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ARCHEAN CHEMICAL INDUSTRIES PVT. LTD. Pre-Feasibility Report - Environmental Clearance Expansion of Chemical Fertilizer Manufacturing Unit of Sulphate of Potash (SOP) from 1,00,000 MTA to 4,00,000 MTA, Bromine from 12,500 MTA to 80,000 MTA, Co-Generation Power Plant (CPP) from 10 MW to 45 MW, production of Bromine derivatives and recovery of Industrial chemicals from waste streams at Greater Rann of Kachchh, Near Hajipir village, Tehsil Bhuj, District Kachchh, Gujarat. FEBRUARY, 2015 Kadam Environmental Consultants www.kadamenviro.com Environment f or Development

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ARCHEAN CHEMICAL INDUSTRIES PVT. LTD.

Pre-Feasibility Report - Environmental Clearance Expansion of Chemical Fertilizer Manufacturing Unit of Sulphate of Potash (SOP) from 1,00,000 MTA to 4,00,000 MTA, Bromine from 12,500 MTA to 80,000 MTA, Co-Generation Power Plant (CPP) from 10 MW to 45 MW, production of Bromine derivatives and recovery of Industrial chemicals from waste streams at Greater Rann of Kachchh, Near Hajipir village, Tehsil Bhuj, District Kachchh, Gujarat.

FEBRUARY, 2015

KadamEnvironmental Consultants w w w . k a d a m e n v i r o . c o m

Env i ronment for Deve lopment

M/S. ARCHEAN CHEMICAL INDUSTRIES LIMITED

PRE-FEASIBILITY REPORT - EXPANSION OF CHEMICAL FERTILIZER MANUFACTURING UNIT AT GREATER RANN OF KACHCHH

QUALITY CONTROL SHEET

KADAM ENVIRONMENTAL CONSULTANTS | FEBRUARY, 2015 II

M/S. ARCHEAN CHEMICAL INDUSTRIES LIMITED

Pre-Feasibility Report - Environmental Clearance Expansion of Chemical Fertilizer Manufacturing Unit of Sulphate of Potash (SOP) from 1,00,000 MTA to 4,00,000 MTA, Bromine from 12,500 MTA to 80,000 MTA, Co-Generation Power Plant (CPP) from 10 MW to 45 MW, production of Bromine derivatives and recovery of Industrial chemicals from waste streams at Greater Rann of Kachchh, Near Hajipir village, Tehsil Bhuj, District Kachchh, Gujarat. © Kadam Environmental Consultants (‘Kadam’), February, 2015

This report is released for the use of the M/s. Archean Chemical Industries Limited, Regulators and relevant stakeholders solely as part of the subject project’s Environmental Clearance process. Information provided (unless attributed to referenced third parties) is otherwise copyrighted and shall not be used for any other purpose without the written consent of Kadam.

PROJECT DETAILS

Name of Publication

Pre-Feasibility Report for Environmental Clearance Expansion of Chemical Fertilizer Manufacturing Unit of Sulphate of Potash (SOP) from 1,00,000 MTA to 4,00,000 MTA,

Bromine from 12,500 MTA to 80,000 MTA, Co-Generation Power Plant (CPP) from 10 MW to 45 MW, production of Bromine derivatives and recovery of Industrial chemicals from waste

streams at Greater Rann of Kachchh, Near Hajipir village, Tehsil Bhuj, District Kachchh, Gujarat.

Project Number 1520711606 Report No. 1 Version 1 Released February,

2015

Prepared & Managed By

Ishita Garg & Bhavin Jambucha Released By Jagdishchandra Rathi

CONTACT DETAILS

Vadodara (Head Office)

871/B/3, GIDC Makarpura, Vadodara, India – 390 010.

E: [email protected]; T:+91-265-3001000; F: +91-265-3001069

Delhi / NCR

Spaze IT Park, Unit No. 1124, IIth Floor, Tower B3, Sector 49, Near Omaxe City Centre Mall, Sohna Road, Gurgaon, Haryana, INDIA - 122002.

E: [email protected]; T: +91-124-4242430 to 436; F: +91-124-4242433

DISCLAIMER

Kadam has taken all reasonable precautions in the preparation of this report as per its auditable quality plan. Kadam also believes that the facts presented in the report are accurate as on the date it was written. However, it is impossible to dismiss absolutely, the possibility of errors or omissions. Kadam therefore specifically disclaims

any liability resulting from the use or application of the information contained in this report. The information is not intended to serve as legal advice related to the individual situation.

M/S. ARCHEAN CHEMICAL INDUSTRIES LIMITED

PRE-FEASIBILITY REPORT - EXPANSION OF CHEMICAL FERTILIZER MANUFACTURING UNIT AT GREATER RANN OF KACHCHH TABLE OF CONTENT

KADAM ENVIRONMENTAL CONSULTANTS | FEBRUARY, 2015 III

CONTENTS

1 INTRODUCTION ....................................................................................... 8

1.1 IDENTIFICATION OF PROJECT AND PROJECT PROPONENT ................................................ 8 1.2 BRIEF DESCRIPTION OF NATURE OF THE PROJECT ...................................................... 8 1.3 NEED FOR THE PROJECT AND ITS IMPORTANCE TO THE COUNTRY AND OR REGION ..................... 8 1.4 DEMAND SUPPLY GAP ................................................................................... 8 1.5 IMPORTS VS. INDIGENOUS PRODUCTION ................................................................ 8 1.6 EXPORT POSSIBILITY & DOMESTIC/EXPORT MARKETS .................................................. 9 1.7 EMPLOYMENT GENERATION (DIRECT AND INDIRECT) DUE TO THE PROJECT ............................. 9

2 PROJECT DESCRIPTION ............................................................................ 10

2.1 TYPE OF PROJECT ..................................................................................... 10 2.2 LOCATION OF THE PROJECT ........................................................................... 10 2.3 DETAILS OF ALTERNATE SITES CONSIDERED .......................................................... 10 2.4 SIZE OR MAGNITUDE OF OPERATION .................................................................. 10

2.4.1 Storage Details of Finished Products ....................................................... 11 2.5 PROCESS DESCRIPTION ............................................................................... 12

2.5.1 Sulphate of Potash ............................................................................ 12 2.5.2 Bromine ........................................................................................ 13 2.5.3 Magnesium Oxide (MgO) .................................................................... 14 2.5.4 TBBA – Tetra Bromo Bisphenol ............................................................. 15 2.5.5 Bromine Derivatives .......................................................................... 16 2.5.6 Hydrobromic Acid 48% (HBr) ............................................................... 16 2.5.7 Magnesium Chloride-46 % (MgCl2) ......................................................... 17 2.5.8 Magnesium Sulphate-98 % (MgSO4) ....................................................... 18 2.5.9 Co-Generation Power Plant .................................................................. 18

2.6 RAW MATERIALS ...................................................................................... 19 2.7 UTILITIES ............................................................................................. 20

2.7.1 Power Requirement ........................................................................... 20 2.7.2 Fuel Requirement ............................................................................. 20 2.7.3 Water Requirement ........................................................................... 21

2.8 POLLUTION LOAD ON ENVIRONMENT DUE TO PROJECT ................................................ 23 2.8.1 Air Emissions & Control ...................................................................... 23 2.8.2 Waste Water Generation ..................................................................... 24 2.8.3 Hazardous Waste and Other Solid Waste ................................................. 25

