HAZCOM & CHEMSAF

7/23/2019 HAZCOM & CHEMSAF

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Hazard Communication& Chemical Safety

Based on OSHAStandard

1910.1200


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Hazard Communication

OSHA Hazard Communication Standard 29CFR 1910.1200 !Ri"ht to #no$% $ent intoeect in 'o(em)er 19*+. Often referred to a,

!Hazcom.% OSHA ha, re(i,ed the Hazard Communication

Standard to )e more in line $ith "lo)al,y,tem,. -he ne$ lo)ally Harmonized

Sy,tem /HS ,tandardize, ,afety data ,heet,and u,e, icto"ram, that can )e under,toodre"ardle,, of a er,on, nati(e lan"ua"e.


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-he uro,e of Hazcom i, to en,ure thatinformation concernin" hazard, a,,ociated$ith the $or3lace i, tran,mitted to

emloyee,.

4ou5 a, an emloyee5 ha(e a Ri"ht to #no$a)out the hazard, in your $or3 areaand

the otential eect, of the,e hazard, uonyour health and ,afety.


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6t may ,eem ea,y enou"h to e7ect chemical,and hy,ical hazard, to )e in la),5 ,ho,5 andmaintenance area,5 ho$e(er hazard, can al,o)e found in o8ce,5 cla,,room,5 and other $or3area,.

-he,e may include

Coier:rinter toner, ;ry era,e cleaner,

Cleanin" chemical, ,ray,


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=e u,e many chemical, Hazardou, material, /chemical roduct, and

hy,ical a"ent, /radiation5 la,er,5 (i)ration5etc. can )e found any$here.6t ha, )eene,timated that o(er a half million chemical

roduct, are u,ed )y )u,ine,, and indu,trye(ery year. Some of the,e hazard, o,e littledan"er to you5 $hile other, may )e deadly.

>odern manufacturin" $ould not )e o,,i)le$ithout chemical, and roce,,e,. Ho$e(er5 li3emachinery or electrical e?uiment5 you mu,t3no$ ho$ to u,e chemical, ,afely.


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=e u,e many chemical,

-he @r,t ,te in u,in" chemical, androce,,e, ,afely i, to reco"nize tho,e

material, and roce,,e, that may )ehazardou, to your health or hy,ical,afety.


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=e u,e many chemical,

=e $ant you to 3no$ ho$ to u,e them ,afely

4ou $ill learn a)out

The Hazards of Chemicals Our Written Proram

Ho! Chemicals are "a#eled Safe $se of Chemicals

%aterial Safet& 'ata Sheets Basic Procedures for S(ills

Who &ou can as) for more information


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Hazard, of Chemical,

-here are 2 )a,ic tye, of chemicalhazard,

hy,ical Hazard, Health Hazard,

-he @r,t rule of Chemical ,afety i,

B#no$ $hat you are $or3in" $ithand ho$ to rotect your,elf andother,!


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hy,ical Hazard,

Chemical, are cla,,i@ed a, ha(in"Ph&sical Hazardsif they are

*+(losi,e

Com(ressed -as

Com#usti#le "iuids

/lamma#le

$nsta#le

Water eacti,e

O+idizers


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hy,ical Hazard,

Some chemicals ma& #e safe #&

themsel,es #ut #ecomedanerous !hen in contact!ith other su#stances.


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Chemicals !ith Ph&sicalHazards

$sed onl& #& trainedem(lo&ees

Stored in a safe manner3e,er mi+ed !ith other

chemicals unless #& an

a((ro,ed (rocedure


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Health Hazard,

Chemical, are cla,,i@ed a, )ein" ahealth hazard if they

Can cau,e cancer Are oi,onou, /to7ic Cau,e harm to your ,3in5 internal

or"an,5 or ner(ou, ,y,tem

Are corro,i(e ,uch a, acid, Cau,e aller"ic reaction, after reeated

e7o,ure


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Chemicals can enter the #od&

throuh4&our lunsif you )reath

fume,5 mi,t, or du,t

&our s)inif li?uid or du,t

touche, or ,ill, on youor ,la,he, in your eye,

&our mouthif you eatafter handlin" chemical,

accidental s!allo!inof a chemical


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Health Dect,

Some chemicalsa5ect s(eci6c

orans such as&our )idne&sli,er

re(roducti,e orner,ous s&stem.


