INDUSTRIAL SPECIALTIES l Petroleum Specialties represent a group of products which find wide...

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INDUSTRIAL SPECIALTIES Petroleum Specialties represent a group of products which find wide application in the various processing industries. These products are primarily used in processing for manufacture of high quality finished goods. In most cases the petroleum specialties become part of the finished articles. They impart desirable properties to raw material to facilitate their processing into finished goods. They assist in the processing operations of the manufactured articles. They improve quality and serviceability of the materials being processed. They generally form part of the manufactured articles imparting them desired properties. They enhance the sales appeal of the finished articles.

Transcript of INDUSTRIAL SPECIALTIES l Petroleum Specialties represent a group of products which find wide...

Page 1: INDUSTRIAL SPECIALTIES l Petroleum Specialties represent a group of products which find wide application in the various processing industries. These products.

INDUSTRIAL SPECIALTIES

Petroleum Specialties represent a group of products which find wide application in the various processing industries. These products are primarily used in processing for manufacture of high quality finished goods. In most cases the petroleum specialties become part of the finished articles.

They impart desirable properties to raw material to facilitate their processing into finished goods.

They assist in the processing operations of the manufactured articles.

They improve quality and serviceability of the materials being processed.

They generally form part of the manufactured articles imparting them desired properties.

They enhance the sales appeal of the finished articles.

Page 2: INDUSTRIAL SPECIALTIES l Petroleum Specialties represent a group of products which find wide application in the various processing industries. These products.

SPECIALTY PRODUCT SERVICE PROGRAMME

Study of processes

Recommendation of most suitable products

Advise on correct application practices

Follow up on performance of the products

Suggestions for improving performance

Development of products for special applications

Technical service to the customers

Page 3: INDUSTRIAL SPECIALTIES l Petroleum Specialties represent a group of products which find wide application in the various processing industries. These products.

INDUSTRIAL SPECIALTIES PRODUCT RANGE ALPROL SPECIAL PROCESS OIL

CONKOTE CHAIN CONVEYOR LUBRICANT

DRAWMET METAL DRAWING OIL

ELASTO RUBBER PROCESS OIL

GLAMOL GLASS MOULD OIL

HYTHERM HEAT TRANSFER OIL

KOOLKUT SOLUBLE CUTTING OIL

METAQUENCH QUENCHING OIL

ROLMET ROLLING OIL

RUSTOP RUST PREVENTIVE OIL

SPRAY OIL E AGRICULTURE OIL

TRIMOFIN STRAIGHT CUTTING OIL

TRIMOL STRAIGHT CUTTING OIL

UNIPRO TEXTILE OIL

Page 4: INDUSTRIAL SPECIALTIES l Petroleum Specialties represent a group of products which find wide application in the various processing industries. These products.

CUTTING OILS

CUTTING OPERATION Chip formation in

metal cutting

Heat sources

Built up edges

Cutting fluid paths

Page 5: INDUSTRIAL SPECIALTIES l Petroleum Specialties represent a group of products which find wide application in the various processing industries. These products.

CUTTING OPERATION

Pressure

Friction

Heat

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NECESSITY OF CUTTING FLUID

Heat generation by external friction is reduced / minimised by placing a

suitable lubrication film between the rubbing surfaces of work piece, tool and

chip

Cooling / lubrication of contact surface between tool, work piece and chip

results in improved finish , higher cutting speeds, depth of cut, reduced

power consumption and reduced rate of tool wear.

Prevents the welding/seizure taking place between tool and work piece

resulting from high pressure and high temperatures.

Page 7: INDUSTRIAL SPECIALTIES l Petroleum Specialties represent a group of products which find wide application in the various processing industries. These products.

FUNCTIONS OF CUTTING FLUID

To lubricate the contacting surface of tool, work piece and chip

To cool work piece, tool and chip

To prevent local welding of metal particles to the tool

( minimise built up edges )

To flush swarf from the cutting area

Page 8: INDUSTRIAL SPECIALTIES l Petroleum Specialties represent a group of products which find wide application in the various processing industries. These products.

CHARACTERISTICS OF THE CUTTING FLUIDS Cause no rusting and corrosion of machines, work piece and tool

Cause no discoloration or staining of the metal

Should not smoke or foam in use

Have no objectionable odour

Should not decompose chemically in use

Should not be harmful to the machine operator

Page 9: INDUSTRIAL SPECIALTIES l Petroleum Specialties represent a group of products which find wide application in the various processing industries. These products.

SEVERITY OF METAL CUTTING OPERATION

(In Descending Order)

Internal Broaching (Greatest )

Surface broaching, pipe threading

Plain Tapping, plain threading

Gear Shaving, Cutting and Removing

Deep drilling

Milling

Multi spindle screw machining

Automatic high speed machining

Drilling, shaping, single point turning

Sawing , grinding (Least)

Page 10: INDUSTRIAL SPECIALTIES l Petroleum Specialties represent a group of products which find wide application in the various processing industries. These products.

TYPES OF CUTTING FLUIDS WATER MIX TYPE CUTTING FLUIDS - Available as following type

Forming milky white emulsions

Forming translucent emulsions

Containing EP additives and forming emulsions

Synthetic/Chemical type miscible with water

OIL TYPE OR STRAIGHT CUTTING FLUIDS

Straight cutting oils

Mineral oil / Fatty oil type of cutting fluids

Transparent sulfurized and/or chlorinated cutting oils

Dark, heavy duty sulfurized cutting oils

Page 11: INDUSTRIAL SPECIALTIES l Petroleum Specialties represent a group of products which find wide application in the various processing industries. These products.

