flR3Q2850 · 2020. 11. 16. · Film >KJPI4 48.7-43.7 a»U. VSTPUIO O1O PPB IC~TSS 9SH XC -X +D...

QUANT REPORT Page 1

Operator ID: USER1 Quant Rev: 7 Quant Time: 950125 09:19Output File: "K3PI4::D7 Injected at: 950125 08:43Data File: >KJPI4::D2 Dilution Factor: 1.00000Name: USTD010 010 PPB 1C Instrument ID: HP03973Misc: -TSS gSM XC -1 +D

ID File: IA8390::DBTitle: 3/90 SOU Uater/Med Soil ID File for Inst. HP03973Last Calibration: 910114 09:42 Last Qcal Time: 941230 10:33

Compound R.T. Q ion Area Cone Units q

1) *Bromochloromethane 9.39 128.0 22544 50.00 UG/L 842) Chloromethane 3.18 50.0 2750 12.24 UG/L 973) Vinyl Chloride 3.41 62.0 3431 11.53 UG/L 994) Bromomethane 3.96 94.0 5837 14.29 UG/L 865) Chloroethana 4.14 64.0 2306 11.55 UG/L 956) 1,1-Dichloroethene 5.80 96.0 4365 11.71 UG/L 957) Acetone 5.93 43.0 767M 15.87 UG/L8) tarbon Disulfide 6.23 76.0 8988 12.95 UG/L 1009) Methylene Chloride . 6.79 84.0 4574 11.56 UG/L 8910) trans-l,2-Dichloroethene 7.31 96.0 5001 11.01 UG/L 94

1,1-Dichloroethane 8.04 63.0 9116 13.06 UG/L 992) cis-l,2-Dichloroethene 9.04 96.0 5000 11.00 UG/L 9413) 2-Butanone 9.07 43.0 592M 6.58 UG/L 7714) Chloroform 9.53 83.0 14266 12.51 UG/L 9715) l,2-Dichloroethane-d4 10.29 65.0- 7490 13.03 UG/L 8716) 1,2-Dichloroethane 10.41 62.0 9054 14.67 UG/L 9617) *l,4-Difluorobenzene 10.96 114.0 84122 50.00 UG/L 9418) 1,1,1-Trichloroethane 9.82 97.0 12691 10.68 UG/L 9319) Carbon Tetrachloride 10.08 117.0 13484 10.84 UG/L 9520) Benzene 10.38 78.0 10262 10.61 UG/L 8921) Trichloroethene 11.34 130.0 7763 9.72 UG/L 9322) 1,2-Dichloropropane 11.67 63.0 4839 11.51 UG/L 9123) Bromodichloromethane 12.07 83.0 14353 11.90 UG/L 9024) cis-l,3

QUANT REPORT Page 2

Operator ID: USER1 Quant Rev: 7 Quant Time: 950125 09:18Output File: *KJPI4::D7 Injected at: 950125 08:43Data File: >KOPI4::D2 Dilution Factor: 1.00000Name: USTD010 010 PPB 1C Instrument ID: HP03973Misc: -TSS gSM XC -1 +D



41) 1,1,2,2-Tetrachloroethane 17.08 83.0 7410 10.43 UG/L 92

* Compound is ISTD

193

&R3G285I

«,

'Film >KJPI4 VSTD010 010 PPB IC~TSS «SM ZC -1 +0 Sc*n 312

k Rb 979. 8.93 Min.

T ii , i!,i

85t

66

ii. >. i, r/

"«?' 1M1 (M f T • I

1000- -̂ .100

800-

600- Q5 -601 ' t

400- 66 .40

200-i ..- ....• ........ ......4'o " ''"' e'o " '' " "s'o " '' "' 166'"'"' ikb 140

Film >KJPI4 48.7-43.7 a»U. VSTPUIO O1O PPB IC~TSS 9SH XC -X +D

•100

80

*0

•40

20

5.70 S.80 5.90 6.00 6.10 6.SO 6.30

Data File: >KJPI4 Quant Output File: AKJPI4Name: USTD010 010 PPB 1C Instrument ID: HP03973Misc: -TSS §Sh JfiC -1 +DQuant Time: 950125 09:18 Quant ID File: IA8390Injected at: 950125 08:43 Last Calibration: 910114.09:42

Compound No: 7Compound Name: AcetoneScan Number: 312Retention Time: 5.93 minQuant Ion: 43.0Area: 767MConcentration: 15.87 UG/Lq-value: 0

This report was produced by QAREA at: 9:41 AM WED., 25 JAN., 1995

194

flR3D2852

Film >KJPI4 VSTD010 010 PPB IC~TSS tStt XC -1 +D Scan 581Bpk flb 674. 9.07 min.

•100600-

-80

400- / -60

•40200-

-20

J-04'Q ' 60 ' ' '

43

( /1 1 1 i 1 ft 1 1 1 1

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96

184

, N>KUPI4 48.7-43.7 *»U.9STDO10OTO PPB IC~TSS *SM J£C -1 +D

EIP

100-

500-

400-•60

300-

g00J ' - ^°

20

0̂8.90 8.90 9.00 9.10 9.20 9.30

Data File: >KJPI4 Quant Output File: "KJPI4Name: USTD010 010 PPB 1C Instrument ID: HP03973Misc: ~TSS gSM \C -1 +DQuant Time: 950125 09:18 Quant ID File: IA8390Injected at: 950125 08:43 Last Calibration: 910114 09:42

Compound No: 13Compound Name: 2-ButanoneScan Number: 581Retention Time: 9.07 minQuant Ion: 43.0Area: 592MConcentration: 6.58 UG/Lq-value: 77

This report was produced by QAREA at: 9:42 AM UED., 25 JAN., 1995

• 195

AR302853

TOTflL ION CHROMBT06RRHFilm >KJPI5 35.0-300.0 *MU. VSTDOOB 005 PPB IC~TSS 9SH ZC »1 +DTIC

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Data File: >KJPI5::D3 Quant Output File: ^KJPI5::D7Name: USTD005 005 PPB 1C Instrument ID: HP03973Misc: -TSS gSM JSC -1 +D

Id File: IA8390::DBTitle: 3/90 SOU Uater/Med Soil ID File for Inst. HP03973Last Calibration: 910114 09:42 Last Qcal Time: 941230 10:33

Operator ID: USER1Quant Time : 950125 09:48Injected at: 950125 09:18

196

ftR30285t*

QUANT REPORT Page 1

Operator ID: USER1 Quant Rev: 7 Quant Time: 950125 09:48Output File: ">KJPI5::D7 Injected at: 950125 09:18Data File: >KJPI5::D3 Dilution Factor: 1.00000Name: USTD005 005 PPB 1C Instrument ID: HP03973Misc: -TSS gSM XC -1 +D



1) *8romochloromethane 9.39 128.0 22405 50.00 UG/L 902) Chloromethane . 3.18 50.0 1373M 6.15 UG/L 543) Uinyl Chloride 3.41 62.0 1530 5.17 UG/L 934) Bromomethane 3.96 94.0 2850 7.02 UG/L 905) Chloroethane 4.14 64.0 1249 6.30 UG/L 796) 1,1-Dichloroethene 5.79 96.0 2233 6.03 UG/L 958) Carbon Disulfide 6.25 76.0 4434 6.43 UG/L 10010) trans-l,2-Dichloroethene 7.30 96.0 2377 5.26 UG/L 8611) 1,1-Dichloroethane 8.04 63.0 4396 6.33 UG/L 9912) cis-l,2-Dichloroethene 9.03 96.0 2195 4.86 UG/L 9014) Chloroform 9.53 83.0 6922 6.11 UG/L 9515) l,2-Dichloroethane-d4 10.29 65.0 3629 6.35 UG/L 9116) 1,2-Dichloroethane 10.40 62.0 4616 7.53 UG/L 9417) *l,4-Difluorobenzene 10.95 114.0 83276 50.00 UG/L 9218) 1,1,1-Trichloroethane 9.80 97.0 6075 5.17 UG/L 9519) Carbon Tetrachloride 10.07 117.0 6090 4.94 UG/L 9120) Benzene 10.37 78.0 4861 5.08 UG/L 9721) Trichloroethene 11.34 130.0 3561 4.50 UG/L 8422) 1,2-Dichloropropane 11.67 63.0 2218 5.33 UG/L 9323) Bromodichloromethane 12.06 83.0 6858 5.75 UG/L 9624) cis-l,3-Dichloropropene 12.73 75.0 3950 5.20 UG/L 8925) trana-l,3-Diehloropropene 13.53 75.0 1377 1.87 UG/L 9226) 1,1,2-Trichloroethane 13.77 97.0 2710 5.64 UG/L 9127) Dibromochloromethane 14.34 129.0 6978 4.81 UG/L 9628) Bromoform 16.42 173.0 5588 4.48 UG/L 9929) »Chlorobenzene-d5 15.18 117.0 69400 50.00 UG/L 8831) Toluene-d8 13.10 98.0 6684 4.80 UG/L 8532) Toluene 13.21 91.0 6045 4.76 UG/L 9033) Tetrachloroethene 14.00 164.0 4598 5.12 UG/L 9135) Chlorobenzene 15.23 112.0 5847 4.95 UG/L 9336) Ethylbenzene 15.37 106.0 2239 4.37 UG/L 9637) m+p-Xylene 15.55 106.0 5908 9.84 UG/L 9338) o-Xylene 16.12 106.0 2653 4.42 UG/L 9639) Styrene 16.14 104.0 4670 4.39 UG/L 7940) 4-Bromofluorobenzene 16.89 95.0 5151 5.04 UG/L 7941) 1,1,2,2-Tetrachloroethane 17.08 83.0 4008 5.33 UG/L 97

* Compound is ISTD

QUANT REPORT Page 1

perator ID: USER1 Quant Rev: 7 Quant Time:' 950125 09:48Output File: 'SKJP!5::D7 . Injected at t~. 950125-09:13Dara File: >KJP15::D3 Dilution Factor:' 1.00000Name: U5TD005 005 PPB 1C Instrument. ID: HP03973tti.*>c: ~T'SS @St1 %C -1 -f-D

ID File: IA8390::DB .Title: 3/'.'0 SOW Water/Had Soil ID File for Inat. HP03973Last Calibration: 910114 09:42 Last Qca1 Time: 941230 10:33

Compound R.T. Q ion Area Cane Units q

Ii *Bromoch lorome thane 9. 39 128.0 22405 50.00 UG/L 902) Chloromethane ' 3.18 5,0.0 1373M 6.15 UG/L 543) Uinyi Chloride 3.41 62.0 15?0 5.17 UG/L 93a) Bromomethane 3.96 . 9'4.0 2950 7.02 UG/L 905) Chloroethane 4.14 64.0 1249 6.30 UG/L 796) 1,1-Dichioroethene 5.79 96". 0 2233 6.03 UG/L 959) Carbon Oisulf'ide 6.25 76.0 4434 6.43 UG/L 10010) trans-1 .2-Dich loroe thene 7.30 96.0 2377 5.26 UG/L ' 8611) 1,1-Dichioroothane 8.04 63.0 4396 6.33 UG/L 9912) cio-l,2-Dichloroethene 9.03 96.0 2195 4.86 UG/L -90.14) Chloroform 9.53 83.0 6922 6.11 UG/L 955) l,2-Dichloroethane-d4 .. 10.29 65.0 3629 6.35 UG/L 916> 1, 2-Dich loroethane 10.40 62.0 4616 7.53 UG/L 9417) *l,4-Dif luorobenzene . 10.95 114.0 83276 50.00 UG/L 9218) 1/1,1-Trich loroe thane 9.80 97.0 6075 5.17 UG/L 9519) Carbon Tet rach lor ids 10.07 117.0 6090 4.94 UG/L 9120) Benzene 10.37 78.0 4861 5.08 UG/L 9721) Trichloroethene 11.34 130.0 3561 4.50 UG/L 8422) 1,2-Dichloropropane 11.67 63.0 2218 5.33 UG/L 9323) Bromodichloromethane. 12.06 83.0 6858 5.75 UG/L 9624) cis-1 ,3-Dichloroprdpene 12.73 75.0 3950 5.20 UG/L 8925) trans-l,3-Dichloropropene 13.53 75 . Q 1377 1.87 UG/L 9226) 1,1,2-Trichloroethane 13.77 97.0 2710 5.64 UG/L 9127) Dibromqchloromethane 14.34 129.0 6978 . .4.81 UG/L 9628) Bromoform 16.42 173.0 5538 4.48 UG/L . 9929) *Chlorobenzene-d9 15.18 117.0 69400 50.00 UG/L 8831) Tol-uene-dS 13.10 98.0 6684 4.80 UG/L 8532) Toluene 13.21 91.0 6045 4.76 UG/L 905-3 ) Tet rach loroethene 14.00 164.0 4593 5.12 UG/L 9135) .Chiorobenzene 15.23 112.0 5847 4.95 UG/L 9336) Ethyibanzene 15.37 106.0 2239 4.37 UG/L 9637) m+p-Xylene 15.55 106.0 5908 9.84 UG/L 9338) o-Xylene 16.12 106.0 2653 4.42 UG/L 9639") Styrene 16.14 104.0 4670 4.39 UG/L 7940) 4-8romoF luorobenzene 16.89 95.0 5151 5.04 UG/L 7941) 1,1,2,2-Tetrachloroethane 17.08 83.0 4008 5.33 UG/L 97

Compound is ISTD

AR302856

Quant ID File: IA8390::DB

Title: 3/90 SOU Uater/Med Soil ID File for Inst. HP03973

Last EDIT Date: 941230 02:54 Last Calib Date: 910114 09:42_ast Qcal Date: 950125 08:05 Calib File: CA824Q::QT

Qcal File: "KJPI3:14906:D7

RT Window Omin -K)Max Hits/CompoundMinimum AreaPeak/Base Peak RatioUp Slope SensitivityDown Slope Sensitivity

.2000 Subtraction Method5 Ignore max check

50 Auto Qdel Method40.00 \ Quantitate Using

.2000000 Units of Cone1.000000 Bunching

2NO5

AREA

Number of Compounds: 21

RR302857

UG/L1

Damp Compound Retention TimeNo. Name (Type) Min. (Rel) R.F. Cone.

