George A. Olah "for his contribution to carbocation chemistry". Nobel Prize in Chemistry, 1994.

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Transcript of George A. Olah "for his contribution to carbocation chemistry". Nobel Prize in Chemistry, 1994.

Page 1: George A. Olah "for his contribution to carbocation chemistry". Nobel Prize in Chemistry, 1994.
Page 2: George A. Olah "for his contribution to carbocation chemistry". Nobel Prize in Chemistry, 1994.

George A. Olah

"for his contribution to carbocation chemistry".

Nobel Prize in Chemistry, 1994

Page 3: George A. Olah "for his contribution to carbocation chemistry". Nobel Prize in Chemistry, 1994.

Childhood

Monarch Education

Hungarian Diaspora

The Supers

Resolving A Decade Controversy

Life Outside

Chemistry

Changing Lanes

Awards

Family

Page 4: George A. Olah "for his contribution to carbocation chemistry". Nobel Prize in Chemistry, 1994.

Born in Budapest, Hungary, on May 22, 1927.

His family never had an interest in science.

His main interests were history, languages, literature and philosophy.

With parents Julius Olah andMagda Krasznai and brother Peter.

Family and Childhood

Page 5: George A. Olah "for his contribution to carbocation chemistry". Nobel Prize in Chemistry, 1994.

Monarch Education

Final Exam (1945):- translation of selected literature passages—without the help of adictionary—not only from 8 foreign languages (including Latin) intoHungarian, but also vice versa.

Budapesti Piarista Gimnazium

Page 6: George A. Olah "for his contribution to carbocation chemistry". Nobel Prize in Chemistry, 1994.

The Technical University of Budapest

The university followed a rigorous program where only the most successful students were allowed to remain.

He took Chemistry and fell in love.

Page 7: George A. Olah "for his contribution to carbocation chemistry". Nobel Prize in Chemistry, 1994.

Geza Zemplen“balcony laboratory”

Emil Fischer

Page 8: George A. Olah "for his contribution to carbocation chemistry". Nobel Prize in Chemistry, 1994.

Hungarian Diaspora

The Olah family went first to London, then Montreal, then Sarnia, Ontario, where Olah worked for Dow Chemical and later to Dow Chemicals, Mass.

In 1956, Hungary revolted against the Soviet rule.

Some 200,000 Hungarians fled their country.

Page 9: George A. Olah "for his contribution to carbocation chemistry". Nobel Prize in Chemistry, 1994.

Loker Hydrocarbon Research Institute at USC

In 1976, he accepted an appointment to the University of Southern California at Los Angeles in the newly established Loker Hydrocarbon Research Institute, where he is currently Distinguished Professor and Loker Chair in Organic Chemistry.

Page 10: George A. Olah "for his contribution to carbocation chemistry". Nobel Prize in Chemistry, 1994.

The Supers

Magic Acid

• A super acid, 1:1 molar ratio, of fluorosulfonic acid (HSO3F) and antimony pentafluoride (SbF5) - 1018 times stronger than H2SO4

• used to catalyze isomerization of saturated hydrocarbons• have been shown to protonate even weak bases, including methane, xenon,

halogens, and molecular hydrogen

Page 11: George A. Olah "for his contribution to carbocation chemistry". Nobel Prize in Chemistry, 1994.

With Herbert Brown andHeinz Staab

Classical vs Non-classical CarbocationHerbert Brown vs Saul Weinstein

Non-Classical Ion Controversy

1962 Brookhaven Mechanism Conference

Nobel Prize in Chemistry in 1994 for his research in carbocation chemistry and for uncovering new ways to use hydrocarbons in the petroleum industry.

Page 12: George A. Olah "for his contribution to carbocation chemistry". Nobel Prize in Chemistry, 1994.

Changing Lanes:Carbocations to Energy Resource

Converting excess carbon dioxide and methane into fuels and derivatives.

Developed a direct methanol fuel cell for generating electrical power from methanol without first producing hydrogen.

Page 13: George A. Olah "for his contribution to carbocation chemistry". Nobel Prize in Chemistry, 1994.
Page 14: George A. Olah "for his contribution to carbocation chemistry". Nobel Prize in Chemistry, 1994.

Awards, Publications and Patents

Olah has authored over 1000 papers and 15 books, and he holds more than 100 patents.

Patents by George A. Olah:• Liquefaction of Coals Using Recyclable Superacid Catalyst• Condensation of Natural Gas or Methane into Gasoline Range

Hydrocarbons• Oxidative COndensation of Natural Gas or Methane into Gasoline

Range Hydrocarbons• Upgrading of Natural Gasoline with Trifluoromethane Sulfonic Acid,

Hydrofluoric Acid and Lewis Acid Catalyst• Process for Affecting Hydrocarbon Isomerization or Alkylation• Environmentally Safe Catalytic Alkylation Using Liquid Onium Poly

(hydrogen Fluorides)

Page 15: George A. Olah "for his contribution to carbocation chemistry". Nobel Prize in Chemistry, 1994.

Awards and Recognitions

• Cotton Medal, 1996

Nobel Prize in Chemistry, 1994

Priestley Medal, 2005

Page 16: George A. Olah "for his contribution to carbocation chemistry". Nobel Prize in Chemistry, 1994.
Page 17: George A. Olah "for his contribution to carbocation chemistry". Nobel Prize in Chemistry, 1994.

Life Outside Chemistry

Marying Judith Lengyel, 1949

“the best thing ever to happen to me in my life”

Page 18: George A. Olah "for his contribution to carbocation chemistry". Nobel Prize in Chemistry, 1994.

George and Ronald Peter (1962)

Peter and Kaitlyn (1999)

Page 19: George A. Olah "for his contribution to carbocation chemistry". Nobel Prize in Chemistry, 1994.

Proud Chemist, Sailor, Goalie

Page 20: George A. Olah "for his contribution to carbocation chemistry". Nobel Prize in Chemistry, 1994.

“A Life of Magic Chemistry”

Page 21: George A. Olah "for his contribution to carbocation chemistry". Nobel Prize in Chemistry, 1994.