Kuwait Export Crude Oil.pdf

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Kuwait Export Crude Oil SAFETY DATA SHEET Product name Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - Europe : 1.1 Product identifier Index number : 649-049-00-5 REACH Registration number EC number : 232-298-5 Registration number Legal entity 02-2119651277-35 - Kuwait Export Crude Oil Material uses : Petroleum refining CAS number 1.3 Details of the supplier of the safety data sheet e-mail address of person responsible for this SDS : : 8002-05-9 1.2 Relevant identified uses of the substance or mixture and uses advised against 1.4 Emergency telephone number National advisory body/Poison Center : Telephone number Not applicable. Manufacturer / Distributor : Kuwait Petroleum Corporation P.O. Box 26565 Safat 13126 Safat Kuwait Tel. +965 1858585, Fax 2423371/2467159/246 [email protected], communication preferably in English only. SECTION 1: Identification of the substance/mixture and of the company/undertaking See Section 11 for more detailed information on health effects and symptoms. Classification according to Regulation (EC) No. 1272/2008 [CLP/GHS] SECTION 2: Hazards identification 2.1 Classification of the substance or mixture Product definition : UVCB Classification according to Directive 67/548/EEC [DSD] See Section 16 for the full text of the R phrases or H statements declared above. 2.2 Label elements F+; R12 R66, R67 R52/53 Flam. Liq. 1, H224 Eye Irrit. 2, H319 Carc. 1B, H350 STOT SE 3, H336 STOT RE 2, H373 Asp. Tox. 1, H304 Aquatic Chronic 2, H411 Date of issue/Date of revision : 1/14 25-01-2011.

Transcript of Kuwait Export Crude Oil.pdf

  • Kuwait Export Crude Oil

    SAFETY DATA SHEET

    Product name

    Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - Europe

    :1.1 Product identifier

    Index number : 649-049-00-5

    REACH Registration numberEC number : 232-298-5

    Registration number Legal entity02-2119651277-35 -

    Kuwait Export Crude Oil

    Material uses : Petroleum refining

    CAS number

    1.3 Details of the supplier of the safety data sheet

    e-mail address of personresponsible for this SDS

    :

    : 8002-05-9

    1.2 Relevant identified uses of the substance or mixture and uses advised against

    1.4 Emergency telephone numberNational advisory body/Poison Center

    :Telephone number

    Not applicable.

    Manufacturer / Distributor : Kuwait Petroleum CorporationP.O. Box 26565 Safat13126 SafatKuwaitTel. +965 1858585, Fax 2423371/2467159/[email protected], communication preferably in English only.

    SECTION 1: Identification of the substance/mixture and of thecompany/undertaking

    See Section 11 for more detailed information on health effects and symptoms.

    Classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]

    SECTION 2: Hazards identification2.1 Classification of the substance or mixture

    Product definition : UVCB

    Classification according to Directive 67/548/EEC [DSD]

    See Section 16 for the full text of the R phrases or H statements declared above.

    2.2 Label elements

    F+; R12R66, R67R52/53

    Flam. Liq. 1, H224Eye Irrit. 2, H319Carc. 1B, H350STOT SE 3, H336STOT RE 2, H373Asp. Tox. 1, H304Aquatic Chronic 2, H411

    Date of issue/Date of revision : 1/1425-01-2011.

  • Kuwait Export Crude OilConforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - Europe

    SECTION 2: Hazards identification

    :Other hazards which do notresult in classification

    Defatting to the skin.

    Hazard pictograms :

    Signal word :Hazard statements :

    Prevention :Precautionary statements

    Response :

    Storage :Disposal :

    DangerExtremely flammable liquid and vapor.Causes serious eye irritation.May cause cancer.May be fatal if swallowed and enters airways.May cause drowsiness and dizziness.May cause damage to organs through prolonged or repeated exposure.Toxic to aquatic life with long lasting effects.

