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MAURO SERGIO MICHELONI

01/01/2017 Curriculum Vitae and Publications Prof. Mauro Sergio Micheloni

Curriculum Vitae and Publications of Mauro Sergio Micheloni

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Curriculum Vitae of Mauro Sergio MICHELONI

Biographical information

- Mauro Sergio MICHELONI was born in Prato (Italy) in 1949.

- After secondary school he attended at the University of Florence, graduating in chemistry in 1973, with the highest score, discussing a thesis on thermochromism of amine copper complexes.

- He then moved at the University of St. Andrews (Scotland) where he worked with Professor D.R. Williams until November 1976.

- Dr. Micheloni was appointed Research Assistant of Inorganic Chemistry at the University of Florence in 1977.

- He was appointed associate professor of Inorganic Chemistry at the University of Florence, Department of Chemistry, in 1980.

- In 1990 Dr. Micheloni was appointed full professor of Inorganic Chemistry, and move to the University of Urbino.

Others biographical and academicals information

- Prof. Micheloni He has been president of the Italian Group of ‘Termodinamica dei Complessi’ (1998-2001)

- He is the Director of the Archaeometric Centre of the University of Urbino (1995-2010)

- He has been member of the Governing Body of the University of Urbino; - He has been head of the Geology Board of the University of Urbino (1998-2000).

- He has been the head of the Technology for Art Conservation Board of the University of Urbino (2003-2010).

- He has been the Director of the Institute of Chemical Sciences of the University of Urbino (1999-2010).

- He has been prochancellor for Scientific Research of the University of Urbino (2009-2014)

- He is the Head of the Board of “Base Sciences and Application” Doctorate (2013-)

- He is member of the Italian and American Chemical Societies (1990- ).


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Teaching activity

Prof. Micheloni’s teaching activity is vast, span from General and

Inorganic Chemistry for student of Faculty of Sciences, Faculty of

Environmental Sciences and Faculty of Pharmacy to Chemistry

courses for students in Art Conservation.

He also has held specialized courses in corrosion chemistry and

metal coordination chemistry.

Research main interest

Prof. Micheloni’s research interests have focused on:

- Synthesis of new ligand molecules, including many macrocyclic

compounds and their metal complexes;

- Thermodynamic of protonation and metal complexes formation

equilibria;

- NMR contrast agents;

- PGM refining and recovery. PGM Plating solutions preparation.

He is authors of 155 international publications and has presented

many research lectures in Italy and abroad.

Industrial Linkages

Prof. Micheloni’s group has been involved in research industrial

project with Bracco Firm on new NMR macrocyclic contrast agents,

when he was in Florence University.

Now, in Urbino, is involved in industrial research and development

on Precious and PGM (Platinum Group Metals) recovery and

refining from spent automobile catalysts and other metal scrapes.


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Aqua Regia plants for Gold refining and related techniques.

Electrolytic Silver Refining plants and related techniques.

He also has a good experience in developing PGM plating

solution, especially for Rhodium and Palladium. TCA Spa (Arezzo

Italy) on Precious Metals. ARTLINEA (Arezzo Italy) on Precious

Metals. Goldlake Group Italy S.p.A on Gold extraction with

tiourea.

He is co-founder (2012-) of CLM Consulting Srl Italian Company

specialized in Precious Metals (including PGM) Recovery and

Refining: www.clmconsultingsrl.it

Addresses

- Current address:

Department of Pure and Applied Sciences , University of Urbino,

Via della Stazione 4, I-61029 Urbino (Italy)

- Home address.

Street: Via C.A. Dalla Chiesa 3; Town: Fermignano; Postal Code:

I-61033; County: Pesaro-Urbino (PU); Country: Italy

Laboratory Phone +39 722 304881; Fax: +39 722 350032

Mobile : +39 331 7203812

E-mail : [email protected]

Skype : mauromicheloniuniurb


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Main Publications

1) Fabbrizzi L., Micheloni M., Paoletti P. "Continuous and Discontinuous Thermochromism of Copper(II) and Nickel(II) Complexes with N,N'-diethylethylene-diamine", Inorg. Chem., 1974, 13, 3019-3021. 2) Fabbrizzi L., Micheloni M., Paoletti P. "Entropy-Controlled Formation of Metal Complexes with Hindered Ligands. The System Zinc(II)-1,3,5-cis-,cis-Triaminocyclohexane" Inorg. Chem., 1976, 15, 1451-1452. 3) Micheloni M., Sabatini A., Vacca A. "Nickel(II) Copper(II) and Zinc(II) "Complexes of 1,1,1-Tris(amino-methyl)propane. A Calculation Procedure of Stepwise Formation Constants and Their Standard Errors from the Values Obtained for the Cumulative Equilibria", Inorg. Chimica Acta, 1977, 25, 41-48. 4) Fabbrizzi L., Micheloni M., Paoletti P., Schwarzenbach G. "Protonation Processes of Unusual Exothermicity" J. Am. Chem. Soc., 1977, 99, 5574-5576. 5) Micheloni M., May P.M., Williams D.R. "Metal-Ligand Complexes Involved in Rheumatoid Arthritis IV. Formation Constant and Species Distribution Considerations for Copper(II) -Cystinate, -Oxidised Penicillaminate and Oxidised Glutathionate Interactions and Considerations of the Action of Penicillamine in Vivo", J. Inorg. Nucl. Chem., 1978, 40, 1209-1219. 6) Fabbrizzi L., Micheloni M., Paoletti P. "Thermochemical Consequences of Delocalization in Metal Biguanide Complexes", Inorg. Chem., 1978, 17, 494-495. 7) Micheloni M., Sabatini A., Paoletti P. "Solution Chemistry of Macrocycles. Part 1. Basicity Constants of 1,4,8,11-Tetra-azacyclotetradecane, 1,4,8,12-Tetraazacyclopentadecane, and 1,4,8,11-Tetra-methyl-1,4,8,11-tetraazacyclotetradecane", J. Chem. Soc., Perkin Trans. II, 1978, 828-830. 8) Micheloni M., Paoletti P., Vacca A. "Solution Chemistry of Macrocycles. Part 2. Enthalpic and Entropic Contributions to the Proton Basicity of Cyclic Tetraamine Ligands: 1,4,8,11-Tetraaza-cyclotetradecane 1,4,8,12-Tetraazacyclopentadecane, and 1,4,8,11-Tetramethyl-1,4,8,11-Tetramethyl-1,4,8,11-Tetraazacyclotetradecane", J. Chem. Soc., Perkin 2 Trans. 1978, 945-947. 9) Fabbrizzi L., Micheloni M., Paoletti P. "Enthalpy of Formation of Copper(II) Complexes with 14-Membered Tetraaza- Macrocycles", J. Chem. Soc. Chem. Commun. 1978, 833-834. 10) Fabbrizzi L., Micheloni M., Paoletti P. "Chelate-ring Sequence and Enthalpy of Formation of Copper(II) Complexes with Tetra-aza Macrocycles", J. Chem. Soc., Dalton Trans., 1979, 1581-1584. 11) Clay R.M., Micheloni M., Paoletti P., Steele W.V. "Enthalpies of Formation and Solution Of Macrocyclic and Noncyclic Tetraaza Ligands. Origins of the Enthalpy Term in the Macrocyclic Effect", J. Am. Chem. Soc., 1979, 101, 4119-4122. 12) Barbucci R., Ferruti P., Micheloni M., Delfini M., Segre A., Conti F. "Thermodynamic and 13C n.m.r. data on the Protonation of Polymeric Bases whose Repeating Units Behaves Independently Towards Protonation", Polymer, 1980, 21, 81-85. 13) Fabbrizzi L., Micheloni M., Paoletti P. "Encircling of Metal Ions by Tetra-aza Macrocycles. Enthalpies of Formation of High- and Low-spin Nickel(II) Complexes of 14-Membered Ligands", J. Chem. Soc., Dalton Trans., 1980, 134-136. 14) Fabbrizzi L., Micheloni M., Paoletti P. "A Microcalorimetric Determination of the Enthalpies of Formation in Solution of Nickel(II) Complexes with Tetraaza Macrocyclic Ligands of Varying Size", Inorg. Chem., 1980, 19, 535-538. 15) Fabbrizzi L., Micheloni M., Paoletti P., "Thermochemistry of Metal Complexes with the Rigid Ligand 1,3,5-cis-cis-Triamino-cyclohexane", J. Chem. Soc., Dalton Trans., 1980, 1055-1059. 16) Gallori E., Martini E., Micheloni M., Paoletti P. "Enthalpic and Entropic Contributions in the Reactions of Hydrogen, Copper(II), and Nickel(II) Ions with the Macrocycle 1,5,9,13-Tetraazacyclohexadecane", J. Chem. Soc., Dalton Trans., 1980, 1722-1725. 17) Micheloni M., Paoletti P. "The Macrocyclic Effect: Thermodynamic Parameters for the Formation of Zinc(II) Complexes with Macrocyclic Ligands of Varying Ring-Size", Inorg. Chimica Acta, 1980, 43, 109-112. 18) Barbucci R., Barone V., Micheloni M., Rusconi L. "Thermodynamics of Protonation of Tetramines with Different Degrees of N-Methylation", J. Phys. Chem., 1981, 85, 64-68.


