Jan.22 Fuels and Vehicle Technology

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    JAJA Workshop for IWorkshop for I--J EPA SWG2J EPA SWG2 . 22, 2010. 22, 2010

    Automotive FuelsAutomotive Fuels

    and Vehicle Technologyand Vehicle Technology

    for Sustainable Mobilityfor Sustainable Mobility

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    Air QualityGlobal Warming

    Surroundings of AutomobilesSurroundings of Automobiles

    Emissions

    CO2

    EnergyCO2 reduction

    Energy

    Three major issues : Energy, COThree major issues : Energy, CO22 reduction, Air qualityreduction, Air quality

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    AutomakersAutomakersEfforts to the IssuesEfforts to the Issues

    Fuel Efficiency Improvement Technology

    Alternative Fuel Vehicle Technology

    Emissions reduction Technology

    Body:Vehicle weight reduction, Reduced aerodynamic resistance

    Engine improvements:

    Combustion, VVT, Reduction of friction lossDrive-train improvements:CVT, Increased number of gearNew System:Hybrid vehicle, EV

    including improvement of fuel quality

    Biofuel, FTD, CNG, Fuel Cell Vehicle

    Combustion, Fuel injection spray, Thermal management,After-treatment system:Catalyst performance, DPF

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    ContentsContents

    1. Fuel Efficiency & CO2Reduction and

    Vehicle Technology

    2. Air Quality Improvement and Fuel Quality

    3. International Approach for Fuel Quality

    4. Bio Fuels

    5.5. International Approach for HarmonizationInternational Approach for HarmonizationofofBiofuelBiofuelSpecificationSpecification

    4

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    ContentsContents

    1. Fuel Efficiency & CO2Reduction and

    Vehicle Technology

    2. Air Quality Improvement and Fuel Quality

    3. International Approach for Fuel Quality

    4. Bio Fuels

    5.5. International Approach for HarmonizationInternational Approach for HarmonizationofofBiofuelBiofuelSpecificationSpecification

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    Engine Technologies for Fuel EfficiencyEngine Technologies for Fuel Efficiency

    Valve-train

    Roller cam followerVariable valve timingVariable valve lift

    Intake air systemElectronic throttleHigh volume EGR

    CombustionIgnition systemDirect injection

    Combustion chamber

    Reduced friction lossPiston surface treatmentLow tension piston ring

    Low viscosity oil

    Variable Valve actuation

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    CVT

    DriveDrive--train Technologies for Fuel Efficiencytrain Technologies for Fuel Efficiency

    Automatic TransmissionIncreased number of gearExpanded lock-up area

    Neutral controlCVT (Continuously Variable Transmission)

    Electric powerElectric 4-wheel driveHybrid system

    Manual TransmissionAutomatic MTReduced friction loss

    Engine

    Motor

    Inverter

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    Clean Energy VehiclesClean Energy Vehicles

    Hybrid Vehicle

    CNG Vehicle

    Electric Vehicle

    LPG Vehicle

    Plug-in Hybrid Vehicle

    Clean Diesel VehicleFuel cell Vehicle

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    ContentsContents

    1. Fuel Efficiency & CO2Reduction and

    Vehicle Technology

    2. Air Quality Improvement and Fuel Quality

    3. International Approach for Fuel Quality

    4. Bio Fuels

    5.5. International Approach for HarmonizationInternational Approach for HarmonizationofofBiofuelBiofuelSpecificationSpecification

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    Aggregate Annual Air Quality TrendsAggregate Annual Air Quality Trends

    in Asian Citiesin Asian Cities

    Source:www.cleanairnet.org/caiasia/1412/article-72383.html

    350

    300

    250

    200

    150

    100

    50

    01993 1995 1997 1999 2001 2003 2005 2007

    TSP

    PM10

    SO2

    WHO guideline

    WHO guideline

    WHO guideline

    g/m3

    Year

    11

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    Changes in Japans Annual Air Pollution AveragesChanges in Japans Annual Air Pollution Averages

    00

    0.020.02

    0.040.04

    0.060.06

    0.080.08

    0.10.1

    0.120.12

    0.140.14

    0.160.16

    0.180.18

    7070 7272 7474 7676 7878 8080 8282 8484 8686 8888 9090 9292 9494 9696 9898 0000 0202 0404 (year)(year)

    Average data taken by theAll Motor Vehicle Emission

    Monitoring Station

    Average data taken by theAll Motor Vehicle Emission

    Monitoring Station

    NO2 (ppm)NO2 (ppm)

