GC-MSD - Agilent .3 7890A/5975C GC/MSD: The Most Popular GC/MS in the World Over 20,000 . 5975...

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Transcript of GC-MSD - Agilent .3 7890A/5975C GC/MSD: The Most Popular GC/MS in the World Over 20,000 . 5975...

  • 1

    GC-MSD Introducing the new 7890B/5977A

    January 8, 2013 Agilent Confidential

    Badr Astiphan GCMS Product Sales Specialist 1-866-524-7936 302-290-5631 cell badr_astiphan@agilent.com

  • January 8, 2013 Agilent Confidential

    2

    We are First in GC Continuously innovating

    5970 MSD Fused Silica Capillary Column

    Microprocessor Control

    5840 GC

    5880 GC

    5890 GC

    Hyperbolic Gold Quad

    Inert MS Ion Source

    6890 GC

    7200 GC QTOF 7000 GC

    Triple Quad

    Capillary Flow Technology

    AutoInjection

    Electronic Pneumatic Control

    Retention Time Locking

    2nd Gen Linear Electron Capture

    Detector

    Low Thermal Mass Technology

    Units Installed >250,000 GC >60,000 MS

    Multi-Mode Inlet

  • January 8, 2013 Agilent Confidential

    3

    7890A/5975C GC/MSD: The Most Popular GC/MS in the World

    Over 20,000 5975 systems since 2005

    The industry standard GCMS

  • Agilent 5977 MSD

    January 8, 2013 Agilent Confidential

    4

  • Proven Technologies Improving the Industry Standards for GC/SQ

    Gold Quartz Quad Triple Axis Detector

    High Temperature Inert Source Unique Entrance

    Lens Design

    All of 5975s features also built in 5977, such as Gold Quad, SIM/Scan, Gain tuning, Triple-Axis Detector, Trace Ion Detection, Auto CI, etc..

    January 8, 2013 Agilent Confidential

    5

  • 230C

    275C

    300C

    325C

    350C

    January 8, 2013 Agilent Confidential

    6

    High Temperature Ion Source Solid inert material not a coating

    Not damaged by multiple cleanings Programmable to 350C Improved response for many compounds

    More robust operation for dirty samples Better response for sticky compounds Sharper peaks for high boilers (late eluters)

    more performance for a wide range of applications

    Polyaromatic Hydrocarbon (PAH)

  • January 8, 2013 Agilent Confidential

    7

    Unique Entrance Lens Eliminates Pre-filter

    New, improved lens

  • January 8, 2013 Agilent Confidential

    8

    Fringe fields

    Unique Entrance Lens Eliminates Pre-filter

  • January 8, 2013 Agilent Confidential

    9

    Quartz Gold Hyperbolic and Beautiful!

    Why quartz?

    Low coefficient of linear expansion

    (expansivity; )

    dL = L0 dt [t = C; dL = change in

    length (m); L0 = length at 0 C]

    Why gold?

    Inert material with excellent electrical

    properties for high voltage

    Why hyperbolic?

    Ideal electrical field is generated by

    hyperbolic surfaces (NOT ROUND)

    Much more than just a beautiful piece of glass

    Round Quad

  • January 8, 2013 Agilent Confidential

    10

    Triple-Axis Detector

    ion beam X

    Y

    Offset Z

    With a combination of three axes and appropriate shielding, noise from secondary particles can be reduced to a minimum

  • January 8, 2013 Agilent Confidential

    11

    Triple Channel EM

    Triple channels improve signal amplification

    Lower initial EM voltage required Triple channels increase life

    Lower cost of operation

    Exit of the triple channels

    Collector removed to show exit passages

    Collector

  • Expanded Capabilities: 7890B/5977A Improving the Industry Standards for GC/SQ

    Higher Ion Count Extractor EI source

    Increased ion count S/N > 1500:1 IDL < 10 fg (industry first) Improved thermal profile

    Save Time & Energy Sequence Scheduler

    Standby post run Ready to run from standby Bake Mode as needed

    Factory backflush option Fast Vent capability DS42i rough pumpstandby power reduction

    Safety/Protection Vacuum failure Shut off gas (He or H2)

    Better Vacuum by Agilent Pump New Agilent V304 Turbo TwisTorr

    Molecular Drag technology Improved pumping light gases

    H2 (220 L/s); He (255 L/s) Agilent Floating Suspension

    Longer life Quiet operation

    Faster Scanning 20,000 u/s

    But never equal to the 7200 Q-TOF speed or scan sensitivity

    7890B GC Direct Communications Features EMF, calculator, etc.

    January 8, 2013 Agilent Confidential

    12

  • New Extractor Ion Source for 5977

    Agilent Confidential Page 13

    Why the Extractor EI Source? Increase in ion count True increase in sensitivity

    Better trace level precision Lower IDL and MDL

    Proven sensitivity increase demonstrated with over 1500 7000 Series GC/TQ!

