METHIC VIOLET E LIQUID (C.I. BASIC VIOLET 4) Yarmouth... · METHIC VIOLET E LIQUID (C.I. BASIC...

SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006

METHIC VIOLET E LIQUID (C.I. BASIC VIOLET 4)

Version 6.0 Print Date 2016/04/05

Revision date / valid from 2016/04/05 MSDS code: GZD080

R45326 1/17 EN

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Trade name : METHIC VIOLET E LIQUID (C.I. BASIC VIOLET 4)

1.2. Relevant identified uses of the substance or mixture and uses advised against

Use of the Substance/Mixture

: Colouring agents, dyes

Uses advised against : At this moment we have not identified any uses advised

against

1.3. Details of the supplier of the safety data sheet

Company : Brenntag Colours Ltd. High Level Way Halifax West Yorkshire HX1 4PN - GB

Telephone : 00 44 (0) 1422 358 431 Telefax : 00 44 (0) 1422 330 867 E-mail address : [email protected]

1.4. Emergency telephone number

Emergency telephone number

: EMERGENCY ONLY TELEPHONE NUMBER:

00 32 (0) 3 575 55 55 (SGS Emergency Response Services -

24 hours)

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008

REGULATION (EC) No 1272/2008

Hazard class Hazard category Target Organs Hazard

statements

Acute toxicity (Oral) Category 4 --- H302

Skin corrosion Category 1B --- H314


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Acute aquatic toxicity Category 1 --- H400

For the full text of the H-Statements mentioned in this Section, see Section 16.

Classification according to EU Directives 67/548/EEC or 1999/45/EC

Directive 67/548/EEC or 1999/45/EC

Hazard symbol / Category of danger Risk phrases

Corrosive (C)Corrosive (C) R34

Harmful (Xn)Harmful (Xn) R22

Dangerous for the environment (N)Dangerous for the environment (N)

R50

For the full text of the R-phrases mentioned in this Section, see Section 16.

Most important adverse effects

Human Health : See section 11 for toxicological information.

Physical and chemical hazards

: See section 9 for physicochemical information.

Potential environmental effects

: See section 12 for environmental information.

2.2. Label elements

Labelling according to Regulation (EC) No 1272/2008 Hazard symbols :

Signal word : Danger

Hazard statements : H302 Harmful if swallowed.

H314 Causes severe skin burns and eye damage. H400 Very toxic to aquatic life.

Precautionary statements

Prevention : P273 Avoid release to the environment.

P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.

Response : P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do

NOT induce vomiting.


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P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.

P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor.

P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Hazardous components which must be listed on the label:

• Tris[4-(diethylamino)phenyl]methylium acetate • acetic acid • hydrochloric acid

2.3. Other hazards

For Results of PBT and vPvB assessment see section 12.5.

SECTION 3: Composition/information on ingredients

3.2. Mixtures

Hazardous components Amount [%]

Classification (REGULATION (EC) No 1272/2008)

Classification

(67/548/EEC) Hazard class /

Hazard category

Hazard

statements

Tris[4-(diethylamino)phenyl]methylium acetate

CAS-No. : 63157-72-2

EC-No. : 263-974-8

>= 30 - < 50 Acute Tox.4 Skin Corr.1B

Aquatic Acute1

H302 H314

H400

Harmful; Xn; R22 Corrosive; C; R34

Dangerous for the environment; N; R50

acetic acid

Index-No. : 607-002-00-6 CAS-No. : 64-19-7

EC-No. : 200-580-7 EC Registration

: 01-2119475328-30-xxxx

>= 30 - < 50 Flam. Liq.3 Skin Corr.1A

H226 H314

R10 Corrosive; C; R35

hydrochloric acid

Index-No. : 017-002-01-X CAS-No. : 7647-01-0

EC-No. : 231-595-7 EC Registration

: 01-2119484862-27-xxxx

>= 1 - < 5 Met. Corr.1 STOT SE3

Skin Corr.1B

H290 H335

H314

Irritant; Xi; R37 Corrosive; C; R34


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For the full text of the R-phrases mentioned in this Section, see Section 16. For the full text of the H-Statements mentioned in this Section, see Section 16.

SECTION 4: First aid measures

4.1. Description of first aid measures

General advice : Take off all contaminated clothing immediately.

If inhaled : If inhaled, remove to fresh air. Seek medical advice.

In case of skin contact : Remove contaminated clothing and shoes. Wash off immediately with soap and plenty of water. Consult a physician.

In case of eye contact : Rinse immediately with plenty of water, also under the eyelids,

for at least 15 minutes. Seek medical advice.

If swallowed : Do NOT induce vomiting. Seek medical advice.