    Obtain special instructions before use. Wear protective gloves. Wear eye or faceprotection. Keep away from heat, sparks, open flames and hot surfaces. - Nosmoking. Use explosion-proof electrical, ventilating, lighting and all material-handlingequipment. Avoid release to the environment. Do not breathe vapor.IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable forbreathing. IF SWALLOWED: Immediately call a POISON CENTER or physician. DoNOT induce vomiting. IF ON SKIN (or hair): Take off immediately all contaminatedclothing. Rinse skin with water or shower.Keep cool.Not applicable.

    Supplemental labelelements

    Containers to be fittedwith child-resistantfastenings

    Not applicable.

    Tactile warning of danger Not applicable.

    :

    :

    : Not applicable.

    Special packaging requirements

    2.3 Other hazardsSubstance meets thecriteria for PBT accordingto Regulation (EC) No.1907/2006, Annex XIII

    : No.PBT: Specified

    Substance meets thecriteria for vPvB accordingto Regulation (EC) No.1907/2006, Annex XIII

    : No.vPvB: Specified

    Petroleum A complexcombination ofhydrocarbons. Itconsists predominantlyof aliphatic, alicyclicand aromatichydrocarbons. It mayalso contain smallamounts of nitrogen,

    REACH #: 02-2119651277-35EC: 232-298-5CAS: 8002-05-9Index: 649-049-00-5

    100 F+; R12

    R66, R67R52/53

    Flam. Liq. 1, H224

    Eye Irrit. 2, H319Carc. 1B, H350STOT SE 3, H336STOT RE 2, H373Asp. Tox. 1, H304Aquatic Chronic 2, H411

    [A]

    Substance/mixture UVCB:

    Identifiers 67/548/EECProduct/ingredientname

    SECTION 3: Composition/information on ingredients

    % TypeRegulation (EC) No.1272/2008 [CLP]

    Classification

    Date of issue/Date of revision : 2/1425-01-2011.

  • Kuwait Export Crude OilConforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - Europe

    SECTION 3: Composition/information on ingredientsoxygen and sulfurcompounds. Thiscategory encompasseslight, medium, andheavy petroleums, aswell as the oilsextracted from tarsands.Hydrocarbonaceousmaterials requiringmajor chemicalchanges for theirrecovery or conversionto petroleum refineryfeedstocks such ascrude shale oils,upgraded shale oilsand liquid coal fuels arenot included in thisdefinition.

    Occupational exposure limits, if available, are listed in Section 8.

    See section 16 for thefull text of the R-phrases declaredabove

    See Section 16 for thefull text of the Hstatements declaredabove.

    [*] Substance[A] Constituent[B] Impurity[C] Stabilizing additive

    Type

    There are no additional ingredients present which, within the current knowledge of the supplier, are classified andcontribute to the classification of the substance and hence require reporting in this section.

    Get medical attention immediately. Call a poison center or physician. Wash outmouth with water. Remove dentures if any. Remove victim to fresh air and keep atrest in a position comfortable for breathing. If material has been swallowed and theexposed person is conscious, give small quantities of water to drink. Stop if theexposed person feels sick as vomiting may be dangerous. Aspiration hazard ifswallowed. Can enter lungs and cause damage. Do not induce vomiting. If vomitingoccurs, the head should be kept low so that vomit does not enter the lungs. Nevergive anything by mouth to an unconscious person. If unconscious, place in recoveryposition and get medical attention immediately. Maintain an open airway. Loosentight clothing such as a collar, tie, belt or waistband.

    Skin contact

    Immediately flush eyes with plenty of water, occasionally lifting the upper and lowereyelids. Check for and remove any contact lenses. Continue to rinse for at least 10minutes. Get medical attention.

    Wash skin thoroughly with soap and water or use recognized skin cleanser. Removecontaminated clothing and shoes. Wash contaminated clothing thoroughly with waterbefore removing it, or wear gloves. Continue to rinse for at least 10 minutes. Getmedical attention. Wash clothing before reuse. Clean shoes thoroughly beforereuse.

