Maths and Chemistry chapter
-
Upload
gosia-garkowska -
Category
Education
-
view
496 -
download
2
description
Transcript of Maths and Chemistry chapter
MATHS AND
CHEMISTY
Page 2
THIS EBOOK WAS PREPARED
AS A PART OF THE COMENIUS PROJECT
WWHHYY MMAATTHHSS??
by the students and the teachers from:
BERKENBOOM HUMANIORA BOVENBOUW, IN SINT-NIKLAAS ( BELGIUM)
EUREKA SECONDARY SCHOOL IN KELLS (IRELAND)
LICEO CLASSICO STATALE CRISTOFORO COLOMBO IN GENOA (ITALY)
GIMNAZJUM IM. ANNY WAZÓWNY IN GOLUB-DOBRZYŃ (POLAND)
ESCOLA SECUNDARIA COM 3.º CICLO D. MANUEL I IN BEJA (PORTUGAL)
IES ÁLVAREZ CUBERO IN PRIEGO DE CÓRDOBA (SPAIN)
This project has been funded with support from the European Commission.
This publication reflects the views only of the author, and the
Commission cannot be held responsible for any use which may be made of the
information contained therein.
Page 3
II.. MMAATTHHSS AAPPPPLLIIEEDD TTOO CCHHEEMMIISSTTRRYY
IIII.. BBAALLAANNCCIINNGG CCHHEEMMIICCAALL EEQQUUAATTIIOONNSS
IIIIII.. HHOOWW TTOO CCAALLCCUULLAATTEE DDEENNSSIITTYY
IIVV.. PPEERRCCEENNTTAAGGEE CCOOMMPPOOSSIITTIIOONN
VV.. DDEETTEERRMMIINNIINNGG EEMMPPIIRRIICCAALL AANNDD MMOOLLEECCUULLAARR FFOORRMMUULLAASS
VVII.. CCOONNCCEENNTTRRAATTIIOONN BBYY PPEERRCCEENNTT
VVIIII.. PPHH AANNDD LLOOGGAARRIITTHHMMSS
Page 4
Math is everywhere. It is an universal language which everyone needs. We use math
every day, everywhere and anytime. We use it automatically. It can be applied in simple tasks,
like figuring out how many time you have until your next class, or in long and complicated
tasks, for example doing your tasks.
Chemists use math for a variety of tasks. We balance the equation of a chemical
reaction, use mathematical calculations that are absolutely necessary to explore important
concepts in chemistry, and utilize dimensional analysis to find any range of information
about reactions from finding the mass of chemicals reacted to the concentration of a chemical
in a solution. Math is also used to calculate energy in reactions, compression of a gas, grams
needed to add to a solution to reach desired concentration, and quantities of reactants needed
to reach a desired product. It is important to know how to mathematically handle chemistry
problems in order to understand what they mean and how to prepare specific quantities of
chemicals.
Math applied to Chemistry
Overall and simpler operations
Math and chemistry are closely linked. We practically need mathematical operations to
do everything in chemistry. Sum, subtraction, division and multiplication are essential things
we need to know before starting to think about being a chemist. Other operations, like the
simple rule of three and proportions, are basic tools you need to know before starting to study
chemistry. Have no doubt that those are key components to have success in chemistry.
Ex:
If there’s 1 mol of Cl in one molecule of NaCl how many moles are in 5 molecules of NaCl
1 1
5 x
x = 5 mol
We used the simple rule of three to figure out the chemical quantity of sodium in 5
molecules of sodium chlorite NaCl.
Page 5
Take chemistry out of the equation
Equations are perhaps the most important math principal you need to learn. We use all
kinds of equations in chemistry.
Ex: N = n x NA
A = Z + N
Eradiation = Eremoval + Ekinetics
If you need to succeed in chemistry you need to know how to make all kinds of
equations.
Different sizes, different views
Chemists transform very often some units of measure into others, according to the
variables of the experiment. To do this they need math. For example, to transform meters in
light-years we use this formula:
1 l.y. = 9.47 ·1015 m
Another example is changing Celsius to Kelvin, two units to measure temperature.
T(K) = T(ºC) + 273
Measuring
To measure a certain object you need math. If you measure it directly, which means
you are there measuring at the spot, you need to know the units therefore you need math. If
you are measuring it indirectly, through an equation or an expression, you also need math
because you need to know how to solve them. Here are some examples:
Directly:
What is the length of the book?
