INDRASHIL UNIVERSITYindrashiluniversity.edu.in/brochures/pdf/M.Sc_Chemistry_syllabus.pdf ·...

INDRASHILUNIVERSITY(EstablishedbyanActundertheGujaratPrivateUniversitiesAct,2009)

ALifeSciencesUniversitySustainedExcellencewithRelevance

1

INDRASHIL UNIVERSITY

DEPARTMENT OF CHEMISTRY (CHE)

PROGRAM STRUCTURE

M. Sc. (Chemistry) 2019-2021



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SEMESTER- I

Subjectcode SubjectName L-T-P Credits

CH4 101 MathematicsforChemists 3-0-0 3

CH4 102 PrinciplesofOrganicChemistry 3-0-0 3

CH4 103InorganicChemistry:Principles,Structureand

Reactivity 3-0-0 3

CH4 104 StatisticalThermodynamicsandKinetics 3-0-0 3

CH4 105 StructuresandFunctionofBiomolecules 3-0-0 3

CH4 106 AdvancedOrganicChemistryLaboratory 0-0-6 3

CH4 107 AdvancedInorganicChemistryLaboratory 0-0-6 3

Total 15L-12P 21

SEMESTER-II


CH4201 AdvancedOrganicChemistryI 3-0-0 3

CH4202 AdvancedInorganicChemistryI 3-0-0 3

CH4203 AdvancedPhysicalChemistry I 3-0-0 3

CH4204 BioinorganicandBioorganicChemistry 3-0-0 3

CH4205 ApplicationsofSpectroscopy I 3-0-0 3

CH4206 SpectroscopicandAnalyticalTechniques 3-0-0 3

CH4207 AdvancedPhysicalChemistryLab 0-0-6 3

CH4208 BiochemicalTechniquesLaboratory 0-0-6 3

IUM 000 BasicCommunicationandSoft Skills 1-0-0 0

Total 19L-12P 24



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SEMESTER-III


CH5101 AdvancedOrganicChemistryII 3-1-0 4

CH5102 AdvancedInorganicChemistryII 3-0-0 3

CH5103 AdvancedPhysicalChemistryII 3-0-0 3

CH5104 ApplicationsOfSpectroscopyII 3-1-0 4

CH5105 AnalyticalTechniquesLab 0-0-6 3

CH5106 OrganicAndMedicinalChemistryLab 0-0-6 3

ElectiveI 2-0-0 2

ElectiveII 2-0-0 2

Total 16L-2T-12P 24

SEMESTER-IV


CH5201 ResearchorIndustrialProject/Viva 0-0-20 10

CH5202StudentSeminar(BasedonRecentResearch

Articles)0-0-2 2

ElectiveIII 2-0-0 2

ElectiveIV 2-0-0 2

TOTAL 4L-22P 16

CredittoHourscalculation:Lecture:1h=1CPracticals:2h=1CTotalcredits: 85

https://erp.iitkgp.ernet.in/ERPWebServices/curricula/CurriculaElectiveList.jsp?stuType=UG&splCode=CY4&semno=3

https://erp.iitkgp.ernet.in/ERPWebServices/curricula/CurriculaElectiveList.jsp?stuType=UG&splCode=CY4&semno=3



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LISTOFELECTIVES

SEMESTERIII

ListofAvailableSubjectsforElectives I,II


CH5 107 ChemistryofNaturalProducts 2-0-0 2

CH5 108 MedicinalChemistry 2-0-0 2

CH5 109 SupramolecularChemistry 2-0-0 2

CH5 110 Chemistry ofMaterials 2-0-0 2

SEMESTERIV

ListofAvailableSubjectsforElectives III,IV


CH5 203 PharmaceuticalAnalysis 2-0-0 2

CH5 204 ChemistryofNanomaterials 2-0-0 2

CH5 205 AdvancedHeterocyclicChemistry 2-0-0 2

CH5 206 EnvironmentalandGreenChemistry 2-0-0 2



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SEMESTER - I

CH4101 MathematicsforChemists (L-T-P-C:3-0-0-3)

Unit 1:DifferentialCalculusFunctionsof severalvariables, continuity anddifferentiability, rulesofdifferentiation,applicationsofdifferentialcalculusincludingmaximaandminima,exactandnon-exactdifferentials,Applicationofintegralcalculus,Coordinatestransformation(e.g.Cartesiantosphericalpolar,cylindrical)Unit 2:VectorsandMatrixAlgebraGradient, divergence and Vector calculus, Green’s theorem, Matrix equations:homogeneous, non-homogeneous linear equations and conditions for the solution,Lineardependenceandindependence,Eigenvalues,EigenvectorsUnit 3:OrdinaryDifferentialEquationsVariablesseparationmethod,Homogeneouslineardifferentialequation,andexactfirstorder differential equations, solutions of differential equations by the power seriesmethod, second and higher order homogeneous differential equations and theirsolutions, Complementary function, Particular integral by variation of parameter andmethod of undetermined coefficient, ODE with variable coefficient: Cauchy-Eulerequation,Legendre’sequation

Text Books:1.BhupendraSingh,“MathematicsforChemist”,15thedition,PragatiPrakashan,2015.

ReferenceBooks:1.PeterTebbutt,“BasicMathematicsforChemists”,2nd edition,Wiley,1998.2. GeorgeTurrell,“MathematicsforChemistryandPhysics”,AcademicPress,2002.



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CH4102PrinciplesofOrganicChemistry(L-T-P-C:3-0-0-3)

Unit 1:StructureandReactivityChemicalbonding,delocalization,resonance,hyderconjugation,tautomerism,inductiveeffect,bondsotherthancovalentlikeionic,hydrogenbonds.Types of reactions, mechanisms, thermodynamic and kinetic requirements, Hammettequation, Hammond’s postulate, Curtin-Hammett principle, Potential energy diagram,transition state & intermediate, methods of determining mechanism, isotope effects,solventeffects,substituenteffects,Hardandsoftacidsandbases,Fateofstructureonreactivity,resonanceandfieldeffects,stericeffects,quantitativetreatment.Generation,structure,stabilityandreactivityoforganicreactiveintermediates,suchascarocations,carbanions,freeradicals,carbenesandnitrenes.Retrosynthesis: Introduction, synthons and synthetic equivalents, functional groupinter-conversion,Synthesisofamines,region-specific,chemo-specificandstereospecificreactions, umpolung methods. Principles and applications of protective groups inprotection of hydroxyl, amino, carbonyl and carboxyl groups, synthetic strategies forcycliccompounds.Unit2: OrganicReactionMechanismAliphatic nucleophilic substitution, SN1, SN2, SNi and mixed mechanism, theneighbouring group participation, anchimeric assistance. Classical andnonclassicalcarbocations, and detection by NMR spectroscopy. Reactivity effects ofsubstrate structure, attachingnucleophile, leaving group and reactionmedium, phasetransfer catalysis, ambidentnucleophilicity. Nucleophilic substitution at an allylic,aliphatictrigonalandvinyliccarbon.Aromaticnucleophilicsubstitutionreactions,SNAr,SN1,benzyneandSRN1mechanisms,Reactivity– effectofsubstratestructure,leavinggroupandattackingnucleophile.Aromaticelectrophilicsubstitutionreactions,areniumionmechanism,orientationandreactivity,energyprofilediagram,theortho/pararatio,ipsoattack,orientationinotherringsystems,andreactionsthereof.Unit 3: StereoChemistryStereochemistry:Basic principles,elementsofsymmetry,chirality,moleculeswithmorethanonechiralcentre,enantiomers,diastereomers,threoanderythroisomers,groupsand faces, absolute configurations at carbon (R, S, E and Z). Stereospecific andstereoselectivereactions. Prochiralrelationship,opticalactivity inbiphenyls,spiranes,allenesandhelicalstructures.Stereochemistry of compounds containing Nitrogen, Sulphur andPhosphorous.Conformationandreactivityinacycliccompounds.

Reference Books:1. Stereochemistryofcarboncompounds- E.L.Eliel2. Stereochemistryoforganiccompounds– D.Nasipuri3. Stereochemistry:conformationandmechanism– P.S.Kalsi4. Reactionmechanisms– JerryMarch5. Aguidebooktoreactionmechanismsinorganicchemistry– PeterSykes6. Mechanismandstructureinorganicchemistry- S.M. Mukherji & S.P.Singh7. OrganicChemistry- L.G.WadeJr



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8. AdvancedOrganicChemistry,PartA:StructureandMechanisms- FrancisA.CareyandRichardJ.Sundberg

9. AdvancedOrganicChemistry:PartB:ReactionandSynthesis- FrancisA.CareyandRichardJ.Sundberg

10. OrganicChemistry- Greeves,Warren,andWothers Clayden.



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CH4103InorganicChemistry:Principles,StructureandReactivity (L-T-P-C:3-0-0-3)

Unit1: PrinciplesofInorganicChemistryVSEPR theory - Coordination polyhedra - Enumeration of geometrical and opticalisomersTheory of Acids and Bases: Bronsted and lewis acids and bases, gas phase versussolutionacidity- solvent levellingeffects,Hardnessandsoftness- Surfaceacidity.OxidationandReduction: Useof redoxpotentialdata - Nernstequation - Influenceofcomplexformation,precipitation,changeofpHandconcentrationonredoxpotentials-Analysis of redox cycles - Redox stability in water -Disproportionation/Comproportionation- Frost,LatimerandPourbaixdiagramsUnit2: StructureSymmetry and Group Theory: Definitions and theorems of group theory, subgroups,Classes Molecular symmetry and symmetry groups – symmetry elements andoperations. Symmetry planes, reflections, inversion centre, proper/ improper axes ofrotation,productsofsymmetryoperations, equivalentsymmetryelementsandatoms,symmetryelementsandopticalisomerism,symmetrypointgroups,classesofsymmetryoperations, classification ofmolecular point groups. Representations of groups. Greatorthogonality theorem, character tables, properties of characters of representations.(Nomathematicalpart.)Grouptheoryandquantummechanics,wavefunctionasbasisforirreduciblerepresentations.Unit3: ReactivityInorganicReactionMechanisms: Substitutionreactions- Dissociativeandassociativeinterchange- trans-effect- Linearfreeenergyrelations- Rearrangements- Berrypseudorotation- Electrontransferreactions- Photo-dissociation,-substitutionand-redoxreactions,Fluxionalmolecules.