    4.1 Description of first aid measures

    Remove victim to fresh air and keep at rest in a position comfortable for breathing. Ifit is suspected that fumes are still present, the rescuer should wear an appropriatemask or self-contained breathing apparatus. If not breathing, if breathing is irregularor if respiratory arrest occurs, provide artificial respiration or oxygen by trainedpersonnel. It may be dangerous to the person providing aid to give mouth-to-mouthresuscitation. Get medical attention. If necessary, call a poison center or physician.If unconscious, place in recovery position and get medical attention immediately.Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

    Ingestion

    Inhalation

    Eye contact

    :

    :

    :

    :

    SECTION 4: First aid measures

    Date of issue/Date of revision : 3/1425-01-2011.

  • Kuwait Export Crude OilConforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - Europe

    SECTION 4: First aid measures

    Notes to physician Treat symptomatically. Contact poison treatment specialist immediately if largequantities have been ingested or inhaled.

    :

    Specific treatments

    Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it issuspected that fumes are still present, the rescuer should wear an appropriate maskor self-contained breathing apparatus. It may be dangerous to the person providingaid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughlywith water before removing it, or wear gloves.

    4.2 Most important symptoms and effects, both acute and delayedPotential acute health effects

    Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness anddizziness.

    Can cause central nervous system (CNS) depression. May be fatal if swallowed andenters airways. Irritating to mouth, throat and stomach.

    :IngestionSkin contact : Defatting to the skin. May cause skin dryness and irritation.

    Causes serious eye irritation.:Eye contact

    Over-exposure signs/symptoms

    Skin contact

    Ingestion

    Inhalation Adverse symptoms may include the following:nausea or vomitingheadachedrowsiness/fatiguedizziness/vertigounconsciousness

    Adverse symptoms may include the following:nausea or vomiting

    Adverse symptoms may include the following:irritationdrynesscracking

    :

    :

    :

    Eye contact : Adverse symptoms may include the following:pain or irritationwateringredness

    4.3 Indication of any immediate medical attention and special treatment needed

    No specific treatment.:

    Hazardous thermaldecomposition products

    Hazards from thesubstance or mixture

    No specific data.

    Extremely flammable liquid and vapor. In a fire or if heated, a pressure increase willoccur and the container may burst, with the risk of a subsequent explosion. Runoff tosewer may create fire or explosion hazard. This material is toxic to aquatic life withlong lasting effects. Fire water contaminated with this material must be contained andprevented from being discharged to any waterway, sewer or drain.

    Use dry chemical, CO2, alcohol-resistant foam or water spray (fog).5.1 Extinguishing media

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    :

    Do not use water jet.

    Suitable extinguishingmedia

    :

    Unsuitable extinguishingmedia

    :

    SECTION 5: Firefighting measures

    5.2 Special hazards arising from the substance or mixture

    5.3 Advice for firefighters

    Date of issue/Date of revision : 4/1425-01-2011.

  • Kuwait Export Crude OilConforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - Europe

    SECTION 5: Firefighting measuresPromptly isolate the scene by removing all persons from the vicinity of the incident ifthere is a fire. No action shall be taken involving any personal risk or without suitabletraining. Move containers from fire area if this can be done without risk. Use waterspray to keep fire-exposed containers cool.Fire-fighters should wear appropriate protective equipment and self-containedbreathing apparatus (SCBA) with a full face-piece operated in positive pressuremode. Clothing for fire-fighters (including helmets, protective boots and gloves)conforming to European standard EN 469 will provide a basic level of protection forchemical incidents.

    Special protectiveequipment for fire-fighters

    :

    Special protective actionsfor fire-fighters

    :

    6.2 Environmentalprecautions

    Stop leak if without risk. Move containers from spill area. Approach release fromupwind. Prevent entry into sewers, water courses, basements or confined areas.Wash spillages into an effluent treatment plant or proceed as follows. Contain andcollect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculiteor diatomaceous earth and place in container for disposal according to localregulations (see section 13). Use spark-proof tools and explosion-proof equipment.Dispose of via a licensed waste disposal contractor. Contaminated absorbentmaterial may pose the same hazard as the spilled product. Note: see section 1 foremergency contact information and section 13 for waste disposal.

