IIT JEE 2011 Paper1 Solutions

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    Please read the instructions carefully. You are allotted 5 minutes specifically for this purpose.

    Date : 11-04-2011 Duration : 3 Hours Max. Marks : 240

    PAPER - 1

    QUESTIONS AND SOLUTIONS OF IIT-JEE 2011

    INSTRUCTIONSA. General :

    1. The question paper CODE is printed on the right hand top corner of this sheet and on the back

    page of this booklet.

    2. No additional sheets will be provided for rough work.

    3. Blank papers, clipboards, log tables, slide rules, calculators, cellular phones, pagers and

    electronic gadgets are NOT allowed.

    4. Write your name and registration number in the space provided on the back page of this booklet.

    5. The answer sheet, a machine-gradable Optical Response Sheet (ORS), is provided separately.

    6. DO NOT TAMPER WITH/MUTILATE THE ORS OR THE BOOKLET.

    7. Do not break the seals of the question-paper booklet before being instructed to do so by the

    invigilators.

    8. This Question Paper contains having 69 questions.

    9. On breaking the seals, please check that all the questions are legible.

    B. Filling the Right Part of the ORS:

    10. The ORS also has a CODE printed on its Left and Right parts.

    11. Make sure the CODE on the ORS is the same as that on this booklet. If the codes do not

    match, ask for a change of the booklet.

    12. Write your Name, Registration No. and the name of centre and sign with pen in the boxes

    provided. Do not write them anywhere else. Darken the appropriate bubble UNDER each digit

    of your Registration No. with a good quality HB pencil.

    C. Question paper format and Marking Scheme:

    13. The question paper consists of 3 parts (Chemistry, Physics and Mathematics). Each part

    consists of four sections.

    14. In Section I (Total Marks: 21), for each question you will be awarded 3 marks if you darken

    ONLY the bubble corresponding to the correct answer and zero marks if no bubble is darkened.

    In all other cases, minus one (-1) mark will be awarded.

    15. In Section Il (Total Marks: 16), for each question you will be awarded 4 marks if you darken ALL

    the bubble(s) corresponding to the correct answer(s) ONLY and zero marks otherwise. There

    are no negative marks in this section.

    16. In Section III (Total Marks: 15), for each question you will be awarded 3 marks if you darken

    ONLY the bubble corresponding to the correct answer and zero marks if no

    bubble is darkened. In all other cases, minus one (-1) mark will be awarded.

    17. In Section IV (Total Marks: 28), for each question you will be awarded 4 marks if you darken

    ONLY the bubble corresponding to the correct answer and zero marks otherwise. There are no

    negative marks in this section.

    Write your Name registration number and sign in the space provided on the back

    page of this booklet.

    DONOTBREAKTHESEALS

    WITHOUTBEING

    INSTRUCTEDTODOSOBYT

    HEINVIGILATOR

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    J10411Page # 2

    Useful Data :

    R = 8.314 JK1 mol1 or 8.206 102 L atm K1 mol1

    1 F = 96500 C mol1

    h = 6.626 1034 Js

    1 eV = 1.602 1019 J

    c = 3.0 108 m s1

    NA = 6.022 1023

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    J10411Page # 3

    SECTION - I (Total Marks : 21)(Single Correct Answer Type)

    This section contains 7 multiple choice questions, Each question has four choices, (A), (B), (C) and (D)

    out of which ONLY ONE is correct.

    1. Extra pure N2

    can be obtained by heating

    (A) NH3 with CuO (B) NH4NO3(C) (NH

    4)

    2Cr

    2O

    7(D) Ba(N

    3)

    2

    Ans. (D)

    Sol. Ba (N3)2 Ba + 3N2

    2. Geometrical shapes of the complexes formed by the reaction of Ni2+ with Cl, CN and H2O, respectively,

    are

    (A) octahedral, tetrahedral and square planar (B) tetrahedral, square planar and octahedral

    (C) square planar, tetrahedral and octahedral (D) octahedral, square planar and octahedral

    Ans. (B)

    Sol. Ni+2 + 4Cl [NiCl4]2

    SP3

    [NiCl4]2 = 3d8 confiuration with Nickel in + 2 Oxidation state. Clbeing weak field ligand does not compel

    for pairing of electrons.

    So,

    Hence, complex has tetrahedral geometry

    Ni+2 + 4Cl [Ni(CN)4]2

    [Ni(CN)4]2

    = 3d8 configuration with nickel in + 2 oxidation state. CN

    being strong field ligand with complesfor pairing of electrons.

    So,

    Hence, complex has square planar gemetry.

    CHEMISTRY

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    Ni+2 + 6H2O [NI(H2O)6]+2[Ni(H2O)6] = 3d

    8 configuration with nickel in + 2 oxidation state. As with 3d8 configuration two d-orbitals are

    not available for d2sp3 hybridisation. So, hybridisation of Ni (II) is sp3d2. As Ni (II) with six co-ordination will

    have octahedral geometry.

    Note : With water as ligand Ni (II) forms octahedral complexes.

    3. Bombardment of aluminum by -particle leads to its artificial disintegration in two ways, (I) and (ii) asshown. Products X, Y and Z respectively are,

    (A) proton, neutron, positron (B) neutron, positron, proton

    (C) proton, positron, neutron (D) positron, proton, neutron

    Ans. (A)

    Sol. +

    4. Dissolving 120 g of urea (mol. wt. 60) in 1000 g of water gave a solution of density 1.15 g/mL. The molarity

    of the solution is :

    (A) 1.78 M (B) 2.00 M (C) 2.05 M (D) 2.22 M

    Ans. (C)

    CHEMISTRY

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    Sol. Mole =60

    120= 2

    mass of solution = 1120 g

    V =100015.1

    1120

    =

    115

    112L

    M = 112

    1152

    = 2.05 mol/litre

    5. AgNO3

    (aq.) was added to an aqueous KCl solution gradually and the conductivity of the solution was

    measured. The plot of conductance () versus the volume of AgNO3

    is :

    (A) (P) (B) Q (C) (R) (D*) (S)

    Ans. (D)

    Sol.

