

Sale to

Authorized

Vendor.

5 Distillation

Residue

20.3/SCH

-I

Mfg. Process

(5-(4-(4-(5-

Cyano1H-

Indol-3-Yl)-

Butyl)-

Piperazin-1-

Yl) Benzo

furan-2-

Carbox

amide)

9020.0 Collection,

Storage,

Transportatio

n & send to

pre/co-

processing

units (cement

industries)

OR disposal

at nearest

CHWIF ((M/s.

DIPL, Kutch).

6

Process

Waste

(Organic)

28.1/SCH

-I

Mfg. Process

(Fesoterodin

e Fumrate &

intermediates

)

5350.0

7 Spent

Carbon

28.3/SCH

-I Mfg. Process 30.0

8 Spent

Catalyst

28.2/SCH

-I Mfg. Process 1.0

9 Inorganic

waste

SCH-I/

26.1

Mfg. Process

(Itraconazole

&

intermediates

4860.0

Collection,

Storage,

Transportatio

n, Disposal at


of 174

) TSDF site.

(M/s BEIL

Dahej)

1

0

Spent

Solvent

28.6/SCH

-I

Mfg. Process

(2,2’-

Azanediyl bis

(1-(6-Fluoro

chroman-2-

Yl) Ethanol))

251448.

0

*

Collection,

Storage,

Transportatio

n recovered &

recycled by

Solvent

Distillation

Plant within

premises.

Solvent

Stripper 840.0

Collection,

Storage,

Transportatio

n recovered &

recycled by

Solvent

Distillation

Plant

Or

Collection,

Storage,

Transportatio

n to pre/co-

processing(ce

ment

industries) to

CHWIF site.

1

1

Spent

H2SO4

(50 %)

28.1/SCH

-I

Mfg. Process

(Finofibrate &

intermediates

)

4320.0

Collection,

Storage,

Transportatio

n Sell to End

Users having

permission


of 174

under Rule-9.

1

2

AlCl3 sol.

(35 %)

28.1/SCH

-I

Mfg. Process

(Fluconazole

and its

intermediates

)

1730.0

Collection,

Storage,

Transportatio

n Sell to End

Users having

permission

under Rule-9.

1

3

Off

Specificati

on

products

28.4/SCH

-I Mfg. Process 1.0

Collection,

Storage,

Transportatio

n & send to

pre/co-

processing

units (cement

industries)

OR disposal

at nearest

CHWIF ((M/s.

DIPL, Kutch).

1

4

Scrubbing

Solution

10% NaCl

28.1/SCH

-I

Scrubber

Mfg. Process

(3-(cyclo

propyl

methoxy)-4-

(difluoro

methoxy)

benzoyl

chloride)

360 KL

Treated with

effluent &

Send to

common ETP

of CETP

Dahej.

1

5

Scrubbing

Solution

(25-30%

Na2SO3)

28.1/SCH

-I

Scrubber

Mfg. Process

(3-

(cyclopropyl

methoxy)-4-

720 KL

Collection,

Storage,

Transportatio

n Sell to End

Users having

permission


of 174

(difluoro

methoxy)

benzoyl

chloride)

under Rule-9.

1

6

Scrubbing

Solution

(30-35 %

NaBr/HBr)

28.1/SCH-I

Scrubber

Mfg. Process

(Ketoconazol

e & its

intermediates

)

720 KL

Collection,

Storage,

Transportatio

n Sell to End

Users having

permission

under Rule-9.

1

7

Scrubbing

Solution

(Liq.

Ammonia)

28.1/SCH-I

Scrubber

Mfg. Process

([(3R,5R)-

tert-butyl 7-

(2-(4-fluoro

phenyl)-5-

isopropyl-3-

phenyl- 4-

(phenyl

carbonyl)4-

pyrol-1-yl)-

3,5-dihydroxy

heptanoate])

720 KL

Collection,

Storage, and

reuse in Mfg.

process of 1 –

Methyl– 3–

Phenyl

Piperazine

(14760 KL/

Annum)

I

Product Solvent Quantity

(MT/Year)

2,2’-

Azanediyl

bis (1-(6-

Fluoro

chroman-

2-Yl)

Ethanol)

Rec. THF 114561

Rec/ Methanol 22916

Rec. Ethyl acetate 22632

Rec. THF 34374

Rec. Methanol 34374

Rec. THF 22632

Rec. Ethyl Acetate 114561


of 174

Total 251448.0


(For HW management)

Applied.


(MSW and others)

Nil



Table Format)

Product Name Solvent B.P.

°C

Qty.

Used

MT/MT

Qty.

