Is possible a regional alternative to partially solve...

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Is possible a regional alternative to partially solve the global biodiesel problem? Dra. María a Jesús s Ramos Marcos, Dra. María a esú Je s Ramos Marcos, R Institute of Chemical and Environmental Technology nmental Technology Ciudad Real, Spain EFICIENCIA ENERGÉTICA E INNOVACIÓN EN ENERGÍA RENOVABLE: HACIA UN NUEVO MODELO SOCIAL DE PRODUCCIÓN

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Page 1: Is possible a regional alternative to partially solve …blog.uclm.es/cytema/files/2014/02/Parte-1.pdfIs possible a regional alternative to partially solve the global biodiesel problem?

Is possible a regional alternative to partially solve the global

biodiesel problem?

Dra. María a Jesúss Ramos Marcos,Dra. Maríaa esúJe s Ramos Marcos,RInstitute of Chemical and Environmental Technologynmental Technology

Ciudad Real, Spain

EFICIENCIA ENERGÉTICA E INNOVACIÓN EN ENERGÍA RENOVABLE:HACIA UN NUEVO MODELO SOCIAL DE PRODUCCIÓN

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Liquid Biofuel Production (2014)(Source: Eurostat statistics explained)

EFICIENCIA ENERGÉTICA E INNOVACIÓN EN ENERGÍA RENOVABLE:HACIA UN NUEVO MODELO SOCIAL DE PRODUCCIÓN

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Indirect Land Use Change (ILUC)

Renewable Energy Directive and the Fuel Quality Directive (2015)

EFICIENCIA ENERGÉTICA E INNOVACIÓN EN ENERGÍA RENOVABLE:HACIA UN NUEVO MODELO SOCIAL DE PRODUCCIÓN

10 % for renewables in transport fuels by 2020

7 % biofuels produced from 'food' crops 3 %

Biofuels from Used Cooking Oil and Animal Fats Renewable electricity in rail Renewable electricity in electric vehicles Advanced biofuels (0.5%)

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EFICIENCIA ENERGÉTICA E INNOVACIÓN EN ENERGÍA RENOVABLE:HACIA UN NUEVO MODELO SOCIAL DE PRODUCCIÓN

Sources: Biofuel facilities: GSI data collection Map of Spain showing Convergence or Competiveness and Employment areas, European Commission (2013).

CapacityCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaapppppppppppppppppppppppppppppppppaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaacccccccccccccccccccccccccccccciiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiitttttttttttttttttttttttttttttttt : 4,9 Mttttttttttttttttttyyyyyyyyyyyyyyyyyyyyyyyyyyyyyyyyy 4444444444444444444444444444444444,,,,,,,,,,,,,,,,,,,,,,,,,,99999999999999999999999999999999999 MMMMMMMMMMMMMMMMMMMMMMMMMMMMMMMMtttttttttttttttttttttttttttttttt:::::::::::::::::::::::::::::: 4444444444444444444444Production

CCCCCaaaaaaaaaapppppppppppppaaaaaaaaaaacccccciiiiiiiittttttttttyyyyyyyyyyyyyyyyyyyyyyyyyyyPPPPPPPPPPPPPPPPPPPPPPPrrrrrrrrroooooooooooooooooooooooooooooddddddddddddddddddddddddddddduuuuuuuuuuuuuuuuuuuuuuuuuuuuuccccccccccccccccccccccccccccctttttttttttttttttttttiiiiiiiioooooooooooooooooooooooooooPPPPPPPPPPPPPPPPPPPPPPPPPPPPPPPPrrrrrrrrrrrrrrrrrrrrrrrrrrrrrroooooooooooooooooooooooooooooooooddddddddddddddddddddddddddddddddduuuuuuuuuuuuuuuuuuuuuuuuuuuucccccccccccccccccccccccccccccctttttttttttttttttttttttttttttiiiiiiiiiiiiiiiiiiiiiiiiiioooooooooooooooooooooooooooooooooo : 0,6 Mt

,,,,,,,,,,,,,,,,,,,,999999999999 MMMMMMMMMMMMMMMMMtttttttttttty 4444444,,,,,,,,,,,,,,,,,,,,,,,,,:::::::::::: 4nnnnnnnnnnnnnnnnnnnnnnnnnnnnnnnnnnnnnnnnnnnnnn 0000000000000000000000000000,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,666666666666666666666666666666 MMMMMMMMMMMMMMMMMMMMMMMMMMMtttttttttttttttttttttt00000000000000000000000000000000 666666666666666666666666666666666666 MMMMMMMMMMMMMMMMMMMMMMMMMMMMMMMtttttttttttttttttttttttttttttttt::::::::::::::::::::::::::: 000000000000000000::::::::::::::::::::::::::: 000000000000000000000000