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19) Graddon D.P., Micheloni M., Paoletti P. "Zinc Complexes of Four Tetra-aza Macrocycles: Enthalpies of Formation in Acetonitrile Solution", J. Chem. Soc., Dalton Trans., 1981, 336-341. 20) Fabbrizzi L., Micheloni M., Paoletti P., Poggi A., Lever A.B.P "High-spin Nickel(II) Complexes of Penta-aza Macrocycles: Characterization, Electronic Spectra, and Thermodynamic Properties", J. Chem. Soc., Dalton Trans, 1981, 1438-1441. 21) Micheloni M., Paoletti P., Poggi A., Fabbrizzi L. "Coordinating Tendencies of a 14-Membered Tetra-aza Macrocycle which forms a Seven-membered Chelate Ring", J. Chem. Soc., Dalton Trans., 1982, 61-65. 22) Micheloni M., Paoletti P., Burki S., Kaden T.A. "Metal Complexes with Macrocyclic Ligands. XVI. Spectrophotometric and Thermodynamic Studies of Solvents and Unidentate Ligands Interaction with the Pentacoordinate Co(II), Ni(II) and Cu(II) Complexes of 1,4,8,11-Tetramethyl-1,4,8,11-tetraazacyclotetradecane" Helvetica Chimica Acta, 1982, 65, 587-594. 23) Clay R.M., McCormac H., Micheloni M., Paoletti P. "w,w'-Dialkylated Tetraaza Linear Ligands as More Appropriate Reference Ligands for Tetraaza Macrocycles. A Comparison of 1,4,7,10-Tetraazacyclododecane with 3,6-Diaza-1,8-diaminooctane", Inorg. Chem., 1982, 21, 2494-2496. 24) Bartolini M., Bianchi A., Micheloni M., Paoletti P. "Solution Chemistry of Macrocycles. Part 3. Synthesis and Thermodynamics of Protonation of Some Tetraazamacrocycles", J. Chem. Soc. Perkin Trans. II, 1982, 1345-1348. 25) Bologni L., Micheloni M., Sabatini A., Vacca A. "Complex Formation Equilibria Between 1,1,1-Tris(N-methylamino-methyl)ethane and Nickel(II), Copper(II), Zinc(II) and Hydrogen Ions", Inorganica Chim. Acta, 1983, 70, 117-119. 26) Micheloni M., Paoletti P., Sabatini A. "First Potentiometric Determination of Stability Constants of Nickel(II) Complexes with Tetraazacycloalkanes", J. Chem. Soc. Dalton Trans., 1983, 1189-1191. 27) Ciampolini M., Micheloni M., Nardi N., Paoletti P., Dapporto P., Zanobini F. "Synthesis and Characterisation of 1,7-Dimethyl-1,4,7,10-tetraazacyclo-dodecane: Crystal Structure of the Nickel(II) Bromide Monohydrate Complex of this Macrocycle; Thermodynamic Studies of Protonation and Metal Complex Formation", J. Chem. Soc. Dalton Trans., 1984, 1357-1362. 28) Bianchi A., Bologni L., Dapporto P., Micheloni M., Paoletti P. "Coordination Tendencies of a Series of Tetraazacycloalkanes Related to 1,4,7,10-Tetraazadecane (Trien): Synthetic, Thermodynamic, and Structural Aspects", Inorg. Chem., 1984, 23, 1201-1205. 29) Ciampolini M., Micheloni M., Nardi N., Vizza F.,Buttafava A., Fabbrizzi L. "Synthesis of 1,2-Bis(1,4,7,10-tetra-azadodecanyl)ethane, a Double-ring Fully Saturated Macrocycle containing 12-Membered Tetra-aza Subunits", J. Chem. Soc., Chem. Commun., 1984, 998-999. 30) Bianchi A., Mangani S., Micheloni M., Nanini V., Orioli P., Paoletti P. "Dicopper(II) Complex of the Large Polyazacycloalkane 1,4,7,10,13,16,19,22-Octa-azacyclotetracosane Bistrien Synthesis, Crystal Structure, Electro-chemistry, and Thermodynamics of Formation", Inorg. Chem., 1985, 24, 1182-1187. 31) Micheloni M., Paoletti P., Siegfried-Hertli L., Kaden T.A. "Solution Chemistry of Macrocycles. Part 4. Thermodynamics of Protonation and Complexation of several N2S2 Macrocycles", J. Chem. Soc. Dalton Trans., 1985, 1169-1172. 32) Garcia-España E., Micheloni M., Paoletti P., Bianchi A. "Anion Coordination Chemistry. Hexacyanoferrate(II) anion Complexed by a Large Polycharged Azacycloalkane. Potentiometric and Electrochemical Studies", Inorg. Chimica Acta, 1985, 102, L9-L11. 33) Garcia-España E., Micheloni M., Paoletti P.,Bianchi A "Synthesis of the New Bis-azamacrocycle 1,2-bis (1,4,8,12-Tetra- azacyclo-tetradecanyl)ethane and its Dicopper(II) Complex", Gazz. Chimica Ital., 1985, 115, 399-400. 34) Clay R.M., Corr S., Micheloni M., Paoletti P. "Noncyclic Reference Ligands for Tetraaza Macrocycles. Synthesis and Thermodynamic Properties of a Series of ,µ-Di-N-methylated Tetraaza Ligands and their Copper(II) Complexes", Inorg. Chem., 1985, 24, 3330-3336. 35) Micheloni M., Paoletti P., Bianchi A. "1,4,7,10,13,16,19-Heptaazacycloheneicosane. A Large, Potentially Dinucleating Polyaza-cycloalkane. Synthesis and Equilibria between Hydrogen and Copper(II) Ions", Inorg. Chem., 1985, 24, 3702-3704. 36) Ciampolini M., Micheloni M., Vizza F., Zanobini F., Chimichi S. Dapporto P. "Synthesis of the Cage Penta-azamacrobicycloalkane 12,17-Dimethyl-1,5,9,12,17-pentaazabicyclo[7.5.5]nonadecane, its Basicity, and Metal Complex Formation. Crystal Structure of the Copper(II) Perchlorate Complex", J. Chem. Soc. Dalton Trans., 1986, 505-510.