    6. Among the following compounds, the most acidic is :

    (A) p-nitrophenol (B) p-hydroxybenzoic acid

    (C) o-hydroxybenzoic acid (D) p-toluic acid

    Ans. (C)

    CHEMISTRY

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    Sol.

    Due to intramolecular hydrogen bonding in conjugate base of o-Hydroxybenzoic acid, it is strongest acid.

    7. The major product of the following reaction is :

    (A) (B)

    (C) (D)

    Ans. (A)

    Sol.

    CHEMISTRY

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    SECTION II (Total Marks : 16)

    (Multiple Correct Answers Type)

    This section contains 4 multiple choice questions. Each question has four choices (A), (B), (C) and (D)

    out of which ONE or MORE may be correct.

    8. Extraction of metal from the ore cassiterite involves

    (A) carbon reduction of an oxide ore (B) self-reduction of a sulphide ore(C) removal of copper impurity (D) removal of iron impurity

    Ans. (A, D)

    Sol. Important ore of tin is cassiterite (SnO2). SnO2 is reduced to metal using carbon at 1200 1300C in an

    electric furnace. The product often contains traces of Fe, which is removed by blowing air through the

    molten mixture to oxidise FeO. Which then floats to the surface.

    SnO2 + 2C Sn + 2COFe + O2 FeO

    9. The correct statement(s) pertiaining to the adsorption of a gas on a solid surface is (are)

    (A) Adsorption is always exothermic

    (B) Physisorption may transform into chemisorption at high temperature

    (C) Physisorption increases with increasing temperature but chemisorption decreases with increasing

    temperature

    (D) Chemisorption is more exothermic than physisorption, however it is very slow due to higher energy of

    activation.

    Ans. (A, B, D)

    Sol. (A) H = ve for adsorption(B) fact

    (D) chemical bonds are stronger than vander waals forces so chemical adsorption is more exothermic.

    10. According to kinetic theory gases

    (A) collisions are always elastic

    (B) heavier molecules transfer more momentum to the wall of the container

    (C) only a small number of molecules have very high velocity

    (D) between collisions, the molecules move in straight lines with constant velocities.

    Ans. (A, B, C, D)

    Sol. (A) Fact

    (B) P = MV =M

    RT3M = MRT3

    (C) Max well distribution

    (D) Fact

    CHEMISTRY

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    11. Amongst the given options, the compound(s) in which all the atoms are in one plane in all the possible

    conformations (if any), is (are)

    (A) (B) HC

    (C) H2C=C=O (D) H

    2C=C=CH

    2

    Ans. (B, C)

    Sol. In (B) and (C) CH2

    == C == O all atoms are always in same plane.

    SECTION Ill (Total Marks : 15)

    (Paragraph Type)

    This section contains 2 paragraphs. Based upon one of the paragraphs 3 multiple choice questions and

    based on the other paragraph 2 multiple choice questions have to be answered. Each of these questions

    has four choices (A), (B), (C) and (D) out of which ONLY ONE is correct.

    Paragraph for Question Nos. 12 and 14

    When a metal rod M is dipped into an aqueous colourless concentrated solution of compound N the solution

    turns light blue. Addition of aqueous NaCl to the blue solution gives a white precipitate O. Addition of

    aqueous NH3dissolves O and gives an intense blue solution.

    12. The metal rod M is :

    (A) Fe (B) Cu (C) Ni (D) Co

    Ans. (B)

    13. The compound N is :

    (A) AgNO3

    (B) Zn(NO3)

    2(C) Al(NO

    3)

    3(D) Pb(NO

    3)

    2

    Ans. (A)

    14. The final solution contains

    (A) [Pb(NH3

    )4

    ]2+ and [CoCl4

    ]2 (B) [Al(NH3

    )4

    ]3+ and [Cu(NH3

    )4

    ]2+

    (C) [Ag(NH3)

    2]+ and [Cu(NH

    3)

    4]2+ (D) [Ag(NH

    3)

    2]+ and [Ni(NH

    3)

    6]2+

    Ans. (C)

    Sol. (12), (13) & (14)

    Cu(M) + AgNO3 (aqueous colorless solution) Resultant solution (Cu(NO3)2 + AgNO3(N) (blue solution)

    Note : Here it is considered that complete AgNO3 is not utilized in the reaction.

    AgNO3 + NaCl AgCl + NaNO3(O) (white ppt.)

    Solution containing white ppt. of AgCl also contains Cu(NO3)2.

    CHEMISTRY

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    Which developed deep blue colouration with aqueous NH3 solution

    AgCl (white) + 2NH3 (aq.) [Ag(NH3)2]+

    Cu(NO3)2 (aq.) + 4NH3 (aq.) [Cu(NH3)4] (NO3)2(deep blue coloration)

    So, Metal rod M is Cu.

    The compound N is AgNO3 and the final solution contains [Ag(NH3)2]+ and [Cu(NH3)4

    2+

    Paragraph for Question Nos. 15 and 16

    An acyclic hydrocarbon P, having molecular formula C6H

    10, gave acetone as the only organic product

    through the following sequence of reactions, in which Q is an intermediate organic compound.

    15. The structure of compound P is

    (A) CH3CH2CH2CH2

    CC

    H (B) H3CH2C

    CC

    CH2CH3

    (C) (D)

    Ans. (D)

    16. The structure of the compound Q is

    (A) (B)

    (C) (D)

    Ans. (B)

    Sol. (15 & 16)

    CHEMISTRY

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    SECTION - IV (Total Marks : 28)

    (Integer Answer Type)

    This section contains 7 questions. The answer to each of the questions is a single-digit integer,

    ranging from 0 to 9. The bubble corresponding to the correct answer is to be darkened in the ORS.

    17. The difference in the oxidation numbers of the two types of sulphur atoms in Na2S

    4O

    6is

    Ans. 5

    Sol.

