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    2

    PART A : MATHEMATICS

    SECTION I

    Straight Objective Type

    Th is s ect ion con t a in s 9 m ult iple ch oice q u es tion s n um ber ed 1 t o 9. E a ch q u es tion h a s

    4 choices (A), (B ), (C) a nd (D ), out of w hich ON LY ONE is corr ect.

    1. The int egra l va lues of x for w hich x2+ 5x + 8 is a perfect squa re are

    (A)4 and 5 (B)4 and 1 (C)1 and 4 (D)4 and 5

    2. The proba bilit y t ha t t he lengt h of a ra ndomly chosen chord of a circle lies

    between1

    2a nd

    4

    5of its dia meter is

    (A)2

    5(B)

    5

    6(C)

    36

    100(D)

    39

    100

    3. I f , 2be the imagina ry cube roots of unity , then

    (100 + 100+ 1022)6(50 + 55+ 50

    2)3is equa l to

    (A)61 (B)0 (C)61 (D)16

    4. The va lue of k if the eq ua tions x2

    + 3x + 4k = 0 a nd 2x2

    + 5x + 7k = 0 ha ve a

    comm on root is

    (A)1 (B)1 (C)2 (D)2

    5. In a n A.P. of 93 term s, th e 47th t erm is 25. Then t he sum of series is

    (A)6225 (B)5065 (C)9325 (D)2325

    6. I n a n exa m in a t ion t her e a r e 10 m ult iple ch oice q uest ion s a n d ea ch q uest ion h a s4 choices. Number of w a ys in w hich a stud ent can fa il to get a ll answ ers correct is

    (A)1142 (B)4

    101 (C)10

    41 (D)10

    44

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    7. I f P a nd Q a re sq ua re ma trices of sa me order such tha t (P + Q)2

    = P2

    + Q2

    + 2P Q,

    then

    (A)P = Q (B)P = Q (C)P Q = QP (D)P = Q

    8. If A, B, C be three equally and collectively exhaustive events and the odds are 5 : 2a gainst A, 7 : 3 a gainst B , then the odds aga inst C is

    (A)41 : 29 (B)53 : 70 (C)41 : 70 (D 23 : 70

    9. The solution of the differential equation 1 y2 x e t a n1

    y dy

    dx= 0 is

    (A) x 2 = ket a n

    1y (B)2xe

    t a n1

    y= e

    2 t a n1

    y k

    (C)xet a n

    1y

    = t a n1

    y k (D)xe2 t a n

    1y

    = et a n

    1y k

    SECTION II

    Reasoning Type

    This sect ion cont a ins 4 q uest ions numbered 10 t o 13. E ach q uest ion conta ins

    STATEMENT 1 (Assertion) and STATEMENT 2 (Reason). Each question has 4 choices

    (A), (B), (C) and (D), out of which ONLY ONE is correct.

    (A) S t a t ement 1 is True, st a t ement 2 is True; st a tement 2 is a correctexpla na tion for sta tement 1.

    (B) S t a tement 1 is True, st a tement 2 is True; st a tement 2 is not a cor rectexpla na tion for sta tement 1.

    (C) St a tement 1 is True, sta tement 2 is False.

    (D) St a tement 1 is False, sta tement 2 is True.

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    SECTION III

    Linked Comprehensive Type

    Th is sect ion con ta in s 2 pa r a gr a ph s. B a sed u pon ea ch pa r a gr a ph , 3 mult iple ch oice

    qu estions ha ve to be a nsw ered. E a ch quest ion h a s 4 choices (A), (B ), (C) an d (D), out ofw hich ONLY ONE is correct.

    Paragraph for Question Nos. 14 to 16

    Let O be t he or th ocen tr e. S in ce AD B C, B E C A, a n d

    CF AB , th en OA BC , OB CA a nd OC AB .

    Solving an y t w o of these, we can get coordina tes of O.

