Magnasoft* CJS Textile Enhancer - Latro Kimya of Textile Silicone Softeners Increased Benefit to...

Magnasoft* CJS Textile Enhancer

Copyright 2009 Momentive Performance Materials Inc. All rights reserved. 2

Evolution of Textile Silicone Softeners

Increased Benefit to Consumers

Overall Perform

ance

PendantAmino Silicones

PendantAmino Polyethers

Linear[AB]n Textile Enhancers

x y

NH

H2N

R = CH3, OH, OCH3

RSi

OSi

OSi

OSi

R

y z

*Si

OSi

RNH

R'O

OO

R'NH

R*

x n"A" "B"

Textile mills require products and processes that are forgiving and that deliver benefits easily felt by

consumers


A new product that further enriches Momentive’s prestigious line of Textile Enhancers such as Magnasoft SRS and DerMa NT Textile Enhancer

Nearly 100% actives patented [AB]n linear silicone copolymer

Easily emulsified using a simple mixer generally available in the industry

Not only hydrophilic, but can help provide luxurious softness with smooth, silky and dry feel for virtually all types of cellulosic fabric

Can help provide natural cotton-like touch to cotton knits and sheeting

Wider pH tolerance at elevated temperatures and good stability to shearing; can be considered for use in very demanding conditions for textile finishing

*Magnasoft is a trademark of Momentive Performance Materials Inc.

Magnasoft* CJS Textile Enhancer

A New Prestigious Textile Softener with Multiple Functionality



Typical Physical Properties -Magnasoft* CJS Textile Enhancer

0.99 gr/cm-3Density at 25°C

Typical Value

20,000 cpsViscosity at 25°C

79°CFlash point

Clear to Hazy Yellow LiquidAppearance

The data values for typical physical properties should not be used as specifications, which are available by contacting Momentive Performance Materials

Magnasoft CJS Textile Enhancer as

received

70% actives emulsion of Magnasoft CJS Textile

Enhancer

10% actives emulsion of Magnasoft CJS Textile

Enhancer


Smooth, silky, rich and in-depth softness with dry/cool feel on virtually all types of cellulosic fabrics

Can help provide natural cotton-like touch on cotton knits and sheeting

Hydrophilic: can help water & perspiration be rapidly absorbed with minimal impact on the hydrophilic nature of cotton

Excellent exhaustibility and affinity towards cellulosic fibers: unique and unusually powerful softness effect at low use levels

Nearly 100% silicone actives, hence potentially economical

Readily emulsified to generate emulsions that generally possess high shear and pH stability (acidic and alkaline)

Virtually no fabric yellowing and no color shade change

May be compatible with textile finishing auxiliaries


Key Features & Typical Benefits -Magnasoft* CJS Textile Enhancer



Performance Positioning -Magnasoft* CJS Textile Enhancer

0

2

4

6

8

10Softness

Smoothness

Fabric Whiteness

Hydrophilicity

Shear Stability

Alkali Stability

Color Migration

Emulsification

Magnasoft CJS Textile Enhancer Amino Silicone Fluid

Benchmark A Benchmark B



Hydrophilic Magnasoft* Textile Enhancers

Very GoodVery GoodExcellentVery GoodAlkaline Stability

90%85%67%100%(AB)n Silicone %

Magnasoft SilQ Textile Enhancer

Magnasoft DerMa NT Textile Enhancer

Magnasoft JSS Textile Enhancer

Magnasoft CJS Textile Enhancer

Brushed cotton fabrics, Terry towels, Cotton knits

Cotton knits & yarns, Viscose, Towels, Denim

Enzyme treated cotton knits, Viscose rayon, Tencel

Cotton sheets & wovens, Cotton/ Spandex blends, Tencel

Typical Target Fabrics

Limp, DrapeSoft, VoluminousDry, smoothSilky, smoothHand feel

1~3 sec5~10 sec3~8 sec9~15 secWater Absorption

8~10 cycles8~10 cycles3~5 cycles3~5 cyclesWash Durability of Softness

Easy with emulsifiers

Easy with emulsifiersNo need to emulsify

Easy with emulsifiers

Emulsifiability

Very GoodGoodExcellent GoodShear Stability

GoodVery GoodModerateGoodStretch Recovery

Typical Data. Actual data may vary.


