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    Chapter 3: Mechanical Properties of Materials

    Why mechanical properties?Why mechanical properties?Why mechanical properties?Why mechanical properties?

    Need to design materials that will withstand

    applied load and in-service uses for

    Bridges for autos and people MEMS devices

    1

    Space elevator?

    skyscrapers

    Space exploration

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    Chapter 7: Mechanical Properties

    ISSUES TO ADDRESS...

    Stress and strain: Normalized force and displacements.

    Elastic behavior: When loads are small.

    Engineering: e= F

    i/A

    0e= l / l

    0

    True: T= F

    i/A

    iT= ln(l

    f/ l

    0)

    '

    Chapter 3: Mechanical Properties of Materials

    2

    Plastic behavior: dislocations andpermanent deformation

    Toughness, ductility, resilience, toughness, and hardness:

    Define and how do we measure?

    Mechanical behavior of the various classes of materials.

    Yield Strength: YS

    [MPa] (permanent deformation)

    UlitmateTensile Strength: TS

    [MPa] (fracture)

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    Tensile specimen Tensile test machine

    Stress & strain Testing

    Often 12.8 mm x 60 mm

    specimenextensometerAdapted from Fig. 7.2,

    Callister & Rethwisch 3e.

    4

    Other types:-compression: brittle materials (e.g., concrete)

    -torsion: cylindrical tubes, shafts.

    gauge

    length

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    Tensile stress, s: Shear stress, t:

    Area, A

    Ft

    Area, A

    Ft

    Fs

    F

    Engineering Stress

    5

    Ft =

    FtA

    ooriginal areabefore loading

    FtF

    Fs

    =Fs

    Ao

    Stress has units: N/m2 (or lb/in2 )

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    Tensile strain: Lateral (width) strain:

    /2

    /2

    Lowo =

    Lo L =L

    wo

    Engineering Strain

    6

    Shear strain:/2

    /2

    /2 -

    /2

    = tan Strain is always

    dimensionless.

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    Simple tension: cable

    =F

    Ao = cross sectionalArea (when unloaded)

    FF

    Common States of Stress

    7

    o Simple shear: drive shaft

    o =

    Fs

    A

    Note: = M/AcR here.

    Ski lift (photo courtesy P.M. Anderson)

    M

    M Ao

    2R

    Fs

    Ac

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    Simple compression:

    Ao

    Common States of Stress

    8

    Canyon Bridge, Los Alamos, NM

    Balanced Rock, ArchesNational Park o =

    F

    A

    Note: compressive

    structural member ( < 0).

    (photo courtesy P.M. Anderson)

    (photo courtesy P.M. Anderson)

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    Bi-axial tension: Hydrostatic compression:

    Common States of Stress

    9

    Fish under waterPressurized tank

    z > 0

    > 0

    < 0h

    (photo courtesy

    P.M. Anderson)

    (photo courtesy

    P.M. Anderson)

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    Pure Tension Pure Compression

    e=Fnormal

    Ao

    e=

    l lo

    lo

    stress

    strain

    e=EElastic

    response

    10

    Pure Shear

    Pure Torsional Shear

    e=Fshear

    Ao

    = tan

    stress

    strain

    e=GElastic

    response

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    Elastic Deformation

    2. Small load

    bonds

    stretch

    1. Initial 3. Unload

    return to

    initial

    11

    Elastic means reversible!

    F

    Linear-

    elastic

    Non-Linear-

    elastic

    F

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    Plastic Deformation of Metals

    1. Initial 2. Small load 3. Unload

    planes

    still

    sheared

    bonds

    stretch

    & planesshear

    12

    Plastic means permanent!

    F

    elastic + plastic plastic

    elastic

    F

    linear

    elasticlinear

    elastic

    plastic

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    Modulus of Elasticity, E:(also known as Young's modulus)

    Hooke's Law: = E

    Units: E [GPa] or [psi]

    Linear Elasticity

    FAxial strain

    13

    Linear-elastic

    E

    FWidth strain

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    Tangent Modulus is experienced in service.

