Gases

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Gases

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Gases. Chemistry Review. Atom – smallest piece of an element Molecule – smallest piece of a compound – two or more atoms chemically bonded Mole – counting number equal to 6.022 x 10 23 Molar Mass – number of grams of a substance per mole – equal to the atomic mass on the periodic table. - PowerPoint PPT Presentation

Transcript of Gases

Page 1: Gases

Gases

Page 2: Gases

Chemistry Review

Atom – smallest piece of an element Molecule – smallest piece of a compound –

two or more atoms chemically bonded Mole – counting number equal to 6.022 x 1023

Molar Mass – number of grams of a substance per mole – equal to the atomic mass on the periodic table

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Review

How many moles in 5.5g of hydrogen gas? How many molecules in 2.5 moles of oxygen? What is the mass of one molecule of helium

gas?

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Kinetic Theory

Matter is made of particles in continuous motion

Particles move in random directions at a variety of speeds

Particles of gases are on average very far apart from one another

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Molecules of gases interact only when they collide

Collisions are perfectly elastic (no loss of kinetic energy)

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Pressure Units

1atm = 760mmHg = 760torr = 101kPa

STP – standard temp and pressure (0°C and 1 atm)

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Gas Laws

Volume is proportional to the temperature – Charles Law ( V1/T1 = V2/T2 )

Volume is inversely prop to temp – Boyles Law ( P1V1 = P2V2)

Pressure is prop to temp – Gay-Lussac’s Law ( P1/T1 = P2/T2 )

Combined Gas Law puts them together

( P1V1/T1 = P2V2/T2 )

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Ideal Gas

One that follows all kinetic theory Volume of a gas also depends on the number

of moles Ideal Gas Law

PV = nRT R = .0821 L•atm/ mol•K

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Examples

Determine the volume of 1.00 mole of a gas at STP.

A container of oxygen at STP has a volume of 10.0 L. What is the mass of the gas?

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Examples

A helium party balloon has a radius of 18.0cm at 20°C and 1.05 atm. How many moles of He are in the balloon and what is the mass of the gas in the balloon?

An auto tire is filled to a pressure of 200kPa at 10°C. After driving 100km, the temp rises to 40°C. What is the pressure now?

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Kinetic Energy of Molecules

The average KE of molecules is directly proportional to the temp

KE = ½ mv2 = 3/2 kT

k – Boltzman’s Constant = 1.38x10-23J/K

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Example

What is the average KE of gas molecules at 37°C?

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Average Velocity

Also called root mean square velocity vrms =

m – mass (in kg) of one molecule of the gas

3kT

M

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Example

What is the rms speed of an oxygen molecule at 20°C?