Softness & Smoothness -Magnasoft* CJS Textile Enhancer

Cotton Woven

Cotton Knit

0.0586

0.0538

0.0425

0.0456

0.0664

0.0436

0.0437

0.0296

0.0324

0.0377

(B+2HB)/2

4.34.20.159Magnasoft CJS Textile Enhancer (10% dilution)

4.44.4N/AMagnasoft CJS Textile Enhancer (10% dilution)

0.169

0.161

0.157

0.186

N/A

N/A

N/A

N/A

MIU

KES value

4.14.0Benchmark A

Hand Panel

4.0

4.4

2.5

4.2

4.1

4.4

2.5

Smoothness

4.2Benchmark B

4.3Amino Micro-emulsion

2.5Control – Cotton Woven Untreated

4.1Benchmark B

4.1Benchmark A


2.5Control – Cotton Knit Untreated

Softness

Note: Test results. Actual results may vary.

Superior Softness & Smoothness to Benchmarks on Cotton Fabrics



What is KES value ?

KES (Kawabata Evaluation System) is a test equipment to measure softness and smoothness.

Treated fabrics are subjected to a KES evaluation. The instrument eliminates the subjective human factor by delivering numerical values for softness and smoothness.


Fabric Whiteness -Magnasoft* CJS Textile Enhancer

63.8466.77Control – Cotton Woven

Cotton Woven

55.0964.15Amino Micro-emulsion

64.8466.94Magnasoft CJS Textile Enhancer

(10% dilution)

Cotton Knit

Whiteness (CIE)

67.56

67.15

77.05

76.83

75.74

76.04

77.19

Dry at 130°°°°C

75.67Magnasoft CJS Textile Enhancer

(10% dilution)

65.13Benchmark A

75.17Benchmark B

63.89Benchmark B

75.68Benchmark A


76.94Control – Cotton Knit

Curing at 170 °°°°C X 2 min


The Lower the Values, the Higher the Fabric Yellowing




Hydrophilicity – Magnasoft* CJS Textile Enhancer

Moderate Hydrophilicity to Optimize the Softness & Smoothness

Cotton Woven by Water Drop Test (Sec)

4.92

4.69

> 60

9.03

1.26

Dry at 130°°°°C

15.1811.6112.00Magnasoft CJS Textile Enhancer (10% dilution)

4.73

5.10

> 60

1.44

Curing at 170°°°°C X 1 min

Hydrophilicity after 24 hrsaging of the treated fabric

Hydrophilicity after 5 days aging of the treated fabric

6.42

10.05

> 60

1.20

Curing at 170°°°°C X 1 min

6.26Benchmark B

8.58Benchmark A

> 60Amino Micro-emulsion

1.17Control – Cotton Knit

Dry at 130°°°°C

* The hydrophilicity of Magnasoft CJS Textile Enhancer can be improved by adding 1~2% Magnasoft TLC Hydrophilic Textile Softener to 10% actives emulsion of Magnasoft CJS Textile Enhancer




Shear & Electrolyte Stability -Magnasoft* CJS Textile Enhancer

No oiling; Translucent appearanceMagnasoft CJS Textile Enhancer (10% dilution)

Significant oiling on surfaceAmino Micro-emulsion

No oiling; Translucent appearanceBenchmark A

No oiling but gel particles deposited on beaker wallBenchmark B

Electrolyte Stability in 10~40 g/lt MgCl2.6H2O at & 50℃℃℃℃ for 5 days

Shear Stability at 50℃℃℃℃, pH10, 1000rpm for 30 min

Stable but becomes translucent

Stable

Unstable

Stable

Observation Results

Benchmark B

Benchmark A

Amino Micro-emulsion

Magnasoft CJS Textile Enhancer (10% dilution)

Product


Amino Micro-emulsion Benchmark BNote: Test results. Actual results may vary.