    Secant Modulus is effective modulus at 2% strain.- grey cast iron is also an example

    Modulus of polymer changes with time and strain-rate.- must report strain-rate d/dt for polymers.

    - must report fracture strain fbefore fracture.

    Polymers: Tangent and Secant Modulus

    14

    %strain

    Stress (MPa)initial E

    secant E

    1 2 3 4 5 ..

    tangent E

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    Hooke's Law: = E (linear elastic behavior)

    Copper sample (305 mm long) is pulled in tension with stress of276

    MPa. If deformation is elastic, what is elongation?

    Example: Hookes Law

    For Cu (polycrystalline), E = 110 GPa. FAxial strain

    15

    =E=E ll

    0

    l =

    l 0E

    l =(276MPa)(305mm)

    110x10

    3

    MPa

    = 0.77mm

    Hookes law involves axial (parallel to applied tensile load) elastic deformation.

    FWidth strain

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    Mechanical Properties

    Recall: Bonding Energy vs distance plots

    16

    Adapted from Fig. 2.8

    Callister & Rethwisch 3e.

    tension

    compression

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    Elastic Behavior

    Elasticity of Ceramics

    Al O

    And Effects of PorosityE= E0(1 - 1.9P + 0.9 P

    2)

    17

    Neither Glass or Alumina experience plastic deformation before fracture!

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    Comparison of Elastic Moduli

    18

    Silicon (single xtal) 120-190 (depends on crystallographic direction)

    Glass (pyrex) 70

    SiC (fused or sintered) 207-483

    Graphite (molded) ~12

    High modulus C-fiber 400Carbon Nanotubes ~1000

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    Magnesium,

    Aluminum

    Platinum

    Silver, Gold

    Tantalum

    Zinc, Ti

    Steel, Ni

    Molybdenum

    Si crystal

    Glass-soda

    Si nitrideAl oxide

    Glass fibers only

    Carbon fibers only

    Aramid fibers only

    6080

    100

    200

    600800

    10001200

    400

    Cu alloys

    Tungsten

    Si carbide

    Diamond

    *

    AFRE(|| fibers)*

    CFRE(|| fibers)*

    Metals

    Alloys

    GraphiteCeramics

    Semicond

    PolymersComposites

    /fibers

    E(GPa)

    Eceramics

    > Emetals>> Epolymers

    Youngs Modulus, E

    19

    0.2

    8

    0.6

    1

    Graphite

    Concrete

    PC

    Wood( grain)

    AFRE( fibers)*

    CFRE*

    GFRE*

    Epoxy only

    0.4

    0.8

    2

    4

    6

    10

    20

    40 n

    PTFE

    HDPE

    LDPE

    PP

    Polyester

    PSPET

    CFRE( fibers)*

    GFRE( fibers)*

    109 Pa

    Based on data in Table B2, Callister 6e.

    Composite data based on

    reinforced epoxy with 60 vol%

    of aligned carbon (CFRE),aramid (AFRE), or glass (GFRE) fibers.

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    Poisson's ratio, :

    Poisson's ratio,

    =

    width strain

    axial strain =

    w /w

    l /l =

    L

    Units: dimensionless

    F

    L

    20

    Why does have minus sign?

    metals: ~ 0.33

    ceramics: ~ 0.25polymers: ~ 0.40

    F

    Axial strain

    Width strain

    -

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    Limits of the Poisson Ratio

    = w/w

    l / l= 1

    Poisson Ratio has a range 1 1/2

    Look at extremes

    No change in aspect ratio: w/w = l/l

    21

    Volume (V = AL) remains constant: V =0.

    Hence, V = (L A+A L) = 0. So,

    In terms of width, A = w2, then A/A = 2 w w/w2 = 2w/w = L/L.