    SPM (mg/m3)SPM (mg/m3)

    Conce

    ntration

    Conce

    ntration

    NO2 standard

    SPM standard

    Air Quality Improvement in JapanAir Quality Improvement in Japan

    (Source: Ministry of the Environment)(Source: Ministry of the Environment)2007 Rate for meeting environmental quality standards2007 Rate for meeting environmental quality standards

    Achieved rateAchieved rate

    Nitrogen dioxide

    NO2

    Nitrogen dioxide

    NO2

    Suspended

    particulate matter

    SPM

    Suspended

    particulate matter

    SPM

    100%100%

    94.4%94.4%

    89.5%89.5%

    88.6%88.6%

    Urban backgroundUrban background

    RoadsideRoadside

    Urban backgroundUrban background

    RoadsideRoadside

    NO2 and SPM are improving, but some areas have not reached targets

    0606

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    * 100% = Emission volume without regulations * IW = Equivalent inertia mass

    1965 1970 1975 1980 1985 1990 1995 2000

    COCO

    NOxNOx

    HCHC

    100

    0

    100

    0

    100

    50

    0

    50%60%

    45% 5%

    59%75%

    48%8%

    Mode change

    (1010-15)

    Mode change(1010-15)

    Mode change

    (10

    10-15)

    39%

    70%

    8%20%

    27%

    * IW 1,000kgIW > 1,000kg

    50

    50

    2.6%

    2.6%

    1.6%

    2005

    (0.8%)

    (1.3%)

    (1.3%)

    Transition of Emission regulation in JapanTransition of Emission regulation in Japan(Gasoline passenger cars)(Gasoline passenger cars)

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    * Direct-injection diesel trucks, medium-duty (over 1.7t, up to 2.5t)

    1975 1980 1985 1990 1995 2000 2005

    COCO

    1975 1980 1985 1990 1995 2000 2005

    100%

    Initial value 30%

    Mode 6concentration reg

    Mode 10-15 mass reg(Unregulated)

    NOxNOx

    HCHC

    1975 1980 1985 1990 1995 2000

    19%

    80%

    2005

    68%

    56%49%

    40% 100%

    Initialvalue

    54% 38%

    Mode 6concentration reg

    Mode 10-15 mass reg

    1975 1980 1985 1990 1995 2000 2005

    100%

    Initial value 30%6%

    Mode 6concentration reg

    Mode 10-15 mass reg

    100%(Unregulated)

    (Unregulated)

    PMPM100%

    Initialvalue

    30%

    Mode 10-15 mass reg

    36%6%

    Black smokeconcentration reg

    Transition of Emission regulation in JapanTransition of Emission regulation in Japan(Diesel Trucks)(Diesel Trucks)

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    Emission and Fuel Regulations in JP & EUEmission and Fuel Regulations in JP & EU

    GasolineGasoline

    Euro3Emission

    regulations

    Euro4

    S150S150 S50S50

    S10 Incentive

    S10S10

    S50Fuel quality

    Euro2Euro1

    All Model All Model

    Europe

    S500S500

    0098 0296 04 06 0894 10929088

    New Short-TermEmissionregulations New Long-Term

    S100, RVP (T50:75S100, RVP (T50:75--110)110) S50S50

    S50 S10Fuel quality

    S10S10

    Japan

    1973 Reg

    1975-77 Reg

    1978 Reg

    Euro5

    0098 0296 04 06 0894 10929088

    (Implemented)

    (Implemented)

    Post New

    Long-Term

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    Emission and Fuel Regulations in JP & EUEmission and Fuel Regulations in JP & EU

    DieselDiesel

    Euro3Emission

    regulations

    Euro4

    S350S350 S50S50

    S10 Incentive

    S10S10

    S50

    Fuel quality

    Euro2Euro1

    All Model All Model

    S2000S2000 S500S500

    Europe

    New Short-Term

    Emission

    regulationsNew Long-Term

    S500S500 S50S50

    S50

    Fuel quality S5000S5000

    From 1974

    S10S10

    Japan

    1974 Reg

    1986 Reg 1990 Reg (NOx) 1994 Reg (PM)

    97 Reg(NOx, PM)

    S2000S2000

    S10

    0098 0296 04 06 0894 10929088

    0098 0296 04 06 0894 10929088

    S2000

    S2000(Implemented)

    (Implemented)