4.2. Most important symptoms and effects, both acute and delayed

Symptoms : See Section 11 for more detailed information on health effects and symptoms.

Effects : See Section 11 for more detailed information on health effects and symptoms.

4.3. Indication of any immediate medical attention and special treatment needed

Treatment : Treat symptomatically.

SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media

: Water spray, Foam

Unsuitable extinguishing media

: No information available.

5.2. Special hazards arising from the substance or mixture

Specific hazards during firefighting

: May decompose in a fire giving off toxic fumes

5.3. Advice for firefighters

Special protective equipment for firefighters

: In the event of fire, wear self-contained breathing apparatus.Wear appropriate body protection (full protective suit)

: Wear self-contained breathing apparatus and protective suit.


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Further advice : Collect contaminated fire extinguishing water separately. This must not be discharged into drains.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Personal precautions : Use personal protective equipment. Keep away unprotected persons. Avoid contact with the skin and the eyes. Do not breathe vapours or spray mist. Wear respiratory protection. For personal protection see section 8.

6.2. Environmental precautions

Environmental precautions

: The product should not be allowed to enter drains, water courses or the soil. In case of large spillage contact the local authority.

6.3. Methods and materials for containment and cleaning up

Methods and materials for containment and cleaning up

: Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13).

Further information : Treat recovered material as described in the section "Disposal

considerations".

6.4. Reference to other sections

See Section 1 for emergency contact information. See Section 8 for information on personal protective equipment. See Section 13 for waste treatment information.

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Advice on safe handling : Ensure adequate ventilation. Avoid contact with the skin and the eyes.

Hygiene measures

: Smoking, eating and drinking should be prohibited in the application area. Wash hands before breaks and at the end of workday. Take off all contaminated clothing immediately. Avoid contact with skin, eyes and clothing. Do not breathe vapours or spray mist.

7.2. Conditions for safe storage, including any incompatibilities

Requirements for storage areas and containers

: Keep containers tightly closed in a dry, cool and well-ventilated place. Keep from freezing. Keep away from food, drink and animal feedingstuffs.


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Advice on protection against fire and explosion

: Normal measures for preventive fire protection.

Further information on storage conditions

: Keep tightly closed in a dry and cool place. Keep in a well-ventilated place. Keep away from heat. Protect from frost.

Advice on common storage

: Keep away from food, drink and animal feedingstuffs.

Other data : Stable under normal conditions.

7.3. Specific end use(s)

Specific use(s) : No information available.

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

Component: acetic acid CAS-No. 64-19-7

Derived No Effect Level (DNEL)/Derived Minimal Effect Level (DMEL)

DNEL

Workers, Long-term - local effects, Inhalation

: 25 mg/m3

DNEL

Workers, Acute - local effects, Inhalation

: 25 mg/m3

DNEL

Consumers, Long-term - local effects, Inhalation

: 25 mg/m3

DNEL

Consumers, Acute - local effects, Inhalation

: 25 mg/m3

Predicted No Effect Concentration (PNEC)

Fresh water

: 3.058 mg/l

Marine water

: 0.306 mg/l

Intermittent releases

: 30.58 mg/l

Sewage treatment plant (STP)

: 85 mg/l

Fresh water sediment

: 11.36 mg/kg d.w.

Marine sediment

: 1.136 mg/kg d.w.


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Soil

: 0.47 mg/kg d.w.

Other Occupational Exposure Limit Values

EU. Indicative Exposure Limit Values in Directives 91/322/EEC, 2000/39/EC, 2006/15/EC, 2009/161/EU, Time Weighted Average (TWA): 10 ppm, 25 mg/m3 Indicative ELV (IE), Short Term Exposure Limit (STEL): 15 ppm, 37 mg/m3 Indicative OELV

Component: hydrochloric acid CAS-No. 7647-01-0

Derived No Effect Level (DNEL)/Derived Minimal Effect Level (DMEL)

DNEL

Workers, Acute - local effects, Inhalation

: 15 mg/m3

DNEL

Workers, Long-term - local effects, Inhalation

: 8 mg/m3

Predicted No Effect Concentration (PNEC)

Fresh water

: 36 µg/l

Marine water

: 36 µg/l

Intermittent releases

: 45 µg/l

Sewage treatment plant (STP)

: 36 µg/l

Fresh water sediment Exposition is not expected.

:

Marine sediment Exposition is not expected.

:

Soil Exposition is not expected.