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EFICIENCIA ENERGÉTICA E INNOVACIÓN EN ENERGÍA RENOVABLE:HACIA UN NUEVO MODELO SOCIAL DE PRODUCCIÓN

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Agricultural production in Castilla La Mancha(Regional Government 2015)

EFICIENCIA ENERGÉTICA E INNOVACIÓN EN ENERGÍA RENOVABLE:HACIA UN NUEVO MODELO SOCIAL DE PRODUCCIÓN

Sunflower 89,8 Mt

Grapes 2909,9 Mt

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Leaders of sustainable Biofuels

““……2…2nd Generation and Advanced Biofuels ((2(2(((( GAB) made from nono-o--food competing………2 dndn Genfeedstocks

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EFICIENCIA ENERGÉTICA E INNOVACIÓN EN ENERGÍA RENOVABLE:HACIA UN NUEVO MODELO SOCIAL DE PRODUCCIÓN

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The viability of the regional biodiesel production is based on non-edible and

residual feedstock

EFICIENCIA ENERGÉTICA E INNOVACIÓN EN ENERGÍA RENOVABLE:HACIA UN NUEVO MODELO SOCIAL DE PRODUCCIÓN

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Institute of Chemical and Environmental Technology

EFICIENCIA ENERGÉTICA E INNOVACIÓN EN ENERGÍA RENOVABLE:HACIA UN NUEVO MODELO SOCIAL DE PRODUCCIÓN

Laboratory of Polymer TechnologyWaste laboratory

Water Technology LaboratoryProcesses Laboratory

Biofuel LaboratoryLaboratory of Catalysis and Material Technology

Laboratory of analysis of risk, safety and labor health

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Research Lines biofuels group:EFICIENCIA ENERGÉTICA E INNOVACIÓN EN ENERGÍA RENOVABLE:

HACIA UN NUEVO MODELO SOCIAL DE PRODUCCIÓN

•• Transesterification•

TransesterificationT•• Interesterification•

nteresterificatioIn•• Pervaporation

•• UNE EN 14214

•• Neutralization•

NeutralizationN•• Esterification•

sterificationE•• Winterization

•• Grapeseed•

GrapeseedG•• Jatropha•

atrophaJa•• Sinapsis Alba•

inapsis AlbaS•• Camelina S.

EXTRACT REFINE

FAMEPRODUCTION

ANALYSIS

Page 11: Is possible a regional alternative to partially solve …blog.uclm.es/cytema/files/2014/02/Parte-1.pdfIs possible a regional alternative to partially solve the global biodiesel problem?

Research Lines biofuels group:EFICIENCIA ENERGÉTICA E INNOVACIÓN EN ENERGÍA RENOVABLE:

HACIA UN NUEVO MODELO SOCIAL DE PRODUCCIÓN

•• Transesterification•

TransesterificationT•• Interesterification•

nteresterificatioIn•• Pervaporation

•• UNE EN 14214

•• Neutralization•

NeutralizationN•• Esterification•

sterificationE•• Winterization

•• Grapeseed•

GrapeseedG•• Jatropha•

atrophaJa•• Sinapsis Alba•

inapsis AlbaS•• Camelina S.

EXTRACT REFINE

FAMEPRODUCTION

ANALYSIS

Page 12: Is possible a regional alternative to partially solve …blog.uclm.es/cytema/files/2014/02/Parte-1.pdfIs possible a regional alternative to partially solve the global biodiesel problem?

Drying Mill Sieved

Feedstock reconditioning

EFICIENCIA ENERGÉTICA E INNOVACIÓN EN ENERGÍA RENOVABLE:HACIA UN NUEVO MODELO SOCIAL DE PRODUCCIÓN

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Mechanical pressing Solvent extraction

Oil extraction techniques

Solvent extractionMechanical pressing

EFICIENCIA ENERGÉTICA E INNOVACIÓN EN ENERGÍA RENOVABLE:HACIA UN NUEVO MODELO SOCIAL DE PRODUCCIÓN

Page 14: Is possible a regional alternative to partially solve …blog.uclm.es/cytema/files/2014/02/Parte-1.pdfIs possible a regional alternative to partially solve the global biodiesel problem?

Oil extraction techniquesExtraction and refining of of of Grape seed oilC. M. Fernández y col. (2010) Bioresource Technology, 101 7019-7024.

