Accurate energy functionals for evaluating electron correlation energies
Introduction to Electron Correlation
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Transcript of Introduction to Electron Correlation
![Page 1: Introduction to Electron Correlation](https://reader030.fdocuments.net/reader030/viewer/2022020208/55aacca31a28ab5c398b480f/html5/thumbnails/1.jpg)
Electron Correlation
Albert DeFusco
March 26, 2015
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Hartree-Fock (SCF) methods
I What it does wellI Geometries
I What it doesn’t do wellI Energies
I No electron correlationI The Fock operator assumes an average electron-electron repulsionI Each orbital energy is independent of anotherI Average interaction is optimized through the SCF procedure
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Perturbation Theory
I Corrections to the Hartree-Fock energy and wavefunctionI Requires that the corrections be smallI HF wavefunction and energy must be pretty good
I Møller-Plesset perturbation (MP2, MP3, etc.)I Perturbations are not convergent
I Coupled ClusterI CCSD, CCSD(t), CCSDT, CCSDTQ, etc.I Perturbations are guaranteed to converge
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Correlated electron motion
He atom
H = −12∇
21 −
Zr1Z−
12∇
22 −
Zr2Z
+1
r1,2
I This is not the Hartree-Fock HamiltonianI There is no analytic solutionI We must use hyrdrogen atom solutions as a guide
I The Hamiltonian diverges at r1,2 = 0I r1,2 = r1 − r2I r1Z = r1 − RZI r2Z = r2 − RZ
I and at the nuclei ri = 0.I The kinetic energy must also diverge to achieve a finite sum.
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A determinant is a wavefunction
Ψ(x1,x2, . . . ,xn) =1√
n!
∣∣∣∣∣∣∣∣∣∣∣∣χ1(x1) χ2(x1) · · · χn(x1)χ1(x2) χ2(x2) · · · χn(x2)...
... · · ·...
χ1(xn) χ2(xn) · · · χn(xn)
∣∣∣∣∣∣∣∣∣∣∣∣I Rows are electron positions and spinsI Columns are spin orbitalsI Ψ(x1,x2, . . . ) = −Ψ(x2,x1, . . . )
I Exchange either two rows or two columns: antisymmetric
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Probability density
Ψ(x1,x2) =∣∣∣χ1(x1)χ2(x2)
⟩P(r1, r2) =
∫dω1dω2 |Ψ|
2 dr1dr2
I The two-electron densityI Probability of finding electron 1 at r1 in a volume dr1 while
simultaneously finding electron 2 at r2 in a volume dr2.
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The helium atom: ground state singlet wavefunctionI Hartree-Fock single determinant for the 11S stateI Minimal 1-electron basis: 2 1s restricted spin orbitals
Ψ(x1,x2) =1√
2
∣∣∣∣∣ ψ1s(r1)α(ω1) ψ1s(r1)β(ω1)ψ1s(r2)α(ω2) ψ1s(r2)β(ω2)
∣∣∣∣∣= 2−
12 (ψ1s(r2)β(ω2)ψ1s(r1)α(ω1)
−ψ1s(r2)α(ω2)ψ1s(r1)β(ω1))
|Ψ|2 =12. . .
=∣∣∣ψ1s(r1)
∣∣∣2 ∣∣∣ψ1s(r2)∣∣∣2
I The spatial orbital is identical for α and β spinI Spatial motion in uncorrelated
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The helium atom: triplet wavefunction
I Hartree-Fock single determinant for the 23S stateI Minimal 1-electron basis: 1s and 2s spin orbitals
Ψ(x1,x2) =1√
2
∣∣∣∣∣ ψ1s(r1)α(ω1) ψ2s(r1)α(ω1)ψ1s(r2)α(ω2) ψ2s(r2)α(ω2)
∣∣∣∣∣= 2−
12 (ψ2s(r2)α(ω2)ψ1s(r1)α(ω1)
−ψ1s(r2)α(ω2)ψ2s(r1)α(ω1))
|Ψ|2 =12. . .