ReferenceBooks:1. P. Atkins, T. Overton, J. Rourke, M. Weller, F. Armstrong: Shriver and Atkins'

Inorganic Chemistry, Fifth Ed., 2009, OUP or D. F. Shriver and P. W. Atkins,‘’InorganicChemistry’’,3rdEd,OUP,1999.

2. C. Housecroft, A. G. Sharpe, ‘’Inorganic Chemistry’’, 3rd Ed., (or 4th Ed. in 2012)PrenticeHall/Pearson,2008.

3. F.A.Cotton,G.Wilkinson,AdvancedInorganicChemistry,5thEd.,JohnWiley,1988(orF.A.Cotton,C.A.Murillo,M.BochmannandR.N.Grimes,‘’AdvancedInorganicChemistry’’,6thEd. Wiley,1999).

4. J.E.Huheey,E.A.Keiter,R.L.Keiter, ‘’InorganicChemistry:PrinciplesofStructureandReactivity’’,4thEd.,PrenticeHall,1997.

5. G.L.Miessler,D.A.Tarr,‘’InorganicChemistry’’,3rdEd. PearsonEducation,2004.6. G.Wulfsberg,‘’InorganicChemistry’’,UniversityScienceBooks,2000.



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CH4104StatisticalThermodynamicsandKinetics (L-T-P-C:3-0-0-3)

Unit 1:StatisticalThermodynamicsLimitations of classical thermodynamics. Introduction to the terms like ensemble,population, equipartition of energy, degeneracy. Boltzmann's distribution law,Evaluationofβ, partitionfunction, Distinguishableandindistinguishableparticles,molar partition function, Electronic, Translational, Rotational and Vibrationalpartitionfunctions.Sackur-Tetrodeequation.DerivationofFermi-DiracstatisticsandBose-Einsteinstatisticsdistributionlawandtheirapplication. Applicationsofstatisticalthermodynamics- Heat capacity behaviour of solid and calculation of equilibriumconstant.Unit 2:ChemicalKineticsComplex Reactions: Reactions approaching equilibrium, steady state approximation,Rate laws for consecutive, opposing andparallel reactions, explosive reactions. Chainreactions(formationanddecompositionofHBr,HI,phosgene,thermaldecompositionofN2O5 and C2H10, oxidation ofmethane). Comparison between gas phase and solutionreactions, factors determining rates in solution. Reaction between ions, reactionsinvolvingdipoles,reactionsinsolution.Fastreactions:Relaxation,stopflowandflashphotolysis.Kineticsofenzymereactions,Harpoonmechanism(MolecularBeammethod).Activated complex theory: Reaction coordinate and the transition state, potentialenergy surface, concentration of activated complex and rate constant, experimentalobservationof activatedcomplex.Theoriesofuni-molecularreactions:Lindemann,Hinshelwood,RRKandRRKM

SuggestedBooks:1. StatisticalThermodynamics,M.C.Gupta,NewAgeInt.Ed.(1998)2. AnIntroductiontoStatisticalThermodynamics,T.L.Hill,DoverPublication(1986)3. FundamentalofClassicalandStatisticalthermodynamics,B.N.Roy,Wiley(2002)4. ChemicalKinetics,K.J. Laidler,(3rd Ed.),PearsonEducation,Noida(1987).5. Molecular reaction Dynamics, R.D. Levine, , Cambridge University Press, NY.

(PaperbackEdition)(2009)6. Kinetics and Mechanism of Chemical Transformations, J. Raja Ram and J.C.

Kuriacose,MacMillanIndianLtd.(1993).



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CH4105StructuresandFunctionofBiomolecules (L-T-P-C:3-0-0-3)

Unit 1:Amino-acids,PeptidesandProteinsClassification, structure and properties of amino acids and proteins, Synthesis ofprotein:reactiveestermethodandMerrifieldsynthesis.Primary and Secondary structure of proteins, forces responsible for holding ofsecondary structures. α-helix, β-sheets, superb secondary structures, triple helixstructureofcollagen.Tertiary structure of protein-folding and domain structure, Quaternary structure.Sequence determination; chemical/enzymatic/mass spectral, racemization/detection.Chemistryofoxytosin andtryptophanreleasinghormone(TRH).Unit2:LipidsClassification,Fattyacids,essentialfattyacids,structureandfunctionoftriacylglycerols,glycerol phospholipids, sphingo lipids, cholesterol, bile acids, prostaglandinseicosanoids,leukotriene.Lipoproteins-compositionandfunction,roleinatherosclerosis.Propertiesoflipidaggregates-micelles,bilayers,liposomesandtheirpossiblebiologicalfunction.Biologicalmembranes.Fluidmosaicmodelofmembranestructure.Unit3:CarbohydratesClassification,Conformationofmonosaccharides,structuresandfunctionsofimportantderivatives of monosaccharides like glycosides, deoxy sugars, myoinositol, aminosugars. N-acetylmuramicacidsialicacid,disaccharidesandpolysaccharides. Structuralpolysaccharides-celluloseandchitin.Storage polysaccharides-starch and glycogen. Structure and biological function ofglucosaminoglycansor mucopolysaccharides.Carbohydratesofglycoproteinsandglycolipids. Roleofsugarsinbiologicalrecognition,bloodgroupsubstances.Unit 4:NucleicAcidsPurineandpyrimidinebasesofnucleicacids,basepairingviaH-bonding.Structureofribonucleicacids(RNA)anddeoxyribonucleicacids(DNA),doublehelixmodelofDNAandforcesresponsibleforholdingit.Chemicalandenzymatichydrolysisofnucleicacids.Chemicalsynthesisofmonoandtrinucleoside.The chemical basis for heredity, an overview of replication of DNA, transcription,translationandgeneticcode.

TextBooks:1. Satyanarayana U, ChakrapaniU.,2014, Essentials of Biochemistry, Elsevier Health

Sciences.2. Robert K. Murray, Victor W. Rodwell, David Bender, Kathleen M. Botham, P.

Anthony Weil, Peter J. Kennelly, 2009,Harper's Illustrated Biochemistry, 28thEdition,McGrawHillProfessional.

ReferenceBooks:1. AlbertL.Lehninger,DavidL.Nelson,MichaelM.Cox,2005,Lehninger, Principlesof

BiochemistryW.H.Freeman, UniversityMichaelMCox.

https://www.google.co.in/search?tbo=p&tbm=bks&q=inauthor:%22Robert+K.+Murray%22

https://www.google.co.in/search?tbo=p&tbm=bks&q=inauthor:%22Victor+W.+Rodwell%22

https://www.google.co.in/search?tbo=p&tbm=bks&q=inauthor:%22David+Bender%22

https://www.google.co.in/search?tbo=p&tbm=bks&q=inauthor:%22Kathleen+M.+Botham%22

https://www.google.co.in/search?tbo=p&tbm=bks&q=inauthor:%22P.+Anthony+Weil%22

https://www.google.co.in/search?tbo=p&tbm=bks&q=inauthor:%22P.+Anthony+Weil%22

https://www.google.co.in/search?tbo=p&tbm=bks&q=inauthor:%22Peter+J.+Kennelly%22

https://www.google.co.in/search?tbo=p&tbm=bks&q=inauthor:%22Albert+L.+Lehninger%22

https://www.google.co.in/search?tbo=p&tbm=bks&q=inauthor:%22David+L.+Nelson%22

https://www.google.co.in/search?tbo=p&tbm=bks&q=inauthor:%22Michael+M.+Cox%22

https://www.google.co.in/search?tbo=p&tbm=bks&q=inauthor:%22University+Michael+M+Cox%22



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2. DonaldVoet,JudithG.Voet, 2011,Biochemistry,4thEd. Hoboken,NJ:JohnWiley&Sons.

