B U R N PIT CHEMICAL P R O F I L E (PHASEE

M P R $_1 -05-7

PROPOSED EFFORT TO BE PERFORMED BY :

SSFL ANALYTICAL CHEMISTRY UNIT, M & P

Submitted by

0

Approved :

Approved

Material s & Produci bi l i ty

r Q"N . u. i cawa, agerSSFL Analytical C emis ryAdv . Mat . A Mfg. echrology

Lie ,ManagerMat . & Mfg . Technology

Materials & Produclbility

D . l.a Fulton , DirectorMaterials & Producibility

I I II I II II I I II I I I II IBNA03472432

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HDMSe00042882

BURN PIT CHEMICAL PROFILE (PHASE I

Reference :

Bjorklund letter to Regional Water Quality Control Board, 4 March 198 1

(81RC0236411, Re : Inactive Burning and Disposal Site (" Burn Pit" )

SUMMARY

This work plan delineates in detail how the site will be examined on a "firs tpass" basis to appropriately estimate the level of effort that will be required

for Phase II, the rigorously conducted sampling and analysis according to the

guidelines established in the EPA manual of test procedures covering such situa-

tions "Test Methods for Evaluating Solid Wastes ", (SW-846, 1980 ), published by

the Office of Water and Waste Management . This work plan also recommends the use

f various other technical disciplines (geologist , ground water specialist) an d

other laboratory services ( Pacific Spectrochemical , West Coast Technical Services ,

Rockwell Environmental Monitoring Center ) as well as literature reviews on appr o

prieteactivities and consulting firms that Rocketdyne may wish to consider . Inaddition, this presentation includes the labor estimate for this assignment a s

well as the capital equipment that may be required for Phase 11 . A p-oposed wor k

schedule is submitted with targeted completion dates to provide flexibility ac-

cording to the chemicalanalysis results .

BACKGROUND

General Site History

The "Burn Pit" site was established in approximately 1958 for the safe disposal

of chemical fuels by Combustion in order to minimize potential public exposure

which could result from transport across public highways to dispose in a conven-

tional landfill . This site was operated by qualified Rocketdyne Protective

Services personnel until 1971 . At that time, the site was closed because of air

pollution considerations . Since its closure, the site has been essentially in-

active with the exception of afew fire department demonstrations and training

1

I I II I IIII 1111111111111111 nBNA03472433

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HDMSe00042883

exercises to maintain their proficiency in dealing with chemical fires and

emergency incidents .

Site Descripti on

Located in Rocketdyne's 2,400-acre Santa Susan Test Facility (SSFL) is a six-

acre area which is referred to as the "Burn Pit" . Within the bounds of the

six-acre area are six pits which range in volume from approximately 200 gallons

to 10,000 gallons . Of these six pits, three of them are lined with concrete and

three unlired earthen pits . The enclosed maps give the geographic location

topography, draining outfalls and a rough plan of the "Bur n

Area Water Run Off

P t

A preliminaty review of the water runoff has led the Rocketdyne Environmenta l

Control Office to believe that no dischargeable hazardous residues resulted

from the combustion processes . Routine sampling at the adjacent perimeter pon d

has not shown any unusual concentrations of any of the substances required to b e

sampled by the current NPDES permit (expiration date = August 31, 1981) .

believed, therefore, that surface runoff is not the problem .

It is

Ground Wa ter

The Rocketdyne SSFL is serviced by one well which is maintained by Rocketdyne .

Two additional wells are planned to be brought on line in six (6) months . None

of these wells are located near the burn pit area and are upgradient . Rocketdyne

believes that there has been no ground water contamination resulting from the

past activities in the burn pit area . This conclusion is based on an evaluation

of the type of the cisposal practices which were employed and a 1958 geologic and

hydrologic survey of the underground water conditions . The study was performed

by C . C. Killingsworth, a consulting geologist from Los Angeles, whose findings

revealed that "the overall average effective porosity appears to be less tha n

one percent 0%) over the 2,000 acres of property" . Furthermore, of the wells

that have been driven or that are currently in operation, the distance from the

surface to reach the aquifer is of the order of 415 feet .

2

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Concrete lined

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17, e Lqu i pr!, n

Re Fr igcretor ;(abandoned)

The California Department of Health Services prepared a document on "Sampler s

and Sampling Procedures for Hazardous Waste Streams that offers the approach

consistent with the Burn Pit chemical profile . Thus, the attached proceduressubmit a plan of action to maximize safety of sampling personnel , minimize sampling

time and cost, reduce errors in sampling, and protect the integrity of the samplesafter sampling ,

The background information about the Burn Pit has been researched and is su b

records substantiate that surface runoff has been monitored continually . Rocketdyne

constituents tnat required reporting under the NPDES permit currently held. These

so that Rocketdyne' s oollution control progran has voluminous documentation on

been kept for years on the general pond/water system/runoff chemical constituency ,

mitted as liable 1, ('SUMMARY OF MATERIALS AND DISPOSAL METHODS" ) . Records have

applied, nationally, before the advent of legislation that more specifically a d

and codes of the agencies during the time frameand with the perspective tha t

has had volintary projects as well as complying with all the existing regulations

dressed the need for restrictive environmental controls .

A list is attached that describes the constituents for which the analyses m

performed . See Table 2 , (" SUMMARY OF CHEMICAL CONSTITUENT TESTS"), that has

been compiled from the data assembled and tabulated as in Table 1 .

I II I II II II I I ~I I ~I I III II IBNA0347243 7

HDMSe00042887

TABLE 1 - SUMMARY OF MATERIALS AND DISPOSAL* METHODS

Type of Material Volume or Mass Disposal Metho d

A . Fuel s

1 . Nitrogen Tetroxide

450,000 gallons

Combustion2 . M'sc . Contaminated Fuels Combustion3 . Pentaborane Combustion4. RP-1 ( Kerosene Base ) Combustion5 . JP-4 ( Kerosene Base ) Combustion6 . Hydrazines Combustion

rriethyl Aluminum Combustionir,ethyl Aluminum Borane Combustion

Igniters #6924 Detonation

Process Chemicals 21,300 gallons Dilute and place

1 . Acids2 . Eases

in earthen pits

Reactive Metals 13 ,810 pound s

1 . Aluminum Burning2. Magnesium Burning3 . Sodium Burning4 . Potassium Burning

Organic Solvents

1 . Tetraisobutylene2 . Alcohol s3 . Hieptane

1,717 gallons

Combustion

CombustionCombustion

Explosives 5,121 pounds

1 . Nitrocellulose Detonation2. Mix Oxides Detonation3 . Dynamite Detonation

Toxic Gase s

1 . Oxygen Diflucride Gas2 . Fluorine Gas3 . Chlorine Gas

Heavy Metal Toxics

1 . Leaded Paint (189 .gallons2. Potassium Cyanid e3. Sodium Arsenite4. Mercury

2,932 feet '

191 gallons

CombustionCombustionCombustio n

CombustionCombustionDilutionDilution

*NOTE : From Fed . Register, May 19, 1980, p . 33119 : "A material is 'disposed of' if it isdischarged , deposited , injected , dumped , spilled, leaked or placed into or on any land orwater so that such material or any constituentthereof may enter the environment or beemitted into the air or discharged into ground or surface waters ."

n VT IIBNA03472438

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HDMSe00042888

TABLE 2

The fundamenta l

P . Toxicity) . Tne equipment required to perform thi s

and groups of compound s

ordered a,nd should

is called the Extraction Procedure (Federal Register ,

Vol . 45, No . 98, Monday, May 19, 1980, E . Section 261 .24 ,

SUMMARY OF CHEMICAL CONSTITUENT TESTS

first step prior to the various separations into classe s

Characteristic of

operation has bee n

arrive by August 1, 1981 . Thus, the following list include s

the analytical chemistry protocol that utilizes the manipulations cited by the

Federal Register methodology as appropriate and designed to identify wastes

likely to leach hazardous concentrations of particular toxic constituents into

the groundwater supply .

7

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H D M Se00042889

IDENTIFICATION OF HAZARDOUS WASTE

EPA REG . 4O-2O]

IGNITABL E

CORROSIVE COMPACTIONTESTER 185

REACTIVE PULVERIZER S 64 5

HASE XTRACTION PROCFDURF TOXICROTARYEXTRACTOR 2100

SHOULDARRIVE

CUTE HAZARDOUS

PRESSUREFILTE R $1100

BY

AUGUST,1981

PHOTO-IONIZATIONDETECTOR $3500

TOXICSONI CDISMEMBRATOR $1211

00z

TEST PROCEDURE FOR DRY SAMPLE EXTRACTIO N

SAMPLE

SAMPLE SIZEREDUCTION

(PULVERIZER)*

<9 . S M M

EXTRACTION PROCEDURE(ROTARY EXTRACTOR) *

ILIQUID SOLID SEPARATION

(PRESSURE FILTER) *

ILIQUID =

E P EXTRACT*REQUIRED CAPITAL ITEMS

STRUCTURALINTEGRITY

(COMPACTION TESTER) *

METALS (AA)VOLATILE ORGANICS (GC )VOLATILE AROMATICS, KETONES AND ETHERS (GC)ACRYLONITRILE, ACETONITRILE AND ACROLEIN (GC)PHENOLS (GC )

9 .5MM----- PARTICLE SIZE

MONOLITHIC

TEST PROCEDURE FOR SONICATION METHO D

SAMPLE

SAMPLE SIZEREDUCTION

I

MM

SONICATE IN SOLVEN T(SONIC DISMEMBRATOR)* j

FILTER ANDDRY EXTRACT

11I CONCENTRAT E

REQUIRED CAPITAL ITEM S

EXTRACTABLE ORGANICS (GC)PCB'S AND ORGANOCHLORINE PESTICIDES (GE)SEMIVOLATILE AROMATICS (GC )POLYNUCLEAR AROMATIC HYDROCARBONS (GC OR HPLC)CHLORINATED HYDROCARBONS (GC)

TABLE 2 - SUMMARY OF CHEMICAL CONSTITUENT TEST S

METALS ]

AluminumArsenicBarium

BerylliumBoronCadmiumChromiumCopperIronLeadMagnesiumMercuryMolybdenumNickelPhosphorusPotassiumSeleniumSiliconSilverSodiumSulfurTinTitaniumZinc

1 .2 .