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37) Ciampolini M., Micheloni M., Orioli P., Vizza F., Mangani S., Zanobini F. "Crystal Structure of the Hydrobromic Salt of 12,17-Dimethyl-1,5,9,12,17-Pentaazabicyclo[7.5.5]nonadecane, a Saturated Azacryptand Behaving as 'Protonic Sponge'", Gazzetta Chimica Italiana, 1986, 116, 189-192. 38) Garcia-España E., Micheloni M., Paoletti P. Bianchi A. "Thermodynamic Studies on Equilibria Between the Branched Hexaamine N,N,N',N'-Tetrakis(3-aminopropyl) ethylenediamine (TAPEN) and Hydrogen, Manganese(II), Iron(II), Cobalt(II), Nickel(II), Copper(II), and Zinc(II) Ions", Inorg. Chem., 1986, 25, 1435-1438. 39) Micheloni M., Paoletti P., Bianchi A.,Garcia-España E "Heats of Reaction between the Branched Hexaammine N,N,N',N'-tetrakis(3-aminopropyl) Ethylenediammine (TAPEN) and Hydrogen, Ni(II), Cu(II), Zn(II) Ions", Inorg. Chimica Acta, 1986, 117, 165-168. 40) Micheloni M., Paoletti P. "Metal Complexes in Solution. Solution Thermochemistry of Polyamine Complexes", Piccin, 1986, 27-38. 41) Bianchi A., Garcia-España E., Micheloni M., Nardi N., Vizza F. "Synthesis of the New Thia-Aza Cage 12,17-Dimethyl-5-thia-1,9,12,17-tetraaza-bicyclo[7.5.5]nonadecane. Thermodynamic Studies on Protonation and Copper(II) Complex Formation", Inorg. Chem., 1986, 25, 4379-4381. 42) Bencini A., Bianchi A., Garcia-España E., Giusti M., Micheloni M., Paoletti P. "Solution Chemistry of Macrocycles. 5. Synthesis and Ligational Behavior toward Hydrogen and Copper(II) Ions of the Large Polyazacycloalkanes 1,4,7,10,13,16,19,22,25-Nonaazacycloheptacosane ([27]aneN9)", Inorg. Chem., 1987, 26, 681-684. 43) Bencini A., Bianchi A., Garcia-España E., Giusti M.,Mangani S., Micheloni M., Paoletti P. "Synthesis and Complexing Properties of the Large Polyazacycloalkane 1,4,7,10,13,16,19,22,25,28-Decaazacyclo-triacontane (L). Crystal Structure of the Monoprotonated Dicopper(II) Complex [Cu2(L)HCl2](ClO4)3

.4H2O", Inorg. Chem., 1987, 26, 1243-1247. 44) Bianchi A., Garcia-España E., Mangani S., Micheloni M. Orioli P., Paoletti P. "Anion Co-ordination Chemistry. Crystal Structure of the 'Super Complex:' [H8L][Co(CN)6]2Cl2

.10H2O (L=1,4,7,10,13,16,19,22,25,28-Decaazacyclotri-acontane ", J. Chem. Soc., Chem. Commun., 1987, 729-731. 45) Bianchi A., Ciampolini M., Micheloni M., Chimichi S., Zanobini F. "Synthesis and Characterization of the Cage 12,17-dioxa-1,5,9-triaza-bicyclo[7.5.5]nonadecane. Its Basicity and Complexing Properties", Gazzetta Chimica Italiana, 1987, 117, 499-502. 46) Bencini A., Bianchi A., Garcia-España E., Giusti M., Mangani S., Micheloni M., Orioli P., Paoletti P. "Anion Coordination Chemistry. 2. Electrochemical, Thermodynamic, and Structural Studies on Supercomplex Formation between Large Polyammonium Cycloalkanes and Two Complex Anions Hexacyanoferrate(II) and Hexacyano-cobaltate(III)", Inorg. Chem., 1987, 26, 3902-3907. 47) Bencini A., Bianchi A., Garcia-España E., Micheloni M. Paoletti P. "Synthesis and Ligational Properties of the Two Very Large Polyazacycloalkanes [33]aneN11 and [36]aneN12 Forming Trinuclear Copper(II) Complexes Inorg. Chem., 1988, 27, 176-180. 48) Bianchi A., Micheloni M., Orioli P., Paoletti P., Mangani S. "Anion Coordination Chenistry. 3. Second-sphere Interaction Between the Complex Anions Hexacyanoferrate(II) and Hexacyanocobaltate(III), with Polycharged Tetraazamacrocycles. Thermodynamic and Single Crystal X-ray Studies", Inorg. Chimica Acta, 1988, 146, 153-159. 49) Bianchi A., Micheloni M., Paoletti P. "Supramolecular Interaction between Adenosine 5'-Tri-phosphate (ATP) and Polycharged Tetraazamacrocycles. Thermodynamic and 31P NMR Studies", Inorg. Chimica Acta, 1988, 151, 269-272. 50) Bencini A., Bianchi A., Garcia-España E., Mangani S., Micheloni M., Orioli P., Paoletti P. "Polynuclear Zinc(II) Complexes with Large Polyazacycloalkanes. Equilibrium Studies and Crystal Structure of the Binuclear [Zn2([30]aneN10)(NCS)](ClO4)3 Complex", Inorg. Chem., 1988, 27, 1104-1107. 51) Bianchi A., Micheloni M., Paoletti P. "Large Polyazacycloalkanes. Ligational Properties and Anion Coordination Chemistry", Pure and Appl. Chem., 1988, 60, 525-532. 52) Micheloni M. "Small Synthetic Macrocyclic Cages. Proton Transfer Properties and Metal Complexes", Coordination Chemistry, section B, 1988, 18, 3-19. 53) Micheloni M. "Large Polyazacycloalkanes and Small Macrocyclic Cages", Comments on Inorganic Chemistry, 1988, 8, 79-100. 54) Bianchi A., Micheloni M., Paoletti P. "Le molecole macrocicliche", Le Scienze, 1988, n° 238 giugno, 68-76.


