Installation Name & Address For inspection purposes only. · PDF fileA2-02 ESP Exhaust...
Transcript of Installation Name & Address For inspection purposes only. · PDF fileA2-02 ESP Exhaust...
ISO/IEC 17025 Accredited Legal Entity, UKAS Accredited Testing Laboratory No. 4279
Exova (UK) Ltd trading as Exova Catalyst & Exova Catalyst Ireland
Unit C5, Emery Court, The Embankment Business Park, Stockport, SK4 3GL
Report Written by
Patrick O'Brien
4th April 2016Report Date
TE1 TE2 TE3 TE4
Stack Emissions Testing Report Commissioned by
1st - 8th March 2016
Job Reference Number
CDU-0594
Installation Name & Address
Stack Reference
Irish EPA IPPC Licence: P0378-02
Signature of Report Approver
Version 1
MM 08 922MCERTS Level 2
Dates of the Monitoring Campaign
Team Leader
Team Leader
TE1 TE2 TE3 TE4MM 08 922
MCERTS Level 2
Patrick O'Brien
Report Approved by
Version
Exova Catalyst Ireland, Unit D8 North City Business Park, North Road, Finglas, Dublin 11T: +353 86 853 8247
E: [email protected] Exova Catalyst Ireland Contact: Nick Kenny (+353 86 853 8247)
BallyconnelScotchtown
Quinn Cement Ltd
County Cavan
Quinn Cement Ltd
A2-02 ESP Exhaust (Clinker Grate Cooler)
CAT-RT (Version BM)
CDU-0594 Quinn Cement A2-02 Dusdt Report
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TITLE PAGE
CONTENTS
Summary of Sampling Deviations
EXECUTIVE SUMMARY
Monitoring Objectives
Monitoring Results
Monitoring Dates & Times
Process Details
Monitoring & Analytical Methods
Sampling Location
Plant Photos / Sample Points
APPENDIX 1 - Monitoring Personnel & List of Equipment
APPENDIX 2 - Raw Data, Sampling Equations & Charts
4
2
7
CONTENTS
9
3
5
6
8
Opinions and interpretations expressed herein are outside the scope of
Exova Catalyst Ireland's ISO 17025 accreditation.
This test report shall not be reproduced, except in full, without the written
approval of Exova Catalyst Ireland.
The testing performed fully meets the technical requirements in Irish EPA
Guidance Note, AG2.
CAT-RT (Version BM)
Page 2 of 20
Quinn Cement Ltd
Ballyconnel
A2-02 ESP Exhaust (Clinker Grate Cooler)
Job Number: CDU-0594, Version 1
Sample Date/s: 1st - 8th March 2016
Irish EPA IPPC Licence: P0378-02
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EPA Export 27-07-2016:01:29:55
Overall Aim of the Monitoring Campaign
Special Requirements
Target Parameters
A2-02 ESP Exhaust (Clinker Grate Cooler)
1st - 8th March 2016
Quinn Cement Ltd, Ballyconnel
(Page 1 of 7)
Exova Catalyst Ireland were commissioned by Quinn Cement Ltd to carry out stack emissions testing on the A2-02 ESP Exhaust
(Clinker Grate Cooler) at Ballyconnel.
The aim of the monitoring campaign was to demonstrate compliance with a set of emission limit values (ELVs) as specified in the
Site's Licence.
There were no special requirements.
Total Particulate Matter
MONITORING OBJECTIVES
Executive Summary
CAT-RT (Version BM)
Page 3 of 20
Quinn Cement Ltd
Ballyconnel
A2-02 ESP Exhaust (Clinker Grate Cooler)
Job Number: CDU-0594, Version 1
Sample Date/s: 1st - 8th March 2016
Irish EPA IPPC Licence: P0378-02
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EPA Export 27-07-2016:01:29:55
where MU = Measurement Uncertainty associated with the Result
Parameter
Total Particulate Matter ¹
Water Vapour
Stack Gas Temperature
Stack Gas Velocity
¹
- -
NOTE: VOLUMETRIC FLOW RATE & VELOCITY DATA TAKEN FROM THE PRELIMINARY VELOCITY TRAVERSE.
¹ Reference Conditions (REF) are: 273K, 101.3kPa, without correction for water vapour content.
°C
Volumetric Flow Rate (ACTUAL)
(Page 2 of 7)
Volumetric Flow Rate (REF)
22712
0.14
494836
m³/hr
1.3
226478 10395
Executive Summary
Mass Emission
501.27
MONITORING RESULTS
A2-02 ESP Exhaust (Clinker Grate Cooler)
-
Units
mg/m³ 5015.6
Result LimitMU
Quinn Cement Ltd, Ballyconnel
1st - 8th March 2016
g/hr 368.622.15
+/-
Units Result
Concentration
MULimit
+/-
% v/v
18.8m/s
0.1
314.8
m³/hr
228700
-
CAT-RT (Version BM)
Page 4 of 20
Quinn Cement Ltd
Ballyconnel
A2-02 ESP Exhaust (Clinker Grate Cooler)
Job Number: CDU-0594, Version 1
Sample Date/s: 1st - 8th March 2016
Irish EPA IPPC Licence: P0378-02
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EPA Export 27-07-2016:01:29:55
Parameter
R1 - -
R1
All results are expressed at the respective reference conditions.
