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INTEGRATED BLANCHING AND COOLING TO REDUCE PLANT EFFLUENT John L. Bomben*, George E. Brown*, William C. Dietrich*, Joyce S. Hudson* and Daniel F. Farkas* INTRODUCTION Blanching of vegetables for freezing, canning or dehydration produces a large portion of the total organic solids in a plant effluent (1). In most cases over 50% of the plant BOD is due to blanching and cooling. Reducing this effluent would give a large reduction in the 800 million pounds of BOD and 392 million pounds of suspended solids produced by the canned and frozen fruits and vegetable industry. In recent years the National Canners Association has investigated means of reducing pollution from blanching. The characteristics of water, steam, microwave and hot gas blanching were studied (2). It was found that hot gas blanching gave a system which reduced blancher effluent to a very low volume for some products (3). However, hot gas blanching required more energy than conventional blanching, and it was applied only to canned vegetables where there is no need for cooling. Cooling can leach as much, or more, solids from the products as does blanching (4) 3 The USDA Western Regional Research Laboratory has conducted research on improving steam blanching so as to reduce effluent volume and BOD as well as improve product quality by reducing over-blanching. This research resulted in the development of a heating and holding technique called Individual Quick Blanching (IQB) (5). With IQB the product is heated with steam in a single layer on a conveyor t o a mass average temperature sufficient for enzyme inactivation, and the product is held adiabatically in a deep bed on a second conveyor allowing enough time for temperature equilibration and enzyme inactivation. This method reduces leaching from the product and thereby reduces effluent BOD because of the uniform heating inherent in a single layer as opposed t o the deep bed used in conventional steam blanching. in leaching can be accomplished by prewarming and partially drying with hot ail: the feed entering the steam heater (4). Further reduction Most cooling after blanching is done in flumes or by water sprays. Both of these cause leaching of solids from the product and generate * USPA, Western Regional Research Laboratory, Berkeley, California. 120

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INTEGRATED BLANCHING AND COOLING TO REDUCE PLANT EFFLUENT

John L. Bomben*, George E . Brown*, W i l l i a m C . Die t r ich* , Joyce S. Hudson* and Daniel F. Farkas*

INTRODUCTION

Blanching of vege tab les f o r f r e e z i n g , canning o r dehydrat ion produces a l a r g e po r t ion of t h e t o t a l o rganic s o l i d s i n a p l a n t e f f l u e n t (1). In most cases over 50% of the p l a n t BOD is due t o blanching and cool ing . Reducing t h i s e f f l u e n t would g ive a l a r g e reduct ion i n t h e 800 m i l l i o n pounds of BOD and 392 m i l l i o n pounds of suspended s o l i d s produced by t h e canned and frozen f r u i t s and vegetab le indus t ry .

In recent years t h e Nat iona l Canners Assoc ia t ion has i n v e s t i g a t e d m e a n s of reducing p o l l u t i o n from blanching. The c h a r a c t e r i s t i c s of water, steam, microwave and hot gas blanching w e r e s tud ied ( 2 ) . It w a s found that hot gas blanching gave a system which reduced b lancher e f f l u e n t t o a very low volume f o r some products ( 3 ) . However, ho t gas blanching requi red more energy than convent ional blanching, and it w a s app l i ed only t o canned vegetab les where t h e r e is no need f o r cool ing . Cooling can leach as much, o r more, s o l i d s from t h e products as does blanching ( 4 ) 3

