Materials Characterization by Positron Annihilation ...
Transcript of Materials Characterization by Positron Annihilation ...
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Materials Characterization by Positron Annihilation Spectroscopy
– A Canadian Perspective
Peter Mascher
Department of Engineering Physics and
Centre for Emerging Device TechnologiesMcMaster University
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Outline
The Pioneers and Their Contributions
The Next Generation
The Future Outlook for Positrons in Canada
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Positron Annihilation in Canada – The Pioneers
Innes K. MacKenzie †Jules Carbotte †
Alec T. Stewart †
Steen Dannefaer
Don Kerr †
Ben Hogg †
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Fundamental Positron Theory
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Momentum Distribution by Positron ACAR
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Vacancies in Metals
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Vacancy Formation Enthalpies - Metals
Aluminum
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Early Positron Studies at Winnipeg
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Positron Lifetimes in Semiconductors
H. Siethoff, phys. stat. sol. (b) 205 R3 (1998)
ZnO
G. Tessaro and P. Mascher, J. Cryst. Growth 197, 581 (1999)
CdTe
ZnTe
ZnSe
ZnS
M. Martyniuk and P. Mascher, Physica B 308-310, 924 (2001)
W. Puff and P. Mascher, J. Phys. F 14, L231 (1984)
>
>
M. Puska et al., PRB 39, 7666 (1989)
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ICPA-14 McMaster University, July 2006
http://icpa.mcmaster.ca
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Positron Annihilation in Canada – The Next Generation
Peter J. Schultz
Peter J. Simpson
Peter Mascher Andy Knights
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The First Canadian Positron Beam
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The Positron Beam Facility at Western
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C.R. Mokry, P.J. Simpson, and A.P. Knights, JAP 105, 114301 (2009)
90 keV Si- ions; 1.4x1017 cm-2
430 nm SiOx w/ 20% excess Si
Annealed at 1070C for 3 hrs
1 2 3 4 5 6 7 8 9 100.95
0.96
0.97
0.98
0.99
1.00
1.01
1.02
Bulk SiliconSiO2
40030020015010050
Mean Depth (nm)
No
rma
lize
d S
-Pa
ram
ete
r
Energy
Reference Si/SiO2
As-implanted
10 s 1170°C in N2
30 min 1170°C in N2SRIM
PAS
TEM
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Positron Beams on the Move
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The McMaster Intense Positron Beam Facility (MIPBF)Project Team
Peter Mascher Project Leader
Chris Heysel MNR
Scott McMaster Beam Delivery System
Andrew P. Knights, Peter J. Simpson Defect Probe
Cody Storry Positron Storage and
Interaction
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MNR Overview • Full containment
• Negative pressure
• MTR-type
• Swimming pool
• Forced downflow
• Licensed to 5 MWth
• Normally operated at 3 MWth
• 16 hours/day, 2 shifts, 5 or 6
days/week
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In the core, gas chambers are inserted daily for medical isotope production and radial
beam ports with direct access to the core (20cm diam ports)
Beam ports:
1 Radiography (industrial)
2 Radiography (industrial)
3 Radiography (research)
4 Prompt-gamma neutron
activation analysis
5 low energy e+ Beam
6 Neutron Scatteringe+ beam
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McMaster Intense Positron Beam Facility (MIPBF)
e+/e-Pair-
production
in Pt foil
e+ transport in
H2O pool
neutron
absorber,
biological shield
e+ 4-way beam switch
e+ beam lines (0.02T, KV)
Reactor
beam
monitor and
e- gun Buffer gas
accumulator
Accumulator/
experiment
electronics
Helium Compressors
and big power supplies
in mechanical room
De
fect
pro
be
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Edge of
reactor
core
Platinum foils:
gammas in foil
produce e+/e- pairs.
~15cm diameter.
Solenoid (>0.01 Tesla) to guide low energy e+ out of pool
Passively cooled by air (requirements at the reactor)
e+ Production Foils Near Reactor Core
Water (pool)
Air
vacuum
Thermal e+
accelerated by
applied potentials on
foils and a drift tube
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e+
MIPBF Vacuum System
Setup for e+ on decay power
Mid section view
Production region
Pt is 2.5” from core
tube
Flange coil
Potential
Flange coil
Detector 1
Detection cone
Detector 2
Detection region
Hat coil Main coil
Pt electrode Potential tube
e+
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y=a*Exp[x/b]-aa = 0.09
a)= 120
b)
a) Simulation of 5000 e+ starting from the platinum at varying energies and
curve as a merit to compare to experimental data.
various S-bend axial magnetic fields. For <200G S-bend fields used, the
detected e+ have <100keV of kinetic energy. b) The area under each field
b±0.02±10 G
200G
Varying
current at S-
Bend
200G
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a = 2.6±0.3 /s
Measured e+ coincidence rate for varying S-bend axial magnetic fields
Main solenoid = 200G
Short solenoid = 200G
200G
Varying
current at S-
Bend
200G
y=a*Exp[x/b]-a
b = 129±8 G ⬅ consistent with model
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~10ev e+
8eV width
● Ideal for nitrogen buffer gas trapDetection region
tube
cone
Positrons pair produced at the platinum foil are moderated by an applied 10V
energy e+ are blocked and the remaining background counts are high energy e+.potential. A blocking potential before the detection region is scanned. The low
Flange coil Flange coil
PotentialDetector 1
Detection
Detector 2
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Measured Coincidence Rate vs. Core Distance
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Positron Defect Probe at MIPBF
Peihai Li, M.A.Sc. Thesis, McMaster University 2015
Courtesy Pierre CARIES, GAP Engineering Co.
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Out of Core Test of Defect Characterization System
The Campaign for McMaster University
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First Results using the Defect Characterization Chamber –
Plasma Doping of Silicon (A.P. Knights et al., unpublished)
- Plasma Doping (PLAD) is a promising alternative to traditional beamline ion
implantation
- Current collaboration with AMAT includes PAS in a round robin experiment to
determine differences in the two doping technologies
- Preliminary data (first data taken on Defect Characterization chamber) shows
defect formation at near-surface region of PLAD exposed wafer
- Fits to data indicate void formation in a thin layer (work on-going).
PLAD
sample
Control sample
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Progress Checklist and Next Steps
Electrical and HVAC Installations – completed
Defect Probe System – tested and operational
Completion and Test of Positron Trap at York – Electronics and Positron
Annihilation Detection System (completed)
Finalization of Shielding and Source Design – completed
Installation of Shielding and Source – completed
Installation of Beam Tube and Positron Switch Yard – completed
Installation of End-stations at McMaster – Summer 2021
Thermal Load Issues Addressed and Solved – TBD
NSERC Grant for New Na-22 Positron Source; Delivery Fall 2021