Liquid thermoplastic resin for tougher composites

Liquid thermoplastic resinfor tougher composites

Elium® resins are innovative materials for the production of thermoplastic composites reinforced by continuous glass, carbon or natural fibers.

The resulting parts show mechanical properties similar to epoxy composites while presenting the major advantages of high impact resistance, post-thermoformability, recyclability and offer new material assembling possibilities.These results enable the production of structural composite parts in such industries as automotive, wind energy, sports, etc.

mm/m/°C

MPa.m0,5

%

MPa

MPa

MPa

GPa

GPa

GPa

Shore D hardness

Coefficient of linear expansion

Fracture toughness stress intensity, K1C

Elongation at break

Flexural strength

Tensile strength

Flexural modulus

Tensile modulus

Compression strength

Compression modulus

ISO 868

ISO 2155-1

ISO 13586

ISO 527

ISO 178

ISO 527

ISO 178

ISO 527

ISO 14126

ISO 14126

85 – 90

0.065

1.2

2.8

111

66

2.91

3.17

116

3.83

Typical cured resin non reinforced properties (post curing 24 h at 60 °C)

Typical impact behaviour compared between Polyester, Epoxy and Elium® in neat resin (figures) and composite (pictures)

Falling weight impact(26J - 4 m/s)

UPR Epoxy Elium®STRE

SS IN

TEN

SITY

FA

CTO

R, K

1C

Elium® resins can be processed by RTM, Infusion and pultrusion depending on the number of parts to be manufactured per day and the specifications of the part.

Elium® resins are pro-cessed on similar equip-ment to that used today for thermoset composites, with similar polymerization cy-cle times and conditions.

Reac

tion

time

Viscosity

Infusion Elium Elium 180Elium 188 O

Light RTM and InfusionElium 150Elium 151 SO

CastingElium C 445

Hand Layup(Repair)Elium 351 SO

Pultrusion, Windingand Wet CompressingElium 591Elium C 595

Fast RTMElium C 195

®

®

®

®

®

®

®

®

®

®

Resin Type Application ProcessViscosity

[mPa.s]Processing

Temperature [°C]ProcessingTime [min] e.g. Peroxide

Elium®

150

Elium®

180Elium®

188 O

Elium®

151 SO

Elium®

151 SO

Elium®

351 SO

Elium®

C 195

Elium®

C 445

Elium®

591Elium®

C 595

SportMedicine

Infusion, Light RTM

Infusion, Light RTM

Infusion, Light RTM

Infusion

Hand Layup

WindMarineB&C

MarineIndustrial

MarineIndustrial

WindMarine

Automotive

Solid Surface

Fast RTM

Casting

AutomotiveWind

Industrial

Pultrusion, Winding, Wet Compressing

Dibenzoyl Peroxide

Dibenzoyl Peroxide

Methyl Ethyl Ketone Peroxide

Acetylacetone Peroxide


Peroxide blend

Peroxide blend

Tert Butyl Monoperoxy

Maleate

100

100

100

100

300

100

400

500

20 – 60

20 – 60

20 – 60

20 – 60

20 – 60

90 - 120

20

20 – 115

20 – 30

45 – 90

20 – 30

45 – 90

Highly Adjustable

2 – 10

5 – 15

Adjustable

Specifications of some Elium® grades. (If a lower or higher reactivity infusion or injection resin is needed, please contact your Arkema representative for more information.) The presented Peroxide systems are commonly used in Europe. For specifications in US or Asia, please contact your Arkema representative for more information.

Elium® resin grades overview: comparison between reactivity and viscosity

Fiber-reinforced Elium® resin parts can be thermoformed with heat and pressure. This process requires the heating of the consolidated part at 180 – 200°C for a few minutes, and the compression at a pressure between 5 and 20 bars depending on the reinforcement type and the thickness of the part.