VOLATILE ORGANICS`

Caron tetrachlorideChlorobenzeneChloroformChloromethaneDichlorobenzeneDibromomethaneEthyl etherFormaldehydeMethano lMethyl ethyl ketoneMethyl isobutyl ketoneTetrachlaroethaneTetrachloroetheneTrichloroetheneTrichloropropaneVinyl chlorideVinylidine chloride

VOLATILE AROMATICS, KETONESETHERS AND I .R S

Acetoni eBenzeneChlorobenzeneDichlorobenzeneEthyl etherMethyl ethyl ketoneMethyl isobuytl ketoneTolueneXylene

OTHER ORGANICS '

Benz (a) anthracene, pyreneBenz (b) fluorantheneChryseneCreosoteMercaptansNapthalenePhenolsPyridineToluene diisocyanat e

By atomic absorption spectroscopy or emission spectrography .By gas chromatography or high pressure liquid chromatography .

3 . By sample preparation followed by gas chromatography .4 . By specific ion electrode/classical wet chemical techniques .5. By calorimetric tests .

ANIONS4

ChlorideFluorideNitratePhosphateSulfate

AMINES"

HydrazineMonomethylhydrazin o

OR EQUALLY SUITABLE METHODS

WORK STATEMENT (Continued )

3. The proper samplers will be selected in accordance with the State and

EPA SW-846 manuals , as well as devices that are uniquely suited to the SSFL

terrain .

4 . The proper sample containers and closures will be obtained using the

referenced regulatory documents as guides .

5 . The sampling plan will include the choice of propersampling points, and

the number and volume of the samples to be taken, including the boring depth .

All proper sampling precautions will be observ e

7 . The samples will be handled properly with the appropriate chain of custody

paperwork .

All samples will be identified correctly and protected from tampering

9 . All sample info-mation willbe recorded and identified in a field notebook .

10 . The chain of custody record will be completed .

11 . The sample analysis request sheet will be filled out .

12 . The samples will be submitted to the appropriate laboratory .

13 . The results of the selected testing will be reviewed and decisions made

where there are questions that need to be answered or issues resolved . If ad-

ditional samples are required or further pretreatment or sample preparation

necessitated, then actions will be taken to complete these tasks .

14 . A report well be written summarizing the work performed, data generated,

results found, and recommendations tendered . This report will be submitted t

theRocketdyne Environmental Control Office as the document covering PHASE I .

12III IIIII II ~II~I~IIIIII II EBNA03472444

HDMSe00042894

DISCUSSION

The sample collection would be performed by maintenance personnel specificall y

instructed in and assigned the task by Rocketdyne Facilities and Industria l

Engineering management . A minimum of 50 samples would be obtained over th e

F & IE Burn Pit Project Engi neer on the advice and counsel of those who have

six-acre area . The specific sampling sites would be chosen by the Rocketdyne

knowledge of the area and its history and drainage patterns so that represen-

tative sampling could be performed. The Rocketdyne Environmental Control Offic e

would approve of the sampling grid prior to the execution of the undertaking s o

that the historical data on past events wouldprovide guidance and direction

for the sample handling . The choice of the chemical tests to accomplish the

sequent actiors taken to accommodate the best technical resolution of the proble m

were to be Bert out to other laboratories, these decisions would be made and sub

of the Rocketdyne M&P SSFL Analytical Chemistry Unit . If, in her opinion , sample s

chemical profile of the Burn Pit area would be the responsibility of the Manager

50-100 samples would be submitted for chemical analyses , and that the number o f

Unit effort is attached as Table 3 . The basic considerations are that fro m

the most expeditious and economical way .

The pricing ( as an internal control document ) for the SSFL Analytical Chemistry

from 25 to 60 depending on type, matrix, level of complexity, and detectio n

constituents per sample, following the initial extraction procedure, could vary

parameters .

I II II IIII II III IIII III IBNA03472445

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TABLE 3 - PRICINGFOR CHEMICAL ANALYSIS ONLY

(F & IE Sampling , etc . Not Included )

Every sold sample would be split and a portion would go out to Pacifi c

Spectrochemical Labs for a semi-quantitative emission spectrographi cdetermination for metals, at $45/ sample . Thus, this cost would be i nthe range of $2250 to $4500 .

Special field sampling bags (for chain o custody identificatior) an dother containers would run about $200 .

Chemical standards , liquid chromatography columns (at a current rate of$400 each ), and other calibration-type supplies would amount to about $3000 .

There ore, the pricing for the SSFL Analytical Chemistry Unit effort is :

MINIMUM , 50 SAMPLE S

HOURS

1250 M&P Personnel &Burden Labor

$2,250 Emission Spec .

$ lot Containers

$1,500 Chemical Standards

$3,850 1250 Hrs . TOTAL

MAXIMUM, 100 SAMPLES

$ HOURS

2500

$4,500

$ 200

$3,000

$7,700 & 2500 Hr s

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HDMSe00042896

RECOMMEN DATIONS

It is recommended herewith that several other activities take place concurrentl y

with the "firs- pass" profiling of the Burn Pit area . These are :

(1) Another geological and hydrological survey should be done by a professiona l

firm with excellent credentials in this discipline . Newer techniques and method s

should be available than those utilized in 1958 when C . C . Killingsworth made hi s

evaluation . Stone Deing stnne, the porosity values should remain the same, bu t

perhaps other data about the SSFL property would be generated which would be help-

ful for the company ' s future plans as wellas its heritage .

(2) A review of the available literature should be made to ascertain how other

companies have been handling the subject of hazardous wastes - particularly the

aerospace waste generators since their activities and Rocketdyne ' sare similar .

For example, TRW prepared a sixteen- volume report for the EPA on recommended

methods of reduction, neutralization , recovery, or disposal of hazardous wastes

(EPA #670/L-73-053-a) .

(3) Outside firms who are in good repute with the regulatory agencies should be

consulted as to their general approach to this type of problem and a rough estimate

of their charges, e :c . for comparison with what might be necessary for Phase II of

the Burn Pit Chemical Profile .

(4) The pcssible capital equipment requirements for Phase II should not be over-

looked if serious considerations are made about performing the project according

to the full extent outlined in the EPA's SW 846 (Test Methods for Evaluating Solid

Waste ), on an in-house basis . This could easily amount to $200,000 worth of equip-

ment . Table 4 lists these . Although the Burn Pit project is viewed as a "one

time thinq", all indications and legislative proclamations point to continual

examination of things on-site in order to reduce the dependency on the unavailable

outside commercial disposal sites .

1

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TABLE 4 - CAPITAL EQUIPMENT REQUIREMENTS FOR PHASE I I

(PRELIMINARY ESTIMATE )

(Provided that the decision is made for the work to b edone in-house by the SSFL Analytical Chemistry Unit )

INSTRUMENT APPROX . COST$198 1

Thermal Analysis Systems $32,000

Ion Chromatograph $33,000

Inductively Coupled Plasma $80,000Atomic Emission Attachmen tfor the Rocketdyne-ownedAtomic AbsorptionSpectrophotometer

Gas Chromatograph/ 55,000Mass Spectograph Compute rData 4 Tape Storage Systems

I

PURPOSE

Examine samples for rea=tivityaccording to the Federa lRegister - ASTM methods .

Excellent screening instrumentfor examining organic and in-organic ions more quic4:ly tha nclassical wet ch em'cal techniques ,

Rapid-fire analysis =ns-rumentation suggested by EPA butnot currently required becaus ethe whole package (aa+]CP )amounts to $ 130,000 .

To provide the accessib-e database of samples, standards ,

ical representation o- -nforma-cases as well as provice craph-at SSFL to use for all futur eprofiles already establishe d

and performance of ccnpiiance .declaration of technica' datalitigation requires suc htion gleaned in the evEnt tha t

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RAC F_TD % 'ntE MANP O

Mont frnni rfart Date

Project &Task Title

1 2 3 4 5 6 7 8 9i 10 11 1 2

START FUNDIN G

Ch se s p l i too am e s es

Lo istics Sam le s

Sampling Performe d

Sample Pre Emiss S c.

. .

Sample E t a t ix r c ons

Metals Analyse s

Volatile Anal s sy e

Other Organics l se sAnions Analysp s

nthAr A lna yses

Data Reductio n

FINAL REPOR T

FORM "Ob"- I I liv. N7 PREPARED IY N . Fujikawa

DATE !/11/fl1 B y

Program Burr Pit Phas,

BNA03472450

Recke!dyne 0vitio n6633 Canoga Avonuc Rockwel l

Telex : 698478 Internationa l

March 1981 In reply refer to 81RCO236 4

Reglor:cl Water Quality Control Board

107 S . 11.road4;ay, Suite 402 7Los Angeles, `-a)ifornia 9001 2

AttenLi or :

WAPTS T#t 53 FL M k

LAB 1-0 coNDu c'r ALL

Re: Inactive Burning and Disposal Site (File 8 1-18

Gent lcmer :

kocketc,re is heret:ith submitting the historical data pertaining to the

inactive dispDsal site known as the "Bum Fit'`%•.hich is located at our

Santa Susana -ield Lab . This submittal is made in accordance with dis-

cussions, kith t'r . N . Yacoub and your letter dated February 19, 1981 .

To assist in the j .~ ;cssI,crt of the sitc_, two information packages are

beiniI prep c' : 'it,t, n pi- historical bt.ckground da!r for the site,

and .ucc,rt', to ptcuide L c .-,ir, , larI deliruating in detail how the site wil l

e su;vc\cd a . -id yze ;IS package contains the hIstorjcai backgroundof t tc arca .

General Site Ii *cr y

Very trL

.hoc-:(°tdy nr Division

Ljo 1 1 r recto1 iu -. t Ln~ .Istrial Enginecrit~g .

AkB :pb

Enclosures

Mr . Raymcnd M . Hertel, Executive Office r

(3)

12 1981

t f

TNT' au FtW PI` T

PRoPosAL' GIv IcS

r Wo2K

?LAW IF F

TA C #4 rM CAS, Pt1ALY5e519 _

III1III IIIII II IIIIIIII HBNA0347245 1

HDMSe00042901

United States Office of Water and aEnvironmental Protection WasteManapement

1980Agency Washington; DC 70460

Solid W ante

III IIIII II IIIIII II I

BNA0347245 2

HDMSe00042902

TECHNICAL REPORT DATAI /deaf p dI pvrta .!f On 1'r Pr e,u ap't', C ' .qfe R/lPJ1~E'D' ~- R1EU1E~. i'S .1L OwlyO •=a .- -EPA-600,12-90-018 , .

T. TI :Lf ANDS~?T I TLE 5 . REPORT D- E.

Samplers and Sz=p_ingFrocedures for H azardous Januar; 19x0 (Issuir,z Date)Waste Streams PE RF.oRMlrvc , ORQANiZA 1ON C C E

77OTnOP R . devera, Bzrr P . S-l=ons , Robert D. P'fRF0KM1NL CRG ..NIZATlON REPCRT NO .