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55) Battaglia L.P., Bianchi A., Bonamartini-Corradi A., Garcia-España E., Micheloni M., Julve M. "Synthesis, Crystal Structure, Magnetic Properties, Thermodynamic and Electrochemical Studies of the Binuclear Complex [(-Oxalato)bis(1,4,8,11-tetraazacyclotetradecane)-Nickel(II)] Nitrate", Inorg. Chem., 1988, 27, 4174-4179. 56) Delgado R., da Silva J.J.R.F., Vaz M.C., Paoletti P., Micheloni M. "The Thermodynamics of Formation of Metal Complexes of 1,4,10-Trioxa-7,13-Diazacyclopentadecane-N,N'-diacetic and of 1,4,10-13-Tetraoxa-7,16-diaza-cyclooctadecane-N,N'-diacetic acids", J. Chem. Soc., Dalton Trans., 1988, 133-137. 57) Bencini A., Bianchi A., Castello M., DiVaira M., Faus, J., Garcia-España, Micheloni M., Paoletti P. "Thermodynamic Study of the Formation in Aqueous Solution of Cadmium(II) Complexes with Polyazacycloalkanes. Synthesis and Crystal Structure of the Dicadmium(II) Complex Na[Cd2(L)Cl2](ClO4)3 (L=1,4,7,10,13,16,19,22,25,28-decaazacyclotriacontane)". Inorg. Chem., 1988, 28, 347-351. 58) Bianchi A., Ciampolini M., Micheloni M., Nardi N., Valtancoli B., Mangani S., "The Small Cage 12,17-Dimethyl-5-oxo-1,9,12,17-tetraazabicyclo[7.5.5]nona-decane (L). Its Synthesis, Characterization and 'Proton Sponge' Behaviour. The Crystal Structure of the Dipicrate Salt [H2L](Picrate)2", J. Chem. Soc., Perkin Trans. 2, 1989, 1131-1137. 59) Bencini A., Bianchi A., Dapporto P., Garcia-España E., Micheloni M., Paoletti P. "Polynuclear Zinc(II) Complexes with Large Polyazacycloalkanes 2. Equilibrium Studies and Crystal Structure of the Binuclear Complex [Zn2LCl2]Cl.ClO4 (L=1,4,7,10,13,16,19,22-Octaazacyclotetracosane). Inorg. Chem., 1989, 28, 1188-1191. 60) Bencini A., Bianchi A., Garcia-España E., Ciampolini, M., Garcia-España E., Dapporto P., Micheloni M., Paoli P., Ramirez J.A., Valtancoli B. "Selective Encapsulation of Lithium Ion by the New Azacage 5,12,17-Trimethyl-1,5,9,12,17-pentaazabicyclo[7.5.5]nonadecane (L). Thermodynamic Studies and Crystal Structures of the Lithium Complex [LiL][BPh4] and of the Monoprotonated Salt

[HL][Cl].3H2O", J. Chem. Soc., Chem. Commun., 1989, 701-702. 61) Bencini A., Bianchi A., Garcia-España E., Micheloni M., Paoletti P. "Anaerobic Complexation of Cobalt(II) by [3k]aneNk (k=7-12) Polyaza-cycloalkanes", Inorg. Chem., 1989, 28, 2480-2482. 62) Bencini A., Bianchi A., Castello M., Dapporto P., Faus J., Garcia-España, Micheloni M., Paoletti P. "Nickel(II) Complexes of [3k]aneNk Polyazacycloalkanes. Solution Studies and Crystal Structures Determination", Inorg. Chem., 1989, 28, 3175-3181. 63) Bencini A., Bianchi A., Ciampolini M., Garcia-España E., Dapporto P., Micheloni M., Paoli P., Ramirez J.A., Valtancoli B. "Synthesis and Characterization of the New Macrocyclic Cage 5,12,17-Trimethyl-1,5,9,12,17-Pentaazabicyclo[7.5.5]nonadecane (L), Which Can Selectively Encapsulate Lithium Ion. Thermodynamic Studies on Protonation and Complex Formation. Crystal Structure of the Salt [HL]Cl.3H2O", Inorg. Chem., 1989, 28, 4279-4284. 64) Bencini A., Bianchi A., Borselli A., Ciampolini M., Dapporto P., E. Garcia-España, Micheloni M., Paoli P., Ramirez J.A., Valtancoli B. "Structural Aspects in Protonation of Small Cages. Preparation of the New Aza-cage 12,17-Dimethyl-1,9,12,17-tetraazabicyclo[7.5.5]nonadecane (L). Thermo-dynamic Studies on Solution Equilibria. Crystal Structures of [H2L][CoCl4] and [H2L1][CoCl4] (L1=5,12,17-Trimethyl-1,5,9,12,17-pentaazabicyclo[7.5.5]nona-decane) Salts", J. Chem. Soc., Perkin Trans. 2, 1989, 209-214. 65) Bencini A., Bianchi A., Borselli A., Ciampolini M., Micheloni M., Nardi N., Paoli P., Valtancoli B., Chimichi S., and Dapporto P. "Synthesis of a Small Azacage which can Selectively Encapsulate a Lithium Ion in Aqueous Solution", J. Chem. Soc., Chem. Commun., 1990, 174-175. 66) Bencini A., Bianchi A., Dapporto P., Garcia-España E., Marcelino V., Micheloni M., Paoletti P., and Paoli P. "Heptacoordination of Manganese(II) by the Polyazacycloalkane [21]aneN7. Crystal Structure of the [Mn([21]aneN7)](ClO4)2 Solid Compound and Thermodynamics of Complexation in Water Solution", Inorg. Chem., 1990, 29, 1716-1718. . 67) Bencini A., Bianchi A., Dapporto P., Garcia-España E., Micheloni M., Paoletti P., and Paoli P. "[PdCl4]2- Inclusion into the Deca-charged Polyammonium Receptor (H10[30]aneN10)10+ ([30]aneN10 = 1,4,7,10,13,16,-19,22,25,28-decaazacyclo triacontane)", J. Chem. Soc., Chem. Commun., 1990, 753-755. 68) Bencini A., Bianchi A., Borselli A., Ciampolini M., Micheloni M., Nardi N., Paoli P., Valtancoli B., Chimichi S., and Dapporto P. "Selective Lithium Encapsulation in Aqueous Solution by the New Cage 4,10-Dimethyl-1,4,7,10,15-pentaazabicyclo[5.5.5]-eptadecane (L). Synthesis, Characterization and Structural Aspects. The Crystal Structures of: [LiL][ClO4], and

[CuL]Br2.3H2O", Inorg. Chem., 1990, 29, 3282-3286.

69) Bencini A., Bianchi A., Dapporto P., Garcia-España E., Micheloni M., Paoletti P., and Paoli P. "Di- and Tripalladium(II) Polyazacycloalkane Complexes. A Case of Deprotonated Secondary Nitrogen in Solution and in Solid State", J. Chem. Soc., Chem. Commun., 1990, 1382-1384.