WATER MIX CUTTING FLUIDS

Koolkut 30 : General purpose

emulsifiable oil

Koolkut 40 : Emulsifiable oil meeting

IS 1115: 1986

Koolkut EP 66 : Emulsifiable oil with EP

additives

Koolkut 70 : Semi- synthetic oil

Koolkut 80 : Premium Quality

emulsifiable oil

Synthkool 100 : Semi-synthetic oil

Page 12: INDUSTRIAL SPECIALTIES l Petroleum Specialties represent a group of products which find wide application in the various processing industries. These products.

STRAIGHT CUTTING FLUIDS( NON STAININMG TYPE) Trimofin 15 : Low viscosity oil for honing

Trimofin 16 : Medium viscosity oil

Trimofin 18 : High lubricity oil

Trimofin 20 : Low viscosity chlorinated oil

Trimofin 21 : High viscosity chlorinated oil

Trimofin 23 : Sulfurized oil meeting IS 3065 : 1985

Trimofin 25 : Sulfurized oil high viscosity

Trimofin 26 : Sulfurized and chlorinated

Trimofin 27 : Sulfurized and chlorinated

STRAIGHT CUTTING FLUIDS ( STAINING TYPE) Trimofin 54 : Low viscosity sulfurized oil

Trimofin 55 : Chlorinated and sulfurized oil

Trimofin 56 : Chlorinated and sulfurized oil

Trimofin 58 : High viscosity sulfurized oil

Page 13: INDUSTRIAL SPECIALTIES l Petroleum Specialties represent a group of products which find wide application in the various processing industries. These products.

SOLUBLE CUTTING FLUIDS V/S STRAIGHT OILS

CHARACTERISTIC SOL. FLUID ST. OIL

Heat generation Moderate Low

Cooling ability High Low

Oiliness/Lubricity Moderate High

Chemical Activity Moderate High

Rust prevention Moderate High

Cutting speed High Low

Cutting tools H.S. Tools Carbide

Page 14: INDUSTRIAL SPECIALTIES l Petroleum Specialties represent a group of products which find wide application in the various processing industries. These products.

ADDITIVES FOR CUTTING FLUIDS

Fatty oils

Sulfurized fatty oils

Chlorinated Hydrocarbons /waxes

Free sulfur

Oxidation inhibitors

Emulsifiers

Deodorants

Bacteriacides

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TESTS CONDUCTED ON CUTTING FLUIDS Density

Flash point

Viscosity

Viscosity Index

Pour point

Neutralisation Number

Volatility

Copper strip corrosion test

Emulsion test

Freeze test

Cast iron corrosion test

Page 16: INDUSTRIAL SPECIALTIES l Petroleum Specialties represent a group of products which find wide application in the various processing industries. These products.

CARE OF CUTTING FLUIDS (SOLUBLE TYPE)

Do not use hard water above 500 ppm for making emulsions

Keep pH of emulsion at 9

Remove chips and fines regularly

Aerate the emulsion periodically

Clean the system thoroughly when changing the oil

Avoid oil blanket on the surface

Bacterial treatment of the emulsion

Keep the emulsion under circulation during weekly shut down

Page 17: INDUSTRIAL SPECIALTIES l Petroleum Specialties represent a group of products which find wide application in the various processing industries. These products.

CARE OF CUTTING FLUIDS (OIL TYPE)

Remove chips and fines regularly

Remove the sludge daily

Before and after work , wash hands & forearms and apply suitable

barrier cream

Do not wear oily clothes

Wear protective clothings

Use splash guards

Page 18: INDUSTRIAL SPECIALTIES l Petroleum Specialties represent a group of products which find wide application in the various processing industries. These products.

TRIMOFINS IN PREFERENCE TO KOOLKUTS

When more lubrication is required between the contacting surfaces

When it is necessary to reduce friction between the tool and work

piece to maximum extent

In situations where it is necessary to prevent local welding of metal

particles to the tool face. Sulfurized additive type straight cutting oil

are best suited for this purpose

For machining of magnesium and its alloys, it is necessary to use

straight cutting oils as magnesium can combine with oxygen in water

and can create fire hazards

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NUMBERING SYSTEM OF TRIMOFINS

BRAND : TRIMOFINS

FIRST DIGIT : Indicative of staining/ non-staining properties

Number 1 & 2 = Non Staining

Number 5 & 6 = Staining

SECOND DIGIT : Indicative of potency scale

Number 0 = Lowest Potency

Number 8 = Highest Potency

Potency gradation based on type of EP additive and content Chlorination alone lowest potency Sulfurization with free sulfur highest potency .

* If first digit is 1 then second digit indicates % of compounding without

EP additives

Page 20: INDUSTRIAL SPECIALTIES l Petroleum Specialties represent a group of products which find wide application in the various processing industries. These products.

RUST PREVENTIVE OILS

TODAYS SHINING MACHINES ARE TOMORROW'S RUST SCRAPS

METAL (IRON)

WATER OXYGEN

Page 21: INDUSTRIAL SPECIALTIES l Petroleum Specialties represent a group of products which find wide application in the various processing industries. These products.

RUSTING - IMPLICATIONS Damage machinery under cover as well as out of door

Delayed schedules

Costly repairs

Expensive Replacements

BASIC METHODS OF RUST PREVENTION Removing causes of Rust (Oxygen and Moisture )

Increasing the resistance of metal to rusting

(Alloying with Chromium, Nickel or Copper)

Application of Protective coatings

- Metallic coatings

- Lacquers and paints

- Oxides and chemically formed films

- Petroleum based rust preventives

Page 22: INDUSTRIAL SPECIALTIES l Petroleum Specialties represent a group of products which find wide application in the various processing industries. These products.

