SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006

METHIC VIOLET E LIQUID (C.I. BASIC VIOLET 4)

Version 6.0 Print Date 2016/04/05

Revision date / valid from 2016/04/05 MSDS code: GZD080

R45326 1/17 EN

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Trade name : METHIC VIOLET E LIQUID (C.I. BASIC VIOLET 4)

1.2. Relevant identified uses of the substance or mixture and uses advised against

Use of the Substance/Mixture

: Colouring agents, dyes

Uses advised against : At this moment we have not identified any uses advised

against

1.3. Details of the supplier of the safety data sheet

Company : Brenntag Colours Ltd. High Level Way Halifax West Yorkshire HX1 4PN - GB

Telephone : 00 44 (0) 1422 358 431 Telefax : 00 44 (0) 1422 330 867 E-mail address : msds@brenntag.co.uk

1.4. Emergency telephone number

Emergency telephone number

: EMERGENCY ONLY TELEPHONE NUMBER:

00 32 (0) 3 575 55 55 (SGS Emergency Response Services -

24 hours)

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008

REGULATION (EC) No 1272/2008

Hazard class Hazard category Target Organs Hazard

statements

Acute toxicity (Oral) Category 4 --- H302

Skin corrosion Category 1B --- H314

METHIC VIOLET E LIQUID (C.I. BASIC VIOLET 4)

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Acute aquatic toxicity Category 1 --- H400

For the full text of the H-Statements mentioned in this Section, see Section 16.

Classification according to EU Directives 67/548/EEC or 1999/45/EC

Directive 67/548/EEC or 1999/45/EC

Hazard symbol / Category of danger Risk phrases

Corrosive (C)Corrosive (C) R34

Harmful (Xn)Harmful (Xn) R22

Dangerous for the environment (N)Dangerous for the environment (N)

R50

For the full text of the R-phrases mentioned in this Section, see Section 16.

Most important adverse effects

Human Health : See section 11 for toxicological information.

Physical and chemical hazards

: See section 9 for physicochemical information.

Potential environmental effects

: See section 12 for environmental information.

2.2. Label elements

Labelling according to Regulation (EC) No 1272/2008 Hazard symbols :

Signal word : Danger

Hazard statements : H302 Harmful if swallowed.

H314 Causes severe skin burns and eye damage. H400 Very toxic to aquatic life.

Precautionary statements

Prevention : P273 Avoid release to the environment.

P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.

Response : P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do

NOT induce vomiting.

METHIC VIOLET E LIQUID (C.I. BASIC VIOLET 4)

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P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.

P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor.

P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Hazardous components which must be listed on the label:

• Tris[4-(diethylamino)phenyl]methylium acetate • acetic acid • hydrochloric acid

2.3. Other hazards

For Results of PBT and vPvB assessment see section 12.5.

SECTION 3: Composition/information on ingredients

3.2. Mixtures

Hazardous components Amount [%]

Classification (REGULATION (EC) No 1272/2008)

Classification

(67/548/EEC) Hazard class /

Hazard category

Hazard

statements

Tris[4-(diethylamino)phenyl]methylium acetate

CAS-No. : 63157-72-2

EC-No. : 263-974-8

>= 30 - < 50 Acute Tox.4 Skin Corr.1B

Aquatic Acute1

H302 H314

H400

Harmful; Xn; R22 Corrosive; C; R34

Dangerous for the environment; N; R50

acetic acid

Index-No. : 607-002-00-6 CAS-No. : 64-19-7

EC-No. : 200-580-7 EC Registration

: 01-2119475328-30-xxxx

>= 30 - < 50 Flam. Liq.3 Skin Corr.1A

H226 H314

R10 Corrosive; C; R35

hydrochloric acid

Index-No. : 017-002-01-X CAS-No. : 7647-01-0

EC-No. : 231-595-7 EC Registration

: 01-2119484862-27-xxxx

>= 1 - < 5 Met. Corr.1 STOT SE3

Skin Corr.1B

H290 H335

H314

Irritant; Xi; R37 Corrosive; C; R34

METHIC VIOLET E LIQUID (C.I. BASIC VIOLET 4)

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For the full text of the R-phrases mentioned in this Section, see Section 16. For the full text of the H-Statements mentioned in this Section, see Section 16.

SECTION 4: First aid measures

4.1. Description of first aid measures

General advice : Take off all contaminated clothing immediately.

If inhaled : If inhaled, remove to fresh air. Seek medical advice.

In case of skin contact : Remove contaminated clothing and shoes. Wash off immediately with soap and plenty of water. Consult a physician.

In case of eye contact : Rinse immediately with plenty of water, also under the eyelids,

for at least 15 minutes. Seek medical advice.

If swallowed : Do NOT induce vomiting. Seek medical advice.

4.2. Most important symptoms and effects, both acute and delayed

Symptoms : See Section 11 for more detailed information on health effects and symptoms.

Effects : See Section 11 for more detailed information on health effects and symptoms.

4.3. Indication of any immediate medical attention and special treatment needed

Treatment : Treat symptomatically.

SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media

: Water spray, Foam

Unsuitable extinguishing media

: No information available.

5.2. Special hazards arising from the substance or mixture

Specific hazards during firefighting

: May decompose in a fire giving off toxic fumes

5.3. Advice for firefighters

Special protective equipment for firefighters

: In the event of fire, wear self-contained breathing apparatus.Wear appropriate body protection (full protective suit)

: Wear self-contained breathing apparatus and protective suit.

METHIC VIOLET E LIQUID (C.I. BASIC VIOLET 4)

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Further advice : Collect contaminated fire extinguishing water separately. This must not be discharged into drains.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Personal precautions : Use personal protective equipment. Keep away unprotected persons. Avoid contact with the skin and the eyes. Do not breathe vapours or spray mist. Wear respiratory protection. For personal protection see section 8.

6.2. Environmental precautions

Environmental precautions

: The product should not be allowed to enter drains, water courses or the soil. In case of large spillage contact the local authority.

6.3. Methods and materials for containment and cleaning up

Methods and materials for containment and cleaning up

: Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13).

Further information : Treat recovered material as described in the section "Disposal

considerations".

6.4. Reference to other sections

See Section 1 for emergency contact information. See Section 8 for information on personal protective equipment. See Section 13 for waste treatment information.

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Advice on safe handling : Ensure adequate ventilation. Avoid contact with the skin and the eyes.

Hygiene measures

: Smoking, eating and drinking should be prohibited in the application area. Wash hands before breaks and at the end of workday. Take off all contaminated clothing immediately. Avoid contact with skin, eyes and clothing. Do not breathe vapours or spray mist.

7.2. Conditions for safe storage, including any incompatibilities

Requirements for storage areas and containers

: Keep containers tightly closed in a dry, cool and well-ventilated place. Keep from freezing. Keep away from food, drink and animal feedingstuffs.

METHIC VIOLET E LIQUID (C.I. BASIC VIOLET 4)

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Advice on protection against fire and explosion

: Normal measures for preventive fire protection.

Further information on storage conditions

: Keep tightly closed in a dry and cool place. Keep in a well- ventilated place. Keep away from heat. Protect from frost