    Avoid dispersal of spilled material and runoff and contact with soil, waterways, drainsand sewers. Inform the relevant authorities if the product has caused environmentalpollution (sewers, waterways, soil or air). Water polluting material. May be harmful tothe environment if released in large quantities. Collect spillage.

    Large spill :

    Stop leak if without risk. Move containers from spill area. Dilute with water and mopup if water-soluble. Alternatively, or if water-insoluble, absorb with an inert drymaterial and place in an appropriate waste disposal container. Use spark-proof toolsand explosion-proof equipment. Dispose of via a licensed waste disposal contractor.

    Small spill :6.3 Methods and materials for containment and cleaning up

    SECTION 6: Accidental release measures6.1 Personal precautions, protective equipment and emergency procedures

    For non-emergencypersonnel

    :

    For emergency responders :

    6.4 Reference to othersections

    See Section 1 for emergency contact information.See Section 8 for information on appropriate personal protective equipment.See Section 13 for additional waste treatment information.

    No action shall be taken involving any personal risk or without suitable training.Evacuate surrounding areas. Keep unnecessary and unprotected personnel fromentering. Do not touch or walk through spilled material. Shut off all ignition sources.No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provideadequate ventilation. Wear appropriate respirator when ventilation is inadequate. Puton appropriate personal protective equipment.If specialised clothing is required to deal with the spillage, take note of any informationin Section 8 on suitable and unsuitable materials. See also the information in "Fornon-emergency personnel".

    :

    :

    SECTION 7: Handling and storageThe information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should beconsulted for any available use-specific information provided in the Exposure Scenario(s).

    7.1 Precautions for safe handlingProtective measures : Put on appropriate personal protective equipment (see Section 8). Avoid exposure -

    obtain special instructions before use. Do not handle until all safety precautions havebeen read and understood. Do not get in eyes or on skin or clothing. Do not breathevapor or mist. Do not swallow. Avoid release to the environment. Use only withadequate ventilation. Wear appropriate respirator when ventilation is inadequate. Donot enter storage areas and confined spaces unless adequately ventilated. Keep inthe original container or an approved alternative made from a compatible material,kept tightly closed when not in use. Store and use away from heat, sparks, openflame or any other ignition source. Use explosion-proof electrical (ventilating, lighting

    Date of issue/Date of revision : 5/1425-01-2011.

  • Kuwait Export Crude OilConforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - Europe

    SECTION 7: Handling and storage

    Store in accordance with local regulations. Store in a segregated and approved area.Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see section 10) and food anddrink. Store locked up. Eliminate all ignition sources. Separate from oxidizingmaterials. Keep container tightly closed and sealed until ready for use. Containersthat have been opened must be carefully resealed and kept upright to preventleakage. Do not store in unlabeled containers. Use appropriate containment to avoidenvironmental contamination.

    Advice on generaloccupational hygiene

    :

    7.2 Conditions for safestorage, including anyincompatibilities

    7.3 Specific end use(s)

    Recommendations ::Industrial sector specific

    solutionsNot available.Not available.

    and material handling) equipment. Use only non-sparking tools. Take precautionarymeasures against electrostatic discharges. Empty containers retain product residueand can be hazardous. Do not reuse container.

    Eating, drinking and smoking should be prohibited in areas where this material ishandled, stored and processed. Workers should wash hands and face before eating,drinking and smoking. Remove contaminated clothing and protective equipmentbefore entering eating areas. See also Section 8 for additional information on hygienemeasures.

    :

    Recommended monitoringprocedures

    No exposure limit value known.Occupational exposure limits

    If this product contains ingredients with exposure limits, personal, workplaceatmosphere or biological monitoring may be required to determine the effectivenessof the ventilation or other control measures and/or the necessity to use respiratoryprotective equipment. Reference should be made to European Standard EN 689 formethods for the assessment of exposure by inhalation to chemical agents andnational guidance documents for methods for the determination of hazardoussubstances.

    :

    Appropriate engineeringcontrols

    : Use only with adequate ventilation. Use process enclosures, local exhaust ventilationor other engineering controls to keep worker exposure to airborne contaminantsbelow any recommended or statutory limits. The engineering controls also need tokeep gas, vapor or dust concentrations below any lower explosive limits. Useexplosion-proof ventilation equipment.