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70) Micheloni M., Nardi N., Valtancoli B. "Synthesis and Characterization of the Branched Azacage 12-Methyl-17-pentyl-1,5,9,12,17-pentaazabicyclo[7.5.5]nonadecane. Basicity and Copper(II) Complex", Gazzetta Chimica Italiana, 1990, 121, 29-31. 71) Bianchi A., Micheloni M., Paoletti P. "Thermodynamic Aspects of the Polyazacycloalkane Complexes with Cations and Anions". Coord. Chem. Reviews, 1991, 101, 17-113. 72) Aragò J., Bencini A., Bianchi A., Garcia-España E., Micheloni M., Paoletti P., Paoli P., and Ramirez J.A. "Interaction of 'Long' Open-Chain Polyazaalkanes with Hydrogen and Copper(II) Ions." Inorg. Chem., 1991, 30, 1843-1849. 73) Bencini A., Bianchi A., Chimichi S., Ciampolini M., Dapporto P., Garcia-España E., Micheloni M., Nardi N., Paoli P., and Valtancoli B. "Lithium Binder in Aqueous Solution. Synthesis and Characterization of the New Cage 4,10,15-Trimethyl-1,4,7,10,15-pentaazabicyclo[5.5.5]eptadecane (L). Protona-tion and Lithium Complex Formation. Crystal Structures of [HL][BPh4] and [LiL][BPh4]." Inorg. Chem., 1991, 30, 3687-3691. 74) Bencini A., Bianchi A., Micheloni M., Paoletti P., Garcia-España E., Niño and M. A. Ramirez J.A. "Co-ordination Tendency of [3k]aneNk Polyazacycloalkanes. Thermodynamic Study of Solution Equilibria." J. Chem. Soc., Dalton Trans., 1991, 1171-1174. 75) Aragò J., Bencini A., Bianchi A., Garcia-España E., Micheloni M., Paoletti P., Ramirez J.A., Rodriguez A. "Interaction of Long Polyazaalkanes with Zinc(II) and Cadmium(II) Ions. A Thermodynamic and 13C Nuclear Magnetic Resonance Study" J. Chem. Soc., Dalton Trans., 1991, 3077-3083. 76) Bencini A., Bianchi A., Ciampolini M., Dapporto P., Micheloni M., Nardi N., Paoli P., and Valtancoli B. "Synthesis and Characterization of the Aza-cage 4-Benzyl-10,15-dimethyl-1,4,7,10,15-penta-azabicyclo[5.5.5]eptadecane (L). Its Proton Transfer Properties and Lithium Complex. The Crystal Structure of the Monoprotonated Salt [HL][BPh4]." J. Chem. Soc., Perkin Trans. 2, 1992, 181-184. 77) Bencini A., Bianchi A., Dapporto P., Garcia-España E., Micheloni M., Paoletti P., Paoli P. "Cation and Anion Coordination Chemistry of Palladium(II) with Polyazacycloalkanes. Thermodynamic and Structural Studies." J. Inclusion Chem., 1992, 12, 263-274. 78) Eglin J.L., Jackson E.P., Moeggenborg K.J., Dye J.L., Bencini A., Micheloni M. "Li+(TMPAND)Na- the First Alkalide Prepared from an Azacage Complexant" J. Inclusion Chem., 1992, 12, 291-304. 79) Micheloni M., Ciampolini M., Nardi N., Valtancoli B. "Small Aza-Cages as 'Fast Proton Sponges' and Strong Lithium Binders" Coord. Chem. Reviews, 1992, 120, 223-236. 80) Bencini A., Bianchi A., E. Garcia-España, Fusi V., Micheloni M., Paoletti P., Ramirez J.A., Rodriguez A., Valtancoli B. "Synthesis and Protonation Behaviour of the Macrocyclic Ligand 1,4,7,13-Tetramethyl-1,4,7,10,13,16-hexaazacyclooctadecane and of its Bicyclic Derivative 4,7,10,17,23-Pentamethyl-1,4,7,10,13,23-heptaazabicyclo[11.7.5]-pentacosane. A Potentiometric and 1H and 13C NMR Study" J. Chem. Soc., Perkin Trans. 2, 1992, 1059-65. 81) Bencini A., Bianchi A., P. Dapporto, E. Garcia-España, Micheloni M., Paoletti P., Paoli P., and Ramirez J.A. "Thermodynamic and Structural Aspects of the Interaction between Macrocyclic Polyammonium Cations and Complexed Anions" Inorg. Chem., 1992, 31, 1902-1908. 82) Pina F., Parola A.J., Bencini A., , Micheloni M., Manfrin M.F., and Moggi L. "Charge effects on the photochemistry of the Co(EDTA)- .I- system in the presence of polyammonium macrocyclic receptors." Inorg. Chim. Acta, 1992, 195, 139-143. 83) Bencini A., Bianchi A., Ciampolini M., Dapporto P., Fusi V., Micheloni M., Nardi N., Paoli P., and Valtancoli B. "Synthesis, Crystal Structure and Ligational Properties of a New Macrotricyclic Ligand" J. Chem. Soc. Dalton Trans., 1992, 2049-2054. 84) Bencini A., Bianchi A., Bazzicalupi C., Ciampolini M., Dapporto P., Fusi V., Micheloni M., Nardi N., Paoli P., and Valtancoli B. "Synthesis and Characterization of an Aza-cage Behaving as a 'Proton Sponge'. Crystal Structures of its Mono- and Tri-protonated Species" J. Chem. Soc., Perkin Trans. 2, 1993, 115-119. 85) Bencini A., Bianchi A., Bazzicalupi C., Ciampolini M., Dapporto P., Fusi V., Micheloni M., Nardi N., Paoli P., and Valtancoli B. "Synthesis and Characterization of an Aza-cage, Basicity Behaviour and Crystal Structure of its Diprotonated Species" J. Chem. Soc., Perkin Trans. 2, 1993, 715-720. 86) Bencini A., Bianchi A., Dapporto P., Fusi V., Garcia-España E., Micheloni M., Paoletti P., Paoli P., Rodriguez A., and Valtancoli B. "Thermodynamic, Kinetic, and Structural Study of the Ligational Properties of the Macrobicyclic Aza-Ligand 4,7,10,17,23-Pentamethyl-1,4,7,10,13,17,23-heptaaza-bicyclo-[11.7.5]pentacosane (L1) and of Its Macrocyclic Precursor 1,4,7,13-Tetramethyl-1,4,7,10,13,16-hexaazacyclooctadecane (L2). Crystal Structure of [Zn(L1)(H

2O)](BPh

4)2

" Inorg. Chem., 1993, 32,

2753-2760.


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87) Bencini A., Bianchi A., Bazzicalupi C., Ciampolini M., Fusi V., Micheloni M., Nardi N., Paoli P., and Valtancoli B. "Proton inclusion properties of a new azamacrocycle. Synthesis, characterization and crystal structure of [H3L][Cl]3