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Our Written HazardCommunication Proram

(ro,ides=ritten information on hazard,

Ei,t, Chemical, $e u,e and their

hazard,Sy,tem for en,urin" chemical, are

la)eled

>ean, to en,ure $e ha(e an>aterial Safety ;ata Sheet />S;Sfor each chemical


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Our =ritten Hazard

Communication ro"ramEi,t, $ho i, re,on,i)le for the

ro"ram

ro(ide, chemical ,eci@c ,afetytrainin" method,

-ell, you $here to @nd chemical

,afety information7ou can see a the !ritten (roram

#& as)in &our su(er,isor


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Our =ritten Hazard

Communication ro"ramEi,t, $ho i, re,on,i)le for the

ro"ram

ro(ide, chemical ,eci@c ,afetytrainin" method,

-ell, you $here to @nd chemical

,afety information7ou can see a the !ritten (roram

#& as)in &our su(er,isor


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Ea)elin" of Chemical,Chemical Ea)el, ro(ide

information on 6dentity5Hazard, and Safe ,e

All chemical container, arela)eled)y themanufacturer

-he comany may laceadditional la)el,on thecontainer,


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Ea)elin" of Chemical, OSHA has u(dated the reuirements for la#elin of

hazardous chemicals under its Hazcom Standard8HCS.

As of :une 1 201; all la#els !ill #e reuired to ha,e4

G Pictorams

G Sinal !ords

G Hazard and (recautionar& statements

G Product identi6erG Su((lier identi6cation


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# li f Ch i l


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"a#elin of Chemicals


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Ea)elin" of Chemical,

6f chemical, are laced in anothercontainer5 thi, ne$ container mu,t

ha(e a a la)el laced on it.

All container, mu,t )e roerly

la)eled


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niform Ea)elin"

Sy,temOur Comany !niform Ea)el,% are

u,ed to en,ure $e ha(e one

la)elin" ,y,tem.

-he,e may )e laced on container,

$hen chemical, are deli(ered to u,or chemical, are tran,ferred toother container,


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2 a,ic !niform Ea)el,%

H%aterial 6denti@cationSy,tem

3/PA 'ational Fire rotection A,,ociation

Both t&(es must identif& the

chemical name and hazards


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niform Ea)el,

icture, may )e u,ed toidentify hazard, and

re?uired rotection

-hi, 6nformation may

al,o )e on the>anufacturer, la)el


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H>6S & 'FA la)el, are (ery

,imilaroth u,e colored )o7e, to identify

,eci@c hazard,

'um)er, or code, in the )o7e, tellyou the hazard (alue

hiher num#ers = hiher hazard


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'FA & H>6S Ea)el Color,

ed Fire Hazard

Blue Health Hazard

7ello!7ello! Reacti(ity Hazard e7lo,i(e5 un,ta)le

WhiteWhite Secial Hazard, corro,i(e5

radioacti(e5 $ater reacti(e5 acid


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H%


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'FA Ea)el..The (ur(ose of the 3/PA>0? la#elin s&stem is to(ro,ide a !a& of uic)l&identif&in the ,arious 6re

related hazardousassociated !ith a(articular material. The3/PA >0? @diamond@ iscommonl& found on #ul)storae containers #ut isalso !idel& used onchemical containers and%S'S sheets.
http://www.fiu.edu/~ehs/_vti_bin/shtml.exe/nfpa704.htm/map


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'FA Flamma)ility Code,

?%aterials that !ill ra(idl& orcom(letel& ,a(orize at atmos(heric(ressure and normal am#ient

tem(erature or that are readil&dis(ersed in air and that !ill #urnreadil&. "iuids !ith a ash(oint#elo! >/ and a #oilin (oint

#elo! 100/.
http://www.fiu.edu/~ehs/_vti_bin/shtml.exe/nfpa704.htm/maphttp://www.fiu.edu/~ehs/_vti_bin/shtml.exe/nfpa704.htm/maphttp://www.fiu.edu/~ehs/_vti_bin/shtml.exe/nfpa704.htm/map


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"iuids and solid that can #einited under almost all am#ient

tem(erature conditions. "iuids!ith a ash(oint #elo! >/ and a#oilin (oint a#o,e 100/ or liuids!ith a ash(oint a#o,e >/ #ut

not e+ceedin 100/ and a #oilin(oint #elo! 100/.