mg/m³
A2-02 ESP Exhaust (Clinker Grate Cooler)
1st - 8th March 2016
5015.6
MONITORING DATE(S) & TIMES
mins
Quinn Cement Ltd, Ballyconnel
Units Concentration
08/03/2016
Sampling
Total Particulate Matter
Units
(Page 3 of 7)
22.1 14:20 - 14:52 32
Executive Summary
Sampling
Times
Velocity & Volumetric Flow Rate 08/03/2016 13:30 -14:15
Date(s)
Mass Emission
g/hr
Duration
CAT-RT (Version BM)
Page 5 of 20
Quinn Cement Ltd
Ballyconnel
A2-02 ESP Exhaust (Clinker Grate Cooler)
Job Number: CDU-0594, Version 1
Sample Date/s: 1st - 8th March 2016
Irish EPA IPPC Licence: P0378-02
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EPA Export 27-07-2016:01:29:55
Standard Operating Conditions
Normal Operation
A2-02 ESP Exhaust (Clinker Grate Cooler)
1st - 8th March 2016
(Page 4 of 7)
Executive Summary
PROCESS DETAILS
Capacity (of 100%) and Tonnes / Hour
Continuous or Batch Process
N/A
Full Capacity
On
Continuous
Parameter
N/A
Fuel
Abatement System
Abatement System Running Status
Plume Appearance
ESP
Not Visible
Process Status
Quinn Cement Ltd, Ballyconnel
Value
Feedstock (if applicable)
CAT-RT (Version BM)
Page 6 of 20
Quinn Cement Ltd
Ballyconnel
A2-02 ESP Exhaust (Clinker Grate Cooler)
Job Number: CDU-0594, Version 1
Sample Date/s: 1st - 8th March 2016
Irish EPA IPPC Licence: P0378-02
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EPA Export 27-07-2016:01:29:55
1st - 8th March 2016
SUMMARY OF SAMPLING DEVIATIONS
Parameter Run Deviation
CAT-TP-03
TPM 1 There are no deviations associated with the sampling employed.
Pitot Tube and Thermocouple
(Page 5 of 7)
Testing
Quinn Cement Ltd, Ballyconnel
Executive Summary
MONITORING & ANALYTICAL METHODS
ANALYSIS LABORATORIES
Velocity & Vol. Flow Rate
(with short name reference as appears in the table above)
Exova Catalyst (CAT)
EN 16911-1 (MID) CAT-TP-41
EN 13284-1
Analysis
CAT Gravimetric
MCERTS
17025
Testing
0.2 mg/m³Yes
Analytical
Technique
Analytical
(Average)
ISOISO
Total Particulate Matter
Water Vapour
A2-02 ESP Exhaust (Clinker Grate Cooler)
Standard
Lab
YesCAT-TP-01
Procedure
LOD
Yes
Lab
Monitoring
CAT
Parameter
Procedure
Technical
Testing
Analysis
CAT Yes
Yes 1.2 m/s
ISO 17025 Accreditation Number: 4279
CAT
CAT-TP-05 YesEN 14790 YesGravimetricCAT-TP-05
Yes
CAT 0.1 % v/v
17025 Analysis
CAT-RT (Version BM)
Page 7 of 20
Quinn Cement Ltd
Ballyconnel
A2-02 ESP Exhaust (Clinker Grate Cooler)
Job Number: CDU-0594, Version 1
Sample Date/s: 1st - 8th March 2016
Irish EPA IPPC Licence: P0378-02
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EPA Export 27-07-2016:01:29:55
Duct Characteristics Location of Sampling Platform
Platform Details
Sampling Location / Platform Improvement Recommendations
EN 15259 Homogeneity Test Requirements
Sampling Plane Validation Criteria (from EN 15259)
Lowest Differential Pressure
Value
Easy Access Available
Depth
21.36
4" BSP
-
-
-
0.00
-
Highest Gas Velocity
Area
Yes
-
-
-
7.31
-
-
Orientation of Duct
Irish EPA Technical Guidance Note AG1 / EN 15259 Platform Requirements
Pa
-
-
Sample Port Size
There is no requirement to perform a EN 15259 Homogeneity Test on this Stack.
121.0
Circular
Value
Safe Access Available
-
Vertical
Yes
Parameter
There are no obstructions present which hamper insertion of sampling equipment
-
0.000.00
-
8
0.00
Port Depth
-
Yes
Traverse 1
m/s
< 3 : 1Ratio of Above : 1 Yes
< 15°
No Local Negative Flow
Platform has vertical base boards (approx. 0.25m high)
> 5 Pa Yes
-
Yes
Yes
m
Lowest Gas Velocity
m/s
Yes
-
17.04
-
-
Required
-
Platform has chains / self closing gates at top of ladders
-18.81
Value
SUITABILITY OF SAMPLING LOCATION
Mean Velocity
Outside
Width
Compliant
-
(Page 6 of 7)
1.25
°
-
--
Units
Yes
19
Permanent / Temporary Platform
Inside / Outside
-
-
m²
m
The sampling location meets all the requirements specified in Irish EPA Guidance Note AG1 and EN 15259, and therefore there are
no improvement recommendations.
