INDUSTRIAL HAZARD STUDY--MSDS--VOL-1,EDITION-1

INDUSTRIAL CONTINUOUS PROCESS IMPROVEMENT

& SAFETY MSDS

2/22/16 1 BILAL MASOOD

HAZOP – HAZAN -‐ HAZID STUDY

CONDUCTED BY

BILAL MASOOD

PRELIMINARY -‐-‐ PAINT INDUSTRY

VOLUME -‐1 EDITION-‐1

2/22/16 BILAL MASOOD 2

PRIMILIARY HAZOP/RISK STUDY

BUILDING

HUMAN

EQUIPMENT

MEDIUM HIGH

LOW VERY LOW

LEVEL OF RISK

OTHER INDUSTRIAL

UNITS

MATERIALS

NEGLECTED

PRODUCTS RAW MATERIALS

WARE HOUSE NITROCELLOUSE

OTHER PRODUCTS

WASTE

BILAL MASOOD

MACHINES

3 2/22/16

BILAL MASOOD

MATERIALS BUILDING

PPE-‐HUMAN WASTE EQUIPMENT/TOOLS/CONTAINERS

HAZID STUDY

MACHINES

CLEANING

OTHER-‐SIGNS

TRANSPORTATION

SAFETY DATA SHEETS

INDUSTRY PATHS/PASSAGES SIGNS

AWARENESS

LABELING/CODING

FIRE SAFETY

ADVANCEMENT MEDICAL/FIRST AID UTILITIES

MANAGEMENT

DISPLAY BOARDS

TOPICS & CHAPTERS

4

CONTROL TECHNIQUES

SAFETY ENGINEER

HAZAN STUDY

HAZOP STUDY

RISK

WORKERS BETTERMENT

EXTERNAL CONDITIONS

BIOLOGICAL SAFETY

OFFICE MANAGEMENT

LOCOMOTION MANAGEMENT

OTHER INDUSTRIAL UNITS

STORAGE & INVENTORY PESTS & RODENTS

SOP’S & QUALITY

SHIFT CHANGE HAZIDS

CHECK SHEETS

DISPATCH & FILLING/PACK

FERNITURE ENVIROMENT

COMMUNICATION

INDUSTRIAL SURVEY

HAZA

N STU

DY

CHAPTERS-‐D

CHAPTERS-‐A

CHAPTERS-‐F

QUALITY

SPECIAL -‐CHAPTERS-‐Z

LAB (GLP) PRODUCTION SUPPLY CHAIN LEAN DECISION TOOLS PLANNING TOOLS GMP ANALYSIS TOOLS WARE HOUSE MANAGEMENT

EXTERNAL WORK

HAZMAT

CHAPTERS-‐R

Nitro Cellouse SAFETY

2/22/16

MSDS MAKING

MSDS CHEMICAL

BILAL MASOOD 5

MSDS-‐-‐CHAPTER SECTIONS INTRODUCTION

MSDS 16 POINTS

MANAGING MSDS TEMPLATE

INDUSTRIAL CONDITION NOTES

UNDERSTANDING MSDS

NEED TO KNOW

2/22/16

INTRODUCTION


NEED TO KNOW


Material Safety Data Sheets

MSDS – what you need to know

about them


PreparaLon:

•  Before you go any further, it would be helpful to download: – Data sheet (click here) – to view the data sheet

you will need to be in slide show, press F5 – This product, used as an example, is a commercial

cleaning product containing some hazardous chemicals


What do MSDSs contain?

•  Identification of the product

•  Teepol Aluminium Cleaner –  - sales unit and stock code –  - address and contact details for the supplier



•  Composition/ information on ingredients. (Exact formulations & details of non-hazardous components not required – protects from rival manufacturers)

•  CAS & EINECS are identifications codes

•  Risk phrases (from CHIP data- see later)

•  Alcohol Ethoxylate <1% •  Phosphoric acid 15 – 30% •  Benzotriazole <1% •  Formaldehyde <1%



•  Hazards identified (i.e. those known about when the product is used in the way the manufacturer intends)

•  Irritating to eye and skin •  Large amounts could be hazardous to aquatic

environment



•  First aid measures –  Eyes - irrigate with water 10-15 minutes –  Skin – remove gloves and wash –  Ingestions – plenty of water to drink

•  (This is incorrect - should be small sips!!) –  Inhalation- remove to fresh air

•  Always check out first aid information with your Departmental First Aider or Safety Services



•  Fire fighting measures

•  The material is non-flammable •  If involved in a fire anyway, it may produce

hydrogen chloride (an acid gas)

•  Breathing apparatus is relevant to the Fire Service – not us!



•  Measures for spillage or accidental release •  Spillage – contain with sand or earth – Beware of slipping hazard – Do not allow to go down the drains (report any

significant leakage down the drains to the water authorities – take advice)

•  You will need to ensure that your department stocks appropriate materials to deal with these incidents.


