Innovations in Ultrapure Water Instrumentation · Innovations in Ultrapure Water Instrumentation...

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Innovations in Ultrapure Water Instrumentation Leading Pure Water Analytics THORNTON History Industries Served THORNTON Products Services Offered

Transcript of Innovations in Ultrapure Water Instrumentation · Innovations in Ultrapure Water Instrumentation...

Page 1: Innovations in Ultrapure Water Instrumentation · Innovations in Ultrapure Water Instrumentation Leading Pure Water Analytics THORNTON History Industries Served ... We work closely

Innovations in UltrapureWater Instrumentation

Leading Pure Water Analytics

THORNTON History

Industries Served

THORNTON Products

Services Offered

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THORNTON History

THORNTON is the recognized leader in resistivity and conductivitymeasurements of high purity water. We work closely with internationalorganizations (such as ASTM, USP and SEMI) in establishing theirstandards. The company, founded in 1964, is based on the research ofDr. Richard D. Thornton, professor of electrical engineering andcomputer science at the Massachusetts Institute of Technology (MIT).The first products were resistivity meters and titanium concentric cellsmanufactured for the US Navy.

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THORNTON created the in-line resistivitymarket and is now recognized as the leaderfor ultrapure water applications andmeasurement expertise throughout theworld. In the semiconductor industry,THORNTON is the leading supplier for ultra-pure water resistivity measurements. In thepharmaceutical market, THORNTON is therecognized leading supplier of conductivityinstrumentation and sensors to meet theUnited States, European and JapanesePharmacopoeia (USP, EP and JP) require-ments. THORNTON’s innovations in thepower industry are generating new con-cepts for measurement, which incorporateunique temperature compensation technol-ogy.

In January 2001, METTLER TOLEDOacquired THORNTON and merged their ana-lytical process businesses, creating aunique partnership between two experts intheir relative fields. THORNTON’s expertisein conductivity and TOC measurement andinnovative instrumentation complementsMETTLER TOLEDO INGOLD’s expertise inpH, dissolved oxygen and turbidity

THORNTON Corporate History

measurements for industrial process con-trol.

By joining forces, THORNTON and METTLERTOLEDO enhanced their capabilities andvalue through expanded instrumentationand applications solutions; helping to betterserve customer needs worldwide in all keyprocess applications. The combined busi-nesses offer customers production centerson four continents and over 250 dedicatedsales and service specialists in more than45 countries (see back cover).

THORNTON’s Autoloop CalibrationSystem ensures product accuracy

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Product & Corporate Capabilities

SEMICONDUCTOR & MICROELECTRONICS PROCESSING:• Sensitive resistivity measurements in ultrapure water systems• High purity temperature compensation• Precision accuracy and repeatability• Reclaim/Reuse water system measurement• High purity chemical delivery control• Dissolved Oxygen measurement• Online TOC measurement

PHARMACEUTICAL WATER MONITORING:• Meet or exceed USP <645> and EP 2.2.38• Accurate, validated, non-temperature compensated conductivity

measurements plus the temperature value• Certified sanitary, stainless steel sensors• Traceable calibration to ASTM and NIST standards

POWER PLANT CYCLE CHEMISTRY:• Specialized temperature compensation for cation conductivity

and ammonia/amine treated specific conductivitymeasurements

• Online measurements for makeup water, boiler feed,condensate polishing and stator cooling

• Dissolved Oxygen measurement

WATER & PANEL SYSTEM FABRICATORS:• Integrated, customized systems providing maximum flexibility• Versatile software for various configurations• Technical support provided through all levels of design,

implementation, calibration, validation and use

SERVICES:• Start-up support• Training seminars and workshops• Application and field support• Traceable instrument calibration• See page 11 for more details

THORNTON’s 770 Series is often used forbio-pharmaceutical control. Stainless steelsensors prevent contamination.

Multiparameter 770 Series meters monitorReverse Osmosis systems for industrialwater pre-treatment. This particular systemuses RO to pretreat and DI to polish.

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THORNTON Capabilities

The 200CR is often used inReverse Osmosis systems

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Benefits• Display 16 measurements on 4 line screen with auto

or manual scrolling• NIST-traceable automatic meter calibration system • Smart Sensors retain factory and user calibration data• Low cost per measurement point, with 6 sensor inputs• One panel cutout replaces 6 for single function

instruments• One instrument - reduces training and parts

Alarm/Control and Outputs• 16 Setpoints for high, low, USP and reset (for

totalizers) alarms• 4 SPDT relay option within the 1/4 DIN case with

individual hysteresis and time delay (optional)• 2 Discrete outputs for logic circuits• 4 powered analog outputs (0/4-20 mA) standard, 8

optional • RS232 serial output / 2 discrete inputs

Features• 6 channels: multiparameter input of 4 Smart Sensors,

including conductivity/resistivity, temperature, flow, pH,ORP, level and pressure, plus 2 pulse flow sensors