Page 6
To measure the length of the book you need to know which unit is the ruler. Of course
it is probably cm and you know this without thinking, but that happens because you learn it
in math class.
Indirectly:
A certain object has a weight of 210 g and a volume of 20 mL. Calculate the density of
the object.
Solution: p = m : V (=)
(=) p = 10,5 g/mL
In this case, we are using an equation to measure a chemical greatness (density).
Scientific Notation
There are certain greatness’s used in chemistry that are too big or too small to
represent the full number. So in chemistry is frequently used something we learn in math,
scientific notation. For example, to represent the number of meters in one parsec we use this
number 3.09·1016m because it’s too big. However to represent mercury’s ionization energy we
use this number 1,21·10-18 J/e.
Also, operations with numbers in scientific notation is commonly used in chemistry-
Ex: In the hydrogen atom, an electron “jumps” from the first level of energy to the
second one. Determine the energy of the photon necessary for this transition to happen.
Resolution: Ef = E2 – E1
Page 7
Avogadro’s number
Fractions
Scientific notation is not the only form of number representation used in chemistry.
Fractions were invented by mathematicians and now is commonly used in chemistry to
represent exact numbers.
Ex: 1:3 = 0.(3)
Statistics
Sometimes it’s used in chemistry charts, tables, graphics, and averages, among others.
Are often used to organize a very large group or to determine or register something’s
behavior. A much known example of the use of statistic in chemistry is the Periodic Table.
The Periodic Table is a table (concept taken from math) that contains every known chemical
element in the world, organized by their atomic number and with some of the atom’s
properties. In this case chemists used statistic to have an organized and easy way to access
information. Another common use for statistics is graphics. Chemists regularly use graphics
to predict or register something’s behavior. For example, it is used a line graphic to register
the several ionization energies of the first 20 elements of the Periodic Table.
We can use line graphics but we can also use other types. It’s frequently used bar
graphs to represent and understand better the evolution of the Earth’s atmosphere.
Diagrams is another concept that is very used in chemistry, especially when trying to
explain an argument. It is sometimes easier to understand when is summarized in a diagram.
These are the forms of data representation. However, are used calculus learnt in
statistics. A common example is average. In chemistry is used to calculate the relative isotopic
mass or to compare results.
In conclusion, knowing statistics is very important in chemistry.
Page 8
In conclusion
To study chemistry, we need math. It is inevitable. Math is an essential part of the
human knowledge, we can’t live without it.
You can also watch the presentation prepared by the Portuguese student here: LINK
Page 9
Picture from: www.wyckoffps.org
Balancing chemical equations
Stoichiometry - is a branch of chemistry that deals with the relative quantities of reactants
and products in chemical reactions. Stoichiometry is the mathematics behind the science of
chemistry.
A chemical equation is an easy way to represent a chemical reaction—it shows which
elements react together and what the resulting products will be. By the Law of Conservation
of Mass, the number of atoms must be the same on both sides because these atoms cannot be
created or destroyed in a reaction.
The number of atoms that we start with at the beginning of the reaction must equal the
number of atoms that you end up with.
When the number of atoms of reactants matches the number of atoms of products, then the
chemical equation is said to be balanced.
We would like to present a simple method of defining the coefficients in the equations of
chemical reactions with the help of a system of linear algebraic equations that describes the
material balance in a chemical reaction.
Example 1:
CH4 + O2 → CO2 + H2O
I. First we use each element to produce an equation involving the
coefficient letters. We need to find the smallest possible positive
integers a, b, c, and d such that the following chemical equation.
aCH4 + bO2 → cCO2 + dH2O
is balanced.
Carbon: a = c There is 1 carbon atom in the a term and 1 in the c term.
Hydrogen: 4a = 2d There are 4 hydrogen atoms in the a term and 2 in the d term.
Oxygen: 2b = 2c + d There are 2 oxygen atoms in the b term and 2 in the c term
and 1 in the d term.
II. As a result we get a system of three linear equations with four unknowns:
Page 10
Picture from: www.earthtimes.org
III. This system has an infinite number of solutions, but we have to get the minimal
natural values only. Since we would like the smallest integral solutions, = 1 works
well.
The system has the following solution - the coefficients are = 1, = 2, = 1 and = 2
When writing our balanced equation, the coefficient 1 is assumed and can be omitted,
yielding the formula:
CH4 + 2O2 → CO2 + 2H2O
The balanced chemical equation has one mole of methane reacting with two moles of oxygen
gas to form one mole of carbon dioxide and two moles of water.