:

Other Occupational Exposure Limit Values

UK. EH40 Workplace Exposure Limits (WELs), Short Term Exposure Limit (STEL):, Gas and aerosol mists. 5 ppm, 8 mg/m3

UK. EH40 Workplace Exposure Limits (WELs), Time Weighted Average (TWA):, Gas and aerosol mists. 1 ppm, 2 mg/m3


R45326 / Version 6.0 8/17 EN

EU. Indicative Exposure Limit Values in Directives 91/322/EEC, 2000/39/EC, 2006/15/EC, 2009/161/EU, Time Weighted Average (TWA): 5 ppm, 8 mg/m3 Indicative EU. Indicative Exposure Limit Values in Directives 91/322/EEC, 2000/39/EC, 2006/15/EC, 2009/161/EU, Short Term Exposure Limit (STEL): 10 ppm, 15 mg/m3 Indicative ELV (IE), Short Term Exposure Limit (STEL): 10 ppm, 15 mg/m3 Indicative OELV ELV (IE), Time Weighted Average (TWA): 5 ppm, 8 mg/m3 Indicative OELV

8.2. Exposure controls

Appropriate engineering controls

Ensure adequate ventilation.

Personal protective equipment

Respiratory protection

Advice : In case of insufficient ventilation, wear suitable respiratory equipment.

Hand protection Advice : Protective gloves

The glove material has to be impermeable and resistant to the product / the substance / the preparation. Take note of the information given by the producer concerning permeability and break through times, and of special workplace conditions (mechanical strain, duration of contact). Protective gloves should be replaced at first signs of wear.

Material : Nitrile rubber

Eye protection

Advice : Tightly fitting safety goggles

Skin and body protection

Advice : Protective work clothing Complete suit protecting against chemicals


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Protective measures

Advice : Personal protective equipment comprising: suitable protective gloves, safety goggles and protective clothing

Environmental exposure controls

General advice : The product should not be allowed to enter drains, water courses or the soil. In case of large spillage contact the local authority.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Form : liquid

Colour : violet

Odour : no data available

Odour Threshold : no data available

pH : 4

Freezing point : no data available

Boiling point : no data available

Flash point : > 100 °C Evaporation rate : no data available

Flammability (solid, gas) : no data available

Upper explosion limit : not determined

Lower explosion limit : not determined

Vapour pressure : no data available

Relative vapour density : no data available

Relative density : no data available

Density : no data available

Water solubility : no data available

Solubility in other solvents : not determined

Solubility/qualitative : No information available.

Partition coefficient: n-octanol/water : no data available


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Auto-ignition temperature : no data available

Thermal decomposition : Under certain fire conditions, traces of other toxic products cannot be excluded.

Viscosity, dynamic : no data available

Viscosity, kinematic : no data available

Explosive properties : EU legislation: not determined

Explosivity : no data available

Oxidizing properties : Not determined.

9.2. Other information

Burning number : (20 °C) not determined

Sublimation point : no data available

Bulk density : no data available

Flow time : no data available

Impact Sensitivity : no data available

Surface tension : not determined

Oxidizing potential : no data available

SECTION 10: Stability and reactivity

10.1. Reactivity

Advice : Stable under recommended storage conditions.

10.2. Chemical stability

Advice : Stable under recommended storage conditions.

10.3. Possibility of hazardous reactions

Hazardous reactions : Hazardous decomposition products formed under fire conditions.

10.4. Conditions to avoid

Conditions to avoid : Keep from freezing.Avoid high temperatures. Thermal decomposition : Under certain fire conditions, traces of other toxic products

cannot be excluded.


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10.5. Incompatible materials

Materials to avoid : Oxidizing agents

10.6. Hazardous decomposition products

Hazardous decomposition products

: May decompose in a fire giving off toxic fumes

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Data for the product

Acute toxicity

Oral

Harmful if swallowed., Cause serious burns with severe pains,

vomiting, pains in the stomach, possibly chock and damaged kidneys. The burn may occur even if only small amounts have been swallowed.

Acute toxicity estimate

: 1064 mg/kg ) (Calculation method)

Inhalation

Inhalation may cause pain in respiratory system, sneezing,

coughing and difficulty in breathing. Risk for pulmonary edema by high concentration.

Dermal

no data available

Other routes

no data available

Irritation

Skin

Result : corrosive effects

Eyes

Result : corrosive effects

Risk of serious damage to eyes.

Splashes in the eyes may cause painful burns, which may result in


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permanent damage to the eyes.

Sensitisation

Result : No sensitizing effect known.

CMR effects

CMR Properties

Carcinogenicity

: no data available

Mutagenicity

: no data available

Teratogenicity

: no data available

Reproductive toxicity

: no data available

Specific Target Organ Toxicity

Single exposure

Remark

: no data available

Repeated exposure

Remark

: no data available

Other toxic properties

Repeated dose toxicity

no data available

Aspiration hazard

no data available,

Further information

Other relevant toxicity information

: If ingested, severe burns of the mouth and throat, as well as a danger of perforation of the oesophagus and the stomach.