What do MSDSs contain? •  Handling and storage

•  Store away from food •  Tightly closed containers •  Away from children •  At temperatures between 5oC & 30oC •  Shelf life 1 year

•  In this case, largely “common sense” information but for some products it could be more critical


What do MSDSs contain? •  Exposure controls &/or personal protective equipment

(PPE)

–  These are standard safety signs denoting the need to wear gloves, face shield and protective clothing.

–  NB It does not tell you what sort of gloves are appropriate. You would need to find this out by consulting a gloves manufacturer regarding the hazardous materials in the product – see the “Guidance” section of Safety Services website



•  Physical & Chemical Properties – Appearance – what it looks like – pH – acidity/alkalinity of the product – a pH of <1

denotes significant acidity – Flash point – it is not flammable – Density (>1 means it is more dense than water)


In terms of hazard, both high pHs (strong alkali) and low pHs (strong acid) are nasty. For substances with pHs around 7 acidity & alkalinity are not generally a problem.



•  Stability & reactivity •  No stability concerns – it won’t “go off” •  Avoid contact with strong oxidisers, chlorine &

chlorine products – nasty gases possible •  Contact with some alloys may produce hydrogen

– explosion potential because of low pH! (but not in normal use)


What do MSDSs contain? •  Toxicological information (what nasty things will it do to

you?)

•  Irritating to organic tissue (skin & eyes) •  Inhalation of aerosol may cause irritation •  Ingestion – irritation to mouth & digestive tract (it’s a

strong acid) •  Eye contact – may cause severe irritation (acid again!) •  Skin contact – irritation!

•  Connected with first aid information here, but in some circumstances, may give details of longer term medical problems, where appropriate



•  Ecological information •  How environmentally friendly is it? – Biodegrades – does not remain in soil etc – Don’t release into surface waters

eg detergents can cause unsightly rivers and may affect waterproofing of water birds



•  Disposal considerations – Use suitable PPE (see previous information) – Rinse out containers – Don’t allow to enter drains – Dispose of according to local regulations – Do not mix with other waste

•  This is not as formidable as it sounds – a bit of advice from Safety Services or Estates will help



•  Transport information – None

– Where substances need special consideration for transport, it will be detailed here – usually only applicable to larger quantities



•  Regulatory information –  Irritant to eyes and skin – Keep away from children – First aid information

– These are “risk phrases” associated with the CHIP regulations – simple advice phrases

– There may also be symbols – as here , indicating “irritant”.


Risk phrases - examples •  R1: Explosive when dry •  R2: Risk of explosion by shock, friction, fire or

other sources of ignition •  R3: Extreme risk of explosion by shock,

friction, fire or other sources of ignition •  R4: Forms very sensitive explosive metallic

compounds •  R5: Heating may cause an explosion •  R6: Explosive with or without contact with air •  R7: May cause fire •  R8: Contact with combustible material may

cause fire •  R9: Explosive when mixed with combustible

material •  R10: Flammable •  R11: Highly flammable •  R12: Extremely flammable •  R14: Reacts violently with water •  R15: Contact with water liberates extremely

flammable gases

�  R20: Harmful by inhalaLon �  R21: Harmful in contact with skin �  R22: Harmful if swallowed �  R23: Toxic by inhalaLon �  R24: Toxic in contact with skin �  R25: Toxic if swallowed �  R26: Very toxic by inhalaLon �  R27: Very toxic in contact with skin �  R28: Very toxic if swallowed �  R29: Contact with water liberates toxic gas. �  R30: Can become highly flammable in use �  R31: Contact with acids liberates toxic gas �  R32: Contact with acids liberates very toxic

gas �  Up to: -‐ �  R66: Repeated exposure may cause skin

dryness or cracking �  R67: Vapours may cause drowsiness and

dizziness �  R68: Possible risk of irreversible effects



•  Other information (variable)

•  In this case it tells you its immediate application and how to use it


REMEMBER

•  MSDS’s are NOT Risk Assessments! •  They make no distinction between a gram and a

tonne of a substance. •  When using substances you must carry out a risk

assessment but use the information in MDSD’s to help you.

•  Controls should be proportional to risk! •  Not all MSDS’s contain comprehensive.

information, although they should have! •  If in doubt, always consult an expert.


MSDS 16 POINTS


• ObjecLve •  to concisely inform you about the hazards of materials you work with so that you can protect yourself and respond to an emergency

•  acts as a “crystal ball” -‐ if you study it, you will see the future


• Purpose •  the material’s physical properLes or fast-‐acLng health effects that make it dangerous to handle

•  the level of protecLve gear you need •  the first aid treatment to be provided when you are exposed to a hazard

•  the preplanning needed for safely handling spills, fires, and day-‐to-‐day operaLons

•  how to respond to accidents


• A Material is Considered Hazardous If-‐-‐

•  specifically listed in the law, 29CFR Part 1910, Subpart Z, Toxic and Hazardous Substances (the Z list)

•  assigned a Threshold Limit Value (TLV) by the American Conference of Governmental Industrial Hygienists, Inc (ACGIH)