Example 2:
Plants use the process of photosynthesis to convert carbon
dioxide and water into glucose and oxygen. This process helps
remove carbon dioxide from the atmosphere. Balance the
following equation for the production of glucose and oxygen
from carbon dioxide and water.
CO2 + H2O → C6H12O6 + O2
This equation needs to be balanced. We must find coefficients
a, b, c and d in the reactants and products - rewrite the
equation as:
aCO2 + bH2O → cC6H12O6 + dO2
where the numbers of carbon, hydrogen, and oxygen atoms are the same on both sides of the
equation:
Carbon: a = 6c
Oxygen: 2a + b = 6c + 2d
Hydrogen: 2b = 12c
Since we would like the smallest integral solutions, = 6 works well and the coefficients are
= 6, = 6, = 1 and = 6
Page 11
Picture from: www.commons.wikimedia.org
Examples of Balancing Chemical Equations
Consider the unbalanced reactions.
1. FeCl3 + NH4OH → Fe(OH)3 + NH4Cl
Assign each molecule a variable a, b, c, d since we have 4 expressions in the reaction
We need to find the smallest possible positive integers a, b, c, and d such that the following
chemical equation.
aFeCl3 + bNH4OH → cFe(OH)3 + dNH4Cl
We can obtain a set of linear equations in these variables by considering the number of times
each type of atom occurs on each side of this equation
1) Fe: a = c There is 1 iron atom in the a term and 1 in the c term.
Cl: 3a = d There are 3 chlorine atoms in the a term and 1 in the d term
N: b = d There is 1 nitrogen atom in the b term and d in the c term
H: 5b = 3c + 4d There are 5 hydrogen atoms in the b term and 3 in the c term
and 4 in d term.
O: b = 3c There is 1 oxygen atom in the a term and 1 in the c term
2) As a result we will get a system of five linear equations with four unknowns:
3)
4)
FeCl3 + 3NH4OH → Fe(OH)3 + 3NH4Cl
2. aNaCl + bSO2 + cH2O + dO2 → eNa2SO4 + f HCl
From this equation we obtain the following relations in the unknowns a, b, c, d, e, and f:
1) Na: a = 2e
Cl: a = f
Page 12
S: b = e
O: 2b + c + 2d = 4e
H: 2c = f
2)
3)
4)
To calculate the smallest possible positive integer value of a, we have to find the least
common denominator of b, c, d, and e which in this case is 4. If we work out the above
equations we calculate the values of our 5 variables to be:
For a = 4 we have:
b = 2
c = 2
d = 1
e = 2
f = 4
4NaCl + 2SO2 + 2H20 + 02 → 2Na2SO4 + 4 HCl
3. aCaCO3 + bHNO3 → cCa(NO3)2 + dH2O + eCO2
Specifying the values a, b, c, d and e for the coefficients of this equation we have:
1) Ca: a = c
Page 13
Picture from:
www.chemistrysmostwanted.wikispaces.com
C: a = e
H: b = 2d = 2a
N: b = 2c = 2a
O: 3a + 3b = 6c + d + 2e
Solving simultaneously and using the smallest integers we have
1)
2) For a = 1
b = 2a = 2
c = a = 1
d = a = 1
e = a = 1
CaCO3 + 2 HNO3 → Ca(NO3)2 + H2O + CO2
How is marble eroded by acid rain? Atmospheric sulfur dioxide
combines with rainwater to create sulfurous acid. The primary
component of marble is calcium carbonate (CaCO3). The sulfurous
acid reacts with the CaCO3 in the marble and dissolves it. Marble
statues (CaCO3) attacked by acid rain (containing HNO3).
4. aHCl + bK2CO3 → cCO2 + dH2O + eKCl The equation for each atom looks like:
1) H: a = 2d d =
Cl: a = e
K: 2b = e b =
C: b = c c =
O: 3b = 2c + d
So we have now after some canceling:
2) b =
c =
Page 14
d =
e =
For a = 2 we have:
3) b = 1 c = 1
d = 1
e = 2
2HCl + K2CO3 → CO2 + H2O + 2KCl
Page 15
How to calculate density
Density is a characteristic property of a substance. The density of
a substance is the relationship between the mass of the substance and how
much space it takes up (volume). The density, or more precisely, the
volumetric mass density, of a substance is its mass per unit volume.
Mathematically, density is defined as mass divided by volume :
v
m
volume
massd
To calculate the specific gravity (S.G.) of an object, you compare the object's
density to the density of water.
