HBr , V(m+i), i = 4-8,10 agust/rannsoknir/Crete/PPT-131202x
-
Upload
ray-gilliam -
Category
Documents
-
view
217 -
download
0
description
Transcript of HBr , V(m+i), i = 4-8,10 agust/rannsoknir/Crete/PPT-131202x
HBr,V(m+i), i = 4-8,10
https://notendur.hi.is/~agust/rannsoknir/Crete/PPT-131202.pptx
https://notendur.hi.is/~agust/rannsoknir/Crete/PXP-131203.pxphttps://notendur.hi.is/~agust/rannsoknir/Crete/XLS-131203.xlsx
8
6
4
2
0
3.02.52.01.51.00.50.0
H+ + Br(1/2)
H+ + Br(3/2)Normalized
HBr, V(m+i)´s
V(m+10)
V(m+8) V(m+7) V(m+6) V(m+5)V(m+4)
H+ <- HBr+(v´)
Agust,lab top,C:/…/PXP-131127a.pxp ; Gr0, Lay0
KER/eV
2.5
2.0
1.5
1.0
0.5
0.0
3.02.52.01.5
HBr; 3/2 <-3/2transitions
KER/eV
V(m+10)
V(m+8)
V(m+7)
V(m+6)
V(m+5)
V(m+4)
Agust,lab top,C:/…/PXP-131127a.pxp ; Gr0, Lay0 <= XLS-131127.xls („KER,I,II“)
3.0
2.5
2.0
1.5
1.0
0.5
0.0
3.02.52.01.51.00.50.0
V(m+6)
V(m+5)
V(m+4)
KER/eV Agust,heima & lab top,C:/…/PXP-131129.pxp ; Gr1, Lay1 <= XLS-131127.xls („KER,I,II“)
v+= 8 10 12 13
v+= 8 10 12 13
v+= 8 10 12 13
HBr; 3/2 <-3/2TransitionsKER spectra normalized to the H+ + Br(3/2)channel
8
6
4
2
0
3.02.52.01.51.00.50.0 KER/eV Agust heima&,lab top,C:/…/PXP-131129.pxp ; Gr2, Lay2 <= XLS-131127.xls („KER,I,II“)
V(m+10)
V(m+8)
V(m+7)
v+= 8 10 12 13 15
v+= 8 10 12 13
v+= 8 10 12 13
HBr; 3/2 <-3/2TransitionsKER spectra normalized to the H+ + Br(3/2)channel
2.5
2.0
1.5
1.0
0.5
0.0
3.02.52.01.5 KER/eV agust heima/…/PXP-131202.pxp ; Gr0, Lay0 <= XLS-131202.xls („KER,III,IV“)
HBr; 1/2 <-1/2transitions
?
3.0
2.5
2.0
1.5
1.0
0.5
0.0
3.02.52.01.51.00.50.0 KER/eV agust heima/…/PXP-131202.pxp ; Gr1 Lay1
HBr; 3/2 <-3/2 (bold sticks) &1/2 <-1/2 (thin sticks)
v+= 8 10 11 12 8 9 10
v+= 8 10 12 13
8 9 10
v+= 8 10 12 13
8 9 10 11
V(m+6)
V(m+5)
V(m+4)
8
6
4
2
0
3.02.52.01.51.00.50.0
v+= 8 10 12 13
8 9 10
v+= 8 10 12 13
8 9 10 11
v+= 8 10 12 13 15
9 10 11
HBr; 3/2 <-3/2 (bold sticks) &1/2 <-1/2 (thin sticks)
KER/eV agust heima/…/PXP-131202.pxp ; Gr1 Lay1
V(m+10)
V(m+8)
V(m+7)
3.0
2.5
2.0
1.5
1.0
0.5
0.0
3.02.52.01.51.00.50.0 KER/eV agust heima/…/PXP-131203.pxp ; Gr1 Lay1
HBr; 1/2 <-3/2 (bold sticks) &3/2 <-1/2 (thin sticks)
v+= 10 12 13
6 7 8 9
v+= 10 12 13
6 7 8 9
v+= 10 12 13 6 7 8 9
V(m+6)
V(m+5)
V(m+4)
8
6
4
2
0
3.02.52.01.51.00.50.0
HBr; 1/2 <-3/2 (bold sticks) &3/2 <-1/2 (thin sticks)
KER/eV agust heima/…/PXP-131203.pxp ; Gr2 Lay2
v+= 10 12 13 15
6 7 8 9
v+= 10 12 13
6 7 8
v+= 10 12 13
6 7 8
V(m+10)
V(m+8)