    Hence,

    A/A = L/L

    = w/w

    l / l=

    (1

    2l / l )

    l / l=

    1

    2

    Incompressible solid.

    Water (almost).

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    Tensile stress is applied along cylindrical brass rod (10 mm diameter).

    Poisson ratio is = 0.34 and E = 97 GPa.

    Determine load needed for 2.5x103 mm change in diameter if the

    deformation is entirely elastic?

    F

    Example: Poisson Effect

    Width strain: (note reduction in diameter)

    23

    simpletensiontest

    x= = . x mm mm = . x

    Axial strain: Given Poisson ratio

    z= x/ = (2.5x104)/0.34 = +7.35x104

    Axial Stress: z = Ez = (97x103 MPa)(7.35x104) = 71.3 MPa.

    Required Load: F = zA0 = (71.3 MPa) (5 mm)2 = 5600 N.

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    Elastic Shear

    modulus, G:

    1

    G

    = G

    M

    M

    simple

    Torsion test

    Other Elastic Properties

    24

    modulus, K:

    P= -KVVo

    V

    1-K

    Vo

    P P

    Pressure test:

    Init. vol = Vo.

    Vol chg. = V

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    Simple tension test:

    engineering stress,

    Elastic+Plastic

    at larger stress

    Elastic

    (at lower temperatures, i.e. T< Tmelt/3)

    Plastic (Permanent) Deformation

    25

    engineering strain, p

    plastic strain

    initially

    Adapted from Fig. 7.10 (a),

    Callister & Rethwisch 3e.

    permanent (plastic)

    after load is removed

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    Stress where noticeable plastic deformation occurs.

    When p = 0.002

    Yield Stress, Y

    For metals agreed upon 0.2%

    P is theproportional limitwhere deviation

    from linear behavior occurs.

    -

    tensile stress,

    Y

    26

    Note: for 2 in. sample

    = 0.002 = z/z

    z = 0.004 in

    Start at 0.2% strain (for most metals). Draw line parallel to elastic curve (slope of E).

    Y is value of stress where dotted line crosses

    stress-strain curve (dashed line).

    Eng. strain, p = 0.002

    Elastic

    recovery

    P

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    Yield-point phenomenon occurs when elastic plastic

    transition is abrupt.

    Yield Points and YS

    No offset method required.

    In steels, this effect is seen when

    dislocations start to move and unbind

    27

    For steels, take the avg. stress

    of lower yield point since less

    sensitive to testing methods.

    .

    Lower yield point taken as Y.

    Jagged curve at lower yield point occurs

    when solute binds dislocation and

    dislocation unbinding again, until work-hardening begins to occur.

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    3 different types of behavior

    Stress-Strain in Polymers

    Brittle

    plastic

    For plastic polymers: YS at maximum stress just

    after elastic region.

    TS is stress at fracture!

    28

    Highly elastic

    Highly elastic polymers:

    Elongate to as much as 1000% (e.g. silly putty).

    7 MPa < E < 4 GPa 3 order of magnitude!

    TS(max) ~ 100 MPa some metal alloys up to 4 GPa

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    Graphite/

    Ceramics/Semicond

    Metals/

    Alloys

    Composites/

    fibersPolymers

    ,y(MP

    a)

    ure,

    occursbefore

    yield.

    300

    400

    500600700

    1000

    2000

    Al (6061)ag

    hr

    Steel (1020)cdSteel (4140)a

    Steel (4140)qt

    Ti (5Al-2.5Sn)aW (pure)

    Mo (pure)Cu (71500)cw

    ure,

    trixcomposite

    s,since

    ccursbeforey

    ield.

    y(ceramics)

    >>y(metals)

    >> y(polymers)

    Compare Yield Stress, YS

    29

    Yield

    strength

    PVC

    Hardtome

    as

    sinceinte

    nsion,fractureusuall

    Nylon 6,6

    LDPE

    70

    20

    40

    6050

    100

    10

    30

    Tin (pure)

    Al (6061)a

    Cu (71500)hrTa (pure)

    Ti (pure)a

    Hardtom

    ea

    inceramicmatrixandepoxym

    intension,fractureusua

    lly

    HDPEPP

    humid

    dry

    PC

    PET

    oom va ues

    Based on data in Table B4,

    Callister 6e.

    a = annealed

    hr = hot rolled

    ag = aged

    cd = cold drawncw = cold worked

    qt = quenched & tempered

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    Maximum possible engineering stress in tension.