Examples of densities:
Solids: Liquids: Gases:
Silver = 10.49 Milk = 1.020-1.050 Air = 0.001293
Aluminum = 2.7 Glucose = 1.350-1.440 Argon = 0.001784
Diamond = 3.01-3.25 Glycerine = 1.259 Chlorine= 0.0032
Gold = 19.3 Flourine = 0.001696
Magnesium = 1.7 Helium = 0.000178
Platinum = 21.4 Neon = 0.0008999
Example 1
Calculate the density of the cube made of silver, whose weight is 262.5 grams and the volume
is 25 cm ³.
Given: Calculate
m = 262.5 g d = ?
V = 25 cm³
1 d =
Answer: Density of silver is 10.5
.
Example 2
There is 250 cm ³ of ethyl alcohol in the glass vessel. The volume of alcohol is 0.197 kg
Calculate the density of alcohol and enter the result in grams per cubic centimeter.
Given: Calculate:
m = 0.197 kg d = ?
V = 250 cm³
1 m = 0.197kg= 0.197 g
Page 16
Picture from: www.bonnibrodnick.com
2 d =
The density of ethyl alcohol is 0.79
Example 3
Calculate the mass of 300 cm³ gasoline which density is 0.75
.
Given: Calculate:
V = 300 cm³ m = ?
d = 0.75
1 d =
m = d V
2 m = 0.75
300cm³ = 225 g
Answer: The mass of gasoline is 225g.
Example 4
A container of volume 0.05m3 is full of ice. When the ice melts into water, how many kg of
water should be added to fill it up? (density of ice = 900
; density of water = 1000
)
Given: Calculate:
dice = 900
mwater = ?
dwater = 1000
Vice = 0.05 m³
1 mice = d V
mice =
2
We should add 5 kg of water to fill the container up.
Example 5
A rubber ball has a radius of 2.5 cm. The density of rubber is 1.2
. What is the mass of the
ball?
Given: Calculate:
r = 2.5 cm m = ?
d = 1.2
1 First we calculate the volume of a ball:
2
Answer: The mass of the ball is about 78.5 g.
Page 17
Example 6
A 5.6-gram marble put in a graduated cylinder raises the water from 30 mL to 32 mL. What is
the marble’s density?
Given: Calculate:
m = 6g d = ?
1 First we calculate the volume of marble:
2
d =
The density of marble is
.
Example 7
A small rectangular slab of lithium has the dimensions 20.9 mm by 11.1 mm by 11.9 mm. Its
mass is 1.49·103 mg. What is the density of lithium in
?
Given: Calculate:
a = 20.9 mm = 2.09 cm d = ?
b = 11.1 mm = 1.11 cm
c = 11.9 mm = 1.19 cm
m = 1.49·103 mg = 1490 mg = 1.49 g
1
V
2
d =
The density of lithium is 0.53
.
Example 8
Find the mass of air inside a room measuring 10m×8m×3m, if the density of air is 1.28
.
Given: Calculate:
a = 10m m = ?
b = 8m
c = 3m
d = 1.28
1
V
2
m = d V
m =
The mass of the air inside the room is
2mL
Page 18
Picture from:www.monarchbearing.com
Example 9
You have two stainless steel balls. The larger has a mass of 25 grams
and a volume of 3.2cm3. The smaller has a mass of 10 grams.
Calculate the volume of the smaller ball.
Given: Calculate:
m1 = 25g V2 = ?
V1 = 3.2cm3
m2 = 10g
1
dsteel =
2
V2 =
=
The volume of the smaller ball is
Since density is a characteristic property of a substance, each liquid has its
own characteristic density. The density of a liquid determines whether it
will float on or sink in another liquid. A liquid will float if it is less dense
than the liquid it is placed in. A liquid will sink if it is more dense than the
liquid it is placed in.
Example 10
A rectangular object is 10 centimeters long, 5 centimeters high, and 20 centimeters wide. Its
mass is 800 grams. Will the object float or sink in water? Remember that the density of water
is about 1
.
Given: Calculate:
a = 10cm d = ?
b = 5cm
c = 20cm
m = 800g
1
V
2 d =
The object will float.
Page 19
carbon oxygen
carbon hydrogen oxygen
Picture from: www.annekeckler.com
Percentage composition
Percentage composition is just a way to describe what
proportions of the different elements there are in a
compound.
If you have the formula of a compound, you should be
able to work out the percentage by mass of an element
in it.