3. Berg JM, Tymoczko JL, Stryer L., 2010, Biochemistry, 7th Ed. W.H. Freeman andCompany.

4. JamesD.Watson,AndrewBerry,2003,DNA:TheSecretLife,AlfredAKnopf.5. KeithWilson, JohnWalker,2010,PrinciplesandTechniquesofBiochemistryand

MolecularBiology,CambridgeUniversityPress.

https://archive.org/search.php?query=subject%3A%22Biochemistry+by+Berg+JM%22

https://archive.org/search.php?query=subject%3A%22Tymoczko+JL%22

https://archive.org/search.php?query=subject%3A%22and+Stryer+L%22

https://archive.org/search.php?query=subject%3A%22published+by+W.H.+Freeman+and+Company%22

https://archive.org/search.php?query=subject%3A%22published+by+W.H.+Freeman+and+Company%22



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CH4106AdvancedOrganicChemistryLaboratory(L-T-P-C:0-0-6-3)

Unit 1:QualitativeAnalysisSeparation, Purification, drying of organic solvents and identification of threecomponentsmixtureofThreeorganiccompounds(threesolidsor two liquidsandonesolidortwosolidsandoneliquid)usingTLCforcheckingpurity,Separatingtechniques,IntroductionofIR,PMRandMassSpectraldata.Unit 2:PurificationTechniquesTLC,Rfvalues,ColumnChromatography,Distillation,VacuumDistillation,SteamDistillation.Unit 3:MultistepOrganicSynthesis1. Preparationofm-dinitrobenzene.2. PreparationofTribromoaniline.3. PreparationofBenzanilide4. Methylorangepreparation.5. Preparationof 2,4-dihydroxyacetophenone.6. PreparationofDibezalacetone

SuggestedBooks:1. Vogel'stextbookofpracticalorganicchemistry– ArthurIsraelVogel,B.S.Furniss2. Practical Organic Chemistry - Frederick George Mann and Bernard Charles

Saunders3. AdvancedPracticalOrganicChemistry- NKVishnoi4. LaboratoryManualofOrganicChemistry- R.K.Bansal



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CH4107AdvancedInorganicChemistryLaboratory (L-T-P-C:0-0-6-3)

Unit 1:QuantitativeAnalysisStatistical analysis of data sampling methods. Redox titrations (permanganometry,dichromatometry, iodometry). Complexometric titrations using EDTA (estimation ofsomemetalions,hardnessofwater).Quantitativeseparationofmetalionsfromabinarymixture(e.g.Cu2+/Fe3+). Gravimetricanalysis(e.g.estimationofNi2+).Analysisoforesandminerals(e.g.Ironore,Potassiumalum).Ionexchangeseparationofmetalions(e.g.Zn2+/Mg2+).Unit2:SynthesisSynthesisofavarietyofInorganicCompounds/Complexesof3dmetalions,maingroupelementsandrareearthsbyusingcommonexperimentaltechniques.Unit3:InstrumentalMethodsIntroductiontovariousphysicalmeasurements(IR,UV-vis,mass,NMR,magneticsusceptibility,EPRandX-raydiffraction)forcharacterizationofthecompounds.Analysisandinterpretationofthephysicaldataofthecompoundstodeterminetheirstructures.

SuggestedBooks:1. Vogel’sTextbookofQuantitativeChemicalAnalysis,5thEdn,OrientLongman,1989.2. Vogel’sTextbookofMacroandSemimicroQualitativeInorganicAnalysis,5thEd.,

OrientLongman,1982.



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SEMESTERII

CH4 201AdvancedOrganicChemistryI (L-T-P-C:3-0-0-3)

Unit 1: OrganicReactionMechanismReactions of multiple bonds, mechanistic and stereochemical aspects of additionreactions involving electrophiles, nucleophiles and free radicals. Regio- andchemoselectivity. Addition to carbon-heteroatom multiple bonds. Addition oforganometallic reagents containing lithium, magnesium, copper, zinc, mercury andcadmium. Ylides and Wittig reaction, mechanism of alkylation and condensationreactionsinvolvingenolates.Eliminationreactions.E2,E1 andE1cB mechanism,orientationofthedoublebond.Oxidationreactions,applicationusingCr,Mn,Ce,Pb,Pd,Pt,Osbasedreagents,m-CPBA,O3, NaIO4, etc. Reduction reactions involving hydrogen and metal catalysts, anddissolvingmetals, R3SnH,Wilkinson catalyst, borane and reagents thereof, LiAlH4 andDibal-H.Unit 2: ReactionsandRearrangementReactionsMolecular Rearrangements. Mechanism of molecular rearrangements involvingnucleophilic, electrophilic and free radical. Carbon-carbon rearrangements: Wagner–Meerwein, Tiffeneau–Demyanov, Favorskii, Wolff, Benzil–Benzilic acid, Neber,Benzidine rearrangements, Carbon–nitrogen rearrangements: Hoffmann, Curtius,Lossen Schmidt and Beckmann rearrangements. Carbon–oxygen rearrangements:Bayer–Villiger, Dakin and Wittig rearrangements. Fries, Claisen, Cope reactions.ReactionsinvolvingP,NandSYlides.Unit 3: IntroductiontoHeterocyclicchemistryHeterocyclic chemistry: Nomenclature, Hantzsch-Widman rules for fused and bridgering systems. Heterocycles containing 3, 4, 5, 6-member rings and their reactivity,synthesisandapplicationsindrugmolecules.Fusedheterocycles.

SuggestedBooks:1. Guidebooktoorganicsynthesis- R.K.Meckie,D.M.Smith,R.A.Atken2. Organicsynthesis-O.House3. Organicsynthesis- M.B.Smith4. Advancedorganicchemistry.PartAStructure&Mechanism-FrancisA.5. Coreyan.RichardJ.SundbergHeterocyclesbyR.K.Bansal6. Anintroductiontochemistryofheterocycliccompounds– R.M.Acheson7. Heterocyclicchemistry– JohnA.JouleandKeithMills8. HeterocyclicChemistry- Thomas.L.Gilchrist



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CH4202AdvancedInorganicChemistryI (L-T-P-C:3-0-0-3)

Unit1:MainGroupChemistryPerspectives, periodicity & periodic anomalies - Relativistic effects on chemicalproperties.Hydrogenanditscompounds:H-bondanditsinfluenceonthestructureandpropertiesof crystals Hydrides→classification: electron deficient, electron precise and electronrichhydrides.Alkali and alkaline earthmetals: Solutions in liquid ammonia - Synthesis, properties,uses and structures of crown ether complexes, cryptands and organometalliccompounds.Group 13 elements: Borides, borates, boron halides, boranes, carboranes andmetallocarboranes, BN compounds, transition-metal stabilized borylene andboryllithium, organoaluminum compounds, Lewis Base adducts of AlR3 compounds,Subvalentorgano-Alcompounds,Organo-gallium,-indium,and–thalliumcompounds.Group14elements:AllotropesofCarbon- C60anditscompounds(fullerenes)- carbonnanotubes: synthesis and properties -Intercalation compounds of graphite - PureSilicon, silica and silicates, Silicones - Low coordinated and hypervalent Siliconcompounds - BriefsurveyofGe,Sn, andPbchemistry- Organo-germanium, -tin,and -leadcompounds.Group 15 elements: P(V) compounds (structure, bonding, reactivity) - P(III)compounds: diphosphenes, phosphaalkenes, iminophosphanes - P-containing ringsystems(phosphabenzene,phosphole),phosphazenes,P-Scompounds.Group16elements:Sulfur polycationic andanionicspecies- SNcompounds.Unit 2:HalogensandNobelGasesGroup17elements:Charge-transfercomplexesofhalogens, inter-halogencompounds,halogenoxidesandoxygenfluorides,pseudohalogens.Group18elements:Noblegasclathratesandcompounds.Unit 3:InnerTransitionElementsInner transition elements: Chemistry of f-block elements - Binary compounds –Organometallic compounds - Relation to p-block and d-block chemistry –Tran’sactinides(super-heavyelements).

SuggestedBooks:1. AG.Massey,“Maingroupchemistry”,Wiley,2000.2. N.N.GreenwoodandA.Earnshaw,“ChemistryoftheElements”,PergamonPress,

1989.3. P.Atkins,T.Overton,J.Rourke,M.Weller,F.Armstrong:ShriverandAtkins'

InorganicChemistry,FifthEdition,2009,OUPorD.F.ShriverandP.W.Atkins,‘’InorganicChemistry’’,3rdEd.,OUP,1999.

4. C.Housecroft,A.G.Sharpe,‘’InorganicChemistry’’,3rdEd. (or4thEd. in2012)PrenticeHall/Pearson,2008.

5. F.A.Cotton,G.Wilkinson,AdvancedInorganicChemistry,5thEd.,JohnWiley,19886. A.Cotton,C.A.Murillo,M.BochmannandR.N.Grimes,‘’AdvancedInorganic

Chemistry’’,6thEdnWiley,1999).7. J.E.Huheey,E.A.Keiter,R.L.Keiter,‘’InorganicChemistry:PrinciplesofStructure

andReactivity’’,4thEd.,PrenticeHall,1997.



16

CH4203AdvancedPhysicalChemistryI(L-T-P-C:3-0-0-3)

Unit1:SurfaceSciencesAdsorption– surfacetension,capillaryactionpressuredifferenceacrosscurvedsurface(Laplace equation), vapour pressure of droplets (Kelvin equation), Gibbs adsorptionisotherm,estimationofsurfacearea (BETequation), surface filmson liquids (Electro-kineticphenomenon),Catalyticactivityatsurfaces.Micelles- Surface active agents, classification of surface active agents, micellization,hydrophobic interaction, critical micellar concentration (CMC), factors affecting theCMCof surfactants, counter ionbinding tomicelles, thermodynamicsofmicellization-phaseseparation,solubilisation,microemulsion,reversemicellesUnit 2:ElectrochemistryElectrochemistryofsolutions.Debye-Hückel-Onsagertreatmentanditsextension, ion-solvent interactions, Debye-Hückel-Jerummodel. Thermodynamics of electrifiedinterface equations, derivation of electro-capillarity, Lippmann equations (surfaceexcess),methodsofdetermination. Structureofelectrifiedinterfaces- Guoy-Chappman,Stern,Graham-Devanathan-Mottwattsmodels.Polarographytheory- Ilkovicequation,half-wavepotentialanditssignificance.Introduction to corrosion, homogeneous theory, forms of corrosion monitoring andpreventionmethods.

