1/10/13 Germanium(IV) chloride for synthesis | Merck Mill ipore Malaysia

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804079 Germanium(IV) chloride for synthesis

For genera l questions p lease contact our Custom er Service:

Merck KGaA

Frankfurter Str. 250

64293 Darm stadt

Germ any

Phone: +49 6151 72-0

Fax: +49 6151 72 2000

10 January 2013

Product number Packaging Qty/Pk

8040790025 Glass bottle 25 ml

Product information

Synonym s Germanium tetrachloride

Hi l l Form ula Cl4Ge

Chem ical form ula GeCl4

HS Code 2827 39 85

EC num ber 233-116-7

Molar m ass 214.4 g/mol

CAS num ber 10038-98-9

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Chemical and physical data

Solubi l i ty (20 °C) Hydrolysis,(decomposition)

Mel ting point -49.5 °C

Molar m ass 214.4 g/mol

Densi ty 1.88 g/cm3 (20 °C)

pH value < - 1 (H2O, 20 °C)

Boi l ing point 83.1 °C

Vapor pressure 101 hPa

Safety information according to GHS

Hazard

Statem ent(s)

H314: Causes severe skin burns and eye damage.

H335: May cause respiratory irritation.

EUH014: Reacts violently with water.

Precautionary

Statem ent(s)

P280: Wear protective gloves/ protective clothing/ eye protection/ face

protection.

P301 + P330 + P331: IF SWALLOWED: rinse mouth. Do NOT induce

vomiting.

P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a

position comfortable for breathing.

P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several

minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P309 + P310: IF exposed or if you feel unwell: Immediately call a POISON

CENTER or doctor/physician.

Signal Word Danger

Hazard

Pictogram (s)

Germanium(IV) chloride for synthesis | Merck Mill ipore Malaysia

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RTECS LY5225000

Storage class 8B Non-combustible, corrosive hazardous materials

WGK WGK 1 slightly water endangering

Disposal 24

Liquid inorganic halides and hydrolysis-sensitive reagents can be carefully

stirred dropwise into ice-cool 10% sodium hydroxide solution (Cat. No.

105587) (caution: caustic gases!); container D or E.

Safety information

R Phrase R 14-34-37-52

Reacts violently with water.Causes burns.Irritating to respiratory

system.Harmful to aquatic organisms.

S Phrase S 7/8-26-36/37/39-45-61

Keep container tightly closed and dry.In case of contact with eyes, rinse

immediately with plenty of water and seek medical advice.Wear suitable

protective clothing, gloves and eye/face protection.In case of accident or if you

feel unwell, seek medical advice immediately (show the label where

possible).Avoid release to the environment. Refer to special instructions/

Safety data sheets.

Categories of

danger

corrosive, dangerous for the environment

Hazard Sym bol

Corrosive

Transport information

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Declaration

(ra i l road and road)

ADR, RID

UN 3264 Ätzender saurer anorganischer flüssiger Stoff, n.a.g.

(GERMANIUMTETRACHLORID), 8, II

Declaration

(transport by sea)

IMDG-Code

UN 3264 CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S.(GERMANIUM

TETRACHLORIDE), 8, II, Segregation Group: 1 (Acids)

Declaration

(transport by a i r)

IATA-DGR

UN 3264 CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S.(GERMANIUM

TETRACHLORIDE), 8, II

Categories

Merck Chemicals Content Topics Reagents according to Functional Groups Chloride

© Merck KGaA, Darmstadt, Germany, info.my(at)merckgroup.com, 2013