    18. Reaction of Br2with Na

    2CO

    3in aqueous solution gives sodium bromide and sodium bromate with evolution

    of CO2gas. The number of sodium bromide molecules involved in the balanced chemical equation is

    Ans. 5

    Sol. 3Br2

    + 3Na2CO

    3 5NaBr + NaBrO

    3+ CO

    2

    19. The maximum number of electrons that can have principal quantum number, n = 3, and spin quantum

    number, ms= 1/2, is

    Ans. 9

    Sol.

    So, electrons with spin quantum number = 2

    1will be 1 + 3 + 5 = 9.

    20. The work function () of some metas is listed below. The number of metals which will show photoelectriceffect when light of 300 nm wavelength falls on the metal is

    Metal Li Na K Mg Cu Ag Fe Pt W

    f (eV)2.4 2.3 2.2 3.7 4.8 4.3 4.7 6.3 4.75

    Ans. 4

    Sol. Ephoton

    =3000

    12400= 4.13 ev

    Photoelectric effect can take place only if Ephoton

    Thus,

    Li, Na, K, Mg can show photoectric effect.

    CHEMISTRY

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    21. To an evacuated vessel with movable piston under external pressure of 1 atm., 0.1 mol of He and 1.0 mol of

    an unknown compound (vapour pressure 0.68 atm. at 0C) are introduced. Considering the ideal gas

    behaviour, the total volume (in litre) of the gases at 0C is close to

    Ans. 7

    Sol. PHe

    = 1 0.68 = 0.32 atm

    V = ?

    n = 0.1 ; V =P

    nRT=

    32.0

    2730821.01.0 = 7

    22. The total number of alkenes possible by dehydrobromination of 3-bromo-3-cyclopentylhexane using alcoholic

    KOH is

    Ans. 5

    Sol.

    Total 5 products.

    23. A decapeptide (Mol. Wt. 796) on complete hydrolysis gives glycine (Mol. Wt. 75), alanine and phenylalanine.

    Glycine contributes 47.0 % to the total weight of the hydrolysed products. The number of glycine units

    present in the decapeptide is

    Ans. 6

    Sol. Molecular weight of decapeptide = 796 g/mol

    Total bonds to be hydrolysed = (10 1) = 9 per molecule

    Total weight of H2O added = 9 18 = 162 g/mol

    Total weight of hydrolysis product = 796 + 162 = 958 g

    Total weight % of glycine (given) = 47%

    Total weight of glycine in product = g100

    47958 = 450 g

    Molecular weight of glycine = 75 g/mol

    Number of glycine molecule =75

    450 = 6.

    CHEMISTRY

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    PART - II

    SECTION - I (Total Marks : 21)(Single Correct Answer Type)

    This section contains 7 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out

    of which ONLY ONE is correct.

    24. A police car with a siren of frequency 8 kHz is moving with uniform velocity 36 km/hr towards a tall building

    which reflects the sound waves. The speed of sound in air is 320 m/s. The frequency of the siren heard by

    the car driver is

    (A) 8.50 kHz (B) 8.25 kHz (C) 7.75 kHz (D) 7.50 kHz

    Ans. (A)

    Sol.

    finisident

    = freflected

    =

    10320

    320

    8 kHz

    fobserved

    =320

    10320 freflected

    = 8 310

    330

    = 8.51 kHz 8.5 kHz

    25. 5.6 liter of helium gas at STP is adiabatically compressed to 0.7 liter. Taking the initial temperature to be T1,

    the work done in the process is :

    (A) 1RT8

    9(B) 1RT

    2

    3(C) 1RT

    8

    15(D) 1RT

    2

    9

    Ans. (A)

    Sol. Number of moles of He =4

    1

    Now T1

    (5.6) 1 = T2

    (0.7) 1

    T1 = T2

    3/2

    8

    1

    PHYSICS

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    4T1

    = T2

    Work done = 1

    ]TT[nR 12

    =

    32

    ]T3[R4

    11

    = 1RT8

    9

    26. Consider an electric field xEE 0

    , where E0

    is a constant. The flux through the shaded area (as shown in

    the figure) due to this field is :

    (A) 2E0a2 (B) 2 E0a

    2 (C) E0a2 (D)

    2

    aE 20

    Ans. (C)

    Sol.

    flux = (E0

    cos 45) area)

    = a2a2

    E0

    = E0a2

    PHYSICS

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    27. The wavelength of the first spectral line in the Balmer series of hydrogen atom is 6561 . The wavelength of

    the second spectral line in the Balmer series of singly ionized helium atom is :

    (A) 1215 (B) 1640 (C) 2430 (D) 4687

    Ans. (A)

    Sol.

    9

    1

    4

    1RZ

    1 2H

    2H= R(1)2

    36

    5

    161

    4

    1RZ

    1 2He

    He= R(4)

    16

    3

    27

    5

    36

    5

    3

    16

    4

    1

    2H

    He

    He = 27

    5

    6561 = 1215

    28. A ball of mass (m) 0.5 kg is attached to the end of a string having length (L) 0.5 m. The ball is rotated on a

    horizontal circular path about vertical axis. The maximum tension that the string can bear is 324 N. The

    maximum possible value of angular velocity of ball (in radian/s) is :

    (A) 9 (B) 18 (C) 27 (D) 36

    Ans. (D)

    Sol. T sin = mLsin2

    324 = 0.5 0.5 2

    2 =5.05.0

    324

    =5.05.0

    324

    = 5.018

    = 36 rad/sec.

    PHYSICS

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    MATHEMATICS29. A meter bridge is set-up as shown, to determine an unknown resistance X using a standard 10 ohm

    resistor. The galvanometer shows null point when tapping-key is at 52 cm mark. The end-corrections are 1

    cm and 2 cm respectively for the ends A and B. The determined value of X is

    (A) 10.2 ohm (B) 10.6 ohm (C) 10.8 ohm (D) 11.1 ohm

    Ans. (B)

    Sol. 1 = 52 + 1 = 53 cm

    2

    = 48 + 2 = 50 cm

    R

    x

    2

    1

    10

    x

    50

    53

    x = 10.6

    30. A 2F capacitor is charged as shown in figure. The percentage of its

    stored energy dissipated after the switch S is turned to position 2 is

    (A) 0%

    (B) 20%

    (C) 75%

    (D) 80%

    Ans. (D)

    Sol. Ui=

    2V)2(

    2

    1, V

    common=

    5

    V

    Uf=

    2

    1(2 + 8)

    2

    5

    V

    100U

    UU

    i

    fi

    = 100V

    5

    VV

    2

    22

    1005

    4

    = 80% Ans.