.2H2O (L=4,10-dimethyl-1,4,7,10-tetraazabicyclo[5.5.2]tetradecane)" Supramolecular Chemistry, 1994, 3, 141-146. 88) Bencini A., Bianchi A., Bazzicalupi C., Ciampolini M., Fusi V., Micheloni M., Nardi N., Paoli P., and Valtancoli B. "Two macrocycles of different molecular topology obtained by the same synthetic procedure. Their crystal structures and ligational properties" Supramolecular Chemistry, 1994, 3, 279-290. 89) Bazzicalupi C., Bencini A., Fusi V., Micheloni M., and Valtancoli B. "A Giant-size Azamacrocycle: Synthesis and Crystal Structure of its Dinuclear Cadmium Complex". J. Chem. Soc., Chem. Commun., 1994, 1119-1120. 90) Bazzicalupi C., Bencini A., Bianchi A., Fusi V., Giorgi C., Micheloni M., Paoletti P. and Valtancoli B. “A Novel Synthetic Pathway for Paracyclophane Receptors”. Tetrahedron Letters., 1994, 35, 8469-8472. 91) Bazzicalupi C., Bencini A., Fusi V., Micheloni M., Paoletti P. and Valtancoli B. “Synthetic Route To Produce Giant-Size Azamacrocycles”. J. Org. Chem., 1994, 59, 7508-7510. 92) Bazzicalupi C., Bencini A., Bianchi A., Fusi V., Micheloni M., Paoletti P. and Valtancoli B. "Toward Ever Bigger Cyclic Molecules". Gazzetta Chimica Italiana, 1995, 125, 163-168. 93) Bazzicalupi C., Bencini A., Ciampolini M., Fusi V., Micheloni M., Nardi N., Razzolini I. and Valtancoli B. “Coloured aza-cages for lithium encapsulation”. Supramolecular Chemistry, 1996, 7, 61-66. 94) Bencini A., Fusi V., Giorgi C., Micheloni M., Nardi N., and Valtancoli B. “Aza-macrocycles bearing lipophilic functions. Their synthesis and selective lithium complexation”. J. Chem. Soc., Perkin Trans. 2, 1996, 2297-2302. 95) Bazzicalupi C., Bencini A., Fusi V., Micheloni M., Pontellini R., Valtancoli B. “Reinforced, piperazine rings containing polyamines: metal complex equilibria and structural studies”. Inorg. Chim. Acta, 1998, 268, 63-68. 96) Dapporto P., Fusi V., Micheloni M., Palma P., Paoli P., and Pontellini R. “Binding Properties and Crystal Structures of Azamacrocycles Containing Nitrophenol Side Arms”. Inorg. Chim. Acta, 1998, 275, 168-174. 97) Bardazzi E., Ciampolini M., Fusi V., Micheloni M., Nardi N., Pontellini R., and Romani P. “Synthetic Route to Produce Phenol-Containing Azamacropolycycles”. J. Org. Chem., 1999, 64, 1335-1337. 98) Formica M., Fusi V., Micheloni M., and Romani P. “Cryptand Ligands for Selective Lithium Coordination”. Coordination Chem. Rev., 1999, 184, 347-363. 99) Bencini A., Bianchi A., Garcia-España E., Micheloni M. and Ramirez J.A. “Proton Coordination by Polyamine Compounds in Aqueous Solution”. Coordination Chem. Rev., 1999, 188, 97-156. 100) Dapporto P., Fusi V., Giorgi C., Micheloni M., Palma P., Paoli P., and Pontellini R. “Conformational Change of an Azamacrocycle Containing Nitrophenol Side Arms by Proton Coordination. Crystal Structures, Heat of Reaction and Molecular Mechanics Calculations”. Supramolecular Chemistry, 1999, 10, 243-252. 101) M. Ciampolini, M. Formica, V. Fusi, A.S. Mauricec, M. Micheloni, N. Nardi, R. Pontellini, F. Pina, P. Romani, A.M. Sabatini, B. Valtancoli. “Selective Lithium Complexation by Photoactive Aza-Cages Bearing the Antracene Function” Eur. J. Inorg. Chem., 1999, 2261-2268. 102) M. Micheloni, M. Formica, V. Fusi, P. Romani, R. Pontellini, P. Dapporto, P. Paoli, P. Rossi, B. Valtancoli. “Synthesis, Crystal Structures and Lithium Encapsulation by Some Phenolic Aza Cages” Eur. J. Inorg. Chem., 2000, 51-57. 103) P. Dapporto, M. Formica, V. Fusi, M. Micheloni, P. Paoli, R. Pontellini, P. Romani, P. Rossi. “Polyamine Macrocycles Incorporating a Phenolic Function: their Synthesis, Basicity and Coordination Behavior Toward Metal Cations. Crystal Structure of a Binuclear Nickel Complex” Inorg. Chem., 2000, 39, 2156-2163. 104) J.A. Aguilar, A.B. Descalzo, P. Diaz, V. Fusi, E. Garcia-España, S.V. Luis, M. Micheloni, J.A. Ramirez, P. Romani and C. Soriano. “New Molecular Catalists for ATP Cleavage. Criteria of Size Complementarity” J. Chemical Society Perkin Trans. 2, 2000, 6, 1187-1192.

105) P. Dapporto, M. Formica, V. Fusi, M. Micheloni, P. Paoli, R. Pontellini and P. Rossi “Synthesis of a Flexible Ligand for Assembling Two Metal Ions in Close Proximity. Crystal Structure of Binuclear Nickel and Copper Complexes” Inorg. Chem., 2000, 39, 4663-4665. 106) M. Formica, V. Fusi, M. Micheloni, R. Pontellini and P. Romani “Synthesis and ligational properties of a new tetra-azamacrocycle containing an anisolic function” Polyhedron, 2000, 19, 2501-2505.


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107) P. Dapporto, M. Formica, V. Fusi, L. Giorgi, M. Micheloni, R. Pontellini, P. Paoli and P. Rossi “Ligational Properties of two New Phenolic Aza-cages Towards Proton and Alkali Metal Ions: a Theoretical and an Experimental Approach.” Eur. J. Inorg. Chem., 2001, 1763-1774

108) A. Bencini, M. Formica, V. Fusi, C. Giorgi, L. Giorgi, M. Micheloni, R. Pontellini and B. Valtancoli

“Synthesis and Characterization of a Macrocycle Containing Different Functional Groups and its Non-Cyclic Counterpart” Inorg. Chim. Acta, 2001, 318, 152-158. 109) P. Dapporto, M. Formica, V. Fusi, M. Micheloni, R. Pontellini, P. Paoli and P. Rossi “A Flexible Ligand for Multipurpose Complexation” Supramolecular Chemistry, 2001, 13, 369-377. 110) N. Ceccanti, M. Formica, V. Fusi, L. Giorgi, M. Micheloni, R. Pardini, R. Pontellini and M.R. Tinè “Anaerobic and Aerobic Complexation of Co(II) by a Polyamine Ditopic Ligand Containing the Phenolic Moiety” Inorg. Chim. Acta, 2001, 321, 153-161. 111) G. Crisponi, F. Cristiani, V. M. Nurchi, R. Pinna, T. Pivetta, V. Fusi and M. Micheloni “Spectrophotometric and Potentiometric Study on Fe(II) Complexes with Some Macrocyclic Ligands” Inorg. Chim. Acta, 2001, 323, 62-68. 112) P. Dapporto, M. Formica, V. Fusi, L. Giorgi, M. Micheloni, R. Pontellini, P. Paoli and P. Rossi “Addition of Small Molecules by Zn(II) and Cu(II) Dinuclear Complexes Obtained by an Amino-Phenolic Ligand. Crystal Structures of the Dinuclear Zinc Complex Assembling Butanolate and Azide Anions” Inorg. Chem., 2001, 40, 6186-6192.

113) M. Formica, V. Fusi, L. Giorgi, M. Micheloni, P. Palma and R. Pontellini “A Template Synthesis of Polyamine Macrocycles Containing the 1,1’-Bis(2-phenol) Function” Eur. J. Org. Chem., 2002, 402-404. 114) V. Fusi, A. Llobet, J. Mahìa, M. Micheloni, P. Paoli, X. Ribas and P. Rossi “A New Cu(I) Complex that Mimics the Cresolase Reaction of Tyrosinase and the Crystal Structure of its Oxygenated Cu(II) Complex” Eur. J. Inorg. Chem., 2002, 4, 987-900. 115) M. Formica, V. Fusi, L. Giorgi, M. Micheloni, R. Pontellini “Two triaza-polyamine units linked together by different aromatics spacers, coordination properties towards metal cations of a new compartmental ligand” Polyhedron, 2002, 21, 1351-1356. 116) G. Ambrosi, P. Dapporto, M. Formica, V. Fusi, L. Giorgi, A. Guerri, M. Micheloni, P. Paoli and P. Rossi “Crystal Structure and Chemical Properties of Ni(II)-Zn(II) Hetero-Dinuclear Complex” J. Supramolecolar Chemistry, 2002, 2, 301-303.