PETROLEUM RUST PREVENTIVES-TEMPORARY RUST PROTECTORS

Low initial cost

Ease of Application

Durability

Impermeability

Sufficient Elasticity of the film

Transparent film

Page 23: INDUSTRIAL SPECIALTIES l Petroleum Specialties represent a group of products which find wide application in the various processing industries. These products.

CHARACTERISTICS OF PETROLEUM RUST PREVENTIVES

THE FILM SHOULD BE

Repellent to water and impervious to both water vapour and gases

Having sufficient thickness and strength to prevent dust or other solid particles from penetrating and coming in contact with metal surfaces

So as not drain out or evaporate from the surfaces

Having self-healing property

Chemically stable and should not harden to a great extent even on continued storage

Page 24: INDUSTRIAL SPECIALTIES l Petroleum Specialties represent a group of products which find wide application in the various processing industries. These products.

FACTORS AFFECTING SELECTION OF RUSTPREVENTIVES

Exposure

Nature of surface and type of equipment.

Handling methods.

Film characteristics desired.

Packaging

Page 25: INDUSTRIAL SPECIALTIES l Petroleum Specialties represent a group of products which find wide application in the various processing industries. These products.

EXPOSURE Humidity

Condensation

Corrosive atmosphere

Duration of exposure

Temperature and sunlight

Exposure to Fresh/Salt water

Packaging

Page 26: INDUSTRIAL SPECIALTIES l Petroleum Specialties represent a group of products which find wide application in the various processing industries. These products.

HANDLING Rough handling can cause rupture of the rust preventive film and thus

expose the metal surface to the atmosphere to cause rusting.

FILM CHARACTERISTICS Oily lubricating film

Greasy lubricating film.

Dry non lubricating film

Transparent film

Ease of removal

Sealing ability

Film stability and durability

Page 27: INDUSTRIAL SPECIALTIES l Petroleum Specialties represent a group of products which find wide application in the various processing industries. These products.

NATURE OF SURFACES AND TYPE OF EQUIPMENT Plain smooth surfaces

Parts having threads,crevices and holes

Open assemblies

Page 28: INDUSTRIAL SPECIALTIES l Petroleum Specialties represent a group of products which find wide application in the various processing industries. These products.

CLASSIFICATION OF RUST PREVENTIVES

Light Duty : For General storage where moderate

humidity prevails with occasional

condensation.

Moderate Duty : For storage in open sheds or under

tarpaulins etc.

Heavy Duty : For most severe conditions of

exposure

Outdoor storage

Page 29: INDUSTRIAL SPECIALTIES l Petroleum Specialties represent a group of products which find wide application in the various processing industries. These products.

FOUR CLASSES OF RUST PREVENTIVES

CLASS USE OR COMPOSITION

HOT DIP : DIP PARTS IN MELTED PRODUCT

SOLVENT CUT BACK : VOLATILE CARRIER PLUS FILM

FORMING INGREDIENTS

OIL TYPE : LUBRICATING OILS PLUS

FILM FORMING INGREDIENTS

EMULSION TYPE : MIXED WITH WATER BEFORE USE

Page 30: INDUSTRIAL SPECIALTIES l Petroleum Specialties represent a group of products which find wide application in the various processing industries. These products.

HP RUST PREVENTIVES HOT DIP TYPE Products : Rustop 387

Rustop 388

Application : Protection during shipment and

subsequent storage involving

For machined steel surfaces,

threaded pipes, dies etc.

Method : Hot Dip

SOLVENT CUT-BACK TYPE Products : Rustop 173, Rustop 274, Rustop 276

Applications : Indoor protection as well

as inter-process/final application

Applied by : Dip, Spray or Brush

Page 31: INDUSTRIAL SPECIALTIES l Petroleum Specialties represent a group of products which find wide application in the various processing industries. These products.

OILY TYPE

Products : Rustop 276

Rustop 285

Rustop 286

Rustop 287

Applications : Hydraulic Systems,

Gear Cases,

Internal combustion engines

Applied by : Circulation

Page 32: INDUSTRIAL SPECIALTIES l Petroleum Specialties represent a group of products which find wide application in the various processing industries. These products.

EMULSION TYPE

Products : Water based Rust Preventive

Applications : Steel sheets in cold rolling industries

Applied by : Dipping

Page 33: INDUSTRIAL SPECIALTIES l Petroleum Specialties represent a group of products which find wide application in the various processing industries. These products.

NUMBERING SYSTEM FOR RUST PREVENTIVES Rustop Grades : Non Asphaltic Products

First Digit : Indicative of product formulation

: 1 for solvent based

: 2 for oil based

: 3 for greasy film type

Second Digit : Indicating of film type and product

Property

: 7 for water displacing

: 8 for oily / greasy film

Third Digit : Indicating of colour

: 0 to 9 as number increases darker

the colour

Page 34: INDUSTRIAL SPECIALTIES l Petroleum Specialties represent a group of products which find wide application in the various processing industries. These products.

QUENCHING OILS

BASICS OF HEAT TREATMENT

When steel is heated and cooled, the iron it contains undergoes a

structural change. Hot steel at its critical temperature and above is a

solid solution of carbon in face - centered - cubic - iron - Austenite.

When Austenite is cooled rapidly it is transformed to Martensite -

hardest possible with body centred structure.

This cooling can be done by the process known as Quenching.