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    MATHEMATICS

    SECTION II (Total Marks : 16)

    (Multiple Correct Answers Type)

    This section contains 4 multiple choice questions. Each question has four choices (A), (B), (C) and (D)

    out of which ONE or MORE may be correct.

    31. A spherical metal shell A of radius RA

    and a solid metal sphere B of radius RB

    (< RA) are kept far apart and

    each is given charge +Q. Now they are connected by a thin metal wire. Then

    (A) 0EinsideA (B) QA > QB (C)A

    B

    B

    A

    R

    R

    (D) surfaceonB

    surfaceonA EE

    Ans. (A), (B), (C), (D)

    Sol.

    QA

    + QB

    = 2Q ...(i)

    B

    B

    A

    A

    R

    KQ

    R

    KQ ...(ii)

    (i) and (ii) QA = QB

    B

    A

    RR

    & QB

    B

    A

    R

    R1 = 2Q Q

    B=

    B

    A

    R

    R1

    Q2=

    BA

    B

    RR

    RQ2

    & QA

    =BA

    A

    RR

    RQ2

    QA > QB

    2BB

    2AA

    B

    A

    R4/Q

    R4/Q

    =

    A

    B

    R

    Rusing (ii)

    EA

    =0

    A

    & EB

    =0

    B

    A

    < B

    EA

    < EB (at surface)

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    PHYSICS32. An electron and a proton are moving on straight parallel paths with same velocity. They enter a semi-infinite

    region of uniform magnetic field perpendicular to the velocity. Which of the following statement(s) is/are

    true?

    (A) They will never come out of the magnetic field region.

    (B) They will come out travelling along parallel paths.

    (C) They will come out at the same time.

    (D) They will come out at different times.

    Ans. (B), (D)

    Sol.

    tp

    =eB

    m2

    eBv

    vm2

    v

    R2 ppP

    te

    =v

    R)22( e=

    eB

    m)22(

    eBv

    vm)22( ee

    te t

    p

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    PHYSICS

    33. A composite block is made of slabs A, B, C, D and E of different thermal conductivities (given in terms of a

    constant K) and sizes (given in terms of length, L) as shown in the figure. All slabs are of same width. Heat

    Q flows only from left to right through the blocks. Then in steady state

    (A) heat flow through A and E slabs are same

    (B) heat flow through slab E is maximum(C) temperature difference across slab E is smallest

    (D) heat flow through C = heat flow through B + heat flow through D.

    Ans. (A), (C), (D)

    Sol. A : At steady state, heat flow through A and E are same.

    C : T = i R

    i is same for A and E but R is smallest for E.

    D : iB

    =BR

    T

    iC

    =CR

    T

    iD

    =DR

    T

    if ic

    = iB

    + iD

    HenceDBC R

    1

    R

    1

    R

    1

    kA5KA3KA8

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    PHYSICS

    34. A metal rod of length L and mass m is pivoted at one end. A thin disk of mass M and radius R ( B

    A

    < B

    SECTIONIII (Total Marks :15)

    (Paragraph Type)

    This section contains 2 paragraphs. Based upon one of the paragraphs 3 multiple choice questions and

    based on the other paragraph 2 multiple choice questions have to be answered. Each of these questions

    has four choices (A), (B), (C) and (D) out of which ONLY ONE is correct.

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    PHYSICSParagraph for Question Nos. 35 to 37

    Phase space diagrams are useful tools in analyzing all kinds of dynamical problems. They are especially

    useful in studying the changes in motion as initial position and momentum are changed. Here we consider

    some simple dynamical systems in one-dimension. For such systems, phase space is a plane in which

    position is plotted along horizontal axis and momentum is plotted along vertical axis. The phase space

    diagram is x(t) vs. p(t) curve in this plane. The arrow on the curve indicates the time flow. For example, the

    phase space diagram for a particle moving with constant velocity is a straight line as shown in the figure.We use the sign convention in which position or momentum. upwards (or to right) is positive and down-

    wards (or to left) is negative.

    35. The phase space diagram for a ball thrown vertically up from ground is :

    (A)Position

    Momentum

    (B)Position

    Momentum

    (C)Position

    Momentum

    (D)

    Position

    Momentum

    Ans. (D)

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    PHYSICS

    Sol.

    36. The phase space diagram for simple harmonic motion is a circle centered at the origin. In the figure, the

    two circles represent the same oscillator but for different initial conditions, and E1

    and E2

    are the total

    mechanical energies respectively. Then

    (A)21 E2E (B) 21 E2E (C) 21 E4E (D) 21 E16E

    Ans. (C)

    Sol. In 1st case amplitude of SHM is a.

    In 2nd case amplitude of SHM is 2a

    Total energy =2

    1k(amplitude)2

    E1

    =2

    1k(2a)2

    E2

    =

    2

    1k(a)2

    21 E4E

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    PHYSICSAlternative :

    Linear momentum P = mv

    = m 22 xA

    P2 = m22 (A2 x2)

    P2 + (m)2x2 = m22A2 ...(i)

    Equation of circle (bigger)

    P2 + x2 = (2a)2

    P2 + x2 = 4a2 ...(ii)

    Equation of circle (smaller)

    P2 + x2 = a2 ...(iii)

    Comparing (i) and (ii)

    Amplitude A = 2a

    and (m)2 = 1 m2 =m

    1

    22

    )A(m2

    1

    So energy E1

    =22 )a2(m

    2

    1

    = )a4(m

    1

    2

    1 2

    =m

    a2 2

    Comparing (i) and (iii)

