K-PURE® - King Industries · Min. Activation Blocking Type Range, °C Attributes TAG-2713 Amine...
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K-PURE® Specialty Additives For Electronic Applications SPECIALTY CHEMICALS ®
Transcript of K-PURE® - King Industries · Min. Activation Blocking Type Range, °C Attributes TAG-2713 Amine...
K-PURE®Specialty AdditivesFor Electronic Applications
SPECIALTY CHEMICALS®
The K-PURE® trademark is used for a range of products that meet the specific needs of various segments in the electronic chemicals market. K-PURE additives and resin modifiers reflect King’s decades of experience in corrosion inhibition, resin modification and catalysis.
K-PURE TAGs and CXC - Thermal Acid Generators and Catalysts
K-PURE TAG and CXC blocked acids are particularly e�ective for accelerating and lowering the activation temperature of stable, one component systems based on; aminoplast, glycoluril, siloxane, silanol and phenoxy condensation reactions as well as epoxy homopolymerization and co-polymerization with polyols, vinyl ethers, oxetane and anhydride resins.
O
SR
O
O-R1
H+N
R2
R3
R1
:NR2
R3
O
SR
O
OHheat
volatile species
O
SR
O
O RO
SR
O
OH * R+heat
reactive species
H+
N+R1
R3 Ar
R2
heat N+
R3 Ar
R2
R1
H
H
O
SR
O
O-O
SR
O
O-O
SR
O
O- Me+
O
SR
O
O-
2
Me++or
K-PURE CDR - Resin Modi�ers
K-PURE resin modi�ers o�er formulators three core chemistries that can be used to improve mechanical properties, crosslinking density and resistance properties. Core chemistries include unique ester diols with low molecular weight and very narrow molecular weight distribution, urethane diols with an aliphatic urethane backbone and an acteoacetate functional reactive diluent.
K-PURE CDR Mechanical Properties(4:1 Epoxy/Hydroxy - Cycloaliphatic Diepoxide, 1 hour @ 100°C)
Control +29% CDR-3314
+27% CDR-3316
+41% CDR-3315
Tensile Strength, psi
Tensile Elongation, %
Young’s Modulus, psi
Viscosity, cPs
1188 7918 7603 3137
0.5 3.7 3.8 19.5
307,000 227,000 225,700 2,641
370 640 400 850
Excellent Clarity
K-PURE CDI - Corrosion Inhibitors
With over �ve decades experience in corrosion protection technologies, King Industries o�ers a broad range of core chemistries and products for the protection of ferrous and non-ferrous metals.
Amine Blocked Acids
Metal Blocked AcidsQuaternary Blocked Acids
Covalently Blocked AcidsSolubility in water and polar solventsBroad activation temperature rangeVolatile by-product
No volatile by-productsNarrower solubility range (hydrophobic)Solventbased
Broad control over activation range100% solids - white powdersNarrower solubility range (hydrophobic)No volatile component
Mono and divalent metalsSurface active compoundsHydrophobic and hydrophilic Corrosion inhibition with catalytic behavior
K-PURE CDI-4311Aluminum Substrate
K-PURE CDI-4302Copper Substrate
K-PURE CDI-4302 & CDI-4312Silver Substrate
Immersed Vapor
No Additive
1% Additive A
No Additive No Additive
1% CDI-4311
1% CDI-4302 1% CDI-4312
1% CDI-43021% Additive A
Immersed Vapor ImmersedVapor
Polished aluminum partially immersed in water based solution, pH 9 for 24 hours @ 50°C.
Polished copper partially immersed in water based solution, pH 9 for 24 hours @ 50°C.
Polished silver partially immersed in water based solution, pH 6 for 24 hours @ 50°C.
K-PURE TAG products are made to meet the needs of the semiconductor manufacturing market. Each are certi�ed for trace metals content. Standard metals testing include Na, Mg, Al, K, Ca, Cr, Mn, Fe, Ni, Cu, Zn, Pb.