    (Ultimate) Tensile Strength, TS

    y F= fracture orultimate

    strength

    eering

    TS

    ress

    30

    Metals: occurs when necking starts.

    Ceramics: occurs when crack propagation starts.

    Polymers: occurs when polymer backbones are

    aligned and about to break.

    strain

    Typical response of a metalNeck acts

    as stress

    concentratorengi

    s

    engineering strain

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    Metals: Tensile Strength, vTS

    For Metals: max. stress in tension when necking starts, which

    is the metals work-hardening tendencies vis--vis those that

    initiate instabilities.

    dF= 0 Maximum eng. Stress (at necking)

    dF= 0 = dA +Ad

    dT =

    dAi

    31

    decreased force due to

    decrease in gage diameter

    Increased force due to

    increase in applied stress

    At the point where these two competing changes in forceequal, there is permanent neck.

    Determined by slope of true stress - true strain curve

    T iFractionalIncrease in

    Flow stress

    fractionaldecrease

    in load-

    bearing

    area

    dT

    T

    = dA

    i

    Ai

    =dl

    i

    li

    dT

    d

    T

    dT

    =T

    IfT=K(

    T)n, then n=

    T

    n = strain-hardening coefficient

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    Room T values

    TS(ceram)

    ~TS(met)

    ~ TS(comp)

    >> TS(poly)

    Compare Tensile Strength, TSGraphite/

    Ceramics/Semicond

    Metals/

    Alloys

    Composites/

    fibersPolymers

    TS

    (M

    Pa)

    200

    300

    1000

    Al (6061) ag

    Cu (71500) hr

    Ta (pure)Ti (pure) a

    Steel (1020)

    Steel (4140) a

    Steel (4140) qt

    Ti (5Al-2.5Sn) a

    W (pure)

    Cu (71500) cw

    2000

    3000

    5000

    Al oxide

    Diamond

    Si nitride

    GFRE (|| fiber)

    C FRE (|| fiber)

    A FRE (|| fiber)

    E-glass fib

    C fibersAramid fib

    32

    Based on data in Table B4,

    Callister & Rethwisch 3e.

    Si crystal

    Tensile

    strength

    ,

    PVC

    Nylon 6,6

    10

    100Al (6061) a

    LDPE

    PP

    PC PET

    20

    3040

    Graphite

    Concrete

    Glass-soda

    HDPE

    wood ( fiber)

    wood(|| fiber)

    1

    GFRE ( fiber)C FRE ( fiber)A FRE( fiber)

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    Example for Metals: Determine E, YS, and TS

    Stress-Strain for Brass Youngs Modulus, E (bond stretch)

    GPaMPa

    E 8.9300016.0

    )0150(

    12

    12 =

    =

    =

    0ffset Yield-Stress, YS (plastic deformation)

    YS= 250 MPa

    33

    Max. Load from Tensile Strength TS

    Fmax =TSA0 =TSd0

    2

    2

    = 450MPa12.8x103m

    2

    2

    = 57,900N

    Change in length atPoint A, l = l0

    Gage is 250 mm (10 in) in length and 12.8 mm

    (0.505 in) in diameter.

    Subject to tensile stress of 345 MPa (50 ksi)

    l = l0 = (0.06)250 mm = 15 mm

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    Most metals are ductile at RT and above, but can become brittle at low T

    bcc Fe

    Temperature matters (see Failure)

    34

    cup-and-cone fracture in Al brittle fracture in mild steel

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    Energy to break a unit volume of material,

    or absorb energy to fracture.