Stephens and David L . Storm. I.CRGANFZ :.TION NAME AN ✓ -DCREaS 10.PFOGFIAM ELEMENTxo ,

Kaz :ardou, Materials L2'hr7 ;4-ory C73D1C, SOS Task 3 2California Departsenc of Health Services 11 . CONT A =.Cr F ;; ;. .N NO .

21:1 Berkeley Way R 80469201 0

Sei keley- , CA 94704

12 .SPONS 0A1hC AGE NCr nAME AND ADDRESS .Ln VB 17 TYPE OF FFPG C,-an1D lE RtCD %CO vE aE O

Mu:.icirz . : :rvironnenta_ researc't Laboratory-- Fina lOff i c e c Re sear ch and LeveloDner t 14 .5PONSCRING ACi ENCY CODE

U .5_ Eno'. :cncental ?rote :--ion 4gencyEYA/600/14

Cin a :i C`.io L526 815 . 50PLE M.E r. T-. I hcT E $

Ric,-.erd A . Carne, Project Of` ; :er (573/584-737 1

16, AeS r NAC T

The g:,al of this project T-'es to develop rim-)le buteffective sanpliag equipmen tand procecures _Dr cc_lecting, .ancling, storing, and recorc_:g sanpies of haza_deus

wastes . he report describes a •.a__cty cf sai=1:ns devices de- :-' ed to eat the need sof those vhe rEgu :a:E and manag s ficcarcoCs wastes . Par*-i,12 :empras :s s given to

:ht devele, :renc ci a ca pooite licuid waste oe ?lcr, t-c Ccliwasa . 71_2 smile deviceis des .-ned for use cn1 quid a .d se__ liquid wastes ir. a .s :_e :y c` ccr, :a_ners, tanks ,and ponds . Devices fo r sa=pling solids and soils are also described .

In addition to the sr=lint devices, the report descri cc proced .es for cevelcp-❑ent of a olz S2^-:le har.dlir.Z„ eafe :y precaut_ors, proper recc :d .ee^_ngand chum . and soEole ccntai er.t, preser rat .on , and tr :r-npor . . als odiscussed l_W,_a : cns cn potential sources of error .,o: exist in th e

ar.d the procedures .' The statistics of Sa^paing are cCvere dbriefly', a:1G addi :orr.aa redo:enCes in this area are given .

11. KEYrvt R CS AN C DOCu MENT ANALYSI S

OEECr.rpTCO . b .iDtNTIFI -.. e

Samplers .epresentacive saplingLagoons (pcr.dsl--vast : disposal orposite sat5__ng 68CHazareous ate : als acpling plan s

anpling procecurc zazardous wast e

oapos{te !:quid wastesacp e r

'- ~IS'R~01/ -t..N S : . . .~ .NT 15 SE{,.:P C_t_=_,•, : 1 .=:rp o .r~ I : 1

20 .5E{ .u Rrrv C--55 lino pogry : . PRiL E.-

R.eto~se "nti ^ired.~ ~.

UnclaoS-tied n .-

' 1k PD•rn 1120 . 1. :~,f 771il•.-•III . I .I / ,. .

,2/I II IIIII II IIIII 1111 n RBNA03472453

HDMSe00042903

1 RI •p R p .C pAl ~{p{pBIBLJ cpnt r .

I

~

SH EET E PA-670/2- 73-05 3-a PB 224 58 0Recommended Methods of Reduction , Neutralization , Recovery , or

Ne O .1 Dal e

issuing date - Aug . 197 3)ispOSAl of Hazardous Waste .Volume Ia Summary Repor t

> A,rrrorfaf R_ S . Ottinger, J . L . Blumenthal , D . F . Dal Porto, S=lcrfor,n OFaraz~c , ofFcpi .6 . I . Gruber, M . J . Santy, and C . C Shih °' 21485-6G13-RU-Ot -

ertmm,aF Ordanrtar , dn hrmr and Address 1D . Pcoj =ct/7 as a; l o ;A l.nor f~ .o .

G PtRW S O S kemsys rouo, re pace arT 11 , concr . i, -Gran : No .Redondo Beach , California 90278

68-03-0D89I 12 l ronsa rnB prranizai ion Name and Addtry s

` hz ti onal Environmental Research Certer13 . :7)j .. of Report b {,rrio~

Covere doffice of Research and Developmen t

S E i l Po t tFina l_ nv r nmen a roIu . ection Agency 1 4 ,

Cinci nnati, Ohio 4526 8:S. S~fplemenrary Notc h

Volume I of 16 volunes .1 5 . hbar,ac .

A sun'ary of the work performed on the hazardous waste research project is p-esented i nthe first volume of the 16 volume report . The report includes an updated listing o fhazardous waste stream constituents, an evaluation of the adequacy of current wast emanagement pract,ces for these materials, and an identification of the research an ddevelopment required to provide necessary information or develop adequa'e treatmen tmethods . The results of this study clearly indicate the requirement for a system o fnational Disposal Sites tc provide a repository for certain classes of hazardous hast estream constituent residues which must be stored and monitored permanently to avoi diarr to the publ c`and/or the environment . : .

17 . Key ;Dias one Doeumeni Analysis . 17a. Descriptor s

Hazardous Wast eNotional Disposal Sit chaste ManagementTreatment Method s

17b: ldcmifiers!Open•Ei ,d Terms

1-4-d be

NATIONAL TECHNICA LINFORMATION SERVIC E

?- cosnn Fired/C-,,, 06F• 06T'018; 07C' 07E• 13E ; 13H• 19h' 19 8

c . . Ava,Jabd ity sr .tcm rn : 1 7 9 . Sccmicy Ciaoa (I his 2 1- To .. of PaFc sReport )

R " IF

elease to public. 1 a 20. rur :y Ciaaa (inra 71 Ps ce

t t rn

III I II I IIII II III I I 1111 IIL R11 I

BNA03472454

HDMSe00042904

RECOMMENDED METHODS OF

REDUCTION, NEUTRALIZATION, RECOVER Y

OR DISPOSAL OF HAZARDOUS WAST E

Volume I . Summary Repor t

By

R. S . Ottinger, J . L . Blumenthal, D . F .1 . Gruber, M . J . Santy, and C .

TRW Systems Grou pOne Space Park

Dal Porto ,Shi h

Redondo Beach , California 90278

Cortract No . 68-03-0089Program Element No . 1D231 1

Project Officer s

Henry Johnso ngorbert B . Schomaker

Solid and Hazardous Waste Research LaboratoryNational Environmental Research Center

Cincinnati , Ohio45268

Prepared forOFFICE OF RESEARCH AND DEVELOPMENT

U .S . ENVIRONMENTAL PROTECTION AGENCYWASHINGTON , D.C . 20460

23

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II I

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REVIEW NOTIC E

Research Center - Cincinnati . U_S_ Environmental Protection Agency ha s

The Solid Waste Research Laboratory of the National Environmenta l

reviewed this report and approved its publication . Approval does not

signify that the contents necessarily reflect the views and policies of

this Laboratory or f the U .S . Environmental Protection Agency , nor doe s

mention of trade names ofcommercial products constitute endorsement or

recommendation for use .

The text of this report is reproduced by the National Environmental

Research Center - Cincinnati in the form received from the Grantee ; new

preliminary pages and new page numbers have been supplied .

m I 111 1BNA03472456

E

HDMSe00042906

FOREWOR D

Man and his environment must be protected from the adverseeffects of pesticides, radiation, noise and other forms of 0011L-'rion, and the unwise management of solid waste . Efforts to protectme environment require a Locus that recognizes the interplay between' h e: components of our physical environmentaited lnd-- r, war, ana .

Nt he ational Environmental Research Centoid thi multidiiers prves sc-plinary focus through programs engaged in .

studies on the effects of environmentalcontaminants on man and the biosphere, and

a search for ways to prevent contaminationand to recycle valuable resources .

Under Section 212 of Public Law 91-512, the Resource RezcveryAcct of 1970, the U .S . Environmental Protection Agency is chargedwith preparing a comprehensive report and plan for the creation ofa system of National Disposal Sites for the storage and disposal ofhazardous wastes . The overall program is being directed Jc7ntly bythe So'id and Hazardous Waste Research Laboratory, Office of Researchand Development, National Environmental Research Center, Cincinnati,and the Office of Solid Waste Management Programs , Office of Hazard-ous Materials Control . Section 212 mandates , in part, that recom-mended methods of reduction, neutral'zation , recovery, or disposalof the materials be determined . This determination effort has beencompleted and prepared into this If-volume study . The 16 volumesconsist of profile reports summarizing the definition of adequatewaste management and evaluation of waste management practices forever 5C0 hazardous materials . In addition to summarizing the defini-tion and evaluation efforts, these reports also serve to des'gnare amaterial as a candidate for a National Disposal Site, if the mate-ialmeets criteria based on quantity, degree of hazard, and difficulty ofdisposal . Those materials which are hazardous but not designated ascandidates for National Disposal Sites , are then designated as candi-dates for the industrial or municipal disposal sites .

A . W . Breidenoach , Ph .D ., DirectorNational Environmental Research Cente r

Cincinnati, Ohio

i i i

of I II II I II II 111111111111111 I II IBNA0347245 7

H D M Se00042907

ACKNOWLEDGMENT

This program owes much to the progran nunitors and other staff of the

shaping this final report . Special thanks go to the program monitor ,

Environmental Protection Agency who provided both advice and insinht to„ar d

lit . Hen-yJuhnson, his predecessor , Dr . Lynn Wallace, and the staff of th e

Solid Waste Research Laboratory, National Environmental Research Center ,

Cincinnati, who have reviewed progress and provided inrormation throughou t

theprogram . Thanks are also due to the staff of the Resource Retove, .y,

Division, Office of 5o'id Waste Management Programs , 'Washington, D .C . ,particularly Messrs . Sam Morekas, on Marlow, Al Hayes, and Ton Goss ,

also reviewed program progress, made constructive suggestions, and

cocrdinated this project with the related projects sponsored by their

organization .