117) P. Dapporto, M. Formica, V. Fusi, L. Giorgi, M. Micheloni, P. Paoli, R. Pontellini and P. Rossi “Molecular Switch Triggered by Solvent Polarità. Synthesis, Acid-Base Behavior, Alkali Metal Ion Complexation, and Crystal Structure” Chemistry, 2003, 42, 800-810. 118) E. Berti, A. Caneschi, C. Daiguebonne, P. Dapporto, M. Formica, V. Fusi, L. Giorgi, A. Guerri, M. Micheloni, P. Paoli, R. Pontellini, and P. Rossi “Ni(II), Cu(II), and Zn(II) Dinuclear Metal Complexes with an Aza-Phenolic Ligand: Crystal Structures, Magnetic Properties, and Solution Studies” Inorg. Chem., 2003, 42, 348-357. 119) G. Ambrosi, M. Formica, V. Fusi, L. Giorgi, A. Guerri, M. Micheloni, R. Pontellini and P. Rossi “Synthesis, acid-base and coordination properties towards Cu(II), Zn(II), and Cd(II) ions of two new polyamino-phenolic ligands, including the crystal structure of a fully protonated ligand” Polyhedron, 2003, 22, 1135-1146. 120) M. Formica, V. Fusi, L. Giorgi, A. Guerri, S. Lucarini, M. Micheloni, P. Paoli, R. Pontellini, P. Rossi, G. Tarzia and G. Zappia “New ligand bearing preorganized binding side-arms interacting with ammonium cations: Synthesis, conformational studies and crystal structure” New J. Chem., 2003, 27, 1575 - 1583. 121) G. Ambrosi, M. Formica, V. Fusi, L. Giorgi, A. Guerri, M. Micheloni, P. Paoli, R. Pontellini and P. Rossi “Heavy metal ion complexes with a simple phenolic ligand. Solid state and solution studies” Inorganica Chimica Acta, 2003, 356, 203-209. 122) M. Cangiotti, M. Formica, V. Fusi, L. Giorgi, M. Micheloni, M.F. Ottaviani, and S. Sanpaolesi “Nitroxide Radicals Interactions with Polyamine-Phenolic Ligands and Their Metal Complexes” Eur. J. Inorg. Chem., 2004, 2853-2860. 123) G. Ambrosi, P. Dapporto, M. Formica, V. Fusi, L. Giorgi, A. Guerri, M. Micheloni, P. Paoli, R. Pontellini and P. Rossi “Synthesis and coordination properties of new macrocyclic ligands. Equilibrium studies and crystal structures” Dalton Trans., 2004, 3468 – 3474. 124) G. Ambrosi, P. Dapporto, M. Formica, V. Fusi, L. Giorgi, A. Guerri, S. Lucarini, M. Micheloni, P. Paoli, R. Pontellini, P. Rossi and G. Zappia “Macrocyclic ligands bearing two 3-(Hydroxy)-2-pyridinone moieties as side-arms. Conformational studies, synthesis, crystal structure, and alkali and alkaline earth complex formation” New J. Chem., 2004, 28, 1359-1367.


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125) G. Ambrosi, A. Boggioni, M. Formica, V. Fusi, L. Giorgi, S. Lucarini, M. Micheloni, F. Secco, M. Venturini, and G. Zappia “A macrocyclic ligand able to bind gallium(III) by preorganized pendant arms; coordination and kinetic studies” Dalton Trans., 2005, 485-490.

126) G. Ambrosi, M. Formica, V. Fusi, L. Giorgi, A. Guerri, S. Lucarini, M. Micheloni, P. Paoli, P. Rossi, and G. Zappia. “Co-ordination Behaviour Towards Cu(II) and Zn(II) Ions of Three Ligands Joining 3-Hydroxy-2-pyridinone and Polyaza Fragments”.Inorg. Chem., 2005, 44, 3249-3260.

127) G. Ambrosi, P. Dapporto, M. Formica, V. Fusi, L. Giorgi, A. Guerri, M. Micheloni, P. Paoli, R. Pontellini and P. Rossi. “Synthesis of a Large Amino-Phenolic Cage. Synthesis, Crystal Structures, and Acid-Base and Coordination Behavior toward Cations and Anions” Inorg. Chem., 2006, 45, 304-314. 128) S. Benedetti, S. Rinalducci, F. Benvenuti, S. Francogli, S. Pagliarani, L. Giorgi, M. Micheloni, G. M. D’Amici, L. Zolla, F. Canestrari. “Purification and characterization of phycocyanin from the blue-green alga Aphanizomenon flos-aquae”. J. of Chromatography B, 2006, 833, 12–18. 129) G. Ambrosi, M. Formica, V. Fusi, L. Giorgi, A. Guerri, M. Micheloni, P. Paoli, R. Pontellini, P. Rossi Modulating the M-M Distance in Dinuclear Complexes. New Ligand with a 2,2'-Biphenol Fragment as Key Unit: Synthesis, Coordination Behavior, and Crystal Structures of Cu(II) and Zn(II) Dinuclear Complexes. Inorg. Chem., 2007, 46(1), 309-320. 130) G. Ambrosi, M. Formica, V. Fusi, L. Giorgi, A. Guerri, M. Micheloni, P. Paoli, R. Pontellini and P. Rossi. “A New Macrocyclic Cryptand with Squaramide Moieties: An Overstructured CuII Complex That Selectively Binds Halides: Synthesis, Acid/Base- and Ligational Behavior, and Crystal Structures” Chem. Eur. J., 2007, 13, 702-712. 131) Gianluca Ambrosi, Mauro Formica, Vieri Fusi, Luca Giorgi, Annalisa Guerri, Mauro Micheloni, Paola Paoli, Roberto Pontellini and Patrizia Rossi. “A New Branched Phenanthroline Derivative Ligand: Synthesis, Solution Chemistry, and Crystal Structures of Copper(II) and Zinc(II) Complexes”. Inorg. Chem., 2007, 46, 4737-4748. 132) Gianluca Ambrosi, Mauro Formica, Vieri Fusi, Luca Giorgi and Mauro Micheloni “Polynuclear metal complexes of ligands containing phenolic units”. Coord. Chem. Review., 2008, 252 1121-1152. 133) Gianluca Ambrosi, Cristina Battelli, Mauro Formica, Vieri Fusi, Luca Giorgi, Eleonora Macedi, Mauro Micheloni, Roberto Pontellini and Luca Prodi “Two polyaminophenolic fluorescent chemosensors for H+ and Zn(II). Spectroscopic behaviour of free ligands and of their dinuclear Zn(II) complexes”. New Journal of Chemistry, 2008, 32, 1-10. 134) Gianluca Ambrosi, Mauro Formica, Vieri Fusi, Luca Giorgi, Eleonora Macedi, Mauro Micheloni, Roberto Pontellini. “ Synthesis of new compartmental amino-phenolic ligands. Basicity, coordination properties towards Cu(II) and Zn(II) ions. A fluorescent chemosensor for H+ and Zn(II)”. Inorg. Chim. Acta, 2009, 362, 2667-2677. 135) Gianluca Ambrosi, Mauro Formica, Vieri Fusi, Luca Giorgi, Eleonora Macedi, Mauro Micheloni, Roberto Pontellini. A family of polyamino phenolic macrocyclic ligands. Acid-base and coordination properties towards Co(II), Ni(II), Cu(II), Zn(II), Cd(II) and Pb(II) ions. Inorg. Chim. Acta, 2009, 362, 3709-3714. 136) Gianluca Ambrosi, Mauro Formica, Vieri Fusi, Luca Giorgi, Eleonora Macedi, Mauro Micheloni, Paola Paoli and Patrizia Rossi “Polynuclear Complexes: Two Amino-Phenol Macrocycles Spaced by Several Linear Polyamines; Synthesis, Binding Properties, and Crystal Structure”. Inorg. Chem. 2009, 48, 10424-10434. 137) Gianluca Ambrosi, Mauro Formica, Vieri Fusi, Luca Giorgi, Annalisa Guerri, Eleonora Macedi, Mauro Micheloni, Paola Paoli, Roberto Pontellini and Patrizia Rossi “Phosphates Sensing: Two Polyamino-Phenolic Zinc Receptors Able to Discriminate and Signal Phosphates in Water.” Inorg. Chem. 2009, 48, 5901-5912. 138) Gianluca Ambrosi, Samuele Ciattini, Mauro Formica, Vieri Fusi, Luca Giorgi, Eleonora Macedi, Mauro Micheloni, Paola Paoli, Patrizia Rossi and Giovanni Zappia “A New Versatile Solvatochromic Amino-macrocycle. From Metal Ions to Cell Sensing in Solution and in Solid State” Chem. Comm., 2009, 7039-7041. 139) Gianluca Ambrosi, Mauro Formica, Vieri Fusi, Luca Giorgi, Eleonora Macedi, Mauro Micheloni, Giovanni Piersanti, and Roberto Pontellini “New Family of Polyamine Macrocycles Containing 2,5-diphenyl[1,3,5]oxadiazole as a Signaling Unit. Synthesis, Acid-Base and Spectrophotometric Properties” Org. Biomol. Chem., 2010, 8, 1471-1478. 140) Gianluca Ambrosi, Mauro Formica, Vieri Fusi, Luca Giorgi, Eleonora Macedi, Mauro Micheloni, Paola Paoli and Patrizia Rossi “Polynuclear Complexes: Two Amino-Phenol Macrocycles Spaced by Several Linear Poliamines; Synthesis, Binding Properties, and Crystal Structure.” Inorg. Chem. 2009, 48, 10424-10434. 141) Gianluca Ambrosi, Mauro Formica, Vieri Fusi, Luca Giorgi, Eleonora Macedi, Mauro Micheloni, Paola Paoli, Patrizia Rossi, Roberto Pontellini “Efficient fluorescent sensors based on 2,5-diphenyl[1,3,4]oxadiazole. A case of specific response to Zn(II) at physiological pH”, Inorg. Chem. 2010, 49, 9940-9948.