    Post NewLong-Term

    Euro5

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    Air qualityAir quality

    improvementimprovement

    VehicleTechnology

    Low Emission

    ReliabilityFuel Economy

    Energy SecurityEnergy Security

    COCO22 ReductionReduction

    Relations between Fuel ImprovementRelations between Fuel Improvement

    and Vehicle Technologyand Vehicle Technology

    Sustainable FutureSustainable Future

    Fuel Improvement Emission Regulation

    Fuel QualityFuel Quality

    Bio Fuels

    CombinedCombined

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    Gasoline Quality for Low EmissionsGasoline Quality for Low Emissions

    Fuel quality to maximize the catalyst performance;

    For air fuel ratio controlDistillation properties (and RVP)Detergent (preventing deposits)

    For quicker warm up of catalystLowering sulfur

    For keeping higher conversion efficiencyLowering sulfurMetal Free

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    Effects of Sulfur on Exhaust EmissionsEffects of Sulfur on Exhaust Emissions

    Three Way Catalyst

    SULEV : Super Ultra Low Emission Vehicle

    ULEV : Ultra Low Emission VehicleLEV : Low Emission Vehicle SAE 2000-01-2019

    Rela

    tiveNOx

    150

    -50

    0

    100

    50

    0 100 200 300 400 500 600Sulfur (ppmw)

    SULEVLEV,ULEV

    Rela

    tiveTHC

    150

    -50

    0

    100

    50

    0 100 200 300 400 500 600Sulfur (ppmw)

    SULEV

    LEV,ULEV

    Emissions from Gasoline Vehicle

    Sulfur gives a significant impact on exhaust emissions.

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    Increasing T50/T90 increases HC emissions dramatically.

    -20

    0

    20

    40

    60

    80

    70 80 90 100 110 120 130

    T50 (deg.C)

    RelativeHC

    -20

    0

    20

    40

    60

    80

    120 140 160 180

    T90 (deg.C)

    RelativeHC

    Note:Base (0) is data from test gasoline that has about 98deg.C of T50 and about 148deg.C of T90

    Effects of T50 & T90 on Exhaust HCEffects of T50 & T90 on Exhaust HC

    Auto/Oil Phase2Current fleet AQIRP Final ReportEPEFE Aromatics/E100 Study SAE972851Toyota SAE972851Ricardo SAE952522

    VehicleTier1Step2

    TLEV/LEVStep2

    Test Mode75FTPSTEP375FTPSTEP2

    Summary of Published DataSummary of Published Data

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    Diesel Fuel Quality for Low EmissionsDiesel Fuel Quality for Low Emissions

    Fuel quality to reduce emissions and protect systems

    For After Treatment Systems and EGR

    Lowering sulfur

    For reducing engine-out emissions

    Increasing CetaneLowering aromatics and T90

    For CR-DI systemsMetal FreeKeep Lubricity

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    0.000

    0.020

    0.040

    0.060

    0.080

    0.100

    0 30000 0 30000 0 30000, km

    PM

    g/kWh Drysoot+H2OSulfate

    SOF

    JARI Engine test cycle

    Distance traveled accumulationkm

    PM Emissions from Diesel Vehicle

    Effect of Sulfur on DPFEffect of Sulfur on DPF

    Sulfur10ppm

    50ppm

    100ppm

    Sulfur effect on sophisticated after treatment system is significant .

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    Milea

    gewhenm

    alfunctionw

    asoccurre

    d

    HFRR(m)Lubricity of fuels in vehicle tank

    0 100 200 300 400 500 600 700 8000

    50000

    100000

    150000

    Market Problem caused by Low LubricityMarket Problem caused by Low Lubricity

    Low lubricity fuels give fetal damage to FIE(*) immediately.* FIE = Fuel Injection Equipment (Fuel Injector and Injection pump) 23

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    The 4th Edition of WWFCThe 4th Edition of WWFC

    The 4th edition WWFC isThe 4th edition WWFC is

    available in following sites.available in following sites.

    WWFCWWFC--The objectiveThe objective

    www.autoalliance.orgwww.acea.be

    www.jama-english.jp

    www.enginemanufacturers.org

    The objective of the global fuels harmonization

    effort is to develop common, world-wide

    recommendations for quality fuels, taking into

    consideration customer requirements and

    vehicle emission technologies.

    WWFCWWFC(World Wide Fuel Charter)(World Wide Fuel Charter)

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    Emission regulations of MotorcyclesEmission regulations of Motorcycles

    2002

    EU

    2003 2004 2005 2006 2007 2008 2009 2010

    Japan

    Thailand

    China

    Indonesia

    Vietnam

    5th 6th

    EURO-2 EURO-3

    2nd

    EURO-2 EURO-3

    EURO-2

    EURO-2

    EURO-2 EURO-3 or equivalent

    4th

    1 st

    EU Regulation (g/km)

    Euro 2

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    Emission Control Technology of MotorcycleEmission Control Technology of Motorcycle

    Carburetor

    Oxidation catalystSecondary air

    Fuel injection system

    Electric controlThree-way catalystO2 sensor

    Catalyst / quick warm-up4 stroke engine

    Euro 2

    Euro 3

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    ContentsContents

    1. Fuel Efficiency & CO2Reduction and

    Vehicle Technology

    2. Air Quality Improvement and Fuel Quality

    3. International Approach for Fuel Quality4. Bio Fuels

    5.5. International Approach for HarmonizationInternational Approach for HarmonizationofofBiofuelBiofuelSpecificationSpecification

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    International Approach for Fuel QualityInternational Approach for Fuel Quality

    // United Nations Environment Program / Partnership for Clean Fuels and VehiclesThe PCFV aims to assist developing countries to reducevehicular air pollution through the promotion of clean fuelsand vehicles.

    The partnership operates towards the implementation oftwo identified priority areas: the elimination of lead ingasoline and the phase down of sulfur in diesel and gasolinefuels, and the adoption of cleaner vehicle technologies.

    The Partnership aims to encourage countries to adoptoverall clean fuel and vehicles strategies, including vehicleand fuel standards, inspection and maintenance.

    http://www.unep.org/pcfv/28

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    Diesel Fuel Sulfur Levels : Global Status

    http://www.unep.org/pcfv/29

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    UNECE / WP29UNECE / WP29UNECE : United Nations Economic Commission for EuropeWP29 : World Forum for Harmonization of Vehicle Regulations

    International Approach for Fuel QualityInternational Approach for Fuel Quality

    WP29 aims to introduce the international harmonization ofvehicle regulations and the mutual recognition of the vehiclecertification between the importing and exporting country orregions each other.

    WP29 recognize that the market fuel quality must becompatible with vehicle technology.

    IPIECA and OICA are starting to discuss the fuelparameters which should be included in possible WP29guideline.

    IPIECA : International Petroleum Industry Environmental Conservation AssociationOICA : International Organization of Motor Vehicle Manufacturers30

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    ContentsContents

    1. Fuel Efficiency & CO2Reduction and

    Vehicle Technology

    2. Air Quality Improvement and Fuel Quality

    3. International Approach for Fuel Quality4. Bio Fuels

    5.5. International Approach for HarmonizationInternational Approach for HarmonizationofofBiofuelBiofuelSpecificationSpecification

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    JAMA Position about Bio FuelsJAMA Position about Bio Fuels

    From the view point of energy security and CO2reduction, bio-fuels become more important.

    JAMA positively corresponds to the introduction ofthe biofuels.

    There are issues to be solved, Good fuel quality at the pump to prevent problems

    and to protect bio fuel reputations.

    Competition with food Cost, etc.

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    Ethanol

    FAME

    Diesel

    Gasoline

    Bio FuelsBio Fuels

    Corn

    Sugarcane

    Wheat

    Wood Cellulose

    Rapeseed

    Palm

    Soybean

    JatrophaCoconut

    Cooking Oil

    Bio Ethanol

    Bio Diesel

    Fatty Acid Methyl Esters

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    Carbonnumber

    Coconut PalmRape-seed

    Jatropha Soy-bean

    Fatty acid

    8 0 Caprylic acid10 0 Capric acid12 0 Lauric acid14 0 Myristic acid16 0 Palmitic acid16 1 Palmitoleic acid18 0 Stearic acid18 1 Oleic acid18 2 Linoleic acid18 3 Linolenic acid20

    Composition of Carboxyl Acids in FAMEComposition of Carboxyl Acids in FAMENumber of

    Double bonds

    The more, the less stable34

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    Aldehyde

    OOO

    O OO O

    OO

    O

    OO

    Acid

    Source: SAE 2008-01-2502

    Oxidation Pathways for FAMEOxidation Pathways for FAME

    Oleic Acid Methyl Ester

    polymerizeOxidize

    Polymer

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    Metal Corrosion

    Deposit

    Deposit

    It is necessary to use high-quality biodiesel fuelto prevent these troubles.