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2 %aterials that must #e moderatel&heated or e+(osed to relati,el&

hih am#ient tem(eratures #eforeinition can occur. "iuids !ithash(oint a#o,e 100/#ut note+ceedin 200/.
http://www.fiu.edu/~ehs/_vti_bin/shtml.exe/nfpa704.htm/maphttp://www.fiu.edu/~ehs/_vti_bin/shtml.exe/nfpa704.htm/map


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1>aterial, that mu,t )e reheated)efore i"nition can occur. Ei?uid, that

ha(e a Ia,hoint a)o(e 200JF.

0 >aterial, that $ill not )urn.


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'FA Health Hazard Code,

?%aterials that on ,er&short e+(osure couldcause death or maDorresidual inDur&.

%aterials that on short

e+(osure could causeserious tem(orar& orresidual inDur&.


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2%aterials that onintense or continued

#ut not chronice+(osure could causeinca(acitation or(ossi#le residual inDur&.


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1>aterial, that on e7o,ure$ould cau,e irritation )ut onlyminor re,idual inKury.

0>aterial, that on e7o,ureunder @re condition, $ould

oer no hazard )eyond that ofordinary com)u,ti)lematerial.


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'FA Reacti(ity Hazard

Code,?%aterials that in themsel,es are

readil& ca(a#le of detonation or of

e+(losi,e decom(osition orreaction at normal tem(eraturesand (ressures.


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Code, %aterials that in themsel,es

are ca(a#le of detonation or

e+(losi,e decom(osition orreaction #ut reuire astron initiatin source or!hich must #e heated under

con6nement #eforeinitiation or !hich reacte+(losi,el& !ith !ater.


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Code,2%aterials that readil& undero

,iolent chemical chane at ele,ated

tem(eratures and (ressures or!hich react ,iolentl& !ith !ater or!hich ma& form e+(losi,e mi+tures!ith !ater.


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'FA Reacti(ity Code,

1%aterials that in themsel,es arenormall& sta#le #ut !hich can

#ecome unsta#le at ele,atedtem(eratures and (ressures.


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'FA Reacti(ity Code,

0%aterials that in themsel,es arenormall& sta#le e,en under 6re

e+(osure conditions and !hich arenot reacti,e !ith !ater.


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'FA Secial Hazard

Code,AC6; L Acid roduct,AE# L Al3ali or a,e,

COR L Corro,i(e roduct,

OM L O7idizer

= LReact, $ith $ater

Radioacti(e


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=hat do 6 do

if there i, no la)el or 6 cannot readthe la)elN

STOP do not u,e the chemicalT*""your ,uer(i,or

*A'the >S;S and ha(e another

la)el ut on the container


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Chemical, can )e ,afely u,edif

you 3no$ the hazard, and ho$ torotect your,elf

they are u,ed only for aro(eduro,e,

they are ,tored roerly

you u,e the correct er,onalrotecti(e e?uiment


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Chemical, can )e ,afely u,edif

you do not eat in area, $herechemical, are u,ed

you $a,h immediately if you comein contact $ith chemical,


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Chemical ;i,o,al

Dach chemical and container mu,t)e di,o,ed of roerly

'o container i, truly BemtyBunle,, roerly cleaned

Follo$ >S;S re?uirement, for

container di,o,al


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Chemical ;i,o,al

Recycle unu,edchemical,

;o not lace hazardou,chemical, in normaltra,h recetacle,.