Page 35: INDUSTRIAL SPECIALTIES l Petroleum Specialties represent a group of products which find wide application in the various processing industries. These products.

HEAT TREATMENT - OBJECTIVE INCREASES

- STRENGTH

- TOUGHNESS

- HARDNESS

- WEAR RESISTANCE

REDUCE BRITTLENESS

IMPROVE MACHINABILITY

RELIEF OF INTERNAL STRAINS

Page 36: INDUSTRIAL SPECIALTIES l Petroleum Specialties represent a group of products which find wide application in the various processing industries. These products.

QUENCHING MEDIUMS Salt Baths

Brine Solution

Synthetic Quenchants

Petroleum quenching Oils

Page 37: INDUSTRIAL SPECIALTIES l Petroleum Specialties represent a group of products which find wide application in the various processing industries. These products.

QUENCHING- OPERATING TEMPERATURES

NATURE OF BATH TEMPERATURE RANGE ( ° C )

WATER : UPTO 100

BRINE SOLUTION : UPTO 102

OIL : UPTO 260

SALT : 149 - 1260

LEAD : 343 - 960

Page 38: INDUSTRIAL SPECIALTIES l Petroleum Specialties represent a group of products which find wide application in the various processing industries. These products.

DISADVANTAGES Salt Baths :

- Difficult to automate

- Formation of sludge

- Quenched parts are difficult to clean

- Difficulties in disposing of spent salts and wash water

Brine Solution :

- Metal corrosion (water)

- Metal distortion

- Metal cracking

Synthetic Quenchants

- Looses concentration

- Expensive

- Not easily available

Page 39: INDUSTRIAL SPECIALTIES l Petroleum Specialties represent a group of products which find wide application in the various processing industries. These products.
Page 40: INDUSTRIAL SPECIALTIES l Petroleum Specialties represent a group of products which find wide application in the various processing industries. These products.

ADVANTAGES OF PETROLEUM QUENCHING OILS• Non corrosive• Non toxic• Suitable for large scale automation• Safe to use• Easily available• Comparatively low price

Page 41: INDUSTRIAL SPECIALTIES l Petroleum Specialties represent a group of products which find wide application in the various processing industries. These products.

OIL CHARACTERISTICS INFLUENCING QUENCHING ABILITY

• BOILING POINT

• VISCOSITY

• OXIDATION STABILITY

• CHEMICAL STABILITY

• THERMAL PROPERTIES

• FLASH POINT

• FREEDOM FROM WATER

Page 42: INDUSTRIAL SPECIALTIES l Petroleum Specialties represent a group of products which find wide application in the various processing industries. These products.

COOLING STAGES IN QUENCHINGA. Leindenfrost stage or vapour blanket stage - Formation of vapour due to sudden immersion of hot steel - Cooling of steel takes place by conduction and radiation - Vapours are poor conductors of heat - Cooling of metal is relatively slow

B. Vapour Transport Stage - Energetic boiling of quenchent - Wetting of metal

- Fastest rate of cooling

C. Liquid Cooling Stage - Formation of vapour bubbles is stopped

- Cooling by conduction and convection - Rate of cooling is slower compared to VT Stage.

Page 43: INDUSTRIAL SPECIALTIES l Petroleum Specialties represent a group of products which find wide application in the various processing industries. These products.
Page 44: INDUSTRIAL SPECIALTIES l Petroleum Specialties represent a group of products which find wide application in the various processing industries. These products.
Page 45: INDUSTRIAL SPECIALTIES l Petroleum Specialties represent a group of products which find wide application in the various processing industries. These products.

TYPE OF PETROLEUM HPC QUENCHING OILQUENCHING OIL

• Straight Oils : Metaquench 39 Metaquench 40

• Compounded Oils : Metaquench 42

• Additive type Oils : Metaquench 43 Metaquench 44

• Marquenching Oils : Metaquench 85Metaquench 86

Page 46: INDUSTRIAL SPECIALTIES l Petroleum Specialties represent a group of products which find wide application in the various processing industries. These products.

STRAIGHT OILS•General purpose quenching oils

•Compatible with cyanide carry over

•Can be used from ambient to 90°C

COMPOUNDED OILS•Blends of straight oil and fatty oils

•Fatty oils assist in better wetting

•Not recommended for cyanided parts.

Page 47: INDUSTRIAL SPECIALTIES l Petroleum Specialties represent a group of products which find wide application in the various processing industries. These products.

ADDITIVE TYPE• Blend of straight oil and additives

• Wetting agents

• Anti oxidants

• Detergents and Dispersants

MARQUENCHING OILS• Bath maintained at martensite temp

• Imparts less thermal shocks to the metal.

• Enables accurate and controllable quenching

• Lesser rejections

• Used mainly in automotive and bearing industries

Page 48: INDUSTRIAL SPECIALTIES l Petroleum Specialties represent a group of products which find wide application in the various processing industries. These products.

OPERATIONAL PROBLEMS Insufficient hardness can be due to

•Change in the composition of steel•Insufficient heating of the metal to its critical temperature•Time lag in transferring the metal from furnace to bath•Thickening of oil due to oxidation / sludging / dirt•Inadequate agitation

FIRE HAZARDS•Contamination with lighter oil fractions.•Insufficient circulation.

•Hot Spots•Presence of water beyond 0.5%

•Foaming•Violent Boiling

Page 49: INDUSTRIAL SPECIALTIES l Petroleum Specialties represent a group of products which find wide application in the various processing industries. These products.