Fiber-reinforced composites made with Elium® resins can be assembled with adhesives. The SAF® 30 adhesive,from AEC Polymers, is recommended for structural bonding. A cohesive rupture is obtained according to the EN-1465.To use the advantage of the thermoplastic behaviour of Elium® resin an assembly by welding is also possible. This process requires the heating of the two consolidated parts at 180 – 200°C for a few minutes, followed by compression till it solidifies again.

The Composite parts made out of Elium® resin can be recycled after End-of-life in two different ways. The first one would involve grinding and compounding to use as chopped fiber compounding resin and the second would be a thermolysis process which allows the recovery of fibers and the monomers by depolymerisation.

The shelf life of the Elium® resins in original sealed container is 6 months guaranteed at a temperature not higher than 25 °C.For further information we advise you to read carefully the current Safety Data Sheet or get in contact with your Arkema representative.

Welded wind blade section without adhesive. (Project in cooperation with Pontis Engineering)

New method: welding

New method: welding

Elium 188 O

Elium® resins are innovative materials for the productionof thermoplastic composites reinforced by continuous glass, carbon or natural fibers.


mm/m/°C

MPa.m0,5

%

MPa

MPa

MPa

GPa

GPa

GPa

Shore D hardness



Elongation at break

Flexural strength

Tensile strength

Flexural modulus

Tensile modulus


Compression modulus

ISO 868

ISO 2155-1

ISO 13586

ISO 527

ISO 178

ISO 527

ISO 178

ISO 527

ISO 14126

ISO 14126

85 – 90

0.065

1.2

2.8

111

66

2.91

3.17

116

3.83





SS IN

TEN

SITY

FA

CTO

R, K

1C



Reac

tion

time

Viscosity

Infusion Elium

Elium 158 O

CastingElium C445

Hand Layup (Repair)Elium 351 EOT

Pultrusion, Winding and SMC

Elium 591Compression, RTM

®

®

®®

®

®

®

®

Resin Type Application ProcessViscosity[cP @25°]

Reactivity[min]

TemperatureRange [°C]

e.g. Peroxide

Elium® 158 O

Elium® 188 O Elium® 188 XO

Elium® 191 O/SA

Elium® 351 EOT

Elium® MC1590

Elium® C040

Elium® C195

SportMedicine

Infusion

Infusion

InfusionWind MarineB&C

Solid Surface

Solid Surface

Casting

Casting

AutomotiveSports

Industrial

DibenzoylPeroxide


100

100

100

300

15

300

500

15– 60

60 - 90

> 60

30 – 60

40 - 50

20

2 - 5

20 – 60

20 - 60

20 – 60

20 - 40

20 - 60

20



Fiber-reinforced composites made with Elium® resins can be assembled with adhesives. The SAF® 30 adhesive,from AEC Polymers, is recommended for structural bonding. A cohesive rupture is obtained according to the EN-1465.To use the advantage of the thermoplastic behaviour of Elium® resin an assembly by welding is also possible. This process requires the heating of the two consolidated parts at 180 – 200°C for a few minutes, followed by compression till it solidifies again.




New method: welding

New method: welding

Hand Layup

Wind Marine

Wind Marine

Elium® 190 InfusionCompression

RTM

Peroxide blend100 5 - 180 40 - 110Industrial

CompressionRTM

100 2 - 5 80 - 115 Peroxide blend

Elium® 591 AutomotiveConstruction

PultrusionPrepreg

500 2 - 5 80 - 115 Peroxide blend

Elium® C595 E AutomotiveConstruction

PultrusionWinding

80 - 115 Peroxide blend

Elium® MC590 Automotive SMC 500 2 - 5 80 - 115 Peroxide blend

Automotive SMC 1500 2 - 5 80 - 115 Peroxide blend

Elium® C445 Tert ButylMonoperoxy

Maleate


Light RTM and Infusion

Elium C595 E Elium® MC590Elium® MC1590

®

Elium C195 Elium 190®

DibenzoylPeroxide


DibenzoylPeroxide

Elium 188 XO Elium 191 O/SA

®

Elium® resins are innovative materials for the production of thermoplastic composites reinforced by continuous glass, carbon or natural fibers.