    January 8, 2013

  • Comparison of Inert and Extractor Ion Source

    Agilent Confidential

    Page 14

    Repeller (Push)

    Drawout Plate

    Ion Focus Lens

    Entrance Lens

    Ionization area

    Ions

    Inert Ion Source

    Extractor Lens (Pull)

    Extractor Source More ions to Mass Filter

    Mass Filter

    January 8, 2013

  • Extractor Source Etune Sensitivity Increase

    January 6, 2013 Agilent Confidential

    15

    Blue Extractor 40ppb solution (SVOC) Red Standard 40ppb solution (SVOC)

  • More improvements on 5977s Extractor Ion Source: Improved Thermal Profile

    Page 16

    Why is this important? Better performance of high boilers i.e. PAH even at lower concentration!

    10 Injections 80 min analysis

    Good repeatability of PAH even at the trace level (5ppb)!!

    Improvement for better Mass Spectrometer of Gas Chromatograph

    January 15, 2013

  • Comparing repeatability of 80min Method

    Phthalates analysis with 5977 GC/MSD

    Oct 2012 Page 17

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    + TIC SIM PAHs-12.D

    Counts (%) vs. Acquisition Time (min)

    37 37.1 37.2 37.3 37.4 37.5 37.6 37.7 37.8 37.9 38 38.1 38.2 38.3 38.4 38.5 38.6 38.7 38.8 38.9

    5977 result

    5975 result Two years ago

    1x10

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    + TIC SIM pah_etune_300_long_R9.D Smooth

    Counts (%) vs. Acquisition Time (min)

    35.2 35.4 35.6 35.8 36 36.2 36.4 36.6 36.8 37 37.2 37.4 37.6 37.8 38 38.2 38.4 38.6 38.8 39 39.2 39.4 39.6 39.8 40

    5977 result

    200ppb PAH 5ppb PAH

  • Key features of Direct Communication between 7890B and 5977A

    Agilent Confidential Page 18

    Sleep/Wake mode Sleep mode saves power (320W 190W) Lower lab operating cost

    Safety Control If 5977A MSD pump fail, 7890B will shut off the gas supply

    Cool Down MSD Faster (FastVent) When MSD Vent Cycle started, GC will cool down MSD analyzer at the

    optimum gas flow to MSD.

    Helium carrier gas : gas waste is eliminated Hydrogen carrier gas: risk of explosion is reduced

    40% faster when cooling down from 280C to 100C (< 25 min)

    January 8, 2013

  • Saving Energy and Time

    19

    050

    100150200250300350400

    NormalOp

    Standby

    Power Consumption - 5977

    0

    50

    100

    150

    200

    250

    0 4 6 7 15 20 23 30 35 40

    Vent FastVent

    Power saved

    Time saved

    Pow

    er( V

    A)

    Sour

    ce T

    emp

    Time(min)

    Time saved using Fast Vent

  • Better HW Features: Agilent Turbo Pump (V304)

    Agilent Confidential Page 20

    Agilent Quality Standard

    TwisTorr 304 FS

    Innovation for: Higher pumping performance

    especially for He and H2 High reliability

    lower cost of operation

    January 8, 2013

    Press release : http://www.agilent.com/about/newsroom/presrel/2012/19dec-ca12077.html

    http://www.agilent.com/about/newsroom/presrel/2012/19dec-ca12077.htmlhttp://www.agilent.com/about/newsroom/presrel/2012/19dec-ca12077.htmlhttp://www.agilent.com/about/newsroom/presrel/2012/19dec-ca12077.htmlhttp://www.agilent.com/about/newsroom/presrel/2012/19dec-ca12077.html

  • 21

    TwisTorr 304 FS: Vacuum Design

    8 EDM turbo stages (rotor) designed to optimize pumping speed for light gases 8 Turbo stators

    made by pressed SST sheet technology

    3 TwisTorr drag stages (spiral channels) designed for high compression ratio performances

    Agilents new patent-pending Floating Suspension for robust, low noise operation

  • Better HW Features: Agilent Rough Pumps

    Agilent Confidential Page 22

    New DS42i New IDP-3c

    High performance Energy saving design Inverter not compatible with diff pump

    High performance Oil-free scroll pump NH3 CI compatible

    with Agilent Quality Standards

    January 8, 2013

  • January 8, 2013 Agilent Confidential

    23

    Agilent Inert Flow Path From Injection to Detection

    Ultimetal TCD, FPD, NPD/FID Jets

    Ultimetal Capillary Flow Technology Devices, Ultimate Union

    Ultimetal Inlet Weldment, Shell and Transfer Lines

    Ultra Inert GC Column

    Ultra Inert Gold Seal

    Ultra Inert Inlet Liner

    New

    now from a single supplier

  • Programmable Helium Conservation Module

    Works with Gas Saver function of 7890 based GC Standby Method can be programmed after the sequence ends Analytical methods are unchanged since Helium is still the carrier during the run

  • 5977A GC/MSD IDL Specification IDL is a s