MECH470: Transformation Induced Plasticity (TRIP) in Austenitic Steels

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ABSTRACT: Transformation induced plasticity (TRIP), in its classical definition, can be explained as the ‘significantly increased plasticity during a phase change for an externally applied load for which the corresponding equivalent stress is small compared to the normal yield stress of the material, plastic deformation occurs’, [1] producing a work hardening effect leading to superior formability (ie. for stamping). In the case of steel, the amount of retained austenite at room temperature is what will transform under applied strain to martensite. Therefore, the amount of retained austenite in the steel will be determinant to the materials workability. The TRIP effect depends on the alloy composition and heart treatment procedures, which are outlined in this report. Further discussion is also done regarding the mechanical deformation properties such as: tensile, instantaneous work hardening, strain path curves and anisotropy parameters.

Transcript of MECH470: Transformation Induced Plasticity (TRIP) in Austenitic Steels

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    MECH 470: Research Project

    Topic: Transformation Induced Plasticity (TRIP)

    TO: DR. KEITH PILKEY

    FROM: ADAM BROOKS

    APRIL 29, 2014

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    Table of Contents

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    The most important underlying factor behind stabilizing the austenite is the addition of

    alloying elements to the steel. The simplest approach is through the addition of nickel

    (ex. 20wt%), which however is expensive from an industry market perspective. [9]

    Recent developments have been implemented towards 1.5wt% silicon and manganese.

    The manganese directly stabilizes the austenite by lowering the martensitic start

    temperature, which additionally lowers the starting temperature for the formation of

    cementite preventing pearlite from forming during cooling. Silicon plays a key roll by

    delaying the formation of carbides, during the bainite transformation (discussed section

    3). The chemical content of carbon however is the most important in stabilizing the

    austenite. Approximately 1wt% stabilizes the austenite the best, but from an industry

    standard the steel is usually limited to 0.2wt% (hypo-eutectoid range, similar to dual

    phase steels) for welding purposes. Additional elements such as Al, P, V, Nb, Cr, Mo can

    also be added into TRIP steels. Fig. 1illustrates this:

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    Strength of the steel formability is increased, thinner sheet can be used. Replacing conventional steel with advanced high-strength steel. Challenge is to design steel, which exhibits both high strength for weight

    reduction and good formability for fitting complex structural shapes.

    An example strain path of TRIP800 2mm thick steel (&UTS= 836 MPa &yl= 546 MPa)

    is presented below [2] Fig. 7,with reported R2plastic anisotropy parameters using

    standard Nakajima and Marciniak tests:

    Fig. 6:This graph shows that the equiaxed microstructure has higher !!values than the lamellar

    at small strains, as well as a higher maximum !! value. However, the lamellar microstructure

    demonstrates higher hardening rates at tensile strains above 0.05.

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    The TRIP 800 experiences relatively good drawability as R2~ 1, the TRIP 800

    will be less prone to thinning/necking compared to conventional HSLA. The value of R2

    does vary as a function of the angle between the tensile specimen and the processing

    rolling direction due to planar anisotropy.

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    The bainite hold is important in the stabilization of austenite at room temperature.

    The bainite nucleates at the boundaries of the austenite. Forming on pre-existing

    dislocations (from cold work), this produces fine lenticular sub units of super saturated

    ferrite, referred to as bainite. The carbon content of the ferrite is higher than equilibrium,

    and hence is partitioned to the surrounding austenite or forms carbides around the bainite

    sheaves [9]. Its growth must be accommodated plastically by the surrounding austenite,

    given that the specific volume of ferrite (BCC) is higher than that of austenite (FCC).

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    Fig. 7:The forming limit curve (FLC) for TRIP 800, showing for two different strain path tests,Marciniak and Nakajima with reported R2anisotropy parameters

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    So really the bainite rate controlling process can be thought of in two ways: i) the

    thermodynamic driving force for nucleation decreases as the carbon content of the

    remaining austenite increases. ii) The bainite must be plastically accommodated by the

    austenite, which is increasingly strain-hardened by the transformation.

    A good understanding comes from the work of Jacques et al. [6], where the length

    of the bainite hold time must be carefully chosen as holds which are too short in duration

    will not allow enough bainite to grow (hence not stabilizing the austenite), and the

    austenite will transform into undesirable martensite upon quenching to room temperature.

    On the contrary, if the bainite hold time is too long the high carbon austenite will

    decompose into carbides, again reducing the volume percent of retained austenite. (Fig.

    8) The silicon content of the TRIP steel is important because silicon is insoluble in

    cementite and the silicon content will then delay the formation of carbides during the

    bainite transformation, as there is a time delay for the silicon to diffuse away from the

    bainite grain boundaries before cementite can form [6].

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