The USDA Western Regional Research Laboratory has conducted research on improving steam blanching s o as t o reduce e f f l u e n t volume and BOD as w e l l as improve product q u a l i t y by reducing over-blanching. This research r e s u l t e d i n t h e development of a hea t ing and hold ing technique c a l l e d Indiv idua l Quick Blanching (IQB) (5). With I Q B t h e product i s heated with steam i n a s i n g l e l a y e r on a conveyor t o a mass average temperature s u f f i c i e n t f o r enzyme i n a c t i v a t i o n , and t h e product is he ld a d i a b a t i c a l l y i n a deep bed on a second conveyor allowing enough t i m e f o r temperature e q u i l i b r a t i o n and enzyme i n a c t i v a t i o n . This method reduces leaching from t h e product and thereby reduces e f f l u e n t BOD because of t h e uniform hea t ing inhe ren t i n a s i n g l e l a y e r as opposed t o the deep bed used i n convent ional steam blanching. i n leaching can be accomplished by prewarming and p a r t i a l l y drying w i t h hot ail: t he feed en te r ing t h e steam h e a t e r ( 4 ) .

:s: ; -:.;

Fur the r reduct ion

Most cooling a f t e r blanching i s done i n flumes o r by water sprays . Both of t hese cause leaching of s o l i d s from t h e product and genera te

* USPA, Western Regional Research Laboratory, Berkeley, C a l i f o r n i a .

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l a r g e volumes of e f f l u e n t . Recently, air cool ing equipment has been i n s t a l l e d i n some f r eez ing p l a n t s (6,7). Water sp rays are used wi th a i r cool ing t o reduce the evapora t ive weight l o s s i n t h e product , and t h e excess w a t e r becomes e f f l u e n t . amount of water needed, e f f l u e n t produced o r product y i e l d when blanched vegetab les are a i r cooled.

A t p re sen t no d a t a are a v a i l a b l e on t h e

The work descr ibed i n t h i s paper w a s done t o demonstrate a means of achieving a blanching and cool ing method t h a t would produce less leaching of s o l i d s from t h e product t o t h e e f f l u e n t stream. conveyors provided a ready means of achieving compact equipment and a design of high h e a t e f f i c i e n c y . descr ibed by Brown, e t a l . (8).

Vibratory

This work is an ex tens ion of t h a t

PILOT PLANT EQUIPMENT

A schematic diagram of t h e equipment used i n t h i s work i s shown i n Figure 1. The equipment c o n s i s t s of t h r e e sec t ions : h e a t e r , ho lder and cooler , The h e a t e r and ho lde r have been completely descr ibed by Brown, e t al . (8), The cooler used i n t h a t earlier work w a s made from a neoprene b e l t conveyor, while i n t h e work descr ibed he re , a v i b r a t o r y conveyor w a s used. Figure 2 is a photograph of t h e assembled blanching- cool ing equipment.

So l id su r face v i b r a t i n g conveyors were chosen as the h e a t t r a n s f e r conveying su r faces i n t h e h e a t e r and cooler . This type of conveyor can be more e a s i l y cleaned than the w i r e mesh b e l t s used i n most steam blanchers . They a l s o provide a very compact design because they can be s tacked c lose toge the r and they do not have t h e r e t u r n s e c t i o n requi red i n a b e l t conveyor. The v i b r a t o r y conveyor a l s o g ives a means of reducing h e a t l o s s e s s i n c e vege tab le p ieces can be used t o form a seal a t t h e en t rance and e x i t . The r e l a t i v e l y s m a l l s i z e of t h e equipment reduces the cos t of i n s u l a t i o n .

Heater

A d e t a i l e d d e s c r i p t i o n of t h e h e a t e r and holder are given by Brown e t a l . (8); t hus only t h e main f e a t u r e s of t h a t equipment i s given here . An e l ec t romagne t i ca l ly dr iven v a r i a b l e amplitude Syntron c i r c u l a r conveyor w a s used i n t h e hea te r . The conveyor operated wi th a motion t h a t impelled the vege tab le p i eces upward and forward a t 3600 s t r o k e s p e r minute. around one t r a y , dropped through an opening and flowed around t h e o t h e r t r a y t o t h e o u t l e t . The res idence time i n t h e heater w a s c o n t r o l l e d by varying t h e feed p o i n t and t h e p o s i t i o n of t h e opening between t h e t r a y s as w e l l as t h e amplitude of v i b r a t i o n . Steam w a s d i s t r i b u t e d above each t r a y through tubes wi th a series of o r f i c e s . i n su la t ed , The feed w a s introduced through a hopper a t t ached t o t h e steam plenum; thus t h e feed formed a seal on one end of t h e h e a t e r and t h e holder formed one a t t h e o the r end (Figure 1).