    I f the sides of t he t r ia ngle a re given , t hen find t he

    eq ua t ions of the line perpendicula r to t hese t wo sides a nd

    pa s sin g t h rou gh t h e oppos it e v er t ices . S olv e t h ese eq u a t ion st o g et t h e coor din a t es of t h e or t hocen t re a n d cen t roid d iv id es

    th e line joining t he orthocentre a nd circumcentre in th e ra tio 2 : 1.

    14.The coordinates of the orthocentre of the triangle having vertices (0, 0), (2, 1) and(1, 3) a re

    (A)1

    5,

    2

    5(B)

    3

    5,

    6

    5(C)

    6

    5,

    3

    5(D)

    2

    5,

    1

    5

    15.Th e coor din a tes of t he or th ocen tr e of t he t ria n gle for med by t he lin es xy = 0 a n d

    y = 1 x are

    (A)(0, 0) (B)(2, 1) (C)(2, 1) (D)(1, 2)

    16. I f a t ria ngle h as it s ort hocen tre a t (2, 3) a nd circumcen tre a t5

    6,

    7

    8, t hen the

    coordina tes of the centroid of th e tria ngle is

    (A)12

    11,

    9

    19(B)

    9

    11,

    12

    19(C)

    19

    12,

    11

    9(D)

    11

    9,

    19

    12

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    Paragraph for Question Nos. 17 to 19

    I nt egr a ls of t he for m f x , a x2 bx c dx ca n be eva lua ted w ith t he help ofthe E uler s substit utions. There a re norma lly 3 Eulers substitutions.

    1. F irs t Eu ler s substitu tion: If a > 0, we put a x2 bx c = t x a

    or a x2+ bx + c = t

    2+ a x

    22t x a or bx c = t

    2 2t x a .

    2. Second E uler s substit ution: If c > 0, we put a x2 bx c = t x c

    or a x + b = t2x 2t c.

    3. Th ir d E u ler s subst it ut ion : I f t he t rin omia l a x2

    + bx + c ha s rea l roots a nd

    tha t i s ax2+ b x + c = a (x ) (x ), th en w e put a x

    2 bx c = x t

    or (x )t .

    17.To eva lua te the integra l dxx 4x

    2 2x 8

    , a good substit ut ion is 4x2 2x 8 =

    (A)t 4x (B)t 8x (C)t 2x (D)t 32x

    18.The value of the integral

    dx

    x 1 x2 6x 5

    is

    (A)1

    2

    x 5

    1 xC (B) 2

    x 5

    1 xC

    (C)1 x

    x 5C (D)

    1

    2

    1 x

    x 5 C

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    PART B : PHYSICS

    SECTION I

    Straight Objective Type

    Th is sect ion con ta in s 9 m ult iple ch oice q uest ion s n um ber ed 23 t o 31. E a ch q uest ion

    ha s 4 choices (A), (B), (C) a nd (D ), out of w hich ONL Y ONE is corr ect.

    23.An a irplane is flying in a horizont a l circle a t a speed of 540 km/h. B a nked for th is

    t urn , t he w ings of the pla ne a re t ilted a t a n a ngle 45 fr om t he h or izon ta l.

    Assume t ha t a lift force a ct ing perpendicula r t o t he w ings holds t he a ircra ft in

    th e sky. The ra dius of t he circle in w hich t he pla ne is flyin g is (Ta ke g = 10 m/s2

    )

    (A)1000 m (B)2250 m (C)500 m (D)4500 m

    24.The ra t io of number of a toms of14

    C t o12

    C in living ma tter is mea sured to be

    1.3 10 12

    a t t h e pr es en t t im e. A 12 g s a mple of ca r bon pr od uces 180 d eca y s/m in

    due to the small a mount of14

    C in it. The ha lf-life of14

    C is nearly

    [1 year = 3.15 107s ]