mm/m/°C

MPa.m0,5

%

MPa

MPa

MPa

GPa

GPa

GPa

Shore D hardness



Elongation at break

Flexural strength

Tensile strength

Flexural modulus

Tensile modulus


Compression modulus

ISO 868

ISO 2155-1

ISO 13586

ISO 527

ISO 178

ISO 527

ISO 178

ISO 527

ISO 14126

ISO 14126

85 – 90

0.065

1.2

2.8

111

66

2.91

3.17

116

3.83





SS IN

TEN

SITY

FA

CTO

R, K

1C



Reac

tion

time

Viscosity

Infusion Elium Elium 180Elium 188 O

Light RTM and InfusionElium 150Elium 151 SO

CastingElium C 445

Hand Layup(Repair)Elium 351 SO

Pultrusion, Windingand Wet CompressingElium 591Elium C 595

Fast RTMElium C 195

®

®

®

®

®

®

®

®

®

®

Resin Type Application ProcessViscosity

[mPa.s]Processing

Temperature [°C]ProcessingTime [min] e.g. Peroxide

Elium®

150

Elium®

180Elium®

188 O

Elium®

151 SO

Elium®

151 SO

Elium®

351 SO

Elium®

C 195

Elium®

C 445

Elium®

591Elium®

C 595

SportMedicine

Infusion, Light RTM

Infusion, Light RTM

Infusion, Light RTM

Infusion

Hand Layup

WindMarineB&C

MarineIndustrial

MarineIndustrial

WindMarine

Automotive

Solid Surface

Fast RTM

Casting

AutomotiveWind

Industrial

Pultrusion, Winding, Wet Compressing

Dibenzoyl Peroxide

Dibenzoyl Peroxide


Acetylacetone Peroxide


Peroxide blend

Peroxide blend

Tert Butyl Monoperoxy

Maleate

100

100

100

100

300

100

400

500

20 – 60

20 – 60

20 – 60

20 – 60

20 – 60

90 - 120

20

20 – 115

20 – 30

45 – 90

20 – 30

45 – 90

Highly Adjustable

2 – 10

5 – 15

Adjustable




Fiber-reinforced composites made with Elium® resins can be assembled with adhesives. The SAF® 30 adhesive, from AEC Polymers, is recommended for structural bonding. A cohesive rupture is obtained according to the EN-1465.To use the advantage of the thermoplastic behaviour of Elium® resin an assembly by welding is also possible. This process requires the heating of the two consolidated parts at 180 – 200°C for a few minutes, followed by compression till it solidifies again.




New method: welding

New method: welding

A global chemical company and France’s leading chemicals producer, Arkema is building the future of the chemical industry every day. Deploying a responsible, innovation-based approach, we produce state-of-the-art specialty chemicals that provide customers with practical solutions to such challenges as climate change, access to drinking water, the future of energy, fossil fuel preservation and the need for lighter materials. With operations in more than 50 countries, some 19,700 employees and 13 research centers, Arkema generates annual revenue of 7.7 billion, and holds leadership positions in all its markets with a portfolio of internationally recognized brands.

The statements, technical information and recommendations contained herein are believed to be accurate as of the date hereof. Since the conditions and methods of use of the product and of the information referred to herein are beyond our control, Arkema expressly disclaims any and all liability as to any results obtained or arising from any use of the product or reliance on such information; NO WARRANTY OF FITNESS FOR ANY PARTICULAR PURPOSE, WARRANTY OF MERCHANTABILITY OR ANY OTHER WARRANTY, EXPRESS OR IMPLIED, IS MADE CONCERNING THE GOODS DESCRIBED OR THE INFORMATION PROVIDED HEREIN. The information provided herein relates only to the specific product designated and may not be applicable when such product is used in combination with other materials or in any process. The user should thoroughly test any application before commercialization. Nothing contained herein constitutes a license to practice under any patent and it should not be construed as an inducement to infringe any patent and the user is advised to take appropriate steps to be sure that any proposed use of the product will not result in patent infringement.See SDS for Health & Safety Considerations.The information contained in this document is based on trials carried out by our Research Centres and data selected from the literature, but shall in no event be held to constitute or imply any warranty, undertaking, express or implied commitment from our part. Our formal specifications define the limit of our commitment. No liability whatsoever can be accepted by Arkema with regard to the handling, processing or use of the product or products concerned which must in all cases be employed in accordance with all relevant laws and/or regulations in force in the country or countries concerned.