1) *8romochloromethane (I) 9.39C 1.000) 1.00000 50.002) Uinyl Chloride (T) 3.40< .362) .81585 50.003) Chloroethane (T) 4.14< .440) .55062 50.004) 1,1-Dichloroethene

Pla >KJPI5 VSTD005 COS PPB ICTSS 8SM 5£C -1 +D Sc*r» 74k Pb 3528. 3.18 min.

"3000-

2000-

1000-

0-

File >K

240-

200-

160-

120-

80-

40-

0-

TT

65 ?7 190 20? 227.j .N t f • f N

40 ' 60 ' 80 ' 100 ' 120 ' 140 ' l&Q ' ISO ' 25d ' 220JP15 49.7-50.7 a*iu. VSTD005 005 PPB IC~TS3 tSM XC »1 *0

EIP3.18

fj \

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\ ̂ N/A A / MV vV^A/ \ A ^' 2.96 ' 3. '06 ' 3.10 ' 3.20 3. '36 ' 3.40 ' 3.'s6

•100

•eo-60

-20

-0

•100

•do••60

•40

•ao•0

Data File: >KJPI5 Quant Output File:Name: USTDQ05 005 PPB 1C Instrument ID: HP03973Misc: ~TSS §SM XC -1 +DQuant Time: 950125 09:48 Quant ID File: IA8390Injected at: 950125 09:18 Last Calibration: 910114 09:42

Compound No: 2Compound Name: Chloromethane ;Scan Number: 74Retention Time: 3.18 minQuant Ion: 50.0Area: 1373MConcentration: 6.15 UG/Lq-value: 54

This report was produced by QAREA at: 11:54 AM MON., 13 FEB., 1995

199

AR302858

. -'vf-K ME "12'i .

. 4-1

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Data File: >K3PI? Quant but put Pile: 'NK.:P{̂Name: USTD005 00? P^B 1C Instrument ID: HPO?973niac: •'•TSS @Sri ?SC --1 +0Quant Time": 950125 09:48 Quant ID File: IA8390Injected a t : • 950127 Oc:18 Last Calibration: 91011-4 09;42

Compound Ho: 2Compound Name: ChloromethaneScan Number: ~>4Rejtantion Time: 3.18 mmQuant Ion: 50.0

Concentration: 6.15 UG/Lq-va lue J 5«4

TI--IS report was produced by QAREA at: 11:54 AM MOM., 13 FEB., 1995

200/ •"••

AR302859

6AVOLATILE ORGANICS INITIAL CALIBRATION DATA

Lab Name: LANCASTER LABS Contract: !___.Lab Code: LANCAS Case No.: ____. SAS No. ____. SDG No.:Instrument ID: HP03974 Calibration Date(s): 01/19/95 01/19/95Heated Purge: (Y/N) N Calibration Times: 1854 2139GC Column: DB624 ID: 0.53 (mm)

LAB FILE ID: RRF 10» >HJJI1 RRF 20- >HJJI2RRF 50= >HJJI3 RRF100= >HJJI4 RRF200» >HJJI5

COMPOUND

DichlorodifluoromethaneChloromethaneVinyl Chloride '

RRF'IO2.1511.476

• 1.175Bromomethane * 1.159ChloroethaneTrichlorofluoromethanen-PentaneFurfuranEthyl EtherAcrolein1,1-DichloroetheneFreon 113AcetoneMethyl IodideCarbon Disulfidek2-Propanol•Ally! ChlorideTMethylene Chloridet-Butyl AlcoholAcrylonitrileMethyl t-Butyl Ether1,2-Dichloroethene (total)n-Hexane1 , 1-Dichl.oroethane2-ButanonePropionitrileEthyl AcetateMethacrylonitrileTet rahydro f uranChloroform <Cyclohexane1,2-Dichloroethane '

.7042.6442.1191.359.821.118

t .9922.497.2672.9982.736.030

2.9951.485.052.2392.5611.4381.291

* 3.176.429.0651.337.276.2823.7002.1342.214

RRF 20

2.2871.4481.2121.210.690

.2.6762.0661.383.743.1091.0672.845.2023.1582.684.0192.6461.420.037.205

2.3331.4261.3812.969.323.0551.145.246.2343.4712.1581.944

RRF 50

2.0751.2321.0881.014.6132.3631.8181.241.689.101.9662.530.1872.8622.369.021

2.3811.245.036.1902.0451.2801.2322.638*273.0521.108.226.2123.0921.9431.702

RRF100

2.0991.3011.108.921.5932.3411.9331.381.719.102.9772.508.1902.8212.099.0212.4891.219.038.1942.1511.2821.3262.760.306.0641.078.254.2373.1801.9681.766

RRF200

2.1381.3791.149.758.5652.2251.8101.409.752.110.8202.481.1892.7532.310.0242.6141.231.046.2042.1171.2241.4012.486.345.0691.210.262.2592.7902.1111.563

RTO?

2.1501.3671.1461.013.6332.4501.9491.355.745.108.9642.572.2072.9192.439.023

2.6251.320.042.2062.2411.3301.3262.806.335.0611.176.253.2453.2462.0631.838

RSD

All other compounds in OLM01.8 must meet a minimum RRF of 0.010.page 1 of 3 FORM VI VOA 3/90 Rev.

201

AR302860

6AVOLATILE ORGANICS INITIAL CALIBRATION DATA

Lab Name: LANCASTER LABS Contract: ___.Lab Code: LANCAS Case No.: ____. SAS No. J___. SDG No.: ____.

Instrument ID: HP03974 Calibration Date(s): 01/19/95 01/19/95Heated Purge: (Y/N) N Calibration Times: 1854 2139GC Column: DB624 ID: 0.53 (mm)LAB FILE ID: RRF 10- >HJJI1 RRF 20= >HJJI2RRF 50* >HJJI3 RRFlOOs. >HJJI4 RRF200* >HJJI5

COMPOUND

Vinyl Acetate1,1, 1-Trichloroethane •

RRF 10

.032k .667

Carbon Tetrachloride * . 629Isobutyl AlcoholBenzene •n-Heptanen-ButanolTrichloroethene •1, 2-DichloropropaneMethyl MethacrylateDibromomethane1,4-Dioxanen-Propyl AcetateBromodichloromethane •2 -Ni tropropane2-Chloroethyl Vinyl Ethercis-l,3-Dichloropropene <

.004I .921

.234

.003k .459

.510

.184

.509

.003

.527k .943

.074

.244t .694

trans-1, 3-Dichloropropene * .5601 . 1 , 2 -Tr ichl oroe thane * .382Dibromochloromethane * .824Bromof orm * .532trans-1 . 4-Dichloro-2-Butene4 -Methyl-2 -PentanoneToluene <Ethyl MethacrylateTetrachloroethene '2-Hexanone1 , 2-DibromoethaneChlorobenzene •1,1,1, 2-TetrachloroethaneEthylbenzene '

.093

.304' 1.018

.420t .471

.166

.638" .855

.537* .351

Xylene (total) * .434Isoamyl Acetate .345Compounds with required minimum RI

RRF 20

.037

.692

.681

.003

.913

.245

.003

.476

.472

.174

.476

.002

.447

.914

.062

.226

.662

.542

.366

.810

.529

.083

.2831.221.455.606.165.6991.015.631.424.521.375

RRF 50

.036

.606

.599

.003

.808

.212

.002

.421

.426

.154

.416

.001

.401

.819

.054

.203

.602

.494

.316

.731

.489

.076

.2631.098.422.550.150.636.908.563.380.472.338

RRF100

.035

.588

.606

.003

.796

.232

.002

.415

.441

.169

.429

.002

.429

.854.. . 078.202.609.513.346.768.534.085.278

1.091.470.542.163.668.952.577.376.456.359

RRF200

.039

.583

.510

.004

.796

.236

.003

.406

.394

.170

.417

.002

.469

.745

.083

.209

.624

.534

.302

.656

.468

.086

.3071.080.474.513.183.635.806.539.360.441.368

ERF.036.627.605.004.847.232.003.436.449.170.450.002.455.855.070.217.638.528.342.758.510.084.2871.102.448.536.166.655.907.569.378.465.357

6A ,VOLATILE ORGANICS INITIAL CALIBRATION DATA

Lab Name: LANCASTER LABS Contract: ____.Lab Code: LANCAS Case No.: ____. SAS No. ___. SDG No.:instrument ID: HP03974 Calibration Date(s): 01/19/95 01/19/95Heated Purge: (Y/N) N Calibration Times: 1854 2139GC Column: DB624 ID: 0.53 (mm)LAB FILE ID: RRF 10= >HJJI1 RRF 20= >HJJI2RRF 50= >HJJI3 RRF100= >HJJI4 RRF200= >HJJI5

COMPOUND

StyreneCumeneCyclohexanone1,1,2,2 -Tetrachloroethane1,2,3 -Tr ichloropropane2 -Chl or ot oluenePent achl oroethane1,3 -Dichlorobenzene1, 4-DichlorobenzeneBenzyl Chloride1 , 3-Diethylbenzene1 , 4 -Diethy Ibenzene1 , 2-Dichlorobenzene1 , 2-Diethylbenzene

RRF 10

.7121.140.008

k .448.092.304.321.572.628.338.534.427.532.467

l,2-Dichloroethane-d4 I 1.586wluene-dS . .8774 -Bromof luorobenzene * .651

I

RRF 20

.8631.433.005.480.101.384.371.652.703.330.586.454.505.455

r.7621.241.879

RRF 50

.7871.293.005.436.090.345;347.605.613.297'.559.423.460.430

1.5801.145.808

RRF100'

.8201.297.005.465.098.348.364.643.635.342.574.456.473.440

1.5511.087.768

RRF200.685

1.245.006.459.092.327.348.601.598.356.545.433.444.409

1.5891.084.749

RW

.7731.282.006.457.095.341.350.615.635.333.560.439.483.440

1.6141.087.771

RSD

9.6*8.224.63.6*4.88.65.65.36.46.63.73.67.45.1sass«

5.212.310.9*

Compounds with required minimum RRF and maximum %RSD values.All other compounds in OLM01.8 must meet a minimum RRF of 0.010.page 3 of 3 FORM VI VOA 3/90 Rev.