Recovered

MT/MT

Total

Losses

Solvent

Recover

y %

Ketoconazole

DMF 153 0.32 0.28 0.03987 87.54

Toluene 111 4.46 4.08 0.37732 91.54

Ethyl

acetate 77 3.35 3.20 0.14941 95.54

MDC 39 6.31 6.09 0.21833 96.54

Methanol 64.5 2.79 2.70 0.09095 96.74

Acetone 56.2 0.67 0.64 0.02988 95.54

Methanol 64.5 0.01 0.01 0.00033 96.74

Ethyl

acetate 77 4.35 4.16 0.19401 95.54

Methanol 64.5 0.91 0.88 0.02967 96.74

DMF 153 0.62 0.54 0.07725 87.54

Toluene 111 4.46 4.08 0.37732 91.54

Ethyl

acetate 77 3.35 3.20 0.14941 95.54

MDC 39 6.31 6.09 0.21833 96.54

Methanol 64.5 2.79 2.70 0.09095 96.74


of 174

Methanol 64.5 0.65 0.63 0.02119 96.74

Methanol 64.5 2.76 2.67 0.08998 96.74

Toluene 111 2.29 2.10 0.19373 91.54

Cis-Tosylate

DMF 153 0.32 0.28 0.03987 87.54

Toluene 111 4.46 4.08 0.37732 91.54

Ethyl

acetate 77 3.35 3.20 0.14941 95.54

MDC 39 6.31 6.09 0.21833 96.54

Methanol 64.5 2.79 2.70 0.09095 96.74

Para-Hydroxy

lphenyl-n-acetyl

piperazine

Methanol 64.5 0.65 0.63 0.02119 96.74

Cis-

bromobenzoate

Methanol 64.5 2.76 2.67 0.08998 96.74

Toluene 111 2.29 2.10 0.19373 91.54

Itraconazole & Its

Intermediates

DMF 153 6.94 6.08 0.86472 87.54

Toluene 111 1.94 1.78 0.16412 91.54

Ethyl

acetate 77 5.08 4.85 0.22657 95.54

Methanol 64.5 8.19 7.92 0.26699 96.74

DMF 153 2.2 1.93 0.27412 87.54

Toluene 111 1.85 1.69 0.15651 91.54

MDC 39 2.28 2.20 0.07889 96.54

DMF 153 1.19 1.04 0.14827 87.54

Methanol 64.5 2.39 2.31 0.07791 96.74

Acetone 56.2 2.42 2.31 0.10793 95.54

DMF 153 2.8 2.45 0.34888 87.54

MDC 39 2.89 2.79 0.09999 96.54

n-Butanol 178 1.74 1.54 0.19940 88.54

DMF 153 4.59 4.20 0.38831 91.54

2-Bromo

butane 91 1.47 1.35 0.12436 91.54

DMF 153 4.2 3.68 0.52332 87.54

Cis-mesylate

DMF 153 1.19 1.15 0.03879 96.74

Methanol 64.5 2.39 2.31 0.07791 96.74

Acetone 56.2 2.42 2.31 0.10793 95.54


of 174

DMF 153 2.8 2.45 0.34888 87.54

MDC 39 2.89 2.79 0.09999 96.54

n-Butanol 178 1.74 1.54 0.19940 88.54

DMF 153 4.59 4.20 0.38831 91.54

2-Bromo

butane 91 1.47 1.35 0.12436 91.54

DMF 153 4.2 3.68 0.52332 87.54

2-Chloro

Ethylamine HCl EDC 83.5 1.875 1.74 0.13988 92.54

Fluconazole And

Its Intermediates

Toluene 111 2.4 2.20 0.20304 91.54

Toluene 111 6 5.49 0.50760 91.54

Methylene

chloride 39 4.8 4.63 0.16608 96.54

IPA 82.5 3.16 3.06 0.10302 96.74

1-(2,4-Difluoro

phenyl)-1-(1H-

1,2,4- triazole-

1yl)-ethanone

(DFTA)

Methylene

chloride 82.5 4.8 4.63 0.16608 96.54

IPA 82.5 3.16 3.06 0.10302 96.74

Trazodone

Hydrochloride &

Its intermediates

Acetone 82.5 1.78 1.70 0.07939 95.54

Ethylene

dichloride 82.5 1.07 0.99 0.07982 92.54

Acetone 82.5 1.19 1.14 0.05307 95.54

1-(3-

chlorophenyl)

piperazine

hydrochloride

Ethylene

dichloride 82.5 1.07 0.99 0.07982 92.54

1-(3-

chlorophenyl)-4-

(3-chloropropyl)

piperazine

hydrochloride

Acetone 82.5 1.19 1.14 0.05307 95.54

Aripiprazole & Its

Intermediates

Tryethyla

mine 82.5 1.78 1.72 0.05803 96.74

Ethylene

dichloride 82.5 1.07 0.99 0.07982 92.54


of 174

DMF 153 1.59 1.39 0.19811 87.54

1-(2,3- Dichloro

phenyl)

piperazine

hydrochloride

Ethylene

dichloride 82.5 1.07 0.99 0.07982 92.54

7-(4-

bromobutoxy)-3

4-dihydro-2(1h)-

quinolinone

DMF 153 1.59 1.39 0.19811 87.54

Teneligliptin & Its

Intermediates

Toluene 82.5 1.28 1.17 0.10829 91.54

Methylene

chloride 82.5 2.55 2.46 0.08823 96.54

IPA 82.5 1.68 1.63 0.05477 96.74

1-(3-Methyl-1-

phenyl-5-

pyrazolyl)Piperaz

ine

Methylene

chloride 82.5 2.55 2.46 0.08823 96.54

IPA 82.5 1.68 1.63 0.05477 96.74

Rivaroxaban &

Its Intermediates

IPA 82.5 16.43 15.89 0.53562 96.74

Toluene 82.5 20.98 19.21 1.77491 91.54

Methanol 64.5 8.17 7.90 0.26634 96.74

DCM 82.5 11.45 11.05 0.39617 96.54

Meloxicam & Its

Intermediates

o-Xylene 82.5 7.4 6.55 0.84804 88.54

Toluene 82.5 0.99 0.91 0.08375 91.54

DMF 153 0.25 0.22 0.03115 87.54

IPA 82.5 3.72 3.60 0.12127 96.74

2-Amino-5-

Methylthiazole Toluene 82.5 0.99 0.91 0.08375 91.54

Methyl 4-

Hydroxy-2H-1,2-

Benzothiazine-3-

Carboxylate 1,1-

Dioxide

DMF 153 0.25 0.22 0.03115 87.54

IPA 82.5 3.72 3.60 0.12127 96.74

Moxifloxacin

Hydrochloride &

Its Intermediate

Methanol 64.5 10 9.67 0.32600 96.74

Acetone 82.5 4 3.82 0.17840 95.54

DMF 153 2 1.75 0.24920 87.54


of 174

7-[(4aS,7aS)-

1,2,3,4,

4a,5,7,7a-

octahydro pyrrolo

[3,4-b]pyridin-6-

yl]-1-cyclopropyl-

6-fluoro-8-

methoxy-4-

oxoquinoline-3-

carboxylic acid

Acetone 82.5 4 3.82 0.17840 95.54

DMF 153 2 1.75 0.24920 87.54

Fingolimod & Its

Intermediate

Toluene 82.5 1.28 1.17 0.10829 91.54

IPA 82.5 1.68 1.63 0.05477 96.74

MDC 82.5 2.55 2.46 0.08823 96.54

N-(1-Hydroxy-2-

(hydroxymethyl)-

4-(4-octylphenyl)

butan-2-yl)

acetamide

IPA 82.5 1.68 1.63 0.05477 96.74

MDC 82.5 2.55 2.46 0.08823 96.54

Pramipexole &

Its Intermediate

Methanol 64.5 0.11 0.11 0.00359 96.74

IPA 82.5 0.19 0.18 0.00619 96.74

Acetone 82.5 3.56 3.40 0.15878 95.54

n-Hexane 82.5 4.17 3.90 0.26938 93.54

Ethylaceta

te 82.5 3.09 2.95 0.13781 95.54

Chloroben

zene 82.5 3.7 3.28 0.42402 88.54

Chloroben

zene 82.5 3.09 2.74 0.35411 88.54

Methanol 64.5 3.7 3.58 0.12062 96.74

Methanol 64.5 2.5 2.42 0.08150 96.74

N-(trans)-4-

hydroxy

cyclohexyl)