SuggestedBooks:1. Non-ionic surfactants,M.J.Schick,SurfactantScienceSeries,(1985)2. ColloidsandInterfaceScience,P.Ghosh,PHIlearningPvt.Ltd.NewDelhi(2009).3. SurfactantsandInterfacialPhenomena,M.J.Rosen,JohnWiley,NewJersey(2004).4. Handbookofsurfactants,M.R.Porter,ChapmanandHall,London(1994).5. PhysicalChemistryofSurface,A.W.Adamson,JohnWiley(1997).6. TextbookofPolymerChemistry,F.W.BillmeyerJr.,JohnWiley(1994)7. IntroductiontoPolymerChemistry,R.B.Seymour,McGrawHill(1971)8. PhysicalchemistryofPolymer,ATager,MirPub(1978)9. PolymerScience,V.R. Gowarikar,N.V.Viswanathan &J.Sreedhar,NewAgeInt.Ed.

(1986)10. PolymericMulticomponentMaterials,L.H.Sperling,JohnWiley(1997)11. PhysicalChemistryofElectrolyticSolution,H.S. Harned&B.B.Owen,Reinhold

(1950)



17

CH4204BioinorganicandBioorganicChemistry(L-T-P-C:3-0-0-3)

Unit 1: BioInorganicChemistryEssential and tracemetals, Na+/ K+ pump, Role ofmetal ions in biological processes,DNA Polymerization, Glucose Storage, metal complexes in transmission of energyChlorophylls,PhotosystemIandPhotosystemIIincleavageofwater.Model systems, Heme proteins and Oxygen uptake, spectrum and function ofhemoglobin,myoglobin,hemocyanins,andhemeerythrin,modelsyntheticcomplexesofIron,CobaltandCopper.Structure and functionofmetalloproteins in electron transport process cytochromesand ionsulphurproteins. Syntheticmodels,BiologicalnitrogenFixation,Molybdenumnitrogenase,Spectroscopicandotherevidences.Unit 2: BioOrganicChemistryBasic considerations, Proximity effects and molecular adaptation, Introduction andhistorical perspective, chemical and biological analysis, remarkable properties ofenzymes like catalytic power, specificity and regulation. Nomenclature andclassification, extraction and purification, Fisher’s Lock and key theory, induced fittheory.Hypothesis,Conceptandidentificationofactivessiteusinginhibitors,affinity labellingand enzyme modification by site directed mutagenesis. Enzyme kinetics, Michaelis-Mentenandlineweaver,Burkplots,reversibleandirreversibleinhibition.

SuggestedBooks:1. Principlesof BiochemistryA.L.Lehninger,Worthpublishers.2. BiochemistrybyL.Stryer,W.H.Freeman.3. BiochemistrybyVoetandVoet,Wiley.4. BiochemistrybyJ.DavidandRawn,NeilPatterson.5. OutlinesofBiochemistry,E.E.ConnandP.K.Stumpf,JohnWiley.6. UnderstandingEnzymesbyTrevorpalmer,PrenticeHall.7. Enzyme chemistry: Impact and applicationsEd. Collins, J. Suckling, Chapman and

Hall.8. EnzymemechanismsEd.,M.I.PageandA.Williams,RSC.9. FundamentalsofEnzymologyN.C.PriceandL.Stevens,Oxford.10. ImmobilizedEnzymes:AnIntroduction andApplicationsinBiotechnology,Michael

D.



18

CH4205Applications ofSpectroscopy I (L-T-P-C:3-0-0-3)

Unit1: Vibrational,UVandIRSpectroscopyVibrational Spectroscopy Rotational and vibrational spectra. Moment of inertia androtational spectra of rigid and non rigid diatomic molecules. Vibrational excitationeffect.Rotationalspectraofsymmetric - topmolecules. Strakeffect. Vibrationalenergyof diatomic molecules.Anharmonic oscillator, overtones and hot bands. Diatomicvibrator rotator (P, Q and R branches of diatomic vibrator rotator). Rotationalvibrationalspectraofsymmetrictopmolecules.UVSpectroscopyOriginofelectronicspectra,Lambert-Beer’sabsorptionlaw,Typesofelectronic transitions. Effect of solvent, substituent, conjugation on electronictransitions.Benzene and its substituted derivatives. Applications of UV visiblespectroscopy in analysis (qualitative/quantitative) of polyenes/aromatic (hetero &homo) systems, geometrical isomers, keto-enoltautomers, components of a mixture,ionization constants of acids and bases. Woodward-Fieser rules for calculatingabsorptionmaximumindienes,trienesandα,β-unsaturatedcarbonylcompounds.R Spectroscopy Vibrational energy of a diatomic molecule-and harmonic oscillator,Selection rules- Overtones-hotbands.Zero-pointenergy-Calculationof force.Constantof diatomic molecules. Rotational –Vibrational spectra of diatomic molecules- P,Q,Rbranches. Instrumentation sources sampling techniques. Characteristic vibrationalfrequencies of alkanes, alkenes, alkynes, aromaticcompounds,alcohols, ethers, phenolsand amines. Detailed study of vibrational frequencies of carbonyl compounds (ketones,aldehydes, esters, amides, acids, anhydrides, lactones, lactamsand

Rofgaseous,solids and polymericmaterials.Unit 2:RamanandMossbauerSpectroscopyRamanspectroscopy QuantumtheoryofRamaneffect,ClassicaltheoryofRamaneffect,PurerotationalRamanspectra,Ramanactivityofvibrations,VibrationalRamanspectra,polarization of light and Raman effect, applications., Mutual exclusion principle andRamanspectraofHg22+,NO3-,ClO3-,N2O,CO2 andCH4.Mossbauer Spectroscopy Basic principles, spectral parameters and spectrum display.Application of the technique to the studies of (1) bonding and structures of Fe+2andFe+3compounds including those of intermediate spin, (2) Sn+2 and Sn+4compounds-nature ofM-L bond, coordination number, structure and detection of oxidation stateandinequivalentMBatoms.Unit 3:Chromatography,GCandHPLCtechniquesChromatographic and Electrophoretic methods of separation, Principles andapplications of Paper, Thin layer & HPTLC, Gas, Gas-liquid, Liquid chromatography,HPLCandFPLC;Paperandgelelectrophoresis.

SuggestedBooks:1. InstrumentalmethodsofAnalysis- Willard,Dean&Settle.2. PrinciplesofInstrumentalAnalysis- Skoog,HollerandWieman3. Introductiontophotoelectronspectroscopy- P.K.Ghosh4. ApplicationsofMössbauerSpectroscopy- GreenWood5. Structuralinorganicchemistry-Mössbauerspectroscopy– Bhide



19

6. Spectroscopicidentification oforganiccompounds- Silverstein,Basselerand Morril7. Applicationofabsorptionspectroscopy- JohnR.Dyer8. NMRinchemistry-Amultinuclearintroduction- WillamKemp9. OrganicSpectroscopy- WilliamKemp10. SpectroscopicmethodsinOrganicchemistry- DHWilliamsandIFleming11. ModernNMRtechniquesforchemistryresearch- AndrewBDerome12. Introductiontoorganicspectroscopy- Pavia13. Carbon-13NMRfororganicchemists- GCLevyandOLNelson14. NuclearMagneticResonanceBasicprinciples- Atta-Ur-Rahman15. ApplicationsofMössbauerspectroscopy-N.N.GreenwoodandT.C.Gibb, Chapman

&Hall16. PrinciplesofMössbauerspectroscopy-T.C. Gibb,Chapman&Hall.17. Physicalmethodsforchemists- R.S.Drago,2nded.(SaundersCollege Publishers)18. Spectroscopyoforganiccompounds- P.S.Kalsi.



20

CH4206SpectroscopicandAnalyticalTechniques(L-T-P-C:3-0-0-3)

Unit1:NMRSpectroscopyIntroduction, Defination, Chemical shift, spin spin interaction, shielding mechanism,mechanism of measurement, chemical shift values and correlation for protonsbondedto carbon (aliphatic, olefinic, aldehydic andaromatic) and other nuclei (alcohols,phenols, enols, carboxylicacids, amines, amides & mercapto), chemical exchange, effectof deuteration, complex spin-spin interaction between two, three, four and five nuclei(firstorderspectra), virtualcoupling.Stereochemistry, hindered rotation, Karpluscurve variation of coupling constant withdihedral angle.Simplification of complex spectra nuclear magnetic double resonance, contact shiftreagents, solvent effects. Fourier transform technique, nuclear Over Hause effect (NOE).Resonanceofothernuclei-F.P.Applicationsofspin-spincouplingindeterminationofstructureandstereochemistryofOrganicmolecules,NOEanditsapplications.Electron Spin Resonance Spectroscopy Hypercoupling,spinpolarizationforatomsandtransitionmetal ions, spin-orbit coupling and significance of g-tensors, application totransitionmetalcomplexes(havingoneunpairedelectronincludingbiologicalsystemsandtoinorganicfreeradicals.Unit 2:MassSpectroscopyOriginofmassspectrum,principlesofEImassspectrometer- Instrumentation.Typesoffragments:oddelectronandevenelectroncontainingneutralandchargedspecies(evenelectron rule, Nitrogen rule, isotopic peaks, metastable ion peaks, determination ofmolecularformulaandHigh-resolutionmassspectrometry.Salientfeaturesof fragmentationpatternoforganiccompounds- α-cleavage,β-cleavage,McLafferty rearrangement,Retro-Diels-Alderfragmentationandorthoeffect.Fragmentation pattern of individual heterocyclic systems viz., Furan, Pyrrole,ThiopheneandPyridine. Preliminaryaccountofchemicalionization.Unit 3: HandsonExamplesBasedonAboveTechniquesCombinedapplicationofUV,IR,1H-NMR,13C-NMRandMassspectra:IntroductiontotheanalyticalapproachtowardsthestructureelucidationofsimpleorganicmoleculesbycombinedapplicationofUV,IR,1H-NMR13C-NMRandMassspectra.