• Metric, S.I., and English units for direct measurements;calculated values for % Rejection, % Recovery, differ-ence, sum, ratio and DI capacity. Custom names iden-tify all measurements

• THORNTON’s highest accuracy with lowest limits ofdetection system for UPW resistivity

• Unique 4-wire resistance measurement technique forhighest installed accuracy

• THORNTON’s temperature compensation provideshighest accuracy for UPW, cation and ammoniaconductivity

• Direct one and two-point sensor calibration• pH automatic buffer recognition, during calibration• Compact Size. 1/4 DIN cutout, case only 12 cm deep• Water resistant panel mount is standard, entire unit

sealed with optional back cover• Panel, wall, pipe mounting options are available• UL and cUL listed, CE compliant

THORNTON Products

770MAX Multiparameter Analyzer/Transmitter with Smart Sensor Technology

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THORNTON’s 770MAX monitorsmore inputs in a smaller caseat a lower cost

• Conductivity/Resistivity• Flow• pH/ORP• Temperature• Pressure• Tank Level

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Features• Two channels of conductivity/resistivity/TDS, with tem-

perature, using two-electrode sensors • Calibration with NIST traceability. Wide rangeability

enables high purity sensor calibration in ASTMstandard solutions

• Field-selectable, application-specific temperature com-pensation. Non-compensated measurement alsostandard to meet USP <645> requirements

• High purity to % concentration ranges from the samemodel

• 200 foot sensor-to-instrument cable length• Backlit LCD alphanumeric display• Two optional powered current outputs plus RS232• Up to 4 relays with individually selec-

table parameter, setpoint, hysteresisand delays

• Selectable function security• Sealed, IP65 enclosure with back

cover• Meets CSA/NRTL and CE requirements,

UL listed

200CR ConductivityResistivity System

• Conductivity/Resistivity• Temperature• Total Dissolved Solids (ppm/ppb)• % Rejection• Difference• Ratio• % Chemical Concentration for HCl, H2SO4, NaOH

Benefits• Single instrument for wide range of measurement with

appropriate two-electrode sensors• Easy operation with text-based menus

THORNTON’s 200CR system includessanitary sensors that withstand steamand/or chemical cleaning

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THORNTON Products

The 200CR is part of the 200 Familyof THORNTON products

100M

Conductivity( S/cm)

Resistivity(ohm-cm)

ApplicationRanges

200CR InstrumentCell Ranges

0.01 0.1 1 10 100 1k 10k 100k 1000k

10M 1M 100k 10k 1k 100 10 1

0.1/cm

50/cm

10/cm

Pure waterDistilled water

Drinking waterCooling tower water

Waste watersBrackish/sea water

DI Regeneration acids/bases

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Features• Two channels for one or two measurement parameters• Calibration with NIST and ASTM traceability• Dual parameter display with back-lit LCD• Plain text menus - no codes to memorize• Two 4-20 mA analog outputs plus RS232• Four alarm setpoints freely assignable to 2 or 4 relays • Accurate, selectable, application-specific temperature

compensation modes plus non-compensatedmeasurement to meet USP <645> conductivity require-ments

• Direct % concentration readout for NaOH, HCl andH2SO4

• Dissolved Oxygen readout to low ppb levels• Plug-in connectors for convenient wiring• Enclosure suitable for sealed panel mounting; back

cover available for wall or pipe mounting - both ratedIP65

• UL and cUL listed, CE compliant• Selectable security levels

THORNTON Products

2000 Two Channel MultiparameterMeasurement System

Benefits• Single instrument model for broad choice of

measurements• Wide conductivity/resistivity rangeability enables sen-

sor calibration in ASTM standard solutions even forhigh purity applications

• Unique dissolved oxygen sensor provides extremelylow-maintenance and long life

• Variety of pH/ORP preamp connections enable widechoice of sensors

THORNTON’s 2000 systemrequires no probe maintenancefor several years

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The 2000 can be used withdetachable pH sensors, offeringmore flexibility and lower costsfor electrode replacement

• Conductivity/Resistivity• pH/ORP• Dissolved Oxygen• Temperature

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Features• Two channels, allowing two measurements of pH plus

temperature, and/or ORP (Oxidation-Reduction/RedoxPotential)

• Combination sensors include measuring and referenceelectrodes plus RTD for temperature compensation ofpH with:- Dual threads for insertion or submersion mounting- Flat membrane to resist fouling- No-maintenance, double-junction reference electrode- Stainless steel flow-through design for high purity water

• Preamp accessories accept virtually any pH electrodewith VP, BNC or K9 connection

• Conventional electrode temperature compensation plusadjustable solution temperature compensation for highpurity water ionization effects

• 200 foot sensor-to-instrument cable length• Backlit LCD alphanumeric display• Two optional powered current outputs plus RS232 • Up to 4 relays with individually selectable parameter,

setpoint, hysteresis and delay• Selectable function security• Optional Sealed, IP65 enclosure and connectors• Meets CSA/NRTL and CE requirements, UL listed.

