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Transcript of Harry Kroto 2004 Sodium Flame Test. © at:...
Harry Kroto 2004
Sodium Flame Test
©at: commons.wikimedia.org/wiki/File:Flametest--Na...
©
Emission Spectrum of a sodium lamp
Absorption Spectrum of sodium atoms
at: web.me.com/dtrapp/ePhysics.f/labII_9.html
Na D lines Orange street lamps - sodium
Fraunhofer Absorption Lines in the Sun’s Spectrum
Harry Kroto 2004
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Electron Configurations of Sodium
Harry Kroto 2004
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Electron Configurations of Sodium
Harry Kroto 2004
1s2 2s2 2p63s1
Electron Configurations of Sodium
2S
Harry Kroto 2004
1s2 2s2 2p63s1
Electron Configurations of Sodium
2S
Harry Kroto 2004
1s2 2s2 2p63s11s2 2s2 2p63p1
2P
Electron Configurations of Sodium
2S
Harry Kroto 2004
1s2 2s2 2p63s11s2 2s2 2p63p1
2P
Electron Configurations of Sodium
2S
Harry Kroto 2004
1s2 2s2 2p63s11s2 2s2 2p63p1
2P1/2 2P
Electron Configurations of Sodium
2P3/2
2S
Harry Kroto 2004
1s2 2s2 2p63s11s2 2s2 2p63p1
2P1/2 2P
Electron Configurations of Sodium
Spin orbit coupling
2P3/2
2S
Harry Kroto 2004
1s2 2s2 2p63s11s2 2s2 2p63p1
2P1/2 2P
N2N2
Electron Configurations of Sodium
589.00 nm
589.59 nm
Spin orbit coupling
2P3/2
2S
Harry Kroto 2004
1s2 2s2 2p63s11s2 2s2 2p63p1
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Wikipedia Sodium D Lines
A dye laser used at the Starfire Optical Range for LIDAR and laser guide star experiments is tuned to the sodium D line and used to excite sodium atoms in the upper atmosphere.
©at: hyperphysics.phy-astr.gsu.edu/.../sodzee.html
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In Voltaire’s “Elémens de la Theorie de Newton“ (1738)
Harry Kroto 2004
Harry Kroto 2004
Flame generated by the burning of a candle.
http://www.nationmaster.com/encyclopedia/Flame
Harry Kroto 2004
Image of a flame test for sodium. Note that the yellow color in this gas flame does not arise from the blackbody emission of soot particles (as the flame is clearly a blue premixed complete combustion flame) but instead comes from the spectral line emission of sodium atoms, specifically the very intense "sodium D lines"