Yes
General Platform Information
Criteria in EN 15259
-
-
-
-
--m/s
Maximum Angle of Swirl
Executive Summary
cm
Yes
-
Permanent
Units
-
Platform has 2 levels of handrails (approx. 0.5m & 1.0m high)
Yes
-
-
-
Sufficient working area to manipulate probe and operate the measuring instruments
Type
-
3.05
-
CAT-RT (Version BM)
Page 8 of 20
Quinn Cement Ltd
Ballyconnel
A2-02 ESP Exhaust (Clinker Grate Cooler)
Job Number: CDU-0594, Version 1
Sample Date/s: 1st - 8th March 2016
Irish EPA IPPC Licence: P0378-02
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EPA Export 27-07-2016:01:29:55
Photo 3
Photo 2
SAMPLE POINTS
Executive Summary
PLANT PHOTOS
(Page 7 of 7)
Photo 1
Photo 4
CAT-RT (Version BM)
Page 9 of 20
Quinn Cement Ltd
Ballyconnel
A2-02 ESP Exhaust (Clinker Grate Cooler)
Job Number: CDU-0594, Version 1
Sample Date/s: 1st - 8th March 2016
Irish EPA IPPC Licence: P0378-02
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EPA Export 27-07-2016:01:29:55
APPENDIX 1 - Stack Emissions Monitoring Personnel, List of Equipment & Methods and Technical Procedures Used
APPENDIX 2 - Summaries, Calculations, Raw Data and Charts
APPENDICES
APPENDIX CONTENTS
CAT-RT (Version BM)
Page 10 of 20
Quinn Cement Ltd
Ballyconnel
A2-02 ESP Exhaust (Clinker Grate Cooler)
Job Number: CDU-0594, Version 1
Sample Date/s: 1st - 8th March 2016
Irish EPA IPPC Licence: P0378-02
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EPA Export 27-07-2016:01:29:55
CAT 3.93
Name
Donal O Faogain MCERTS Level 2
Equipment I.D.
STACK EMISSIONS MONITORING PERSONNEL
APPENDIX 1
MM131259
-
-
1m Heated Line (3)
Control Box DGM (1)
Equipment I.D.
Digital Manometer (1)SELECT Horiba Model (1)
Oven Box (2)
Miscellaneous Items
CAT 7.42
Equipment I.D.
-
Position
CAT-TP-05
CAT 3.27
CAT 14.67
-
S-Pitot (1)
L-Pitot
-
-
Laboratory Balance CAT 1.18 / 1.18a
Tape Measure CAT 16.94
Single Channel Heater Controller
CAT 23.30
Instrumental Analysers
S-Pitot (2) -
-
Equipment Type
CAT 4.540
Equipment Type
Technical Endorsements
Team Leader PatricO'Brien MCERTS Level 2
Team Leader
-
EN 13284-1
Technical ProcedureStandard
Heated Probe (1)
-
TE1 TE2 TE4
CAT-TP-01
Barometer
Digital Manometer (2)
Umbilical (1)
Box Thermocouples (2)
Box Thermocouples (1)
5m Heated Line (1) -
500g Check Weight
SELECT Heated Head
Stack Thermocouple (2)
-
-
-
CAT 3.103
-
Mass View (2)
EN 14790
Team Leader
-
-
Umbilical (2) Servomex 5200MP
Oven Box (1)
-
-
Stack Thermocouple (3)
EN 16911-1 (MID) CAT-TP-41
Mass Flow Controller (2) -
Mass View (1) -
20m Heated Line (2)
Parameter
Total Particulate Matter
Bernath 3006 FID -
Water Vapour
- 1m Heated Line (2)
-
SELECT Logger 2 -
Dual Channel Heater Controller -1Kg Check Weight CAT 17.30
Last Impinger Arm -
Callipers
- 20m Heated Line (1)
-
METHODS & TECHNICAL PROCEDURES USED
Tubes Kit Thermocouple -
Stopwatch
15m Heated Line (1)
CAT 17.30
-
SELECT Gas Conditioning
CAT 13.2
Mass Flow Controller (1)
MCERTS Number
-
MCERTS Level 2 MM12 1194 TE1 TE2 TE3 TE4
Heated Probe (2)
-
ABB AO2020-URAS26
-
CAT 3.103
SELECT FTIR
SELECT Horiba Model (2)
Digital Temperature Meter
Heated Probe (3) -
-
Equipment Type
Conor Cooney
SELECT Logger 1
Control Box DGM (2)
Extractive Sampling
LIST OF EQUIPMENT
MCERTS Accreditation
MM08 922 TE1 TE2 TE3 TE4
Team Leader John Glennon MCERTS Level 2 MM101074 TE1 TE2 TE3 TE4
CAT 3.93-
-
CAT 21S.46
Stack Thermocouple (1)
Gasmet Sampling SystemCAT 5.40 1m Heated Line (1)
Servomex 4900
-
Eco Physics CLD 822Mh
Velocity & Vol. Flow Rate
Bioaerosols Temperature Logger -
Electronic Refrigerator -
CAT-RT (Version BM)
Page 11 of 20
Quinn Cement Ltd
