G - L’s Law – Pressure vs. Temperature

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G - L’s Law – Pressure vs. Temperature

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G - L’s Law – Pressure vs. Temperature. Experiment to develop the relationship between the pressure and temperature of a gas. Include : Gay-Lussac’s Law , Combined Gas Law, partial pressure Additional KEY Terms. BOYLE’S LAW – Pressure vs. Volume. P 1 V 1. P 2 V 2. =. Pressure ( kPa ). - PowerPoint PPT Presentation

Transcript of G - L’s Law – Pressure vs. Temperature

Page 1: G - L’s Law – Pressure vs. Temperature

G - L’s Law – Pressure vs. Temperature

Page 2: G - L’s Law – Pressure vs. Temperature

• Experiment to develop the relationship between the pressure and temperature of a gas.

Include: Gay-Lussac’s Law, Combined Gas Law, partial pressure

Additional KEY Terms

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Pre

ssur

e (k

Pa)

Volume (mL)

BOYLE’S LAW – Pressure vs. Volume

=

P1V1 P2V2

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Temperature (K)

Vol

ume

(mL

)

CHARLES’S LAW – Temp vs. Volume

=

V1 V2

T2

T1

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Joseph Gay-Lussac (1778-1850)

Determined that temperature and pressure of a gas is a direct relationship (volume and amount of gas are held constant)

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=

P1 P2

T2

T1

**As with Charles’ Law, temperature in Kelvin.

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If a 12.0 L sample of gas is found to have a pressure of 101.3 kPa at 0.0°C, calculate the new pressure at 128°C if the volume is held constant.

0.0°C + 273 = 273 K128°C +273 = 401 K

=

P1 P2

T2

T1

=

101.3 P2 (401) 273

149 kPa

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Boyle’s Law: Pressure α ___1___

volume

Charles’ Law: Volume α temperature

Gay-Lussac’s Law: Pressure α temperature

=

P1 P2

T2

T1

V1 V2

combined gas law

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If a gas occupies a volume of 25.0 L at 25.0°C and 1.25 atm, calculate the volume at 128°C and 0.750 atm.

=

P1 P2

T2

T1

V1 V2

=

(1.25)(401) 298 (0.750)

25 V2

25°C + 273 = 298 K128°C +273 = 401 K

56.1 L

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A gas has a volume of 125 L at 325 kPa and 58.0°C, calculate the temperature in Celsius to produce a volume of 22.4 L at 101.3 kPa

=

P1 P2

T2

T1

V1 V2

=

(101.3) (331) 325 (125)

22.4T2

58°C + 273 = 331 K

18.5 K

18.5 K - 273 = -254°C

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A bag contains 145 L of air at the bottom of a lake, at a temperature of 5.20°C and a pressure of 6.00 atm. When the bag is released, it ascends to the surface where the pressure is 1.00 atm and 16.0°C.

Given:P1 = 6.00 atm

V1 = 145L

T1 = 5.20°C

P2 = 1.00 atm

T2 = 16.0°C

Find: V2

If the maximum volume of the lift bag is 750 L, will the bag burst at the surface?

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Dalton’s Law of Partial Pressure:

Each gas in a mixture exerts pressure independently.

Total pressure = sum of the pressures of each gas (partial

pressures)

Partial pressure depends on the number of gas particles present, the temperature and volume of container.

Ptotal = P1 + P2 + P3 + P4 …

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1.0 mol H2 2.0 mol He 1.0 mol H2

2.0 mol He3.0 mol gas

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The following gases are placed in a 10.00 litre container and held at a constant temperature:

2.0 L of O2 at an original pressure of 202.6 kPa 3.00 L of Ne at an original pressure of 303.9 kPa

What pressure is produced inside the container?

HINT: Each gas is will expand when put into the 10.00 L container, so each will exert a partial pressure less than its original pressure.

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P1V1 = P2V2

Oxygen:(202.6)(2.00) = P2 (10.00)P2 = 40.5 kPa

Neon:(303.9)(3.00) = P2 (10.00)P2 = 91.2 kPa

Total pressure = 40.5 + 91.2 = 131.7 kPa

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CAN YOU / HAVE YOU?

• Experiment to develop the relationship between the pressure and temperature of a gas.

Include: Gay-Lussac’s Law, Combined Gas Law, partial pressure

Additional KEY Terms