    A = a

    (m)2 = 1 m2 =m

    1

    So E2

    =22Am

    2

    1 = 2a

    m

    1

    2

    1 =

    2

    2

    m

    a

    2

    1

    m

    a

    2

    1 2

    So 4E

    E

    2

    1 E1

    = 4E2

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    PHYSICS

    37. Consider the spring-mass system, with the mass submerged in water,

    as shown in the figure. The phase space diagram for one cycle of this

    system is :

    (A)Position

    Momentum

    (B)

    (C) (D)

    Ans. (B)

    Sol. Linear momentum

    P = mv

    =22 xAm

    P2 + m22x2 = m22A2

    represents a circle on Px diagram with radius of circle R = A ( m22 = 1)

    of spring mass system remains constant and equal tom

    k

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    PHYSICSAmplitude of oscillation inside liquid will decrease due to viscous force

    So radius of circular arcs will decrease as position change

    Correctly shown in option B

    Paragraph for Question Nos. 38 and 39

    A dense collection of equal number of electrons and positive ions is called neutral plasma. Certain solids

    containing fixed positive ions surrounded by free electrons can be treated as neutral plasma. Let N be the

    number density of free electrons, each of mass m. When the electrons are subjected to an electric field,

    they are displaced relatively away from the heavy positive ions. If the electric field becomes zero, the

    electrons begin to oscillate about the positive ions with a natural angular frequency p, which is called the

    plasma frequency. To sustain the oscillations, a time varying electric field needs to be applied that has an

    angular frequency , where a part of the energy is absorbed and a part of it is reflected. As approaches

    pall the free electrons are set to resonance together and all the energy is reflected. This is the explanation

    of high reflectivity of metals.

    38. Taking the electronic charge as eand the permitlivity as 0, use dimensional analysis to determine the

    correct expression for p.

    (A)0m

    Ne

    (B) Ne

    m 0(C)

    0

    2

    m

    Ne

    (D) 20

    Ne

    m

    Ans. (C)

    Sol. T

    1

    FL

    QM

    QL

    1

    m

    Ne

    2

    2

    2

    3

    0

    2

    So only (C) is dimensionally correct

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    PHYSICS

    39. Estimate the wavelength at which plasma reflection will occur for a metal having the density of electrons

    N 4 x 1027 m3. Take 0 10111 and m 1030, where these quantities are in proper SI units.s.

    (A) 800 nm (B) 600 nm (C) 300 nm (D) 200 nm

    Ans. (B)

    Sol. For resonance

    = P

    = 1130

    21927

    0

    2

    1010

    )106.1(104

    m

    Ne

    = 3.2 1015

    f =14.32

    102.3

    2

    15

    2

    1 1015

    =f

    c= 15

    8

    102

    1103

    600 nm

    SECTION IV (Total Marks : 28)

    (Integer Answers Type)

    This sections contains 7 questions. The answer to each of the questions is a single-digit integer, ranging

    from 0 to 9. The bubble corresponding to the correct answer is to be darkened in the ORS.

    40. A boy is pushing a ring of mass 2 kg and radius 0.5 m with a stick as shown in the figure. The stick applies

    a force of 2 N on the ring and rolls it without slipping with an acceleration of 0.3 m/s2. The coefficient of

    friction between the ground and the ring is large enough that rolling always occurs and the coefficient of

    friction between the stick and the ring is (P/10). The value of P is

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    PHYSICS

    Sol.

    Note : If net force applied by the rod is considered to be 2 N.

    2Ff 22' ...(i)

    FR f 'R = 2mR2R

    a

    F f ' = 2ma = 1.2 . ..(i i)From (i) & (ii)

    (1.2 + f')2 + f '2 = 22

    2f '2 + 2.4f ' + 1.44 = 4

    f '2 + 1.2f' + 0.72 2 = 0

    f '2 + 1.2f' 1.28 = 0

    f ' =2

    )28.1(444.12.1

    = 0.6 28.136.0

    = 0.6 64.1

    = 0.68

    From eq. (2)

    F = 1.88

    =88.1

    68.0=

    10

    P P = 3.61 4 Ans.

    Note : In Hindi friction force is aksed, so the answer is P = 6.8. (for Hindi)

    Note : But if only normal reaction applied by the rod is considered to be 2 N.

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    PHYSICS

    Law 2 f = 2 [0.3]

    f = 2 0.6

    f - 1.4 Nx ...(i)

    a = R

    0.3 = [0.5]

    = 53

    rad/s ....(ii)

    c

    = c

    fR 2R = mR2

    f 2 = mR

    1.4 2 =2

    2

    5

    3

    1.4 0.6 = 2

    0.8 = 2 = 0.4 = 10

    P

    P = 4 Ans.

    Note : In Hindi friction force is aksed, so the answer is P = 8. (for Hindi)

    41. A block is moving on an inclined plane making an angle 45 with the horizontal and the coefficient of friction

    is . The force required to just push it up the inclined plane is 3 times the force required to just prevent it

    from sliding down. If we define N = 10 , then N is

    Sol.

    F1

    =2

    mg

    2

    mg

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    PHYSICS

    F2

    =2

    mg

    2

    mg

    F1

    = 3F2

    1 + = 3 3

    4 = 2

    =21

    N = 10

    N = 5 Ans.

    42. Four point charges, each of +q, are rigidly fixed at the four corners of a square planar soap film of side

    a.The surface tension of the soap film is . The system of charges and planar film are in equilibrium, and

    a = k

    N/12q

    , wherekis a constant. Then Nis

    Sol. Surface Tension =length

    force

    2

    2

    2

    2

    a2

    kq

    a

    kq22 = 2a

    a = (Some constant)

    3

    12q

    So N = 3 Ans.

    43. Steel wire of length L at 40C is suspended from the ceiling and then a mass m is hung from its free end.

    The wire is cooled down from 40C to 30C to regain its original length L. The coefficient of linear thermal

    expansion of the steel is 105 /C, Youngs modulus of steel is 1011 N/m2 and radius of the wire is 1 mm.