    (A)574 year s (B)5740 year s (C)2870 year s (D)287 year s

    25.A r ocket is in ou ter spa ce, fa r fr om a n y pla n et , w h en t he r ocket en gin e is t ur ned

    on . I n t he fir st secon d of fir in g, t he r ocket eject s 1

    120of it s ma ss w it h a rela tive

    speed of 2400 m/s. The r ocket s in it ia l a ccelera ti on is

    (A)20 m /s2 (B)30 m/s

    2 (C)40 m /s

    2 (D)50 m/s

    2

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    26.Tw o sq ua r e con du ct in g pla t es w it h sides of len gt h L a r e sepa r a t ed by a dist a n ce

    D . A dielect ric sla b w ith const ant k w ith dimensions L L D is insert ed a

    dist a nce x in to t he spa ce bet w een t he pla t es. A con st a nt pot en tia l differ en ce V

    betw een t he pla tes is ma in ta ined by connect ing a ba t t ery to the pla tes. I f t he

    d ielect r ic is in ser ted a n a d dit ion a l d is ta n ce d x in t o t h e s pa ce bet w een t h e pla t es ,

    th e cha nge in stored energy is

    (A)

    0V

    2dx

    2 (B)

    k0

    L2

    V2

    dx

    2 D

    (C)

    k 1 0

    L V d x

    D (D)

    k 1 0

    V2

    L dx

    2 D

    27.Tw o poin t ch a r ges q 1

    = 2 C a nd q 2

    = 2 C a re loca t ed a t x = 0, y = 0.3 m a nd

    x = 0, y = 0.3 m respect ively . Th e n et elect ric force on a t hird poin t ch a rge

    Q = 4 C a t x = 0.4 m, y = 0 is

    (A)(0.46 N) i (B)(0.34 N) j

    (C)(0.34 N) j (D)(0.46 N) i

    28.A diverging lens a nd a n object a re posit ioned a s

    sh ow n in t he Figure a t left . Which of t he ra ys a , b,

    c a nd d could ema na te from poin t Q a t t he top of

    t he object ?

    (A)a , b and c (B)a a n d c

    (C)a a nd b (D)a l l

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    29.The int ensit y a t a ny poin t in t he interference pa ttern is I = I0

    5

    9

    4

    9cos ,

    where is the pha se difference betw een the tw o w a ves a s mea sured a t a

    pa rt icula r point on t he screen a nd I0

    is t he ma ximum in tensit y in t he pa t tern .

    Then t he ra tio of the a mplitud es of the w a ve from th e tw o slits is

    (A)5

    4or

    5

    4(B)

    1

    3or 3 (C)2 or

    1

    2(D)

    1

    5or 5

    30.A pia n o t un er st ret ch es a st eel pia n o w ir e w it h a t en sion of 800 N. Th e st eel w ir eis 0.4 m long a nd ha s a ma ss 2 g. Th e number of t he highest ha rmonic t ha t could

    be heard by a person w ho is ca pable of hea ring frequencies up to 104Hz is

    (A)100 (B)150 (C)50 (D)20

    31.Th e engine of a sport s ca r t akes in a ir a t 27C a n d 1 a t m os ph er e a n d com pr es ses

    it a dia ba t ica lly t o 0.09 t imes t he origina l volume. The a ir ma y be t rea ted a s a n

    idea l ga s w i th = 1.5. The fina l temperat ure of the ga s is

    (A)1000 K (B)900 K (C)300 K (D)100 K

    SECTION II

    Reasoning Type

    This sect ion cont a ins 4 q uest ions numbered 32 t o 35. E ach q uest ion conta ins

    STATEMENT 1 (Assertion) and STATEMENT 2 (Reason). Each question has 4 choices(A), (B ), (C) a nd (D ), out of wh ich ONL Y ONE is corr ect.

    (A) S t a t ement 1 is True, sta t ement 2 is True; st a tement 2 is a correctexplan a tion for sta tement 1.

    (B) S t a tement 1 is True, sta tement 2 is True; st a tement 2 is not a cor rectexplan a tion for sta tement 1.

    (C) St a tement 1 is True, sta tement 2 is False.

    (D) St a tement 1 is False, sta tement 2 is True.