    Approximate as area under the stress-strain curve.

    Toughness

    E ngineering

    tensile

    small toughness (ceramics)

    large toughness (metals)

    36

    very small toughness

    (unreinforced polymers)

    Engineering tensile strain,

    ,

    UT= do

    f

    Brittle fracture: elastic energy

    Ductile fracture: elastic + plastic energy

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    Stress-Strain in Polymers

    brittle polymer

    plastic

    elastomer

    37

    elastic moduli

    less than for metals Adapted from Fig. 7.22,Callister & Rethwisch 3e.

    Fracture strengths of polymers ~ 10% of those for metals.

    Deformation strains for polymers > 1000%.

    for most metals, deformation strains < 10%.

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    Decreasing T...

    -- increases E

    -- increases TS

    -- decreases %EL

    Increasing

    Influence ofTand Strain Rate on Thermoplastics

    40

    60

    80 4C

    20C

    (MPa)

    Plots for

    semicrystalline

    PMMA (Plexiglas)

    38

    strain rate...-- same effectsas decreasing T.

    Adapted from Fig. 7.24, Callister & Rethwisch 3e. (Fig. 7.24 is from T.S. Carswell

    and J.K. Nason, 'Effect of Environmental Conditions on the Mechanical Properties

    of Organic Plastics", Symposium on Plastics, American Society for Testing and

    Materials, Philadelphia, PA, 1944.)

    20

    00 0.1 0.2 0.3

    60Cto 1.3

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    Necking appears along entire

    sample after YS!

    Stress-Strain in Polymers

    Mechanism unlike metals, necking due

    to alignment of crystallites.

    Load vertical

    39

    Align crystalline sections by

    straightening chains in the

    amorphous sections

    After YS, necking

    proceeds by

    unraveling; hence,

    neck propagates,

    unlike in metals!See Chpt 8

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    Time-dependent deformation in Polymers

    Stress relaxation test:

    -strain in tension to and hold.

    - observe decrease instress with time.

    tensile test

    Large decrease in Erfor T> Tg.

    (amorphous

    polystyrene)

    Fig. 7.28, Callister &

    Rethwisch 3e.

    (Fig. 7.28 from A.V.Tobolsky, Properties

    and Structures of

    Polymers, Wiley and

    Sons, Inc., 1960.)

    103

    101

    10-1

    105

    rigid solid

    (small relax)

    transitionregion

    Er(10 s)

    in MPa

    viscous liquid

    40

    Representative Tg values (in C):

    PE (low density)

    PE (high density)PVC

    PS

    PC

    -110

    - 90+ 87

    +100

    +150Selected values from Table 11.3, Callister & Rethwisch 3e.

    o

    r

    ttE

    =

    )()(

    Relaxation modulus:

    time

    straino

    (t)

    10-

    60 100 140 180 T(C)Tg

    (large relax)

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    Wh T S i ?

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    Why use True Strain?

    Up to YS, there is volume change due to Poisson Effect!

    In a metal, from YS and TS, there is plastic deformation, as dislocations move

    atoms by slip, but V=0 (volume is constant).

    A0l 0 = Ail i

    t= ln

    li

    l0

    lnli l

    0+ l

    0

    l0

    = ln(1+)

    42

    Sum of incremental strain does

    NOT equal total strain!

    Test length Eng. Eng.

    0-1-2-3 0-3

    0 2.00

    1 2.20 0.1

    2 2.42 0.1

    3 2.662 0.1 0.662/2.0

    TOTAL 0.3 0.331

    t= ln

    2.2

    2.0+ ln

    2.42

    2.20+ ln

    2.662

    2.42= ln

    2.662

    2.00

    Eng.

    Strain

    True

    StrainSum of incremental strain does

    equal total strain.