3 SITE ANALYSIS ....................................................................................... 26

3.1 CONNECTIVITY ........................................................................................ 26 3.1.1 By Road ........................................................................................ 26 3.1.2 By Rail .......................................................................................... 26 3.1.3 By Air ........................................................................................... 26 3.1.4 By Water ....................................................................................... 26

3.2 LAND FORM, LAND USE AND LAND OWNERSHIP ....................................................... 26

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3.3 TOPOGRAPHY (ALONG WITH MAP) ..................................................................... 26 3.4 EXISTING LAND USE PATTERN ........................................................................ 26 3.5 SENSITIVE AREAS ..................................................................................... 27

3.5.1 Water Bodies .................................................................................. 27 3.5.2 Defense Installation .......................................................................... 27 3.5.3 Religious Place ................................................................................ 27 3.5.4 Flora and Fauna ............................................................................... 27

3.6 SOCIAL INFRASTRUCTURE AVAILABLE ................................................................. 28 3.7 SOIL CLASSIFICATION ................................................................................. 28 3.8 CLIMATIC DATA FROM SECONDARY SOURCES ......................................................... 28 3.9 EXISTING INFRASTRUCTURE ........................................................................... 28

4 PLANNING BRIEF ..................................................................................... 30

4.1 PLANNING CONCEPT ................................................................................... 30 4.2 ASSESSMENT OF INFRASTRUCTURE DEMAND (PHYSICAL & SOCIAL) ................................... 30 4.3 AMENITIES/FACILITIES ................................................................................ 30

5 PROPOSED INFRASTRUCTURE ................................................................... 31

5.1 INDUSTRIAL AREA (PROCESSING AREA) ............................................................... 31 5.2 RESIDENTIAL AREA (NON-PROCESSING AREA) ........................................................ 31 5.3 EQUIPMENT LIST ...................................................................................... 31 5.4 GREEN BELT ........................................................................................... 33 5.5 SOCIAL INFRASTRUCTURE ............................................................................. 33 5.6 CONNECTIVITY (TRAFFIC AND TRANSPORTATION ROAD/ RAIL/METRO/WATER WAYS ETC) ............. 33 5.7 DRINKING WATER MANAGEMENT (SOURCE & SUPPLY OF WATER) .................................... 33 5.8 SEWAGE SYSTEM ...................................................................................... 33 5.9 SOLID & INDUSTRIAL WASTE MANAGEMENT .......................................................... 33

6 REHABILITATION AND RESETTLEMENTS (R& R) PLAN ................................... 34

7 PROJECT SCHEDULE AND COST ESTIMATE ................................................... 35

7.1 LIKELY DATE OF START OF CONSTRUCTION AND LIKELY DATA OF COMPLETION ........................ 35 7.2 ESTIMATED PROJECT COST ............................................................................ 35

7.2.1 Profitability ..................................................................................... 35

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ANNEXURES

Annexure 1: Land Lease and Possession Documents ...................................................................... 37

Annexure 2: General and Specific Location Map ............................................................................ 53

Annexure 3: Project Boundary Map .............................................................................................. 54

Annexure 4: Project Site Located on Toposheet ............................................................................. 55

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LIST OF TABLES

Table 2-1: Co-ordinates of Project Boundary ................................................................................. 10

Table 2-2: List of Proposed Products and Production Capacity ........................................................ 10

Table 2-3: Finished Products Storage Details ................................................................................. 11

Table 2-4: Mass Balance – Sulphate of Potash (SOP) ..................................................................... 13

Table 2-5: Mass Balance – Bromine .............................................................................................. 14

Table 2-6: Mass Balance – Magnesium Oxide (MgO) ...................................................................... 14

Table 2-7: Mass Balance – TBBA – Tetra Bromo Bisphenol ............................................................. 15

Table 2-8: Mass Balance – Hydrobromic Acid (48%) ...................................................................... 17

Table 2-9: Mass Balance – Magnesium Chloride-46 % (MgCl2) ........................................................ 17

Table 2-10: Details of Raw Material Quantity and Means of Storage ................................................ 19

Table 2-11: Fuel Details ............................................................................................................... 20

Table 2-12: Details of Existing Stacks, Fuel Used and APCM ........................................................... 23

Table 2-13: Waste Water Details .................................................................................................. 24

Table 2-14: Hazardous Waste Details ........................................................................................... 25

Table 3-1: Distance of Villages from Project Site ............................................................................ 27

Table 3-2: Distance of Ponds from Project Site .............................................................................. 27

Table 3-3: Distance of Reserve Forest from Project Site ................................................................. 28

Table 5-1: Equipment List ............................................................................................................ 32

Table 7-1: Project Cost ................................................................................................................ 35

LIST OF FIGURES

Figure 2-1: Process Flow Diagram – Sulphate of Potash (SOP) ....................................................... 12

Figure 2-2: Process Flow Diagram – Bromine ................................................................................ 14

Figure 2-3: Process Flow Diagram – TBBA – Tetra Bromo Bisphenol ............................................... 15

Figure 2-4: Process Flow Diagram – Hydrobromic Acid (48%) ........................................................ 17

Figure 2-5: Flow diagram of CPP .................................................................................................. 19

Figure 2-6: Water Diagram .......................................................................................................... 22

Figure 2-7: Block Diagram of ETP ................................................................................................. 24

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LIST OF PHOTOGRAPHS

Photograph 3-1: Photographs of Existing & Proposed Site .............................................................. 29

Photograph 5-1: Green Belt Development at Existing Site .............................................................. 33

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1 INTRODUCTION

1.1 Identification of Project and project Proponent

Archean Chemical Industries Limited (ACIL) have established marine based fertilizer chemical complex at Greater Ran of Kutch in the leased land allotted to by Gujarat Government & having valid EC vide No.- J-11011/149/2010-IA II (1) dated 02-09-2011. Commercial operations were started in the year 2014. Greater Ran of Kutch is the best location for extraction of marine Chemicals. To meet demand & supply in the market globally for products like Bromine & Sulphate of Potash, it was essential to go for expansion to capture domestic & Global Market.

1.2 Brief Description of Nature of the Project

ACIL is having existing unit located in Greater Rann of Kutch, Near Hajipir, Tal. Bhuj, Gujarat. The company intends to go for expansion of the existing products (Sulphate of Potash, Liquid Bromine, Green Bromine and Epsomite) & with other by products related to Bromine & Bromine derivatives in the existing manufacturing facilities.

The area of Existing manufacturing facility will be about 75 hectares from a total area of 500 hectares. The site is about 16 Kms north of Hajipir, which is the nearest village. In this regard, the unit intends to obtain environmental clearance from the Ministry of Environment and Forest for expansion & to include value added bromine related products. A total investment of approx. Rs. 1,400 crores will be made for this new project.

1.3 Need for the Project and its Importance to the Country and or Region

By expanding our Bromine capacity & Sulphate of Potash, we can reduce the imports in to India, & exports can be increased which will generate foreign exchange to the country. Further there is scope for additional employment about 1,000 peoples & the remote area where our plant exist can generate more ancillary engineering industries.

1.4 Demand Supply Gap

About 18,000 MT Per Annum Bromine is being consumed in India by Pharma/Pesticide/Dyes & Intermediate Industries. Further the global market for Bromine is about 6,00,000 MTPA.