TYPICAL INSPECTION OF QUENCHING OIL

Grade Viscosity Flash GM

CST @ 40 °C COC.°C QUENCHO

METER READING,

SECONDS

Metaquench 39 28 190 27.9

Metaquench 40 62 220 29.0

Metaquench 42 28 190 24.1

Metaquench 43 28 190 20.6

Metaquench 44 28 190 9.0

Metaquench 85 16 @100 °C 240 34.6

Metaquench 86 16 @ 100 °C 240 12.5

Page 50: INDUSTRIAL SPECIALTIES l Petroleum Specialties represent a group of products which find wide application in the various processing industries. These products.
Page 51: INDUSTRIAL SPECIALTIES l Petroleum Specialties represent a group of products which find wide application in the various processing industries. These products.

ROLLING OILS

Page 52: INDUSTRIAL SPECIALTIES l Petroleum Specialties represent a group of products which find wide application in the various processing industries. These products.

METAL ROLLING OILS

Rolling of metals is a process by which the thickness of the metal is reduced to the desired level by means of rotating rolls.

Page 53: INDUSTRIAL SPECIALTIES l Petroleum Specialties represent a group of products which find wide application in the various processing industries. These products.

Metal rolling process may be divided into two basic categories :

Hot Rolling : Where the metal is pre-heated

and rolled

Cold Rolling : Where the metal is rolled at

the ambient temperature

Page 54: INDUSTRIAL SPECIALTIES l Petroleum Specialties represent a group of products which find wide application in the various processing industries. These products.

FUNCTIONS OF ROLLING OIL• Reduce friction between rolls.

• Provide adequate 'Bite' between roll and work.

• Good conductor of heat.

• Proper viscosity

• Good Oxidation Stability

• Non Corrosive

• Non Staining

• Non toxic

Page 55: INDUSTRIAL SPECIALTIES l Petroleum Specialties represent a group of products which find wide application in the various processing industries. These products.

CHARACTERISTICS OF ROLLING OIL• Proper viscosity.

• Water demulsibility property.

• Good oxidation stability.

• Non corrosive.

• Non staining.

• Non toxic.

Page 56: INDUSTRIAL SPECIALTIES l Petroleum Specialties represent a group of products which find wide application in the various processing industries. These products.

SELECTION OF ROLL OILS• Type of metal being rolled.

• Temperature of the metal.

• Rolling speed.

• Reduction schedule.

• Roll oil system-Recirculating or once used.

• Annealing equipment.

• Quality requirements.

Page 57: INDUSTRIAL SPECIALTIES l Petroleum Specialties represent a group of products which find wide application in the various processing industries. These products.

TYPES OF ROLL OILS :• Straight Mineral Roll Oils• Compounded Roll Oils• Emulsifiable Roll Oils

HP GRADES :• ROLMET 40• ROLMET 43• ROLMET 45

Page 58: INDUSTRIAL SPECIALTIES l Petroleum Specialties represent a group of products which find wide application in the various processing industries. These products.

TYPICAL INSPECTION OF ROLL OILS

Characteristics ROLMET40 ROLMET N 34 ROLMET V 40

Appearance Clear Clear Clear

Viscosity Kin.@ 40 0 C 24 10 25

Flash PointCOC 0 C 160 150 170

Pour Point 0 C 0 0 0

Neutralisation No 1 0.05 0.5mgh KOH/gm

Page 59: INDUSTRIAL SPECIALTIES l Petroleum Specialties represent a group of products which find wide application in the various processing industries. These products.

RUBBER OILS

Page 60: INDUSTRIAL SPECIALTIES l Petroleum Specialties represent a group of products which find wide application in the various processing industries. These products.
Page 61: INDUSTRIAL SPECIALTIES l Petroleum Specialties represent a group of products which find wide application in the various processing industries. These products.

ASTM Elastomer Trade names

Classification

NR Isoprene Rubber Natural Natural

SBR Styrene - Butadiene Rubbers GR-S, BUNA S

IIR Isobutylene - Isoprene Rubbers BUTYL

NRB Nitrile - Butadine Rubbers BUNA N

CR Chloroprene Rubbers Neoprene

EPM Ethylene Propylene Copolymer EPR, EPN

BR Butadine Rubbers Polybutadiene PB

Page 62: INDUSTRIAL SPECIALTIES l Petroleum Specialties represent a group of products which find wide application in the various processing industries. These products.

PROCESSING OF GENERAL RUBBER GOODS

In order to process crude, synthetic or reclaimed rubber into condition suitable for use it must be put through several processes such as :

1. Break Down

2. Mixing

3. Calendering

4. Extruding

5. Preparation for curing

6. Vulcanizing

Page 63: INDUSTRIAL SPECIALTIES l Petroleum Specialties represent a group of products which find wide application in the various processing industries. These products.
Page 64: INDUSTRIAL SPECIALTIES l Petroleum Specialties represent a group of products which find wide application in the various processing industries. These products.

COMPOUNDING INGREDIENTS USED IN RUBBER GOODS MANUFACTURE

Vulcanizing Agents (Sulfur)

Accelerators (Sulfur Derivatives)

Activators (Stearic Acid)

Antioxidants (Phenolic Derivatives)

Fillers (Carbon Black)

Reinforcing Agents (Nylon, Rayon)

Softeners (Easters, Resins, Veg. Oils)

Tackifiers

Pigments (Colouring materials)

Retarders

Plasticizers oils / chemicals

Anti Ozonants

Page 65: INDUSTRIAL SPECIALTIES l Petroleum Specialties represent a group of products which find wide application in the various processing industries. These products.

FUNCTIONS OF RUBBER OIL1.Process Oils:

To improve processibility of rubber in milling, mixing and extruding.