    Assume that L >>diameter of the wire. Then the value of m in kg is nearly.

    Sol.A

    F=y

    L

    L

    )(yA

    mg

    m =g

    )(yr

    g

    )(Ay 2

    =

    10

    101010)10( 51123 = 3

    Ans. 3

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    PHYSICS44. The activity of a freshly prepared radioactive sample is 1010 disintegrations per second, whose mean life is

    109 s. The mass of an atom of this radioisotope is 1025 kg. The mass (in mg) of the radioactive sample is

    Sol. N = N0

    et

    dt

    dN= 1010 = N

    0() t10 9e

    at (t = 0)

    1010 = N0

    109

    N0

    = 1019

    mass of sample = N0

    1025

    = N0

    (mass of the atom)

    = 106 kgm

    = 106 103 gm

    = 103 gm

    = 1 mg

    Ans. 1

    45. A long circular tube of length 10 m and radius 0.3 m carries a current along its curved surface as shown.

    A wire-loop of resistance 0.005 ohm and of radius 0.1 m is placed inside the tube with its axis coinciding

    with the axis of the tube. The current varies as = 0

    cos (300 t) where 0 is constant. If the magnetic

    moment of the loop is N 0

    0sin (300 t), then N is

    Sol. Flux through circular ring

    = (0

    ni) r2

    =20 r

    L

    0cos 300 t

    i =Rdt

    d

    i =RL

    r 02

    0 . sin 300 t 300

    = 00 sin 300 t

    RL

    300.r2

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    PHYSICSM = . r2

    = 0

    0sin 300 t

    RL

    300.r42

    (Take 2 = 10)

    =10100

    3001010 4

    N = 6 Ans.

    46. Four solid spheres each of diameter 5 cm and mass 0.5 kg are placed with their centers at the corners of

    a square of side 4cm. The moment of inertia of the system about the diagonal of the square is

    N 104 kg-m2, then N is

    Sol.

    =

    2MR

    5

    22 + 2MxMR

    5

    2 22

    = 2MR5

    2 2

    + 2MR

    5

    2 2

    + (Mx2) 2

    = 4

    2MR5

    2+ 2mx2

    =2

    MR5

    8

    + 2mx2

    =4

    2

    10)24()5.0(22

    55.0

    5

    8

    =

    8

    5

    5 104

    = 9 104= N 104

    So, N = 9 Ans.

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    MATHEMATICS

    PART - III

    SECTION - I (Total Marks : 21)(Single Correct Answer Type)

    This section contains 7 multiple choice questions. Each question has four choices (A), (B), (C) and (D)out of which ONLY ONE is correct.

    47. Let (x0, y0) be the solution of the following equations

    (2x)n2 = (3y)n3

    3nx = 2ny .

    Then x0 is

    (A)6

    1(B)

    3

    1(C)

    2

    1(D) 6

    Ans. (C)

    Sol. (2x)n2 = (3y)n3

    n2 n(2x) = n3 n(3y) = n3 (n3 + ny) ......... (1)

    also 3nx = 2ny

    nx n3 = ny n2 ......... (2)

    by (1) n2 n(2x) = n3 (n3 + ny) n 2 . n (2x) = n3

    2n

    3nnx3n

    n22 n2x = n23 (n2 + nx)

    3n2n 22 (n2x) = 0

    n2x = 0 x =2

    1

    48. The value of 3n

    2n

    22

    2

    dx)x6nsin(xsin

    xsinx

    is

    (A)4

    1n

    2

    3(B)

    2

    1n

    2

    3(C) n

    2

    3(D)

    6

    1n

    2

    3

    Ans. (A)

    Sol. Put x2 =t

    x dx =2

    dt

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    I = 3n

    2n)t6n(sintsin

    tsin

    .2

    dt......(1)

    apply b

    adx)x(f =

    b

    adx)xba(f

    I =2

    1

    3n

    2ntsin)t6nsin(

    )t6nsin(

    dt .......(2)

    adding (1) and (2)

    2I =2

    1

    3n

    2n

    dt.1

    I = 23

    n4

    1

    49. Let kjia

    , kjib

    and kjic

    be three vectors. A vector

    in the plane of a

    and b

    , whose

    projection on c

    is3

    1, is given by

    (A) k3j3i (B) kj3i3 (C) k3ji3 (D) k3j3i

    Ans. (C)

    Sol. Let

    = ba

    = )( i + )( j + k)(

    Now c. =3

    1

    3

    )()()( =

    3

    1

    =

    = (2+ 1) i j + (2) k

    For 1,

    = k3jl3

    MATHEMATICS

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    50. Let P = { : sin cos = 2 cos } and Q = { : sin + cos = 2 sin } be two sets. Then

    (A) P Q and Q P (B) Q P

    (C) P Q (D) P = Q

    Ans. (D)

    Sol. P = {: sin cos = 2 cos }

    sin = ( 2 + 1) cos

    tan = 2 + 1

    = n+8

    3; n I

    Q = {: sin + cos = 2 sin }

    cos = ( 2

    1) sin

    tan =12

    1= 2 + 1

    = n+8

    3; n I

    P = Q

    51. Let the straight line x = b divide the area enclosed by y = (1 x)2, y = 0, and x = 0 into two parts

    R1 (0 x b) and R2(b x 1) such that R1 R2 = 41

    . Then b equals

    (A)4

    3(B)

    2

    1(C)

    3

    1(D)

    4

    1

    Ans. (B)

    Sol. R1

    = b

    0

    2dx)1x( =

    b

    0

    3

    3

    )1x(=

    3

    1)1b( 3

    also R2

    = 1

    b

    2dx)1x( =

    1

    b

    3

    3

    )1x(=

    3

    )1b( 3

    R1 R

    2=

    3

    1

    3

    )1b(2 3

    4

    1=

    3

    1

    3

    )1b(2 3 (b 1)3 =

    8

    1

    b =2

    1

    MATHEMATICS

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    52. Let and be the roots of x2 6x 2 = 0, with > . If an