1.5 Imports vs. Indigenous Production

Due to high demand of Bromine in Indian Market, many industries are importing Bromine from Isreal/USA. To substitute imports in to Indian market & to increase exports mainly to China & other European Countries, ACIL intend to go for expansion of Bromine & SOP Plants.

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1.6 Export Possibility & Domestic/Export Markets

With the expansion project, ACIL can increase their domestic/exports markets for Bromine & Sulphate of Potash to various countries.

1.7 Employment Generation (Direct and Indirect) due to the project

Presently about 3,000 employees are employed. By the expansion project, additional local employment for about 1,000 peoples shall be generated.

Local skilled and semi-skilled workers will be engaged during construction phase. The positives impact include enhanced direct employment for technical/administrative works and indirect employment opportunities for transporters of raw materials and finished goods.

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2 PROJECT DESCRIPTION

2.1 Type of Project

As per the EIA notification dated 14th September, 2006, as amended till date, the proposed project falls under the Project / Activity: 5(a) – Chemical fertilizers which shall be treated as Category “A”.

2.2 Location of the Project

The project is located at Greater Rann of Kachchh, Near Hajipir village, Tehsil Bhuj, District Kachchh, Gujarat. The area is already under use for the existing plant process.

Plot is taken on lease from Governor of Gujarat. Agreement documents of the same and Land possession documents for plot are attached as Annexure 1.

Location map showing general & specific location of proposed project is given in Annexure 2. Project boundary map is given in Annexure 3. The co-ordinates of the project site are given in Table 2-1.

Table 2-1: Co-ordinates of Project Boundary Code Latitude Longitude

1 23°50'23.78"N 69°13'31.93"E

2 23°50'26.22"N 69°14'58.77"E

3 23°49'24.02"N 69°15'0.76"E

4 23°49'22.20"N 69°13'33.26"E

2.3 Details of Alternate Sites Considered Alternative sites are not identified since the existing facility possesses sufficient land, infrastructure, utilities and road connectivity for expansion activities.

2.4 Size or Magnitude of Operation

Plot area of the project consists of 500 Ha. Details of all the proposed products are listed in Table 2-2.

Table 2-2: List of Proposed Products and Production Capacity

S. No Name Existing Capacity

(MT) Expansion

(MT) Total Capacity

(MT)

Products

1 Sulphate of Potash (SOP) 1,00,000 3,00,000 4,00,000

2 Bromine (Br2) 12,500 67,500 80,000

3 Green Bromine 2,500 0 2,500

4 Epsomite (MgSO4.7H2O) 81,000 1,62,000 2,43,000

5 Magnesium Oxide (MgO) 0 2,00,000 2,00,000

6 Tetra Bromo Bisphenol -A(TBBA) 0 10,000 10,000

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S. No Name Existing Capacity

(MT) Expansion

(MT) Total Capacity

(MT)

7 Bis-di-Bromo Propyle Ether (BDDP) 0 5,000 5,000

8 Deca Bromo Diphenyl Ether (DBDE) 0 4,000 4,000

9 Hexa Bromo Benzene (HBB) 0 1,000 1,000

10 Hydro Bromic Acid- 48%(HBR) 0 5,000 5,000

11 Magnesium Chloride-46 % (MgCl2) 0 6,00,000 6,00,000

12 Magnesium Sulphate-98 % (MgSO4) 0 6,00,000 6,00,000

Co-Generation Power Plant

CO-GEN 10 MW 35 MW 45 MW

2.4.1 Storage Details of Finished Products

Storage details of the finished products are tabulated in Table 2-3.

Table 2-3: Finished Products Storage Details

S. No

Product State

Existing Expansion

Consumption (TPM)

Storage Consumption

(TPM) Storage

1 Bromine Liquid 1,042 Tanks

(2 x 45 MT) 5,625 Tanks

2 Epsomite Solid 6,750 HDPE Bags 13,500 HDPE Bags

3 Sulphate of Potash

(SOP) Solid 8,333

HDPE Bags/storage

25,000 HDPE

Bags/storage

4 Magnesium Oxide

(MgO) Solid Nil Nil 16,666 HDPE Bags

5 Tetra bromo bis phenol-

A (TBBA) Solid Nil Nil 833 HDPE Bags

6 Bis Di Bromo propyle

ether (BDDP) Solid Nil Nil 416 HDPE Bags

7 Deca Bromo Diphenyl

Ether (DBDE) Solid Nil Nil 333 HDPE Bags

8 Hexa bromo Benzene Solid Nil Nil 83 HDPE Bags

9 Hydro Bromic Acid

(HBR) Liquid Nil Nil 416 Tanks

10 Magnesium Chloride-46

% (MgCl2) Solid Nil Nil 50,000 HDPE Bags

11 Magnesium sulphate-

98% (MgSO4) Solid Nil Nil 50,000 HDPE Bags

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2.5 Process Description

2.5.1 Sulphate of Potash

Process Description

Harvested crude Magnesium salt will be leached in NaCl saturated circulating brine at an elevated temperature making MgSO4 and minor amounts KCl (if any) get dissolved. After adjustment of the solution in terms of MgSO4 concentration and post separation of non-dissolved NaCl, the clear liquor will be cooled to 10 - 15 °C to produce a pure and NaCl free Epsomite. Some of this Epsomite will be used in the process of SOP production, while the rest is saleable. The same circulation liquor will be reused and a small part will be bleed-off and sent to the solar pond system. The non-dissolved NaCl will be re-dissolved in Sea water and sent back to the solar ponds.

Secondly the Harvested Salt Mixture will be mixed with seawater in order to decompose Carnallite and dissolve MgCl2. The remaining un-dissolved KCl, MgSO4 and NaCl mixture will be used for the SOP process and the mother liquor called ‘Carnallite decomposed liquor’ will be recycled to Solar Pond.

The above two beneficiated raw salts

Harvested epsomite salt; Harvested salt mixture;

will be mixed together, in a KCl:MgSO4 concentration that corresponds to the same ratio as existing in Kainite. This mixture called ‘Synthetic Kainite’ will be mixed with seawater and cooled SOP mother liquor for dissolution, so that Primary Schoenite will be generated. The ‘Schoenite mother liquor ‘separated from Primary Schoenite will be re-cycled to Solar Pond.

Primary Schoenite generated from the earlier stage and the recovered/secondary Schoenite will be leached with seawater at 48°C, by which K2SO4 begins to crystallize out while MgSO4 will remain in solution. When the MgSO4 concentration will reach approx 225 g/1000g H2O, the resulting slurry will be centrifuged, washed with small amount of fresh water and dewatered to produce SOP and a Hot SOP mother liquor. The Hot SOP mother liquor will be cooled to 10 -15 °C in order to generate recovered /secondary Schoenite and cooled SOP mother liquor, depending on the NaCl concentration in Schoenite, purification of Schoenite will be accomplished by using a wash with fresh water and / or a flotation to remove NaCl.

Process flow diagram (PFD) and Material Balance for Sulphate of Potash is given in Figure 2-1 &

Table 2-4 respectively.