This project relied very heavily on information obtained by persona l

Commission , W ashington . D . C ., Mr . Lou Meyers , Office of Radiation Programs

communication an, therefore , mush thanks is due to the indivicuals providin g

information . The industrial contacts are too numerous to mention specifically ;

however, certain individuals within the government sector were especiall y

iJnportant in obtaining military and radioactive waste data . The collectio n

of military hazardous waste data was coordinated through Col . Herbert Bell ,

Office of the Deputy Assistant Secretary of Defense for Environmental Quality ,

and Col . Walsh, Major Donald Rogers , and other members of the Department of

Defense Environmental Pollution Control Commmittee . Information on radioactiv ewastes was obtained through Mr . Alex F . Perge, Assistant Director for

Operations, Division of Waste Management and Transportation, Atomic Energy

Envi ronmental P ro tection Agency , Rockville, and Mr . Charles Hardin of th e

Kentucky State Department of Health .

0

,

The ingor an ur ma or subcontractors, Hazeiton Laboratories

and Roliins Environmental Services, deserve appreciation as much information

necessary to the successful completion of the project was obtained fro m

v

26

II I I II I IIII II III I III I I IBNA03472458

R

HDMSe00042908

their programs . Finally, the contributions of our editor, Mrs . Marilyn

Jennings, and of our secretarial staff have been extremely important to

the preparation of our voluminous monthly re ports and this final report .

We appreciate their efforts .

I

2,

I II I IIII II III I I DI I II IIIIBNA0347245 9

HDMSe00042909

Technology ,OR\rA S . I`VJ1KAW 1\lanatsr }

SSFL Analyrical Chemistr y

NationalTransportation

Safety Board maps present

lime-sequenced data from

past spills for researchers,

emergency response teams

"We need data," was the plea heardconcerning hazardous materialstransportation accidents .

There are mode's sh win' howhazardous materials will onhme in aspill . But "one equation says you'll beburned Lu a cinder . Anotnor saysyou'll be pleasantly warn- . "Thatconcern for data was ez

Engineers in Philadelphia early this . soliciting G) RI-nEnts and' iggestionsmonth. The program involves devel - from interested parties . It expects toopmentof hazardous materials acci- propo e a t nal srandardi :ed systemdent spill maps by the National by the end of this ,ear .Transportation Safety Board . The spill maps feature a time-se-

The maps were devised by NTSB quenced display of dispersion pat-following a 1978 special investigation tenets and ranges , weather it the- timesthat indicated a need by researchers , reported , injury/fataiitv exposure

hmat ematical modelers, emergency locations , andasynopsi, of the acci-response personnel , and others for dent scenario.data to support predictions about So far, yiTSB has puhlikhed mapshow hazardous materials could be for five accidents:expected to behave in in accident- . Map 9-1 : On Dec .They are being developed under the railroad locorotice struck a tankoffice of Ludwig Benner .Jr_, chid oT semitrailer containing so) gal of li-NTSB's hazardous materials divi- quefied anhydrous amrn"nia na asion. grade crossing near Boutte l,a. Th r

The idea of the maps, N TSB aaz ammonia vapo-i7ed .end i,,rm od iardous materials safety specialist ground fog 30 to 10 feet hii h f p er aRebecca A . Rote told the symposium 1000-foot tadiu with n 10 -ri ipressed in support of a new program is to report observed behavior of More than 18 tons of anhydrous am-

that had just been de cubed at the hazardous materials in an accident in monia escaped during this time, and14th loss prevention symposium, held a standardized format . NTSB con- ammonia continued to be vented forduring the 88th Hai iona, Meeting of siders its current standardized way of four hours after the collision . Threethe American Institute of Chemical reporting the data as tentative and is motorists within 200 feet of th e

Hazardous materialspill maps record accident data in standardized for m

!,1

/ ) 7

WENT SITE

7 ,

•r .

TIME AFTER INITIAL HAZ . MAT. RELEASE-- JTo + 112b MIN. '

. ~.r . ..

f• BO

`.I1 r lam' ~~ ~

'eIW / Vie( A

. C~ aYe I n>r~ .. . . rv wwr .c .fnfrn

[CC.aTgN

IM~ T [l

a . .a a. ! ! !. ♦ N a a Y

swn w .f wvi wc . al.w a[ ., [„Imll .CI C .a.,nmgt •cWrtv cO,Ct WJf•tC! ~Lst.,Th t rt :.

W T w ti M![4r[m.

U Wil ifl rlan : W

ItY>t.LLG . T

a a' Y a . a s Y . Y

NOW • s yr of Gf! "D a s tuff a°Q1 _ tafa di4a5,q hota[da m fM b.ba,4 r in • raFO,.d d.. fn..C.

46 C&EN June 23, 19153

III IIIII II ~IIIIIII I IBNA0347246 0

HDMSe0004291 0

sY 0Y101TYJYMnGr

!

av w.r,funK w. ~Me

TY[[ .cc u+r fwtso funtwwwrou'~u

crossing died from ammonia inhala- surface effects the release led to sub-tion, although the truck driver wan surface effects lag the chemical snot affected leached into the soil.

Map 792 : On April 8, 1979, a In its 1978 investigation NTSB,train derailment near Crestview, Fla., heard from emergencvresponseDerinvoivea cars cc ntainirg anhydrous sonnet, who reported problems enammonia, acetone, mr-nanol, chlo countered in developing pre•eme rrive, phen')1, carhon tetrachloride , gency plans and making tactical desulfur, and urea . Flammable liquid cisions during emergencies such a sand noxi rus gases were released these . For preplanning or onscenethrough riptur(s and punctures in decision making, Rote explains ,the tank car shells, resulting in propp ulsiveventing and fire . Flammable ,liquid flowed down an embankment the hazardous material or containe rtoward a trestle and ignited, And an likely to go if released during th eanhydrous ammonia car tank rock- emergency? Why is the hazardouseted, injuring a motorist 450 feet from material likely to go there? When isthe tracks. By an hour and a half after the material likely to go there? Ho wthe accident, winds had dispersed the will the material get there? Wha tescaping gas plume over a 15- harm will occur when the materia lsquare-mile area, extending 5 miles gets there "downwind To meet users ' needs, Nl'S13 es-

7]llnp y-3 : On Oct . 24, :975, a tablished some basic criteria for ma p30-inch l :il +'line I ransportin .; natural base choice, information content . andgas at 56U psi ruptured near Pearland, layout. F considered essential a mapTex . Tb gas Was ignited by an uu- base with a uniform scale , availabl eknown souse, re,ultirp in an expli,- nationwide'at list cost to all users ,sion and i ire . The fire's ,nitiation way For this purpose, it chose the U S ..described a : nasin- been wide and GeologicalSune ; '; t,_ minute series ,low, gradual , r . ing a_ a column of 1 :24 .000 scale, topographic map serie sfire between 30U and hid f(-c- hi,h as the standard "napping base: 'T'h pThe blaze taus e :- .;mated 1, ha~e bi•i'n standard also provides for scales ofup to 2001 e-i in d ameter Six per,uns 1 .12,1~(N7 or 1 :6000 to permit reportin gwere killed z nd ' I person , sere hrn"- of small release pattern spitated . 111 manpinr; Role paints nw.., tim e

\lap On Au. . :SU . 19?9 . a sequencing is important for emer-freighter on the .Iiesis :ipiii F.iter ger I cv respurise Fer<ci eel . Canse-etruck a decked ;,autane tank barge quently,mapstrs'to show' the -rowt hluadcd r irh about 2_ -,ili ; ra : of li- of the It az,irdi its material dicoa r~ion

'quell -d pct- ,Ieum Qa, .] ne fro i hter J)'Oterrn- in area , fYec[ed du eruhturcu c t 1-i,[ „ne i h - tankr . and T,, env irenmcntal condition- such a se•_allu g ' _P~, fr,rrned a v apsir c.oud wind direction, chan7e ., in nun-ber o hthat :u gni .sI the freidl ter and was people a -lected, nr rher chanves i nignited is an unl ii s .cn source Thee the hazardous materiail bell"" for tha tbtirnir - g . isr7 .5rd ;, 117, [),ill nun - affect emergency reslxmse ac .ii,nsdred'- r *er t that 1 st_~- I,,,- than Both surrsee and airl ;on :c cffect sone minute ii c: i_, "I ;stihlcc are displaced fries of''rsed data ,on tile frei_ h or, the C1 ck _~ :boat, supplemented bs' ecriaieus suggestedand tsc re,arl s s :iurel ii s ':,I : ;4I nip be nmmenl , .f tti .nr se5 A shade dStir : I i ka i . cd I r, b rn,, nine died . circa is u 'ed to shy a ('tin .atcd suifai eTl-.rec b,,d t ;ern, r e t , r-fror_, the effects, a ith s o l i d I it(-- et . clu--in - ii hriser. a c `. 1 urf -ice Cl .eCT. D ra-. .

• Mal, 0 :; y e. IPTh r; n red lu c repro its the h iu s ir ,Ira ii derailec neat in','.ixid 11A_ and cl air :erne eife : t- . and ad :3nc~c tie rfl- nr : :ciiiI I, ;1 , Its re pn~d•c_t' ti's i bse~sed bc,urdarc .leakec tii, ei ht breached tani. cur ; . t soft 'r conditic+e, at the ti :newA small fire seas „,led la,er at the mapped are displa .-ed ill a blor'k in-drrai in,i r~ e he as-ai~ed cars dicotink stiind diru,tion 5 . ; sprat ,COntriuieU :,, ru scii rr',dride i leaked)- she cot ndi :io; :. .La',s1 cell ,",1t (le k,c i buts,l ii,ci r temperature . An x .s ei,"rd ir :rtha<nl :ate e h, . acrsiatc Beal :edl, no, grid Zsstcni i used t 1:inpoin tetl :rl chl~aide, eth}let, ._ :,tilde, isc- ne locate„n-5f tetalexf,u-ore, . An, lhcisl alc~,I .-,1 i',ic . ir, tlucc ,]ir l , ~crq'n's da+r al-out the eccidrn tai i nc wt 1, i h ;:, arc pn,cidrd i i i a t' '1a c, rc ;,i, r.a,L tslit'

n- nAc Id ;'lc, . Pr r burn product r,lc,,-ed . niap ba-i ., inc : neapin,r tl,ri ,it, t~ >,1i trriu ;li ~r rcuip!es 'i . 1 ,ti,~c, anrt tit-L . n .•-- in the chest, in '1 -t H expcstc, the spill iaat ., to

1311d cc "wiIie1 of rpplication- torod,r,' 1:. i ;ii! , i .'r t,, , . :roe "soli t yari ;la!e . m„deI ccrilirnti rn . release

III IIIII II ~IIII II I

BNA0347246 1

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emergency response personnel needanswers to five questions : Where is

comparisons, and accident simula - emergency personnel during an actualtions . Also, Rote points out, mapping emergenc ymay be expanded from recording re- Although NTSB is preparing theleases due to transportation accidents maps now , it expects that eventuallyto mapping other types of releases , it will be necessary to establish asuch as at storage or manufacturing clearinghou se for map publicatio nfacilities . Regulatory agencies might and distribution . The Safety Board ,also find the maps useful Rote points out, isn 't equipped t o

NTSB expects that in the future handle such a large project, whic hspill maps will aid on -scene response would likely include maps for nonactivities . Stored maps and associated transportation uses . Thus, public ordata could be recalled at a one -call private agencies may have to shareinformation center tohelp local the task .