    = nn for n 1, then the value of9

    810

    a2

    a2a

    is

    (A) 1 (B) 2 (C) 3 (D) 4

    Ans. (C)

    Sol. x2 6x 2 = 0 having roots and

    2 6 2 = 0

    10 69 28 = 0

    10 28 = 69 .... (i)

    similarly 10 28 = 69 .... (ii)

    by (i) and (ii)

    (10 10) 2(8 8) = 6 (9 9)

    a10

    2a8

    = 6a9

    9810

    a2

    a2a

    = 3

    Aliter

    )(2

    )(299

    881010

    =

    )(2

    )(99

    881010

    =

    )(2

    )()(99

    99

    =2

    =

    2

    6= 3

    53. A straight line L through the point (3, 2) is inclined at an angle 60 to the line 1yx3 . If L also

    intersects the x-axis, then the equation of L is

    (A) y + 3 x + 2 3 3 = 0 (B) y 3 x + 2 + 3 3 = 0

    (C) 3 y x + 3 + 2 3 = 0 (D) 3 y + x 3 + 2 3 = 0

    Ans. (B)

    Sol. Let slope of line L = m

    )3(m1

    )3(m

    = tan 60 = 3 m31

    3m

    = 3

    taking positive sign, m + 3 = 3 3m

    m = 0

    taking negative sign

    m + 3 + 3 3m = 0

    m = 3

    As L cuts x-axis m = 3

    so L is y + 2 = 3 (x 3)

    MATHEMATICS

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    SECTION - II (Total Marks : 16)

    (Multiple Correct Answers Type)

    The section contains 4 multiple choice questions. Each question has four choices (A), (B), (C) and (D)

    out of which ONE or MORE may be correct.

    54. The vector(s) which is/are coplanar with vectors k2ji and kj2i , and perpendicular to the vector

    kji is/are

    (A) kj (B) ji (C) ji (D) kj

    Ans. (A, D)

    Sol. a = i + j + 2 k

    b = i+2 j

    + k

    c = i + j + k

    Required vector is c

    ( a

    b

    )

    [( c

    .b

    ) a

    ( c

    . a

    ) b

    ]

    [(1+2+1) ( i + j +2 k ) (1+1+2) ( i +2 j + k ) ]

    [4 j +4 k ]

    so our vector in parallel j + k

    55. Let M and N be two 3 3 non-singular skew-symmetric matrices such that MN = NM. If PT denotes the

    transpose of P, then M2 N2 (MT N)1 (MN1)T is equal to

    (A) M2 (B) N2 (C) M2 (D) MN

    Ans. (C)

    Sol. Data inconsistent

    A 3 3 non-singular matrix cannot be skew-symmetricHowever considering M, N matrices as even order, we obtain correct answer.

    M2 N2 (MT N)1 (MN1)T = M2N2 N1 (MT)1 (N1)T MT

    M2 N2 N1 M1 N1 M

    M2 NM1 N1 M

    MNN1 M M2

    (So the question is wrong)

    MATHEMATICS

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    56. Let the eccentricity of the hyperbola 2

    2

    a

    x 2

    2

    b

    y= 1 be reciprocal to that of the ellipse x2 + 4y2 = 4. If the

    hyperbola passes through a focus of the ellipse, then

    (A) the equation of the hyperbola is

    3

    x2

    2

    y2= 1

    (B) a focus of the hyperbola is (2, 0)

    (C) the eccentricity of the hyperbola is3

    5

    (D) the equation of the hyperbola is x2 3y2 = 3

    Ans. (B, D)

    Sol. Eccentricity of ellipse =4

    11 =

    2

    3

    2

    2

    a

    b1 =

    3

    2

    a

    b=

    3

    1

    focus of ellipse 0,3

    2

    2

    a

    )3(= 1 a = 3

    b = 1 & focus of hyperbola (2, 0)

    Hence equation of hyperbola

    1

    y

    3

    x 22 = 1

    57. Let f : RR be a function such that f(x + y) = f(x) + f(y), x, y R. If f(x) is differentiable at x = 0, then

    (A) f(x) is differentiable only in a finite interval containing zero

    (B) f(x) is continuous x R

    (C) f(x) is constant x R

    (D) f(x) is differentiable except at finitely many points

    Ans. (B, C)

    Sol. f(x) = kx

    Hence f(x) is continuous & differentiable at x R & f(x) = k (constant)

    MATHEMATICS

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    SECTION - III (Total Marks : 15)

    (Paragraph Type)

    This section contains 2 paragraphs. Based upon one of the paragraphs 3 multiple choice questions and

    based on the other paragraph 2 multiple choice questions have to be answered. Each of these questions

    has four choice (A), (B), (C) and (D) out of which ONLY ONE is correct.

    Paragraph for Questions Nos. 58 to 60

    Let a, b and c be three real numbers satisfying

    [a b c]

    737

    728

    791

    = [0 0 0] ...........(E)

    58. If the point P(a, b, c), with reference to (E), lies on the plane 2x + y + z = 1, then the value of 7a + b + c is

    (A) 0 (B) 12 (C) 7 (D) 6

    Ans. (D)

    59. Let be a solution of x3 1 = 0 with m () > 0. if a = 2 with b and c satisfying (E), then the value of

    a

    3

    + b

    1

    + c

    3

    is equal to

    (A) 2 (B) 2 (C) 3 (D) 3

    Ans. (A)

    60. Let b = 6, with a and c satisfying (E). If and are the roots of the quadratic equation ax2 + bx + c = 0,

    then

    n

    0n

    11

    is

    (A) 6 (B) 7 (C)7

    6(D)

    Ans. (B)

    Sol. (Q.No. 58 to 60)

    a + 8b + 7c = 0 . .. ... .. ... ( i)

    9a + 2b + 3c = 0 ........... (ii)

    a + b + c = 0 ........... (iii)