%Composition A=
Example 1
What is the percentage composition of carbon and oxygen in
?
First we need to find the mass of the compound.
Molar mass of compound: 12.01+ 2
Next we need to find the mass of carbon and oxygen in the
compound.
Molar mass of carbon: 12.01
Molar mass of oxygen: 32
Then we should divide the mass of each element by the mass of
the compound and multiply by 100%.
The percentage composition of carbon is:
%C =
The percentage composition of oxygen is:
% O =
72.71%
Example 2
What is the percentage composition by mass of the elements in
the compound
We start by finding the atomic weights.
Molar mass of C: = 12.01
Molar mass of H: = 1.01
Molar mass of O: = 16.00
Work out the molecular weight of glucose: 6 12.01 + 12 1.01 + 6 16 = 180
Page 20
potassium chromium oxygen
Picture from: www.commons.wikimedia.org
Picture from: www.aromaticscience.com
Mass of carbon: 6 12.01 = 72.06
Mass of hydrogen: 12 1.01 = 12.12
Mass of oxygen: 6 16 = 96
The percentage composition of carbon is:
The percentage composition of hydrogen is:
The percentage composition of oxygen is:
Examples 3
What is the percentage composition of chromium in ?
Molar mass of compound: 2 39 + 2 52 + 7 16 = 249
Molar mass of chromium:
The percentage composition of Cr is:
Examples 4
What is the percentage by mass of nitrogen in ammonium nitrate, NH4NO3 an important
source of fertilizer?
Molar mass of N: = 14.01
Molar mass of compound: 2 + 4 + 3 16 =
The percentage composition of nitrogen is:
The percentage composition of N is 35%
Examples 5
Cinnamaldehyde, C9H8O, is responsible for the characteristic
odour of cinnamon. Determine the percentage composition of
cinnamaldehyde by calculating the mass percents of carbon,
hydrogen, and oxygen.
The molecular formula of cinnamaldehyde is C9H8O.
Molar mass of C: = 12.01
Page 21
Molar mass of H: = 1.01
Molar mass of O: = 16.00
First we calculate the molar mass of cinnamaldehyde:
12.01 + 8 1.01 + 16 = 132.17
Mass of carbon: = 9 12.01 = 108.09
Mass of hydrogen: = 8 1.01 = 8.08
Mass of oxygen: = 16
The percentage composition of carbon is:
The percentage composition of hydrogen is:
The percentage composition of oxygen is:
Page 22
Determining empirical and molecular formulas
The empirical formula is the simplest formula for a compound. A molecular formula is the
same as or a multiple of the empirical formula, and is based on the actual number of atoms of
each type in the compound. For example, if the empirical formula of a compound is C3H8 , its
molecular formula may be C3H8 , C6H16 , etc.
An empirical formula is often calculated from elemental composition data. The weight
percentage of each of the elements present in the compound is given by this elemental
composition.
Using basic mathematics skills like ratio, percentage, linear equations and system of linear
equations we can determine the empirical formula of an unknown compound from its atomic
masses and percent composition.
Example 1
Analysis of a compound gives 30.43 % N and 69.57% O. The mass for this compound is 92u.
What is its molecular formula?
Given Find
Formula:
%N = 30.43%
%O = 69.57%
Molar mass of N: = 14
Molar mass of O: = 16
First method
We assume that the molecular weight is 100% and calculate the mass of nitrogen
It means that 28 in the compound is for the atoms of nitrogen and the rest:
92 - 28 = 64 is for the oxygen.
The numbers of atoms in the compound is:
atoms of N
atoms of O
The formula is .
Picture from: www.chem4kids.com
Page 23
Second method
In the second method we use the system of linear equations.
First equation: Second equation:
The formula molecular is .
Empirical Formula Calculation Steps
Step 1
If we have masses go onto step 2.
If we have %. Assume the mass to be 100g, so the % becomes grams e.g. 40% of a compound
is carbon. 40% of 100 g is 40 grams.
Step 2
Determine the moles of each element.
Step 3
Determine the mole ratio by dividing each elements number of moles by the smallest value
from step 2.
Pictu
re from
:ww
w.co
mm
on
s.wik
imed
ia.o
rg
Page 24
Step 4
Round your ratio to the nearest whole number as long as it is “close.” For example, 1.99987
can be rounded to 2, but 1.3333 cannot be rounded to 1. It is four-thirds, so we must multiply
all ratios by 3 to rid ourselves of the fraction. If we have the empirical formula C1.5H3O1 we
should convert all subscripts to whole numbers, multiply each subscript by 2. This gives us
the empirical formula C3H6O2. Thus, a ratio that involves a decimal ending in .5 must be
doubled. We should double, triple to get an integer if they are not all whole numbers.