•  determined to be cancer causing, corrosive, toxic, an irritant, a sensiLzer, or has damaging effects on specific body organs


• The MSDS Format

•  must be in English •  have a heading •  cover 16 different informaLonal categories


• Heading

•  name and address of the manufacturer

•  telephone numbers –  transportaLon emergency number

–  nontransportaLon informaLon and emergency numbers


• Categories of InformaLon 1. Chemical ProducLon InformaLon

–  product name –  product code –  chemical family –  chemical name –  synonyms –  formula


Chemical Product InformaLon


Categories 2. ComposiLon/InformaLon on Ingredients

–  ingredient name –  CAS number –  exposure limits –  concentraLon (%) –  names of hazardous ingredients


ComposiLon/InformaLon on Ingredients


Categories

3. Hazards IdenLficaLon – emergency overview,i.e.,Danger! Toxic – potenLal health effects –  routes of entry – human effects & symptoms of overexposure – acute effects of overexposure – chronic effects of overexposure – carcinogenicity – medical condiLons aggravated by exposure


2/22/16 45

Hazards IdenLficaLon


Categories 4. First Aid Measures

–  first aid for eyes –  first aid for skin –  first aid for inhalaLon –  first aid for ingesLon –  note to physician


First Aid Measures


Categories 5. Fire FighLng Measures

–  flash point –  flammable limits

•  upper explosive limit (UEL)(%) •  lower explosive limit (LEL)(%)

–  exLnguishing media –  special fire fighLng procedures


Fire FighLng Measures


Categories

6. Accidental Release Measures –  spill or leak procedures


Categories 7. Handling and Storage

–  storage temperature (min/max) –  shelf life –  special sensiLvity –  handling/storage precauLons


Handling and Storage


Categories 8. Personal ProtecLon –  eye protecLon requirements –  skin protecLon requirements –  venLlaLon requirements –  respirator requirements –  medical surveillance –  addiLonal protecLve measures

2/22/16 55

PPE


Categories 9. Physical and Chemical ProperLes

–  physical form –  color –  odor –  odor threshold –  molecular weight –  boiling point –  melLng/freezing point –  solubility in water –  specific gravity –  bulk density –  % volaLle by volume –  vapor pressure –  vapor density


Physical and Chemical ProperLes


Categories

10. Stability and ReacLvity – stability – hazardous polymerizaLon –  incompaLbiliLes –  instability condiLons – decomposiLon products


2/22/16 63

Stability and ReacLvity


Categories 11. Toxicological InformaLon

–  Acute Toxicity •  oral LD50 •  dermal LD50 •  inhalaLon LC50 •  eye effects •  skin effects •  sensiLzaLon

–  Subchronic Toxicity –  Chronic Toxicity –  Carcinogenicity –  Mutagenicity –  Developmental Toxicity –  ReproducLon –  Neurotoxicity


Toxicological InformaLon


Categories

12. Ecological InformaLon


13. Disposal InformaLon


Categories

14. TransportaLon InformaLon –  technical shipping name –  freight class package – product label – DOT (DomesLc Surface) •  proper shipping name •  UN/UA number •  packing group •  DOT product RQ lbs. (kgs) •  hazard label(s)


•  hazard placard(s)

–  IMO / IMDG Code (Ocean) •  proper shipping name •  hazard class division number •  UN number •  packing group •  hazard(s) •  hazard placard(s)

–  ICAO / IATA (Air) •  proper shipping name


•  hazard class division number •  UN number •  subsidiary risk •  packing group •  hazard label(s) •  radioacLvity •  passenger air -‐ max. qty •  passenger packing instrucLons •  cargo air -‐ max. qty •  cargo passenger packing instrucLons


Categories

15. Regulatory InformaLon – OSHA status – TSCA status – CERLA Reportable QuanLty •  SARA Title III

–  SecLon 302 Extremely Hazardous Substances –  SecLon 311/312 Hazard Categories –  SecLon313

– RCRA Status


Regulatory InformaLon


Categories

16. Other InformaLon – NFPA 704M RaLngs – Reason for Issue – Prepared by: – Approved by: – Title: – Approval Date: – Supersedes Date – MSDA number


Other InformaLon


Disclaimers

•  no warranLes, expressed or implied


MSDS

•  is an OSHA document •  not an EPA document •  not part of the labeling unless received at the Lme of purchase


UNDERSTANDING MSDS


MANAGING MSDS


TEMPLATE


INDUSTRIAL CONDITION


MSDS

LEVEL HIGH

MEDIUM LOW

NEGLECTED


RISK

LEVEL HIGH

MEDIUM

REMARKS

HIGH

HIGH

OCCURANCE

LOW

117

NEGLECTED

BILAL MASOOD

HIGH

HIGH NEGLECTED

HIGH HIGH

NEGLECTED HIGH HIGH

ACTION

HIGH NEGLECTED

HIGH HIGH

2/22/16

NOTES


INDUSTRIAL HAZARD STUDY--MSDS--VOL-1,EDITION-1

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