=∣∣∣ψ1s(r1)
∣∣∣2 ∣∣∣ψ2s(r2)∣∣∣2 +
∣∣∣ψ1s(r2)∣∣∣2 ∣∣∣ψ2s(r1)
∣∣∣2I Parallel spin electrons have Fermi correlation
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Cusp conditions
Figure: Hylleraas Hamiltonian for Helium with relative coordinates.(Figure from
Fred Manby)
I electron-nucleas cusplimri→0
(∂Ψ∂ri
)ave
= −ZΨ(ri = 0)
I Exists in Slater orbitals, but approximated in Gaussian orbitalsI More angular momentum means a sharper cusp
I electron-electron cusplimr1,2→0
(∂Ψ∂r1,2
)ave
= 12 Ψ(r1,2 = 0)
I Leads to a depletion in in the two-electron density at r1,2
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Hylleraas wavefunction
Figure: Hartree-Fock wavefunction andHylleraas wavefunction. (Figure from Fred Manby)
I One slater determinant is notenough
I To help electrons “avoid” eachother, we can distribute themamong more orbitals usingmany determinants
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Helium determinants: double zeta basis
I Singlet HeliumI ψ2s is a “virtual” or unoccupied spin orbitalI Ψ2 is a “doubly excited” determinantI CI Singles and Double (CISD)
I Why no singles?
Ψ0 =∣∣∣ψ1sψ1s
⟩Ψ2 =
∣∣∣ψ2sψ2s
⟩Ψ(x1,x2) = K1
∣∣∣ψ1sψ1s
⟩+ K2
∣∣∣ψ2sψ2s
⟩P(r1, r2) =
∣∣∣ K1ψ1s(r1)ψ1s(r2) + K2ψ2s(r1)ψ2s(r2)∣∣∣2
limr1→r2
P(r1, r2) =(K1
∣∣∣ψ1s(r1)∣∣∣2 + K2
∣∣∣ψ2s(r1)∣∣∣2)2
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Configuration Interaction
I Solving for the determinant coefficients
Ψ = K0Ψ0 + K2Ψ2
H =
( ⟨Ψ0|H|Ψ0
⟩ ⟨Ψ0|H|Ψ2
⟩⟨Ψ2|H|Ψ0
⟩ ⟨Ψ2|H|Ψ2
⟩ )⟨Ψ2|H|Ψ0
⟩=
⟨11
∣∣∣22⟩−
⟨11
∣∣∣22⟩
= K12
H(
K0K2
)= ECISD
(K0K2
)
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Helium convergence
ERHF = −2.85516 a.u.
Table: FCI/cc-pVQZ
Spatial Orbital CI coefficient1s 0.9959742s -0.0392002p -0.0284293d -0.0051643f -0.001472
Table: Helium Full CI total energy J.
Chem. Phys. 127 , 224104 (2007)
Basis Set Energy (a.u.)cc-pVDZ -2.8875948cc-pVTZ -2.9002322cc-pVQZ -2.9024109cc-pV5Z -2.9031519
Exact Energy -2.9037225
I The difference between Full CI and Hartree-Fock energies iscalled the correlation energy
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Helium cusp
Figure: Helium wavefunction cusps for cc-pVDZ,cc-pVTZ, cc-pVQZ and cc-pV5Z basis sets fromMartin Schutz
I Slater determinantexpansions have evenpowers of r1,2(Helgaker)
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Configuration Interaction
I Exact when all possible determinants used with a complete basisset
I Full CI
I Basis setsI HF has a factorizable two-electron density and requires fewer basis
functions to convergeI Correlation methods seek to improve the two-electron density and
require much more functions to converge
I Orbitals are frozen at the HF solution
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More than two electronsI Excited determinants and matrix elements (Slater Rules)
I Single excitations are zero by Brilloun’s theoremI Determinants differening by one spin orbital⟨
Ψ|H|Ψpm
⟩=
⟨m
∣∣∣h∣∣∣p⟩+
N∑n
(〈mn|pn〉 − 〈mn|np〉)
I Determinants differing by two spin orbitals⟨Ψ|H|Ψpq
mn
⟩= 〈mn|pq〉 − 〈mn|qp〉
I determinants differing by more than two spin orbitals contributes 0
H =
⟨Ψ0
∣∣∣H ∣∣∣Ψ0⟩
0⟨Ψ0
∣∣∣H ∣∣∣Ψ2⟩
0 0 · · ·⟨Ψ1
∣∣∣H ∣∣∣Ψ1⟩ ⟨
Ψ1
∣∣∣H ∣∣∣Ψ2⟩ ⟨
Ψ1
∣∣∣H ∣∣∣Ψ3⟩
0 · · ·⟨Ψ2
∣∣∣H ∣∣∣Ψ2⟩ ⟨
Ψ2
∣∣∣H ∣∣∣Ψ3⟩ ⟨
Ψ2
∣∣∣H ∣∣∣Ψ4⟩· · ·⟨
Ψ3
∣∣∣H ∣∣∣Ψ3⟩ ⟨
Ψ3
∣∣∣H ∣∣∣Ψ4⟩· · ·⟨
Ψ4
∣∣∣H ∣∣∣Ψ4⟩· · ·
...