Figure 2-1: Process Flow Diagram – Sulphate of Potash (SOP)

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Table 2-4: Mass Balance – Sulphate of Potash (SOP) S. N. Raw Materials Input (MT) / MT of Product

1 KTMS 10

2 Sea Water 20

3 Process Water 5

4 RO Water 1

Total 36

S. N. Product Output/Day of Product

1 SOP 1 MT

2 Effluent 22 m3

2.5.2 Bromine

Steaming out process (STO) for Liquid Bromine:

Feed bitterns from reservoir will be acidified to 3.5 pH by addition of acid in a feed tank and pumped to the top of stripping tower packed with pall rings. Steam and chlorine will be injected at the bottom of thetower. Liberated bromine will be condensed and purified in a separate tower by heating with indirectsteam, Bromine will again get condensed and refluxed backed to top of tower and liquid bromine will bedrawn from the bottom of this purifying tower, cooled and bottled in glass bottles and/or filled in ISO tanks for dispatch.

Air Blow out Process (ABO) for Liquid Bromine

Bittern from the reservoir will be acidified to pH 3.5 by the addition of acid in a feed tank and pumped to the top of stripping tower packed with pall rings; air and chlorine will be injected at the bottom of the tower. Liberated Bromine laden by air will be made to react with soda ash or caustic soda solution venting of un-reacted air by circulating in a series of packed towers.

The reaction in the absorber reactor is as follows:

3Na2CO3 + 3Br2 = 5NaBr + NaBrO3 + 3CO2

or, 6NaOH + 3Br2 = 5NaBr + NaBrO3 + 3H2O

Part of this enriched alkaline solution (AB solution) will be the mixture of bromide, bromate compounds from which again Bromine will be regenerated by the addition of acid. Regeneration of Bromine will be done by a method similar to steaming out process but with smaller equipment as the feed liquor will be highly concentrated.

5NaBr + NaBrO3 + 6HCl = 6NaCl + 3Br2 + 3H2O

Regenerated Bromine led out by steam given at the bottom of the tower will be condensed, separated and processed further in distillation unit for the removal of impurities and packed in glass bottles and /or in ISO tanks for dispatch.

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Process flow diagram (PFD) and Material Balance for Bromine is given in Figure 2-4 & Table 2-5 respectively.

Figure 2-2: Process Flow Diagram – Bromine

Table 2-5: Mass Balance – Bromine

S. N. Raw Materials Input/ MT of

Product Unit

1 Bittern 201 m3

2 Sulphuric Acid 0.51 MT

3 Liquid Chlorine 0.55 MT

4 Caustic Lye (48%) 0.1 MT

5 Lime 0.77 MT

6 Caster Oil 0.010 MT

7 RO Water (make up water) 25 m3

8 Reject Water(Dilution & Washing water) 25 m3

S. No. Product Output/Day of Product

1 Bromine 1 MT

2 Effluent 434 m3

3 ETP Sludge 0.715 MT

2.5.3 Magnesium Oxide (MgO)

Process Description

STEP-1: De-sulphatation of Bittern & Removal of Gypsum

STEP-2: Hydrated lime Addition and Precipitation of Mg(OH)2 and Filtration and Washing of Mg(OH)2

STEP-3: Calcination of Magnesium Hydroxide at 1800°C to form Dead Burnt Magnesia

STEP-4: Evaporation of 15% Calcium Chloride Solution to produce 70% Calcium Chloride Flakes.

Material Balance for Magnesium Oxide (MgO) is given in Table 2-6.

Table 2-6: Mass Balance – Magnesium Oxide (MgO)

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S. N. Raw Materials Input/ MT of Product

1 Bittern 7 % Mg 9 MT

2 Hydrated Lime 80% 2.4 MT

3 Water 10 m3

4 Steam 3 MT

S. No. Product Output/Day of Product (MT)

1 MgO 1

2 By Product-Gypsum 0.162

3 CaCl2 Flakes 0.66

2.5.4 TBBA – Tetra Bromo Bisphenol

TBBA-Tetra Bromo Bisphenol-A is prepared by bromination of Bisphenol-A in MCB as a solvent using Bromine, Hydrogen Peroxide and Water. The reaction mass is maintained at a specific temperature for a period of time sufficient for Bisphenol-A to undergo tetrabromination .Here liberated Hydrogen Bromide is getting oxidized by Hydrogen Peroxide to Bromine.

The Product solution then washed with an alkali solution then cooled to crystallize the product .Filter this mass and Then again heating the reaction mass for the removal of traces impurities that present in the mass up to specific temperature. The final product is filtered, dried, pulverized and packed.

Process flow diagram (PFD) and Material Balance for TBBA – Tetra Bromo Bisphenol is given in Figure 2-3 & Table 2-7 respectively.

Figure 2-3: Process Flow Diagram – TBBA – Tetra Bromo Bisphenol

Table 2-7: Mass Balance – TBBA – Tetra Bromo Bisphenol S. No. Raw Materials Input (MT) / MT of Product

1 Bromine 0.65

2 Bis Phenol-A 0.456

3 Mono Chlorobenzene (MCB) 0.06

4 Sodium Meta bisulphide 0.028

5 Sodium Sulphide 0.02

6 Hydrogen Peroxide 0.3

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S. No. Product Output/Day of Product (MT)

1 TBBA 1

2.5.5 Bromine Derivatives

Bis-di-Bromo Propyle Ether (BDDP)

Process: Complete bromination of ether.

Deca Bromo Diphenyl Ether (DBDE)

Process:

Step 1: Solution preparation- Charge bromine to reactor, cool br2 to 10°C, charge AlCl3 to reactor.

Step 2: Reaction & Cooling- Charge DPE to melter, add DPE in liquid form, maintain temperature upto 17°C, after completion of addition of DPE raise temperature to reflux. Add water to the reaction mass and cool the reaction mass to 30°C, distill the excess bromine to recover, cool the contents to room temperature.

Step 3: Filtration- Transfer reactor mix to nutsche filter/centrifuge in lots, unload wet cake, wash wet cake with dilute HCl & spin dry, transfer ML to storage tank.

Step 4: Drying- Charge wet cake DBDPE finished product to vacuum tray dryer. Dry product at 50-50°C, check moisture content less than 0.5% w/w, unload dry DBDPE finished product from vacuum tray dryer is Deca bromo diphenylethane.

Hexa Bromo Benzene (HBB)

Process:

Hexa bromo benzene is synthesized by using benzene and bromine as raw materials and AlCl3 as catalyst. The reaction conditions are improved and optimized. Under the obtained optimum conditions, the purity of product is over 99%, the yield of product is98%.

2.5.6 Hydrobromic Acid 48% (HBr)

Process:

HBr is produced as a gas from the combustion of hydrogen and bromine gases, then absorbed into water and cooled. The combustion process is highly controlled to provide ultimate safety. During the combustion process, bromine and hydrogen react in equal volumes to produce HBr gas:

H2 + Br2 2 HBrg

This exothermic reaction generates a flame temperature of around 1,200°C and a heat load of approximately 110 kcal/kg HBr when producing a cooled HBr gas at 50°C.

The combustion process is operated with a slight excess of H2 over stoichiometric conditions (typically 20-30%). Operating the system with this excess of H2 ensures the complete combustion of Br2, thus preventing it from escaping into the atmosphere and producing a highly pure bromhydric acid.

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Process flow diagram (PFD) and Material Balance for Hydrobromic Acid (48%) is given in Figure 2-4 & Table 2-8 respectively.