acetamide

Acetone 82.5 3.56 3.40 0.15878 95.54

N-(trans)-4-

oxocyclohexyl)

n-Hexane 82.5 4.17 3.90 0.26938 93.54

Ethylaceta 82.5 3.09 2.95 0.13781 95.54


of 174

acetamide te

Chloroben

zene 82.5 3.7 3.28 0.42402 88.54

(-/+)2,6-Diamino-

4,5,6,7-

tetrahydro

benzothiozole

Chloroben

zene 82.5 3.09 2.74 0.35411 88.54

Methanol 64.5 3.7 3.58 0.12062 96.74

(+)2,6-Diamino-

4,5,6,7-

tetrahydro

benzothiozole

Methanol 64.5 2.5 2.42 0.08150 96.74

Tamsulosin & Its

Intermediate

Ethanol 82.5 5.58 5.40 0.18191 96.74

Methanol 64.5 3.6 3.48 0.11736 96.74

Methanol 64.5 12.42 12.02 0.40489 96.74

n-Hexane 82.5 3.73 3.49 0.24096 93.54

Ethyl

acetate 82.5 14.28 13.64 0.63689 95.54

Tamsulosin Base

Methanol 64.5 12.42 12.02 0.40489 96.74

n-Hexane 82.5 3.73 3.49 0.24096 93.54

Ethyl

acetate 82.5 14.28 13.64 0.63689 95.54

Ethanol 82.5 8.69 8.41 0.28329 96.74

Bimatoprost And

Its Intermediate

Acetone 82.5 8 7.64 0.35680 95.54

Ethyl

Acetate 82.5 14 13.38 0.62440 95.54

Tetrahydr

ofuran 82.5 12 11.61 0.39120 96.74

Ethyl

Acetate 82.5 20 19.11 0.89200 95.54

Acetone 82.5 10 9.55 0.44600 95.54

Methanol 64.5 6.2 6.00 0.20212 96.74

Cyclopentane

methyl

heptenoate ,5-

cis-2-(3 -

Tetrahydr

ofuran 82.5 12 11.61 0.39120 96.74

Ethyl

Acetate 82.5 20 19.11 0.89200 95.54


of 174

hydroxy-5-

phenyl-1-trans-

pentenyl)-3,5 -

dihydroxy[1

,2 ,3 ,5 ]

Acetone 82.5 10 9.55 0.44600 95.54

Desvenlafaxine &

Its Intermediate

Acetone 82.5 3.77 3.60 0.16814 95.54

Acetone 82.5 0.37 0.35 0.01650 95.54

Acetone 82.5 0.37 0.35 0.01650 95.54

DCM 82.5 3.6 3.48 0.12456 96.54

DCM 82.5 3.2 3.09 0.11072 96.54

DMF 153 2.64 2.31 0.32894 87.54

DMF 153 1.36 1.19 0.16946 87.54

Methanol 64.5 1.64 1.59 0.05346 96.74

Desvenlafexine

base dry

DCM 82.5 3.6 3.48 0.12456 96.54

DCM 82.5 3.2 3.09 0.11072 96.54

DMF 153 2.64 2.31 0.32894 87.54

DMF 153 1.36 1.19 0.16946 87.54

Methanol 64.5 1.64 1.59 0.05346 96.74

Sitagliptin & Its

Intermediate

Methanol 64.5 7 6.77 0.22820 96.74

MDC 82.5 5 4.83 0.17300 96.54

IPA 82.5 4 3.87 0.13040 96.74

Sitaglimptin base MDC 82.5 5 4.83 0.17300 96.54

IPA 82.5 4 3.87 0.13040 96.74

Atorvastatin & Its

Intermediate

THF 82.5 9.5 9.19 0.30970 96.74

N‐Butyl

Lithium 82.5 7.35 7.11 0.23961 96.74

Ethyl

Acetate 82.5 17.06 16.30 0.76088 95.54

Methanol 64.5 13.64 13.20 0.44466 96.74

n‐Hexane 82.5 2.81 2.63 0.18153 93.54

Methyl

Tert Butyl 82.5 4.01 3.88 0.13073 96.74

Febuxostat & Its

Intermediate

Ethanol 82.5 10 9.67 0.32600 96.74

THF 82.5 15 14.51 0.48900 96.74

Ethanol 82.5 10 9.67 0.32600 96.74


of 174

DMF 153 11 9.63 1.37060 87.54

THF 82.5 10 9.67 0.32600 96.74

Ethyl 2-[3-Cyano-

4-(2-methyl

propoxy) phenyl

]-4-methyl-5-

thiazole

carboxylate

DMF 153 11 9.63 1.37060 87.54

2-[3-Cyano-4-(2-

methylpropoxy)

phenyl]-4-methyl-

5-thiazole

carboxylic Acid

THF 82.5 10 9.67 0.32600 96.74

Carbazepamine Ethanol 82.5 10.82 10.47 0.35273 96.74

Metoprolo & Its

Intermediate Toluene 82.5 2.25 2.06 0.19035 91.54

Levocitrizine

DIHCL & Its

Intermediate

MDC 82.5 23.83 23.01 0.82452 96.54

Acetone 82.5 15.38 14.69 0.68595 95.54

Ethyl

acetate 82.5 19.77 18.89 0.88174 95.54

Toluene 82.5 5.2 4.76 0.43992 91.54

Cyclohexa

ne 82.5 4.7 4.40 0.30362 93.54

C-(4-Chloro-

phenyl)-C-phenyl

methylamine

Toluene 82.5 5.2 4.76 0.43992 91.54

Cyclohexa

ne 82.5 4.7 4.40 0.30362 93.54

Finofibrate

Acetone 82.5 9.26 8.85 0.41300 95.54

Chlorofor

m 82.5 0.33 0.32 0.01472 95.54

IPA 82.5 0.17 0.16 0.00554 96.74

Toluene 82.5 53.89 49.33 4.55909 91.54

Chlorofor

m 82.5 2.99 2.86 0.13335 95.54

Levatiracetam &

Its Intermediate

Ethyl

acetate 82.5 6.07 5.80 0.27072 95.54


of 174

Methylene

Dichlorde 82.5 9.7 9.36 0.33562 96.54

2-Chloro Ethyl

Amine

Hydrochloride

EDC 82.5 1.88 1.74 0.14025 92.54

N,N, Bis (2-

Chloro Ethyl)