To improve physical properties of valcanizites To reduce production costs

2.Extender Oils

Used in extended SBR aromatic / naphthenic oil use for desired finish They

contain 20 to 50% of oils per 100 parts of Rubber.

3.Reclaiming Oils

Aromatic oils are widely used.

5% of oil on the wt. of rubber is generally used

4.Secondary Plasticizers

Used in PVC cloth manufacture

Di-Octyl Phathalate (DOP)

Di-Isooctyl Phathalate (DIOP)

DI-Butly-Phthalate (DBP)

Page 66: INDUSTRIAL SPECIALTIES l Petroleum Specialties represent a group of products which find wide application in the various processing industries. These products.

DESCRIPTION OF PETROLEUM OILS

(AS PER ASTM)% Saturates % Polar % Asphaltenes

Compounds

Type 101

(Highly aromatic) 20 Max. 25 Max. 0.75 Max.

Type 102

(Aromatic)2 0.1 - 35 12 Max. 0.5 Max.

Type 103

(Naphthenic) 35.1 - 65 6 Mix. 0.3 Max.

Type 104

(Napthenic &

Paraffinic) 65.1 Min. 1 Max. 0.1 Max.

Page 67: INDUSTRIAL SPECIALTIES l Petroleum Specialties represent a group of products which find wide application in the various processing industries. These products.

HP RUBBER OILSElasto 245 Paraffinic

Elasto 215

Elasto 541 Naphthenic

Elasto 590

Elasto 710 Aromatic

Elasto 715

ELASTO 215, 245Paraffinic Type

High Flash Point

Low Solvency

Greatest use in butyl and EP DM rubbers

Used for processing light coloured goods, white walled tyres, shoe soles, toys, sporting goods.

Page 68: INDUSTRIAL SPECIALTIES l Petroleum Specialties represent a group of products which find wide application in the various processing industries. These products.

ELASTO 541, 590• Naphthenic type

• Good colour stability

• Solvency better than Elasto 245

• Used as general purpose rubber oil, tyres, mats, footwear,

moulded and extruded goods

ELASTO 710, 715• Aromatic type

• Dark colour

• Compatible with most rubber polymers

• Automobile tyres, beltings, battery cases

• For oil extended rubber

• For rubber reclaiming

Page 69: INDUSTRIAL SPECIALTIES l Petroleum Specialties represent a group of products which find wide application in the various processing industries. These products.

TESTING OF THE PROPERTIES OF EXTENDER AND RUBBER OILS• Specific Gravity

• Viscosity

• Flash Points

• Volatality

• Pour Point

• Aniline Point

• Neutralization Number

• Refractive Index & Refractive Intercept

• Viscosity Gravity Constant

• U.V. Absorptivity

Page 70: INDUSTRIAL SPECIALTIES l Petroleum Specialties represent a group of products which find wide application in the various processing industries. These products.

REFRACTIVITY INTERCEPT

The refractivity intercept of an oil is equal to refractive index @ 20 0 C ½ density 2 0 C.

VISCOSITY GRAVITY CONSTANT

VGC = (G - 0.24) - 0.022 LOG (V1 - 35.5)

0.755

G = Sp. Gravity @ 60 0 F

V1 = SUS @ 210 0 F

GENERAL INTERPRETATION OF VGC

VGC Range Oil Type

0.79 - 0.82 Paraffinic

0.82 - 0.90 Naphthenic

0.90 and above Aromatic

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Page 72: INDUSTRIAL SPECIALTIES l Petroleum Specialties represent a group of products which find wide application in the various processing industries. These products.
Page 73: INDUSTRIAL SPECIALTIES l Petroleum Specialties represent a group of products which find wide application in the various processing industries. These products.

RUBBER OILS : NOMENCLATURE

Brand ELASTO

First Digit : Indicative of aromatic content.

First digit multiplied by 10

gives approx. % aromatics.

Second and

Third Digits :Indicative viscosity

Second and Third digits together show approx. SUS @ 100 OC

When product viscosity is more than 100 @ 210 0FLast two digits

Multiplied by 10 give products

viscosity @ 100 OC.

Page 74: INDUSTRIAL SPECIALTIES l Petroleum Specialties represent a group of products which find wide application in the various processing industries. These products.

RUBBER OILSProperties Elasto

245 541 710

Viscosity cst @ 40 OC 33 21 -

@ 100 0C - - 23

Flash Point, COC OC 190 160 220

Aniline Point, COC OC 96 75 48

Pour Point OC 0 0 15

Molecular Analysis

ASTM D 2007

Asphltenes Wt % Nil Nil Nil

Polar Compounds wt % 0.6 1.3 17

Aromatics wt % 20.3 47.5 73

Saturates wt % 79.1 51.2 10

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HEAT TRANSFER OILS

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Heat transfer fluids or heat carriers are defined as fluids which absorb thermal energy delivered from a source and then by cooling, or change of phase surrender to a place of utilization called a sink.

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TYPES OF HEAT TRANSFER MEDIAGrases - Air

Vapours - Steam

Liquids - Mineral Oil

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HEAT TRANSFER FLUIDMajor Advantage of Liquid heat transfer fluid

• Lower cost installation

Large diameter piping

Safety Valves

• Capital Cost Reduction Steam Traps

Water treatment facilities

• Lower Operating Cost

Low Maintenance Requirement

Reduced Make Up

Page 79: INDUSTRIAL SPECIALTIES l Petroleum Specialties represent a group of products which find wide application in the various processing industries. These products.