Ballyconnel
A2-02 ESP Exhaust (Clinker Grate Cooler)
Job Number: CDU-0594, Version 1
Sample Date/s: 1st - 8th March 2016
Irish EPA IPPC Licence: P0378-02
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EPA Export 27-07-2016:01:29:55
General Stack Details
Stack Gas Composition & Molecular Weights
CO₂ (Estimated)
O₂ (Estimated)
Moisture (H₂O)
Where: p = M / 22.41
pi = r x p
Calculation of Stack Gas Densities
Where: P STD = sum of component concentrations, kg/m³ (not including water vapour)
P STW = sum of all wet concentrations / 100 x density, kg/m³ (including water vapour)
P Actual = P STD x (TSTP / (PSTP)) x ((Pstatic + Pb) / Ta)
P ActualW (at each sampling point) = P STW x (Ts / Ps) x (Pa / Ta)
Calculation of Stack Gas Volumetric Flowrate, Q
Gas Volumetric Flowrate (Actual)
-0.0
-
1.2498
44.01
223509
Gas Volumetric Flowrate REF ¹
%
0.8037
Result
1.9635
-
-
0.2000
m³/hr
REF ¹
0.586
Dry Density (Actual), P Actual
m³/hr
Gas Volumetric Flowrate (STP, Dry)
kg/m³
Gas Volumetric Flowrate (STP, Wet)
Moisture
Conc
0.00118
Pa
0.06
314.8
99.8
% v/v
Units
1.31
kg/m³ 1.280
Duct gas flow conditions
226478
494836
0.589
Wet Density (STP), P STW
-
1.4277 0.28554-
Units
101.3
Temperature
N₂
-
Units
Average Pitot Tube Calibration Coefficient, Cp
ppm kg/m³
Average Stack Gas Pressure
Conc
1.31
Conc
M
Wet
r% v/v
kg/m³
m³/hr
Total Pressure
Average Wet Density (Actual), P ActualW
1.31
79.94 0.99913
1.286
78.89
Dry Density (STP), P STD
18.02
Determinand
0.0006
226478
kg/m³
kPa
0.0131
19.74
p pi
Mass
Component
m³/hr
Result
°C
kg/m³
0.7994 28.01
Fraction
Density
Dry
0.01053
20.00 32.00
Actual
0.06
Volume
148.1
Molar Conc
7.31Stack Area, A
APPENDIX 2
mStack Width, W
314.8
Average Barometric Pressure, Pb
m
Stack Details (from Traverse)
kPa
0.84
Value
3.05
100.0
Average Stack Gas Temperature, Ta
-0.173
m²
-
Units
PRELIMINARY STACK SURVEY: CALCULATIONS
Average Stack Static Pressure, Pstatic kPa
°C
Stack Diameter / Depth, D
Gas Volumetric Flowrate (from Traverse)
CAT-RT (Version BM)
Page 12 of 20
Quinn Cement Ltd
Ballyconnel
A2-02 ESP Exhaust (Clinker Grate Cooler)
Job Number: CDU-0594, Version 1
Sample Date/s: 1st - 8th March 2016
Irish EPA IPPC Licence: P0378-02
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EPA Export 27-07-2016:01:29:56
Parameter Parameter
Date of Survey Initial Pitot Leak Check
Time of Survey Final Pitot Leak Check
Atmospheric Pressure Orientation of Duct
Average Stack Static Pressure Pitot Tube, Cp
Result of Pitot Stagnation Test Number of Lines Available
Are Water Droplets Present? Number of Lines Used
Device Used
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
--
-
-
-
-
-
- -
-
--
-
- -
0.585
136.5
-
-- -
18.09
0.585
18.85
314.0
315.0
-
-
-
-
-
5.0
5.0
- -
-
-
-
-
-
-
-
-
-
- --
8.0
-
-
5.0182.0
--
-
7
315.0
-
121.0
136.0
0.586
8
315.0
314.0
150.0
18.59
162.0
159.6
0.585
314.6Mean
-
0.585
0.32
-
315.0
-
142.0
315.0
2.46
0.586
7.0
0.585
0.585
177.0
2.95
4.0
- -
18.98
151.0
143.020.90
3.0
3
6
19.72
- -
19.04
-
2.06
6.0144.0
17.52
7.0
6.0
0.585
315.0
- -
kg/m³Point °
314.0
4
6.0
-
17.04
315.0
17.92
17.18
315.0 0.585
5.0
315.0
18.46190.0
134.0
5.0
0.585
0.585
20.61
315.0 18.07
18.53
0.586
m/sPa
0.585
m
0.10
18.19
1
0.585
315.00.59
kg/m³
3.0
°C
7.0
°
128.0
148.0
m/s°C
-171.0
5
315.0
123.0 315.0
315.0
-174.0
Pass
VelocitySwirl
No
kPa
-
Wet Density
-
Swirl
Vertical
Pass
Traverse Depth
-
Velocity
Units
APPENDIX 2
7.0
138.0
21.36
19.53
STATIC (Units: Pa)
Value
∆P Temp
Sampling Line B
Pa
100.0
2.73
2
0.586
0.99
Temp
--
13:30 -14:15
Sampling Line A
0.585
PRELIMINARY STACK SURVEY: VELOCITY TRAVERSE TO EN 16911-1 (MID)