    Wash hands, forearms and face thoroughly after handling chemical products, beforeeating, smoking and using the lavatory and at the end of the working period.Appropriate techniques should be used to remove potentially contaminated clothing.Wash contaminated clothing before reusing. Ensure that eyewash stations andsafety showers are close to the workstation location.

    8.2 Exposure controls

    Hygiene measures :

    No DELs available.

    Predicted effect concentrationsNo PECs available.

    SECTION 8: Exposure controls/personal protectionThe information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should beconsulted for any available use-specific information provided in the Exposure Scenario(s).

    8.1 Control parameters

    Derived effect levels

    Individual protection measures

    Date of issue/Date of revision : 6/1425-01-2011.

  • Kuwait Export Crude OilConforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - Europe

    SECTION 8: Exposure controls/personal protection

    Hand protection

    Use a properly fitted, air-purifying or air-fed respirator complying with an approvedstandard if a risk assessment indicates this is necessary. Respirator selection mustbe based on known or anticipated exposure levels, the hazards of the product andthe safe working limits of the selected respirator.

    Chemical-resistant, impervious gloves complying with an approved standard shouldbe worn at all times when handling chemical products if a risk assessment indicatesthis is necessary.

    Safety eyewear complying with an approved standard should be used when a riskassessment indicates this is necessary to avoid exposure to liquid splashes, mists,gases or dusts.

    Eye/face protection

    Respiratory protection :

    :

    :

    Skin protection

    Personal protective equipment for the body should be selected based on the taskbeing performed and the risks involved and should be approved by a specialistbefore handling this product.

    :

    Environmental exposurecontrols

    : Emissions from ventilation or work process equipment should be checked to ensurethey comply with the requirements of environmental protection legislation. In somecases, fume scrubbers, filters or engineering modifications to the process equipmentwill be necessary to reduce emissions to acceptable levels.

    Body protection :

    Other skin protection Appropriate footwear and any additional skin protection measures should be selectedbased on the task being performed and the risks involved and should be approved bya specialist before handling this product.

    SECTION 9: Physical and chemical properties9.1 Information on basic physical and chemical properties

    0 to 750C

    Physical state

    Melting point/freezing pointInitial boiling point and boilingrange

    Vapor pressure

    Relative densityVapor density

    Solubility(ies)

    Liquid. [A thick, flammable, liquid]

    300C

    Flammability (solid, gas) : Not available.

    No additional information.

    Appearance : Not available.

    Viscosity (40C) 7 to 16 cSt:

    Date of issue/Date of revision : 7/1425-01-2011.

  • Kuwait Export Crude OilConforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - Europe

    10.6 Hazardousdecomposition products

    10.4 Conditions to avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,braze, solder, drill, grind or expose containers to heat or sources of ignition.

    Under normal conditions of storage and use, hazardous decomposition productsshould not be produced.

    The product is stable.10.2 Chemical stability

    Reactive or incompatible with the following materials:oxidizing materials

    :

    :

    :

    10.5 Incompatible materials :

    10.3 Possibility of hazardousreactions

    : Under normal conditions of storage and use, hazardous reactions will not occur.

    SECTION 10: Stability and reactivity10.1 Reactivity : No specific test data related to reactivity available for this product or its ingredients.

    Acute toxicityConclusion/Summary : Not available.

    CarcinogenicityConclusion/Summary : Not available.

    MutagenicityConclusion/Summary : Not available.

    TeratogenicityConclusion/Summary : Not available.

    Reproductive toxicityConclusion/Summary : Not available.

    Irritation/Corrosion

    Petroleum A complexcombination ofhydrocarbons. It consistspredominantly of aliphatic,alicyclic and aromatichydrocarbons. It may alsocontain small amounts ofnitrogen, oxygen and sulfurcompounds. This categoryencompasses light, medium,and heavy petroleums, aswell as the oils extractedfrom tar sands.Hydrocarbonaceousmaterials requiring majorchemical changes for theirrecovery or conversion topetroleum refineryfeedstocks such as crudeshale oils, upgraded shaleoils and liquid coal fuels arenot included in this definition.

