Metal chalcogenide nanoclusters with ‘tailored’ surfaces via ‘designer’ silylated chalcogen...
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Transcript of Metal chalcogenide nanoclusters with ‘tailored’ surfaces via ‘designer’ silylated chalcogen...
![Page 1: Metal chalcogenide nanoclusters with ‘tailored’ surfaces via ‘designer’ silylated chalcogen reagents by Daniel G. MacDonald, and John F. Corrigan Philosophical.](https://reader035.fdocuments.net/reader035/viewer/2022081603/56649f355503460f94c535ca/html5/thumbnails/1.jpg)
Metal chalcogenide nanoclusters with ‘tailored’ surfaces via ‘designer’ silylated chalcogen reagents
by Daniel G. MacDonald, and John F. Corrigan
Philosophical Transactions AVolume 368(1915):1455-1472
March 28, 2010
©2010 by The Royal Society
![Page 2: Metal chalcogenide nanoclusters with ‘tailored’ surfaces via ‘designer’ silylated chalcogen reagents by Daniel G. MacDonald, and John F. Corrigan Philosophical.](https://reader035.fdocuments.net/reader035/viewer/2022081603/56649f355503460f94c535ca/html5/thumbnails/2.jpg)
Common coordination modes of chalcogenide (E2−) ligands.
Daniel G. MacDonald, and John F. Corrigan Phil. Trans. R. Soc. A 2010;368:1455-1472
©2010 by The Royal Society
![Page 3: Metal chalcogenide nanoclusters with ‘tailored’ surfaces via ‘designer’ silylated chalcogen reagents by Daniel G. MacDonald, and John F. Corrigan Philosophical.](https://reader035.fdocuments.net/reader035/viewer/2022081603/56649f355503460f94c535ca/html5/thumbnails/3.jpg)
Molecular structure of [Cd10Te4(SePh)12(PPr2Ph)4]: black, Cd; light grey, Te; medium grey, Se; small grey spheres, C, P.
Daniel G. MacDonald, and John F. Corrigan Phil. Trans. R. Soc. A 2010;368:1455-1472
©2010 by The Royal Society
![Page 4: Metal chalcogenide nanoclusters with ‘tailored’ surfaces via ‘designer’ silylated chalcogen reagents by Daniel G. MacDonald, and John F. Corrigan Philosophical.](https://reader035.fdocuments.net/reader035/viewer/2022081603/56649f355503460f94c535ca/html5/thumbnails/4.jpg)
Molecular structure of [Cu72Se14(SPh)36(OAc)8(PPh3)6]: black, Cu; light grey, Se; medium grey, S; small grey spheres, C, O and P.
Daniel G. MacDonald, and John F. Corrigan Phil. Trans. R. Soc. A 2010;368:1455-1472
©2010 by The Royal Society
![Page 5: Metal chalcogenide nanoclusters with ‘tailored’ surfaces via ‘designer’ silylated chalcogen reagents by Daniel G. MacDonald, and John F. Corrigan Philosophical.](https://reader035.fdocuments.net/reader035/viewer/2022081603/56649f355503460f94c535ca/html5/thumbnails/5.jpg)
Molecular structure of [Cu22Se6(S-p-C6H4NO2)10(PPh3)8]: black, Cu; light grey, Se; medium grey, S; small grey spheres, C, O, P. NO2 on phenyl rings emphasized for clarity.
Daniel G. MacDonald, and John F. Corrigan Phil. Trans. R. Soc. A 2010;368:1455-1472
©2010 by The Royal Society
![Page 6: Metal chalcogenide nanoclusters with ‘tailored’ surfaces via ‘designer’ silylated chalcogen reagents by Daniel G. MacDonald, and John F. Corrigan Philosophical.](https://reader035.fdocuments.net/reader035/viewer/2022081603/56649f355503460f94c535ca/html5/thumbnails/6.jpg)
Molecular structure of [Ag76Se13(S-p-C6H4NMe2)50(PPh3)6.5]: black, Cu; light grey, Se; medium grey, S; small grey spheres, C, O, P. NMe2 on phenyl rings emphasized for clarity.
Daniel G. MacDonald, and John F. Corrigan Phil. Trans. R. Soc. A 2010;368:1455-1472
©2010 by The Royal Society
![Page 7: Metal chalcogenide nanoclusters with ‘tailored’ surfaces via ‘designer’ silylated chalcogen reagents by Daniel G. MacDonald, and John F. Corrigan Philosophical.](https://reader035.fdocuments.net/reader035/viewer/2022081603/56649f355503460f94c535ca/html5/thumbnails/7.jpg)
Molecular structure of [nBuSn(O)OC(O)(C5H4)Fe(C5H5)]6: black, Sn; light grey, O; medium grey, Fe; small grey spheres, C.