203

AR302862

TOTfiL ION CHROMflTOSRflMFile >HJJI1 35.0-300.0 a»u. VSTDOlw 015 PFB 1C,TCflZ 9HL SC «1 +CEOC

400 800 1200 1600_i r_. t_i _t_ i i i i r i t i i t i L L > i i i « 11 i t _ i L160000-

140000-

8 ' iS ia r i4 16 ' is ^ 20 ' a'a

"Data File: >HJJI1::06 Quant Output File: AHJJI1::D7Name: USTD010 010 PPB 1C Instrument ID: HP03974Misc:. ~CA2 §UL XC -1 +CE05X &5 *5

Id File: IA5824::DBTitle: Method 8240A Water low ID File for Inst. HP03974Last Calibration: 950119 01:16 Last Qcal Time:

Operator IDi US£R2Quant Time : 950119 19:22Injected at: 950119 18:54

204

"AR3028ET

QUANT REPORT Page 1

Operator ID: USER2 Quant Rev: 7 Quant Time: 950119 19:22Output File: AHJJI1::D7 Injected at: 950119 18:54Data File: >rUJIl::D6 Dilution Factor: 1.00000Name: USTD010 010 PPB 1C Instrument ID: HP03974Misc: ~CAZ @UIL HC -1 +CE05X &5 *5

ID File: IA5824::DBTitle: Method 8240A Uater low ID File for Inst. HP03974Last Calibration: 950119 01:16 Last Qcal Time:


1) *Bromochloromethane 9.16 128.0 27690 50.00 UG/L 762) Dichlorodifluoromethane 2.85 85.0 11911 10.23 UG/L 933) Chloromethane 3.06 50.0 8173M 12.32 UG/L 954) Uinyl Chloride 3.23 62.0 6505 11.13 UG/L 965) Bromomethane 3.77 94.0 6420 14.30 UG/L 926) Chloroethane ' 3.94 64.0 3897 15.03 UG/L 957) Trichlorofluoromethane • 4.41 101.0 14644 12.42 UG/L 938) n-Pentane 4.57 43.0 11735 12.93 UG/L 839) Furfuran 5.08 68.0 7525 11.00 UG/L 6910) Ethyl Ether 5.03 59.0 4547 12.68 UG/L 7011) Acrolein 5.25 56.0 3275 60.93 UG/L 9012) 1,1-Dichloroethene 5.46 96.0 5491 10.35 UG/L 81.13) Freon 113 , ' 5.54 101.0 13830 10.14 UG/L 9214) Acetone 5.61 43.0 1481 15.40 UG/L 9015) Methyl Iodide 5.74 142.0 16605 9.88 UG/L 7616) Carbon Disulfide 5.88 76.0 15150 11.35 UG/L 10017) 2-Propanol 5.97 45.0 823 53.83 UG/L 8918) Allyl Chloride 6.22 41.0 16587M 13.82 UG/L 7719) Methylene Chloride 6.44 84.0 8226 12.36 UG/L 7620) t-Butyl Alcohol 6.78 59.0 2894 110.80 UG/L 6621) Acrylonitrile 6.92 53.0 6612 63.52 UG/L 9322) Methyl t-Butyl Ether 7.04 73.0 14184 12.90 UG/L 9023) trans-l,2-Dichloroethene 7.00 96.0 7133 10.77 UG/L 8524) n-Hexane 7.56 57.0 7148 11.60 UG/L 9225) 1,1-Dichloroethane 7.77 63.0 17589 12.07 UG/L 9426) 1-Propanol 8.06 59.0 23M 19.86 UG/L27) cis-l,2-Dichloroethene 8.79 96.0 8791 11.73 UG/L 9428) 2-Butanone 8.81 43.0 2377 15.47 UG/L 8829) Propionitrile 8.87 54.0 1812 54.06 UG/L 9730) Ethyl Acetate 8.96 43.0 7406 14.05 UG/L 9531) Methacrylonitrile 9.14 67.0 3817 29.98 UG/L 7732) Tetrahydrofuran 9.29 42.0 1563 13.68 UG/L 9533) Chloroform 9.31 83.0 20488 11.83 UG/L 9434) Cyclohexane 9.72 56.0 11816 12.17 UG/L 7935) l,2-Dichloroethane-d4 10.08 65.0 8781 11.00 UG/L 9236) 1,2-Dichloroethane 10.21 62.0 12263 13.28 UG/L 8037) »l,4-Difluorobenzene 10.78 114.0 121378 50.00 UG/L 8338) Uinyl Acetate 7.90 86.0 785 8.87 UG/L 8839) 1,1,1-Trichloroethane 9.62 97.0 16198 11.71 UG/L 8740) Carbon Tetrach loride 9.90 117.0 15279 10.59 UG/L 96

205

QUANT REPORT Page 2

Operator ID: USER2 Quant Rev: 7 Quant Time: 950119 19:22Output File: ^HJJI1::D7 Injected at: 950119 18:54Data File: >HJJI1::D6 Dilution Factor: 1.00000Name: USTD010 010 PPB 1C Instrument ID: HP03974Misc: -CAZ §UIL XC -1 +CE05X &5 *5

ID File: IA5824::DBTitle: Method 8240A Uater low ID File for Inst. HP03974Last Calibration: 950119 01:16 * Last Qcal Time:

Compound " R.T. Q ion Area Cone Units q

41) Isobutyl Alcohol 10.08 41.0 1280 128.91 UG/L 9342) Benzene 10.20 78.0 22362 12.19 UG/L 8943) n-Heptane 10.67 71.0 5671 11.98 UG/L 7344) n-Butanol 11.10 56.0 849 116.85 UG/L 9245) Trichloroethen'e 11.19 130.0 11134 10.94 UG/L 8446) 1,2-Dichloropropane ' 11.48 63.0 12385 12.13 UG/L 7047) Methyl Methacrylate 11.68 69.0 4475 12.16 UG/L 7048) Dibromomethane 11.66 93.0 12365 12.20 UG/L 8749) 1,4-Dioxane 11.72 88.0 355 72.56 UG/L 9350) n-Propyl Acetate 11.78 43.0 12805 14.19 UG/L 8951) Bromodichloromethane 11.89 83.0 228.87 11.25 UG/L 92'52) 2-Nitropropane 12.18 41.0 1808 12.91 UG/L 9853) 2-Chloroethyl Uinyl Ether 12.32 63.0 5920 12.67 UG/L 8554) cis-l,3-Dichloropropene 12.55 75.0 16857 12.02 UG/L 8655) trans-l,3-Dichloropropene 13.34 75.0 5169 4.39 UG/L 9056) 1,1,2-Trichloroethane 13.60 97.0 9280 11.24 UG/L 9057) Dibromochloromethane 14.18 129.0 20004 10.53 UG/L 9658) Bromoform 16.25 173.0 12910 8.98 UG/L 9959) trans-l,4-Dichloro-2-Butene 16.98 53.0 5615 27.42 UG/L 8360) *Chlorobenzene-d5 15.02 117.0 123529 50^00 UG/L 8561) 4-Methyl-2-Pentanone 12.77 43.0 7514 12.20 UG/L 8762) Toluene-d8 12.95 98.0 21661 8.04 UG/L 98"63) Toluene 13.05 91.0 25156 9.51 UG/L 9564) Ethyl Methacrylate 13.48 69.0 10387 9.58 UG/L 6265) Tetrachloroethene 13.85 164.0 11645 8.54 UG/L 9666) 2-Hexanone 13.95 43.0 4090 10.94 UG/L 9767) 1,2-Dibromoethane 14.34 107.0 15760 9.61 UG/L 9368) Chlorobenzene 15.07 112.0 21129 8.81 UG/L 8369) 1,1,1,2-Tetrachloroethane 15.17 131.0 13277 9.00 UG/L 8970) Ethylbenzene 15.22 106.0 8668 9.62 UG/L 9971) m+p-Xylene 15.40 106.0 21579 18.99 UG/L 9872) Isoamyl Acetate 15.49 70.0 8518 10.04 UG/L 9073) o-Xylene 15.97 106.0 10734 9.68 UG/L 9674) Styrene 15.98 104.0 17597 8.63 UG/L 8275) Cumene 16.50 105.0 28164 9.27 UG/L 9976) Cyclohexanone 16.63 55.0 1035 62.02 UG/L 8777) 4-Bromofluorobenzene 16.73 95.0 16073M 7.96 UG/L 9178) 1,1,2,2-Tetrachloroethane 16.90 83.0 11064 9.33 UG/L 9679) 1,2,3-Trichloropropane 16.97 110.0 2276 9.07 UG/L 6180) 2-Chlorotoluene 17.24 126.0 7503 8.18 UG/L 9081) Pentachloroethane 17.88 167.0 7921 7.55 UG/L 80

200

AR3Q2865

QUANT REPORT Page 3

I Operator ID: USER2 Quant Rev: 7 Quant Time: 950119 19:22Output File: AHJail::D7 Injected at: 950119 18:54Data File: >HJJI1::D6 Dilution Factor: 1.00000Name: USTD010 010 PPB 1C Instrument ID: HP03974Misc: -CAZ gWL XC -1 +CE05X 8,5 »5

ID File: IA5824::DBTitle: Method 8240A Water low ID File for Inst. HP03974Last Calibration: 950119 01:16 Last Qcal Time:


82) 1,3-Dichlorobenzene 18.35 146.0 14138 7.89 UG/L 9283) 1,4-Dichlorobenzene 18.48 146.0 15524 8.32 UG/L 9184) Benzyl Chloride 18.65 91.0 8359 8.57 UG/L 9785) 1,3-Diethylbenzene 18.83 105.0 13205 8.78 UG/L 9786) 1,4-Diethylbenzene . 18.96 105.0 10549 8.89 UG/L 9787) 1,2-Dichlorobenzene 19.03 146.0 13155 9.55 UG/L 3983) 1,2-Diethylbenzene 19.13 105.0 11536 9.76 UG/L 9989) l,2-Dibromo-3-Chloropropane 20.17 157.0 8723 71.72 UG/L 89

* Compound is ISTD

207

fiR3Q2866

Film >HJJI1 VSTD010 010 PPB ICTflZ &HL. XC «1 +CE05X '15 *5 Scan 90Bpk Ob 2512. 3.06 Min.

4085QOH

2000-

1500-

1000-

500- 37

1

44\

47 49_\\

50

85

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100

-80

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Film >HJJI1 49.7-50.7 mnu.^VSTDOlO OlOTPB TC~CAẐ HL XC *1 +CE05X tEIP3.06

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3000-

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0-

Fil« >H3000-

S500-

2000-

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, f

VSTD010 010 PPB IC~CflZ 9UL XC -1 *CE05X 15 *5 Se»n 3616.82 Min.

41"s.

,

76

/8 /4 4\ 4\ 5\ 1̂40 44 48 5'2 56 60 64 68 72 76

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' s'.'s'o

40.7-41.7 4»u. VSTD010 010 PPB IC~CftZ UWL XC «1 -t-CEO!EIP

6.22

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'

6. 'do ' 6.'lO ' 6.'a6 ' 6.30 ' 6. '46 ' 6. 'SO ' 6.60

•100

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•80••60

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Data File: >HJJI1 Quant Output File:Name: USTD010 010 PPB 1C Instrument ID: HP03974Misc: -CAZ @UL XC -1 +CE05X 8.5 *5Quant Time: 950119 19:22 Quant ID File: IA5824Injected at: 950119'18:54 Last Calibration: 950119 01:16

Compound No: 18Compound Name: Allyl ChlorideScan Number: 361Retention Time: 6.22 minQuant Ion: 41.0Area: 16587MConcentration: 13.82 UG/Lq-value: 77

This report was produced by QAREA at: 4:12 PM MON., 23 JAN., 1995

Fil* >HJJI1 VSTD010Bpk Rb 814.

-i 40800;

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-400-.

20&; 39

/

010 PPB IC~CflZ 9UL XC »1 +CE05X 15 *5 Seam 5198.06 Min.

43

rr( 59i i

•100

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•60

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-038 40 42 44 46 43 50 52 54 56 S3 60 ' 6*2

Film >HJJI1 58.7-59.7

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8.06 r

i -LM100

80

•60

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20

j\8.00 ' • 8.10 ' 8.20 ' 8 .'3D

Data'File: >HJJI1 Quant Output File: AHJJI1Name: USTD010 010 PPB 1C Instrument ID: HP03974Misc: -CAZ gUIL XC -1 +CE05X 8,5 *5Quant Time: 950119 19:22 Quant ID File: IA5824Injected at:. 950119 18:54 Last Calibration: 950119 01:16

Compound No: 26Compound Name: 1-PropanolScan Number: 519Retention Time: 8.06 minQuant Ion: 59.0Area: 23MConcentration: 19.86 UG/Lq-value: 0


AR302869

Film >HJJI1 VSTD010 010 PPB IC~CflZ 9UL XC «=1 t-CEOSX 15 *5 ScanBpk fib 4083. 16.73

4000-

3000-

2000-

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4000;

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2000-

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/I \ 1,11,,. ,1,, III ,i .Hi 11 II' 46 " ' " " 60 ' ' "

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1261Min.