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    32.Statement 1: Cy clotron frequ ency does n ot depend on speed of cha rged pa rticle

    and

    Statement 2: K in et ic en er gy of ch a r ged pa r t icle in cy clot r on is in depen den t of

    its cha rge.

    33.Statement 1: According t o Lenz s la w of electroma gnetic induction, t he inducede.m.f is in t he direction opposing t he cha nge in ma gnet ic flux

    and

    Statement 2: If t he flux is increa sing sod

    B

    dtis positive, th en th e induced e.m.f

    or current is nega tive.

    34.Statement 1: I n You ngs dou ble slit in terfer en ce pa t t er n t he fr in ge w id th is a

    universal consta nt

    and

    Statement 2: The fringe w idth ca n be cha nged eit her by cha nging thewa velength or by cha nging the sepa ra tion between the tw o sli ts .

    35.Statement 1: Th e a n gu la r momen tum of a n elect ron m ovin g in a st a ble orbita round t he nucleus is qua ntised

    and

    Statement 2: E ach elect ron in a n a tom w ill exist only w it h certa in specificva lue of energy.

    SECTION III

    Linked Comprehension Type

    Th is sect ion con ta in s 2 pa ra gra ph s. B a sed u pon ea ch pa r agra ph , 3 mult iple ch oice

    qu estions ha ve to be a nsw ered. Ea ch quest ion h a s 4 choices (A), (B ), (C) an d (D ), out of

    w hich ONLY ONE is correct.

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    Paragraph for Question Nos. 36 to 38

    An eleva t or of 2000 kg w it h broken ca bles is fa llin g a t 4 m/s a n d it is st opped by a

    spring a t t he bot t om of the sha ft . The spring is supposed to st op the eleva tor ,

    compressing 2 m. D uring t he mot ion a sa fety cla mp a pplies a consta nt 17000 N

    frictiona l force to th e elevat or.

    36. Init ia l tota l mecha nica l energy is

    (A)21.2 103J (B)16 10

    3J

    (C)18 103J (D)16 10

    3J

    37.The force consta nt of the spring is n ea rly

    (A)104N/m (B)10

    3N/m (C)10

    2N/m (D)10 N /m

    38. I f t her e is n o sa fet y cla m p a t t he bot t om , t hen w h ich of t he follow in g st a t em en t iswrong ?

    (A)There must be a n et upw a rd force 1600 N on th e eleva tor.

    (B)The elevation would bounce back upward.

    (C)There must be a net down w a rd force 1600 N on th e elevat or.

    (D)There is no energy loss d ue t o frictiona l force.

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    SECTION IV

    Matrix-Match Type

    Th is sect ion con ta in s 3 q uest ion s. E a ch q uest ion con ta in s st a temen ts given in t w o

    column s w hich ha ve t o be ma tch ed. S ta temen ts (A, B , C , D ) in Column I ha ve t o bema tched w ith sta tement s (p, q , r , s) in Column II . Th e a n sw ers t o t hese q uest ion sha ve to be a ppropriat ely bubbled as illustra ted in th e follow ing example.

    I f t he correct ma tches a re A-p, A-s, B -q , B -r , C -p, C -q a nd D -s, t hen t he correct ly

    bubbled 4 4 ma trix should be as follows:

    p q r s

    A p q r s

    B p q r sC p q r s

    D p q r s

    42. Column I Column II

    (A) Electrosta tic field (p) Conservat ive field

    (B) In duced electr ic field (q) Lin es of force open

    (C) Magnetic field (r) Non -conservative field

    (D) Electromagnetic field (s) Lin es of force closed

    43. Column I Column II

    (A) A solid cylinder is rolling dow n (p) the frictional force is dissipative

    a n inclined pla ne of inclina tion

    (B) A block is sliding d own a n (q) t he frictiona l force is zero

    inclined plane of inclination

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    (C) A solid cylinder is r olling w ith out (r) th e frictiona l force w ill aidslipping in th e horizonta l surfa ce rota tion but hinder tra nsla tion