Amine

Hydrochloride

EDC 82.5 1.88 1.74 0.14025 92.54

Di Ethyl Amino

Ethyl Chloride

Hydrochloride

Toluene 82.5 1.5 1.37 0.12690 91.54

Acetone 82.5 1 0.96 0.04460 95.54

Di Methyl Amino

Ethyl Chloride

Hydrochloride

Ethylene

dichloride 82.5 2 1.85 0.14920 92.54

Isopropyl

alcohol 82.5 0.5 0.48 0.01630 96.74

1-[2-(2-

Hydroxyethoxy)

Ethyl]Piperazine

Methanol 64.5 0.39 0.38 0.01271 96.74

1 – Methyl– 3–

Phenyl

Piperazine

Toluene 82.5 6.92 6.33 0.58543 91.54

Ethyl

Acetate 82.5 1.8 1.72 0.08028 95.54

4-(2-Chloroethyl)

Morpholine

Hydrochloride

EDC 82.5 3.19 2.95 0.23797 92.54

5-(4-(4-(5-

Cyano1H-Indol-

3-Yl)- Butyl)-

Piperazin-1-

Yl)Benzofuran-2-

Carboxamide

DMF 153 100.5 87.98 12.5223

0 87.54

(R)-5-(2-

Aminopropyl)-2-

Methoxy

Benzene

Sulfonamide

Methanol 64.5 15.73 15.22 0.51280 96.74


of 174

(E)-7-((1R,2R,

3R,5S)-3,5-

Dihydroxy-2-((E)-

3-Hydroxy-5-

Phenylpent-1-En-

1-Yl)Cyclopentl)

Hept-5-Enoic

Acid

Methanol 64.5 12.43 12.02 0.40522 96.74

THF 82.5 7.81 7.56 0.25461 96.74

DMSO 82.5 7.81 6.84 0.97313 87.54

(S)-4-(4-(5-

Aminomethyl)-

2oxooxa Zolidin-

3-Yl) Phenyl)

Phorpholin-3-

One

THF 82.5 13.54 13.10 0.44140 96.74

Ethanol 82.5 14.43 13.96 0.47042 96.74

(3R,5R)-Tert-

Butyl 7-(2-(4-

Fluoro Phenyl)-5-

Isopropyl-3-

Phenyl- 4-

(Phenyl

Carbonyl)4-

Pyrol-1-Yl)-3,5-

Dihydroxy

Heptanoate

Methanol 64.5 2.49 2.41 0.08117 96.74

Cyclohexa

ne 82.5 11.29 10.56 0.72933 93.54

Toluene 82.5 2.13 1.95 0.18020 91.54

IPA 82.5 7.43 7.19 0.24222 96.74

(R)-2-(2-(4-((4-

Chlorophenyl)

Oxirane (Phenyl)

Methyl)

Piperazin- 1-

Yl)Ethoxy)

Acetamide

Toluene 111 4.73 4.33 0.40016 91.54

Cyclohexa

ne 69 4.27 3.99 0.27584 93.54

2-(4-(4-Chloro

benzoyl)

Phenoxy-2-

Methylpropanoic

Acid

Chlorolor

m 61.2 0.75 0.72 0.03345 95.54

Acetone 56.2 0.36 0.34 0.01606 95.54


of 174

2,2’-

Azanediylbis(1-

(6-

Fluorochroman-

2-Yl) Ethanol)

THF 65 65.79 63.65 2.14475 96.74

Methanol 64.5 13.16 12.73 0.42902 96.74

Ethyl

acetate 77 13.16 12.57 0.58694 95.54

THF 65 19.74 19.10 0.64352 96.74

Methanol 64.5 19.74 19.10 0.64352 96.74

Ethyl

acetate 77 13.16 12.57 0.58694 95.54


Sources - Charging Materials

Measures

- Enclose Process

- Minimum flanges & joints

- Handled by pump with double mechanical seals

- Proper Ventilation

- Adequate PPEs


Storage

details

Name of major Hazardous chemicals Remarks

Storage

tanks

Thionyl Chloride, Liquor Ammonia, Toluene,

Hydrochloric Acid, Methanol, MDC,

Storage

condition as ATP

Drum &

Carboy

storage

Ethyl Acetate, Sodium Hydroxide, Acetic anhydride,

Benzoyl Chloride, Triethyl Amine, Aluminium

Chloride, o-xylene, Pyridine, Chlorobenzene,

Potassium Hydroxide, Formaldehyde,

Epichlorohydrin, Chloroform, Cyclohexane,

Phosphoric Acid, n-Haxane, Acetone, IPA.

Storage

condition as ATP

Cylinder

Storage

Ammonia Gas, Hydrogen Gas. Storage

condition as

Under Pressure

Glass Bottle Bromine Storage

condition as ATP


Technical presentation was made by the project proponent with consultant/expert M/s. Green Leaf Envirotech

Pvt Ltd, Surat during SEAC meeting dated 11/02/2020.

Committee noted that this proposal is for new unit located in GIDC Dahej. Source of water is GIDC. PP


of 174

mentioned that concentrated effluent generated from process will be treated in Solvent Stripper followed by

Primary ETP – 2 & MEE, condensate from MEE will be treated in Secondary & Tertiary ETP – 1 and treated

effluent will be discharged into CETP Dahej after meeting its inlet norms while dilute effluent generated

washing, boiler blow down, cooling tower blow down and scrubber will be treated in proposed in-house

Primary, Secondary & Tertiary ETP – 1 along with MEE condensate and treated effluent will be discharged

into CETP Dahej after meeting its inlet norms. PP has proposed one steam boiler, HAG, TFH. Fuel used will

be Briquette of Bio-Coal/Agro Waste/Coal/Natural Gas. PP has addressed Hazardous Waste as per HWR –

2016.


Terms of Reference.



















6. Characteristic of effluent to be treated in proposed ETP – 1 consisting of Primary, Secondary &

Tertiary treatment along with its Adequacy.

7. Characteristic of effluent to be discharged into CETP of Dahej along with its quantity.

8. Membership Certificate from Common Facility in-line with the direction given by GPCB vide Letter

No. GPCB/P-1/8-G (5)/550706 dated 08/01/2020.

9. Membership Certificate from Common Facility (mentioning total capacity, consented quantity,

occupied capacity and spare capacity and norms of acceptance of effluent from member units) in-

line with the direction given by GPCB vide Letter No. GPCB/P-1/8-G (5)/550706 dated 08/01/2020.


of 174










15 SIA/GJ/IND2/48775/2019 M/S. Dharti Industries

Plot no. 57/1, Katosan Road, Detroj,

Ahmedabad.