1. Physical Methods for Chemistry, R. S. Drago, Saunders Company.2. Structural Methods in Inorganic Chemistry, E.A.V.Ebsworth, D.W.H. Rankin and S.

Cradock, ELBS.3. Infrared and Raman Spectra: Inorganic and Coordination Compounds, K. Nakamoto,

Wiley.4. Progress in Inorganic Chemistry vol.,8, ed., F.A. Cotton, Vol., 15, ed.S.J. Lippard,

Wiley.5. NMR, NOR, EPR and Mossbauer Spectroscopy in Inorganic Chemistry, R.V. Parish,

Ellis Horwood.6. Practical NMR Spectroscopy, M.L. Martin, J.J. Delpeuch and G.J.IV Brtin, Heyden.7. Spectrometric Identification of Organic Compounds, R.M. Silverstein, G.C. Bassler

and,T.C. Morrill, JohnWiley.



21

8. Introduction to NMR Spectroscopy, R.J. Abraham, J. Fisher and P. Loftus, Wiley.9.10. Spectroscopic Methods in Organic Chemistry, D.H. Williams, I. Fleming, Tata

McGraw-Hill.



22

CH4207AdvancedPhysicalChemistryLab(L-T-P-C:0-0-6-3)

1. To determine the percentage composition of strong acid andweak acid in givenmixtureusingconductometricmethod.

2. To determine the rate constant and energy of activation of hydrolysis of methylacetateattwodifferenttemperature.

3. To determine the relative strengths of the given strong acids by studying thekineticsofinversionofcanesugarusingpolarimetericmethod.

4. To determine the Critical Micelle Concentration of given surfactant (SDS) byconductometricmethod.

5. To determine the viscosity averagemolecular weight of a given polymer sampleusingOstwald’sviscometer.

6. TodeterminetheRedoxpotentialofFe2+/Fe3+ systembypotentiometricmethod.7. TodeterminethestrengthofgivenunknownAgNO3 usingpotentiometricmethod.8. Todetermine thedissociationconstants (pK1 andpK2)ofgivendibasicacidusing

pH-metricmethod.9. TodeterminetheKsp ofBariumSulphate,SilverChlorideandSilverChromateusing

conductometricmethod.10. Todeterminethedissociationconstantofmonobasicacids(aceticacid,benzoicacid

andSalicylicacid)bypotentiometricmethod.

CH4208BiochemicalTechniquesLaboratory (L-T-P-C:0-0-6-3)

1. DeterminationofpIofAminoacidbytitrationmethod.2. Identificationofmonosacharidesanddi-sacharidesbyrecrystalization.3. SeparationofaminoacidsbyTLC.4. EstimationoftotalsugarbyAnthronemethod.5. EstimationofaminoacidbyAnthronemethod.6. EstimationofproteinbyLowery’smethod.7. Determinationofa)Iodinenumberb)AcetylnumberofaLipid.8. Separationofaminoacidsbypaperchromatography.

SuggestedBooks:1. AnalyticaltechniquesinBiochemistryandMolecularBiologybyKatoch,R,Springer

(2011).2. BasicmethodsfortheBiochemicalLab;MartinH,Springer(2007).3. PrinciplesandTechniquesinBiochemistryandMolecularBiology7th Ed.Wilson.K.,

Walker.J,CambridgeUniversityPress(2010)4. Biochemistry Lab fax Ed. J.A.A. Chambers and D. Rickwood, Blackwell Science,

(1993).5. LaboratoryTechniquesinBiochemistryandmolecularbiology,WorkandWorkVol.

I&II.



23

IUM000BasicCommunicationandSoftSkills(L-T-P-C:1-0-0-0)

Unit 1: FundamentalsofCommunication∑ ImportanceofCommunication∑ ImportanceofInterpersonalCommunication∑ ProcessofCommunication∑ FlowsandTypesofCommunication

Unit 2: BarrierstoCommunication∑ Definition∑ TypesofBarriers

Unit 3: Listening∑ Hearing&Listening∑ TypesofListening∑ Do’sandDon’tsofEffectiveListening

Unit 4: EffectivePresentation∑ Patterns&MethodsofPresentation,OralPresentation∑ Howtopreparepresentation∑ Effectivewaystodeliverthepresentation∑ Howtopreparemulti-mediapresentation∑ DifferencebetweenC.V&Resume,typesofresume

Unit5: CorporateEtiquettes∑ Non-verbalCommunication∑ E-mailetiquette,telephoneetiquette,diningetiquette∑ Officemeetingetiquettes,dressetiquette

TextBooks:1. SoftSkillsforEveryonebyJeffButterfield,Cengagepublication2. TechnicalCommunication;PrinciplesandPractice”byMeenakshiRaman&Sangita

Sharma(OxfordUniversityPress)3. “CommunicationSkills”byDr.SanjayKumarandDr.PushpLata,OxfordUniversity

Press

ReferenceBooks:1. PersonalityDevelopmentandSoftSkillsbyBarunKMitra2. BusinessCorrespondenceandReportwriting”- RCSharmaandKrishnaMohan,

TataMcGrawHill,8th Ed.2015



24

SEMESTER- III

CH5101AdvancedOrganicChemistryII (L-T-P-C:3-1-0-4)

Unit 1: FreeRadicals,PhotochemistryandPericyclicReactionsFormation, stability and detection of short and long lived free radicals, homolysis,additionandrearrangementsandcyclizationoffreeradicalsandtheirapplications.Basicsofphotochemicalreactions,photochemistryofolefins,carbonylcompoundsandaromatic compounds (Isomerization,NorrishType I and II, photoreduction, Patterno-Buchireaction, cycloaddition, rearrangement and aromatic substitution reactions.Bartonreaction,reactionsofsingletoxygen. Applicationsofphotochemicalreactionsinorganicsynthesisandnaturalproductsynthesis.Orbitals, molecular orbital symmetry, molecular orbital of ethylene, 1,3-butadiene,1,3,5–hexatriene and allyl systems, concerted reactions, classification of pericyclicreactions,derivationofselectionrulesthroughconstructionofcorrelationdiagramsforcycloaddition reactions and for electrocyclic reactionswith 4n and 4n+2π electrons,conrotatory and disrotatory motions for electrocyclic ring opening and ring closure.FMOapproach forderivationofWoodward-Hoffmanselection rules forcyclo additionand electrocyclic reactions, suprafacial and antarafacialcyclo additions. Secondaryeffects and stereochemistry of cyclo additions; 2s+2a cyclo addition of ketenes. TheCopeandtheClaisen rearrangements, theenereaction.Unit2: OrganicSynthesisTransitional metals complexes in organic synthesis and Boron, Si, Sn Chemistry,Transition metal complexes in organic synthesis-Introduction-oxidation states oftransitionmetals, 16-18 rule, dissociation, association, insertion, oxidative addition,reductive eliminationof transition metalOrganopalladium in organic synthesis- Heckarylation,allylicactivation,carbonylation,wackeroxidation,isomarizationformationN-arylandN-alkylbondtransmetalation,allyldeprotectioninpeptides,couplingreactions:Stillecoupling,SonogashiraandSuzukicouplingreactionsandtheirimportanceReactionsIroncarbonyls,ferrocenes,Fe-cyclopentadienecomplex,protectionofdienes,Isomerization.Wilkinson, Noyori, Knowls catalyst of Ruthenium and Rhodium –synthesis and uses its use inhydrogenation reactions-deallylation, C-C, C-O, C-N bondcleavages, Synthesis and uses of organosilane and organo tin compounds, OlefinmetathesisbyIst,andIIndgenerationcatalyst,reactionmechanismandapplicationinthesynthesisofhomoandheterocycliccompoundsUnit 3:AssymetricsynthesisRecapitulationofStereochemicalconcepts- enantiomers,diastereomers,homotopicandheterotopic ligands, stereoselective and stereospecific reactions, prochirality, Chemo-,regio-,diastereo- and enantio-controlled approaches; Chirality transfer, Asymmetricinductions; Chiralpools, Chiral auxiliaries, chiral reagents and catalysts, andtemplates;Asymmetricallylation, Asymmetriccycloaddition reactions. Stereoselectiveadditionofnucleophilestocarbonylgroup:Re-Sifaceconcepts,Cram’srule, FelkinAnhrule,Houkmodel,Cram’schelatemodel.Asymmetricsynthesisuseofchiral auxiliaries,asymmetrichydrogenation,asymmetricepoxidationandasymmetricdihydroxylation.



25

Asymmetric reduction reactions: Reduction of ketones, imines and olefins(use ofBINOLS) AsymmetricC-Cbondformingreaction:Simmon-Smithreaction,aldolreactionandalkylation basedonOrgano catalyticmethods,Mukayamaaldolreaction,Shibasakibi-metallic catalyst system; RAMP-SAMP based alkylation strategy, Meyers oxazolineandbis-lactambasedmethods.