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    Example:

    A cylindrical specimen of steel having an original diameter of 12.8

    mm (0.505 in.) is tensile tested to fracture and found to have an

    engineering fracture strength of 460 MPa (67,000 psi). If its cross-

    sectional diameter at fracture is 10.7 mm (0.422 in.), determine:

    (a) The ductility in terms of percent reduction in area(b) The true stress at fracture

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    Hardness

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    Resistance to permanently indenting the surface.

    Large hardness means:--resistance to plastic deformation or cracking in compression.

    --better wear properties.

    e.g.,apply known force(1 to 1000g)

    measure sizeof indent after

    Hardness

    45

    mm sp ere

    removing load

    dDSmaller indentsmean largerhardness.

    increasing hardness

    mostplastics

    brassesAl alloys

    easy to machinesteels file hard

    cuttingtools

    nitridedsteels diamond

    Adapted from Fig. 7.18.

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    Hardness: Measurement

    Rockwell

    No major sample damage

    Each scale runs to 130 (useful in range 20-100). Minor load 10 kg

    Major load 60 (A), 100 (B) & 150 (C) kg

    46

    A = diamond, B = 1/16 in. ball, C = diamond

    HB = Brinell Hardness

    TS (psia) = 500 x HB

    TS (MPa) = 3.45 x HB

    H d M t

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    Hardness: Measurement

    47

    F ti

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    Under fluctuating / cyclic stresses, failure can occur atconsiderably lower loads than tensile or yield strengths of

    material under a static load.Causes 90% of all failures of metallic structures (bridges,aircraft, machine components, etc.)

    Fatigue

    Failure under fluctuating stress

    48

    Fatigue failure is brittle-like (relatively little plastic deformation)

    - even in normally ductile materials. Thus sudden and

    catastrophic!

    Fatigue failure has three stages:

    crack initiation in areas of stress concentration

    (near stress raisers)

    incremental crack propagation

    catastrophic failure

    F i C li S

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    Fatigue: Cyclic StressesCyclic stresses characterized by maximum, minimum and mean stress, the range of stress, the

    stress amplitude, and the stress ratio

    Mean stress m = (max + min) / 2

    Range of stress r = (max - min)

    Stress amplitude a = r/2 = (max - min) / 2

    Stress ratio R = min / max

    49

    Convention: tensile stresses positive

    compressive stresses negative

    Creep

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    pTime-dependent and permanent

    deformation of materials subjected to a constant load at hightemperature (> 0.4 Tm).

    Examples: turbine blades, steam generators.

    Creep testing:

    50 Creep testing

    Furnace

    Stages of creep

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    S ages o c eep

    51

    1. Instantaneous deformation, mainly elastic.

    2. Primary/transient creep. Slope of strain vs. time decreases with time:

    work-hardening

    3. Secondary/steady-state creep. Rate of straining constant: work-hardening

    and recovery.

    4. Tertiary. Rapidly accelerating strain rate up to failure: formation of internal

    cracks, voids, grain boundary separation, necking, etc.

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    Mechanisms of Creep

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    Mechanisms of Creep

    Different mechanisms act in different materials and underdifferent loading and temperature conditions:

    Stress-assisted vacancy diffusion

    Grain boundary diffusion

    Grain boundary sliding

    Dislocation motion

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    Different mechanisms different n, Qc.

    Grain boundary diffusion Dislocation glide and climb

    Typical Forming Operations

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    Typical Forming Operations

    rollingforging

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    Wire drawing extrusion Deep drawing

    die

    Stretch formingbending

    shearing

    Summary

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    Stress and strain: These are size-independent measures of load and

    displacement, respectively.

    Elastic behavior: This reversible behavior often shows a linear

    relation between stress and strain.

    To minimize deformation, select a material with a large elastic

    modulus (E or G).

    Summary

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    Plastic behavior: This permanent deformation

    behavior occurs when the tensile (or compressive)

    uniaxial stress reaches sy.

    Toughness: The energy needed to break a unit

    volume of material. Ductility: The plastic strain at failure.