    (D) A solid rin g is rolling on t he horizonta l (s) th e frictiona l force is cha nged ifsurfa ce a nd externa l force F is a pplied a ngle of plane is cha nged

    a t th e topmost of a ring

    44.A w ire a long t he x-a xis ca rr ies a current of 2 A in t he nega t ive direct ion . Th e

    force on 1 cm section of th e wir e exert ed by t hese ma gnet ic fields

    (a) B1

    = 0.8 T j T,

    (b) B2

    = 0.2 i 0.3 j 0.3 k T

    (c) B

    3

    = 0.8 j 0.4 k T

    (d) B4

    = 0.4 i T

    are F1, F

    2, F

    3a nd F

    4r espectively.

    Then match Column I w ith th ose in Column II .

    Column I Column II

    (A) F

    3

    (p) 0.2 10 2

    3 j 5 k

    (B) F4

    (q) 0.2 10 2

    j 3 k

    (C) Force due to a ll ma gnetic (r) 8 10 3

    j 2 k N

    fields B1, B

    2, B

    3and B

    4, F

    (D) Force due t o mag netic fields (s) zero

    B1and B

    2, F

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    PART C : CHEMISTRY

    SECTION I

    Straight Objective Type

    Th is s ect ion con t a in s 9 m ult iple ch oice q u es tion s n um ber ed 45 t o 53. E a ch q u est ion

    has 4 choices (A), (B), (C) and (D), out of which ONLY ONE is correct.

    45.The pH a t w hich Mg(OH )2

    st a rt s precipit a t ing from a solut ion cont a in ing

    1 10 3

    M Mg2+

    ions is (Ksp

    Mg(OH )2= 1 10

    11)

    (A)3.8 (B)9.0 (C)6.9 (D)10

    46. In a redox reaction one molecule of KN O3ga ins 3 electr ons. The product w ill be

    (A)N O2 (B)N

    2O

    5 (C)N

    2O (D)N O

    47.C on sid er t h e r ea ct ion : 2N2O

    5 4N O

    2+ O

    2. Th e r a te con st a n t for t he r ea ct ion

    is 3.2 10 5

    s 1

    . The ra te of t he rea ct ion is 2.4 10 5

    mol L 1

    s 1

    . Th e mola r

    concentr a tion of N2O

    5is

    (A)0.875 (B)0.75 (C)0.4375 (D)0.375

    48.The product P in th e rea ction, is

    (A)(+ ) 2-B romosuccinic a cid (B)Meso-dibromosuccinic acid

    (C)() Dibromosuccinic acid (D)() 2-B romosuccinic a cid

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    49.(CH3)3C Mg B r + D

    2O P roduct. The product is

    (A)(C D3)3C OD (B)(C D

    3)3C D

    (C)(C H 3)3C D (D)(C H 3)3C OD

    50.Nucleophilic a ddit ion is most fa voured in

    (A)C H3C H O (B)C H

    3C H

    2C H O

    (C) (D)

    51.O3(I); N

    O2(II ); CO

    2(III); N

    3

    (IV)

    Among th e a bove species, those ha ving similar sha pe are

    (A)(I) an d (II ) (B)(II I) an d (IV)

    (C)(I), (II ) an d (III ) (D)(II), (II I) a nd (IV)

    52.The correct decreas ing order of bond energy a mong ha logens is

    (A) F2> C l2> B r2> I2 (B)C l2> F2> B r2> I2

    (C) C l2> B r

    2> F

    2> I

    2 (D)C l

    2> F

    2> I

    2> B r

    2

    53.The correct in crea sing order of bond a ngle is

    (A) C lO2< OF

    2< C l

    2O < H

    2O (B)C lO

    2< C l

    2O < H

    2O < OF

    2

    (C) OF2< H

    2O < Cl

    2O < ClO

    2 (D)OF

    2< C l

    2O < H

    2O < ClO

    2

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    SECTION II

    Reasoning Type

    This sect ion cont a ins 4 q uest ions numbered 54 t o 57. E ach q uest ion conta ins

    STATEMENT 1 (Assertion) and STATEMENT 2 (Reason). Each question has 4 choices

    (A), (B ), (C) a nd (D ), out of wh ich ONL Y ONE is corr ect.

