for FPD MATERIALS UV CURABLE RESINS - …pds.magichome.co.kr › board › wrchem › 11_7_21...
Transcript of for FPD MATERIALS UV CURABLE RESINS - …pds.magichome.co.kr › board › wrchem › 11_7_21...
塾. N1戸戸口N IくAYAKU [ニロ,[:「ロ..゛,"即脱0"紅 0"印に心"臼.、'.0脚0",臼
UV CURABLE RESINS
for FPD MATERIALS
NIPPONKAYAKU CO., LTD.
Functional chemicals R&D Labolatories Group l
31-12, shim03・chome, Kita・ku, Tokyo,115-8588, Japan
FAX :+81-3.3598-5431TEL :+81-3-3598.5100
C叩"冷hloNIPPON KAYA刈CO. L"
20IV4/26
Con力'denti引
や. NIPP口N IくAYAKU 区口,に「ロ.^^ FUNC「10N貞L CH走MIC真1.S 武E3. L轟"0"'T0角作S
Uv curable Resins for FPD
Process
Exposure
Development
Demand
Characteristics
Post cure
R日liab11ity of film
Sensitivlw
Line width of marginResidue
Rate ofresldua1 例m
Tg
Heat Reslstance
Adheslon(Humid卿Resi5tanC田
2011/4126
Con力dentlal
Materials
Key Mat引ials
MU川functional
Monomers
.01四omers
CO0"司hloNIPPONKAYA凧Ico ud
Binderresins
0
0Developing evaluationDMA、TG/DTA (Film)
0
2
◎
◎
◎
0
◎ 0
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Multifunctional
Monomers
C叩"冷hloNIPPON KAYA風.1CO,.LW
201ν4126
Conガden力冷1
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3
MU能ifunctional Monomers
DPHA
Acryloyl equivalent
(theorical valU田
Tg (DMA)
Vvater
absorption ratio
96 gleq
43゜C
Formula
3.6%
DPCA60
211 gleq
68 ゜C
Feature$
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201ν4126
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0.8%
DPEA・12
185 gleq
65 ゜C
. High
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No data
4
FM、700
・ Flexibility
.water
resistance
105 gleq
89 ゜C
No data
^、1
・Good
d巳νelopabiliw
Confidential
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MU龍ifunctional Monomers
Developing evaluation
CompositionMethacrylic copolymer
侶ZMNMMNMA(AA), MW=15,000, AV=160mgKOH/g)Monomer
Irgacure 184Irgacure oxE・02
Process Coating (Glass, applicator,20~30μ m)
Prebake (80゜C12min.)
Exposure (10omJ/cm2)
DeV巳10pment(1% Na.CO. aq.)
Postbake (20O C11min.)
C叩Yr19hlo NIPPONKAYAκⅡCO. ud
201ν4/26
Conガdenガal
や. NIPP口N 1くAYA111仁口,じ「ロ..゛,""郎"乢 0"'"に乢."'..、".0"',0剛"
7
Multifunctional Monomers
Developing evaluation -Break point-
DPHA
50
67
DeV巳10ping tlme(S)
Rate of residualfilm
(EXPOS山e area ,%)
PE丁一30
Developin宮 time (S)
Rate ofresidua1州m
(Exposure area ,%)
100
FM-700
40
COOYrohl
201ν4尼6
Conガdential
RP-1040
NIPPON KAYAlnloo L峠
100
100
GPO-303
DPCA-60
40
100
100
DPHA-40H
8
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100
100
KU-201-M20
20
Develo ments eed
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Multifunctional Monomers
High resolution !
201114126
Conガdentlal
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Acryloyl equivalent (g/eq.)
(= sensitivi
9
Oligomers(pevelopable
201ν4126
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ZAR- series (Multifunctional Bis-A )
ZFR- series (Multi兪"1nctional Bis-F )
Acid value (m底KOH/宮) 98
Diluting solvent PGMEA
C010r (Gardner)
MW 8,000
Acryloyl equivalent (且/eq.) 450
ΦMA,10HZ,Film)、 94゜CTg
①SC, Liquld) 34゜C
* These results are obtained from cured 行lm.
The aboV6 打宮Ur6S ar6 for r6ferenC6 Purposes only 且nd ar6 not $poci5Cauon valueβ
14
C卯Yf肺t NIPPON ,ζAYA111CO.山
201ν4126
Confidential
1.゜ZAR-1494H ZAR-200IH
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CCR・ series (cresol novolak type)
13
98
PGMEA
10.000
550
80゜C
ZFR-1491H
98
PGMEA
11,000
500
65゜C
28゜C
CCR-1171H
Acid value (mgKOH/套) 98
Dilutin且 Solvent PGMEA
C010r (Gardner)
MW 6,500
Acryloyl equivalent (g/eq.) 400
(DMA.10HZ,Film) 120゜CT宮
ΦSC, Liquid) 35゜C
士 These results are obtained from cured 打lm.
入
CCR-1307H
60
PGMEA
2
5,700
350
152゜C
41゜C
The aboV6 "宮UreS 討6 for refer6nC6 Purp05as only and ヨr6 not 5Peci行oa虹on valU8S.
CM"叩ht NIPPON 1くAYAI0,1CO..山
201ν4126
Conf耐ential
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201114/26や.N1戸戸口N 1くAYAKU に口,ι:m. Confidential.゛,""0"0"乢 0"'"'0山"臼.、'.0"',0"作. 15
UXE-30oo series (Alkali-developable urethane (Meth)aC四late、虹"、1tl、 C
De、elopablEFlexible paHS 写.........巨.
' He'1tre"st'1ntPnr6
Con力den力al
140
Acid value (m昌KOH/g)
DⅡUtin目 Solvent
C010r (Gardner)
MW
AC則10yl equivalent (g/eq.)
(DMA,10HZ,Film)*T宮
(DSC, Liquid)
史 These results are obtained from cured 側m.
Th日 aboV6 "且Ur.5 ヨro for r.ference purposes only and ar. not speci介oauon values
......'...urethane bond
UXE-3002
100
PGMEA
2
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550
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.
,゛ゆhl NIPPONKAYA肌Ico tld
C叩γ,ゆhlo NIPPON ,〔AYA,11CO, Lld
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OligomersHeat Resistance 、T留一DMA-
Tg cc)
UXE-3024
60
PGMEA
10,000
450
126゜C
40゜C
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OligomersDevelo in evaluation -Break point-
Oli"omers
Monomers
DPHA I0%
DPHA 20%
ZCR-
1761H
(56%)(70%)(50%)(0%)
(82%)DPHA 20% (75%)20S 30S30S 30S
(): Rate ofresidualfilm (Exposure area,60s dev,)
Developmentspeed uxE 3002 > CCR 1171H > UXE-3024, ZFR-1491H> ZAR-1494H> ZAR-200IH > ZCRーシリーズ
Monomers
DPHA I0%
Oli宮omers
> 120S > 120S > 120S > 120S
ZOR-
1664H
ZCR-
1642H
Copyr,9hl NIPPON KAYA岨、1CO.ud
201ν4126
Confldentlal 20
201114126
Conガdential 19
ZAR-
200IH
ZCR-
1569H
ZAR-
1494H
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OligomersPaせeming
ZFR-
1491H
CCR-
1171H
UXE-
3024
UXE30241DPHA=80120 B.P30S
UXE-
3002
US=50μm150μ mUS=50μm/50μ m
COPYrohl NIPPON I〔禽YA111CO.,Lld
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