Blocking techniques and features are:
Min. Activation Range, °C Attributes Blocking Type
TAG-2713 Amine Solventbased, low color
CXC-1820 Amine Waterbased, low color
120-140
120-140pTSA
TAG-2172 Amine Low color, more hydrophobic
TAG-2179 Amine Low color, more hydrophobic
120-140
160-180
DD
BSA
TAG-2507 Covalent Hydrophobic120-140
CXC-1612 Quaternary Powder, most e�cient product
Liquid, 60% in H2O/alcohol
Powder, lowest temperature
Powder
Powder, improved solubility/stability
Powder, highest temperature
Solventbased 2K systems
Powder, Non Sb version of 1612
80-110SbF 6
CXC-1615 Amine
CXC-1614 Quaternary
100-120
100-150
OTf TAG-2678 Quaternary 100-150
TAG-2689 Quaternary
TAG-2690 Quaternary
130-170
180-220
CXC-1613 Metal 60-100
CXC-1821 Quaternary 80-110
TPFB
CXC-1756 Metal Liquid, water or solvent 110-130
CXC-1767 Amine 110-140
Oth
er
OH # / AN / EW Viscosity Range, cPs Tg Adhesion Toughness
CDR-3314
Este
r Dio
ls CDR-3315
225-245 (OH#)
132-145 (OH#)
10,000 - 12,000 High Best
Low Good
Excellent
Good
Good4,000 - 5,000
CDR-3316
CDR-3317
Ure
than
e
250-270 (OH#)
340-360 (OH#)
1,200 - 1,800 Med Best
High Good Good150,000 - 300,000
CDR-3320
CDR-3441
190 (EW)
135 (OH#) / 30 (AN)
900 - 1,200 N/A Fair
Low Best
Best
Fair40,000 - 60,000
Core Chemistries
Sulfonic Acid Amino AcidDerivatives
TriazoleDerivatives
AcetoacetatePolymers Phosphate
Type of Protection
K-PURE CDI Products
Ferrous Ferrous & Soft Metals Ferrous & Soft MetalsSoft Metals Aluminum
CDI-4301CDI-4303CDI-4310
CDI-4302CDI-4308 CDR-3320
CDI-4311CDI-4312
Low color. Alternative to pTSA where sublimation is concern
Am
inop
last
and
Sila
ne
Cond
ensa
tion
Reac
tions
Epox
y H
omop
olym
eriz
atio
n an
d Co
poly
mer
izat
ion
Reac
tions
with
alc
ohol
or v
inyl
eth
er
Epoxy Anhydride
K-PURE® Selection ChartO
ther
AA
Global HeadquartersTech. Service, R&D, and SalesKing Industries, Inc.1 Science Rd.Norwalk, CT 06852Phone: 1-203-866-5551
European Tech. Sales O�ceKing Industries, InternationalNoordkade 642741 EZ WaddinxveenThe NetherlandsPhone: 31 182 631360
Asia-Paci�c Tech. Sales O�ceSynlico Tech Co., Ltd.42 Ju Lin Ya YuanRichMond Hill (Juhaoyuan)Zhongshan, ChinaPhone: 86 760 88229866
Contact Information www.kingindustries.com
The conditions of your use and application of our products, technical assistance and information (whether verbal, written or by way of product evaluations), including any suggested formulations and recommendations, are beyond our control. Therefore, it is imperative that you test our products, technical assistance and information to determine to your own satisfaction whether they are suitable for your intended uses and applications. Such testing has not necessarily been done by King Industries, Inc. ("King"). The facts, recommendations and suggestions herein stated are believed to be reliable; however, no guaranty or warranty of their accuracy is made. EXCEPT AS STATED, THERE ARE NO WARRANTIES, EXPRESS OR IMPLIED, OF MERCHANTABILITY, FITNESS OR OTHERWISE. KING SHALL NOT BE HELD LIABLE FOR SPECIAL, INCIDENTAL, CONSEQUENTIAL OR EXEMPLARY DAMAGES. Any statement inconsistent herewith is not authorized and shall not bind King. Nothing herein shall be construed as a recommendation to use any product(s) in con�ict with patents covering any material or its use. No license is implied or granted under the claims of any patent. Sales or use of all products are pursuant to Standard Terms and Conditions stated in King sales documents.
SPECIALTY CHEMICALS®
K-PURE_tvs 4/4/16
ISO 14001ISO 9001 OHSAS 18001
K-PURE® Specialty Chemicals
References
Tri�uoroantimonate sulfonic acid
SbF6
Dodecylbenzene
pTSAPara toluene sulfonic acid
Hexa�uoroantimonate
Tetrakis (penta�uorophenyl) borate TPFB
Acetoacetate AA
DDBSA
OTf
Notes:
