Isomerization in Coordination Compounds Do for octahedral Complexes.

26
Isomerization in Coordination Compounds Do for octahedral Complexes

  • date post

    22-Dec-2015

  • Category

    Documents

  • view

    249

  • download

    3

TAGS:

Transcript of Isomerization in Coordination Compounds Do for octahedral Complexes.

Page 1: Isomerization in Coordination Compounds Do for octahedral Complexes.

Isomerization in Coordination Compounds

Do for octahedral Complexes

Page 2: Isomerization in Coordination Compounds Do for octahedral Complexes.

Inner and Outer Spheres

CrCl3(H2O)32 H2O [CrCl2(H2O)4 ]ClH2O

Page 3: Isomerization in Coordination Compounds Do for octahedral Complexes.

All compounds

Structural (constitutional) Stereo

linkage ionization hydration geometric optical

[Co(NH3)5Cl]NO2

[Co(NH3)5NO2]Cl [Co(NH3)4Cl(H2O)]Cl2

[Co(NH3)4Cl2]ClH2O[Co(NH3)5SCN]2+

[Co(NH3)5NCS]2+

Page 4: Isomerization in Coordination Compounds Do for octahedral Complexes.

Optical Isomers: enantiomers (mirror images)key to recognizing: no mirror planes of symmetry

Type 1. arrangement of monodentate ligands

Type 2. arrangement of bidentate ligands

Page 5: Isomerization in Coordination Compounds Do for octahedral Complexes.

Geometric Isomers: like cis-trans

Use M = metala, b, c, etc. are different ligands

Example 1: Co(NH3)4Cl2

Page 6: Isomerization in Coordination Compounds Do for octahedral Complexes.
Page 7: Isomerization in Coordination Compounds Do for octahedral Complexes.
Page 8: Isomerization in Coordination Compounds Do for octahedral Complexes.
Page 9: Isomerization in Coordination Compounds Do for octahedral Complexes.
Page 10: Isomerization in Coordination Compounds Do for octahedral Complexes.
Page 11: Isomerization in Coordination Compounds Do for octahedral Complexes.
Page 12: Isomerization in Coordination Compounds Do for octahedral Complexes.
Page 13: Isomerization in Coordination Compounds Do for octahedral Complexes.
Page 14: Isomerization in Coordination Compounds Do for octahedral Complexes.
Page 15: Isomerization in Coordination Compounds Do for octahedral Complexes.
Page 16: Isomerization in Coordination Compounds Do for octahedral Complexes.
Page 17: Isomerization in Coordination Compounds Do for octahedral Complexes.
Page 18: Isomerization in Coordination Compounds Do for octahedral Complexes.
Page 19: Isomerization in Coordination Compounds Do for octahedral Complexes.
Page 20: Isomerization in Coordination Compounds Do for octahedral Complexes.
Page 21: Isomerization in Coordination Compounds Do for octahedral Complexes.
Page 22: Isomerization in Coordination Compounds Do for octahedral Complexes.
Page 23: Isomerization in Coordination Compounds Do for octahedral Complexes.
Page 24: Isomerization in Coordination Compounds Do for octahedral Complexes.
Page 25: Isomerization in Coordination Compounds Do for octahedral Complexes.
Page 26: Isomerization in Coordination Compounds Do for octahedral Complexes.

Principal mechanisms of ligand exchange in octahedral complexes Dissociative Associative.

Principal mechanisms of ligand exchange in octahedral complexes Dissociative Associative.

Transition-Metal Complexes - Roald Hoffmann · Octahedral Deformation in d4 Transition- Metal Complexes ... arbitrary six-coordinate complex, ... of the three orbitals and determine

Transition-Metal Complexes - Roald Hoffmann · Octahedral Deformation in d4 Transition- Metal Complexes ... arbitrary six-coordinate complex, ... of the three orbitals and determine

Supporting Information Iridium(III) ComplexesSupporting Information Twist it! The Acid-Dependent Isomerization of Homoleptic Carbenic Iridium(III) Complexes Jaroslaw G. Osiak†a,

Supporting Information Iridium(III) ComplexesSupporting Information Twist it! The Acid-Dependent Isomerization of Homoleptic Carbenic Iridium(III) Complexes Jaroslaw G. Osiak†a,

High Pressure Chemistry€¦ · Ligand Substitution Reactions 12 Octahedral Complexes 13 Square-Planar Complexes 19 Electron Transfer Reactions 21 Self-Exchange Reactions 22 Non-Symmetrical

High Pressure Chemistry€¦ · Ligand Substitution Reactions 12 Octahedral Complexes 13 Square-Planar Complexes 19 Electron Transfer Reactions 21 Self-Exchange Reactions 22 Non-Symmetrical

Chim.Inorg.3 3 3. 2… · Chimica Inorganica 3 Octahedral ML 6 Sigma Complexes An octahedral complex comprises a central metal ion and six terminal ligands. If the ligands are exclusively

Chim.Inorg.3 3 3. 2… · Chimica Inorganica 3 Octahedral ML 6 Sigma Complexes An octahedral complex comprises a central metal ion and six terminal ligands. If the ligands are exclusively

Transition Elements and Complexes - The University of ... · Transition Elements and Complexes ... Can wrap around metal and bond at six positions in octahedral complex ... Valence

Transition Elements and Complexes - The University of ... · Transition Elements and Complexes ... Can wrap around metal and bond at six positions in octahedral complex ... Valence

OCT 111966 EWAL AH64 0152 - H. Tracy Hall Foundationdocuments.htracyhall.org/pdf/HTH-Archives/Cabinet 2/E/(Elwald, A.D... · truly octahedral complexes ML6 could exist in which both

OCT 111966 EWAL AH64 0152 - H. Tracy Hall Foundationdocuments.htracyhall.org/pdf/HTH-Archives/Cabinet 2/E/(Elwald, A.D... · truly octahedral complexes ML6 could exist in which both

Isomerization i Sobutene

Isomerization i Sobutene

Isomerization from Silacyclopentadienyl Complexes to Rhodasilabenzenes, Possible or Not? Ying huang.

Isomerization from Silacyclopentadienyl Complexes to Rhodasilabenzenes, Possible or Not? Ying huang.

Chapter 20 Coordination chemistry: reactions of …...Chapter 20 Coordination chemistry: reactions of complexes Redox reactions Ligand substitution in octahedral complexes Ligand substitution

Chapter 20 Coordination chemistry: reactions of …...Chapter 20 Coordination chemistry: reactions of complexes Redox reactions Ligand substitution in octahedral complexes Ligand substitution

Molecular Orbital Theory for Octahedral and Tetrahedral Metal Complexes (1)

Molecular Orbital Theory for Octahedral and Tetrahedral Metal Complexes (1)

PRIFYSGOL C ERDY[§>orca-mwe.cf.ac.uk/55745/1/U584267.pdf1.3.2 Complexes of nitrogen containing bidentate N-heterocyclic ligands 14 1.3.2.1 Square planar complexes 14 1.3.2.2 Octahedral

PRIFYSGOL C ERDY[§>orca-mwe.cf.ac.uk/55745/1/U584267.pdf1.3.2 Complexes of nitrogen containing bidentate N-heterocyclic ligands 14 1.3.2.1 Square planar complexes 14 1.3.2.2 Octahedral

Water Oxidation By Metal Complexes: Storing Solar Energy€¦ · • Metal atoms commonly have 6, 5 or 4 ligands. • Common geometries are octahedral, square pyramid, trigonal bipyramid,

Water Oxidation By Metal Complexes: Storing Solar Energy€¦ · • Metal atoms commonly have 6, 5 or 4 ligands. • Common geometries are octahedral, square pyramid, trigonal bipyramid,

Transition Metals & Complex ions State and give examples of complexes with six-fold coordination with an octahedral shape State and give examples of complexes.

Transition Metals & Complex ions State and give examples of complexes with six-fold coordination with an octahedral shape State and give examples of complexes.

Stochastic Simulations of Polymer Growth and Isomerization in Ethylene/ -Olefin Polymerization Catalyzed by Late Transition Metal Complexes - - From.

Stochastic Simulations of Polymer Growth and Isomerization in Ethylene/ -Olefin Polymerization Catalyzed by Late Transition Metal Complexes - - From.

spectrochemical and naphelauxetic series, Charge Transfer transition. Molecular Orbital Theory (MOT) as applied to octahedral and tetrahedral complexes. The MO concept of sigma bonded

spectrochemical and naphelauxetic series, Charge Transfer transition. Molecular Orbital Theory (MOT) as applied to octahedral and tetrahedral complexes. The MO concept of sigma bonded

Electronic Supplementary Information Eugenol isomerization ... · Electronic Supplementary Information . Eugenol isomerization promoted by ... Isomerization of eugenol in the absence

Electronic Supplementary Information Eugenol isomerization ... · Electronic Supplementary Information . Eugenol isomerization promoted by ... Isomerization of eugenol in the absence

Inorganic Chemistry - The Godless Theist · 2018. 8. 3. · 1 Inorganic Chemistry Reactions of Octahedral Complexes Lability and Inertness Stability of a reactant depends upon the

Inorganic Chemistry - The Godless Theist · 2018. 8. 3. · 1 Inorganic Chemistry Reactions of Octahedral Complexes Lability and Inertness Stability of a reactant depends upon the

Chapter 10 Coordination Chemistry II: Bondingchem.yonsei.ac.kr/chem/upload/CHE3103-01/119091058812405.pdf · Molecular orbitals for Octahedral complexes CFT & MO were combined ...

Chapter 10 Coordination Chemistry II: Bondingchem.yonsei.ac.kr/chem/upload/CHE3103-01/119091058812405.pdf · Molecular orbitals for Octahedral complexes CFT & MO were combined ...

Transition Elements and Complexes - The University of Tennessee at Chattanooga · Transition Elements and Complexes ... Fe octahedral ligand: 4 to ring, ... Molecular Orbital theory

Transition Elements and Complexes - The University of Tennessee at Chattanooga · Transition Elements and Complexes ... Fe octahedral ligand: 4 to ring, ... Molecular Orbital theory