-
(1 of 1)
2
Pass
∆P
-
Wet Density
Pa
2
08/03/2016
Value
-
Units
-173 -
-
0.84
S-Type Pitot with KIMO MP 200 (500Pa)
0.585
CAT-RT (Version BM)
Page 13 of 20
Quinn Cement Ltd
Ballyconnel
A2-02 ESP Exhaust (Clinker Grate Cooler)
Job Number: CDU-0594, Version 1
Sample Date/s: 1st - 8th March 2016
Irish EPA IPPC Licence: P0378-02
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EPA Export 27-07-2016:01:29:56
Performance characteristics (Uncertainty Components) UnitsValueUncertainty
0.00053
-
u(k) 0.005
u(∆pi)
u(vi) 0.178
u(v) 0.073
Uc(v) 0.143
Uc,rel(v) 0.76
Standard Uncertainty on the coefficient of the Pitot Tube
Standard Uncertainty associated with the mean local dynamic pressures
- Resolution
- Calibration
- Drift
- Lack of Fit
- Overall corrections to dynamic measurements
Standard uncertainty associated with the molar mass of the gas
- φO₂,w
- φCO₂,w
- Oxygen, dry
- Carbon Dioxide, dry
- Water Vapour
- Oxygen, wet
- Carbon Dioxide, wet
-
Standard uncertainty associated with the mean velocity (95% Confidence)
Standard uncertainty associated with the mean velocity (95% Confidence), relative
Standard uncertainty associated with the volume flow rate (95% Confidence)
%
m/s
Pa
u(res) 0.00087
5.824
175.692
u(pstat) 1.847
u(ρ) 0.00316
%
Uc(qV,w)
0.00055
- #########
- 11587.8
Uc,rel(qV,w) 4.59
Standard uncertainty associated with the mean velocity
-
Standard uncertainty associated with the stack temperature
u(φH₂O) 0.067
u(φO₂,w) 0.604
-
Pa
m/s
-
u(φCO₂,d) 0.002
K
u(pc) 175.702 Pa
u(patm)
u(fit) 3.457
Standard uncertainty associated with the absolute pressure in the duct
- Atmospheric Pressure
u(drift) 0.083
- u(qV,w)
Standard uncertainty associated with the volume flow rate (95% Confidence), relative
u(M) 0.00003
- Static Pressure
Standard uncertainty associated with the density in the duct
Standard uncertainty associated with the local velocities
u(Cf)
u(cal) 2.283
2.612
u(Tc) 2.999
APPENDIX 2
22712.1 m³/hr
- u²(qV,w)
PRELIMINARY STACK SURVEY: VELOCITY TRAVERSE TO EN 16911-1 (MID) - MEASUREMENT UNCERTAINTY(1 of 1)
19.738
- 0.059
u(φO₂,d) 0.612
u(φCO₂,w) 0.002
- u²(a)/a²
- u²(qV,w)/q²V,w
-
CAT-RT (Version BM)
Page 14 of 20
Quinn Cement Ltd
Ballyconnel
A2-02 ESP Exhaust (Clinker Grate Cooler)
Job Number: CDU-0594, Version 1
Sample Date/s: 1st - 8th March 2016
Irish EPA IPPC Licence: P0378-02
For
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ectio
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Conse
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EPA Export 27-07-2016:01:29:56
Sample Runs
- -
- -
- -
- -
- -
- -
- -
- -
Blank Runs
- -
- -
General Sampling Information
FORMAT: Number Used / Number Required
FORMAT: Number Used / Number Required
Reference Conditions
Reference Conditions are: 273K, 101.3kPa, without correction for water vapour content.
g/hr 5015.6
A2-02 ESP Exhaust (Clinker Grate Cooler)
Parameter
Concentration
22.15
Blank 1
Uncertainty
Filter Size and Material
Out Stack
Technical Procedure
Parameter Units
Uncertainty ±g/hr
Quinn Cement Ltd, Ballyconnel
Mean
1.31
Positioning of Filter
Number of Sampling Lines Used 2 / 2
Number of Sampling Points Used 16 / 16
Titanium
Filter Housing Material Borosilicate Glass
Probe Material
Parameter Units
Run 1
Water Vapour
Concentration
Mass Emission
Uncertainty ±mg/m³ 1.27 1.27
Units
TOTAL PARTICULATE MATTER: RESULTS SUMMARY
Mean
368.6
0.08 0.08
368.6
±% v/v
Standard
NOTE: Where the Balance Uncertainty / Limit of Detection is higher than the Blank concentration, the Balance Uncertainty / Limit of Detection concentration has
been reported.