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142) Gianluca Ambrosi, Mauro Formica, Vieri Fusi, Luca Giorgi, Eleonora Macedi, Mauro Micheloni, Paola Paoli, Patrizia Rossi, Roberto Pontellini, Maria Antonietta Varrese “Macrocyclic Ligand as Receptor and Zn(II)-Receptor for Anions in Water. Binding Properties and Crystal Structures”. Chemistry- A European Journal, 2011, 17, 1670-1682. 143) Luigia Sabatini, Claudio Ferrini, Mauro Micheloni, Anna Pianetti, Barbara Citterio, Chiara Parlani, Francesca Bruscolini “Isolation of a strain of Aspergillus Fumigatus able to grow in minimal medium added with an industrial cyanide waste”, World J. Microbiol. Biotech. 2012, 28, 165-173.

144) Mauro Formica, Vieri Fusi, Luca Giorgi, Mauro Micheloni “New fluorophores for metal ions in solution”, Coord. Chem. Rev. 2012, 256, 170-192. 145) Stefano Amatori, Gianluca Ambrosi, Mirco Fanelli, Mauro Formica, Vieri Fusi, Luca Giorgi, Eleonora Macedi, Mauro Micheloni, Paola Paoli, Roberto Pontellini, Patrizia Rossi, Maria Antonietta Varrese “Multi-use NBD-based tetra-amino macrocycle: fluorescent probe for metals and anions and live cell marker”. Chem. Eur. J., 2012, 18, 4274-4284.

146) Stefano Amatori, Gianluca Ambrosi, Mirco Fanelli, Mauro Formica, Vieri Fusi, Luca Giorgi, Eleonora Macedi, Mauro Micheloni, Paola Paoli, Roberto Pontellini, Patrizia Rossi “Synthesis, Basicity, Structural Characterization, and Biochemical Properties of Two [(3-Hydroxy-4-pyron-2-yl)methyl]amine Derivatives Showing Antineoplastic Features”. J. Org. Chem. 2012, 77, 2207-2218. 147) Elisa Borgogelli, Mauro Formica, Vieri Fusi, Luca Giorgi, Eleonora Macedi, Mauro Micheloni, Paola Paoli, Patrizia Rossi “Preorganizing binding side-arms on a cyclen scaffold: the choice of a suitable metal ion”. Dalton Trans., 2013, 42, 2902-2912.

148) Cristiano Benelli, Elisa Borgogelli, Mauro Formica, Vieri Fusi, Luca Giorgi, Eleonora Macedi, Mauro Micheloni, Paola Paoli, Patrizia Rossi “Di-maltol-polyamine ligands to form heterotrinuclear metal complexes: solid state, aqueous solution and magnetic characterization”. Dalton Trans., 2013, 42, 5848-5859.

149) Stefano Amatori, Gianluca Ambrosi,

Elisa Borgogelli,

Mirco Fanelli,

Mauro Formica,

Vieri Fusi,

Luca Giorgi,

Eleonora

Macedi, Mauro Micheloni,

Paola Paoli,

Patrizia Rossi,

and Aurora Tassoni “Modulating the Sensor Response to Halide Using

NBD-Based Azamacrocycles”. Inorg. Chem., 2014, 53(9), 4560 – 4569.

150) Chiara Cappelli, Celia Duce, Mauro Formica, Vieri Fusi, Lisa Ghezzi, Luca Giorgi, Mauro Micheloni, Paola Paoli, Patrizia Rossi, Maria Rosaria Tiné ”Cobalt complexes able to bind dioxygen: Thermodynamic studies and DFT calculations”. Inorg. Chim. Acta, 2014, 417, 230-238.

151) Stefano Amatori, Gianluca Ambrosi,

Mirco Fanelli,

Mauro Formica,

Vieri Fusi,

Luca Giorgi,

Eleonora Macedi,

Mauro

Micheloni, Paola Paoli,

Patrizia Rossi “A Preorganized Metalloreceptor for Alkaline Earth Ions Showing Calcium Versus

Magnesium Selectivity in Water: Biological Activity of Selected Metal Complexes”, Chem. Eur. J., 2014, 20, 11048-11057.

152) Gianluca Ambrosi, Elisa Borgogelli, Mauro Formica,

Vieri Fusi,

Luca Giorgi,

Mauro Micheloni, Enrico Rampazzo, Massimo

Sgarzi, Nelsi Zaccheroni, Luca Prodi “PluS Nanoparticles as a tool to control the metal complex stoichiometry of a new thio-aza macrocyclic chemosensor for Ag(I) and Hg(II) in water”. Sensors and Actuators, B: Chemical, 2015, B 207, 1035-1044.

153) Mirco Fanelli, Mauro Formica, Vieri Fusi, Luca Giorgi, Mauro Micheloni, Paola Paoli “New trends in platinum and palladium complexes as antineoplastic agents”, Coord. Chem. Rev., 2016, 310, 41-79.

154) Gianluca Ambrosi,

Mauro Formica,

Vieri Fusi, Luca Giorgi,

Eleonora Macedi,

Mauro Micheloni,

Paola Paoli,

and

Patrizia Rossi “A Biphenol-Based Chemosensor for Zn(II) and Cd(II) Metal Ions: Synthesis, Potentiometric Studies, and Crystal

Structures”, Inorg. Chem., 2016, 55, 7676-7687.

155) Stefano Amatori, Gianluca Ambrosi, Alfredo Errico Provenzano, Mirco Fanelli, Mauro Formica, Vieri Fusi, Luca Giorgi, Eleonora Macedi, Mauro Micheloni, Paola Paoli, Patrizia Rossi “Pd(II)

and Pt(II)

complexes with a thio-aza macrocycle ligand

containing an intercalating fragment: Structural and antitumor activity studies”, J. Inorg. Biochem., 2016, 162, 154-161


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MAURO SERGIO MICHELONI - uniurb.it · Curriculum Vitae and Publications of Mauro Sergio Micheloni 5...

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