Daniel G. MacDonald, and John F. Corrigan Phil. Trans. R. Soc. A 2010;368:1455-1472
©2010 by The Royal Society
![Page 8: Metal chalcogenide nanoclusters with ‘tailored’ surfaces via ‘designer’ silylated chalcogen reagents by Daniel G. MacDonald, and John F. Corrigan Philosophical.](https://reader035.fdocuments.net/reader035/viewer/2022081603/56649f355503460f94c535ca/html5/thumbnails/8.jpg)
Molecular structure of [Sn8O4(Fe(C5H5(O)CO)2)6]: black, Sn; light grey, O; medium grey, Fe; small grey spheres, C.
Daniel G. MacDonald, and John F. Corrigan Phil. Trans. R. Soc. A 2010;368:1455-1472
©2010 by The Royal Society
![Page 9: Metal chalcogenide nanoclusters with ‘tailored’ surfaces via ‘designer’ silylated chalcogen reagents by Daniel G. MacDonald, and John F. Corrigan Philosophical.](https://reader035.fdocuments.net/reader035/viewer/2022081603/56649f355503460f94c535ca/html5/thumbnails/9.jpg)
Molecular structures of (a) [Cu4(μ2-FcSe2)2(PnPr3)4], (b) [Cu8(μ2-FcSe2)4(PPh2Et)4] and (c) [Cu4(μ2-Se{O}CFc)4(PPh3)4]: black, Cu; light grey, Se; medium grey, Fe; small grey spheres C,
P.
Daniel G. MacDonald, and John F. Corrigan Phil. Trans. R. Soc. A 2010;368:1455-1472
©2010 by The Royal Society
![Page 10: Metal chalcogenide nanoclusters with ‘tailored’ surfaces via ‘designer’ silylated chalcogen reagents by Daniel G. MacDonald, and John F. Corrigan Philosophical.](https://reader035.fdocuments.net/reader035/viewer/2022081603/56649f355503460f94c535ca/html5/thumbnails/10.jpg)
Molecular structure of [Ag4(FcSe2)3]2−: black, Ag; light grey, Se; medium grey, Fe; small grey spheres C.
Daniel G. MacDonald, and John F. Corrigan Phil. Trans. R. Soc. A 2010;368:1455-1472
©2010 by The Royal Society
![Page 11: Metal chalcogenide nanoclusters with ‘tailored’ surfaces via ‘designer’ silylated chalcogen reagents by Daniel G. MacDonald, and John F. Corrigan Philosophical.](https://reader035.fdocuments.net/reader035/viewer/2022081603/56649f355503460f94c535ca/html5/thumbnails/11.jpg)
Molecular structure of (a) [Ag8(Se2Fc)4(PnPr3)4] and (b) [Ag16(Se2Fc)8(PPh2Et)6]: black, Ag; light grey, Se; medium grey, Fe; small grey spheres C, P.
Daniel G. MacDonald, and John F. Corrigan Phil. Trans. R. Soc. A 2010;368:1455-1472
©2010 by The Royal Society
![Page 12: Metal chalcogenide nanoclusters with ‘tailored’ surfaces via ‘designer’ silylated chalcogen reagents by Daniel G. MacDonald, and John F. Corrigan Philosophical.](https://reader035.fdocuments.net/reader035/viewer/2022081603/56649f355503460f94c535ca/html5/thumbnails/12.jpg)
Molecular structure of [Cu20Se6(Se2Fc)4(PPr3)10]: black, Cu; light grey, Se; medium grey, Fe; small grey spheres C, P.
Daniel G. MacDonald, and John F. Corrigan Phil. Trans. R. Soc. A 2010;368:1455-1472
©2010 by The Royal Society
![Page 13: Metal chalcogenide nanoclusters with ‘tailored’ surfaces via ‘designer’ silylated chalcogen reagents by Daniel G. MacDonald, and John F. Corrigan Philosophical.](https://reader035.fdocuments.net/reader035/viewer/2022081603/56649f355503460f94c535ca/html5/thumbnails/13.jpg)
Molecular structure of [Cu36Se12(Se2Fc)6(PnPr3)10(Ph2P(CH2)3SH)2]: black, Cu; light grey, Se; medium grey, Fe; small grey spheres C, P. S atoms emphasized for clarity.
Daniel G. MacDonald, and John F. Corrigan Phil. Trans. R. Soc. A 2010;368:1455-1472
©2010 by The Royal Society
![Page 14: Metal chalcogenide nanoclusters with ‘tailored’ surfaces via ‘designer’ silylated chalcogen reagents by Daniel G. MacDonald, and John F. Corrigan Philosophical.](https://reader035.fdocuments.net/reader035/viewer/2022081603/56649f355503460f94c535ca/html5/thumbnails/14.jpg)
Molecular structure of [Cu40Se12(Se2Fc)8(PPh3)9]: black, Cu; light grey, Se; medium grey, Fe; small grey spheres C, P.
Daniel G. MacDonald, and John F. Corrigan Phil. Trans. R. Soc. A 2010;368:1455-1472
©2010 by The Royal Society