SuggestedBooks:1. Molecularreactionsandphotochemistry-C.Dupey&O.L.Chapman2. Molecularphotochemistry-Turro3. MolecularPhotochemistry- Gilbert&Baggo4. OrganicPhotochemistry- DCoyle5. MolecularReactionsandPhotochemistry– DepuyandChapman6. Photochemistry- CWJWells7. Somemodernmethodsoforganicsynthesis-W.Carruthers8. Guidebooktoorganicsynthesis- R.K.Meckie,D.M.Smith,R.A.Atken9. Organicsynthesis-O.House10. Organicsynthesis- M.B.Smith11. Advancedorganicchemistry.PartAStructure&Mechanism-FrancisA.1. CoreyandRichardJ.Sundberg12. March'sAdvancedOrganicChemistry-MichaelB.Smith13. ConservationofOrbitalSymmetry-WoodwardandHoffmann14. OrganicReactionsandOrbitalSymmetry,-GilchristandStorr15. PericyclicReactions— aproblemsolvingapproach- LehrandMerchand16. Pericyclic Reactions - A Textbook: Reactions, Applications and Theory- S.

Sankararaman,RoaldHoffmann17. PericyclicReactions- MukherjeeSM



26

CH5102AdvancedInorganicChemistryII(L-T-P-C:3-0-0-3)

Unit 1:OrganometallicChemistryandCatalysisOrganometallic Chemistry: Complexeswith pi-acceptor and sigma-donor ligands - 16electronand18electronrules– StabilityandReactivity - Isolobalanalogy- Structureandbonding- Agnosticinteraction.Dbockcarbonyl,s-Organyls,Metalcarbenesandmetalcarbynes,Ferrocene.Homogeneous and Heterogeneous Catalysis: Hydrogenation, carbonylation,polymerization, Wacker oxidation and other reactions catalyzed by transition metalcomplexes.Metal Cluster Compounds: Metal-metal bond - Carbonyl and non-carbonyl clusters -Structureandbonding- Low-dimensionalsolids- Clustersincatalysis.Unit 2:PropertiesofSolidsThermal Properties: Lattice vibrations - phonon spectrum; Lattice heat capacity;Thermalexpansion;Thermalconductivity.ElectricalProperties:Freeelectrontheory-electricalconductivityandOhm'slaw- Halleffect;Bandtheory- bandgap- metalsandsemiconductors - intrinsic and extrinsic semiconductors; Hopping semiconductors;Semiconductor/metaltransition;p-njunctions;Superconductors- Meissnereffect- typeIandIIsuperconductors- isotopeeffect- basicconceptsofBCStheory- manifestationsof theenergygap - Josephsondevices.MagneticProperties:Classificationofmagneticmaterials; Langevin diamagnetism; Quantum theory of paramagnetism; Cooperativephenomena - ferro, antiferro and ferrimagnetism - magnetic domains and hysteresis;Super paramagnetism.Optical Properties: Optical reflectance - plasmon frequency; Raman scattering incrystals; Photoconduction; Photo and electroluminescence; Lasers; Photovoltaic andphotoelectrochemicaleffects.

SuggestedBooks:1. H.V.Keer,PrinciplesoftheSolidState(541.0421K25P)2. L.E.SmartandE.A.Moore,SolidStateChemistry:anIntroduction(541.0421

Sm295)3. M.T.Weller,InorganicMaterialsChemistry(546W45I)4. K.J.Klabunde,NanoscaleMaterialsinChemistry(660K66N)5. W.D.Callister,MaterialsScienceandEngineering,AnIntroduction(620.11C13M)6. C.Kittel,IntroductiontoSolidStatePhysics(530.41K65I)



27

CH5103AdvancedPhysicalChemistryII(L-T-P-C:3-0-0-3)

Unit1:CatalysisIHeterogeneous catalysis: Kinetics and Mechanism of surface reactions. Surfaceheterogeneity, activity and selectivity, deactivation and regeneration. Theories ofpromotion and poisoning of catalysts. Catalyst Synthesis: supports and supportedcatalysts. Zeolites and zeolite-likematerials, precipitation and impregnationmethods.Characterization of catalysts: Surface area, pore size distribution (mercuryporosimetry) Thermal methods (DTA, TG, TPD and TPR), Surface acidity,Photoelectron spectroscopy (XPS, AES, XRF),LEED, Mossbauer spectroscopy, IR,SIMS,ScanningTunnelingMicroscopy(STM),AtomicForce Microscopy(AFM).Unit2:CatalysisIITheoriesofcatalysisbymetals,semiconductorsandsupportedcatalysts.Geometricandelectronicfactors. Important applications ofheterogeneouscatalysis in petroleum,petrochemicals and fine chemicals, catalysis in pollution control. Homogeneouscatalysis: Reactions involving carbocations, transition metal complexes as catalysts,OlefinhydrogenationwithWilkinson’scatalystandmethanolcarbonylation.Importantindustrialapplications.Unit3:SolidStateChemistryCrystallography- Recapitulation, diffraction properties of crystals. symmetryelements, space groups. Ionic crystals. Determination of crystal structure.Imperfection in crystals- point defects (Thermodynamic treatment) and line defects.Crystalgrowth,Crystalengineeringandpolymorphism.Electronicpropertiesandbandtheory-Metal,insulatorsandsemiconductors,electronicstructure of solid- band theory, band structure of metals, insulators andsemiconductors. Intrinsic and extrinsic semiconductors. Optical properties andmagneticproperties.

SuggestedBooks:1. CatalyticChemistry,B.C.Gates,JohnWiley(1992)2. PrinciplesandPracticeofHeterogeneousCatalysis,J.M.Thomas&W.J.Thomas,

WeinheimNY(1997)3. Spectroscopic Characterization of Heterogeneous Catalysis, J.L.G. Fierro, Elsevier

(1990)4. AdsorptionandCatalysis,D.K.Chakrabarty,NewAgeInternationalPvt.Ltd.Tailored

MetalComplexes,Y.Ivasawa,D.ReidelCo.(1986).5. SolidStateChemistryanditsApplications,A.R.West,JohnWiley(2014).6. SolidStateChemistry,D.K.Chakrabarty,NewAgeInt.,NewDelhi,(2009).7. AtomicStructure&ChemicalBond,ManasChandra,TataMcGrawHill(1995).8. TreatiseonSolidStateChemistryVolI,VII,B.N.Hannay,PlenumPress(1975).9. IntroductiontoSolids,L.V.Azaroff,McGrawHill(1960).10. TheCrystalasASupramolecularEntity:PerspectivesinSupramolecular.11. Chemistry,G.R.Desiraju,Wiley-VCH(1996)



28

CH5104ApplicationofSpectroscopyII(L-T-P-C:3-1-0-4)

Unit 1:NMRSpectroscopySecond order effects, examples of AB, AX and ABX systems, simplification of secondorderspectrum,selectivedecoupling,useofchemicalshiftreagentsforstereochemicalassignments. 13C NMR, introduction to FT technique, relaxation phenomena, NOEeffects,1Hand13Cchemicalshiftstostructurecorrelations.Editingtechniques:INEPTandDEPTmethodsStudyofdynamicprocessesbyVTNMR,restrictedrotation (DMF,DMA, biphenyls, annulenes), cyclohexane ring inversion, degenerate rearrangements(bullvaleneand related systems).2DNMRspectroscopy,COSY,HMBC,HMQC,NOESY.Time scale- Multinuclear andOrganometallicNMR spectroscopy -Morecommonspin-1/2nuclei,19F,31P,withfewexamples.Unit 2:ORDandCD,PolarimetryBasic concepts of optical rotatory dispersion (ORD) and circular dichroism (CD),Deductionofabsoluteconfiguration–Cottoneffect–Octantruleforketones.ApplicationsofORDandCDspectroscopy.Unit 3:ProblemSolvingExamplesofstructureelucidationusingUV,IR,NMRandMasstechniques.Handsontrainingwithexperimentsonabovetechniques

SuggestedReadings:1. Practical NMR Spectroscopy, M.L. Martin, J.J. Delpeuch and G.J.IV Brtin, Heyden.2. Spectrometric Identification of Organic Compounds, R.M. Silverstein, G.C. Bassler

and T.C. Morrill, John Wiley.3. Introduction to NMR Spectroscopy, R.J. Abraham, J. Fisher and P. Loftus,Wiley.4.5. Spectroscopic Methods in Organic Chemistry, D.H. Williams, I. Fleming, Tata

McGraw-Hill.



29

CH5105AnalyticalTechniquesLab(L-T-P-C:0-0-6-3)

1. DeterminationBathochromicshiftin alkalinemediumofp-NitrophenolComparedtopNitrophenol.

2. DeterminationHypsochromicshiftinacidicmediumofAnilinecomparedtoAniline.

3. RecordingtheI.RSpectrumDifferentOrganiccompoundsa) Aliphatic and aromatic alcohols. b) Aliphatic and aromatic carbonyl compounds

(aldehydes,ketones,estersandacidsetc.) c)AromaticandaliphaticNitro,Amines,Nitriles,alkenes,alkynesandAmides.

4. UseofComputertechniquesa) Chem Draw, Chem Sketch, ISIS Draw, Pymol calculations, Mestrec Softwares

operations. b)Draw the Structureof Simple aliphatic, aromatic andheterocycliccompoundsinChem Drawwithdifferentsubstituent.GetthecorrectIUPACNameandpredicttheIH-NMRSpectra.