Screening & Scoping





EIA/EMP report.



Sr.

no.

Name of the

Products

CAS no. /

CI no.

Quantity

MT/Month End-use of

the products


1 Ferric Alum 7783-83-7 250 -- 250 Water

purification

2 Aluminium Sulphate 7784-31-8 100 -- 100

water purificati

on and as a

mordant in

dyeing and

printing textiles

3 DCP (Di-calcium

Phosphate Dihydrate) 7757-93-9 100 -- 100

Water

purification to



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remove

dissolved

organic

material

4 Aluminium Hydroxide 21645-51-2 50 -- 50 Used in

pharma

5

Aluminium

chlorohydrate

solution

12042-91-0 25 -- 25

Water

purification to

remove

dissolved

organic

material

6 Imino Rifamycin 13292-46-1 0.5 0.5

Pharma

Intermediate

7

6-(4-methoxy-3-

tricyclo [3.3.1.1.]dec-

1-yl phenyl)

napthalene-2-

carboxylic acid

106685-40-9 -- 0.5 0.5

8

Methyl 6-[3-(1-

adamantyl)-4-

methoxyphenyl]-2-

naphthoate

106685-41-0 -- 0.5 0.5

9 Intermediate of

Nebivolol HCl 152520-56-4 -- 0.5 0.5

10 Intermediate of

Levosulpride 181289-33-9 -- 1.0 1.0

11

1-Trityl-4-formyl

imidazole or 1-

Tritylimidazole-4-

carboxaldehyde

331016-47-6 -- 0.5 0.5

12 Benzbromarone 3562-84-3 -- 1.0 1.0

13 Cyano Imidazole 288-32-4 -- 0.5 0.5

14

[3-Fluoro-4-(4-

morpholinyl)

nitrobenzene]

2689-39-6 -- 0.3 0.3

15 Benidipine HCl 91599-74-5 -- 0.3 0.3


of 174

16

3–(Carbamoyl

methyl)–5–methyl

hexanoic Acid

181289-33-8 -- 2.0 2.0

17 Bisphenol 80-05-7 -- 10.0 10.0

18 Benzyl Triethyl

Ammonium Chloride 1112-67.0 -- 200 200

19 3,4 dimethoxy

benzoic acid 93-07-2 -- 2 2

20 O Anisic Acid 579-75-9 -- 2.5 2.5

21 1,3 Propane diol 504-63-2 -- 10 10

22 Disulfiram 97-77-8 --

50 50

Total 525 282.1 807.1




Sr.

no. Particulars Details


(Rs. in Crores):

Existing*: 0.65 Crores

Proposed: 1.20 Crores

Total: 1.85 lakhs Crores

B Total Plot area

( sq. meter)

Existing*: 2502 Sq. m.

Proposed: 0 Sq. m.

Total: 2502 Sq. m.

Green belt area

( sq. meter)

Existing*: 250 Sq. m.

Proposed: 575 Sq. m.

Total: 825 Sq. m.

C Employment generation Existing*: 6

Proposed: 15

Total: 21

D Water


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i



GIDC water supply

Status of permission from the concern authority. Permission obtained from GIDC


Existing

KLD

Proposed

(Additional)

KLD

Total after

Expansion

KLD

Remarks

(P) Domestic 4 1 5 --

(Q) Gardening 2.5 1.8 4.3 --

(R) Industrial

Process Nil 1.4 1.4 --

Washing 0.2 0.5 0.7 --

Boiler 4.0 Nil 4.0 --

Cooling 7.5 Nil 7.5 --

Scrubber Nil 0.1 0.1

Others -- -- -- --

Industrial Total 14.2 3.8 18 --

Grand Total (A+B+C) 18.2 4.8 23 --







of 174

Category Existing

KLD

Proposed

(Additional)

KLD

Total after

Expansion

KLD

Remarks

(K) Domestic 3.6 0.9 4.5 Septic tank followed by

soak pit

(L) Industrial

Process Nil 3.4 3.4

To ETP

Washing 0.2 0.5 0.7

Boiler 0.2 Nil 0.2

Cooling 0.3 Nil 0.3

Scrubber Nil 0.1 0.1

Others -- -- --


water

4.7



Primary ETP: 7KLD


Chemical Dosing Tank

(200 L) * 3 Nos.

Collection Tank (7 KL)

Flash Mixer Cum

Primary Settling

Tank (6 KL)

Nutch Filter

(1 KL)

Thermic

Evaporator

@ 500 lit/hour

Sludge Evaporation Salt


of 174




Effluent will be treated in in-house ETP, and it will be evaporated.


Not Applicable, As there is in-house effluent treatment plant, which will be followed by

evaporation.


Domestic: Septic tank followed by Soak-pit

Industrial: Diluted streams will be treated in in-house ETP and treated effluent

will be evaporated



Not Applicable



Will be obtained



of 174



Total reuse: 0.0KLD

Source of waste

water for reuse with

quantity in KLD

(From where it is

coming)

Application area

with quantity in

KLD (Where it is

used)



BOD, TDS etc.)

Remarks

regarding

feasibility to

reuse i.e.

Not Applicable

E Air



Existing & Proposed

-

GIDC Water

Existing*: 17 KLD

Proposed: 6 KLD

Total: 23 KLD

Domestic

Existing*: 4 KLD

Proposed: 1 KLD

Total: 5 KLD

Gardening

Existing*: 2.5 KLD

Proposed: 1.8 KLD

Total: 4.3 KLD

Industrial

Existing*: 11.7 KLD

Proposed: 2 KLD

Total: 13.7 KLD

Sewage

Existing*: 3.6

Proposed: 0.9 KLD

Total: 4.5 KLD

Floor Washing

Existing*: 0.2 KLD

Proposed: 0.1 KLD

Total: 0.3 KLD

Cooling

Existing*: 7.5 KLD

Proposed: 0 KLD

Total: 7.5 KLD

Boiler

Existing*: 4.0 KLD

Proposed: 0 KLD

Total: 4.0 KLD

Vessel Washing

Existing*: 0 KLD

Proposed: 0.4 KLD

Total: 0.4 KLD

Scrubber

Existing*: 0 KLD

Proposed: 0.1 KLD

Total: 0.1 KLD

Process

Existing*: 0 KLD

Proposed: 1.4 KLD

Total: 1.4 KLD

0.3 0.3 0.2 0.4 0.1 3.4

To Septic tank

followed by soak

pit

Floor Washing

Existing*: 0.2 KLD

Proposed: 0.1 KLD

Total: 0.3 KLD

Cooling

Existing*: 7.5 KLD

Proposed: 0 KLD

Total: 7.5 KLD

Boiler

Existing*: 4.0 KLD

Proposed: 0 KLD

Total: 4.0 KLD

Washing

Existing*: 0 KLD

Proposed: 0.4 KLD

Total: 0.4 KLD

Scrubber

Existing*: 0 KLD

Proposed: 0.1 KLD

Total: 0.1 KLD

Process

Existing*: 0 KLD

Proposed: 1.4 KLD

Total: 1.4 KLD

ETP

Existing*: 0.7 KLD

Proposed: 4 KLD

Total: 4.7 KLD

Treated water will be evaporated


of 174

Sr.

no.