Two conveyor t r a y s were s tacked so t h a t product flowed

The h e a t e r w a s completely

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Holder

The holder , a t tached t o t h e h e a t e r plenum, w a s an i n s u l a t e d neoprene tube 6 inches i n diameter and 10 inches long (Figure 1 ) . leaving t h e h e a t e r passed over a screen t o s e p a r a t e i t from t h e h e a t e r condensate, and from t h e r e i t dropped i n t o t h e holder . The level of product i n t h e holder w a s measured wi th a d i p s t i c k . The bulk d e n s i t y of t h e vege tab le p i eces , t h e holder c ros s s e c t i o n a l area and t h e feed rate were t h e d a t a used t o c a l i b r a t e t h e d i p s t i c k s e t t i n g f o r t h e res idence t i m e i n t h e holder .

The product

Cooler

The cooler (Figure 1) used i n these experiments w a s made from a s p i r a l v i b r a t i n g e l e v a t o r (Syntron, Model N o . ES-22). I t , l i k e t h e h e a t e r , had a frequency of 3600 cycles/second and gave t h e product an upward-forward impulse which moved the product up t h e s p i r a l . A photograph of t h i s cooler is shown in Figure 3, where t h e surrounding plenum, which d i r e c t e d the a i r flow and confined t h e atomized h e a t e r condensate, has been p a r t i a l l y removed t o show t h e s p i r a l e l eva to r . e l e v a t o r cons is ted of f i v e 4 inch wide f l i g h t s of 14 5/8 inch diameter. The l eng th over which t h e product t r a v e l e d on t h e conveyor w a s 1 7 f e e t . The plenum surrounding t h e conveyor w a s supported independent ly s o i t d id not contac t t he v i b r a t i n g conveyor. The two blowers (1/5 horsepower, s q u i r r e l cage type ) , connected t o t h e plenum, passed 750 cfm of a i r over t h e product co-cur ren t ly . A i r v e l o c i t y , measured wi th a vane anemometer, w a s regula ted by an o r f i c e a t t he e x i t of each blower, and i t w a s kept a t t h e maximum p o s s i b l e without d i s t u r b i n g t h e flow of t h e product on t h e conveyor. Heater condensate w a s atomized i n t o t h e a i r a t each blower.

The 36 inch high

EXPERIMENTAL METHODS

Most of t h e opera t ing d a t a on t h i s equipment w a s ob ta ined wi th green beans (1/2 inch c ross c u t , mixed sieves s i z e Galagreen v a r i e t y ) . Washed and screened green beans were obtained i n 400 l b l o t s from P a t t e r s o n Frozen Foods, Pa t t e r son , Ca l i fo rn ia . They w e r e mixed wi th ice , t r ans - por ted i n in su la t ed con ta ine r s and used 24 t o 96 hours later. Since c a r r o t d i c e were found t o be t h e most d i f f i c u l t t o convey, uniformity of flow i n the coo le r was t e s t e d wi th c a r r o t d i c e as descr ibed by Brown et a l . (8) . Ca r ro t s were topped, diced without pee l ing and screened t o remoye f i n e s . Raw and blanched b r o c c o l i spea r s and cau l i f lower w e r e a l s o t e s t e d on the cooler t o observe i f t hese could be conveyed.

An experimental run cons is ted of blanching and cool ing approximately 50 l b . of r a w vegetable . The feed, cooled product and e f f l u e n t w e r e weighed. Samples of coo le r e f f l u e n t were r e f r i g e r a t e d f o r l a te r a n a l y s i s . Samples of t h e feed and cooled product , taken during t h e run, w e r e frozen.