Benefits• Single instrument for pure water, industrial process and

wastewater measurements with appropriate sensors• Low cost per measurement point• Rapid startup with pre-calibrated, low maintenance

sensors• Complimentary to 200 Series Conductivity, Resistivity

and Flow instrumentation

200pH SensorsProcess pH and ORP sensors are designed for easymounting with dual NPT threaded ends for in-line, sub-mersion, or, with a pipe tee, flow through mounting.The flat surface and sealed double junction referenceelectrode greatly reduce maintenance.

The high purity pH sensor provides a sealed flow cham-ber to prevent carbon dioxide contamination from theair. Stainless steel construction shields the electrodeand eliminates flow sensitivity. A combination pH sen-sor with reservoir-fed, flowing junction reference elec-trode gives stable performance in high purity water andbuffer solutions.

200pH & ORP System

The 200pH offers rapid start-up with pre-calibrated, lowmaintenance sensors

THORNTON Products

Several THORNTON sensors can beused in conjunction with the 200pH,such as this retractable sensor.

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Features• Four inputs from any combination of paddle wheel,

vortex, turbine, or other pulse output flow sensors• Total flow, difference and/or % recovery computations• Up to four relays with individually selectable set-

point(s), hysteresis and delay• Batch control capabilities• Two optional, powered 0/4-20 mA output circuits can

be time-shared to give four measurement values• RS232 or RS422 digital outputs are standard to

transmit up to eight flow, total flow, and % recoveryvalues.

• Sealed, IP65 enclosure with back cover• Meets CSA/NRTL and CE requirements, UL listed.

FEED

FLOWSENSOR

RO MEMBRANE

REJECT

Channel A measurement can include % recovery

PRODUCT

FLOWSENSOR

A

B

THORNTON Products

200FLOW 4-ChannelMeasurement System

Virtually all pure water andchemical flow applications can behandled more efficiently withTHORNTON’s 200FLOW.

Benefits• Lowest cost per measurement point• Simplified batch control with multi-stages in a single

instrument• Easy start up and operation with text-based menus• Compatibility with existing sensors• Complementary to 200 Series conductivity, resistivity,

pH and ORP instrumentation

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The 200FLOW can be used in conjunctionwith a variety of sensors such as the flatpaddlewheel flow sensor (above) and theinsertion vortex sensor (right).

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502P Total OrganicCarbon Analyzer

Features• Continuous 15-second analysis with 2-second dis-

play updates• Display TOC, Resistivity or Conductivity

(compensated or uncompensated) and Temperaturesimultaneously

• 4-20 mA analog output for TOC, Resistivity orTemperature

• RS232 digital output for TOC, Resistivity orConductivity (compensated or uncompensated) andTemperature

• Two high/low setpoint alarms• UV Lamp alarm and diagnostics• Stored history of last 255 data points taken• Password lockout of maintenance menus

Benefits• Real-time continuous monitoring• No time-consuming batch measurements• Obtain real data as it happens and react with alarms

when necessary• Wide dynamic operating range of 0.05 MΩ-cm to

18.2 MΩ-cm• Point-of-use or portable monitoring • Low maintenance: no gases or reagents to handle,

store or replace. No membranes or moving parts.• Easy access to UV Lamp with diagnostics and lamp

expiration alarm• Small, flexible, versatile: use as an on-line monitor or

to profile TOC, Resistivity & Temperature throughoutthe system

THORNTON’s 502P measurescontinuously, unlike otherTOC analyzers

By-passSampleOutlet

OxidizedSampleOutlet

TOCResistivityTemperature

UV OxidationPressureControl

Valve

PressureOrifice

ResistivitySensor - 1

esistivityensor - 3

ResistivitySensor - 2

FlowMeter Flow

ControlValve

CPU

LCDDisplay

4-20 mAAnalogOutput

Terminal

Printer(Optional)

(Fine Adjustment)

THORNTON Products

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X

0 10 20 30 40 50 60

5-10 minutesBetweenReadings

Time (minutes)

Brand XBrand Y

Thornton 502P

SEE WHAT YOU'RE MISSING!