'o not (our

chemicals into sin)sonto the round orin storm drains


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Safe Stora"e

Store incomati)le chemical, in,earate area,

Eimit the amount of Iamma)lematerial to the minimum needed

Store Iamma)le li?uid, in

aro(ed Iamma)le ,tora"eloc3er,


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Safe Stora"e

Store acid, in ,earate Iamma)le,tora"e loc3er,

;o not ,tore chemical, in arefri"erator u,ed for food ,tora"e

;o not ,tore food in refri"erator,

u,ed for chemical ,tora"e


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6n ca,e of an emer"ency

6mlement the roer Dmer"encyAction lan

D(acuate eole from the area6,olate the area 3ee other from

enterin"

-urn o i"nition and heat ,ource,Only trained emloyee, areermitted to clean u ,ill,


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>aterial Safety ;ata Sheet,

/>S;SSho$ chemical ,afety information

Dach chemical ha, a ,earate >S;S

>S;S i, $ritten )y the chemicalmanufacturer

>S;S are 3et in the $or3lace foryour u,e


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>aterial Safety ;ata Sheet,

are (ro,ided #& the chemical manufacturerto (ro,ide additional informationconcernin safe use of the (roduct.

%aterial Safet& 'ata Sheets 8%S'S

Current /ormat

F

Safet& 'ata Sheets 8S'S

3e! format reuired #& :une 1 201;


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Dach >S;S tell, you

1. Common 'ame and Chemical'ame of the material

2. 'ame5 addre,, and hone num)erof the manufacturer

. Dmer"ency hone num)er, for

immediate hazard informationP. ;ate the >S;S $a, $ritten


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>S;S

+. Hazardou, in"redient,

. hy,ical & Health Hazard, of the

chemical,. 6denti@cation of chemical and

hy,ical roertie,

*. Fir,t Aid : Dmer"ency 6nformation9. Safe handlin" and u,e information


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>S;S

ha(e ,eci@c hazard information on Fire & D7lo,ion

Chemical Reaction, Control >ea,ure,

Health Hazard,

Sill & Eea3 rocedure,


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>S;S /ire F *+(losionaterial Fla,h oint5 autoi"nition temerature anduer:lo$er Iamma)ility

limit,Fire e7tin"ui,hin" a"ent,

to )e u,ed

Fire @"htin" techni?ue,

Any unu,ual @re ore7lo,i(e hazard,


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>S;S eaction


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>S;S Control %easures

Dn"ineerin" Control, re?uired for,afe roduct u,e

er,onal rotecti(e e?uimentre?uired for u,e of roduct

Safe ,tora"e re?uirement, and

"uideline,Safe handlin" rocedure,


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>S;S Health Hazards

Permissi#le *+(osure andThreshold "imits 8P*" F T"G

S&m(toms of e+(osureoutes of entr& into the #od&

%edical conditions that can #emade !orse #& e+(osure

Cancer causin (ro(erties

*merenc& F /irst Aid Procedures

S S


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>S;S S(ill F "ea)Procedures

Clean u techni?ue,

er,onal rotecti(e D?uiment to

)e u,ed durin" cleanu;i,o,al of $a,te & cleanu

material


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rotectin" 4our,elf

er,onal rotecti(eD?uiment /D may )eneeded to rotect your,elf

from chemical hazard,,e the D our Comany

ha, re?uired for eachchemical

Chec3 the D )efore u,e toma3e ,ure it i, notdama"ed


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rotectin" 4our,elf

,e face ,hield and o""le, ifthere i, a ,la,h hazard

,e the roer re,irator for du,t,5mi,t, and fume,


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rotectin" 4our,elf

,e the ri"ht "lo(e, $hen handlin"chemical,

roerly clean and ,tore your Dafter u,e

;onTt ta3e D home $hy ri,3

e7o,in" your familyN

St f h i


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Stay ,afe $hen u,in"chemical,

#no$ $hat you are $or3in" $ith

#no$ $here >S;S are located and

ho$ to u,e themA,3 your ,uer(i,or if you ha(e

?ue,tion,

Only trained emloyee, may u,echemical,


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Stay Safe

>a3e ,ure all container,are roerly la)eled

,e the roer rotecti(ee?uiment

Store chemical, only inaro(ed area,

6mmediately reort lea3,and ,ill,

;i,o,eof u,ed chemical,and container, roerly


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THA3 7O$

A3'

-O' B"*SS..

HAZCOM & CHEMSAF

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