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JJI1 94.7-95.7 amu. VSTD010 010' PPB IC~CfiZ 9WL XC *1 -«-CEO

16.73

4

16.50 16 60 . 16.70 16.80 16.90 17.00

•100

•80

-60

•40

-20

-0

5X 1

•100

•80

•60-•40

-0

Data File: >HJJI1 Quant Output File:Name: USTD010 010 PPB 1C Instrument ID: HP03974Misc: ~CAZ gUIL XC -1 +CE05X 8,5 *5Quant Time: 950119 19:22 Quant ID File: IA5824Injected at: 950119 18:54 Last Calibration: 950119 01:16

Compound No: 77Compound Name: 4-BromofluorobenzeneScan Number: 1261Retention Time: 16.73 minQuant Ion: 95.0Area: 16073MConcentration: 7.96 UG/Lq-value: 91


flR302870

TOTflL ION CHROMOTOQROMFile >HJJI2 35.0-300.0 amu. VSTD020020 PPB lC~CflZ ?UL XC »1 +CEOS

TIC4pO ( 8pO t 12̂ 0 t 1600

180000-

160000-

140000;

120000J

100000-

I ' I ' I"1 I ' I • I ' I '10 12 14 16

Data File: >HJJI2::D6 Quant Output File: -SHJJI2::D7Name: USTD020 020 PP8 1C ' Instrument ID: HP03974Misc: ~CAZ gUL XC -1 +CE05X 8,5 *5



212

QUANT REPORT Page 1

Operator ID: USER2 Quant Rev: 7 Quant Time: 950119 19:58Output File: ~HJJI2::D7 Injected at: 950119 19:30Data File: >HJJI2::D6 Dilution Factor: 1.00000Name: USTD020 020 PPB 1C Instrument ID: HP03974Misc: ~CAZ JBWL XC -1 +CE05X 8,5 *5


Compound _ R.T. Q ion Area Cone Units q

1) *Bromochloromethane 9.16 128.0 33217 50.00 UG/L 812) Dichlorodifluoromethane 2.85 85.0 30385 21.75 UG/L 973) Chloromethane 3.07 50.0 19238M 24.18 UG/L 984) Uinyl Chloride 3.24 62.0 16109 22.98 UG/L 985) Bromomethane .. 3.76 94.0 16081 29.85 UG/L 966) Chloroethane 3.94 64.0 9170 29.49 UG/L 947) Trichlorofluoromethane 4.39 101.0 35549 25.14 UG/L 948) n-Pentane 4.56 43.0 27450 25.21 UG/L 849) Furfuran 5.04 68.0 18382 22.39 UG/L 7110) Ethyl Ether 5.03 59.0 9877 22.97 UG/L 7411) Acrolein 5.23 56.0 7214 111.89 UG/L 9212) 1,1-Dichloroethene 5.44 96.0 14177 22.29 UG/L 8813) Freon 113 5,54 101.0 37801 23.10 UG/L 9314) Acetone 5.56 43.0 2683 23.26 UG/L 9315) Methyl Iodide 5.72 142.0 41962 20.82 UG/L 7616) Carbon Disulfide 5.87 76.0 35658 22.27 UG/L 10017) 2-Propanol 5.96 45.0 1251 68.22 UG/L 9718) AllylChloride 6.19 41.0 35158M 24.43 UG/L 7719) Methylene Chloride 6.43 84.0 18866 23.63 UG/L 8220) t-Butyl Alcohol 6.76 59.0 4949 157.95 UG/L 8821) Acrylonitrile 6.89 53.0 13630 109.16 UG/L 9622) Methyl t-Butyl Ether 7.03 73.0 31002 23.50 UG/L 9323) trans-l,2-Dichloroethene 6.99 96.0 17391 21.88 UG/L 9024) n-Hexane 7.55 57.0 18353 24.84 UG/L 9125) 1,1-Dichloroethane 7.75 63.0 39443 22.56 UG/L 9526) 1-Propanol 8.07 59.0 69M 49.67 UG/L27) cis-l,2-Dichloroethene 8.78 96.0 20505 22.81 UG/L 9428) 2-Butanone 8.80 43.0 4297 23.32 UG/L 8629) Propionitrile 8.86 54.0 3643 90.59 UG/L 8930) Ethyl Acetate 8.95 43.0 15208 24.04 UG/L 9731) Methacrylonitrile 9.13 67.0 8167 53.48 UG/L 8032) Tetrahydrofuran 9.28 42.0 3115 22.72 UG/L 9133) Chloroform 9.32 83.0 46113 22.20 UG/L 9834) Cyclohexane 9.73 56.0 28674 24.61 UG/L 8435) l,2-Dichloroethane-d4 10.09 65.0 23415 24.46 UG/L 9936) 1,2-Dichloroethane 10.21 62.0 25831 23.31 UG/L 8237) *l,4-Difluorobenzene 10.79 114.0 137110 50.00 UG/L 8838) Uinyl Acetate 7.89 86.0 2047 20.48 UG/L 9039) 1,1,1-Trichloroethane 9.62 97.0 37940 24.29 UG/L 8640) Carbon Tetrachloride 9.90 117.0 37348 22.92 UG/L 95

213

AR302872

QUANT REPORT Page 2

Operator ID: USER2 Quant Rev: 7 Quant Time: 950119 19:58Output File: AHJJI2::D7 Injected at: 950119 19:30Data File: >HJJI2::D6 Dilution Factor: 1.00000Name: USTD020 020 PPB 1C Instrument ID: HP03974Misc: -CAZ gWL XC -1 +CE05X 8,5 «5



41). Isobutyl Alcohol 10.11 41.0 2223 198.19 UG/L 9442) Benzene 10.21 78.0 50083 24.17 UG/L 9243) n-Heptane 10.67 71.0 13435 25.13 UG/L 7744) n-Butanol . 11.12 56.0 1405 171.19 UG/L 8145) Trichloroethene 11.20 130.0 26113 22.72 UG/L 8346) 1,2-Dichloropropane 11.50 63.0 25874 22.43 UG/L 7047) Methyl Methacrylate 11.69 69.0 9557 22.99 UG/L 7348) Dibromomethane 11.67 93.0 26113 22.82 UG/L 8949) 1,4-Dipxane 11.72 88.0 439 79.44 UG/L 8350) n-Propyl Acetate 11.78 43.0 24522 24.06 UG/L 9251) Bromodichloromethane 11.90 83.0 50129 21.82 UG/L 9452) 2-Nitropropane 12.19 41.0 3386s 21.41 UG/L 9153) 2-Chloroethyl Uinyl Ether 12.34 63.0 12422 23.53 UG/L 8454) cis-l,3-Dichloropropene 12.55 75.0 36316 22.92 UG/L 8655} trans-l,3-Dichloropropene 13.34 75.0 11290 8.49 UG/L 9056) 1,1,2-Trichloroethane 13.60 97.0 20072 21.53 UG/L 9057) Dibromochloromethane 14.18 129.0 44419 20.69 UG/L 9958) Bromoform 16.25 173.0 29037 17.87 UG/L 98.59) trans-l,4-Dichloro-2-Butene 17.00 53.0 11372 49.17 UG/L 8960) *Chlorobenzene-d5 15.03 117.0 118035 50.00 UG/L 8661) 4-Methyl-2-Pentanone 12.76 43.0 13360M 22.71 UG/L 8762) Toluene-d8 . 12.96 98.0 58588 22.75 UG/L 9863) Toluene 13.06 91.0 57650 22.81 UG/L 9964) Ethyl' Methacrylate 13.48 69.0 21482 20.74 UG/L 7065) Tetrachloroethene 13.86 164.0 28590 21.94 UG/L 9666) 2-Hexanone 13.96 43.0 7803 21.85 UG/L 9967) 1,2-Dibromoethane 14.35 107.0 33022 21.08 UG/L 9368) Chlorobenzene 15.08 112.0 47917 20.91 UG/L 8669) 1,1,1,2-Tetrachloroethane 15.18 131.0 29779 21.13 UG/L 9170) Ethylbenzene 15.23 106.0 19996 23.22 UG/L 9771) m+p-Xylene 15.39 106.0 50185 46.23 UG/L 9872) Isoamyl Acetate 15.49 70.0 17703 21.83 UG/L 9373) o-Xylene 15.98 106.0 24577 23.18 UG/L 9674) Styrene 15.99 104.0 40748 20.92 UG/L 8975) Cumene 16.52 105.0 67656 .23.31 UG/L 9876) Cyclohexanone 16.61 55.0 1147 71.93 UG/L 8177) 4-Bromofluorobenzene 16.74 95.0 41503M 21.52 UG/L 9078) 1,1,2,2-Tetrachloroethane 16.91 83.0 22650 19.98 UG/L 9479) 1,2,3-Trichloropropane 16.98 110.0 4777 19.92 UG/L 5980) 2-Chlorotoluene 17.25 126.0 18112 20.68 UG/L 9181) Pentachloroethane 17.88 167.0 17525 17.49 UG/L 84

21

A R 3:0 2 8r7;3

QUANT REPORT Page 3

Operator ID: USER2 Quant Rev: 7 Quant Time: 950119 19:58Output. File: ^HJJI2::D7 Injected at: 950119 19:30Data File: >HJJI2::D6 Dilution Factor: 1.00000Name: USTD020 020 PPB 1C Instrument ID: HP03974Misc: ~CAZ gWL XC -1 +CE05X 8,5 *5



82) 1,3-Dichlorobenzene 18.35 146.0 30784 17.98 UG/L 9383) 1,4-Dichlorobenzene 18.48 146.0 33211 18.63 UG/L 9284) Benzyl Chloride 18.67 91.0 15561 16.70 UG/L 9785) 1,3-Diethylben.zene 18.84 105.0 27664 19.24 UG/L 9586) 1,4-Diethylbenzene . 18.97 105.0 21458 18.92 UG/L 9787) .1,2-Dichlorobenzene 19.03 146.0 23836 18.12 UG/L 9083) 1,2-Diethylbenzene 19.15 105.0 21494 19.03 UG/L 9589) l,2-Dibromo-3-Chloropropane 20.19 157.0 7150 61.52 UG/L 92

* Compound is ISTD

215

AB'302871*

Fil« >HJJ13 VSTD020 030 PPB IC~CRZ »HU XC -1 +CE05X 15 *5 Scan 93Bpk flb 2577. 3.07 Min.

2500-

2000-

1500-

1000-

500-

40

50

44/

I. I

52.85

77 \ 87

/ I / N40 50 60 70 " '' " "80" " '' " 90" " '" " i6o

100

80

60

40

20

L0

File >HJJI2 49.7-50,

2.70 2.80 2.90 3.00 3.10 3.20 3.30 3.40 3.54 3.60

Data File: >HJJI2 Quant Output File:Name: USTD020 020 PPB 1C Instrument ID: HP03974Misc: -CAZ gWL XC -1 +CE05X 8,5 *5Quant Time: 950119 19:58 Quant ID File: IA5824Injected at: 950119 19:30 Last Calibration: 950119 01:16

Compound No: 3Compound Name: ChloromethaneScan Number: 93Retention Time: 3.07 minQuant Ion: 50.0Area: 19238MConcentration: 24.18 UG/Lq-value: 98


Film >HJJI2 VST0020 020 PPB IC~CflZ 9UL XC -1 +CE05X 15 *5 Scan 360Bpk flb 6263, 6.19 min.

41

6000 ' -100•SO

39*000̂

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4451 61 72

76/

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20

36 40 44 43 52 56 60 64 68 72 76

File >HJJI2 40.7-41.7 amu. VSTD020F20 TP8 TfCfiZ 9UL XC »1 +Ct]55X&!EIP

fi.196000̂ ~ 0̂0

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•80

2000̂IOOHJJI2 Quant Output File: AHJJI2Name: USTD020 020 PPB 1C Instrument ID: HP03974Misc: ~CAZ §WL XC -1 +CE05X 8,5 *5Quant Time: 950119 19:58 Quant ID File: IA5824Injected at: 950119 19:30 Last Calibration: 950119 01:16



f.&

File >HJJI2 VSTD020 020 PPB IC^CflZ tUL XC »1 +CE05X 15 *5 Scan 521Bpk flb 648. 8.07 Min.

_, 40

600-.

400-

200-

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30-

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15-

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JJI2 58.

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8.07. i.90 • • • ' • ' 'g.'o'o ' ' i ' ' •g>'1'0' ' ' ' ' gJgQ • • . • • •g_'30I • • i • •

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5.X t

•80

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Data File: >HJJI2 Quant Output File: AHJJI2Name: USTD020 020 PPB 1C Instrument ID: HP03974Misc: ~CAZ gWL XC -1 +CE05X 8,5 *5Quant Time: 950119 19:58 Quant ID File: IA5824Injected at: 950119 19:30 Last Calibration: 950119 01:16

Compound No: 26Compound Name: 1-PropanolScan Number: 521Retention Time: 8.07 minQuant Ion: 59.0Area: 69MConcentration: 49.67 UG/Lq-value: 0


AR302877

File >HJJI2 VSTD020 020 PPB IC~CftZ 9M. XC «1 +CE05X 15 *5 Scan 923Bpk fib 3042. . 12.76 Min.

t 43 r3000-

2000-

1000-

0-

File >H

3000-

2500-

2000-

1500-

1000-

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0-

1,

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1

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50 56 i

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HJJI2 Quant Output File: AHJJI2,Name: USTD020 020 PPB 1C Instrument ID: HP03974Misc: ~CAZ §WL XC -1 +CE05X 8,5 *5Quant Time: 950119 19:58 Quant ID File: IA5824Injected at: 950119 19:30 Last Calibration: 950119 01:16

Compound No: 61Compound Name: 4-Methyl-2-PentanoneScan Number: 923Retention Time: 12.76 minQuant Ion: 43.0Area: 13360MConcentration: 22.71 UG/Lq-value: 87


File >HJJI2 VSTD020 020 PPB IC~CflZ fWL XC -1 +CE05X 15 »5 ScanBpk fib 10258. . 16.74

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105 117 130 141I. ,(. f.. f f.