SuggestedBooks:1. PracticalOrganicChemistry,R.K.Bansal.2. OrganicStructures fromSpectra,4thEdition,L.D.Field,S.Sternhell, J.R.Kalman,

Wiley&Sons,Ltd.3. PracticalOrganicChemistrybyMann&Saunders.4. Kemp,W(1994):OrganicSpectroscopy,3rdEd.,MacMillan5. Kalsi,P.S (2007): Spectroscopy of Organic Compounds, 6th Edition, New age

internationalpublishers.6. Sharma Y.R (1992): Elementary Organic Spectroscopy – Principles and Chemical

applications,S.Chand

CH5106OrganicandMedicinalChemistryLab(L-T-P-C: 0-0-6-3)

1)Multistepsynthesis:i) BenzanilidebyBeckmann’srearrangement:(a) Preparationofbenzophenoneoxime (b)Beckmann’srearrangementtobenzanilideii) Benzilicacidfrombenzoin:(a) Benzilfrombenzoin(b)Benzilicacidfrombenziliii) Anthranilicacidfromphthalicanhydride:

(a)Phthalimide fromPhthalicanhydride (b) Hoffmann’srearrangement toanthranilicacid.2)MonitorizationofEachstepwithHPLC,I.RandNMR. 3)CalculationofOpticaticalrotationvalueofGlucoseandSucrose. 4)IsolationofPiperinefromblackpepper.

RecommendedBooks:1. PracticalorganicchemistrybyMann&Saunders2. TextbookofpracticalorganicchemistrybyVogel3. ThesystematicidentificationoforganiccompoundsbyRalphL.Shriner,4. ChristineK.F.Hermann,TerenceC.Morrill andDavidY.Curtin5. PracticalorganicchemistrybyMann&Saunders6. SpectroscopicidentificationoforganiccompoundsbyRMSilversteinandFX



30

ELECTIVES: SEMESTER - IIICH5107ChemistryofNaturalProducts(L-T-P-C:2-0-0-2)

Unit1:Terpenoidsand CarotenoidsClassification, nomenclature, occurrence, isolation, general methods of structuredetermination, isoprenerule. Structure determination, stereochemistry, biosynthesisand synthesis of the following representative molecules: Citral, Menthol, Santonin, andB-Carotene.Unit 2:AlkaloidsDefinition, nomenclature and physiological action, occurrence, isolation, generalmethods of structure elucidation, degradation, classification based on nitrogenheterocyclic ring, role of alkaloid sin plants. Structure, stereochemistry, synthesis andbiosynthesis of the following: Ephedrine,(+)-Nicotineand Morphine.

Occurrence, nomenclature, basic skeleton, Diel's hydrocarbon and stereochemistry.Isolation, structure determination and synthesis of Cholesterol, Bileacids, Estrone,.Biosynthesis of steroids.Unit 4:ProstaglandinsOccurrence, nomenclature, classification, biogenesis and physiological effects.Synthesis of PGE2 and PGF2a.

1. Natural Products:ChemistryandBiologicalSignificance,J. Mann,R.S. Davidson,J.B.Hobbs,

2. OrganicChemistry,Vol2,I.L.Finar,ELBS.3.4.5. Chemistry,Biological andPharmacologicalProperties ofMedicinalPlantsfrom the

Americas, Ed. Kurt Hostettmann, M.P. Gupta and A. Marston, Harwood AcademicPublishers.

6.7.

8.



31

Unit1:DrugDesignDevelopment of new drugs, procedures followed in Drug design, Concepts of LeadcompoundandLeadmodification,ConceptsofProdrugsandSoftdrugs,Structureandactivityrelationship(SAR), factorseffectingthebioactivity,resonanceinductiveeffect,isosterism,Bio isosterism, spatial considerations.Theoriesofdrugactivity, occupancytheory, rate theory, induced fit theory, Quantitative structure activity relationship.HistoryanddevelopmentofQSAR,Conceptsofdrugreceptors,Elementarytreatment ofdrug receptor interaction. Physico chemical parameters, lipophilicity, partitioncoefficient,electronionizationconstants,steric,Sheltonandsurfaceactivityparametersand redox potentials. Free Wilson analysis, Hansch analysis, relationships betweenWilson and Hansch analysis. LD 50, ED-50 (Mathematical derivation of equationsexcluded).Introductiontoadsorption,disposition,eliminationusingpharmacokinetics,Important Pharmacokinetic parameters in defining drug disposition and intherapeutics, mention of uses of pharmacokinetics in drug development process.Introduction, elementary treatment of enzyme stimulation, enzyme inhibition,Sulphonamides, membrane active drugs, Drug metabolism, Xenobiotics,Biotranformation,Significanceofdrugmetabolisminmedicinalchemistry.Unit 2: AntineoPlasticAgents,CardioVascular,AntiInfectiveDrugs

mercaptopurine. Recent development in cancerchemotherapy. Hormone and natural products.CardiovascularDrugsandanti-infectivedrugs:

Local Antiinfective Drugs:

Unit 3:AntimalarialandAntituberculosisandAntiBioticDrugsAntimalarials:Modern chemotherapy ofmalaria, 4-amino and 8-amino quinolins, 9-amino acridine. Synthesis of mefloquines, chloroquine, primaquine and daraprimMode of action of antimalarial agents SAR of antimalarial agents Anti tuberculosis:Synthesisofonlythefollowingdrugs:Isoniazid(INH),Ethionamide,Ethambutol,DDS(Dapsone)Antibiotics:



32

SuggestedBooks:1.2. WilsonandGisvoldsTextbookofOrganicMedicinalandPharmaceuticalChemistry3. An Introduction to Drug Design, S.S. Pandeya and J.R. Dimmock, New Age

International.4. Burger's Medicinal Chemistry and Drug Discovery, Vol-1(Chapter-9andCh14),Ed.

M.E. Wolff,JohnWiley.5.6. The Organic Chemistry of Drug Design and Drug Action, R.B. Silverman, Academic

Press.7.



33

CH5109SupramolecularChemistry

Unit 1:Definition of supramolecular chemistry, Hydrogen bonding and nature ofsupramolecular interactions: ion-ion, ion-dipole, dipole-dipole, cation-π, anion-π, π-πandVanderWaalsinteractions.Unit 2:Receptors, host-guest interactions, lock and key analogy, pre-organization andcomplimentarity, binding of cationic, anionic, ion pair and neutral guest molecules,selectivity and solution behaviour of crown ethers, complexation of organic cations,siderophores,biologicalanionreceptors,cnticrownsandcoordinationinteractions.Unit3:Self-Assembly Self-assembly of molecules: Design, synthesis and properties of themolecules, self-assembling by H-bonding, metal-ligand interactions and other weakinteractions,metallomacrocycles,catenanes,rotaxanes,helicatesandknots,examplesofrecentdevelopmentsinsupramolecularchemistry.Unit4:CrystalengineeringCrystalengineering:roleofH-bonding,halogenbondingandotherweakinteractions,co-crystals,salts,polymorphsandtheirphysico-chemicalproperties,coordinationpolymers,metalorganicframeworksandtheirproperties.

Text Books:1. J.M.Lehn,SupramolecularChemistry-ConceptsandPerspectives,Wiley-VCH,1995.2. P.D.Beer,P.A.GaleandD.K.Smith,SupramolecularChemistry,OxfordUniversity

Press,1999.3. J.W.SteedandJ.L.Atwood,SupramolecularChemistry,1stEd.,Wiley,2000.4. J.W.Steed,CoreConceptsinSupramolecularChemistryandNanochemistry,1stEd.,

JohnWiley&Sons,2007.5. J.D.Seader,I.W.Hamley,IntroductiontosoftmaterSyntheticandBiologicalself

49M.Sc.(Chemistry)2017-18assemblymaterials,Separationprocessprinciples,2ndEd.,Wiley,2010.

6. G.R.Desiraju,J.J.VittalandA.Ramanan,CrystalEngineering:ATextbook,WorldScientific,2011.



34

CH5110ChemistryofMaterials(L-T-P-C:2-0-0-2)

Unit1: MultiphaseMaterialsFerrous Alloys, Fe-C phase transformations in ferrous alloys; stainless steels, non-ferrousalloys,propertiesofferrousandnon-ferrousalloysandtheirapplications.Glasses,Ceramics,CompositesandNanomaterials: Glassystate,glassformersandglassmodifiers, applications. Ceramic structures, mechanical properties, clay products,Refractories- characterization, properties and applications.Microscopic composites:dispersion-strengthened and particle-reinforced, fibre-reinforced composites,macroscopic composites. Thin films and Langmuir-Blodgett Films: Preparationtechniques,evaporation/sputtering,chemicalprocesses,MOCVDsol-geletc.Langmuir-Blodgett(LB)film,growthtechniques,photolithography,propertiesandapplicationsofthinandLBfilms.Unit 2: LiquidCrystalsMesomorphic behaviour, thermotropic liquid crystals, positional order, bondorientational order, nematic and smecticmesophases; smectic- nematic transition andclearing temperature-homeotropic, planar and schlieren textures, twisted nematics,chiral nematics, molecular arrangement in smectic A and Smectic C phases, opticalpropertiesofliquidcrystals,Dilectricsuspceptibilityanddielectriccosntants.Lyotropicphasesandtheirdescriptionoforderinginliquidcrystals.Polymericmaterials:Molecularshape,structureandconfiguration,crystallinity,stress-strainbehaviour, thermalbehaviour,polymertypesandtheirapplications,conductingandferro-electricpolymers.Unit 3: IonicConductorsTypesofionicconductors,mechanismofionicconduction,interstitialjumps(Frenkel);vacancymechanism,diffusionsuperionicconductors;phasetransitionsandmechanismofconductioninsuperionicconductors,examplesandapplicationsofionicconductors.HighTc Materials:Defectprovskites,highTc superconductivityincuprates,preparationandcharacterizationof1-2-3and2-1-4materials,normalstateproperties,anisotropy,temperature dependence of electrical resistance, optical phonon modes,superconducting state, heat capacity, coherence length, elastic constants, positronlifetimes, microwave absorption-pairing andmultigap structure in high Tc materials,applicationsofhighTc materials.MaterialsforSolidstatedevices:Rectifiers,transistors,capacitorsIV-Vcompounds,lowdimensionalquantumstructures,opticalproperties.