EFICIENCIA ENERGÉTICA E INNOVACIÓN EN ENERGÍA RENOVABLE:HACIA UN NUEVO MODELO SOCIAL DE PRODUCCIÓN

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Oil extraction techniquesExtraction and refining of of of Jatropha a a curcass seed oil

C.M. Fernández y col. (2015) Environmental Engineering and Management Journal 14 (12) 2855-2864

EFICIENCIA ENERGÉTICA E INNOVACIÓN EN ENERGÍA RENOVABLE:HACIA UN NUEVO MODELO SOCIAL DE PRODUCCIÓN

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Oil extraction techniquesExtraction and refining of ofof Camelinaaa Sativaa seed oil

C. Ciubota-Rosie y col. (2013) Fuel 105 572-577.

EFICIENCIA ENERGÉTICA E INNOVACIÓN EN ENERGÍA RENOVABLE:HACIA UN NUEVO MODELO SOCIAL DE PRODUCCIÓN

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Oil extraction techniquesExtraction and refining of of of Sinapisisis Alba seed oilC. Ciubota-Rosie y col. (2013). Biomass and Bioenergy 51 83-90.

EFICIENCIA ENERGÉTICA E INNOVACIÓN EN ENERGÍA RENOVABLE:HACIA UN NUEVO MODELO SOCIAL DE PRODUCCIÓN

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CO22 supercritical extraction2

Oil extraction techniques

EFICIENCIA ENERGÉTICA E INNOVACIÓN EN ENERGÍA RENOVABLE:HACIA UN NUEVO MODELO SOCIAL DE PRODUCCIÓN

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Supercritical extraction of Jatropha seed oilSupercritical extraction oof atropha seedJaOil extraction techniques

EFICIENCIA ENERGÉTICA E INNOVACIÓN EN ENERGÍA RENOVABLE:HACIA UN NUEVO MODELO SOCIAL DE PRODUCCIÓN

C.M. Fernández y col. (2015). The Journal of Supercritical Fluids 97 100-106.

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Supercritical extraction of Jatropha seed oilSupercritical extraction oof atropha seedJaOil extraction techniques

EFICIENCIA ENERGÉTICA E INNOVACIÓN EN ENERGÍA RENOVABLE:HACIA UN NUEVO MODELO SOCIAL DE PRODUCCIÓN

C.M. Fernández y col. (2015). The Journal of Supercritical Fluids 97 100-106.

Page 21: Is possible a regional alternative to partially solve …blog.uclm.es/cytema/files/2014/02/Parte-1.pdfIs possible a regional alternative to partially solve the global biodiesel problem?

Research Lines biofuels group:EFICIENCIA ENERGÉTICA E INNOVACIÓN EN ENERGÍA RENOVABLE:

HACIA UN NUEVO MODELO SOCIAL DE PRODUCCIÓN

•• Transesterification•

TransesterificationT•• Interesterification•

nteresterificatioIn•• Pervaporation

•• UNE EN 14214

•• Neutralization•

NeutralizationN•• Esterification•

sterificationE•• Winterization

•• Grapeseed•

GrapeseedG•• Jatropha•

atrophaJa•• Sinapsis Alba•

inapsis AlbaS•• Camelina S.

EXTRACT REFINE

FAMEPRODUCTION

ANALYSIS

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Oil refine

Grapeseed oil

C. M. Fernández y col. (2010) Bioresource Technology, 101 7019-7024.

EFICIENCIA ENERGÉTICA E INNOVACIÓN EN ENERGÍA RENOVABLE:HACIA UN NUEVO MODELO SOCIAL DE PRODUCCIÓN

Sinapis Alba

C. Ciubota-Rosie y col. (2013). Biomass and Bioenergy 51 83-90.

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WinterizationPeanut oilA. Pérez y col. (2010). Bioresource Technology, 101 (2010) 7375-7381.

EFICIENCIA ENERGÉTICA E INNOVACIÓN EN ENERGÍA RENOVABLE:HACIA UN NUEVO MODELO SOCIAL DE PRODUCCIÓN

Page 24: Is possible a regional alternative to partially solve …blog.uclm.es/cytema/files/2014/02/Parte-1.pdfIs possible a regional alternative to partially solve the global biodiesel problem?

Research Lines biofuels group:EFICIENCIA ENERGÉTICA E INNOVACIÓN EN ENERGÍA RENOVABLE:

HACIA UN NUEVO MODELO SOCIAL DE PRODUCCIÓN

•• Transesterification•

TransesterificationT•• Interesterification•

nteresterificatioIn•• Pervaporation

•• UNE EN 14214

•• Neutralization•

NeutralizationN•• Esterification•

sterificationE•• Winterization

•• Grapeseed•

GrapeseedG•• Jatropha•

atrophaJa•• Sinapsis Alba•

inapsis AlbaS•• Camelina S.

EXTRACT REFINE

FAMEPRODUCTION

ANALYSIS