    Eyes - Mild irritant Rabbit - - -

    Skin - Moderate irritant Rabbit - - -

    Product/ingredient name Result Score Exposure Observation

    Conclusion/Summary : Not available.SensitizationConclusion/Summary : Not available.

    Species

    SECTION 11: Toxicological information11.1 Information on toxicological effects

    Date of issue/Date of revision : 8/1425-01-2011.

  • Kuwait Export Crude OilConforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - Europe

    SECTION 11: Toxicological information

    Potential acute health effects

    Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness anddizziness.

    Can cause central nervous system (CNS) depression. May be fatal if swallowed andenters airways. Irritating to mouth, throat and stomach.

    :IngestionSkin contact : Defatting to the skin. May cause skin dryness and irritation.

    Causes serious eye irritation.:Eye contact

    Symptoms related to the physical, chemical and toxicological characteristicsEye contact : Adverse symptoms may include the following:

    pain or irritationwateringredness

    Not available.

    Specific target organ toxicity (single exposure)

    Specific target organ toxicity (repeated exposure)

    Product/ingredient name Category

    Product/ingredient name Category

    Aspiration hazard

    Product/ingredient name Result

    Route ofexposure

    Target organs

    Route ofexposure

    Target organs

    Information on the likelyroutes of exposure

    :

    Petroleum A complex combination of hydrocarbons. It consistspredominantly of aliphatic, alicyclic and aromatic hydrocarbons. Itmay also contain small amounts of nitrogen, oxygen and sulfurcompounds. This category encompasses light, medium, andheavy petroleums, as well as the oils extracted from tar sands.Hydrocarbonaceous materials requiring major chemical changesfor their recovery or conversion to petroleum refinery feedstockssuch as crude shale oils, upgraded shale oils and liquid coal fuelsare not included in this definition.

    ASPIRATION HAZARD - Category 1

    Petroleum A complex combination of hydrocarbons. Itconsists predominantly of aliphatic, alicyclic and aromatichydrocarbons. It may also contain small amounts ofnitrogen, oxygen and sulfur compounds. This categoryencompasses light, medium, and heavy petroleums, aswell as the oils extracted from tar sands.Hydrocarbonaceous materials requiring major chemicalchanges for their recovery or conversion to petroleumrefinery feedstocks such as crude shale oils, upgradedshale oils and liquid coal fuels are not included in thisdefinition.

    Category 3 Not determined Narcotic effects

    Petroleum A complex combination of hydrocarbons. Itconsists predominantly of aliphatic, alicyclic and aromatichydrocarbons. It may also contain small amounts ofnitrogen, oxygen and sulfur compounds. This categoryencompasses light, medium, and heavy petroleums, aswell as the oils extracted from tar sands.Hydrocarbonaceous materials requiring major chemicalchanges for their recovery or conversion to petroleumrefinery feedstocks such as crude shale oils, upgradedshale oils and liquid coal fuels are not included in thisdefinition.

    Category 2 Not determined Not determined

    Date of issue/Date of revision : 9/1425-01-2011.

  • Kuwait Export Crude OilConforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - Europe

    SECTION 11: Toxicological information

    Potential chronic health effects

    May cause damage to organs through prolonged or repeated exposure.General :May cause cancer. Risk of cancer depends on duration and level of exposure.Carcinogenicity :No known significant effects or critical hazards.Mutagenicity :No known significant effects or critical hazards.Teratogenicity :

    Not available.

    Conclusion/Summary : Not available.

    Developmental effects : No known significant effects or critical hazards.Fertility effects : No known significant effects or critical hazards.