    (A) Statement 1 is True, statement 2 is True; statement 2 is a correct explanationfor sta tement 1.

    (B) S t a tement 1 is True, sta tement 2 is True; st a tement 2 is not a cor rectexplan a tion for sta tement 1.

    (C) St a tement 1 is True, sta tement 2 is False.

    (D) St a tement 1 is False, sta tement 2 is True.

    54.Statement 1: The complex [Co(NH3

    )6

    ]3+

    w ill be pa ra ma gnetic.

    and

    Statement 2: Coba lt (Z = 27) ha s a n odd num ber of electrons in its dsub sh ell.

    55.Statement 1: D urin g isot herma l expa n sion of a n idea l ga s in to va cuum, h ea ta bsorbed is zero.

    and

    Statement 2: Idea l ga s molecules occupy zero volume.

    56.Statement 1: For ma ny rea ct ion s, t he ra t e of t he rea ct ion doubles for every

    10C r ise of temperat ure.and

    Statement 2: The energy of a ct iva t ion ra pidly decrea ses w it h rise oftemperature.

    57.Statement 1: H y dr oly sis of R C l is slow but t a kes pla ce fa st er in presen ce of

    a l i t t le qua nti ty of added KI.

    and

    Statement 2: I

    is a wea ker nucleophile and a better leaving group tha n C l

    .

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    Paragraph for Question Nos. 61 to 63

    For the reaction, 2A + B22AB , the follow ing da ta w ere obta ined.

    Experiment [A] mol L

    1

    [B2] mol L

    1

    Initial Rate

    1 0.50 0.50 1.75 10 3

    2 0.50 1.00 3.5 10 3

    3 1.00 1.00 3.5 10 3

    61.Order wit h respect t o A a nd B2a re, respectively

    (A)2, 1 (B)1, 1 (C)0, 1 (D)1, 0

    62.Ra te consta nt for the reaction is

    (A)1.75 103

    (B)3.5 103

    (C)1.75 104

    (D)3.5 104

    63. In it ia l ra te if t he concent ra tion of A is 2 mol L 1

    a n d con cen tr at ion of B2

    is

    2 mol L 1

    i s

    (A)3.5 103 (B)1.75 103 (C)7.0 103 (D)3.5 104

    SECTION IV

    Matrix-Match Type

    Th is sect ion con ta in s 3 q uest ion s. E a ch q uest ion con ta in s st a temen ts given in t w o

    column s w hich ha ve t o be ma tch ed. S ta temen ts (A, B , C , D ) in Column I ha ve t o bema tched w ith sta tement s (p, q , r , s) in Column II . Th e a n sw ers t o t hese q uest ion sha ve to be a ppropriat ely bubbled as illustra ted in th e follow ing example.

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    I f t he correct ma tches a re A-p, A-s, B -q , B -r , C -p, C -q a nd D -s, t hen t he correct ly

    bubbled 4 4 ma trix should be as follows:

    p q r s

    A p q r sB p q r s

    C p q r s

    D p q r s

    64. Column I Column II

    (A) XeF4 (p)sp

    3d

    2

    (B) I3

    (q) sp

    3d

    (C) XeF2 (r) 2 lone pairs on centr a l a tom

    (D) B rF4

    (s) 3 lone pairs on centr a l a tom

    65. Column I Column II

    (A) S O2a t 0 .5 a t m and 0C (p) Z 1

    (B) NH3a t 0.001 a tm a nd 1000C (q) P(V nb) = nRT

    (C) H e ga s a t P 0, 0C (r) S trong int ermolecular at tra ctive forces

    (D) He gas a t P = 200 a t m, 0C (s) P V = n RT

    66. Column I Column II

    (A) Sucrose (p)Glycosidic linkage

    (B) Maltose (q) Reducing

    (C) Starch (r) Non -reducing

    (D) Protein (s) Na tura l polymer

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