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Samples of feed, product and e f f l u e n t w e r e analyzed f o r t o t a l s o l i d s by AOAC method 20.010 (9) . Chemical oxygen demand (COD) of t h e e f f l u e n t samples w a s es t imated using a Beckman To ta l Carbon Analyzer (Model 915) (10) . Peroxidase and chlorophyl were measured according t o t h e methods descr ibed by D i e t r i c h and Neumann (11).

RESULTS

Table 1 summarizes t y p i c a l opera t ing condi t ions used i n t h e s e experiments.

Table 1. Typical opera t ing condi t ions

Heating Holding Feed R a t e Excess Cooling Cooler T i m e T i m e ( l b s / h r ) Steam* Time Product (set> (set) (8 (sec) Temp. (OF)

Green Beans 45 45 19 0 12 45 100

Carro ts 25 60 145 24 60 105

* Equals percent over t h e o r e t i c a l steam consumption. Theore t i ca l steam consumption f o r 60°F i n i t i a l temperature and a 195°F f i n a l m a s s average temperature i s 13.8 lb/100 l b feed.

Table 2 g ives t h e y i e l d of cooled green beans obta ined wi th t h e above opera t ing condi t ions as compared t o convent ional blanching and cool ing . It a l s o shows the e f f l u e n t s o l i d s l o s s , which measures t h e amount of s o l i d s l o s t from t h e feed t o t h e e f f l u e n t .

Table 3 g ives t h e amount and COD of t h e e f f l u e n t from the coo le r . These are compared t o those obtained under convent ional blanching condi t ions .

DISCUSSION OF RESULTS

The v i b r a t o r y s p i r a l conveyor used i n t h e coo le r conveyed both t h e c a r r o t s and t h e green beans uniformly and cont inuously. When t h e con- veyor w a s t r i e d wi th c u t cau l i f lower and b r o c c o l i spea r s , t h e 4 inch conveyor w a s too narrow t o convey these vege tab les w e l l , bu t they d i d move up t h e l eng th of t h e s p i r a l .

It w a s found t h a t t h e s p i r a l conveyor requi red a product v e l o c i t y of approximately 17 feet /min. t o g ive a uniform s teady flow of product. This product v e l o c i t y gave a res idence time of only 1 min. w i t h green beans and c a r r o t d i ce . The r e s u l t i n g product temperature of 100-105°F i s h igher

12 3

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than t h e 70-80'F usua l ly achieved before f r eez ing i n a commercial process. A conveyor twice as long would provide a 2 min. res idence t i m e , which would g ive adequate cool ing (8).

Table 2. Comparison of Yields and So l ids Loss i n E f f luen t f o r Green Beans Between Combined Blanching and Cooling vs Conventional Blanching and Flume Cooling

Ef f luen t Gross Yield* So l ids Loss** Reference

(X) (XI

Combined Vibratory B 1 an ch- C o o 1 88

Conventional Steam Blanch

Conventionnl Water Blanch

Flume Cool 95

Flume Cool 96

* W t . of cooled product

** % s o l i d s i n e f f l u e n t X w t . o f e f f l u e n t

W t . of feed t o b lancher Gross Yield =

X w t . of feed Ef f luen t So l ids Loss = % solids in feed

Table 3. Comparison of E f f luen t from Green Beans f o r Combined Blanching and Cooling and Conventional Blanching and Flume Cooling

Ef f luen t COD (lb/lOO l b feed) (lb/lOO l b feed) Reference

Combined Vibratory B l a n ch-Coo 1 7.0 0.17 This work

Conventional Steam Blanch

Conventional Water Blanch

Flume Cooling 500

Flume Cooling 520

0.35 (2

0.32 (2

The lower gross y i e l d of green beans f o r combined blanch-cooling as shown i n Table 2 is c h a r a c t e r i s t i c of a i r cool ing (8). The condensate sprayed on t h e product is only p a r t i a l l y reabsorbed, and i t does no t

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completely compensate f o r evaporat ion of moisture i n t o t h e a i r stream. In flume cool ing t h e r e i s no evapora t ive weight l o s s , b u t t h e h ighe r y i e l d i s accompanied by twice as much s o l i d s l o s t from the product . Since frozen vegetab les are s o l d on t h e b a s i s of weight , a lower y i e l d means less product ion and can be j u s t i f i e d economically only i f t h e va lue of l o s t product is balanced by t h e c o s t of increased waste d i sposa l .