elium-composites.com

Arkema North America100 PA Route 413Bristol, PA 19007T : +1(0) 800 523 1532F : +1(0) 215 826 2796

Arkema France420, rue d’Estienne d’OrvesF-92705 Colombes CedexT : +33 (0)1 49 00 80 80F : +33 (0)1 49 00 83 96

Arkema Asia Pacific7F, 21 Gukhoe-daero62-gil, Yeangdeungpo-guSeoul 150-874, Korea

www.arkema.com

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pie Liquid thermoplastic resin

for tougher composites

· Liquid at room temperature

· Easily processed by RTM, infusionand pultrusion

· Excellent strength, stiffness and toughness

· Assembly by welding and/or adhesives

A global chemical company and France’s leading chemicals producer, Arkema is building the future of the chemical industry every day. Deploying a responsible, innovation-based approach, we produce state-of-the-art specialty chemicals that provide customers with practical solutions to such challenges as climate change, access to drinking water, the future of energy, fossil fuel preservation and the need for lighter materials. With operations in more than 55 countries, some 20,600 employees and 15 research centers, Arkema generates annual revenue of 7.9 billion, and holds leadership positions in all its markets with a portfolio of internationally recognized brands.

The statements, technical information and recommendations contained herein are believed to be accurate as of the date hereof. Since the conditions and methods of use of the product and of the information referred to herein are beyond our control, Arkema expressly disclaims any and all liability as to any results obtained or arising from any use of the product or reliance on such information; NO WARRANTY OF FITNESS FOR ANY PARTICULAR PURPOSE, WARRANTY OF MERCHANTABILITY OR ANY OTHER WARRANTY, EXPRESS OR IMPLIED, IS MADE CONCERNING THE GOODS DESCRIBED OR THE INFORMATION PROVIDED HEREIN. The information provided herein relates only to the specific product designated and may not be applicable when such product is used in combination with other materials or in any process. The user should thoroughly test any application before commercialization. Nothing contained herein constitutes a license to practice under any patent and it should not be construed as an inducement to infringe any patent and the user is advised to take appropriate steps to be sure that any proposed use of the product will not result in patent infringement.See SDS for Health & Safety Considerations.The information contained in this document is based on trials carried out by our Research Centres and data selected from the literature, but shall in no event be held to constitute or imply any warranty, undertaking, express or implied commitment from our part. Our formal specifications define the limit of our commitment. No liability whatsoever can be accepted by Arkema with regard to the handling, processing or use of the product or products concerned which must in all cases be employed in accordance with all relevant laws and/or regulations in force in the country or countries concerned.

elium-composites.com

Arkema North America 900 First AvenueKing of Prussia, PA 19406 USAT: +1(0) 610 205 7000

Arkema France420, rue d’Estienne d’Orves F-92705 Colombes CedexT: +33 (0)1 49 00 80 80F: +33 (0)1 49 00 83 96

Arkema Asia Pacific 7F, 21 Gukhoe-daero 62-gil, Yeangdeungpo-gu Seoul 150-874, Korea

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Liquid thermoplastic resinfor tougher composites

· Liquid at room temperature

· Easily processed by RTM, infusionand pultrusion

· Excellent strength, stiffness and toughness

· Assembly by welding and/or adhesives

Headquaters: Arkema France420, d’Estienne d’Orves

92705 Colombes Cedex - FranceTel: +33 (0)1 49 00 80 80

Fax: +33 (0)1 49 00 83 96arkema.com

Liquid thermoplastic resin for tougher composites

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