Source of

emission

With

Capacity

Stack

Height

(meter)

Type

of Fuel

Quantity

of Fuel

MT/Day

Type of

emissions

i.e. Air

Pollutants

Air Pollution

Control

Measures

(APCM)

1 Boiler

(1 TPH) 12

Briq

uette

s/

firew

ood

150

Kg/Hour

PM< 150

mg/Nm3

SO2≤100pp

m

NOx < 50

ppm

Multi Cyclone

Separator

followed by

Stack

2 D.G. Set

(35 KVA) 5

Dies

el 5 Lit/Hour

PM< 150

mg/Nm3

SO2≤100pp

m

NOx < 50

ppm

Acoustic

Enclosure

-


Existing & Pr posed

-

Sr.

no.

Specific

Source of

emission

(Name of

the Product

& Process)

Type of

emission

Stack/Vent

Height

(meter)


Measures

(APCM)


of 174

1 Reactor Acid Fumes 12 Alkali Scrubber

-


Standard handling practices are adopted for powdered chemical. Proper storage, charging

system, handling system and online monitoring systems are provided and same will be taken

care for proposed project.

F Hazardous waste


Existing & Proposed

i

Sr.

no.

Type/Name of

Hazardous

waste

Categor

y and

Schedul

e as per

HW

Rules.

Specific

Source of

generation

(Name of the

Activity,

Product etc.)

Quantity

(MT/Annum)

Management of

HW


1 Used /Spent

Oil

5.1 Plant &

machi-neries

0.012 0.02 0.032 Collection,

storage and

reused within

premises as

lubricant or

selling to

registered

recycler

2 Empty barrels/

Containers/

Liners

33.1 Raw material

storage

60 15 75 Transportation and

disposal by

selling to


of 174

Contaminated

with Hazardous

chemicals/

wastes

registered

recycler

3 Chemical

Sludge from

waste water

treatment

35.3 Effluent

treatment

plant

10 14 24 Collection,

storage,

Transportation

and disposal to

approved TSDF

4 Evaporator

salt

35.3 Effluent

treatment

plant

0 6 6 Collection,

storage,

Transportation

and disposal to

approved TSDF

5 Spent Carbon 28.2 Manu-

facturing

Process

0 2 2 Collection,

Storage,

Transportation

and Disposal to

CHWIF

6 Spent

Solvents

28.5 Manu-

facturing

Process

0 50 50 Collection,

recovery and

reuse in next

batch or sell to

common solvent

distillation unit

under rule-9

7 Residue and

wastes

28.1 Manu-

facturing

Process

0 65 65 Collection,

Storage,

Transportation

and Disposal to

CHWIF

8 Process

Sludge

17.1 Manu-

facturing

Process

300 0 300 Collection,

storage,

Transportation

and disposal to

approved TSDF


of 174

-


(For HW management)

Membership will be obtained as soon as possible

iii Details of Non-Hazardous waste & its disposal(MSW

and others)

Not applicable



Table Format)

** Please refer Annexure-1


Sr. No. Name Of Solvent

Recovered

Quantity

(MT/Month)

Fresh

Quantity

(MT/Month)

Recovery (%)

1 Iso Propyl Alcohol 57.65 5.71 93.4

2 Toluene 42.21 2.13 93.7

3 Methanol 9.23 0.49 95.6

4 Chloroform 3.00 0.15 95.0

5 Di Isopropyl Ether 3.00 0.17 94.5

6 Tetrahydrofuran 20.50 1.05 95.1

7 Acetic Acid 5.79 0.32 94.2

8 Methylene Di Chloride 0.06 0.003 95.7

9 Ethyl Acetate 142.06 6.86 94.9

10 Acetone 0.03 0.00 94.4

11 Di Chloro Methane 5.77 0.29 94.9

12 Triethyl Amine 1.54 0.08 95.0

13 Dimethyl Sulphoxide 7.21 0.26 96.4

14 T-Butanol 0.79 0.03 96.5

15 Ethylene di Chloride 2.68 0.17 93.8

16 p-aminobenzoic acid 4.13 0.27 93.5

17 Ethylene Glycol 0.60 0.02 96.8

18 Acetonitrite 80.00 4.72 94.1

19 4-formyl imidazole 0.46 0.03 94.4

20 Trityl Chloride 0.46 0.02 95.7

21 Methylene Chloride 5.80 0.32 93.8

22 Di-methyl formamide 2.88 0.16 94.6

23 Methyl Ethyl Ketone 7.10 0.46 93.5

403.0 23.7 95Total


of 174

Due to Manufacturing process and solvent handling chances of VOC emissions. Entire process

and material charging has been carried out in closed loop. Regular work place monitoring will be

done. Standard SOP will be followed to handle powder and liquid raw materials.


Storage tanks Methanol, Toluene, Sulphuric Acid HCl etc. ---

Drum/Barrel storage Caustic Flakes, Activated Carbon, Sodium

Sulphate, Caustic Lye etc.

--


Applicability of PESO: PESO permission will be obtained at time of commencement of project.

Technical presentation was made by the project proponent during SEAC meeting dated 11/02/2020.

Committee noted that this proposal is for expansion of project located in Village: Detroj. Committee noted that

PP has received Closure Direction under Section 33 (A) of the Water Act, 1974 from Gujarat Pollution Control

Board with Outward No. 503547 dated 26/04/2019 for non-compliance of existing CC&A and the Gujarat

Pollution Control Board has only given temporary revocation not exceeding three months from the dated

29/05/2019 with Outward No. 508452.

Committee asked PP to show permanent revocation order along with its compliance. PP mentioned that unit

has not been issued the same.