The r e s u l t s i n Table 3 show t h e l a r g e d i f f e r e n c e i n volume of e f f l u e n t between convent ional processing and the combined blanch-cooling. Most of t h i s volume (96%) i s due t o the flume cooling. Assuming a product temperature out of t h e blancher of 195°F and cool ing water temperature of 60"F, i t r equ i r e s 5.8 l b of water p e r l b of product t o o b t a i n an 80°F product temperature. This amount of flume water when added t o the blancher e f f l u e n t r e s u l t s i n twice t h e amount of COD and 70 t i m e s t he volume of e f f l u e n t from combined blanching and cool ing.

I f no change is made i n t h e way f rozen vegetab les are marketed, then a i r cool ing of any kind s u f f e r s a l a r g e c o s t disadvantage. gives a comparison of t h e approximate opera t ing c o s t s of t h r e e d i f f e r e n t k inds of blanching. The b a s i s f o r t h i s cos t estimate is taken from Brown e t a l . (8). It must be emphasized t h a t these c o s t s are approximate, and they are shown merely t o make a comparison. It is obvious t h a t t he c o s t of l o s t green beans (a t $0.20/lb) due t o reduced y i e l d is overwhelming i n comparison t o o t h e r cos t s . Even though t h e combined v i b r a t o r y blanch-cooler can g ive s u b s t a n t i a l savings i n steam and e f f l u e n t c o s t s , and a product wi th more r e t a i n e d s o l i d s , t hese w i l l no t ba lance t h e cos t of product l o s t through evaporat ion.

Table 4

Design of Large Scale Vibratory Blanch-Cooler

To eva lua te f u l l y t h e t echn ica l f e a s i b i l i t y of t h e combined blanch-cooling approach t o processing f rozen vegetab les i t is necessary t o work wi th l a r g e r scale equipment. Figure 4 i s a schematic diagram showing the conf igura t ion and the dimensions of a 1 ton/hr . v i b r a t o r y blanch-cooler. The h e a t e r and coo le r would have a d j u s t a b l e feed po in t s t o accomodate t h e d i f f e r e n t res idence t i m e s needed f o r d i f f e r e n t products . The holder would be a l i ve bottom b i n wi th an automatic level c o n t r o l , which could be ad jus ted t o maintain d i f f e r e n t ho lde r res idence t i m e s .

The coo le r would use t h e same type of conveyor as i n t h e h e a t e r , b u t the c e n t r a l column of t h e s p i r a l could be used t o d i r e c t t he a i r flow. The coo le r s p i r a l conveyor would have t o be much longer t o accomodate up t o 5 min. res idence t i m e f o r l a r g e vege tab les such as b r o c c o l i and Brussels sprouts .

Equipment of t h i s s i z e is a v a i l a b l e from several manufacturers a t an est imated cos t of $60,000. f t . x 15 f t .

It would r e q u i r e a f l o o r area of about 15

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Table 4. An E s t i m a t e of Water, Steam, E f f luen t , E l e c t r i c i t y and Product Loss Costs i n Blanching and Cooling of Green Beans*

Water 6 Eff luen t COD

Vol c o s t Amount Disposal E l e c t r i c i t y Steam Product** To ta l (ga l / ton) ($/ton) ( l b / t o n ) c o s t ($/ton) ($ / ton) l o s s c o s t

($ / ton) ($ / ton) ($/ton)

Combined Vibratory

Conventional S team Blanch

blanch-cool 140 0.06 3 0.06 0.060 0.31 28.00 28.43

flume coo l 1200 0.48 7 0.14 0.007 0.55 0 1.17

flume coo l 12 50 0.50 6.4 0.13 0.007 0.80 0 1.43

P N o\

Conventional Water Blanch

* ** Cost of u t i l i t i e s and waste d i s p o s a l taken from Brown e t a l . (8) .