47mm Glass Fibre
0.20
Parameter
EN 13284-1
Sample Point I.D.'s
1.31
CAT-TP-01
A1, A2, A3, A4, B1, B2, B3, B4, C1, C2, C3, C4, D1,
D2, D3, D4
% v/v
Value
APPENDIX 2
5015.6
mg/m³ 22.15
Run 1
Maximum
mg/m³ 0.20
CAT-RT (Version BM)
Page 15 of 20
Quinn Cement Ltd
Ballyconnel
A2-02 ESP Exhaust (Clinker Grate Cooler)
Job Number: CDU-0594, Version 1
Sample Date/s: 1st - 8th March 2016
Irish EPA IPPC Licence: P0378-02
For
insp
ectio
n pur
pose
s only
.
Conse
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EPA Export 27-07-2016:01:29:56
Absolute pressure of stack gas, Ps
Volume of water vapour collected, Vwstd
Volume of gas metered dry, Vmstd
Moisture content, Bwo & Rwv
Bwo as a percentage
Reported Water Vapour, checked with Tables in EN 14790, Rwv
Volume of gas metered wet, Vmstw
Volume of gas metered at Oxygen Reference Conditions, Vmstd@X%O₂ & Vmstw@X%O₂
Molecular weight of dry gas stream, Md
CO₂ (Estimated)
O₂ (Estimated)
Molecular weight of stack gas (wet), Ms
Total flow of stack gas: Actual (Qa), Wet (Qstw), Dry (Qstd), Wet@O₂REF (QstwO₂), Dry@O₂REF (QstdO₂)
Percent isokinetic, %I
N/A
QstdO₂ = ((Qa)(Ps)(Cf)(1 - (Rwv/100))) / ((Ts) + 273) / (O₂REFd) m³/min N/A
Velocity pressure coefficient, Cp
Vmstw = (Vmstd)(100/(100 - Rwv))
Average square root of velocity heads, √∆P
Nozzle area, An mm²
% v/v
0.6943
APPENDIX 2
% v/v
mmH₂O
0.0092
Volume of gas sample through gas meter, Vm m³
Gas meter correction factor, Yd
0.5
109.8
m/s
-
Stack static pressure, Pstatic
m³/min
% v/v 1.31
QstwO₂ = ((Qa)(Ps)(Cf)) / ((Ts) + 273) / (O₂REFw)
%I = (4.6398E⁶)(Ts+273)(Vmstd) / (Ps)(Vs)(An)(q)(1 - (Rwv/100))
m³
Vwstd = (0.001246)(Vlc)
Average dry gas meter temperature, Tm °C 16.0
Vmstd = ((0.3592)(Vm)(Pb + (∆H/13.6))(Yd)) / (Tm + 273) m³
√mmH₂O
-17.1
7.4
Nozzle diameter, Dn
79.14
% oxygen reference condition, REF%O₂ % v/v N/A
% dry oxygen measured in gas stream, ACT%O₂d
O₂ Reference Factor dry (O₂REFd) = (21 - REF%O₂) / (21 - ACT%O₂d)
Vmstw@X%oxygen = (Vmstw) / (O₂REFw) m³ N/A
g
TOTAL PARTICULATE MATTER: ISOKINETIC SAMPLING CALCULATIONS
Test Units
Total mass collected in impingers (liquid trap)
mmH₂O
6.9
g
Total mass of liquid collected, Vlc
m³/min
Barometric pressure, Pb
0.84
O₂ Reference Factor wet (O₂REFw) = (21 - REF%O₂) / (21 - ACT%O₂w)
0.8940
1.31
Md = 0.44(%CO₂)+0.32(%O₂)+0.28(%N₂)
% v/v
0.7035
0.8282
Run 1
-
g
Average of velocity heads, ∆Pavg mmH₂O
Total sampling time, q
7.31
%
310.0
% v/v
-
min 32
% v/v
°C
Total
3868.3
Qstd = ((Qa)(Ps)(Cf)(1 - (Rwv/100))) / ((Ts) + 273) m³/min 3817.6
Ms = Md(1 - (Rwv/100)) + 18(Rwv/100)
N/A
Average stack gas temperature, Ts
15.63
3.95
37.83
m³/min
Vs = ((Kp)(Cp)(√∆P)(√Ts + 273)) / (√(Ms)(Ps)) 19.13
% v/v 20.86
mm
Qstw = ((Qa)(Ps)(Cf)) / ((Ts) + 273)
Conversion factor (K/mm.Hg), Cf
6.94
20.80
Ps = (Pb + (Pstatic / 13.6) mmHg
% wet oxygen measured in gas stream, ACT%O₂w
mmHg
N/A
Qa = (60)(As)(Vs)
Vmstd@X%oxygen = (Vmstd) / (O₂REFd)
Velocity of stack gas, Vs
N/A
N/A
-
m³
m³
Average pressure drop across orifice, ∆H
-
Total mass collected in impingers (silica trap)
Area of stack, As m²
% v/v
Bwo = Vwstd / (Vmstd + Vwstd) 0.0131
60.3
34.97
0.3592
750.0
m³
g/gmol 28.84
748.7
N₂
- N/A
No
Pitot tube velocity constant, Kp
g/gmol 28.70
-
0.06
8385.2
IED & Incinerates Hazardous Material? (Yes = no positive O₂ correction)
CAT-RT (Version BM)
Page 16 of 20
Quinn Cement Ltd
Ballyconnel
A2-02 ESP Exhaust (Clinker Grate Cooler)
Job Number: CDU-0594, Version 1
Sample Date/s: 1st - 8th March 2016
Irish EPA IPPC Licence: P0378-02
For
insp
ectio
n pur
pose
s only
.