Committee noted that unit is not having permanent revocation and in this circumstance unit is in closer

direction as per the order of GPCB dated 29/05/2019 with Outward No. 508452 and expansion in such case

cannot be given as unit is not in compliance of existing CC&A.

After detail deliberation, Committee unanimously decided to Reject the Proposal with above

mentioned reason and Close the File. The same was conveyed to project proponent as well as

Consultant during presentation.

16 SIA/GJ/IND2/46756/2019 M/S. Archit Organosys Ltd. Screening & Scoping


of 174

Plot No.: 25/9/A, Phase III, GIDC Naroda,

Ahmedabad.





EIA/EMP report.



Sr.

No. Name of the product CAS No.

Quantity in MT/Month

End User Existin

g

Propose

d Ultimate

1 Mono Chloro Acetic Acid (MCAA) 79-11-8 120.00 380.00 500.00

Pharmaceutical

s Industries

2 Chloro Acetyl Chloride (CAC) 79-04-9

0.00 100.00 100.00 3 Tri Chloro acetyl chloride (TCAC) 76-02-8

4 Tri chloro Acetic Acid (TCAA) 76-03-9

5 Sulphur Mono Chloride (SMC) 10025-67-9 0.00 25.00 25.00 Intermediate for

captive use

6 Acid Chlorides likes

0.00 100.00 100.00 Pharma

Intermediates

6.1 Para Chloro Benzoyl Chloride 122-01-0

6.2 Propionyl Chloride 79-03-8

6.3 Octenyl Chloride 62568-82-5

6.4 Iso Phthaloyl Chloride 99-63-8

6.5 Isobutyril Chloride 79-30-1

6.6 Valeryl Chloride 638-29-9

6.7 Pivaloyl Chloride 3282-30-2

6.8 3 Chloro Propionyl Chloride 625-36-5

6.9 2 Chloro Propionyl Chloride 7629-09-8

6.10 4 Chloro butyryl Chloride 4635-59-0

6.11 Chloro pivaloly Chloride 4300-97-4

6.12 Neodecanoyl Chloride 40292-82-8

6.13 2-Ethyl Hexanoyl Chloride 760-67-8

6.14 Isononanoyl Chloride 3282-30-2

6.15 Neopentyl Chloride 753-89-9


of 174

6.16 Terephthaloyl Chloride 100-20-9

6.17 Phthaloyl Chloride 88-95-9

6.18 n-Butyryl Chloride 141-75-3

7 MCA Derivatives likes

0.00 150.00 150.00

7.1 Methyl Mono Chloro Acetate

(MMCA) 96-34-4

Pharmaceutical

s Industries 7.2 Ethyl Mono Chloro Acetate (EMCA) 105-39-5

7.3 Butyl Mono Chloro Acetate (BMCA) 590-02-3

7.4 Iso Propyl Chloro Acetate (IPCA) 105-48-6

7.5 Sodium Mono Chloro Acetate

(SMCA) 3926-62-3

Surfectants 7.6 Methyl Tri Chloro Acetate (MTCA) 598-99-2

7.7 Methyl Di Chloro Acetate (MDCA) 116-54-1

7.8 Carboxy Methyl Cellulose (CMC) 9004-32-4 Cosmetics/

Surfactants

8.1 2,6 Di Chloro Phenol (2,6 DCP) 87-65-0 0.00 50.00 50.00

Pharmaceutical

s Industries 8.2 2,4 Di Chloro Phenol (2,4 DCP) 120-83-2

9 Glycolic acid 79-14-1 0.00 100.00 100.00 Surfectants

10 Glycine 56-40-6 0.00 50.00 50.00

11 Betaine 107-43-7 0.00 15.00 15.00 Cosmetics

Total 120.00 970.00 1090.00 --




Sr

No

Particulars Details


(Rs. in Crores):

Existing:4.2 Cr

Proposed:5.0 Cr

Total: 9.2 Cr

B Total Plot area

( sq. meter)



Total:3959.00 Sq. m.

Green belt area

( sq. meter)



Total: 395.00 Sq. m.


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C Employment generation Existing:15

Proposed:10

Total:25

D Water

i



GIDC Supply

Status of permission from the concern authority. Applied for permission to concern

authority for additional water

supply


Sr.

No. Category

Water Consumption in KLD

Remark

Existing Proposed Ultimate

1 Domestic 1.00 1.00 2.00

Water Source :

GIDC Water

Supply

2 Gardening 0.00 2.00 2.00

3

Industrial

(a) Process 0.00 1.40 1.40

(b) Boiler 0.50 6.00 6.50

(c) Cooling 0.00 2.00 2.00

(d) Other Use (Scrubbing

System) 8.10 42.00 50.10

Total industrial (3) 8.60 51.40 60.00

Total ( 1,2 &3 ) 9.60 54.40 64.00


2) Quantity to be recycled: 0.80 KLD




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Sr.

No. Category

Wastewater Generation in KLD

Remark

Existing Proposed Ultimate

1 Domestic 0.80 0.80 1.60

will be disposed off

through soak pit

system/septic tank.

2 Gardening 0.00 0.00 0.00 --

3

Industrial

@0.80 KLD effluent will be

reused in scrubbing

system.

(a) Process 0.00 0.00 0.00

(b) Boiler 0.00 0.60 0.60

(c) Cooling 0.00 0.20 0.20

(d) Other Use

(Scrubbing System) 0.00 0.00 0.00

Total industrial (3) 0.00 0.80 0.80

Total (1,2 &3) 0.80 1.60 2.40 --



Sr. No. Name of the Unit Nos Volume Remarks

1 Collection Tank 1 2.0 KL Proposed


Not Applicable

Note: (In case of CETP discharge):



Not Applicable


Not Applicable


Domestic: 1.60 KLD will be disposed through septic/soak pit system

Industrial: 0.80 KLD will be reused in scrubbing system.



Not Applicable


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Total reuse:0.80 KLD

Source of waste water for

reuse with quantity in KLD

(From where it is coming)

Application area with

quantity in KLD

(Where it is used)

Characteristics of

waste water to be

reused (COD, BOD,

TDS etc.)

Remarks

regarding

feasibility to

reuse i.e.

Cooling bleed-off & Boiler

blow-down

(0.80 KLD)

Scrubbing System TDS:4,000 - 5,000 mg/L Feasible

E Air



Existing & Proposed

Existing:

Sr.

No.

Stack

Attached

to

Stack

Height

(Meter)

Fuel

Type

Fuel

consumption

rate (MT/Day)

Type of

emissions i.e.