Example 2
A sulfide of iron was formed by combining 2.233 g of Fe with 1.926 g of S calculate the
empirical formula.
Molar mass of iron: = 55.85
Molar mass of sulfur: = 32.1
1 Mass of iron: = 2.233g
Mass of sulfur: = 1.926g
2 Convert masses to amounts in moles
Numbers of moles of iron:
Numbers of moles of sulfur:
3 Divide these numbers of moles by the smallest number (0.03998 in this case)
Fe ⇒
S ⇒
Preliminary formula is:
Now we should multiply to get a whole number. In order to turn 1.5 into a whole number, we
need to multiply by 2 – therefore all results must be multiplied by 2.
The simplest formula is:
Example 3
Find the empirical formula for a compound containing 36.5% sodium, 25.4% sulfur and
38.1% oxygen.
Molar mass of sodium Na: = 23
Molar mass of sulfur S: = 32.1
Molar mass of oxygen O: = 16
·2
Page 25
1
We assume that we have 100g of total material, and % becomes grams
Mass of sodium: = 36.5g
Mass of hydrogen: = 25.4g
Mass of oxygen: = 38.1g
2 Convert masses to amounts in moles
Numbers of moles of sodium:
Numbers of moles of sulfur:
Numbers of moles of oxygen:
3 Divide these numbers of moles by the smallest number (0.79 in this case)
Na ⇒
S ⇒
O ⇒
The formula is sodium sulfite.
Example 4
The composition of ascorbic acid (vitamin C) is 40.92% carbon, 4.58%
hydrogen, and 54.50% oxygen. What is the empirical formula for vitamin C?
Molar mass of carbon C: = 12.01
Molar mass of hydrogen H: = 1.01
Molar mass of oxygen O: = 16
1
We are only given mass %, and no weight of the compound so we will assume 100g of the
compound, and % becomes grams
Mass carbon = 40.92g
Mass hydrogen = 4.58g
Mass oxygen = 54.5g
Pictu
re from
:ww
w.h
lylh
g.co
m
Page 26
Picture from:www:rippedclub.net
2 Convert masses to amounts in moles
numbers of moles of carbon:
numbers of moles of hydrogen:
numbers of moles of oxygen:
3 Divide these numbers of moles by the smallest number (3.4 in this case)
C ⇒
H ⇒ 4.533.4=1.33 O ⇒ 3.43.4=1
Preliminary formula is:
Multiply to get a whole number. In order to
turn 1.33 into a whole number, we need to
multiply by 3 – therefore all results must be
multiplied by 3
The simplest empirical formula of vitamin C is
C3H4O3
Example 5
Muscle soreness from physical activity is caused by a buildup of
lactic acid in muscle tissue. Analysis of lactic acid reveals it to be
40.0% carbon, 6.7% hydrogen, and 53.3% oxygen by mass. Its molar
mass is 90.088
. What are the empirical and molecular formulas?
Molar mass of carbon C: = 12.01
Molar mass of hydrogen H: = 1.01
Molar mass of oxygen O: = 16
1
We are only given mass %, and no weight of the compound so we will assume 100g of the
compound, and % becomes grams
Mass carbon = 40g
Mass hydrogen = 6.7g
Mass oxygen = 53.3g
2 Convert masses to amounts in moles
numbers of moles of carbon:
·3
Page 27
numbers of moles of hydrogen:
numbers of moles of oxygen:
3 Divide these numbers of moles by the smallest number
C ⇒
H ⇒
O ⇒
The empirical formula of lactic acid C is C1H2O1
4 Next we calculate the empirical formula weight: 12.01 + 21.01+ 16 = 30.03
5 Divide the molecule weight 90.08
by the empirical formula weight
The molecular formula of lactic acid is C3H6O3.
Example 6
A compound is found to contain 50.05 % sulfur and 49.95 % oxygen by weight. The molecular
weight for this compound is 64.07
. What is its molecular formula?