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JJI2 94.7-95.7 a»u. VSTD020 020 PPB IC~CftZ 9WL XC «1 +CEOEIP

16.74

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16 '.50 ' 16.60 ' 16'.70 ' ielsO ' 16 ! 90 ' i/.OO '

Data File: >HJJI2 Quant Output File: "HJJI2Name: USTD020 020 PPB 1C Instrument ID: HP03974Misc: -CAZ gWL XC -1 +CE05X 8,5 *5Quant Time: 950119 19:58 Quant ID File: IA5824Injected at: 950119 19:30 Last Calibration: 950119 01:16

Compound'No: 77Compound Name: 4-BromofluorobenzeneScan Number: 1263Retention Time: 16.74 minQuant Ion: 95.0Area: 41503MConcentration: 21.52 UG/Lq-value: 90


TOTflL ION CHRQflRTOGRfltt

— — — — — — • • • • • • • • • • •-T". • • • • , .lg,°? . . . . . 160?

220000J

200000J

Data File: >HJJI3::D6 Quant Output File: /NHJJI3::D7Name: USTD050 050 PPB 1C Instrument ID: HP03974Misc: ~CAZ §WL XC -1.+CE05X 8,5 *5



221 K

AR30288Q

QUANT REPORT Page 1

Operator ID: USER2 Quant Rev: 7 Quant Time: 950119 20:36Output File: "HJJI3::D7 Injected at: 950119 20:08Data File: >HJJI3::D6 Dilution Factor: 1.00000Name: USTD050 050 PPB 1C Instrument ID: HP03974Misc: ~CAZ @WL XC -1 +CE05X 8.5 *5

ID File: IA5824::DBTitle: Method 8240A Water low ID File for Inst. HP03974Last Calibration: 950119 01:16 . Last Qcal Time:


1) *BroTnochloromethane 9.16 128.0 35275 50.00 UG/L 812) Dichlorodifluoromethane 2.84 85.0 73199 49.34 UG/L 963) Chloromethane 3.06 50.0 43476 51.46 UG/L 994) Uinyl Chloride 3.23 62.0 38379 51.56 UG/L 995) Bromomethane 3.76 94.0 35783 62.56 UG/L 976) Chloroethane ' 3.94 64.0 21623 65.48 UG/L 957) Trichlorofluoromethane ' 4.38 101.0 83355 55.50 UG/L 928) n-Pentane 4.56 43.0 64120 55.45 UG/L 819) Furfuran 5.03 68.0 43769 50.21 UG/L 7310) Ethyl Ether 5.01 59.0 24309 53.23 UG/L 7011) Acrolein 5.22 56.0 17800 259.97 UG/L 9612) 1,1-Dichloroethene 5.44 96.0 34092 50.46 UG/L 8813) Freon 113 5.55 101.0 89237 51.34 UG/L 9514) Acetone 5.58 43.0 6599 53.87 UG/L 9315) Methyl Iodide 5-72 142.0 100964 47.17 UG/L 7616) Carbon Disulfide 5.86 76.0 83565 49.15 UG/L 10017) 2-Propanol 5.97 45.0 3641 186.96 UG/L 9118) Allyl Chloride 6.19 41.0 84002M 54.96 UG/L 8219) Methylene Chloride 6.43 84.0 43916 51.80 UG/L 7920) t-Butyl Alcohol 6.75 59.0 12583 378.15 UG/L 8221) Acrylonitrile 6.88 53.0 33556 253.06 UG/L 9522) Methyl t-Butyl Ether 7.03 73.0 72142 51.49 UG/L 9723) trans-l,2-Dichloroethene 6.99 96.0 41459 49.12 UG/L 8924) n-Hexane 7.56 57.0 43461 55.39 UG/L 9325) 1,1-Dichloroethane 7.76 63.0 93061 50.13 UG/L 9726) 1-Propanol 8.06 59.0 484 328.07 UG/L 10027) cis-l,2-Dichloroethene 8.77 96.0 48858 51.17 UG/L 9528) 2-Butanone 8.81 43.0 9627 . 49.20 UG/L 9229) Propionitrile 8.85 54.0 9159 214.48 UG/L 9030) Ethyl Acetate 8.95 43.0 39099 58.21 UG/L 9731) Methacrylonitrile 9.12 67.0 19929 122.88 UG/L 8032) Tetrahydrofuran 9.28 42.0 7491 51.45 UG/L 9533) Chloroform 9.31 83.0 109080 49.45 UG/L 9734) Cyclohexane . 9.73 56.0 68531 55.40 UG/L 83

•35) l,2-Dichloroethane-d4' 10.08 65.0 55738 54.82 UG/L 9536) 1,2-Dichloroethane 10.20 62.0 60046 51.03 UG/L 8137) *l,4-Difluorobenzene 10.78 114.0 148296 50.00 UG/L 8738) Uinyl Acetate 7.90 86.0 5299 49.01 UG/L 9139) 1,1,1-Trichloroethane 9.61 97.0 89837 53.17 UG/L 8840) Carbon Tetrachloride 9.89 117.0 88819 50.40 UG/L 94

29,9

AR30288I

t -QUANT REPORT Page 2.*

Operator ID: USER2 Quant Rev: 7 Quant Time: 950119 20:36Output File: *-HJJI3::D7 ' Injected at: 950119 20:08Data File: >.HJJI3::D6 Dilution Factor: 1.00000Name: USTD050 050 PPB 1C Instrument ID: HP03974Misc: ~CAZ gWL XC -1 +CE05X 8,5 *5



41) Isobutyl Alcohol 10.11 41.0 5866 483.52 UG/L 9142) Benzene 10.20 78.0 119859 53.49 UG/L 9243) n-Heptane ' 10.67 71.0 31387 54.27 UG/L 7644) n-Butanol 11.09 56.0 3230 363.87 UG/L 8745) Trichloroethene . 11.19 130.0 62491 50.26 UG/L 8646) 1,2-Dichloropropane 11.50 63.0 63233 50.68 UG/L 6947) Methyl Methacrylate 11.68 69.0 22827 50.76 UG/L 7448) Dibromomethane 11.66 93.0 61709 49.85 UG/L 8449) 1,4-Dioxane 11.72 88.0 1002 167.63 UG/L 8650) n-Propyl Acetate 11.78 43.0 59445 53.92 UG/L 9351) Bromodichloromethane 11.90 83.0 121511 48.89 UG/L 9652) 2-Nitropropane 12.19 41.0 8030 46.94 UG/L 9953) 2-Chloroethyl Uinyl Ether 12.34 63.0 30153' 52.81 UG/L 8654) cis-l,3-Dichloropropene 12.55 75.0 89243 52.07 UG/L 8755) trans-l,3-Dichloropropene 13.33 75.0 27812 19.34 UG/L 9356) 1,1,2-Trichloroethane 13.60 97.0 46803 46.41 UG/L 9157) Dibromochloromethane 14.18 129.0 108397 46.68 UG/L 9658) Bromoform 16.25 173.0 72466 41.24 UG/L 9959) trans-l,4-Dichloro-2-Butene 16.99 53.0 28217 112.79 UG/L 8960) *Chlorobenzene-d5 15.03 117.0 125928 50.00 UG/L 8561) 4-Methyl-2-Pentanone 12.76 43.0 33153M 52.82 UG/L 89>62) Toluene-d8 12.96 98.0 144247 52.49 UG/L 9863) Toluene 13.05 91.0 138267 51.28 UG/L 9764) Ethyl Methacrylate 13.48 69.0 53195 48.14 UG/L 6865) Tetrachloroethene 13.86 164.0 69319 49.85 UG/L 9566) 2-Hexanone 13.95 43.0 18925 49.68 UG/L 9667) 1,2-Dibromoethane 14.35 107.0 80054 47.90 UG/L 9368) Chlorobenzene 15.06 112.0 114392 46.79 UG/L 8969) 1,1,1,2-Tetrachloroethane 15.18 131.0 70892 47.15 UG/L 9270) Ethylbenzene 15.23 106.0 47892 52.14 UG/L 9871) m+p-Xylene 15.40 106.0 119587 103.25 UG/L 9772) Isoamyl Acetate 15.49 70.0 42626 49.27 UG/L 9173) o-Xylene 15.98 106.0 59475 52.59 UG/L 9674) Styrene 15.99 104.0 99094 47.68 UG/L 8875) Cumene 16.51 105.0 162812 52.57 UG/L 9876) Cyclohexanone 16.62 55.0 3160 185.76 UG/L 8877) 4-Bromofluorobenzene 16.72 95.0 101806M 49.49 UG/L 9578) 1,1,2,2-Tetrachloroethane 16.90 83.0 54894 45.39 UG/L 9379) 1,2,3-Trichloropropane 16.97 110.0 11396 44.53 UG/L 6180) 2-Chlorotoluene 17.25 126.0 43388 46.42 UG/L 921) Pentachloroethane 17.88 167.0 43758 40.92 UG/L 86

223

fiR302882

QUANT REPORT Page 3

Operator ID: USER2 Quant Rev: 7 Quant Time: 950119 20:36Output File: "NHJJIS: :D7 Injected at: 950119 20:08Data File: >HJJI3::D6 Dilution Factor: 1.00000Name: USTD050 050 PPB 1C Instrument ID: HP03974Misc: -CAZ gWL XC -1 +CE05X 8,5 «5



82) 1,3-Dichlorobenzene 18.35 146.0 76193 41.72 UG/L 9283) 1,4-Dichlorobenzene 18.48 146.0 77169 40.57 UG/L 9284) Benzyl Chloride 18.66 91.0 37461 37.69 UG/L 9785) 1,3-Diethylbenzene 18.84 105.0 70358 45.87 UG/L 9786) 1,4-Diethylbenzene . 18.96 105.0 53285 44.04 UG/L 9887) 1,2-Dichlorobenzene 19.03 146.0 57961 41.30 UG/L 9188) 1,2-Diethylbenzene 19.14 105.0 54093 44.90 UG/L 9689) l,2-Dibromo-3-Chloropropane 20.18 157.0 11285 91.01 UG/L 90

* Compound is

fiR302883

File >HJJ!3 VSTD050 050 PPB IC~CflZ 9WL XC -1 +CE05X 15 *5 Scan 358Bpk flb 14249. 6.19 Min.

-12000-

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Data. File: >HJJI3 - Quant Output File: ~HJJI3Name: USTD050 050 PPB 1C Instrument ID: HP03974Mi so: ~CAZ @WL XC -1 +CEO5X 8,5 *5Quant Time: 950119 20:36 Quant ID File: IA5824Injected at: 950119 20:08 Last Calibration: 950119 01:16



AR302881*

File >HJJI3Bpk Rb 7624

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VSTD050 050 PPB IC~C«Z 9UL XC «1 +CED5X 15 *5 Scan 92012.76 Min.

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42.7-43.7 AlfCJ. VSTD050 059 PPS IC~CflZ flfWL XC «1 +CEO!EIP

12.76A

' 12.6

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Data File: >HJJI3 Quant Output File: ~HJJI3Name: USTD050 050 PPB 1C Instrument ID: HP03974Misc: -CAZ @WL XC -1 +CE05X &

File >HJJ13 VSTD050 050 PPB IC~CRZ 9UL XC «1 *CE05X 15 *5 Scan 1259Bpk fib 25416. 16.72 Min.

25000-

20000-

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File >H

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105 117 130 1tf 148 *J!.. ..if. ...HJJI3 Quant Output File: -"HJJI3Name: OSTD050 050 PPB 1C Instrument ID: HP03974Misc: -CAZ §WL XC -1 +CE05X 8,5 *5Quant Time: 950119 20:36 Quant ID File: IA5824Injected at: 950119 20:08 Last Calibration: 950119 01:16

Compound No: 77Compound Name: 4-BromofluorobenzeneScan Number: 1259Retention Time: 16.72 minQuant Ion: 95.0Area: 101806MConcentration: 49.49 UG/Lq-value: 95


AR302886

TOTOL ION CHRQMOTOQBOMFile >HJJI4 35.0-300.0 amu. VS. 0100. 100 PPB 1C C»Z 9WL XC «1 +CEO!