    Skin contact

    Ingestion

    Inhalation Adverse symptoms may include the following:nausea or vomitingheadachedrowsiness/fatiguedizziness/vertigounconsciousness

    Adverse symptoms may include the following:nausea or vomiting

    Adverse symptoms may include the following:irritationdrynesscracking

    :

    :

    :

    Delayed and immediate effects and also chronic effects from short and long term exposureShort term exposure

    Long term exposure

    Potential immediateeffectsPotential delayed effects :

    :

    Potential immediateeffectsPotential delayed effects :

    :

    Other information :

    Not available.

    Not available.

    Not available.

    Not available.

    Not available.

    12.1 Toxicity

    Petroleum A complexcombination ofhydrocarbons. It consistspredominantly of aliphatic,alicyclic and aromatichydrocarbons. It may alsocontain small amounts ofnitrogen, oxygen and sulfurcompounds. This categoryencompasses light, medium,and heavy petroleums, aswell as the oils extractedfrom tar sands.Hydrocarbonaceousmaterials requiring majorchemical changes for theirrecovery or conversion topetroleum refinery

    Acute EC50 1.8 mg/L Marine water Crustaceans - Artemia sp. -Nauplii

    48 hoursProduct/ingredient name SpeciesResult Exposure

    SECTION 12: Ecological information

    Date of issue/Date of revision : 10/1425-01-2011.

  • Kuwait Export Crude OilConforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - Europe

    SECTION 12: Ecological information

    Mobility Not available.:

    12.3 Bioaccumulative potential

    12.6 Other adverse effects No known significant effects or critical hazards.

    Not available.

    feedstocks such as crudeshale oils, upgraded shaleoils and liquid coal fuels arenot included in this definition.

    Acute EC50

  • Kuwait Export Crude OilConforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - Europe

    SECTION 13: Disposal considerationsSpecial precautions : This material and its container must be disposed of in a safe way. Care should be

    taken when handling emptied containers that have not been cleaned or rinsed out.Empty containers or liners may retain some product residues. Vapor from productresidues may create a highly flammable or explosive atmosphere inside the container.Do not cut, weld or grind used containers unless they have been cleaned thoroughlyinternally. Avoid dispersal of spilled material and runoff and contact with soil,waterways, drains and sewers.

    PETROLEUM CRUDEOIL(vapour pressure at50 C not more than110 kPa)

    3

    II

    PETROLEUM CRUDEOIL

    3

    II

    Petroleum crude oil

    UN1267

    33

    PETROLEUM CRUDEOIL(vapour pressure at50 C not more than110 kPa)

    II

    UN 1267

    II

    UN1267 UN1267

    Hazard identificationnumber33

    Limited quantityLQ4

    Special provisions640D 649

    Tunnel codeD/E

    - Emergencyschedules (EmS)F-E, S-E

    Passenger and CargoAircraftQuantitylimitation: 5 LPackaging instructions:305Cargo Aircraft OnlyQuantity limitation: 60 LPackaging instructions:307Limited Quantities -Passenger AircraftQuantity limitation: 1 LPackaging instructions:Y305

    SECTION 14: Transport informationADR/RID IMDG IATA

    14.1 UN number

    14.2 UN propershipping name

    14.3 Transporthazard class(es)

    14.4 Packing group

    ADN/ADNR

    Additionalinformation

    14.5 Environmentalhazards

    14.6 Specialprecautions foruser

    14.7 Transport in bulkaccording to Annex II ofMARPOL 73/78 and the IBCCode

    Yes. Yes. Yes. Yes.

    Not available. Not available. Not available. Not available.

    : Not available.

    SECTION 15: Regulatory information15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

    EU Regulation (EC) No. 1907/2006 (REACH)Annex XIV - List of substances subject to authorization

    Substances of very high concernNone of the components are listed.

    Date of issue/Date of revision : 12/1425-01-2011.