PETROLEUM HEAT TRANSFER FLUID

Meet the exacting requirement of the customer.

Manufactured under special refining process.

Contribute an unusual versatility that improves operating characteristics in a number of important respects.

Page 80: INDUSTRIAL SPECIALTIES l Petroleum Specialties represent a group of products which find wide application in the various processing industries. These products.

SELECTION CRITERIA

1. Design Properties (Heat transfer and Transport properties).

Density specific gravity expansion coefficient.

Heat capacity (Specific heat).

Heat content (Enthalpy).

Heat conductivity.

Viscosity.

2. Construction Properties (Limited Properties)

Physical stability.

Chemical stability.

Thermal stability.

Cost

3. Operation Properties (Handling Properties)

Surface tension.

Corrosion.

Flammability.

Physiological effects

Page 81: INDUSTRIAL SPECIALTIES l Petroleum Specialties represent a group of products which find wide application in the various processing industries. These products.

PROPERTIES OF THERMIC FLUID

Reasonably low pour point.

Specific heat - heat transfer properties are reasonably well maintained.

Thermally stable.

Stability to oxidation.

Not too viscous at ambient temperature (Cold start problem)

Should not loose viscosity too much at high temperature - (High VI)

Low vapour pressure - Fairly high Boiling Point

Free from water & insoluble materials.

Free from acidic reaction.

Page 82: INDUSTRIAL SPECIALTIES l Petroleum Specialties represent a group of products which find wide application in the various processing industries. These products.

HP HEAT TRANSFER FLUIDS

HYTHERM 400

HYTHERM 500

HYTHERM 600

Page 83: INDUSTRIAL SPECIALTIES l Petroleum Specialties represent a group of products which find wide application in the various processing industries. These products.

TYPICAL INSPECTION OF THERMIC FLUIDS

CHARACTERISTICS HYTHERM 500 HYTHERM600

Viscosity Kin. cSt.@

40 0C 30 33

Flash Point, COC, 0 C 200 205

Pour Point, 0 C 0

Neut No, mg KOH/gm 0.1 0.05

Specific heat @ 300 0 C 0.665 0.666

Thermal Conductivity@ 300 0 C 97.2 94.1

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Page 85: INDUSTRIAL SPECIALTIES l Petroleum Specialties represent a group of products which find wide application in the various processing industries. These products.

DRAWING COMPOUNDS

Page 86: INDUSTRIAL SPECIALTIES l Petroleum Specialties represent a group of products which find wide application in the various processing industries. These products.

METAL FORMING PROCESS

• PRESSING

• STAMPING

• FORGING

• DEEP DRAWING

• WIRE DRAWING

• TUBE DRAWING

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TYPES OF DRAWING

• HOT DRAWING• COLD DRAWING

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TYPES OF DRAWING COMPOUNDS

• WATER BASED• OIL BASED• SOLID LUBRICANTS

Page 89: INDUSTRIAL SPECIALTIES l Petroleum Specialties represent a group of products which find wide application in the various processing industries. These products.

HP DRAWING COMPOUNDS

• DRAWMET 15• DRAWMET 22• DRAWMET 44• DRAWMET 66

Page 90: INDUSTRIAL SPECIALTIES l Petroleum Specialties represent a group of products which find wide application in the various processing industries. These products.

SELECTION OF DRAWING COMPOUNDS

• TYPE OF DRAWING OPERATION

• METAL BEING DRAWN

• SEVERITY OF DRAWING

Page 91: INDUSTRIAL SPECIALTIES l Petroleum Specialties represent a group of products which find wide application in the various processing industries. These products.

AUTOMOTIVE SPECIALTIES

•HP KOOLGARD

•SHOCK ABSORBER OIL

•SUPER DUTY BRAKE FLUID-DOT3

Page 92: INDUSTRIAL SPECIALTIES l Petroleum Specialties represent a group of products which find wide application in the various processing industries. These products.

HP SHOCK ABSORBER OILS:

•HP SHOCK ABSORBER OIL LIGHT

• HP SHOCK ABSORBER OIL HEAVY

•HP SHOCK ABSORBER OIL AW

•HP SHOCK ABSORBER OIL TELE

Page 93: INDUSTRIAL SPECIALTIES l Petroleum Specialties represent a group of products which find wide application in the various processing industries. These products.

SHOCK ABSORBER OILS

SHOCK ABSORBER DAMPING EFFECTINCREASES COMFORT

SHOCK ABSORBER HYDRULIC TYPEPNEUMATIC TYPE

BOTH THESE TYPES OF SHOCK ABSORBERS NEED TO BEOIL FILLED,SEALED FOR LIFE.SHOCK ABSORBER ASSEMBLY HAS RUBBER COMPONENTS TO SEAL OIL LEAKAGE WHICH COMES IN CONTACT WITH OIL.MINERAL OIL AFFECTS RUBBER.HENCE DUE IMPORTANCE IS GIVEN WHILE FORMULATING SHOCK ABSORBER OILS.THUS ANNILINE POINT SPECIFICATION BECOMES IMPORTANT.

Page 94: INDUSTRIAL SPECIALTIES l Petroleum Specialties represent a group of products which find wide application in the various processing industries. These products.

IMPORTANT MANUFACTURERS OF SHOCK ABSORBERSSTALLION SHOXHYDRAULICS LTD.INTERNATIONAL INSTRUMENTSGABRIEL INDIA LTD.D.H.WOODHEADSACHSARMSTRONGMUNJAL SHOVA(HERO HONDA- REAR)ESCORTS TELE

Page 95: INDUSTRIAL SPECIALTIES l Petroleum Specialties represent a group of products which find wide application in the various processing industries. These products.