Stability at Various Bath pH & Temperatures

Bath pHBath Temperature

Clear, No oilingClear, No oilingClear, No oilingClear, No oiling30℃

Significant OilingHazy, No oilingHaze, No oilingClear, No oiling50℃

Clear, No oilingClear, No oilingClear, No oilingClear, No oiling30℃

Haze, No oilingClear, No oilingClear, No oilingClear, No oiling50℃

Oiling on surfaceOiling on surfaceNo oilingNo oiling30℃

Significant oiling on surface

Significant oiling on surface

OilingNo oiling50℃

Clear, No oilingClear, No oilingClear, No oilingClear, No oiling30℃Magnasoft* CJS Textile Enhancer

(10% dilution)Hazy, No oilingHazy, No oilingClear, No oilingClear, No oiling50℃

Benchmark B

Benchmark A

Amino Micro-emulsion

Product

80℃

80℃

80℃

80℃ Hazy, OilingHazy, OilingClear, No oilingClear, No oiling

Hazy, No oilingHazy, No oilingClear, No oilingClear, No oiling

Oiling

Oiling

7

Much Oiling

Much oiling on surface

10

Clear, No oiling

Gelling

4

Significant Oiling

Much oiling on surface

12

Magnasoft CJS Textile Enhancer: Excellent Stability in Most Conditions




Easy Emulsification -Magnasoft* CJS Textile Enhancer

--0.1Sodium Acetate

6.06.084.2Water

-11.761.7Tridecyl Alcohol 12 Ethoxylate

10.010.01.5Butyl Carbitol

Per manufacturer’s label

0.2

-

2.3

10.0

-2.24Tridecyl Alcohol 6 Ethoxylate

10% Actives Formulation

70% Actives FormulationMaterial

-

14.0

70.0

B

Biocide

-Acetic Acid

-Tridecyl Alcohol 10 Ethoxylate

70.0Magnasoft CJS Textile Enhancer

A


Product formulations are included as illustrative examples only. Momentive makes no representation or warranty of any kind with respect to such formulations, including, without limitation, concerning the efficacy or safety of any product manufactured using such formulations.



Easy Emulsification -Magnasoft* CJS Textile Enhancer

Procedure for 70% actives emulsion formulation

- Charge Magnasoft CJS Textile Enhancer, emulsifiers & butyl carbitol. Mix well until fully homogeneous.

- Slowly add the water solution to silicone/ emulsifiers blend while mixing. Avoid stirring at high speed to prevent foaming.

Procedure for 10% actives emulsion formulation

- Charge Magnasoft CJS Textile Enhancer, emulsifiers & butyl carbitol. Mix well until fully homogeneous.

- Dissolve acetic acid and sodium acetate in water.

- Slowly add the water solution to silicone/ emulsifiers blend while mixing. Avoid stirring at high speed to prevent foaming.





A Sample Emulsification for More Hydrophilicity -Magnasoft* CJS Textile Enhancer

NoteWeight %Material

8.0Initial Water

73.0Final Water

TDE-10 emulsifier3.0Tridecyl Alcohol 10 Ethoxylate

Per manufacturer’s label

4.0

2.0

10.0

Magnasoft TLC Hydrophilic Textile Softener

TDE-5 emulsifier

Biocide

Tridecyl Alcohol 5 Ethoxylate






A Sample Emulsification for More Hydrophilicity -Magnasoft* CJS Textile Enhancer

Procedure for the sample emulsification

- Charge Magnasoft CJS Textile Enhancer, Magnasoft TLC Hydrophilic Textile Softener, TDE-5 and TDE-10 into a mixer.

- Start stirring at 500 rpm for 5 minutes.

- Add initial water and keep stirring at 500~800 rpm until fully homogeneous and translucent.

- Slowly add the final water while stirring at 500 rpm.

- Stop stirring and wait until the foam collapses.

- A clear micro-emulsion may be obtained.