Changing priorities may reshape oil refineriesBefore crude oil prices soared in the there may be some minor revolu-mid-1970' ; a popular technical ex- tionary changes as wel ; .ercise was depicting the petroleum The high cost of crude oil, Murphyrefiner} of the future . In addition to says, will require that atr,inimumbeing a source for the usual mix of amount of crude be processed for afuels . th(- future refinery was often given product output . That could poseviewed as a source of an ever greater some stringent technical require .number of feedsocks and even some ments for designers. Future produc tconsumer chemicals. The trend would demand will be almost entirely forbe toward bigger and more complex transportation fuels with a minimu mrefineries serving a greg :ter ' ariety of production of petrochemical feed-customers stocks. That 's the exact opposite of

The tenderim to depict the refiner} the usual assumpttous a decade a_-of the future persists . hut the objec- There certainly will Inc no br-prvd-tives have changed. ucts with a market value less thanFor example , James R . Mui phy. that of the parent cruce oil .manager of process technolct icr Residual fuel production will b ePullman Kellogg,addressing Petro- di,continuedaltogether. he saee _tech b0 in Amsterdam late la-t Future refineries will hate crl ider-n .unth, nulcd that petroleum refi ners able hydrogenation rind de~ulturiza-ir the future will he processing heat - tint cahar'ly but the h ero eit t

.~ -cnsumedon- site with ter . mrre cis iu~ crude crnta um feed it no l rr,LCj gill e me t ur i stea mnostorzgeor r"rue cnntamrnants Sanre e~nlu reforming fnapl~thrr,ri hth .dro-transpert prot tisnar, chanl_ti in rclinerc crmfrgu carbons . Inatear it v ill c,rre ironsl msi no supply rati n ssrli be required, he says, but residual asphaltenes or pith .worrie s

L

0, : higher potential tha npermanganate :Higher ihanper,xide Highertna nchlorine Mgbe ban chromtcaci d

And ozone ge eraled an d

i„J

O,: nc residues,nc pollut o nOzonescontrib jtes no'hinn bu toxygen to the oxidationproces sLeaves nothing but o r , germ to dea lwth : ND co-ip~iciated residues nodlsfasal headaches Itsat si nglea 2u,-~ t r

O, grams/hour toolcns'drr ywB15b5Ct rr to nent cZon-alor,fort oc, :tmmfrcmafee:grarnsps,nccL,r`vri anage poet ;i ;ie5 ,--r efa} fo'Che-n~ca lprocessing ment an dOdor c'7i . _ ~I r nc otr -mor erepo-ut u .,r fr ibooklet: Puthr. gOzone to NJor 4sNelsja( o-- n eSystem' C, re

Refine ry of future will process atmospheric residue to fuel s

AlmoscOeric residu e

Asphs . :ent3~fti

H, plant(partial

cs dation)

H,S, Cz and lighte r

ca-c,

C, - 220 C

Gasom a

220 -2E0 CLight aas,0i '

Y i

cracker

- .mow>400 C trtc :wC- uo r

hp;.[Gr:1 5

III I I II 1111 II III II III IIIII IBNA0347246 2

HDMSe00042912

Write-On Whirl-Pak bags make sample identification easy' We've take nour 1 oz ., 2 oz, 6 oz., and 18 oz. Whirl-Pak bags and redesigned them wit ha white write-on strip for more accurate identification and added convenience .

Its easy to write on this white strip with an ordinary ball-point pen or pencil eliminates thecost of special felt tip pens and labels . The ball-point pen makes writing more legible andidentification easier - ink stays on longer and there are no labels to come off .

To assist in volume control, the top of the white strip car also be used as a fill line . On the 2 oz.bag . the top of the strip is the 2 oz, fill line ; and on the 6 oz . bag, the top of the strip is the 4 oz.fill line . All fill lines are approximat e

These Whirl-Pak bags are made of heavy , transparent polyethylene , and are ideal for milk, wale'and food sampling . Whirl-Pak bags are sterilized , easy to store , disposable , and economical .

1 oz 2 cz. 6 oz 1 6 c-21 x F. 3" x 5' 6. x 7 ,A, : ' x 9

81067WA BlD64WAwith 2 o zfill lin e

1'f. 2 Y, v. - x 3_•while strip white Strip

81062WAWith 4 CUfill line

1%,'x3"white Stri p

milkdsampies milk samples, milk samples rn I Sa~pIF

for autornaterl packaging water samples tt)ec7 samp es .

equipment tool samples pull sdnryif; S

500 per box - IOM per master on 1, 21 and 6 oz_6M per master on 18 oz . 3 1 s

~~II~~IIII II ~IIIIIII ~BNA0347246 3

HDMSe00042913

s-

MAR t

UNITED STATES ENVIRONMENTAL PROTECTION AGENC Y

3 tse 1

qa ion ide' :.pproval for the Use of NASCO Whirl-Pak Bags

Victo r J . Kio , Deputy Assistant Administrato r"-" Cffi,_ e of Drinking Water ( W :1-550 )

,,All :Reyior al Administrator s

bacteriacnly .Requiatior" (NIPDWR) compliance monitoring, total coliform

nationwidE use for "National I:terin Primary Drinking Water

water sampl es using a product which I have approved forListed be]ow is an alternate method e' collecting potabl e

spec : .1ications contained in Standard Methods .with the raaufacturer's instructions, will :neet the containe r

have sown that the product in question, when used in accordance

Data provided to and statistically analyzed by the Environnenta_Munitorin_ and Support Laboratory (ENSL) in Cincinnat i

Mea suremen Total Coliform Bacteri a

Step : Sample Collection

Product :''LASCC Whirl-Pak Sterilized Water Sampling sagsccntaining sodium thicsu-fate

lm his product is available from NASCO ; 90_ Janesville Avenue ;Fort. Atkinson, Wisconsin ; 5353 8

cc : Regional water Supply RepresentativesRobert L . Booth, Acting Director, EMSL

EPA Fa,.. 1323-6 (R, - 14C

n I II I IIII I II III I IIII II I RBNA03472464

I

HDMSe00042914

THE HANDBOOK OFHAZARDOUS WASTE

MANAGEMEN T

byAmir A. Metry, Ph.D., P.

`" a TECHNQMIC

1 TMC-111,TOMIC Publishing Co , Inc .

265 Post Road West . Westport . CT 0688 0

;"+• -C- - r r --- T ,p

I II VIII Il III I I III IBNA03472465

i

HDMSe00042915

F-

HDMSe00042916

CAPITAL EQUIPMENT REQUIREMENTS

CURRENTLY PROJECTED FOR

HDMSe00042917

TABLE 4 - CAPITAL EQUIPMENT REQUIREMENTS FOR PHASE 1 1

(PRELIMINARY ESTIMATE )

Provided that the decision is made for the work to bedone in-house by the SSFL Analytical Chemistry Unit )

INSTRUMENT APPROX . COST1981

Thermal Analysis Systems $32,00 0

Ion Chromatograph $33,000

Inductively Coupled Plasma $80,000Atomic Emission Attachmentfor the Rccketdyne-owne dAtomic Absorptio nspectrophotomete r

Gas Chromatograph/ 55,000Mass Spectograph Compute rData + Tape Storage Systems

9

PURPOS E

Examine samples for reactivityaccording to the FederalRegister - ASTM methods .

Excellent screening instrumen tfor examining organic and in-organic ions more quickly tha nclassical wet chemical techniques .

Rapid-fire analysis instrumen-tation suggested by EPA butnot currently required becausethe whole package (aa+ICP)amounts to $130,000 .

To provide the accessible database of samples, standards,profiles already establishedat SSFL to use for all futurecases as well as provide graph-ical representation of informa-tion gleaned in the event thatlitigation requires suchdeclaration of technical dataand performance of comp -, iance .

4111111 III I LII RIII II i nBNA03472468

HDMSe00042918

A- A MIrr7. Ph D, P. E.

These highly reactive hazardous substances are substances which :

I . Autopelyrrertz e

2, React vigorously with air or wate r

i Are unvrahle with respect to heat nr shoc k

4 Arc strong oxidizing agcr i s

5 . React read ly to give off toxic fumes

one commonlin,< amone highly ccaclive substances. and an important reason for their hazardousness , is thatagyas a '"shock' or tic addition of an initiating agent .Pit these categori :s (c' . cpt 4) usually rci uire an extcmad impetus to precip itate the reaction either in the form o f

These categories are not discrete , but overlap. For instance . some peroxides would fit four of the above categories .6 Are explos c e

silts of confining the sample in a specially designed vessel equipped with a shielded thermal-couple .cedure that can he , ;ed to identify wastes which give off large amounts of heat when reacting. The procedure conmethods of testing for and measuring these effects - Differential Thermal Analysts A l ST, i E ) is onepro-- X a,etheir reactions can cause the tormatton of steep temperature or pressure gradients w it h time. There are standard

Amir A. Metry, Ph.D., P .

I II I IIII II III I IBNA03472469

n E

HDMSe00042919

Thermal Analysis

a _s' rc :gig gist ., reraae ir_ cncassurance Ha

MAIN—^Cr' _' .-- ation The-rna,-!

el; _ '-gip Ica for

Industry Typ cal Application

es CF J - ;e s

a. r1 H( Is:'~' . .

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LC-

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L: C!e 'al ' .'ai, a r.

z arc Stab' Te_' no Pra,~ __ e . c :ess7777F Tan ' diverse r . ._ur .'n_ _no a

Industry

IndependentResearch .ac s

Ino,ganrc Chem can,Irume.n1secirat De . ces

C er'c _s n., eta S

Typical Application

Ca a :, ,

C"a1n nl"-, a~l c

M P -I a' C ag'amS

Ptvec e C_-3 1 n sr I .r1IntY1n FCr~a ce Equipment Cuing of _c -I D'

L : r' ,a 5 C °a : ;e .C~d~ .a is dCd Jicbll C. r C"aanic Chemicals Meltinct _ 11 nts 7 herm3 stao .l .t y,y r ;I aeral s

_oalreact CoSiro~ C~mGo t c r

Corr bustion Analysis and CoalPacKagin g

Paint

Analy ze C _t ",r eSol .enl L-.Ss So-T-'r -c P

"cnvers!c" Research Fe' 'urrii C'_uc p_ nianJ Pc . ;r -_. m C910^,S =S rn'eleohones

_ .