TOC

(ppb

)

0

5

10

15

20

30

25

35

45

50

40

XX

XX

X

X

X

X

XXX XX

XX

X X

X X

X

X

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Sensor Features• Non-fouling insertion or submersion mounted sensors• No wetted metal parts• Chemically resistant PEEK or polypropylene• High-temperatures to 200 °C (392 °F)• Wide measuring range to 2000 mS/cm• Unaffected by severe fouling• Simple installation of sensors and accessories• Robust sensor design for maintenance-free operation• Integrated temperature probe for direct temperature

compensation

Features• Continuous sensor diagnostics• Instrument self-monitoring• Simple calibration• 0/4 to 20 mA current output• 4 alarm relays• UL/CSA and CE

Benefits• Offers wide measuring range 0-2000 mS/cm• Ease of use with simultaneous readings• SensoCheck® and GainCheck® monitor system for

any disruptions• Quick connection and start-up with plug-in connectors• Choice of sensors

THORNTON Products

7100 InductiveConductivity System

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The 7100 Inductive Conductivitysystem features non-fouling inser-tion or submersion mounted sensors

These sensors can withstand high-temperatures to 200 °C (392 °F)

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THORNTON Services

On-Site Instrument Operation & CalibrationTraining WorkshopsTHORNTON’s Operator Training Courses are tailored toeach customer’s requirements. The course is conductedin a classroom setting where interaction between instruc-tor and participants is encouraged. Each attendee issupplied with a binder of material detailing the coursecontent and instruments are available for hands-on par-ticipation. The areas covered in this training programfocus on THORNTON instrumentation, calibration, andmaintenance specific to your facility. Additional topicsmay be added or substituted per customer request.

Traceable Instrument CalibrationTHORNTON offers instrument calibration traceable tonational standards. Calibrations are available at our facil-ities in Waltham, Massachusetts, or to minimize downtime, calibrations may be performed at your facility. Eachcalibrated instrument is supplied with a Certificate ofCalibration that provides “as found” and “as left” data thatenables the operator to track instrument performance.Instruments returned to THORNTON are upgraded to latestrevisions of hardware and software at no additional costto the customer.

THORNTON offers customtraining, which meansthat you’ll never spendtime learning materialyou won’t use.

THORNTON Services

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Specialized Conductivity CalibrationsChoose one of seven unique conductivity calibrations tofit your application needs. Choose from standard cali-brations to unique, customer-specified temperature andASTM verification points. System calibrations are alsoavailable where the instrument and sensors are calibrat-ed as a single unit, optimizing system accuracy.

Service & Calibration ContractsTHORNTON will travel to the Customer’s site for thoseitems covered under this agreement, and will providelabor and travel time for the on-site service. Service shallinclude, but is not limited to:• Calibration/Verification of equipment listed in the

contract• Issuance of a “Certificate of Calibration” for each

instrument listed in the contract• Placement of Calibration Stickers on each instrument

listed on the contract• Verification of instrument performance• Identification and verification of all software revisions• Minor repairs and/or adjustment of instruments at a

discounted labor rate

We’ll come to you for instrumentcalibration, minimizing applicationdown-time and maximizing productivity.

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Contact Us

Mettler-Toledo GermanyOckerweg 3D-35396 Giessen, GERMANYTel: +49 641 507 333Fax: +49 641 507 [email protected]

Mettler-Toledo K.K.5F Tokyo Ryutsu Center Annex6-1-1 Heiwajima Ohta-kuTokyo 143-0006, JAPANTel: +81 3 5762-0606Fax: +81 3 5762-0971www.jp.mt.com

Mettler-Toledo Thornton,Worldwide Corporate Office36 Middlesex TurnpikeBedford, MA 01730, USATel: (781) 301-8600Toll Free: 1-800-510-PUREFax: (781) [email protected]

Mettler-Toledo ThorntonParallel Strasse 2D-47198 Duisburg, GERMANYTel: +49 2066 50 99 057Fax: +49 2066 50 99 [email protected]

Mettler-Toledo BrazilAl. Araguaia, 451-AlphavilleBarueri-SP-Brazil 06455-000Tel: +55 11 4166 7400Fax: +55 114166 [email protected]

Mettler-Toledo China589 Gui Ping RoadCao He Jing Hi-Tech ParkShanghai, PRC 200233Tel: +86 21 6485 0435Fax: +86 21 6485 [email protected]

Mettler-Toledo France30, Bd de Douaumont-BP 94975829 Paris Cedex 17, FRANCETel: +33 1 47 37 06 00Fax: +33 1 47 37 46 [email protected]

Mettler-Toledo (Schweiz) AGIm Langacher, PostfachCH-8606 Greifensee SWITZERLANDTel: +41 1 944 45 45Fax: +41 1 944 46 [email protected]

Other worldwide THORNTON distributors

ML0083 Rev. A, 12/01Printed in U.S.A.

Contact THORNTON

www.thorntoninc.com

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