Figure 2-4: Process Flow Diagram – Hydrobromic Acid (48%)

Table 2-8: Mass Balance – Hydrobromic Acid (48%) S. N. Raw Materials Input/ MT of Product

1 Bromine 0.5 MT

2 SO2 0.45 MT

3 Water 2 m3

S. No. Product Output/Day of Product (MT)

1 HBR 1 MT

2 Effluent 2.95 m3

2.5.7 Magnesium Chloride-46 % (MgCl2)

Process Description

STEP 1: Removal of sulphate by precipitation of Gypsum (Adding CaCl2-solution)

STEP 2: Evaporation of water from De-sulphated Bittern, upgrading the MgCl2-brine (37.5° containing 7% Magnesium) to a Smelt that contains 46% Magnesium Chloride

STEP 3: Preparation of Magnesium Chloride Flakes by continuously cooling of the smelt on water-cooled cooling drum.

STEP 4: Product packing unit (50 Kg HDPE Woven Bags with Inner LLDPE Liners)

Material Balance for Magnesium Chloride-46 % (MgCl2) is given in Table 2-9.

Table 2-9: Mass Balance – Magnesium Chloride-46 % (MgCl2) S. N. Raw Materials Input/ MT of Product

1 37.5° Bittern 7% Mg 1.7 MT

2 CaCl2 70% 0.11 MT

3 Steam at 6 Bar 0.6 MT

S. No. Product Output/Day of Product (MT)

1 46% MgCl2 1 MT

2 By Product-Gypsum as 75% CaSO4.2H2O 0.162 MT

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2.5.8 Magnesium Sulphate-98 % (MgSO4)

Process Description

Step 1: Harvested Crude Epsom Salt + Saturated Brine Leaching (24° Brine)

Step 2: Crude MgSO4 Solution + Salt (Solid) + Filtration produces Crude MgSO4 Solution

Step 3: Crude MgSO4 Solution on Crystallization gives Epsom Salt

Step 4: Epsom Salt on Drying at 250°C produces MgSO4 (Product)

2.5.9 Co-Generation Power Plant

Coal/lignite based Captive Co-generation Power Plant (CPP) consists of condensing type steam turbine with boilers at operating steam temperature 540+/- 5deg C.

Basic process involves steam generation by combustion of coal in boiler. Steam is used to run turbine for power generation.

Electricity is generated and distributed to process plant.

Power plant is mainly divided in following sections:

1. Coal yard and coal handling plant 2. Boiler and auxiliaries 3. Steam turbine and alternator 4. Condensers 5. Utility 6. Ash disposal system 1. Coal yard and Coal handling plant

Coal unloading activity involves unloading of coal from dumpers and truck by JCB’s in coal yard. Coal is fed to coal bunker with the help of conveyor belt, screen and crusher.

2. Boiler and auxiliaries

There is a pulverized fuel boiler for generation of steam. It consists of steam drum, water wall and economizer. Heat generated due to coal combustion in the form of flue gas is used at various levels in boiler to maximize thermal efficiency. Steam is passed through super heaters to achieve final temperature.

3. Steam turbine and alternator

High temperature, high pressure steam enters in turbine where heat energy is converted into kinetic energy. Turbine is directly coupled to alternator where electricity is generated by electro motive force produced. Steam is extracted for process and for heating water before feeding in boiler from various extraction points in turbine. Power is generated and feed to different areas of plant through double bus bar system to cater high reliability of electrical system.

4. Condenser system

Exhaust steam is condensed and recycled in boiler with pumping devices at various stages with minimum make up of DM water.

5. Utility

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Instrument air compressors are installed for requirement of air at various control valves.

Cooling tower with well-designed water distribution system for removing heat from condenser, alternator, oil coolers and at various fan bearing locations.

6. Ash disposal system

The ash is trapped in ESP and stored in an ash silo. The ash shall be sold to brick making units.

The Flow diagram of Coal based co-generation power plant is given in Figure 2-5.

Figure 2-5: Flow diagram of CPP

2.6 Raw Materials

Raw material shall be sourced from registered supplier within India and Imported (if required) based on the need and availability. Details of raw material along with the Quantity and Means of storage is given in Table 2-10.

Table 2-10: Details of Raw Material Quantity and Means of Storage

S. No.

Raw Material State Existing Expansion

Consumption Storage Details Consumption Storage Details

1 KTMS-RM for

SOP Solid 83,000 TPM

Open area (60,000 m2)

2,49,000 TPM Open area

(1,50,000 m2)

2 Sea Water-RM

for SOP Liquid

2,00,000 (m3/month)

Reservoir (40000 m3)

6,00,000 (m3/month)

Reservoir (10,00,000 m3)

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S. No.

Raw Material State Existing Expansion

Consumption Storage Details Consumption Storage Details

3 Bittern-RM for

Br2 Liquid 2,10,000 TPM

Open reservoir (27,75,000 m3)

5,24,000 TPM Within Existing

area

4 Liquid Chlorine-

RM for Br2 Liquid 575 TPM

Tonners under chlorine shed (2,500 m2)

2,530 TPM Tonners under chlorine shed (3,750 m2)

5 Sulphuric acid-

RM for Br2 Liquid 533 TPM

Tanks

(40 MT x4) 2,346 TPM 300 MT

6 Castor Oil-

additive for Br2 Liquid 2.6 TPM

Cans in storage godowns

11.4 TPM Cans in storage

godowns

7 SO2- RM for

HBr Gas Nil Nil 200 TPM

Tonners under shed

8 BIS phenol-A-RM for TBBA

Solid Nil Nil 380 TPM HDPE Bags

9

Mono Chlorobenzene (MCB)-RM for

TBBA

Liquid Nil Nil 50 TPM Tanks

10 Sodium

Metabisulphite-RM for TBBA

Solid Nil Nil 24 TPM HDPE Bags in

storage godowns

11 Sodium

Sulphide-RM for TBBA

Solid Nil Nil 17 TPM HDPE Bags in

storage godowns

12 Hydrogen

Peroxide-RM for TBBA

Liquid Nil Nil 250 TPM Tanks

2.7 Utilities

2.7.1 Power Requirement

Co-generation power plant of 10 MW is existing and will undergo expansion of 35 MW for supply of power to the plant. 2 Nos. of DG Sets (3000 kVA + 500 KVA) will be installed & used during emergency conditions and power outrages only.

2.7.2 Fuel Requirement

Coal / Lignite will be used for boilers and HSD will be used for DG Sets. Details of the same is tabulated in Table 2-11

Table 2-11: Fuel Details

S. No.

Type of Fuel

Used in Quantity

Source Existing Proposed

1 Coal / Lignite

Coal Fire Steam Boiler 6.75 TPH 23.6 TPH Imported/ Indigenous

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S. No.

Type of Fuel

Used in Quantity

Source Existing Proposed

2 HSD DG Sets

(2 Nos. 3,000 kVA & 500 kVA) 680 Ltr/Hr. -

Local Depot/ Suppliers

2.7.3 Water Requirement

Total Water requirement of 75,000 KLD will be extracted from Sea. Flow chart of Water and waste water distribution is shown in Figure 2-6.

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Figure 2-6: Water Diagram

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2.8 Pollution Load on Environment due to Project

Environmental issues associated with pesticides manufacturing, formulation and packaging include:

Air emissions; Wastewater; Hazardous Materials; Wastes.

2.8.1 Air Emissions & Control

During construction phase, vehicular emissions shall be from use of construction machinery and vehicles. Apart from it, application of heavy machinery and earth movers will generate emissions. Suitable dust suppression techniques such as water sprinkling will be taken at these times as relevant.