SPECIFICATIONS

CHARACTERISTIC HP SHOCK ABSORBER OIL TELE AW

KINEMATIC VISCOSITY CST @ 40 oC 35--40 11.5--13.1CST @ 100 oC 5.75 2.7

POUR POINT, oC -21 -45FLASH POINT, oC 200 149ANNILINE POINT, oC 105 78RUBBER SWELLING TESTCHANGE IN VOL%MAX. +5 +5

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SPECIFICATIONS

CHARACTERISTIC HP SHOCK ABSORBER OIL LIGHT HEAVY

KINEMATIC VISCOSITY CST @ 40 oC 11.0--12.3 18.1--21.3CST @ 100 oC 2.6 AVG. 3.3 MIN.

POUR POINT, oC -40 -37FLASH POINT, oC 145 160ANNILINE POINT, oC 71--77 71--82SAP VALUE,MG.KOH/gm. 5.5--7.0 5.5--7.0COPPER STRIP CORROSION - - 3 HRS.@ 100 oC MAX.FOAM STABILITY 0/0/0 0/0/02 INC MIN. 0.15 0.15

Page 97: INDUSTRIAL SPECIALTIES l Petroleum Specialties represent a group of products which find wide application in the various processing industries. These products.

SIGNIFICANCE OF THE CHARACTERISTICS

ANILINE POINT LOWER THE ANNILINE POINT

GREATER THE SWELLING TENDENCY.

POUR POINT LOWER POUR POINT MAKES THESE OILS

SUITABLE FOR YEAR ROUND SERVICE IN ALL WEATHER CONDITIONS.

Page 98: INDUSTRIAL SPECIALTIES l Petroleum Specialties represent a group of products which find wide application in the various processing industries. These products.

AUTOMOTIVE BRAKE FLUIDS

MINERAL OIL AFFECTS ALL TYPES OF RUBBER HENCE BRAKE FLUID IS NOT MADE WITH USE OF MINERAL OIL.

SIMILARLY VEGETABLE OILS DETERIORATE FASTER AT HIGH TEMPERATURE AND CAUSE SAFETY RISK.

HENCE NOT USED IN MODERN VEHICLES.

MIXTURE OF CASTOR OIL AND ALCOHOL, GLYCOLS AND POLYGLYCOLS ARE USED TO PRODUCE DIFFERENT TYPES OF BRAKE FLUIDS.

Page 99: INDUSTRIAL SPECIALTIES l Petroleum Specialties represent a group of products which find wide application in the various processing industries. These products.

BRAKE FLUIDS

ISI HAS WITHDRAWN IS:317-1970 FOR MODERATE DUTY BRAKE FLUID

HP STANDARD BRAKE FLUID NO LONGER MARKETED.

WE MARKET TWO TYPES OF BRAKE FLUIDS-

- HP HEAVY DUTY BRAKE FLUID MEETS IS:8654-1977 (AMENDMENT-1) SPECS.

SUITABLE FOR USE IN MOST AUTOMOTIVE VEHICLES AND CARRIES THEIR APPROVAL.

- HP SUPER DUTY BRAKE FLUID (DOT 3) MEETS - FMVSS

16 DOT 3 OF USE\A

SAE 3 1703 JAN. 80

IS : 8654 - 1977

Page 100: INDUSTRIAL SPECIALTIES l Petroleum Specialties represent a group of products which find wide application in the various processing industries. These products.

BRAKE FLUIDS

SPECIFICATION HP SUPER DUTY BRAKE FLUID Dot-4 Dot 3

KINEMATIC VISCOSITY CST @100 0 C 1.5 MIN 1.5 MIN CST @ -40 0 C 1800 MAX. 1500 MAX

MAX BOILING POINT 0 C 230 205

SIGNIFICANCE OF TESTS:REFLUXE BOILING POINT - HIGH REFLUXE BOILING POINT AVOIDS VAPOUR LOCK AT HIGH SERVICE TEMPERATURE

Page 101: INDUSTRIAL SPECIALTIES l Petroleum Specialties represent a group of products which find wide application in the various processing industries. These products.

AUTOMOTIVE BRAKE FLUIDS

MINERAL OIL AFFECTS ALL THESE TYPES OF RUBBER HENCE BRAKE FLUID IS NOT MADE WITH USE OF MINERAL OIL.

SIMILARLY VEGETABLE OILS DETERIORATE FASTER AT HIGH TEMPERATURE AND CAUSE SAFETY RISK.

HENCE NOT USED IN MODERN VEHICLES.

MIXTURE OF CASTOR OIL AND ALCOHOL, GLYCOLS AND POLYGLYCOLS ARE USED TO PRODUCE DIFFERENT TYPES OF BRAKE FLUIDS.

Page 102: INDUSTRIAL SPECIALTIES l Petroleum Specialties represent a group of products which find wide application in the various processing industries. These products.

HP KOOLGARD

• EFFECTIVE COOLANT

• FREEZE PROTECTION

• COOLING SYSTEM PROTECTION

Page 103: INDUSTRIAL SPECIALTIES l Petroleum Specialties represent a group of products which find wide application in the various processing industries. These products.

HP KOOLGARD

• MEETS JIS-2234 SPECIFICATIONS

• MEETS ASTM - 3306 PERFORMANCE

• CONCENTRATIONS RECOMMENDED

33% IN WATER FOR AMBIENT TEMPERATURES UP TO (-) 15 OC

50% IN WATER FOR AMBIENT TEMPERATURES UP TO (-) 34 OC