Parr,air ticai PGr`r

°la j c-c u : r, a nd Plurnb!ncPnc :~~'eph„̂L) a

Char5c re ~ G ,~e :t" rIm Base

C cc ' ansdlon s

71-% Efieo of Addl res ano Fil ler s_on!a rers ":- et -ic ; on -an-,

?r h .r Tuo Maon"t V, I i Sri G' ) nusme!c; o tvlraxySubstr ate P l , Er : n i

Dair yDisplays

V,rlrnc fnaracterisFcs of Butter')-r- . i ~Jre S abildy of Liquid

i, pa! : spa r

R-sin sRubber

-ree a c oun . aEffe ,: .f Cald , _t5 c'; C'r ?GlassTran -r,ion Ten 'eratur e

Educatio nElasiomers

Sp e,Ia-

'i c Lauoratory Project s-ra into rnTe^ peratu i es

5em icncu .c'orsS-_el

Curing cI Lrca :.5olatirca t.lalerial sStress Reliet

~ ,Electrcal Oxic a'!vn SlaLu ,' of nsulation Sportiro Eca'pmenl Rel, abiiity at Nyl_ ~ ruin 5 1 ing s

Fectronic s7erl izers

_ l CD% Nr sula['_ n

Ge . r, , ; ; _ he or erli,!ze i s

Te, 1, e sIr e5

Ehect c Fla Ti- Relar cant sSul ur Cross L in kirp'a Ruttie r

-dins h'ePnq cf Pc'. ester F Ims Ltiaxes Melting Profiles Crys' al in r,'

F_cdClass

O-1 . C at nde of Fats

ccf'tring PPoct

wire and Cable Cross-Linking of insular o n

Why you should want to know more about Thermal Analysis.

Thermal Analysis is one of the fastest growing instrumental techniques . Thermal Analysis is used In manyindustries including pharmaceutical, plastics, fertilizer, food, electrical and electronics, automotive, aerospace,packaging , metals, and energy, and In unive rsities and research institutes. It is used on virtually every type ofmaterial including plastics and rubber, metals, glass and ceramics, organic and inorganic materials , and ha sbeen found invaluable for research and development and quality control .

Find out more today. Contact your Perkin-Elmer Thermal Analysis representative .

n14P

1111 IIII 111111111111 I uBNA03472470

HDMSe0004292O

111 19 1 1 33,000

DIONEX IONC+fRoMATOGRA

NEWFAST RUN ANION COLUMNS

CUT STANDARD ANALYSIS TIMES IN HALF

Results

Higher Sample Throughput and Lower Cost Per Sampleanalyze 44 samples per channel per 8-hour day - as many as 400 individual anion determination s

Sensitivity is Increased Up To A Factor Of Three For SO, and NO,less sample is re:uired per injectio n

• Improved Selectivitye g ., sulfate and oxalate can be separated using a single column in 8 minute s

Some typical chromatograms follow :

NO ,

J u

0- 1 s 12-- 16 20. .Minutes

OLD A NION STANDARD

n III

H

II0~ ~ 11 11111111111 mBNA0347247 1

HDMSe00042921

By T .J . Hansen and R .D Ediger

I /IA/%Ty RoGErsoi'/rtotlh

1_1111g \A an d

r L , ;IIci tas

F'an n,/ .tar int csr Ira ndc~-

u~.el, _~,_i!,Ied p alma (ICf' 1Ifecausc ICP

_n,' 3I ui otl''11 )n sFectro-hs. i-A \s) .u co,) p ;cmcntar y

left that a

Inc ~u ~It t :arunauorl of both

ea :,i,tue ; nd _hcir rc'. ationshi p

t"' )i'mc useful .such a ~raIs 1111 ld roue twopur-

i urr pa e t~'._ acsar,tages

nl-d ~'r .id .~ti t,EEes t ee n lrh-i~ : .- trl fn ci 0ternl ne the feasi

it- h n, ng I, P anc AASn ~inl~in :r~rncn TheresuIt s

Ja ; study and [he 1a~elopntenl

an rstnru .nt t . pci Io n,iia g

\ft And I C11 I re reported here .

ante rrison olAAS and ICP

Because many I apers havehecn sitter on both :As,S andI' P anal t",elleit rr'.iew papers

ai (: i 5, hiI. IC sIii ICP cntissio tr'-'

1111' -eport 'sill not go into the

fu .damental details of wiat aiti ui urw it work, In-

ca it will examine close) the

rs'lauun ;hips l'Ctwccn the Iwoic :tiiiiS IF . aid h,rw they in be

1,,111] to complement each other .'SE -n uno: ahsoolplloil 1 c the older

of the two techniques, caringh te : to 1955 whet Sir AlanWash fit of reported on AAS asan anAvhcal :ool .' A consider

rr-c _ o l nn/urr S ,• ulrsf ;

,'ur is

116 MARE;H ?080

IC!'

ahfe a,iltiuni Ft matenal aTitten centr .itiine rf th otcrtcring

since then has made AAS ex spcrier ire ca,.ch nig'tcr . Thetrem el y' well documented and hoerterences that are oL,et,ec

easy to OSe on a routine tasis_ D t- may ;trio illy h,,, due to phys :aWiled methodology r'ias 0 r elICC ,,_oh as visositp rather

most kinds of applieatiors . The than t~ ;!~~nical =f ;_ ., . Anotherdevelopment and growth of ICP camnnii rlarne AA interferenceemission have occurred more re - t, caused cy iontzatior. of easilyGentl y . The .tfnrrnation avail ionized .~peeics 1ac .̀ t a, the alkaliable, particularly in terms ofap- metals . WiL I t(P emission theplicat (ons, is ess comprehensive, degree of ionization 1, controlled ,bras is increasing as more lab- and ionization mterfzrences doorauirics acquire IC PW The re- not arpear to be a p-ob]enn . Wilticress articles mentioned carlier AAS, these interference ha,endudereferences toa,a i genum been identified and in general

her of papers dealing with1CP they ate sery easy Iu canirol Theemission amid applications . main advantage of lOP enlis,ro n

The greatest anal -heal capa- in this regard is that no >pecialhility' of 1CP emission is :hat re- sample preparation is required tofractory elements uch as boron, control chemical and ionizationphosphorus , tungsten , zir- interference sconium , niobium, and uranium Until recently most ICPs haveare determined very easily . These been designed to perform simul-elements can be determined by taneous multielement analyses-AAS only at high concentration as many a: 60 elements simulta-lescls . Even the development ofneously . For appl cations inIli- graphite It rnacehas not elim- which a large nuirber of elementsfnaied or changed this problem are to be determined in eachsignificantlS . For most elements ,ariiple, this is try far tic quickestthe detection limits for the LOP way t0 run samples . HCG{ise theare onre .kha : better than for plasma itscll a an Optically thatflame A,A, hi I rot ncaily an good ?niitisiuir ,uu :ce, the linear uurk-asforg,raphiFCIurnaceAA ingrange associated w,th ICl'si s

13ciaase of (lie extreniclc high around lour to sic orders of

temperatures and long residence magnitude , Ahich means that thetimes associated with the plasma, determination of trace to majorIUP emission is noted far is lack constituents can 'IC I Ii farmed si-of matrix interferences , known as rnultaneously with the sonic sam-chemical interferences in AAS A ple preparation aid dilution . Forclassic Illustration is the dc ; res- aboratories is which ihC samesion of a calcium signal by alums types of samples are always run,numor phocphaie in Game A AS . a system such as this can be useIn ICP emission tins depressive fu leffect is notnc :teed until the con - Howevcr, for many laborator-

5

n III III n i III I I RBNA03472472

HDMSe00042922

SPECTROMETRY continue d

-u 7 ee r,~ratur. ~1 „w u c : porcelain o plastic

ie> new and different sampletypes must he ruin . Using a directreadiae spectrun . uet, ~ hr . ;nalict

I .i ted to running element, and

,ample types that -were identifiedat '.hc snip- ill p °ar~ha~, e \ need

has arisen Ijr int" :tiici t, thatusc'heIt~Pi, : , iii , Lu.l . .lseascann :ni,! in Cii hits r : ." theeIhar-, n poll c :nrGmator Both

rass-l c 1 i Ru .mans ` Irtserecoi ,red th neec Icr and A accjt sey',ien ;i 11 [(-P, . A dtr e -ea,~ -ng sp .ctromrter is at erihle nut

only; in te :ni ; ni irn elerl2nt5 it

can dctcrroiur bin : al>o tilt, scave-length it te s, for :; ;, : h element .Tite best eruiss on line for boron

in winker i , CJt i~iL hr,t of:e fo rboron in steel b'e<,ue o f pectralinterferences tro n-, IIut This istrue for -nary other eL men(s aswell .

The problem of sp,ctij1 i :ucr-

ferchses is one that get crap} has

been gncred bs most ICY users .11 e,Cr , His Old con , tnon

apcctral interlercncc , I I .e teenidentified .- I sao are . Ito .t n inFigure Tli .s dines nit p-etcnt a

problem ssuh a ,cquential ICP

because other sv,nclenihi , _ ttherionic 'tannic in nature, ::aa beused . Atomic ahsltrpiina ,pectro-

scopY , howcscr, is relailsely free

of spectral intcrleren,es because

the et .tis ;o❑ ~oarce is nher the

element of inter , t 1 , I i a fill 'as

or, at most, escrai elenlenu,

ofie, rnultielcmert l amps are

u,.-d_ I hereto - e, it is casq to iso-

latca L Icn resvnuuec beak andperform yin :uuilat i n analysis

free lr , rni 1--di le pectral interferenccs . Atomic ab,orptionhasalwans had the advantage of spe-

cifictte .

An additional advantage ofAA's has been C IC relatively low

cw,i of the instrumentation incomparison to the costs of ICPs

wish nit] It ich :urnai capab .lilies;

many laboratories unaf Ic I,raf-ford ILPs turned toA.AS . if thenumber of element ; to b, . dete r

1 -•r, ..an elean , our old ones wit h

R13S n z ,,peen cIeaii inl agent ann cc i se, Polymer ResinsGr!•III, Chit-'F11~[ Ci i . in " Grca,ci ' N Is - Tta,.es i f

R tdt"~-I~rrs l cs pi,-I, rill iil, and I aceK Partially Carbonized

t„J P stdac~ I . c d Tars TcnactousPrectpdatcs Cedar AfIi .ut11 EP 111S( 7a

R1iti t ; I ;rtrn r, s t, shin ald elotFin , is hi dcg ; ;:dahle has iir iordret, >nrnu~~ . c

Teat it vou",ell aurl nt kill he sarpnscd at the csccllcnt results !