The principal air pollutants are volatile organic compounds (HBr) and particulate matter (PM). It will be controlled by caustic scrubbers. Adequate stack height and proper pollution control equipment will be provided for all flue gas stacks & process stacks. Fugitive emissions from storage & handling of bromine is also envisaged due to the project.

The ambient air quality & stack emissions will be maintained as per GPCB/CPCB norms.

Details of existing & proposed stacks with fuel consumption and attached Air Pollution Control Equipment details are tabulated in Table 2-12

Table 2-12: Details of Existing & Proposed Stacks, Fuel Used and APCM

S. No.

Stack Attached to No of Stack

(Existing)

No of Stack

(Expansion) Fuel Used

APCM Expected Pollutants

Stack Height Existing & Proposed

(m)

Flue Gas Stacks

1 Boiler - 1 1 1

Coal / Lignite

ESP PM, SO2 &

NOx Common Stack

of 76 m 2 Boiler - 2

3 D.G. Set - 1 (3,000 kVA)

1 -

HSD Adequate Stack Ht.

PM, SO2 & NOx

30

4 D.G. Set -2

(500 kVA each) HSD

Adequate Stack Ht.

PM, SO2 & NOx

9

Process Stacks / Vents

1 Bromine Plant Process Vent

1 2 - Caustic

Scrubber HBr 29

2 Chlorine Vaporizer

Unit 1 1 -

Dry Absorbent Aluminum

Oxide

HBr 20

3 Bromine Bottling

Section 1 1 -

Caustic Scrubber

HBr 20

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2.8.2 Waste Water Generation

Waste Water Generation and Treatment Details

The waste water will be generated from the process, utilities and domestic area as shown in Table 2-13 and Figure 2-7

Currently, sewage is treated in STP (150 KLD). Waste water stream from SOP is sent to reservoir for further recovery. Effluent from bromine plant & boiler is treated in ETP designed for a flow rate of m3/hr. Treated effluent is send to Solar Evaporation ponds for evaporation. Settled sludge is used for bund and road strengthening and hence achieving Zero Liquid discharge.

For the expansion units, sewage will be treated in existing STP (150 KLD). Waste water stream from SOP will be sent to reservoir for further recovery. Effluent from proposed bromine plant & boilers shall be treated in proposed ETP designed for flow rate of 1,000 m3/hr. Treated effluent shall be send to Solar Evaporation ponds for evaporation. Effluent from Bromine plant shall be used for manufacturing of fine chemicals. Settled sludge will be used bund & road strengthening and hence achieving Zero Liquid discharge.

Table 2-13: Waste Water Details

S. No. Waste Water Stream Treatment/Disposal Recovery / Reuse

1 SOP Reservoir Recovery of other chemicals*.

2 Bromine ETP 1) Effluent - used for fine chemicals

(during expansion phase).

2) Solar Pond - Gypsum used for strengthening of bund & roads. 3 Boiler ETP

4 Cooling Systems & Washing Slurry preparation Lime slurry

5 Domestic STP Gardening

* Epsomite, MgSO4, MgCl2 and MgO

Block diagram of Effluent Treatment System is shown below as Figure 2-7.

Figure 2-7: Block Diagram of ETP

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2.8.3 Hazardous Waste and Other Solid Waste

Summary of Hazardous waste from the proposed unit is tabulated in Table 2-14.

Table 2-14: Hazardous Waste Details

S. No.

Type of Waste

Hazardous Waste Category

Generation (TPA) Source

Treatment / Disposal Existing Proposed

1 ETP sludge-

Gypsum 34.3 10,725 80,000 ETP

Used for preparation and maintenance of

bunds and roads

2 Used Oil 5.1 1 - DG Sets Sold to authorized recyclers/vendors

3 Fly Ash - 3,600 10,000 Power Plant

Sold to brick manufacturers

4 Discarded Bottles &

Bags 33.3 5 15

Bromine Section

Sold to authorized recyclers/vendors

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3 SITE ANALYSIS

3.1 Connectivity

3.1.1 By Road

ACIL has developed an approach road (Salt pan Road) from Hajipir which is ~ 16 Km in South Direction. This road connects to the State Highway (SH – 42) at a distance of ~ 30 Km in South Direction.

3.1.2 By Rail

Major railway station for public transportation is Bhuj Railway Station located at an aerial distance of ~80 Km in SE Direction from the project site.

3.1.3 By Air

Nearest airport from project site is Bhuj Airport located at an aerial distance of ~ 75 Km in SE Direction.

3.1.4 By Water

Jakhau harbour at Kutch is located at an aerial distance of ~90 Km in SW direction. Also, Kandla port at Gandhidham is located at an aerial distance of ~125 Km in SE direction.

3.2 Land Form, Land Use and Land ownership

The 500 ha un-surveyed land owned by the company is earmarked for industrial use. Only 15% of this land is used for existing plant activities. Remaining area is available for expansion project.

3.3 Topography (along with map)

Project site shown on Toposheet No. F42D1, F42D2, F42D5 & F42D6 (Kachchh, Gujarat) is shown in Annexure 4.

3.4 Existing Land Use Pattern

Waste land at Greater Rann of Kachchh has been developed for industrial use.

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3.5 Sensitive Areas

There are no villages within 10 Km from the project site. Distance of other villages from project site is tabulated in Table 3-1.

Table 3-1: Distance of Villages from Project Site

S. N. Villages Distance from Site (in Km) Direction w.r.t Site

1 Luna 13.29 S

2 Bhitara Mota 11.87 SE

3 Hajipir 16.07 SSW

4 Udhamo 21.57 ESE

5 Gorewali 29.2 ESE

6 Mithadi 25 SE

7 Nara 23.27 SSW

8 Jumara 24.29 SW

9 Dhoro 26.4 SSW

3.5.1 Water Bodies

There are no major water bodies in vicinity of site. Rann of Kachchh gets flooded with sea water. Distance and direction of other water bodies with respect to site are tabulated in Table 3-2.

Table 3-2: Distance of Ponds from Project Site S. N. Villages Distance from Site (in Km) Direction w.r.t Site

1 Luna Pond 13.57 SSE

2 Hajipir Pond 16.25 SSW

3 Chhari Lake 26.22 SSE

4 Nara Dam 24.17 SSW

3.5.2 Defense Installation

Site is approached through Border Security Force post which is at a distance of ~6-8 km from project site.

3.5.3 Religious Place

Hajipir, a religious place, visited by people during festivals is at a distance of ~16 km from project site.

3.5.4 Flora and Fauna

Banni Grasslands is an area spanning 3,500 sq km having a large shallow lake of 80 sq km. This area is best accessible from Nakhatrana and is part of Chari-Dhand Wetland Conservation Reserve. This makes the area heaven for birds for nesting and for bird watches to spot them. This area of great Rann of kutch lies on one of India’s most important avian highways (both the birds flying from the southward in winter and the few species migrating eastward from the middle-east and Africa stopover in this area) are a top site for birding with waterfowl congregations at Charri Fulay lake, grassland and scrubland birds, as also characteristic desert species seen in the vicinity.

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No forests, national park, wild life sanctuary, etc. are located in 15 Km from the nearest boundary of the project site. Details of reserve forest from the project site are tabulated in Table 3-3.