T I C400 t 800

16 18 20 22

Data File: >HJJI4::D6 Quant' Output File: AHJJI4::D7Name: USTD100 100 PPB 1C Instrument ID: HP03974Misc: -CAZ gWL XC -1 +CE05X 8,5 *5



228

BR302887

QUANT REPORT Page 1

Operator ID: USER2 Quant Rev: 7 Quant Time: 950119 21:17Output File: *HJJI4::D7 « Injected at: 950119 20:49Data File: >HJJI4::D6 . Dilution Factor: 1.00000Name: USTD100 100 PPB 1C Instrument ID: HP03974Misc: -CAZ @WL XC -1 +CE05X 8,5 *5



1) *Bromochloromethane 9.17 128.0 32255 50.00 UG/L 782) Dichlorodifluoromethane 2.84 85.0 135382 99.80 UG/L 983) Chloromethane 3.06 50.0 S3924M 108.63 UG/L 994) Uinyl Chloride 3.24 62.0 71458 104.98 UG/L 995) Bromomethane 3.73 94.0 59424 113.61 UG/L 946) Chloroethane ' 3.95 64.0 38251 126.68 UG/L 947) Trichlorofluoromethane ' 4.39 101.0 151044 109.99 UG/L 968) n-Pentane 4.56 43.0 124679 117.91 UG/L 839) Furfuran 5.05 68.0 89088 111.76 UG/L 7210) Ethyl Ether 5.04 59.0 46393 111.09 UG/L 6911) Acrolein 5.25 56.0 33040 527.73 UG/L 9312). 1,1-Dichloroethene 5.46 96.0 62996 101.98 UG/L 8713) Freon 113 5.54 iOl.O 161766 101.78 UG/L 9514) Acetone 5.57, 43.0 12277 109.61 UG/L 9215) Methyl Iodide 5.74 142.0 182004 93.00 UG/L 7416) Carbon Disulfide 5.88 76.0 135421 87.10 UG/L 10017) 2-Propanol 5.98 45.0 6640 372'.87 UG/L 8418) Allyl Chloride 6.21 41.0 160563M 114.83 UG/L 80.19) Methylene Chloride 6.44 84.0 78668 101.49 UG/L 8020) t-Butyl Alcohol 6.78 59.0 24293 798.42 UG/L 9221) Acrylonitrile 6.89 53.0 62457 515.12 UG/L 9522) Methyl t-Butyl Ether 7.05 73.0 138770 108.33 UG/L 9623) trans-l,2-Dichloroethene 7..00 96.0 77511 100.43 UG/L , 8824) n-Hexane 7.57 57.0 85554 119.24 UG/L 9325) 1,1-Dichloroethane 7.76 63.0 178028 104.88 UG/L 9626) 1-Propanol 8.06, 59.0 1120 830.26 UG/L 10027) cis-l,2-Dichloroethene 8.79 96.0 87821 100.59 UG/L 9428) 2-Butanone 8.82 43.0 19715 110.18 UG/L 8629) Propionitrile 8.87 54.0 20745 531.28 UG/L 8530) Ethyl.Acetate 8.96 43.0 69560 113.26.UG/L 9531) Methacrylonitrile 9.14 67.0 41003 276.49 UG/L 7732) 'Tetrahydrofuran 9.29 42.0 15321 115.08 UG/L 9433) Chloroform 9.32 83.0 205137 101.71 UG/L 9734) Cyclohexane 9.75 56.0 126958 112.24 UG/L 8335) l,2-Dichloroethane-d4 10.10 65.0 100061 107.62'UG/L 9636) 1,2-Dichloroethane 10.21 62.0 113923 105.88 UG/L 8037) *l,4-Difluorobenzene 10.80 114.0 136683 50.00 UG/L 8738) Uinyl. Acetate 7.90 86.0 9570 96.03 UG/L 9039) 1,1,1-Trichloroethane 9.63 97.0 160770 103.24.UG/L 8840) Carbon Tetrachloride 9.91 117.0 165548 101.93 UG/L 96

229

AR302888

QUANT REPORT . Page 2

Operator ID: USER2 Quant Rev: 7 Quant Time: 950119 21:17Output File: ^HJJI4::D7 Injected at: 950119 20:49Data File: >HJJI4::D6 Dilution Factor: 1.00000Name: USTD100 100 PPB 1C Instrument ID: HP03974Misc: ~CAZ gWL XC -1 -t-CE05X &5 *5

ID File: IA5824: : DBTitle: Method 8240A Water low ID File for Inst. HP03974Last Calibration: 950119 01:16 Last Qcal Time:

Compound' " R.T. Q ion Area Cone Units q

41) Isobutyl Alcohol 10.12 41.0 11895 1063.78 UG/L 8742) Benzene , 10.20 78.0 217652 105.38 UG/L 9143) n-Heptane 10.67 71.0 63547 119.21 UG/L 7744) n-Butanol 11.10 56.0 6825 834.18 UG/L 9445) Trichloroethene 11.20 130.0 113576 99.11 UG/L 8846) 1,2-Dichloropropane ' 11.50 63.0 120535 104.81 UG/L 6847) Methyl Methacrylate 11.69 69.0 46063 111.13 UG/L 7648) Dibromomethane 11.68 93.0 117357 102.86 UG/L 8849) 1,4-Dioxane 11.71 88.0 2274 412.76 UG/L 6150) n-Propyl Acetate 11.78 43.0 117344 115.47 UG/L 9351) Bromodichloromethane 11.91 83.0 233318 101.85 UG/L 9552) 2-Nitropropane 12.20 41.0 21377 135.59 UG/L 9353) 2-Chloroethyl Uinyl Ether 12.34 63.0 55094 104.69 UG/L 8754) cis-l,3-Dichloropropene 12.55 75.0 166446 105.36 UG/L 87

.55) trans-l,3-Dichloropropene 13.34 75.0 53313 40.22 UG/L 9356) 1,1,2-Trichloroethane 13.61 97.0 94572 101.75 UG/L 9257) Dibromochloromethane 14.18 129.0 209890 98.07 UG/L 9858) Bromoform 16.25 173.0 146021 90.15 UG/L 9859) trans-l,4-Dichloro-2-Butene 16.99 53.0 57956 251.35 UG/L 8560) *Chlorobenzene-d5 15.04 117.0 115669 50.00 UG/L 8561) 4-Methyl-2-Pentanone 12.76 43.0 64299M 111.52 UG/L 8962) . Toluene-d8 12.96 98.0 251372 99.59 UG/L 9863) Toluene . 13.06 91.0 252384 101.91 UG/L 9664) Ethyl Methacrylate 13.48 69.0 108764 107.16 UG/L 6965) Tetrachloroethene . 13.86 164.0 125281 98.09 UG/L 9566) 2-Hexanone 13.96 43.0 37820 108.08 UG/L 9267) 1,2-Dibromoethane 14.35 107.0 154506 100.66 UG/L 9468) Chlorobenzene 15.07 112.0 220300 98.10 UG/L 8969) 1,1,1,2-Tetrachloroethane 15.19 131.0 133421 96.60 UG/L 9270) Ethylbenzene 15.23 106.0 86992 103.10 UG/L 9871) m-t-p-Xylene 15.40 106.0 219637 206.46 UG/L 9672) Isoamyl Acetate 15.49 70.0 82986 104.42 UG/L 9173) o-Xylene 15.98 106.0 105584 101.64 UG/L 9574) Styrene 16.00 104.0 189805 99.43 UG/L 8975) Cumene 16.52 105.0 299949 105.44 UG/L 9876) Cyclohexanone 16.63 55.0 6182 395.64 UG/L 9277) 4-Bromofluorobenzene 16.73 95.0 177717M 94.05 UG/L 9778) 1,1,2,2-Tetrachloroethane 16.92 83.0 107464 96.75 UG/L 9379) 1,2,3-Trichloropropane 16.98 110.0 22697 96.56 UG/L 6080) 2-Chlorotoluene 17.25 126.0 80397 93.65 UG/L 9281) Pentachloroethane 17.88 167.0 84187 85.72 UG/L 85

230

AR302889

QUANT REPORT ^

•r-;-;,::; SB.- -~ '*J&&% ̂SisDutput File. 33l4!lD6 lnstrument ID.S=: S?£ -w-«..SwSHsj"-J"*10 wu for' - *-s"- -o>

rri-r Units q~. • £*r*is uone "̂R.T. Q 10" Area ___——— —————— ---

C°mP°und _____— ———— ———- ""r̂ l~62 S3-61 UG/L ??18.35 146.0 14S662 yG/L 9382) 1,3-Dichlorobenzene le.^v J.-TV-.-1,4-Dichlorobenzene 18.48 146.0 146845 84.uv o«,_

Benzyl Chloride 18.67 91.0 79194 86.75 UG/L 9785) 1,3-Diethylbenzene 18.84 105.0 132804 94.26 UG/L 9586) 1,4-Diethylbenzene '18.97 105.0 105570 94.98 UG/L 9787) 1,2-Dichlorobenzene 19.03 146.0 109372 84.84 UG/L 9188) 1,2-Diethylbenzene 19.15 105.0 101788 91.98 UG/L 9889) l,2-Dibromo-3-Chloropropane 20.19 ̂ 7-Q 21197 186.12 UG/L 91

* Compound is ISTD

831

AR302890

File >HJJI4 VSTD100 100 PPB IC~CflZ 9UL ZC -1 +CE05X t5 *5 Scan 96Bpk flb 8864. 3.06 min.

50•100

8000-LSO

6000-

4000-

2000-

40\

44/

•H

52

8566 68 77 78 f ,01

N / \/ 1 ,

•40

L-20

40 50 60 70 30 90 100File >HJJI4 49.7-50.7 AMU. V570100 100 PPB 1C CH2 tUL ZC »1 +CE05X

EIP•100

8000-y v

•80t \6000-

•60

•202000-

i i i ,L02.70 2.30 2.90 3.00 3.10 3.20 3.30 3.40 3.50 3.60

Data File: >HJJI4 . Quant Output File:Name: USTD100 100 PPB 1C Instrument ID: HP03974Misc: -CAZ @WL XC -1 +CE05X 8,5 *5Quant Time: 950119 21:17 Quant ID File: IA5824Injected at: 950119 20:49 Last Calibration: 950119 01:16

Compound No: 3Compound Name: Chloromethane.Scan Number: 96Retention Time: 3.06 minQuant Ion: 50.0Area: 83924MConcentration: 108.63 UG/Lq-value: 99


mAR302891

File >HJJI4 VSTD100 100 PPB IC~Cf)Z 9ML XC -1 +CE05X 15 *5 Se»n 365Bpk flb 27936. 6.21 win.

300001 ^ j-ioo•80

200004'60

f-4010000-

49s

7661 71 ( 101 1£7 151\.. N...I.I. /______/_________/_______\

40 60 30 100 120 140

•20

-0

File >HJvJI4 40.7-41.7 amu. VSTDIOO 100 PPB IC~CflZ 9ML XC =1 +CE05XEIP

6.21

Data File: >HJJI4 Quant Output File: AHJJI4Name: USTD10Q 100 PPB 1C Instrument ID: HP03974Misc: ~CA2 @WL XC -1 +CE05X 8,5 *5Quant Time: 950119 21:17 Quant ID File? IA5824Injected at: 950119 20:49 Last Calibration: 950119 01:16

Compound No: 18Compound Name: Allyl Chloride'Scan Number: 365Retention Time: 6.21.minQuant Ion: 41.0Area: 160563MConcentration: 114.88 UG/Lq-value: 80


233

AR302892 "——

File >HJJI4 VSTD100 100 PPB !C~CftZ 9UL ZC «1 +CE05X 15 *5 Scan 926Bpk Ob 14704. 12.76 Min.

160001

12000-

8000-

43/ •100

•30

•60

-404000- S575 \ 86 y° 11Q 11? 163 teo

53

40 60 SO 100 120 140 160File >HHJJI4 Quant Output File: "-HJJI4Name: USTD100 100 PPB 1C Instrument ID: HP03974Misc: ~CAZ gWL XC -1 +CE05X 8,5 *5Quant Time: 950119 21:17 Quant ID File: IA5824Injected at: 950119 20:49 Last Calibration: 950119 01:16

Compound No: 61Compound Name: 4-Methyl-2-PentanoneScan Number: 926Retention Time: 12.76 minQuant Ion: 43.0Area: 64299MConcentration: 111.52 UG/Lq-value: 89


' BR302893

2.

File'- >HMi4

Quant Output F11..JH33I4Instrument ID: HP03974

o M°ame:74-Bromof luorobenzene

Scan Number: 1265̂Retention Time. ie-Quant Ion: 95̂ 0Area: 177717H yG/LConcentration:q-alue: 97 23 3AM. , 1995

AR30289U

TOTflL ION CHROttflTOSRflMFile >HJJI5 35.0-300.0 a«u. VSTD200200 PPB TC~Cfl2 eML ZĈ l +CEO!