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Expansions
I Slow convergence with excitation
I Scaling problemI Full CI grows factoriallyI Many billion determinant Full CI is possible, but only small
molecules
I Truncation CI expansionsI CISD: CI Singles and DoublesI CISDT: With triple excitationsI CISDTQ: With quadruple excitationsI QCISD is closely related to coupled-cluster
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What is still missing?
I Bond breakingI Including transition states
I DiradicalsI Degenerate orbital pictures
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H2 dissociation
I UHFI Not smooth due to spin
contaminationI RHF
I MP2 likely to fail
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H2 dissociation determinantsI A single determinant has a spurious J integral at long range
ψσ = φA + φB
ψσ∗ = φA − φB
Eeq = 2hσσ + JσσE∞ = 2hσσ + Jσσ = 2hσ∗σ∗ + Jσ∗σ∗
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H2 dissociation determinants
I Full CI minimum basis
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Separate correlation
I Dynamic correlationI Short range cusp conditionsI Perturbation theories are very efficientI Requires large basis sets
I Static correlationI Degeneracies in orbitals or determinantsI “chemical intuition”
I Full CI does both
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Diradicals
I What is the Lewis structure of ozone?
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Ozone
I What are the molecular orbitals?I Each oxygen supplies 1s, 2s and 3 2p orbitals
I Hartree-Fock will only fill the first 12 orbitals
I The HOMO energy is -0.4810 a.u.
I The LUMO energy is -0.0299 a.u.
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Ozone
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Ozone
I Distribute 4 electrons in the 3 π orbitalsI Full CI = CISD
0.929
-0.224
-0.224
-0.166
-0.066
0.066
Determinant weights for Hartree-Fock orbitals
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Ozone
I Multi-configurational Self Consistent Field (MCSCF)I Improve the energy by minimizing the orbitalsI New definition of Fock matrix
I Fully Optimized Reaction Space (FORS)I Complete Active Space Self Consistent Field (CAS)I Full CI within a “chosen” orbital space
I MCSCF does not imply CASSCF
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Ozone
I Determinant weights for CASSCF optimized orbitals
0.864
-0.240
-0.240
-0.295
-0.159
0.159
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What about the orbitals?
I Hartree-Fock orbitals have little physical meaningI DFT orbitals even lessI Orbital energies may be helpful to pick active space
I Determinants define electron configurations
I Natural orbitals have populationsI Diagonalize the density matrixI U are orbitals and n are electron occupations
Ψ =∑
k
Ak Ψk
P = Ψ∗Ψ
PU = nU
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OzoneElectron populations in natural orbitals for the active space
1.993 1.598 0.409
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Dynamic correlation
I CASSCF has no dynamic correlationI Similar to Hartree-Fock
I Multi-reference CI (MR-CISD)I Very accurate for excitation energiesI Still not size-consistent
I Alternatives to MR-CI expansions, perturbation theoryI MRPT (MRMP), CASPT, MCQDPTI MRCC: Multiple typesI Good for potential energy surfaces
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Pople Diagram
Figure: From Chem. Soc. Rev., 2012,41, 6259-6293