Table 3-3: Distance of Reserve Forest from Project Site S. N. Name of Reserve Forest Distance from Site (in Km) Direction w.r.t Site

1 Jumara 20.85 SW

2 Rajday 26 SSW

3 Lodiya 52 E

3.6 Social Infrastructure Available

Hajipir Village is the nearest habitation at an aerial distance of ~ 16 Km from project site having private hospital, school, place of worship and community facility.

3.7 Soil Classification

Soil investigation has been done and accordingly existing plant has been established.

3.8 Climatic Data from Secondary Sources

Based on the available long-term climatological tables (1961 – 1990) published by India Meteorological Department (IMD) of Bhuj (Rudramata (A)) District, average temperature, relative humidity and wind speed for summer season were 37.9°C, 48% and 16.5 Km/Hr respectively. 1st Pre-dominant wind direction is noted from West to East (42.12 %). 2nd pre-dominant wind direction is from SW to NE (21.7%).

Above mentioned climatic conditions will be considered during designing stage.

3.9 Existing Infrastructure

Existing infrastructure includes roads, Medical facility, Laboratory, Power plant, SOP plant, ETP, STP, Desalination Plant etc. at the project premises. Photographs of site are shown in Photograph 3-1.

Existing Project Site Bromine Bottling section

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Proposed Expansion Site Salt wash and conveyor area

EIA Team member at SOP Plant EIA Co-ordinator’ at Power Plant

Photograph 3-1: Photographs of Existing & Proposed Site

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4 PLANNING BRIEF

4.1 Planning Concept

Basic facilities of infrastructure like admin building, processing area, storage area, internal roads etc. are already developed on the project site and will be expanded as per the requirement. Transportation of raw material and finished goods will be carried out through approach road and finally through existing state high SH-42.

4.2 Assessment of Infrastructure Demand (Physical & Social)

Key infrastructure such as hospitals, schools, bank, places of worship and social/ community facilities such as park, market, playground etc. education, health care and community development are available in Nakhatrana Town.

4.3 Amenities/Facilities

Basic Amenities like public transport, water supply, telecommunications, educational institutions, hospitals etc. are available in Nakhatrana Town.

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PROPOSED INFRASTRUCTURE

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5 PROPOSED INFRASTRUCTURE

5.1 Industrial Area (Processing Area)

The industrial area shall comprise of following sections:

1. Process section 2. Raw material storage 3. Packing material storage 4. Finished product storage 5. ETP area

The Plant building will have ground floor + four floors for installing reaction vessels etc., and five mezzanine floors in between for installing heat exchangers, dosing vessels, receivers etc. Cooling tower and various scrubbers will to be located on the terrace roof.

SOP, Bromine and its derivatives will be manufactured in a dedicated set of equipment of the Plant.

Procurement of Raw materials will be undertaken as per the production plan maintaining their stock level around one week’s requirement.

Finished products will be stocked for a maximum period of one week under normal circumstances.

5.2 Residential Area (Non-Processing Area)

Requirement of residential area will be developed as shown below:

1. Administration building 2. Truck parking area 3. Security cabin 4. Utility area 5. Laboratory 6. Canteen

5.3 Equipment List

For the proposed project equipment mentioned in Table 5-1 shall be in place:

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Table 5-1: Equipment List S. N. Name of Equipment

Plant Section

1. MS Glass Lined Reactor

2. Reactor

3. Distillation Column

4. Evaporator

5. Heat exchangers

6. Centrifuge

7. Dryer

8. Centrifugal pump

9. Steam jet ejector

10. Storage Tank

11. MS Storage tank

12. Cooling tower with pumps

13. Chilled Water Plant with pumps

14. Steam Boiler

15. Compressed Air

16. BFW softener

17. HBr scrubber

18. Vent gas scrubber

Utility Section

19. Emergency Power Generator

20. Power transformer with switch gear

21. Water storage tank

22. Fire Hydrant System

23. Chlorine cylinder. Hoist

24. E T P

25. R O Plant

26. Fork Lift

27. STP

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5.4 Green Belt

Since, the project is located in Rann of Kachchh, having high alkalinity of the soil, it is not feasible to develop green belt. However, attempts are made to develop local species of the Rann as shown in Photograph 5-1.

Photograph 5-1: Green Belt Development at Existing Site

3 layers of green belt Green belt development along the periphery of the site

5.5 Social Infrastructure

Refer Chapter 3, Section 3.6.

5.6 Connectivity (Traffic and transportation road/ rail/metro/water ways etc)

Refer Chapter 3, Section 3.1.

5.7 Drinking Water Management (Source & Supply of Water)

Ground water is presently being purchased from nearby village and is used for domestic and process purposes after desalination.

5.8 Sewage System

Domestic waste water shall be treated STP and reused in gardening. Process waste will be treated in ETP and sludge will be used for strengthening of roads and bunds.

5.9 Solid & Industrial Waste Management

Solid and hazardous waste as mentioned in Chapter 2, Section 2.8.3 shall be collected, stored, disposed to authorized vendors and sold to local suppliers as per it’s characterization and based on the prescribed Hazardous Waste Rules, 2008 amended till date.

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6 REHABILITATION AND RESETTLEMENTS (R& R) PLAN

Not Envisaged as the expansion project site is a waste land developed for industrial use.

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PROJECT SCHEDULE & COST ESTIMATE

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7 PROJECT SCHEDULE AND COST ESTIMATE

7.1 Likely date of start of construction and likely data of completion

The construction is likely to start after getting Environmental Clearance and NOC/CTE from the authorized committee. The EIA studies are likely to get completed in 9-14 months. After receiving EC, tenders shall be floated, offers/bids shall be received. Once, CTE is obtained finalization of contractors, and civil work shall be started. Mechanical completion and commissioning is expected to be completed in 30 months. CTO shall be obtained before operating the plant.

7.2 Estimated Project Cost

The project cost is estimated to be INR 1,400 Crore. Summary of project cost is shown in Table 7-1.

Table 7-1: Project Cost S. No. Particulars Amount (INR in Crores)

1 Bromine Plant 600

2 SOP 250

3 MgO 300

4 Co-Generation Power Plant 120

5 Derivatives 60

6 Others (ETP, STP, Desalination Plant) 70

TOTAL 1,400

7.2.1 Profitability

ACIL will be the first manufacturer of SOP in India. Also, with this expansion project, they will be the biggest producers of Bromine and Bromine derivatives in India. The project will be a substitute of import of SOP and Bromine by providing a suitable source for import, export and coastal movement of SOP & Bromine. It will encourage industrial growth in the region and result in additional revenue for government.