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SD('P -Cit . ilE a ._;St P7 .'S . or (',;Sii~C Or pnre rC_ri0.t S:• LJt n ! :tiro _rlir , .',: :. if . ty Cr f.; ailk corrects;rl r'eqacred

Pit- n nor,-,ry~j to clean . p

• rJ: r.urt°"; <, ii Pre sure serslsm,tde wrt i tsji- in cis- '• ~l~ ;L rrp , .,• 11 rl-It 3redJCt,on for plots Of vuiut l 1e31r1'e1dtS-

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BNA0347247 3III IIII IIIII IIIII II IIIII IIII Iiii I III E

HDMSe00042923

SPECTROMETRY continue d

Vw backeien d _)reciio0 measure-inc tt~ brce made at d ;fterent i ntonal- on c,i -I >IJe of tae peak todet .-mine I .a,_hne posi_tcii ac-Ltrr .1 l r "

it jpi a !I Am 1I1 Ii l~rl I l

ac l- 11-cc hor hilt' 1A-A5

H P c ii . cn, it th,- A\me ,ite i ~ciri~aticm~ . Th e

"I'll" r. is . . art a A

.all ,C tFc aT. I tl ,c rc-

ir r - II- I ori i lIe u .tl : dtf -

laLt n : : . :- U li~ ;l on does

at 'dot A-\s late the capacity

o ?ert 'rso and flame emis-sion, ir~~se e is emit ICP is

used as an , n,siuil ource, .Owe

of the cpi .~_a -sq_: rots t irechanged F it is rl 3 ;on, no_ allAA, Gsn he a ed I )r kAS anti

Icppr : :' n: hc tc,t ~

c 1 V~ .iuJ IC P . an w -

a,e ~as huti o ran>Ie- laht

o n he Ii' ul a w,~ Ill x041 1

rop ate,meter IIle, El

uter) . the 05tH) was desieced to

in_l~ : p~ru[e r, eats F- r,qi red

I ii ICF en :is, . t It ha, a igh-

.Itt pI:I ii ti ❑ n`; . uc!tI I llatrlI ,,lil t

a r :~ipro :al ir, .ur -ispersIt r Itii rivi mri -hc tirtt orlcr

ac" a rest~lnr un .st '-0 Q) Inn .h IC P it is mpottant to tare

eoe .l r-rAuioa b~.aux of 'I e

n_:rnbr A r i,s .iu,t I no s

prc ;cnt . i t filer ti;_tt an iCI' is

s~,, a x~ .~u svtr e rrca,~s prob

c'nK r. term : Si heir C aO .e IU R•-

~ .',e th_ t' Isticall, usctl e nis-itt ii l triin hcothcriines .the In "11 Inunt grating i s

Jr en b,' a di g tal stepper moto r)n :ri) eLl h'i tl0 I1 LIIL-l,l Ini0ro-

,trput-rT-'crform ICP vork

1 I t . ir,lc : is Tp.~itit io

has,_ tl h s0-1 .101 I tJ :asst t,ie

Ira only a, .rnl-rur :'-andd'gital

upper mi it can provide .

I?ccausc there ;re Sc many emir-

I can lines pre', ni a' th a typica l

120 MARCH 1980

-r .

WE

Figure 3 Tie !G? 3 rs'e-7, rcuarng tnc torsi aasembly .ndpoweiautosam r, lerc, and rata system

iPGfY,

sample, i1e wavelength ,ruing bet sects I'S ano 465 n-n In .his

must he ~ .r• accurate in order to wavelen3'h region tae opical el

Iind he :,)'reel peak . This is :rue fictency is s er'r close to tit it of a

tol ai-v ,cyucnt .a : ICP if it Is .o tonveniio :uills rand drat ng

Fc (tpcrnred in an outomanu bla ed a' P 10 rim Ahovc 45S ,m

nIJJC aruled erutine blec_d a'. '8U 'll a

Stray I,cht and 'he probianu is used to prop ide optimum perassociated with it havr_ tern d, formance in the sisit tC,-inn

cussed in detail br' Larsen et aL` Because serY tc',s elements arc de-A major source of stray light, termined atone 4OP nm and :trayknown as Rowland gI'nsr is tie light is not a _ionifi,~art prohiem,

imperfection is t rulec grating a holoprap :nic ,rating is not reLoused byperiod'c ciliary in krat- rfuitcd .:n,, groose spac .n! . inc,e :trots For case ;wi'choset tram \ .An ~t result of mer :'ttin cal Iinper- to ICP, th?'I'stem IFt",,re 3) was

cctioits [it illO ;Ming ongiuc used designed a th tic ICP gcrinan-'o make the master cranngs, ently mounted on one end . The

Thee n o - , and the graphite furance or burner forRowland ghost car, be el mina :ed flame AA i, ir:o uucd ri the nor-

byusing holographically rc orJ trial position for AA . Changeover

edgratings . Holographic gratincs from AA to IL ..' is achieved by

are produced n ; tuicg :ul [11C I- It inirig a knnh An optical inter-ference phennn,en?n impinged lace tolratutsr ci iis, on how theon a glass pl .ite ss,th an ,Optically ICP to the rr:onochromator waslei urfa e cnatcr' •aitn a photo- installed betsseenthe IC .P and thesensitive material gratings pro- 5000 . The lessing height of th es,used in is I:1ai1nCr a free of plasma iS r unrolled at the inter-

psrindicerr ii' in troo%c pacing face With this particular torch

;uld .Jill csti III( low lesels of dill eontigur . Lion the most com-

0! it scuucteJ Hg'lt . mcn viewing height is appri, ..l

?-n naint .tin optical ci icicrtcy mainly IS mm abo%c the coil, bit

tor optinurn AA pertcrmance, this can beadjusted as needed .

the nolugraplE- grating s blazed The instrument is capable of

at 210 nm anu :c,igncd for use having the entire optical pat h

n III III4~fI III I II

r

III IBNA03472474

HDMSe00042924

O1 iq/m cd t228 .502 rm -"

U girl As o pgirnlbiy2'28- ire 2043 rm ~ f

1

_,q -nI -I

t ~c .`55 ri m

3 .S rm 2:19a nm 202 3 rim 202.8 ri m

Figure / ctr rt it rrr e ; a it P a T` drier I, no

COIt1C ~rn 1nI rrv ;; ,I 29 ~' 2 , tit a

u_ crnnear ,,3 ?I 202 3 crn cra t,^c a! ? 1 2

m n I a ~_t n _arip ; ra i_

;i' cap ns a:are r -,,I .~a 1ur_ r ad y ,.~ch

1 :~~ Itl .rn ,I_P It h t, pr c

J` .i~a IC ',ll i'~it ; Jci red t>r

,in _u-al"is, ~l,imc ~ Sri I, ' .

i tiilre ~r.c~h :n~at~ have r~~ n

maJ° n,aln~lrln , lr ;i~l!~~c,~l,Si-iti Ps, prcc>ivn ril crnnin ;you than aithtaneASi( : V

fun burr proirr,> is tuarie in In-

derst3ncinr thr _uIt inc fief, F

sar, .p c tr,:dt .,'iuu anal

this p cci,ion d Flu rncc ma} bePoine v -mull~ r

f)rr: of I is hIs e>I 3Gr 3nt3~es

r A_AS is its ahilit': to u,c other

types 'C uncti/ it r 1 :1 'Mr,

such as ercohltc turn : :,,- nd

mei__urc l;cdride -'stem . B01)

Alici 1 i :e Seu,_s'S IaAC_ rcmly

low -red dtc ruin II 1 It tdr eIe -

II

~h, C I IL I i~ C r .1- ~

,:,i ihrr'5d the plasma .

u is ;r i,,tner prc,blam T i,I nsrrurren s. . the Ii Ii ht

an he ;au _d by gratinC rnr cr-

I~L I II : nr h .,,rrur A r lIt,II Ate r

deli o n . In _ rh 1 chrcmar r

;tens . tie pt,ublem of ceaimc

v In hackcrt urld hac been

an a e ; or ui perform baok-

oround _oirect .on, out thi ; -na ,,

Ilml . 1-or flea', H0iii' IOC _Calin 3

; ; 1 :1 .littcrVn clc :ucl-i : ; ~:sd

luanti3l ICP', towerer . Huse the

capa'oili15 I,) mei,urc hrrk-

ground on oneor both 'IA_- of

the prak at varying intervals, a

Aersa ri le means of back:erot .n d

i ituriiun . traylight has beenreduceu in someinstrumenva by afactor of 10, dependolg o n

ments that car tr I c-rmined condirion ; , withth - u :e of hclo

with them . With : h_ graphite fur - graphic gratings . Figure P , i ws

nace, detcet i3nlintii, Ire is mu : I

as tao orders of a Li .2it,tui , :: Iowci

than nnth I(- P emi'. ion . n add,

Lion, Ilrirto li : ;rs rt ~airple are

used is open ;ed t~) ne I ' ❑~illi-

liter- normally u ;cd'.alth in ICP .