Molar mass of sulfur S: = 32.1
Molar mass of oxygen O: = 16
1 First we will find the empirical formula. We assume 100 g of the compound is present and
change the percents to grams:
Mass sulfur = 50.05g
Mass oxygen = 49.95g
2 Then we convert the masses to moles:
Numbers of moles of sulfur:
Numbers of moles of oxygen:
3 Divide by the lowest, seeking the smallest whole-number ratio:
S ⇒
O ⇒
4 And now we can write the empirical formula: SO2
5 Next we calculate the empirical formula weight
32 + 216 = 64
Page 28
6 Divide the molecule weight by the empirical formula weight
7 Use the scaling factor computed just above to determine the molecular formula:
SO2 times 1 gives SO2 for the molecular formula.
Example 7
An analysis of nicotine, an addictive compound found in tobacco leaves, shows that it is
74.0% C, 8.65% H, and 17.35% N. Its molar mass is 162 g/mol. What are its empirical and
molecular formulas?
Molar mass of carbon C: = 12.01
Molar mass of hydrogen H: = 1.01
Molar mass of nitrogen N: = 14
1
We assume 100g of the compound, and % becomes grams
Mass carbon = 74g
Mass hydrogen = 8.65g
Mass nitrogen = 17.35g
2 Convert masses to amounts in moles
Numbers of moles of carbon:
Numbers of moles of hydrogen:
Numbers of moles of nitrogen:
3 Divide by the lowest, seeking the smallest whole-number ratio:
C ⇒
O ⇒
N ⇒
4 And now we can write the empirical formula:
5 Next we calculate the empirical formula weight
5·12.01 + 71.01+ 14 = 81.12
Page 29
Picture from:www.previewcf.turbosquid.com
6 Divide the molecule weight by the empirical formula weight
The molecular formula of nicotine is .
Page 30
Concentration by percent
Medicated syrup is an example of
the concentration.
Brine and syrup
Brine is a concentrated solution of sodium chloride in
water.
In Poland we use brine to prepare our special
cucumbers - gherkins.
Syrup is a concentrated solution of sugar in water.
Example of syrup is fruit syrup
Calculating concentration of a chemical solution requires basic math skills like knowing percentage,
equations or system of equations.
Solutions are homogeneous mixtures of solute and solvent.
Solvent - the most abundant substance in a solution. In a liquid solution, the solvent does the
dissolving.
Solute - the other substance in a solution. In a liquid solution, the solute is dissolved.
Concentration refers to the amount of solute that is dissolved in a solvent. The concentration
of a solution in percent can be expressed in two ways: as the ratio of the volume of the solute
to the volume of the solution or as the ratio of the mass of the solute to the mass of the
solution.
To calculate percent concentration we use a formula:
The mass percent of a solution is a way of expressing its concentration. Mass percent is found by
dividing the mass of the solute by the mass of the solution and multiplying by 100; e.g. a solution of
NaOH that is 28% NaOH by mass contains 28 g of NaOH for each 100 g of solution.
Picture from: www.styl.pl
Page 31
Example 1:
Calculate concentration of sugar in compote. For every kilogram of fruits
you need syrup made from 0.4 liter of water and 0.4 kilogram of sugar.
Given Calculate
mwater = 0.4L= 400g Cp = ?
mfruit = 0.4kg= 400g
msyrup = 400g+ 400g= 800g
Answer: Concentration of syrup is 50%.
Example 2:
We mingled 200L milk which contain 2% butterfat and 50L milk which contain 4% butterfat.
Calculate final percent concentration in milk.
Given: Calculate
Cp = ?
1
2
Answer: We got 2.4% milk.
Example 3
A bottle of the antiseptic hydrogen peroxide H2O2 is labeled 3%. How
many mL H2O2 are in a 473 mL bottle of this solution?
Given: Calculate
Cp = 3%
1
Answer: There are about 14.2mL of H2O2 in a bottle of this solution.
Pictu
re from
:ww
w.n
et/hum
an
-medica
tion
s-to-g
ive-at-h
om
e
Page 32
Example 4
How many grams of salt do you need to make 500
grams of a solution with a concentration of 5% salt?
Given Calculate
Cp = 5% msolute = x ?
msolution =500g
msolute = x = 25g
Answer: We need 25g of salt.
Example 5
How many grams of water must be evaporated from 10 grams of a 40% saline solution to
produce a 50% saline solution?
Given Calculate
x the amount of evaporated water
( in grams)
The amount of salt in the beginning and after the evaporation of water is the same,
Answer: 2 grams of water must be evaporated from the 40% saline solution.