    =111329 781 = 1.(1) 8(6) + 7(7) = 0

    MATHEMATICS

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    J10411Page # 38

    Let C =

    a + 8b = 7

    a + b =

    b =7

    6 & a =

    7

    (a, b, c) ,

    76,

    7where R

    58. P(a, b, c) lies on the plane 2x + y + z = 1

    7

    6

    7

    2= 1

    7

    = 1 = 7

    7a + b +c = 7 + 6 7 = 6

    59. a = 2 = 14

    b = 12 & c = 14

    Now cba313

    =

    14

    122.3

    13

    = 3 + 1 + 32 = 3(+2) + 1 = 2

    60. b = 6 = 7

    a = 1 & c = 7

    now ax2 + bx + c = 0 x2 + 6x 7 = 0

    x = 7 , 1

    n

    0n

    11

    =

    n

    0n76

    = 1 +7

    6+

    2

    7

    6

    + ....... =

    7

    61

    1

    = 7

    Paragraph for Question Nos. 61 and 62

    Let U1 and U2 be two urns such that U1 contains 3 white and 2 red balls, and U2 contains only 1 white ball.A fair coin is tossed. If head appears then 1 ball is drawn at random from U1 and put into U2. However, if tail

    appears then 2 balls are drawn at random from U1 and put into U2. Now 1 ball is drawn at random from U2.

    61. The probability of the drawn ball from U2 being white is

    (A)30

    13(B*)

    30

    23(C)

    30

    19(D)

    30

    11

    Ans. (B)

    Sol. P(white) = P (H white) + P(T white)

    =

    32

    CCC

    31

    CC1

    CC

    21

    21

    521

    53

    21

    25

    1213

    25

    22

    25

    23

    MATHEMATICS

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    J10411Page # 39

    =

    30

    12

    30

    1

    10

    3

    2

    1

    10

    8

    2

    1

    =30

    22

    2

    1

    10

    4

    =30

    23

    62. Given that the drawn ball from U2 is white, the probability that head appeared on the coin is

    (A)23

    17(B)

    23

    11(C)

    23

    15(D)

    23

    12

    Ans. (D)

    Sol. WhiteHead

    P = )white(P

    )whiteHead(P

    =

    30

    23

    2

    1

    5

    21

    5

    3

    2

    1

    =

    30

    2310

    4

    =23

    12

    SECTION - IV (Total Marks : 28)

    (Integer Answer Type)

    This section contains 7 questions. The answer to each of the questions is a single-digit integer, ranging

    from 0 to 9). The boubble corresponding to the correct answer is to be darkened in the ORS.

    63. Consider the parabola y2 = 8x. Let 1 be the area of the triangle formed by the end points of its latus rectum

    and the point

    2,

    2

    1P

    on the parabola, and 2 be the area of the triangle formed by drawing tangents at P

    and at the end points of the latus rectum. Then2

    1

    is

    Ans. (2)

    Sol. 2 = 21

    (by property)

    2

    1

    = 2

    MATHEMATICS

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    64. Let a1, a2, a3,....., a100 be an arithmetic progression with a1 = 3 and Sp =

    p

    1i

    ia , 1 p 100.

    For any integer n with 1 n 20, let m = 5n. Ifn

    m

    S

    Sdoes not depend on n, then a2 is

    Ans. (9)

    Sol.n

    m

    S

    S=

    n

    n5

    S

    S=

    ]d)1n(6[2

    n

    ]d)1n5(6[2

    n5

    =]nd)d6[(

    ]nd5)d6[(5

    d = 6 or d = 0 Now if d = 0 then a2 = 3 else a2 = 9

    for single choice more appropriate choice is 9, but in principal, question seems to have an error.

    a2 = 3 + 6 = 9

    65. The positive integer value of n > 3 satisfying the equation

    n

    3sin

    1

    n

    2sin

    1

    nsin

    1is

    Ans. (n = 7)

    Sol.

    nsin

    1

    n

    3sin

    1

    =

    n

    2sin

    1

    n

    3sin

    nsin

    nsin

    n

    2cos2

    =n

    2sin

    1

    sinn

    4= sin

    n

    3

    n

    4= (1)k

    n

    3+ k , k

    If k = 2m n

    = 2m

    n

    1= 2m , not possible

    If k = 2m + 1 n

    7= (2m + 1)

    n = 7, m = 0

    Ans. n = 7

    MATHEMATICS

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    J10411Page # 41

    66. Let f : [1, ) [2, ) be a differentiable function such that f(1) = 2. If

    x

    1

    3x)x(xf3dt)t(f6

    for all x 1, then the value of f(2) is

    Ans. (6)

    Sol. Data inconsistent.

    Putting x = 1 , in given integral equation f(1) = 1/3 , a contradiction (given that f(1) = 2).

    However if considering integral equation as x

    1

    3x)x(xf3dt)t(f6 5

    we obtain correct answer.

    Differentiating the integral equation

    6f(x) = 3f(x) + 3xf(x)

    3x2

    f(x) x

    1f(x) = x

    put y = f(x)

    dx

    dy

    x

    1y = x

    I.F. =x

    1

    General solution is yx

    1= x + c

    Put x = 1, y = 2 c = 1

    y = x2 + x

    f(x) = x2 + x

    f(2) = 4 + 2 = 6

    67. If z is any complex number satisfying |z 3 2i| 2, then the minimum value of |2z 6 + 5i| is

    Ans. (5)

    Sol. |2z 6 + 5i| = 2

    2

    i53z

    for minimum = 2 2

    5= 5

    MATHEMATICS

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    J10411Page # 42

    68. The minimum value of the sum of real numbers a5, a4, 3a3, 1, a8 and a10 where a > 0 is

    Ans. (8)

    Sol. A.M. G.M.

    8/1

    108

    33345

    108

    33345

    a.a.1.a

    1.

    a

    1.

    a

    1.

    a

    1.

    a

    1

    8

    aa1a

    1

    a

    1

    a

    1

    a

    1

    a

    1

    8/1108

    345)1(8aa1

    a

    3

    a

    1

    a

    1

    minimum value of103

    345aa1

    a

    3

    a

    1

    a

    1 = 8, at a = 1

    69. Let f() =

    2cos

    sintansin 1 , where

    4