Potential Applications -Magnasoft* CJS Textile Enhancer

Cotton sheets & woven

Cotton/Spandex blended knits & woven

Cotton knits bio-polished

Tencel and its blends

Surface smoothness with silky & full hand

Good shear stability & compatibility withelectrolytes

Moderate hydrophilicity to absorb water& perspiration

MagnasoftCJS TextileEnhancer

Target F

abrics

Functio

nality



You‘ll feel Magnasoft* Textile

Enhancers


DISCLAIMER: THE MATERIALS, PRODUCTS AND SERVICES OF MOMENTIVE PERFORMANCE MATERIALS INC., MOMENTIVE PERFORMANCE MATERIALS USA INC., MOMENTIVE PERFORMANCE MATERIALS ASIA PACIFIC PTE. LTD., MOMENTIVE PERFORMANCE MATERIALS WORLDWIDE INC., MOMENTIVE PERFORMANCE MATERIALS GmbH, THEIR SUBSIDIARIES AND AFFILIATES DOING BUSINESS IN LOCAL JURISDICTIONS (collectively “SUPPLIERS”), ARE SOLD BY THE RESPECTIVE LEGAL ENTITY OF THE SUPPLIER SUBJECT TO SUPPLIERS’ STANDARD CONDITIONS OF SALE, WHICH ARE INCLUDED IN THE APPLICABLE DISTRIBUTOR OR OTHER SALES AGREEMENT, PRINTED ON THE BACK OF ORDER ACKNOWLEDGMENTS AND INVOICES, AND AVAILABLE UPON REQUEST. ALTHOUGH ANY INFORMATION, RECOMMENDATIONS, OR ADVICE CONTAINED HEREIN IS GIVEN IN GOOD FAITH, SUPPLIERS MAKE NO WARRANTY OR GUARANTEE, EXPRESS OR IMPLIED, (i) THAT THE RESULTS DESCRIBED HEREIN WILL BE OBTAINED UNDER END-USE CONDITIONS, OR (ii) AS TO THE EFFECTIVENESS OR SAFETY OF ANY DESIGN INCORPORATING SUPPLIERS’ PRODUCTS, MATERIALS, SERVICES, RECOMMENDATIONS OR ADVICE. AFOREMENTIONED EXCLUSIONS OR LIMITATION OF LIABILITY ARE NOT APPLICABLE TO THE EXTENT THAT THE END-USE CONDITIONS AND/OR INCORPORATION CONDITIONS CORRESPOND TO THE RECOMMENDED CONDITIONS OF USE AND/OR OF INCORPORATION AS DESCRIBED BY SUPPLIER IN ITS PRODUCT DATA SHEET AND/OR PRODUCT SPECIFICATIONS. EXCEPT AS PROVIDED IN SUPPLIERS’ STANDARD CONDITIONS OF SALE, SUPPLIERS AND THEIR REPRESENTATIVES SHALL IN NO EVENT BE RESPONSIBLE FOR ANY LOSS RESULTING FROM ANY USE OF ITS MATERIALS, PRODUCTS OR SERVICES DESCRIBED HEREIN. Each user bears full responsibility for making its own determination as to the suitability of Suppliers’ materials, services, recommendations, or advice for its own particular use. Each user must identify and perform all tests and analyses necessary to assure that its finished parts incorporating Suppliers’ products, materials, or services will be safe and suitable for use under end-use conditions. Nothing in this or any other document, nor any oral recommendation or advice, shall be deemed to alter, vary, supersede, or waive any provision of Suppliers’ Standard Conditions of Sale or this Disclaimer, unless any such modification is specifically agreed to in a writing signed by Suppliers. No statement contained herein concerning a possible or suggested use of any material, product, service or design is intended, or should be construed, to grant any license under any patent or other intellectual property right of Suppliers or any of its subsidiaries or affiliates covering such use or design, or as a recommendation for the use of such material, product, service or design in the infringement of any patent or other intellectual property right.

*Magnasoft is a trademark of Momentive Performance Materials Inc.Momentive, M-design logo and “The Science behind the solutions” are trademarks of Momentive Performance Materials Inc.

Technical subject matter in this publication is described and protected by one or more of the following U.S. Patents and their foreign counterparts and/or patent applications: U.S. Patent Nos. 5,807,956 and 5,981,681. Other U.S. and foreign patents and/or patent applications not listed covering the subject matter may be relevant.

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