Pictu
re from
:ww
w.b
log.fa
rwestclim
ateco
ntrol.com
In the beginning In the end
10g of solution
40%·10 the
amount of salt
(10-x) of solution
50%·(10-x) the
amount of salt
x g of water
Page 33
Example 6
How many grams of salt must be added to 30kilos of a 10% salt solution to increase the salt
concentration to 25%. How many kilos of salt were added?
Given Calculate
x the amount of added salt ( in kilos)
The amount of water in the beginning and after adding salt is the same.
Answer: 0.6 kilograms of salt must be added to the solution to increase the salt
concentration.
To solve word problems involving percent concentration amounts, knowledge of solving
systems of equations and percents is necessary. Below there are some percent
concentration problems involve solving systems of equations when mixing two liquids with
differing percent concentration amounts.
Example 7
A 16% salt solution is mixed with a 4% salt solution. How many milliliters of each solution are
needed to obtain 600 milliliters of a 10% solution?
The table below help us organise information.
Amount of
solution
(in mL)
Percent Total
16% salt solution x 0.16 0.16x
4% salt solution y 0.4 0.4y
mixture x + y = 600 0.10 0.10·600 = 60
The liters of salt solution from
the 16% solution, plus the liters
of acid in the 30% solution, add
up to the liters of acid in the
10% solution
The first column is for
the amount of each
item we have.
In the beginning In the end
30kg of solution
10%·30 the
amount of salt
90%·30 the
amount of water
(30+x) of solution
25%·(30+x) the
amount of salt
75%·(30+x) the
amount of salt
x g of salt
Page 34
Answer: 300mL of these solutions are needed to obtain 600 milliliters of a 10% solution.
Example 8
How much 10% sulfuric acid (H2SO4) must be mixed with how
much 30% sulfuric acid to make 200 milliliters of 15% sulfuric
acid?
Let's organise the information in the table
Volume Percent Amount of salt
10% sulfuric acid x 0.10 0.1x
30% sulfuric acid y 0.30 0.3y
mixture x + y = 200 0.15 0.15·200 = 30
Now that the table is filled, we can use it to get two equations. The "volume" and "amount of
acid" columns will let us get two equations.
Since x + y = 600, then x = 600 – y.
We can substitute for x in our second equation, and eliminate
one of the variables
Since x + y = 200, then x = 200 – y.
The liters of sulfuric acid from
the 10% solution, plus the
liters of acid in the 30%
solution, add up to the liters of
acid in the 15% solution
The first column is for
the amount of each
item we have.
Page 35
Answer: 150mL 10% sulfuric acid must be mixed with 50mL 30% sulfuric acid to make 200
milliliters of 15% sulfuric acid.
We can substitute for x in our second equation, and eliminate
one of the variables
Page 36
PH AND LOGARITHMS
WHAT IS pH?
SOME INFORMATION ABOUT pH
PH is the scale of the measure of acidity and basicity of a liquid
solution, based on the concentration of positive ions and negative
ions.
The term "PH" was introduced in 1909 by the Danish chemist
Soren Sorensen.
The PH's scale goes from 0 to 14. 0
stands for the maximum acidity (for
example hydrochloric acid), 14 stands
for the maximum basicity (so it is
sodium hydroxide). The medium
value is 7 and it belongs to distilled
water at the temperature of 25°C and
stands for a neutral solution.
The traditional indicator for PH is the
litmus test, a special paper that turns
from green to red immersed in an acid
solution. At the contrary in a basic
solution the paper turns from green to
dark blue.
Page 37
WHAT IS pOH?
The pOH scale calculates the concentration of OH ions in a liquid solution. It is the exact
opposite of the pH and they are complementary. The logarithmic function of one completes
the one of the other too.
WHAT IS A LOGARITHM?
It defines logarithm in basis a of a number N the exponent it has to give to a to get the
number N (N is called the argument of the logarithm).
CONNECTION BETWEEN LOGARITHMS AND PH
We have already given a definition of the pH, but it can be given another definition linked to
the logarithms. In fact the pH is the negative logarithm to the base 10 of the concentration of
H+ ions (the same definition is right for the pOH). So the pH grows and shrinks in a
logarithm scale, while at the opposite the pOH shrinks and grows complementary.
Page 38
Example
Calculate the pH of 0.06 mol/L HCl.
pH = −log0.06 = 1.22
You can see some examples how to calculate ph and about oxidation numbers and vectors
watching the presentation prepared by the Belgian students here: LINK
Page 39
Links:
www.en.wikipedia.org
www.bbc.co.uk/schools/gcsebitesize/science/
www.towson.edu
Page 40