  • Kuwait Export Crude OilConforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - Europe

    SECTION 15: Regulatory information

    Other EU regulations

    Restricted to professional users.Annex XVII - Restrictionson the manufacture,placing on the market anduse of certain dangeroussubstances, mixtures andarticles

    :

    Europe inventory : This material is listed or exempted.Black List Chemicals : Not listedPriority List Chemicals : Not listedIntegrated pollutionprevention and control list(IPPC) - Air

    : Not listed

    Integrated pollutionprevention and control list(IPPC) - Water

    : Not listed

    Chemical WeaponsConvention List Schedule IChemicals

    : Not listed

    Chemical WeaponsConvention List Schedule IIChemicals

    : Not listed

    Chemical WeaponsConvention List Schedule IIIChemicals

    : Not listed

    International regulations

    Product/ingredient name Carcinogeniceffects

    Mutagenic effects Developmentaleffects

    Fertility effects

    Petroleum A complexcombination ofhydrocarbons. It consistspredominantly of aliphatic,alicyclic and aromatichydrocarbons. It may alsocontain small amounts ofnitrogen, oxygen and sulfurcompounds. This categoryencompasses light,medium, and heavypetroleums, as well as theoils extracted from tarsands.Hydrocarbonaceousmaterials requiring majorchemical changes for theirrecovery or conversion topetroleum refineryfeedstocks such as crudeshale oils, upgraded shaleoils and liquid coal fuels arenot included in thisdefinition.

    Carc. 1B, H350 - - -

    15.2 Chemical SafetyAssessment

    Complete.:

    Date of issue/Date of revision : 13/1425-01-2011.

  • Kuwait Export Crude OilConforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - Europe

    25-01-2011.Date of printingDate of issue/ Date ofrevision

    Version

    To the best of our knowledge, the information contained herein is accurate. However, neither the above-namedsupplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of theinformation contained herein.Final determination of suitability of any material is the sole responsibility of the user. All materials may presentunknown hazards and should be used with caution. Although certain hazards are described herein, we cannotguarantee that these are the only hazards that exist.

    Notice to reader

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    R12- Extremely flammable.R66- Repeated exposure may cause skin dryness or cracking.R67- Vapors may cause drowsiness and dizziness.R52/53- Harmful to aquatic organisms, may cause long-term adverse effects in theaquatic environment.

    Full text of abbreviated Rphrases

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    F+ - Extremely flammable:Full text of classifications[DSD/DPD]

    Indicates information that has changed from previously issued version.

    25-01-2011.

    No previous validation.1

    SECTION 16: Other information

    Full text of abbreviated Hstatements

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    Abbreviations and acronyms : ATE = Acute Toxicity EstimateCLP = Classification, Labelling and Packaging Regulation [Regulation (EC) No.1272/2008]DNEL = Derived No Effect LevelEUH statement = CLP-specific Hazard statementPNEC = Predicted No Effect ConcentrationRRN = REACH Registration Number

    Procedure used to derive the classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]

    Classification JustificationFlam. Liq. 1, H224 Expert judgmentEye Irrit. 2, H319 Expert judgmentCarc. 1B, H350 Expert judgmentSTOT SE 3, H336 Expert judgmentSTOT RE 2, H373 Expert judgmentAsp. Tox. 1, H304 Expert judgmentAquatic Chronic 2, H411 Expert judgment

    Full text of classifications[CLP/GHS]

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    H224 Extremely flammable liquid and vapor.H304 May be fatal if swallowed and enters airways.H319 Causes serious eye irritation.H336 May cause drowsiness and dizziness.H350 May cause cancer.H373 May cause damage to organs through prolonged or repeated exposure.H411 Toxic to aquatic life with long lasting effects.Aquatic Chronic 2, H411 AQUATIC TOXICITY (CHRONIC) - Category 2Asp. Tox. 1, H304 ASPIRATION HAZARD - Category 1Carc. 1B, H350 CARCINOGENICITY - Category 1BEye Irrit. 2, H319 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2Flam. Liq. 1, H224 FLAMMABLE LIQUIDS - Category 1STOT RE 2, H373 SPECIFIC TARGET ORGAN TOXICITY (REPEATED

    EXPOSURE) - Category 2STOT SE 3, H336 SPECIFIC TARGET ORGAN TOXICITY (SINGLE

    EXPOSURE) [Narcotic effects] - Category 3

    Prepared by : Kuwait Petroleum Research & Technology B.V., The Netherlands

    Date of issue/Date of revision : 14/1425-01-2011.