Conse
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EPA Export 27-07-2016:01:29:56
Sample Runs
Filter I.D. Number
Probe Rinse I.D. Number
Where: ISO stands for Manual Isokinetic Sampling Train
Blank Runs
Filter I.D. Number
Probe Rinse I.D. Number
g
08/03/2016
g
g
2.83164
Total Mass Collected
Volume Sampled (REF) m³
0.00004
mg
g
g
-
Total Mass in Probe Rinse
Sampling Times
Blank 1
APPENDIX 2
-
End Probe Rinse Mass
2.96458
15.58
Average Volume Sampled (REF)
0.00010
Start Filter Mass
Total Mass in Probe Rinse
14:20 - 14:52
Sampling Dates -
End Probe Rinse Mass
g
0.14616
0.14900
Start Probe Rinse Mass
g
47-31325
47-31273
mg 0.14
0.20
Calculated Concentration
Total Mass Collected
End Filter Mass
-
Parameter
Parameter Units
m³
Balance Uncertainty / LOD
Calculated Concentration
08/03/2016
0.14518
Total Mass on Filter
PR-47-31325
mg/m³
g
g
0.7035
0.00284
-
End Filter Mass g
mg/m³
0.20
0.7035
Units
2.97732
g
0.14508
-
Blank Dates -
mg/m³
2.83168
Total Mass on Filter
TOTAL PARTICULATE MATTER: SAMPLING DETAILS
-
g
PR-47-31273
Start Filter Mass
22.15
0.20
Start Probe Rinse Mass
0.01274
Run 1
Sampling Device ISO
Balance Uncertainty / LOD mg/m³
CAT-RT (Version BM)
Page 17 of 20
Quinn Cement Ltd
Ballyconnel
A2-02 ESP Exhaust (Clinker Grate Cooler)
Job Number: CDU-0594, Version 1
Sample Date/s: 1st - 8th March 2016
Irish EPA IPPC Licence: P0378-02
For
insp
ectio
n pur
pose
s only
.
Conse
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EPA Export 27-07-2016:01:29:56
Sample Runs
MU (Concurrent Water Vapour)
Run 1
-
Yes
APPENDIX 2
Pre-Conditioning Temperature °C
°C
mg/m³ 2.50
Water Droplets
%
Ambient Temperature Recorded? -
Overall Weighing Uncertainty
Less than 50% Faded
Units
Run 1
Units
Filter Temperatures
Units
Yes
Units Run 1
Pre-Sampling Leak Rate l/min 0.11
%
l/min 0.11
Allowable MU
(PAGE 1 OF 2)
Run 1
Run 1
Overall Weighing Uncertainty ± mg
20
°C
Isokinetic Criterion Compliance
Units
Measurement Uncertainty (MU)
-
Allowable Leak Rate
%
109.8%
Leak Test Results
Yes
0.38
120
Mean Sampling Rate l/min 23.14
%
Units
No
Isokinetic Variation
Yes
Run 1
Weighing Uncertainty Acceptable
TOTAL PARTICULATE MATTER: QUALITY ASSURANCE
Isokineticity Acceptable - Yes
-
Silica Gel (Concurrent Water Vapour) Units
Maximum Filter Temperature
Run 1
Post-Sampling Leak Rate
Are Water Droplets Present
l/min
Post-Conditioning Temperature
6.1
0.46
Leak Test Acceptable
ELV [Daily ELV for IED] mg/m³ 50.00
0.27
Run 1
Yes
± mg/m³
Weighing Uncertainty Criteria
160
Allowable Isokinetic Range %
MU Acceptable
Test Conditions Units
Allowable Weighing Uncertainty
95 - 115
180
CAT-RT (Version BM)
Page 18 of 20
Quinn Cement Ltd
Ballyconnel
A2-02 ESP Exhaust (Clinker Grate Cooler)
Job Number: CDU-0594, Version 1
Sample Date/s: 1st - 8th March 2016
Irish EPA IPPC Licence: P0378-02
For
insp
ectio
n pur
pose
s only
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Conse
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EPA Export 27-07-2016:01:29:56
Blank Runs
Method Deviations
1
wx
- - - - -
- - - - -
- - - - -
- - - - -
- - - - -
l/min
-
Yes
Nature of Deviation
Expected Sampling Rate
Blank Acceptable
Blank Acceptable
Allowable Blank
mg/l
25.00
(x = deviation applies to the associated run, wx = deviation also applies to the concurrent water vapour run)
2.7
Blank 1
10
0.13
Post-Sampling Leak Rate l/min 11.00
Allowable Leak Rate
Acetone / Water Rinse Value
mg/m³
Validity of Blank vs ELV Units
5.0
l/min 0.50
l/min
(PAGE 2 OF 2)
There are no deviations associated with the sampling employed.