Air Pollutants

APCM

1 Steam Boiler

(600 kg/Hr) 12

Briquette/

Agro waste 2.7 MT/Day

SPM,

SO2,

Multi

Cyclone


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2

Hot Air

Generator

(120000

kcal/Hr)

12 Briquette/

Agro waste 0.5 MT/Day

NOx Separator

Proposed:

There is no any additional flue gas emission after proposed expansion.


Existing and Proposed :

Sr.

No.

Specific Source of

emission (Name of the

Product & Process)

Type of emission

Stack

Height

(meter)


Measures (APCM)

Existing

1

Reaction Vessel

(MCA) (CAC, TCAC,

TCAA, 2,4 DCP & 2, 6

DCP)

HCl<20 mg/NM3,

PM<150 mg/NM3,

Cl2<09 mg/NM3,

SO2<60 mg/NM3

20

Four stage water scrubber**

followed by two stage Alkali

Scrubber

Proposed

2 Reaction Vessel

(Acid Chlorides)

HCl<20 mg/NM3,

PM<150 mg/NM3,

Cl2<09 mg/NM3

20

Four stage water scrubber

followed by two stage alkali

scrubber

Note:-

*Existing reaction vessel for MCA will be used for proposed production of CAC, TCAC, TCAA,

2,4 DCP & 2, 6 DCP product after expansion.

**After expansion, four stage water scrubbers will be proposed instead of present existing two

stage water scrubber as APCM with existing reaction vessel of MCA.


Following measures will be followed to reduce the fugitive emission:

Internal road will be either concreted or asphalted or paved properly to reduce the fugitive emission

during vehicular movement.

Air borne dust will be controlled with water sprinklers at suitable locations in the plant.

A greenbelt will be developed around the plant boundary and also along the roads to mitigate fugitive

and transport dust emission.

F Hazardous waste


Existing & Proposed


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i Sr.

No.

Type

of Waste

Source

of

Generation

Catego

ry

Quantity, MT/Annum Disposal/ Management

Facility Exist

ing

Propos

ed

Ultim

ate

1 Used Oil Plant

Machineries 5.1 0.05 0.30 0.35

Collection, Storage & reused

as lubricant in plant

machinery within premises.

2

Discarded

Container/

Liners

Storage of

Raw

material and

Products

33.1 36.00 108.00 144.0

0


Transportation & Disposal by

sold out to authorized

recyclers

3 Distillation

Residue

From

Process 36.4 0.00 20.00 20.00


Transportation & Disposal to

authorized CHWIF site

4 NH4Cl

Solution

From

Process

(Group No.

7)

26.1 0.00 300.00 300.0

0



sold out to actual users

under rule 9 of HWM Rules,

2016.

5

Sodium Bi

Sulphate

Solution

From

scrubbing

system

26.1 0.00 7100.00 7100.

00





2016.

6

HCl

Solution

(30 %)

From

scrubbing

system

26.3 2400.

00

20600.0

0

23000

.00





2016.

7 NaCl

Solution

From

Process

(Glycolic

Acid &

Betaine)

26.3 0.00 800.00 800.0

0





2016.


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8 Spent

Catalyst

From

Process

(Glycine)

26.5 0.00 70.00 70.

00


Transportation & Disposal to

authorized CHWIF site

9 Mother

Liquor

From

Process

(MCAA)

26.3 0.00 1200.00 1200.

00

Collection, Storage &

Reused in manufacturing

process(in TCAC & TCAA)

within premises.

10 Spent

Solvent

From

Distillation

Process

26.4 0.00 22.00 22.00





2016.


(For HW management)

Will be obtained at time of REIA report

submission.


(MSW and others)

--



Table Format)

Sr.

No. Solvent Name

Consumption

MT/M

Recovered

MT/Month

Fresh

MT/Month

%

Recovery

1 Methanol 43.48 41.35 2.13 95.10

2 Ethanol 38.10 36.65 1.45 96.20

3 Butanol 38.10 36.57 1.52 96.00

4 IPA 38.10 36.65 1.45 96.20

5 Tri Methyl Amine 6.45 6.13 0.32 95.00


--



Storage tanks Acetic Acid, Methanol, HCL,Solvent --

Drum/Barrel storage n-valeric acid, isobutyric acid, 2-hexanoic acid --

Tonners Chlorine --


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Applicability of PESO : PESO permission Will be obtained at time of commencement of said

project for additional storage.

Technical presentation was made by the project proponent with consultant/expert Ramans Enviro Service Pvt

Ltd, Ahmedabad during SEAC meeting dated 11/02/2020.

Committee noted that this proposal is for expansion of project located in GIDC - Naroda. PP has submitted

compliance of earlier CC&A. PP mentioned that there are no any court case or public complaints pending

against this unit. Source of water is GIDC. PP mentioned that effluent generated from cooling blow down &

boiler blow down will be directly reused in scrubber. PP mentioned that there will no additional fuel

requirement and existing boiler & HAG will be able to cater the steam requirement. Committee noted that PP

has addressed the Hazardous Waste as per HWR – 2016.


Terms of Reference.





1. Details with respect to justification for proposed expansion: (1) To address proportionate

availability of space for production plant. (2) To address proportionate availability of storage area

for raw materials finished goods, utilities considering fire-safety norms & PESO standards and

goods carrier movement within premises. (3) To address proportionate captive/common

infrastructure available to accommodate additional load due to proposed expansion. (4)

Environment impact and its mitigation measures for common/ captive infrastructure due to

proposed production.














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7. Characteristic of effluent from boiler blow down & cooling tower blow down along with its quantity

and its feasibility for direct reuse in Scrubber.

8. Steam balance mentioning that existing utility shall be capable to cater the load of expansion.


10. Material Mass Balance expelling that there will be no any waste water generation from

manufacturing process.

11. Technical Justification for no requirement of any washing effluent.









Meeting ended with thanks to the Chair.

Minutes approved by:

1. Dr. Dinesh Misra, Chairman, SEAC

2. Shri S. C. Srivastav, Vice Chairman, SEAC

3. Shri V. N. Patel, Member, SEAC

4. Shri. R. J. Shah, Member, SEAC

5. Dr. V. K. Jain, Member, SEAC

6. Shri. A. K. Muley, Member, SEAC


Minutes of the 596th Minutes of the 596th I.pdf596th meeting of SEAC-Gujarat, dated 11.02.2020 Page...

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Transcript of Minutes of the 596th Minutes of the 596th I.pdf596th meeting of SEAC-Gujarat, dated 11.02.2020 Page...