Frozen green beans a t $0.20/lb (12 ) .

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1.

2.

3.

4.

5.

6.

7.

8.

9.

10.

11.

12.

NATIONAL CANNERS ASSOCIATION, "Liquid Wastes from Canning and Freezing F r u i t s and Vegetables," Of f i ce of Research and Monitoring, Environmental P ro tec t ion Agency, Washington, D.C. (1971).

FULLS, J. W . , MAAGDENBERG, H. J., YACOUB, N. L. , ZINNECKER, M. E., REIMAN, J . M., KARNATH, H. O. , HOMNICK, D. N . , and MERCER, W. A. Reduced waste genera t ion by alternate vegetab le blanching systems. Proceedings of t h e 3rd Nat ional Symposium on Food Processing Wastes, New Orleans, La., Environmnetal P ro tec t ion Technology Series EPA- R2-72-018, 25 (1972).

RALLS, J. W . , MAAGDENBERG, H. J., YACOUB, N. L., ZINNECKER, M. E., REIMAN, J. M., KARNATH, H. O . , HOMNICK, D. N. , and MERCER, W. A. In-plant hot-gas blanching of vege tab les . Assoc ia t ion Pub l i ca t ion D-2614, (1972).

Nat iona l Canners

BOMBEN, J. L., DIETRICH, W. C. , FARKAS, D. F., HUDSON, J . S., DE MARCHENA, E. S., and SANSHUCK, D. W. P i l o t p l a n t eva lua t ion of Ind iv idua l Quick Blanching (IQB) f o r vege tab les . J. Food Sc i . , 38: 590 (1973).

LAZAR, M. E . , LUND, D. B., and DIETRICH, W. C. IQB: A new concept i n blanching. Food Tech., 25: 684 (1971).

COFFELT, R. J., and WINTER, F. H. Evaporative cool ing of blanched vegetab les . J. Food Sc i . , 38: 89 (1973).

SMITH, W. L. , and ROBE, K. Saves 300-400 gpm water, improves vege tab le q u a l i t y . Food Processing, 34(3) : 36 (1973).

BROWN, G. E., BOMBEN, J . L., DIETRICH, W. C . , HUDSON, J. S., and FARKAS, D. F. A reduced e f f l u e n t blanch-cooling method us ing a v i b r a t o r y conveyor. J. Food Sc i . , ( i n p re s s ) .

AOAC. O f f i c i a l Methods of Analysis , 10 th Ed. Associat ion of O f f i c i a l Agr i cu l tu ra l Chemists, p. 308, Washington, D.C. (1965).

APHA. Standard Methods f o r t h e Examination of Water and Wastewater, 13 th ed., p. 257. American Pub l i c Health Assoc ia t ion , New York (1965).

DIETRICH, W. C . , and NEUMA", H. J. Blanching Brusse l Sprouts. Food Tech., 19 (5) : 150 (1965).

IELMINI, J. P r i v a t e communication on c o s t of green beans. (1974).

Reference t o a company and/or product name does no t imply approval o r recommendation of t h i s product by t h e U.S. Department of Agr icu l ture t o t h e exc lus ion of o t h e r s which may a l s o be s u i t a b l e .

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Fig

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Photograph

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130

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Enlarged cut a w a y section of heater

--*-

AIR BLOWER WITH FILTER

P w I-

Enlarged cut a w a y section of cooler

Figure 4 . ONE TON PER HOUR VIBRATORY BLANCHER COOLER