Acetone / Water Rinse Blank Units Blank
Allowable Blank
Leak Test Results
mg/l
-
Run Number
NoLeak Test Acceptable
Pre-Sampling Leak Rate
Units Blank 1
APPENDIX 2
TOTAL PARTICULATE MATTER: QUALITY ASSURANCE
- Yes
CAT-RT (Version BM)
Page 19 of 20
Quinn Cement Ltd
Ballyconnel
A2-02 ESP Exhaust (Clinker Grate Cooler)
Job Number: CDU-0594, Version 1
Sample Date/s: 1st - 8th March 2016
Irish EPA IPPC Licence: P0378-02
For
insp
ectio
n pur
pose
s only
.
Conse
nt of
copy
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r req
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ny ot
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se.
EPA Export 27-07-2016:01:29:56
Sampled Volume (Actual)
Sampled Gas Temperature
Sampled Gas Pressure
Sampled Gas Humidity
Leak
Mass of Particulate
Uncollected Mass
Sampled Volume (Actual)
Sampled Gas Temperature
Sampled Gas Pressure
Sampled Gas Humidity
Leak
Mass of Particulate
Uncollected Mass
Sampled Volume (STP)
Leak
Mass of Particulate
Uncollected Mass
Sampled Volume (STP)
Leak
Mass of Particulate
Uncollected Mass
O₂ Correction Factor
Stack Gas O₂ Content
MU for O₂ Correction
Combined uncertainty
Expanded uncertainty (95% confidence), without Oxygen Correction
Expanded uncertainty (95% confidence), with Oxygen Correction
Expanded uncertainty (95% confidence), estimated with Method Deviations
Reported Uncertainty
Expanded uncertainty (95% confidence), without Oxygen Correction
Expanded uncertainty (95% confidence), with Oxygen Correction
Expanded uncertainty (95% confidence), estimated with Method Deviations
Reported Uncertainty
Units
289.0
ρm 99.8
Uncertainty in Result
mg/m³
mg/m³
0.14
UCM
L
Vm
% v/v
uρm
Tm uTm K 2.0
0.5
0.8282
Measured Quantities
uUCM mg -
≤1%
0.65
0.6943
% 0.40
Lr mg
uVm m³
≤1%
% 1.00
0.14
1.27
m³
0.0608
<5% of ELV
% 5.7
1.42
mg/m³ 1.27
0.69
%
Measured Quantities
%
uHm
0.0166
N/A
%
Run 1
2.00
Symbol Units Run 1
Run 1
-
Run 1 Requirement of Standard
mg/m³
Overall MU For O₂ Measurement
mg/m³ N/A
5.7
UCM
%
0.08
Uncertainty as a Percentage
N/A
Parameter
%
Symbol Units
mg/m³ 0.603
15.58
1.00
Units
mg
APPENDIX 2
TOTAL PARTICULATE MATTER: MEASUREMENT UNCERTAINTY CALCULATIONS
Value Standard uncertainty
Measured Quantities
- N/A
≤1%
mg/m³ 1.27
% 0.48
mg/m³
% N/A
Units
Run 1
31.90
mg/m³
Run 1
um
Vm
-uL %L 0.48
0.0Hm
kPa
m
≤2%
1.0
Measured Quantities Symbol
Uncertainty in Measurement Units Sensitivity Coefficient
%
Units Run 1
5.7
15.580
1.42
-
0.50
mg/m³
0.1990
0.061
0.1149
Run 1
≤2%
% v/v N/A
-
mg
%
Oxygen Correction Part of MU Budget
Measured Quantities
CAT-RT (Version BM)
Page 20 of 20
Quinn Cement Ltd
Ballyconnel
A2-02 ESP Exhaust (Clinker Grate Cooler)
Job Number: CDU-0594, Version 1
Sample Date/s: 1st - 8th March 2016
Irish EPA IPPC Licence: P0378-02
For
insp
ectio
n pur
pose
s only
.
Conse
nt of
copy
right
owne
r req
uired
for a
ny ot
her u
se.
EPA Export 27-07-2016:01:29:56