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ANNXURES

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PRE-FEASIBILITY REPORT - EXPANSION OF CHEMICAL FERTILIZER MANUFACTURING UNIT AT GREATER RANN OF KACHCHH ANNEXURES

KADAM ENVIRONMENTAL CONSULTANTS | FEBRUARY, 2015 37

Annexure 1: Land Lease and Possession Documents

M/S. ARCHEAN CHEMICAL INDUSTRIES LIMITED

PRE-FEASIBILITY REPORT - EXPANSION OF CHEMICAL FERTILIZER MANUFACTURING UNIT AT GREATER RANN OF KACHCHH ANNEXURES

KADAM ENVIRONMENTAL CONSULTANTS | FEBRUARY, 2015 38

M/S. ARCHEAN CHEMICAL INDUSTRIES LIMITED

PRE-FEASIBILITY REPORT - EXPANSION OF CHEMICAL FERTILIZER MANUFACTURING UNIT AT GREATER RANN OF KACHCHH ANNEXURES

KADAM ENVIRONMENTAL CONSULTANTS | FEBRUARY, 2015 39

M/S. ARCHEAN CHEMICAL INDUSTRIES LIMITED

PRE-FEASIBILITY REPORT - EXPANSION OF CHEMICAL FERTILIZER MANUFACTURING UNIT AT GREATER RANN OF KACHCHH ANNEXURES

KADAM ENVIRONMENTAL CONSULTANTS | FEBRUARY, 2015 40

M/S. ARCHEAN CHEMICAL INDUSTRIES LIMITED

PRE-FEASIBILITY REPORT - EXPANSION OF CHEMICAL FERTILIZER MANUFACTURING UNIT AT GREATER RANN OF KACHCHH ANNEXURES

KADAM ENVIRONMENTAL CONSULTANTS | FEBRUARY, 2015 41

M/S. ARCHEAN CHEMICAL INDUSTRIES LIMITED

PRE-FEASIBILITY REPORT - EXPANSION OF CHEMICAL FERTILIZER MANUFACTURING UNIT AT GREATER RANN OF KACHCHH ANNEXURES

KADAM ENVIRONMENTAL CONSULTANTS | FEBRUARY, 2015 42

M/S. ARCHEAN CHEMICAL INDUSTRIES LIMITED

PRE-FEASIBILITY REPORT - EXPANSION OF CHEMICAL FERTILIZER MANUFACTURING UNIT AT GREATER RANN OF KACHCHH ANNEXURES

KADAM ENVIRONMENTAL CONSULTANTS | FEBRUARY, 2015 43

M/S. ARCHEAN CHEMICAL INDUSTRIES LIMITED

PRE-FEASIBILITY REPORT - EXPANSION OF CHEMICAL FERTILIZER MANUFACTURING UNIT AT GREATER RANN OF KACHCHH ANNEXURES

KADAM ENVIRONMENTAL CONSULTANTS | FEBRUARY, 2015 44

Copy of Lease Agreement – Translated in English

M/S. ARCHEAN CHEMICAL INDUSTRIES LIMITED

PRE-FEASIBILITY REPORT - EXPANSION OF CHEMICAL FERTILIZER MANUFACTURING UNIT AT GREATER RANN OF KACHCHH ANNEXURES

KADAM ENVIRONMENTAL CONSULTANTS | FEBRUARY, 2015 45

M/S. ARCHEAN CHEMICAL INDUSTRIES LIMITED

PRE-FEASIBILITY REPORT - EXPANSION OF CHEMICAL FERTILIZER MANUFACTURING UNIT AT GREATER RANN OF KACHCHH ANNEXURES

KADAM ENVIRONMENTAL CONSULTANTS | FEBRUARY, 2015 46

M/S. ARCHEAN CHEMICAL INDUSTRIES LIMITED

PRE-FEASIBILITY REPORT - EXPANSION OF CHEMICAL FERTILIZER MANUFACTURING UNIT AT GREATER RANN OF KACHCHH ANNEXURES

KADAM ENVIRONMENTAL CONSULTANTS | FEBRUARY, 2015 47

M/S. ARCHEAN CHEMICAL INDUSTRIES LIMITED

PRE-FEASIBILITY REPORT - EXPANSION OF CHEMICAL FERTILIZER MANUFACTURING UNIT AT GREATER RANN OF KACHCHH ANNEXURES

KADAM ENVIRONMENTAL CONSULTANTS | FEBRUARY, 2015 48

M/S. ARCHEAN CHEMICAL INDUSTRIES LIMITED

PRE-FEASIBILITY REPORT - EXPANSION OF CHEMICAL FERTILIZER MANUFACTURING UNIT AT GREATER RANN OF KACHCHH ANNEXURES

KADAM ENVIRONMENTAL CONSULTANTS | FEBRUARY, 2015 49

M/S. ARCHEAN CHEMICAL INDUSTRIES LIMITED

PRE-FEASIBILITY REPORT - EXPANSION OF CHEMICAL FERTILIZER MANUFACTURING UNIT AT GREATER RANN OF KACHCHH ANNEXURES

KADAM ENVIRONMENTAL CONSULTANTS | FEBRUARY, 2015 50

M/S. ARCHEAN CHEMICAL INDUSTRIES LIMITED

PRE-FEASIBILITY REPORT - EXPANSION OF CHEMICAL FERTILIZER MANUFACTURING UNIT AT GREATER RANN OF KACHCHH ANNEXURES

KADAM ENVIRONMENTAL CONSULTANTS | FEBRUARY, 2015 51

M/S. ARCHEAN CHEMICAL INDUSTRIES LIMITED

PRE-FEASIBILITY REPORT - EXPANSION OF CHEMICAL FERTILIZER MANUFACTURING UNIT AT GREATER RANN OF KACHCHH ANNEXURES

KADAM ENVIRONMENTAL CONSULTANTS | FEBRUARY, 2015 52

M/S. ARCHEAN CHEMICAL INDUSTRIES LIMITED

PRE-FEASIBILITY REPORT - EXPANSION OF CHEMICAL FERTILIZER MANUFACTURING UNIT AT GREATER RANN OF KACHCHH ANNEXURES

KADAM ENVIRONMENTAL CONSULTANTS | FEBRUARY, 2015 53

Annexure 2: General and Specific Location Map

M/S. ARCHEAN CHEMICAL INDUSTRIES LIMITED

PRE-FEASIBILITY REPORT - EXPANSION OF CHEMICAL FERTILIZER MANUFACTURING UNIT AT GREATER RANN OF KACHCHH ANNEXURES

KADAM ENVIRONMENTAL CONSULTANTS | FEBRUARY, 2015 54

Annexure 3: Project Boundary Map

M/S. ARCHEAN CHEMICAL INDUSTRIES LIMITED

PRE-FEASIBILITY REPORT - EXPANSION OF CHEMICAL FERTILIZER MANUFACTURING UNIT AT GREATER RANN OF KACHCHH ANNEXURES

KADAM ENVIRONMENTAL CONSULTANTS | FEBRUARY, 2015 55

Annexure 4: Project Site Located on Toposheet

(Map showing Project Site on Toposheet No. F42D1, F42D2, F42D5 & F42D6 (Kachchh, Gujarat) – 5 Km Radius Circle)

M/S. ARCHEAN CHEMICAL INDUSTRIES LIMITED

PRE-FEASIBILITY REPORT - EXPANSION OF CHEMICAL FERTILIZER MANUFACTURING UNIT AT GREATER RANN OF KACHCHH ANNEXURES

KADAM ENVIRONMENTAL CONSULTANTS | FEBRUARY, 2015 56

(Map showing Project Site on Toposheet No. F42D1, F42D2, F42D5 & F42D6 (Kachchh, Gujarat) – 10 Km Radius Circle)

CONTACT DETAILS

Vadodara (Head Office)

871/B/3, GIDC Makarpura, Vadodara, India – 390 010.

E: [email protected]; T:+91-265-3001000; F: +91-265-3001069

Delhi / NCR

Spaze IT Park, Unit No. 1124, IIth Floor, Tower B3, Sector 49, Near Omaxe City Centre Mall, Sohna Road, Gurgaon, Haryana, INDIA - 122002.

E: [email protected]; T: +91-124-4242430 to 436; F: +91-124-4242433

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