V(m+7)
1.0
0.8
0.6
0.4
0.2
0.0
2.52.01.51.00.50.0
https://notendur.hi.is/~agust/rannsoknir/Crete/PXP-131208.pxp
HBr; 3/2 <-3/2 (bold sticks) &1/2 <-1/2 (thin sticks)
KER/eV
E(0),J´=1
v+= 8 10 11 12 13 9 10
The vibrational structure in the„H+ + Br/Br* via HBr+(v+) ionization channel“ isdue to a combination of H+ + Br(3/2) <- HBr+(v+)(3/2) (i.e. 3/2 <-3/2)andH+ + Br(1/2) <- HBr+(v+)(1/2) (i.e. 1/2 <-1/2)transitions
1.25x105
1.20
1.15
1.10
1.05
1.00
0.95
Ene
rgy
/cm
-1
1.31.21.11.00.9
Internuclear Distance / Å
v+(3/2)1615
1413
12
11
10
v+(1/2)1413
12
11
10
9
8
V(m+10)
https://notendur.hi.is/~agust/rannsoknir/Crete/PXP-131203.pxp
1.25x105
1.20
1.15
1.10
1.05
1.00
0.95
Ene
rgy
/cm
-1
1.31.21.11.00.9
Internuclear Distance / Å
v+(3/2)1615
1413
12
11
10
v+(1/2)1413
12
11
10
9
8
V(m+8)
https://notendur.hi.is/~agust/rannsoknir/Crete/PXP-131203.pxp
1.25x105
1.20
1.15
1.10
1.05
1.00
0.95
Ene
rgy
/cm
-1
1.31.21.11.00.9
Internuclear Distance / Å
v+(3/2)1615
1413
12
11
10
v+(1/2)1413
12
11
10
9
8
V(m+7)
https://notendur.hi.is/~agust/rannsoknir/Crete/PXP-131203.pxp
1.25x105
1.20
1.15
1.10
1.05
1.00
0.95
Ene
rgy
/cm
-1
1.31.21.11.00.9
Internuclear Distance / Å
v+(3/2)1615
1413
12
11
10
v+(1/2)1413
12
11
10
9
8
V(m+6)
https://notendur.hi.is/~agust/rannsoknir/Crete/PXP-131203.pxp
1.25x105
1.20
1.15
1.10
1.05
1.00
0.95
Ene
rgy
/cm
-1
1.31.21.11.00.9
Internuclear Distance / Å
v+(3/2)1615
1413
12
11
10
v+(1/2)1413
12
11
10
9
8
V(m+5)
https://notendur.hi.is/~agust/rannsoknir/Crete/PXP-131203.pxp
1.25x105
1.20
1.15
1.10
1.05
1.00
0.95
Ene
rgy
/cm
-1
1.31.21.11.00.9
Internuclear Distance / Å
v+(3/2)1615
1413
12
11
10
v+(1/2)1413
12
11
10
9
8
V(m+4)
https://notendur.hi.is/~agust/rannsoknir/Crete/PXP-131203.pxp
V+max(3/2) V+max(1/2)
spectra calc spectra calc
V(m+10) 16 16 ? 14
V(m+8) 14 14 ? 13
V(m+7) 14 14 ? 12
V(m+6) 13 13 ? 11
V(m+5) 12 12 ? 11
V(m+4) 12 12 ? 10
1.4x105
1.3
1.2
1.1
1.0
0.9
0.8
Ene
rgy
/cm
-1
54321
Internuclear Distance / Å
[4P,5s] Rydb.
H + Br**(5s)
H*(n=2)+Br
H+ + Br-
H+Br+ + e
H++Br+e
[B2S+] ..superexcited state
[(3)2P] ..superexcited state
HBr+*(A)
HBr+(X)
2hn to V(m+7)
https://notendur.hi.is/~agust/rannsoknir/Crete/PXP-131203.pxp
V
F
H
HBr+*(X)
v+=14v+=12
E
8
6
4
2
0
3.02.52.01.51.00.50.0
H+ + Br(1/2)
H+ + Br(3/2)Normalized
HBr, V(m+i)´s
V(m+10) V(m+9) V(m+8) V(m+7) V(m+6) V(m+5)V(m+4)
H+ <- HBr+(v´)
KER/eV
https://notendur.hi.is/~agust/rannsoknir/Crete/PXP-131209a.pxp ; Gr0 Lay0