    Example of troublesExample of troubles

    caused bycaused byLow QualityLow QualityBiodieselBiodiesel

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    Source: METI Conformity Test

    Dosage of Anti-Oxidant Agent, ppmOxidationStability,HrbyRancimat

    200 400 600 800 120010000

    5

    10

    15

    20

    0

    Effect of AntiEffect of Anti--Oxidant on B100Oxidant on B100

    Oxidation Stability of PME

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    Recommendation of AntiRecommendation of Anti--OxidantOxidant

    CEN Standards recommend the use of Anti-Oxidant

    Final draft of Diesel blending FAME (prEN590)

    Fatty acid methyl ester (FAME)- - -

    It is strongly recommended to add oxidation stability enhancingadditives in the FAME product, at the production stage and

    before storage, providing an action similar to that obtained with1000 mg/kg of butylated hydroxyl-toluene (BHT).

    Final draft of FAME (prEN14214) Stabilizing agentsIn order to improve the long term stability of FAME, it isrecommended that stabilizing agents should be added to theproduct immediately after its production, at least before itseventual blending into a mixture with petroleum based diesel fuel.

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    HydroHydro--treating of Vegetable Oiltreating of Vegetable Oil

    CH3

    CH3

    CH3 CO-O-CH2

    CO-O-CH

    CO-O-CH2

    Hydro-treating FAME

    3 O 2

    -

    - 2

    CO2, CH4

    3 HC CH33 HC CH3

    H2O H2O

    CH3-CH2-CH3

    3 HC CO-O-CH3

    CH OHCH2OHCH2OH

    CH OHCH2OH

    CH2OH

    Source : Nippon Oil / TOYOTA JSAE Nov.29, 2006

    Double bond

    (glycerin)

    Hydrogenated

    Vegetable Oil

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    FAME has poor oxidation stability, and might causetroubles in the fuel system when fuel quality cannotbe secured.

    Adequate Specifications, Good house keeping andFuel quality monitoring system for biodiesel arenecessary.

    It will be more preferable to utilize BTL Biomass ToLiquid or Hydrogenated Biodiesel ascompared to the use of FAME from the technical viewpoints.

    Requirement from Automobiles forRequirement from Automobiles forBiodieselBiodiesel

    Biomass to LiquidBiomass to LiquidHydrogenatedHydrogenated BiodieselBiodiesel

    FAMEFAME40

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    ContentsContents

    1. Fuel Efficiency & CO2Reduction and

    Vehicle Technology2. Air Quality Improvement and Fuel Quality

    3. International Approach for Fuel Quality4. Bio Fuels

    5.5. International Approach for HarmonizationInternational Approach for HarmonizationofofBiofuelBiofuelSpecificationSpecification

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    ISO / TC28 / TC7 LiquidISO / TC28 / TC7 Liquid BiofuelsBiofuelsObjectivesTo harmonize the specifications and test methods of biofuels

    in case of the increase of trade between markets world wide

    ProgressFirst meeting was held in Rio de Janeiro on 27-28 Jan. 2009.

    Discussions were Sustainability criteria for biofuels, andStandardization of terminology, classification, specification,

    analysis and testing for liquid biofuels.

    International Organization for Standardization

    International Approach forInternational Approach for

    Harmonization ofHarmonization ofBiofuelBiofuelSpecificationSpecification

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    Objectives To get a common agreement for BDF standardization.

    To support the formulation of BDF standards in ASEAN

    and East Asia.

    MembersAustralia, China, India, Indonesia, Malaysia, New Zealand,

    Philippines, Singapore, South Korea, Thailand, Vietnam and JapanOutcomeProposal of BDF specification was decided by the meeting

    held in Indonesia on November, 2008.

    ERIA:Economic Research Institute for ASEAN and East Asia ERIA Energy ProjectERIA Energy ProjectWorking Group for the Standardization of Biodiesel Fuel in East Asia

    International Approach forInternational Approach for

    Harmonization ofHarmonization ofBiofuelBiofuelSpecificationSpecification

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    WWFCWWFC

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    WWFCWWFC World Wide Fuel Charter E100 & B100 guidelines for E10 & B5 will be published

    soon for harmonize the fuel quality worldwide.

    B100Guidelines

    E100Guidelines

    44

    F S i bl M biliF S t i bl M bilit

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    For Sustainable MobilityFor Sustainable Mobility

    Government

    Auto Industries Oil Industries

    EnvironmentProtection

    EnvironmentEnvironment

    ProtectionProtectionEnergy

    Conservation

    Energy

    Conservation

    CO2ReductionCO2Reduction

    Clean AirClean Air

    Alternative FuelAlternative Fuel

    45

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    Thank you for your attention !Thank you for your attention !

    46