TIC. . . , 4?°. i .8?°. i I12,00. ! ?-6i09

SOOOOO-f

700000;

600000̂

500000-

400000-

300000-

200000;

10000&

' 6 ' ' ' 8 ' 'I'O' ' "iV ' 'l!4 ' 'i'6' ' "I'S" ' "20 ' 'g'2'

Data File: >HJJI5::D6 Quant Output File:Name: USTD200 200 PPB 1C Instrument ID: HP03974Misc: -CAZ §WL XC -1 +CE05X 8,5 *5

Id File: IA5824::DB ' 'Title: Method 8240A Water low ID File for Inst. HP03974Last Calibration: 950119 01:16 Last Qcal Time:


336

AR302895

QUANT REPORT Page 1

Operator ID: USER2 Quant Rev: 7 Quant Time: 950119 22:08Output File: -*HJJI5::D7 Injected at: 950'll9 21:39Data File: >HJJI5::D6 Dilution Factor: 1.00000Name: VSTD200 200 PPB 1C Instrument ID: HP03974Misc: -CAZ @WL XC -1 +CE05X 8,5 *5



1) *Bromochloromethane 9.18 128.0 30870 50.00 UG/L 722) Dichlorodifluoromethane 2.85 85.0 264013 203.35 UG/L 963) Chloromethane 3.06 50.0 170220M 230.22 UG/L 984) Vinyl Chloride 3.23 62.0 141935 217.88 UG/L. 995) Bromomethane 3.74 94.0 93595 186.97 UG/L 956> Chloroethane " 3.91 64.0 69715 241.23 UG/L 967) Trichlorofluoromethane " 4.38 101.0 274765 209.07 UG/L 958) n-Pentane 4.56 43.0 223458 220.81 UG/L 819) Furfuran 5.05 68.0 174045 228.13 UG/L 7010) Ethyl Ether 5.03 59.0 92804 232.20 UG/L 6711) Acrolein 5.25 56.0 67694 1129.75 UG/L 9812) 1,1-Dichloroethene 5.46 96.0 101306 171.36 UG/L 8513) Freon 113 5.56' 101.0 306343 201.40 UG/L 9414). Acetone • 5.60 43.0 23364 217.95 UG/L 9015) Methyl Iodide 5.74 142.0 339934 181.49 UG/L 7616) Carbon Disulfide . 5.88 76.0 285195 191.67 UG/L 10017) 2-Propanol 6.02 45.0 14809 868.91 UG/L 7618) -Allyl Chloride 6.21 41.0 322793M 241.32 UG/L 7719) Methylene Chloride 6.44 84.0 151971 204.85 UG/L 7820) t-Butyl Alcohol 6.80 59.0 57309 1968.05 UG/L 9121) Acrylonitrile 6.91 53.0 125752 1083.69 UG/L - 9322) Methyl t-Butyl Ether 7.06 73.0 261370 213.19 UG/L 9723) trans-l,2-Dichloroethene 7.00 96.0 129139 174.83 UG/L 8724) n-Hexane 7.57 57.0 173032 251.97 UG/L 9325) 1,1-Dichloroethane 7.77 63.0 307025 188.99 UG/L 9526) 1-Propanol 8.09 59.0 2385 1847.33 UG/L 10027) cis-l,2~Dichloroethene 8.79 96.0 172999 207.04 UG/L 9328) 2-Butanone 8.82 43.0 42620 248.88 UG/L 8329) Propionitrile 8.87 54.0 42688 1142.28 UG/L 8430) Ethyl Acetate 8.96 43.0 149445 254.25 UG/L 9631) Methacrylonitrile 9.14 67.0 80921 570.15 UG/L 7632) Tetrahydrofuran 9.29 42.0 31962 250.84 UG/L 9733) Chloroform 9.33 83.0 344454 178.44 UG/L 9634) Cyclohexane 9.74 56.0 260622 240.74 UG/L 8335) l,2-Dichloroethane-d4 10.09 65.0 196256 220.56 UG/L 9736) 1,2-Dichloroethane 10.21 62.0 192976 187.40 UG/L 7937) *l,4-Difluorobenzene 10.79 114.0 133663 50.00 UG/L 8638) Uinyl Acetate 7.91 86.0 20675 212.16 UG/L 8939) 1,1,1-Trichloroethane • 9.62 97.0 311690 204.68 UG/L 8940) Carbon Tetrachloride 9.90 117.0 272511 171.58 UG/L 96

337

AR302896

QUANT REPORT Page 2

Operator ID: USER2 • Quant Rev: 7 Quant Time: 950119 22:08Output File: ^HJJIS^D? Injected at: 950119 21:39Data File: >HJJI5::D6 Dilution Factor: 1.00000Name: USTD200 200 PPB 1C Instrument ID: HP03974Misc: ~CAZ §WL XC -1 +CE05X 8,5 *5


Compound " R.T. Q ion Area . Cone Units q

41) Isobutyl Alcohol 10.11 41.0 24885 2275.77 UG/L 7742) Benzene 10.21 78.0 425632 210.73 UG/L 9243) n-Heptane 10.67 71.0 125995 241.71 UG/L 7744) n-Butanol , 11.11 56.0 15096 1886.78 UG/L 9445) Trichloroethene 11.19 130.0 217109 193.74 UG/L 8646) 1,2-Dichloropropane ' 11.50 63.0 210880 187.51 UG/L 6847) Methyl Methacrylate 11.69 69.0 90985 224.47 UG/L 7648) Dibromomethane 11.67 93.0 222741 199.64 UG/L 8749) 1,4-Dioxane 11.70 88.0 4245 787.94 UG/L 6350) n-Propyl Acetate 11.79 43.0 250725 252.30 UG/L 9151) . Bromodichloromethane 11.90. 83.0 398273 177.79 UG/L 9552) 2-Nitropropane '. " 12.20 41.0 44617 289.38 UG/L 9653) 2-Chloroethyl Uinyl Ether 12.34 63.0 111561 216.77 UG/L 8554) cis-l,3-Dichloropropene 12.56 75.0 333808 216.07 UG/L 8655) trans-l,3-Dichloropropene 13.34 75.0 108408 83.64 UG/L 9256) 1,1,2-Trichloroethane 13.60 97.0 161335 177.50 UG/L 9357)" Dibromochloromethane 14.19 129.0 350800. 167.62 UG/L 9858) Bromoform 16.26 173.0 250009 157.85 UG/L 9859) trans-l,4-Dichloro-2-Butene 17.00 53.0 114720 508.77 UG/L 8960) *Chlorobenzene-d5 15.04 117.0 116357 50.00 UG/L 8661) 4-Methyl-2-Pentanone 12.77 43.0 142837M 246.27 UG/L 8862) Toluene-d8 12.97 98.0 504320 198.62 UG/L .9963) Toluene 13.06 91.0 502810 201.83 UG/L 9764) Ethyl Methacrylate 13.48 69.0 220648 216.11 UG/L 6765) Tetrachloroethene 13.87 164.0 238568 185.68 UG/L 9466) 2-Hexanone 13.96 43.0 85206 242.06 UG/L 9567) 1,2-Dibromoethane 14.35 107.0 295452 191.34 UG/L 9368) Chlorobenzene 15.08 112.0 375354 166.15 UG/L 8869) 1,1,1,2-Tetrachloroethane 15.18 131.0 250934 180.61 UG/L 9270) Ethylbenzene . 15.24 106.0 167699 197.58 UG/L 9871) m+p-Xylene 15.41 106.0 387382 361.98 UG/L 9772) Isoamyl Acetate 15.50 70.0 17133.9 214.32 UG/L 9073) o-Xylene 15.98 106.0 205135 196.30 UG/L 9674) Styrene 16.00 104.0 318661 165.95 UG/L 8875) Cumene 16.52 105.0 579500 202.50 UG/L 9876) Cyclohexanone 16.64 55.0 13350 849.32 UG/L 8377) 4-Bromofluorobenzene 16.74 95.0 348504M 183.34 UG/L 9478) 1,1,2,2-Tetrachloroethane 16.92 83.0 213542 191.11 UG/L 9479) 1,2,3-Trichloropropane 16.98 110.0 42989 181.81 UG/L 6180) 2-Chlorotoluene 17.26 126.0 152418 176.50 UG/L 9381) Pentachloroethane 17.89' 167.0 162029 164.00 UG/L. 84

238

AR302897

I

QUANT REPORT Page 3

Operator ID: USER2 . Quant Rev: 7 Quant Time: 950119 22:08Output File: ^HJJI5::D7 Injected at: 950119 21:39Data File: >HJJI5::D6 Dilution Factor: 1.00000Name: USTD200 200 PPB 1C Instrument ID: HP03974Misc: ~CAZ §WL XC -1 +CE05X 8,5 *5


Compound " R.T. Q ion Area Cone Units q«>^^»^«*>«VMM*^^___«BM •• •» • •» ̂ •» «• «• «P ̂ ̂ ••» «V ••

File >HJJI5 VSTD200 200 PPB 1C~CRZ *UL ZC -1 +CE05X 15 *5 Sc»n 90Bpk Ob 18473. 3.06 Min.

20000} °̂•100

16000-

12000-

8000-

4000-40

52/ x /• \ r,

40 50 60 70 80 90 100

-40

20

-0

File >HJJI5 49.7-50.7 »MU.VSTD300200 PPBIC~CRZSWL %C «1 +CE05X 1

;100

•80

•60

•40

•20

02.70 2.80 2. '90 3.00 3.10 3.20 3.30 3.40 3.'50 3.'60

Data File: >HJJI5 Quant Output File: AHJJI5Name: USTD200 200 PPB 1C Instrument ID: HP03974Misc: ~CAZ gWL XC -1 +CE05X 8,5 *5Quant Time: 950119 22:08 Quant ID File: IA5824Injected at: 950119 21:39 Last Calibration: 950119 01:16

Compound No: 3Compound Name: ChloromethaneScan Number: 90Retention Time: 3.06 minQuant Ion: 50.0 •Area: 170220MConcentration: 230.22 UG/Lq-value: 98


flR"30'2899

File >HJJI5 VSTD200 200 PPB !C~CflZ »UL XC -1 +CE05X 15 *5 Scan 359Bpk flb 57096. 6.21 Min.

60000- -100

8040000-

•60

20000-

41/

76 •40

•20f X X . Lo

61 72 „„ 101 142 151v X.UT r / \ \40 60 30 100 120 140

File >HJJI5 40.7-41.7 AMU. VSTD^QO 20C PPB IC~CfiZ 9MU 7.C

5.90 ' 6.00 6.10 6.20 6.30 6.40 6.'50

Data File: >HJJI5 Quant Output FilesName: USTD200 200 PPB 1C Instrument ID: HP03974Misc: ~CAZ gWL XC -1 +CE05X 8,5 *5Quant Time: 950119 22:08 Quant ID File: IA5824Injected at: 950119 21:39 Last Calibration: 950119 01:16

Compound No: 18Compound Name: Allyl ChlorideScan Number: 359Retention Time: 6.21 minQuant Ion: 41.0Area: 322793MConcentration: 241.32 UG/Lq-value: 77 ,


flR302900

File >HJJI5 VST0200 200 PPB IC~CfiZ 9UL ZC "i +CE05.X 15 +5 Scan 920Bpk Pb 31944.

J 43

30000;

20000̂

10000;

'1

Jill

r

55 i

i ,fl. .̂ .......

12.77 Min.

59

8575 V 86 1°° Ifi3X \ ~f " / 110 119 v

i... .,,...>..... ..l

File >HJJI5 VSTD200 200 PPB IC~CflZ 9HL ZC -1 +CE05X 15 *5 Scan 1259Bpk flb 86664. 16.74 Min.

80000-

60000-

40000-

20000;

0-

174

75- rr 68\[ ft 117 143155iiii..iA.i«.i)...I.Aii,..ji M _ **..JL. ,.._ .. ../.... ..f...40 ' ' 80 ' ' ' 120 ' ' ' ' ' iio '

File >HJJI5 94.7-95.7 AMU. £STD200 200

-80000-

-60000-.

4000?

16.74

f \

" I \

201N

' ' ' 266 ' ' ' • ' 240 ' ' ' ' 28

•100

•80

•60

•40

•20

•00

PPB IC~CflZ (JML ZC =1 -t-CEOSX 1

^ ——— ——— ̂_' is'.so ' ie'.eb ' iel^b" "is'.eo '" "ifilsb" '"i/'.bb"1

-100.•80••60

140

•0

Data File: >HJJI5 Quant Output File: AHJJI5Name: USTD200 200 PPB 1C Instrument ID: HP03974Misc: ~CAZ §WL XC -1 *CE05X 8,5 *5Quant Time: 950119 22:08 Quant ID File: IA5824Injected at: 950119 21:39 Last Calibration: 950119 01:16

Compound No: 77Compound Name: 4-Bromofluorobenzene <Scan Number: 1259Retention Time: 16.74 minQuant Ion: 95.0Area: 348504MConcentration: 183.34 UG/Lq-value: 94


AR302902

7AVOLATILE CONTINUING CALIBRATION CHECK

Lab Name: LANCASTER LABS Contract: ____.