SuggestedBooks:1. SolidStatePhysics,N.W.AshcroftandN.D.Mermiin,SaundersCollege.2. MaterialsScienceandEngineering,Anintroduction,W.D.Callister,Wiley.3. PrinciplesoftheSolidstate,H.V.Keer,WileyEastern.4. MaterialsScience,J.C.Anderson,K.D.Leaver,J.M.AlexanderandR.D.Rawlings,

ELBS5. ThermotropicliquidCrystals,Ed.G.W.Gray,JohnWiley.6. Handbookofliquidcrystals,KelkerandHatz,Chemie Verlag.



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SEMESTER - IV

CH5201ResearchorIndustrialProject/Viva(L-T-P-C:0-0-20-10)

CH5202StudentSeminar(BasedonRecentResearchArticles)(L-T-P-C:0-0-2-2)

CH5203PharmaceuticalAnalysis(L-T-P-C:2-0-0-2)

Unit1:PharmaceuticalAnalysisISources of impurities in pharmaceuticals (chemicals, raw materials, methods ofmanufacture, reagents,solvents,atmosphericandmicrobialcontaminants)andstorageeffects.Limittests,solubilitytests,disintegrationtests,stabilitystudies,impurityprofileofdrugs,Processanalyticaltechnology,qualityauditsetc. Validationofmanufacturingand analytical equipment, process validation in production of pharmaceuticals,developmentofnewanalytical/bioanalyticalmethodanditsvalidation.Unit2:PharmaceuticalAnalysis IIAssay of main classes of pharmaceuticals-with reference to Introduction-Type-Properties-MethodofAnalysisElectrochemical Methods: Potentiometry and conductometry. Flame photometry,Atomic absorption spectrophotometry, nuclearmagnetic resonance spectroscopy andmassspectrometrySpectroscopicMethods:Ultraviolet,visible,InfraredandRamanspectroscopyChromatographic Methods: Ion exchange, column, paper, thin layer, gas and highperformanceliquidchromatography.Assay of polymorphs in pharmaceutical Industry- introduction to polymorphs,methodsofidentificationandanalysisofpolymorphsusingNear-IR,Raman,XRPD,solid state NMR, DSC,TGA. Methods of analysis of common excipients /additives informulations. Determinationofactiveconstituentsinpresenceoftheseexcipients.

SuggestedBooks:1. PharmaceuticalAnalysis,T. HighchiandE.Brochmann,Hanssen Interscience.2. Thequantitativeanalysisofdrugs,D.C.Garrent,ChapmanandHall.3. PharmaceuticalAnalysis,A.H.BackettandJ.B.Stenlake,ChapmanandHall.4. Methodsofdruganalysis,S.F.Granbowrshll,LeeandFehiger.5. Analysisofdrugandchemicals,N.Evers,W.SmithandC.Grikin.6. Isolationandidentificationofdrugs,E.G.JClerks, PharmaceuticalPress.7. Pharmaceutical analysis, A textbook for pharmacy students and pharmaceutical

chemists,DavidG.Watson,ChurhillLivingstone,2000.8. The practical evaluation of phyto pharmaceuticals, Brain K.R and Turner T.T

Wright-Scientechnica,Bristil.



36

CH5204ChemistryofNanomaterials(L-T-P-C:2-0-0-2)

Unit1:SynthesisofNanoMaterialsIntroduction: Definitionandterminologies,nanoparticlemorphologies,sizedependentpropertieslikeoptical,electricalandmagneticproperties.Synthesisofnano materials Physicalmethods:Mechanicalmethods,methodsbasedonevaporation,laserablation,sputtering, CVD,MBE.Chemical methods: Quantum dots and 1D nano materials (chemical precipitationmethod,synthesisinconfinedmedialikereversemicelles,zeolitesetc),synthesisfrommolecularprecursorsandmolecularclusters, sol-gelmethod. 2Dnano materials (L-Bthinfilms,SelfAssembledMonolayers,softlithography).3D nano materials and biological methods: Synthesis using microorganisms, use ofnatural templates like DNA. Biomimetic synthesis of nano particles. Synthesis ofgraphemesandnano compositesUnit 2: Techniques for CharacterizingNano materials andApplications of Nanomaterials(15h)Ellipsometry, and dual polarization interferometry (DPI) as methods used toobtain nano-grammasses,nano-scale thicknesses,andtheopticalpropertiesofultra-thinassemblies.Infrared spectroscopy of nano-assemblies. Attenuated-total reflection (ATR) andgrazing incidence angle techniques. Reflection-absorption IR spectroscopy (RAIRS).SurfaceenhancedRamanspectroscopy(SERS).Imagingtechniques:AFM,STM,SEM,EDX,imagingellipsometry.Optical microscopy. Fluorescence/phase contrast microscopy, confocal microscopy,totalinternalreflectionmicroscopy(TIRM),Brewsteranglemicroscopy(BAM),Nano-optics and local spectroscopy. Scanning near-field optical microscopy and photonscanning tunneling microscopy, scanning Plasmon near-field optical spectroscopy(SPNM),near-fieldopticalspectroscopy,fluorescencespectroscopy,nearfieldnonlinearoptics.Sizedetermination:DLS,XRD,TEM.Applicationsofnano materials:Opticalandbiosensors, Energycell,Catalysis,Drugdelivery systems, Waste remediation Risk assessment and management of nanoparticles

SuggestedBooks:1.Chemistryofnano materials,VolumeI&II,Ed.CNRRao,A.Muller,AKCheethamWiley,VCH.(2004).2.IntroductiontoNanotechnologyCPPooleJr.,FJOwens,Wiley(2006)3.Nanotechnology,M.RatnerandD.Ratner,Pearson.



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CH5205AdvancedHeterocyclicChemistry(L-T-P-C:2-0-0-2)

Unit 1:IntroductionNomenclature of Heterocycles

Heteroaromatic reactivity and tautomerism in aromatic heterocyclesStrain-bond angle and torsional strains and their consequences in small ringheterocycles.

Unit 2: Heterocyclic Synthesis

Synthesis andreactions of quinolizinium and benzopyrylium salts, coumarins and

Unit3: Heterocyclic SystemsContainingP,As,Sb

and6-memberedringsystems.

SuggestedBooks:1.2. TheChemistryofHeterocycles,T. EicherandS. Hauptmann,Thieme.3.4.5. ContemporaryHeterocyclicChemistry,G.R. NewkomeandW.W. Paudler,Wiley-6.



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CH5206EnvironmentalandGreenChemistry(L-T-P-C:2-0-0-2)

Unit 1: EnvironmentalChemistryEnvironmental Chemistry of water Properties of Water, Major aquatic chemicalprocessesWaterPollution:Types,sourcesandconsequencesofwaterpollution.sewageandwastewater treatment and recycling Environmental Impact Assessment. Environmentalauditing.CarboncreditsSoilPollution:Physicalandchemicalpropertiesofsoil,soilmicro-organismsand theirfunctions, Different kinds of synthetic fertilizer (N, PandK) and pesticides-their interactionswith different components of soil. Theirtoxicityandpollution.Industrialeffluentsofdifferentkinds, theirinteractionswithsoilcomponents,problemsoftoxicheavymetalsandpollution.Deteriorationofsoilduetominingactivities.SoilPollutionControlUnit2:GreenChemistryGreenChemistry:Definition,toolsandprinciplesofgreenchemistry,evaluationofstarting materials and reaction types. Solvent free systems, supercritical fluids, ionicliquidsascatalystsandsolventsEmerging Green Technologies: Photochemical reactions (advantages and challenges),examples, chemistryusingmicrowaves,sonochemistry,electrochemicalsyntheses.Waste Minimization techniques: Concept of Recycling, recovery and reuse,Bioremediationofwastesandsoils,phytoremediationofsoilsandsediments

SuggestedBooks:1. EnvironmentalPollutionanalysis,S.M.Khopkar,WileyEasternLtd.,Environmental

Chemistry,S.K.Banerji,PrenticeHallofIndiaPvt.Ltd.,NewDelhi2. EnvironmentalChemistry,StanleyManahan,LewisPublishersCRCPress,USA.6th

Edition3. IdentificationandAnalysisofOrganicPollutantsinwaterL.H.Keith,Arber Science

Publications.4. Standardmethodsforexaminationofwaterandwastewateranalysis,American

Public5. Health Association, New York. Chemical treatment and water purification, F .J.

Belan,MirPublishingHouse,Moscow.6. StandardMethods for Examination ofWater andwaste water analysis American

Public Health Association, N.Y. Water and water pollution (Hand Book) Ed.,Seonard’L.Ciacere,Vol.(ItoIV),MarcelDekkerInc.N.Y.(1972).

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