A BAC5Jn ✓JVO Jti65--' t ~,

I'-; P1-CSP-u 'E l-: K

(06 c9 /RBI I' )

J 50 J, + m

If desired, in some sl uauon'; - n T -oa solid samplescan he Full ( n ilecil y

in the graphite furnace .In environmenlsl chemistr y

there is a great deal of interest indetermining mercury, arsenic,and selenium These elements arebest dctrrmir.cd by using a mercurb 1aride aen, r .rtor with anAAA Chr capability .,l 3ASto beused ,sith ihcsc alternateatcnucauon systems gases it atlc .ylbiliIv net yet completely real-ized by ICI' AIthough hydride

LOWER5660 CORP

UPPER8KGDCOR R

ANALYTE

Figure 2 An erarepic of uram or rPe-leImmaton In pnosphare ~QC,r r,,,background t0 measured at 0 12 ambelow theanalyie peak and 0 Ili 7,-7above.

outside the clean roo m

A[.OS80

Micro-Clean Adhesive Mats1011, u product c t

cop 606-CT ONE e

Circle except Service Card No . 6 6

AMERICAN LABCFPATC ° Y 119

n8

III I II II II III IIII 111 11 I nBNA0347247 5

HDMSe00042925

si r~u~„yen, hu, zicndin ga il' ran,( It hc fist ii-

n t ;t I ') US ITi . I oh,' n'_,rI CL~C'i ana Ct l

It ,`1)7 Ill ., d Id'J) I

t,p Mer r1'aa i is at l yl i

ni . tic r n;iti c C

F, F, hr, u, ipl 1orus anH ), [I'll, hr 1u,L l

n t c ;r rt ,~d, a ss :n ,'ICH LI.re-irn- .ith tcrr :h__,rai .nier ;er-

r _ul,,rl, she :l 1-,n i ; fir.I1 .1' rix I ' iv IF rieJ i ignre

hors, a pectn. Ill o fl'h•,,lvrt;~ und ; illnr r an inm

, cr : hels .,rn i- and '.?t r,n- .as t ae purg e

177 -m `JBS 147 N- TE IRC N.) b 00 m l

r . -tlumirtti, n is Ihr rg `"a , .[I,a iliLr, e17111I11Cer i s

needr1 frr c<, 1( 51 c[IJ is rest c . t

fhu da t . li l! .i ; i,c a c_cdicat_ i

01 _r,~e,~rnp ucr w h to I ,1S _l Ikc,l, ,ni .1 ~tiid i ( ST IS

d T he Oompu r hu haK ofm,^inr- rr : h rush tll ,py Jis r

iii . Tlu_ 114 ) iic ii,, SI nn .inin rat operating parameter s

and the na, c ; ,tCn olio arc, Lrir,1 IAio 1, i u cor,rutcr is pr o

grdmrn .i 'ole in I)A ;Ii ter use as aIahora :ory Scniputer. All

parameters ;or the S(ax) mein,'JCP operation are controlled bythe computer . flee r'a the opera-tor is prompted hr C,-c computer,prior computer traintnf, is ti nnIcessary .

Suf~uare nas been develope dti-at controls all instrument har,i-rierers, peak finding, qua ttita-ion of resu l ts, and sl atis., a lcatalysis of the ICP 5DOO. The

aoftware has Iwo operatin gmodes, one for single-elemen tand oiie for multielement anal yyes Because the rnultielement

mode i, made up of a series o frinela clement pruerams, the sin-gle-el-merit program will be di scussed Bes t

When the opcra :or chi hies th esingle -element mode by arrestingthe apptopriatC function Fes alorm appears on the ('RT Is ve t

LIP the ins(runten to run the ele-ment of intherest, the ope atorcanipletes the lorm that appear son the screen by entering dat athrough the es-board . Unee theform has been completed, the i nforniauvn, alone %ki[h he til ename and ret tiarks, c an I:c Lia m

ferred to a Ithraty disk for long-term .slot age . The process,o sloe-

g parametersor recalling them

s perto :mrd ~e pier ir. g cne o fthe labeled functicn Icss abovethe keihoard . Ali c r : .ni,rnl yu,ed CUfiinadnds itoe a n" 1e : ion .

cc ,~ Ihat iferato need no tr cus 7' I r

l !n_c f'•,c rrn_rlm. r. its ,^ ._

r

r on -1 -ether inu iii ii si,Ehe kerII)i t1 e - ~ :Z iii .ta',Is ur i ;

i jFIri,tiun ritii He ,,~ ta, .Ini-plcr . After the Rt neti

i,dcpoCs-cL.,nhc,,p_~ .t1uris -,2 5

the )ppCrr, .nitr I c a r

ng warelcnnth _alibrauon Th es pe-ator t 1 .°n is asked o aspiratetnc :first standard and pr,esRL .,,D .`,b hen this step in completed th enest inst, 1 ( lion is to aspirate theblar k and press READ This samesequence ecrr tinucs for ap tip tou rmCre stan,'.a-ds and for eac hsample rn he railneri_ ~~ hen theRUN ;t Ti mode is L~ciug u,ed,

the ', or mat a the sans t'xcept tha t

he -R I deploys inst-uct ,sn, forg uh tlic rAs-, i - <tu'r, .

pier . Aler a s set up, RCA ;) i spressed , and :he data s}st :n a ssumesContriII .

If a rnulliclrmeat program is

desired . t i, Iito nccc-, nary to fil lits i smcle cleman'' pa-ait-ehe rform i r is h eiOrnent to be d etens incd . ThL multie'cnrcn

t exam is deigned so that up to 2 0clerr.ents corn he determined ;A .'ter all single- element condi-[ion, h,ne IS-en entered alon g

with a method file naime, the e n

tire prier nnl : .iii he stored s i aHopp% drh ii I I IC _uudiuUn s

ana parainel have hccii :-tabitshed , the anal}si, pi oc~c ;l, i n

the same nay as the ringte-at ement `almaly-is with ht- exceptio nthat each ,lemcnt is dcicrniinc dsequentiadly - ,iron r~it .`i thi elowest wavelength and soinn i norder to the highest .

Finally, the eapahility to per-for-n h : It ninindcorrection i t5 xr1 iilC i,ItcrvplS on s rC or f7OUi

49I II I IIII II III III IBNA03472476

HDMSe00042926

2

to.

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fi3il uzge~beirr d 2.Just Costs Less !

CALL NOW 617 -272-521 2This powerful computer was designed for today's laboratory software -

programs, available thro ugh Eastern Analytical Laboratory.The Bluebird 2 is e, complete all in one computer systems offeri ng the . : .

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of III I IIII II III IIII II II II

BNA03472477

lidos it tie anal,lc peak is as

ti egra . part of the oft,,, arc te r

the 1l P, 50th". title ntpu ~anLe o f

being able to vary tt e lot rsal ;

whi,h the background is c~eas-

ured has been sh,-,%riexample of a situation 1 whic hthis would arise is Shottir, in F g

ure

(:anrhls :on

'v ,hasThe authors' aim `a a sthe almplelr.enrtr~ at lyre cif IC P

einisaion and atomi . absorption .The Jul i du iwinttuted that bot htechniques have a place in ir e

analytical laboratory ins •,ti, i Lbe used in conju act .on snith cac t

other . A second goal was to de-termine if an ICP could be suc-

cessfu lty interfaced to an A A

This was proved feasible with a n

instrument that can be operate sat optimal conditions for either

technique.

Reference s

FAoSEL . Arh Seer 202, 101r 197 i i

ufREFNFlEl i SIC EACHIN ,

H 51 , IF C. 0.1 I H . I' ii , aran ( u 23, . . .

IIs-6 )

3 . B,JUoI ss-, P w I SI ord DE BOER.

t, 1 Pro -1naL I Chem . Sec

,2, I400 9'S )a, AL.`,IL ~. . Jpacvorh tin . -1 71a 7,

Ii0 (195 5 .

5 . F 1SSEL " .A ., Arta! . Cher, 51. (11) ,

6 11'1151 sN5, I' .W J'1 .4,uI 'ii 1 (, 1 ,

<35 197S) .

F OIt LR R.D dnA F1 RNANiDEL.

F j ., gaper presented at -ederauo n

.r Analytical Chemistry and Specr aeopy Society Meeting, 1979 .

6 . . w .\RD,A F., CARARRA, L .A., an d

SIARCIELLO, C .F ... : paper presen teda . Federation of AnalytlcalChcmiItry and Spectroscopy Society Meet-ing, 1979 .

9. LARSEN, S F . F 4SSRL, V a

WINCE . R K , and h.NISFLES . R . N

AppI. Spn t' "- C )4), -'4 11910-

WALLACE. G .F . and ROULT. D W ..

paper prescnted at Federation ofAnalyneat Chemistry and Sprxuo-

scopy Society Meeting, 1979.

v ~ a t r a actr~ phcIra a e . T O

1-?s .ire a

prcd- air?~c ~,a ,~,,~ rcen

;I J-1 .•re 1 n,-a'ed m

7c- n1a ld rn s-an 3f"9'l a aP t r ." 1 11'F,r - 'aa, in s

1 ih , ar t

3 rli-,, Fr r---riry cr-,afy Commerce Road ,

St3 nfr r .l Ti CG0N (2Q'~) 343 at3 1

BARNES Your IR spectroscopy sourceCircle Reade r Se rv ic e Card No. 14 6

Circle Reader Se rv ice Card No,21

AMERICAN LABORATORY 123

HDMSe0004292 7

. - I C "D' disc• L3H,',r t,'1 _rass . . I , . fl »stem

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• Two "9c Mcm processors• A- (-beratarig System

-hero screen image

Ri,yged Vonstrucuon

` 52995 .00 complete system

A A A rACft fNT = 4'&c,ooo

the JY.i8P DlTect Readingi PJcsmatlementdl Analyzerss des~ned to ~,~.,Tapld

~ 1ement1attomeoasmuulUemtrgladilysis bh a loupeusers a4samp7es 'l~ 1p il„~

Ies oe materials that canby the.JY-18P1nanb

e. water and waste waferpies. all samples (tnclud-,addilives and wear o*Is)1ges, biologicals. dedloal~

als . metals. alloyse general principles of ap7-wito1tine JY-48P are rela--

I9elY ample . SadioirequeecybdiatIoa kissed to heat a 42.

o gm snto a pi ma ayoe an inductl i foil.

Yen a sample filrdroduciUMMo 2&'eztremd* hofA500D lc

11)000'10 argon p105mQ.'Ib9 -

-f ple Isbrokendown Into Iii` imdnal atom- L which are then

urUter excited by the ptastaa_eseeiadted atoms then Memit thLs` energy as elec-

comapnettc rcfdtation (lgbt) !Er t:5ehIch is Chd

chemicalelementsa'he emirtad light is thenpassed into thespec trometer ofthe JY-48P. The spectrometer

' ,.dlspelses the light across Itslocal curve. sep rc ring thevarious emission lines present1t}iherotdiatlon.Atapproprtate:

on the local curveore i-;2'=ed photomuttlptieilutes: one for oath aaalytlcd

'J%e desired on the system.-these convert the light energy =•

~miited by the atoms lIItO-eJeL=;-bical cssrrents.-

The current tram each ;pho#omulitpliertube istnteg= ,#

over a period of time (on,the orof seconds). and iizen

;~Iigitized so that the data may`be Ied into a computer for star:age and calculations Anaiytltat results can then be printe d

-but on the computer terminaLor displayed on avideo screent. The computer. besides cal-lecting data and calculatingresult- also controls the Overalllundioning otthespectrometer,,,

72na%dng the sysfemreasonably"automadia and removing

operatormom the system,dependence.1

IIIIIIIII II ~III IBNA0347247 8

HDMSe00042928