Component: acetic acid CAS-No. 64-19-7

Acute toxicity

Oral

LD50 Oral : 3310 mg/kg (Rat)


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SECTION 12: Ecological information

12.1. Toxicity


Acute toxicity

Fish

no data available

Toxicity to daphnia and other aquatic invertebrates

EC50

: < 0.1 mg/l (Daphnia (water flea); 48 h)

algae

no data available

Acute aquatic toxicity

Result

: no data available

Chronic toxicity

Chronic aquatic toxicity

Result

: no data available

12.2. Persistence and degradability


Persistence and degradability

Biodegradability

Result

: This information is not available.

12.3. Bioaccumulative potential


Bioaccumulation

Result



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12.4. Mobility in soil


Mobility

Result


Surface tension

Result

: not determined

12.5. Results of PBT and vPvB assessment


Results of PBT and vPvB assessment

Result

: no data available

Result

: This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

12.6. Other adverse effects


Biochemical Oxygen Demand (BOD)

Result

: no data available

Chemical Oxygen Demand (COD)

Result

: no data available

Additional ecological information

Result

: Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

SECTION 13: Disposal considerations

13.1. Waste treatment methods

Product

: Disposal together with normal waste is not allowed. Special disposal required according to local regulations. Do not let product enter drains. Contact waste disposal services.


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Contaminated packaging

: Empty contaminated packagings thoroughly. They can be recycled after thorough and proper cleaning. Packagings that cannot be cleaned are to be disposed of in the same manner as the product.

European Waste Catalogue Number

: No waste code according to the European Waste Catalogue can be assigned for this product, as the intended use dictates the assignment. The waste code is established in consultation with the regional waste disposer.

European Waste Catalogue Number

: Waste codes should be assigned by the user based on the application for which the product was used.

SECTION 14: Transport information

14.1. UN number

2801

14.2. UN proper shipping name

ADR : DYE, LIQUID, CORROSIVE, N.O.S. (Acetic acid, C.I. BASIC VIOLET 4) RID : DYE, LIQUID, CORROSIVE, N.O.S. (Acetic acid, C.I. BASIC VIOLET 4) IMDG : DYE, LIQUID, CORROSIVE, N.O.S. (Acetic acid, C.I. BASIC VIOLET 4)

14.3. Transport hazard class(es)

ADR-Class (Labels; Classification Code; Hazard identification No; Tunnel restriction code)

: 8

8; C9; 80; (E)

RID-Class (Labels; Classification Code; Hazard identification No)

: 8

8; C9; 80

IMDG-Class (Labels; EmS)

: 8

8; F-A, S-B

14.4. Packaging group

ADR : III RID : III IMDG : III

14.5. Environmental hazards

Environmentally hazardous according to ADR : yes Environmentally hazardous according to RID : yes Marine Pollutant according to IMDG-Code : yes


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14.6. Special precautions for user

Not applicable.

14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code

IMDG : Not applicable.

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture


Other regulations : Occupational restrictions: Take note of Dir 92/85/EEC on the

safety and health of pregnant workers at work and of Dir 94/33/EC on the protection of young people at work.

German legislation on water endangering substances VwVwS

: WGK 3: highly water endangering; Self-classification according VwVwS of 17 May 1999, Annex 4

15.2. Chemical safety assessment

There is no data available for this product.

SECTION 16: Other information

Full text of R-phrases referred to under sections 2 and 3.

R10 Flammable. R22 Harmful if swallowed. R34 Causes burns. R35 Causes severe burns. R37 Irritating to respiratory system. R50 Very toxic to aquatic organisms.

Full text of H-Statements referred to under sections 2 and 3.

H226 Flammable liquid and vapour. H290 May be corrosive to metals. H302 Harmful if swallowed. H314 Causes severe skin burns and eye damage. H335 May cause respiratory irritation. H400 Very toxic to aquatic life.


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Further information

Training advice : Provide adequate information, instruction and training for operators.

Key literature references and sources for data

: Supplier information and data from the "Database of registered substances" of the European Chemicals Agency (ECHA) were used to create this safety data sheet.

Other information : The information provided in this Safety Data Sheet is correct to

our knowledge at the date of its revision. The information given only describes the products with regard to safety arrangements and is not to be considered as a warranty or quality specification and does not constitute a legal relationship. The information contained in this Safety Data Sheet relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text

|| Indicates updated section.

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