Lab Code: LANCAS Case No.: ____. SAS No.: ____. SDG No.:

Instrument ID: HP03973 Calibration Date: 01/25/95 Time: 2022

Lab File ID: >KTOS3 Init. Calib. Date(s): 01/25/95 01/25/95

Heated Purge: (Y/N) N Init. Calib. Times: 0653 0918

GC Column: DB624 ID: 0.53(mm)

COMPOUND

ChloromethaneVinyl ChlorideBromomethane •Chl or oethane1 , 1-DichloroetheneAcetoneCarbon DisulfideMethylene Chloride1 , 2 -Dichloroethene ( total )1, 1-Dichloroe thane2-ButanoneChloroform1, 2-Dichloroethane1,1, 1-TrichloroethaneCarbon TetrachlorideBenzeneTrichloroethene1, 2-DichloropropaneBromodichloromethanecis-1, 3-Dichloropropenetrans-1, 3-Dichloropropene1,1, 2-TrichloroethaneDibromochloromethaneBromoform4 -Methyl -2 -PentanoneTolueneTetrachloroethene2-HexanoneChlorobenzeneEthylbenzeneXylene (total)Styrene

RRF.607.775

1.235.514

1.007.193

2.0021.0271.1172.078.219

3.2412.100.777.805.633.457.301.907.533.516.342.925.765.250.991.650.161.929.373.451.804

RRF 50

.561

.6811.168.467.779.2101.711.900.954

1.766.235

2.9302.004.724.752.541.406.269.888.503.486.336.936.818.249.879.552.158.854.333.406.749

MINRRF

0.1000.100

0.100

0.200

0.2000.1000.1000.1000.5000.300

0.2000.2000.1000.1000.1000.100

0.4000.200

0.5000.1000.3000.300


Name: LANCASTER LABS Contract: ____.

Lab Code: LANCAS Case No.: ___. SAS No.: ___. SDG No.: ___.Instrument ID: HP03973 Calibration Date: 01/25/95 Time: 2022

Lab File ID: >KJOS3 Init. Calib. Date(s): 01/25/95 01/25/95Heated Purge: (Y/N) N Init. Calib. Times: 0653 0918

GC Column: DB624 ID: 0.53(mm)

COMPOUND

1,1,2, 2-Tetrachloroethane1, 2-Dichloroethane-d4Toluene-d84 -Bromof luorobenzene

RRF

.645

1.7391.077.808

RRF 50

.641

1.8431.113.832

MINRRF

0.500

0.200

%D

.7

-6.0-3.3-3.0

MAX%D

25.0

25.0

All other compounds must meet a minimum RRF of 0.010.

page 2 of 2 FORM VII VGA 3/90

•' 245

AR302901*

TOTPL ION CHROMfiTOBRPM

70000;

60000-

50000-

4000O;

30000-

20000-

10000-

File >KJOS3 35.0-300.0 amu. V8TD050 50 PPB CC ~CflZ tSM XC -1 +DXTIC

.4PQ.100000;

90000:

10 12 14 16 18 20 22

Data File: >KJOS3::D3 Quant Output File: ^KJOS3::D7Name: USTD050 50 PPB CC Instrument ID: HP03973Misc: ~CAZ §SM XC -1 +DX



246

AR302905

^̂ Opi

QUANT REPORT Page

perator ID: USER2 Quant Rev: 7 Quant Time: 950125 20:53Output File: ">KJOS3::D7 Injected at: 950125 20:22Data File: >KJOS3::D3 Dilution Factor: 1.00000Name: USTD050 50 PPB CC Instrument ID: HP03973Misc: -CAZ §SM XC -1 +DX

ID File: IA8390::DBTitle: 3/90 SOU Uater/Med Soil ID File for Inst. HP03973Last Calibration: 910114 09:42 Last Qcal' Time: 950125 08:05


1) *Bromochloromethane 9.37 128.0 15620 50.00 UGxL 872) Chloromethane 3.10 50.0 8768 45.18 UG/L 953) Uinyl Chloride 3.33 62.0 10643 41.76 UG/L 954) Bromomethane 3.89 94.0 18241 45.85 UG/L 945) Chloroethane 4.08 64.0 7290 42.38 UG/L 986) 1,1-Dichloroethene 5.74 96.0 12162 38.55 UG/L 897) Acetone 5.88 43.0 3278M 51.05 UG/L 978) Carbon Disulfide 6.17 76.0 26729 42.71 UG/L 1009) Methylene Chloride 6.74 84.0 14063 45.30 UG/L 900) trans-l,2-Dichloroethene 7.26 96.0 14210 41.03 UG/L 89

1,1-Dichloroethane 8.01 63.0 27583 43.17 UG/L 97cis-l,2-Dichloroethene 8.99 96.0 15602 45.05 UG/L 972-Butanone 9.03 43.0 3667 48.36 UG/L 88Chloroform 9.51 83.0 45769 44.81 UG/L 96l,2-Dichloroethane-d4 10.26 65.0 28789 51.25 UG/L 82l>2-Dichloroethane 10.38 62.0 31304 47.49 UG/L 95

»l,4-Difluorobenzene 10.93 114.0 55633 50.00 UG/L 951,1,1-Trichloroethane 9.79 97.0 40303 45.54 UG/L 95Carbon Tetrachloride 10.05 117.0 41810 44.53 UG/L 95Benzene 10.35 78.0 30097 42.64 UG/L 88Trichloroethene 11.32 130.0 22561 43.58 UG/L 891,2-Dichloropropane 11.64 63.0 14940 43.49 UG/L 96Bromodichloromethane 12.04 83.0 49413 47.64 UG/L 97cis-1,3-Dichloropropene 12.69 75.0 28011 45.99 UG/L 89trans-1,3-Dichloropropene 13.49 75.0 10268 16.59 UG/L 901,1,2-Trichloroethane 13.75 97.0 18683 46.20 UG/L 97Dibromochloromethane 14.32 129.0 52069 48.45 UG/L 97Bromoform 16.39 173.0 45495 48.23 UG/L 97

*Chlorobenzene-d5 15.16 117.0 44048 50.00 UG/L 904-Methyl-2-Pentanone 12.90 43.0 10961 46.91 UG/L 92Toluene-d8 13.08 98.0 49027 50.65 UG/L 96Toluene 13.19 91.0 38714 44.00 UG/L 98Tetrachloroethene 13.97 164.0 24299 43.52 UG/L 882-Hexanone 14.10 43.0 6966 43.98 UG/L 98Chlorobenzene 15.21 112.0 37618 45.74 UG/L 91Ethylbenzene 15.35 106.0 14676 43.77 UG/L 97m+p-Xylene 15.53 106.0 37143 93.06 UG/L 97

«o-Xylene 16.10 106.0 17895 44.83 UG/L 94Styrene 16.13 104.0 32980 45.79 UG/L 834-Bromofluorobenzene 16.88 95.0 36660 49.57 UG/L 89

2

AR302906

QUANT REPORT Page 2

Operator ID: USER2 Quant Rev: 7 Quant Time: 950125 20:53Output File: ">KJOS3::D7 Injected at: 950125 20:22Data File: >KJOS3::D3 Dilution Factor: 1.00000Name: USTD050 50 PPB CC Instrument ID: HP03973Misc: ~CAZ §SM XC -1 +DX




* Compound is ISTD

248AR302907

VSTD050 50 PPB CC "CAZ.iSM XC "1 +OX

2500i '« ^•30aooo- ^

1500-

1000-

. ...-..... ... . ...... ... . , ....... ..............40 '' 60 ''"" 80 100 "' " 120 140 '" 160 180

*•

;

85

43 50 / 83

1 .1 III, ,.|Jj, \ ill. till.

m *•t

151

"̂ 119 132

! |l!h . ,u!

155

! (1 **' \

File >KJOS3 42.7-43.7 aau. VSTD05Q 50 PPB CC ~CBZ tSrt XC -1 +DXEIP

40«

300-

200-•40

100-

5.60 5.70 5.80 5.90 6.00 6.10 6.80 6.30

Data File: >KJOS3 Quant Output File: ^KJOS3Name: USTD050 50 PPB CC Instrument ID: HP03973Misc: -CAZ §SM XC -1 +DXQuant Time: 950125 20:53 Quant ID File: IA8390Injected at: 950125 20:22 Last Calibration: 910114 09:42

Compound No: 7Compound Name: AcetoneScan Number: 308Retention Time: 5.88 minQuant Ion: 43.0Area: 3278MConcentration: 51.05 UG/Lq-value: 97

This report was produced by QAREA at: 10:08 PM UED., 25 JAN., 1995

V1

AR302908


Lab Name: LANCASTER LABS Contract: ____..


Instrument ID: HP03973 Calibration Date: 01/26/95 Time: 0315Lab File ID: >KJQS3 Init. Calib. Date(s): 01/25/95 01/25/95

Heated Purge: (Y/N) N Init. Calib. Times: 0653 0918GC Column: DB624 ID: 0.53(mm)

COMPOUND

ChloromethaneVinyl ChlorideBromomethaneChloroethane1 , 1-DichloroetheneAcetoneCarbon DisulfideMethyl ene Chloride1 , 2-Dichloroethene (total)1 , 1-Dichloroethane2-ButanoneChloroform1, 2-Dichloroethane1,1, 1-TrichloroethaneCarbon TetrachlorideBenzeneTrichloroethene1, 2-DichloropropaneBromodichloromethanecis-l, 3-Dichloropropenetrans-l, 3-Dichloropropene1,1, 2-TrichloroethaneDibromochloromethaneBromoform4-Methyl-2-.PentanoneTolueneTetrachloroethene2-HexanoneChlorobenzeneEthylbenzeneXylene (total)Styrene

IRT.607.775

1.235.5141.007.1932.0021.0271.1172.078.219

3.2412.100.777.805.633.457.301.907.533.516.342.925.765.250.991.650.161.929.373.451.804

RRF 50

.621

.8201.333.560

1.003.1342.0201.0291.1652.125.2173.3282.115.827.844.645.483.306.950.557.544.350.974.817.219

1.035.669.139.967.389.479.846

MINRRF

0.1000.100

0.100

0.200

0.2000.1000.1000.1000.5000.300

0.2000.2000.1000.1000.1000.100

0.4000.200

0.5000.1000.3000.300

All other compounds must meet a minimum RRF of

%D

-2.4-5.8-8.0-9.0.4

30.4-.9-.2

-4.3-2.31.1

-2.7-.7

-6.4-4.9-1.9-5.6-1.6-4.7-4.4-5.4-2.5-5.3-6.912.2-4.5-2.913.6-4.1-4.4-6.1-5.2

MAX%D

25.025.0

25.0

25.0

25.025.025.025.025.025.0

25.025.025.025.025.025.0

25.025.0

25.025.025.025.0

3.010.

page 1 of 2 FORM VII VOA 3/90

250

AR302909


Lab Name: LANCASTER LABS Contract:Lab Code: LANCAS Case No.: ____. SAS No.: ____. SDG No.:



COMPOUND

1,1,2, 2-Tetrachloroethane1, 2-Dichloroethane-d4Toluene-d84-Bromof luorobenzene

RRF

.645

1.7391.077.808

RRF 50

.643

1.8221.151.852

All other compounds must meet a minimum RIpage 2 of 2 FORM VII VOA

MINRRF

0.500

0.200

IF of 1

%D

.2

-4.8-6.9-5.5

MAX%D

25.0

25.0

).010.

3/90

51

AR3Q29IO

TOTflL ION CHROMRTOSRfiMFilm >KJQS3 38.0-300.0 AMU. VSTDOBO 50 PPB CC TSS Tisn ZC -1+DX

4pQ } 800

140000-

120000-

100000-

80000-

6000O-

40000-

20000-

Data File: >KJQS3::D3 Quant Output File: "KJQS3::D7Name: USTD050 50 PPB CC Instrument ID: HP03973Misc: -TSS §SM XC -1 +DX



252

AR3029U-

QUANT REPORT Page 1

Operator ID: USER2 Quant Rev: 7 Quant Time: 950126 03:43Output File: /XKJQS3::D7 Injected at: 950126 03:15Data File: >KJQS3::D3 Dilution Factor: 1.00000Name: USTD050 50 PPB CC Instrument ID: HP03973Misc: -TSS §SM XC -1 +DX



1) *Bromochloromethane 9.37 128.0 22142 50.00 UG/L 892) Chloromethane 3.13 50.0 13759 54.50 UG/L 933) Uinyl Chloride 3.38 62.0 18161 53.30 UG/L 984) Bromomethane 3.91 94.0 29520 52.90 UG/L 995) Chloroethane 4.12 64.0 12401 53.48 UG/L 956) 1,1-Dichloroethene 5.76 96.0 22211 50.11 UG/L 957) Acetone 5.92 43.0 2975 36.99 UG/L 678) Carbon Disulfide 6.19 76.0 44735 53.70 UG/L 1009) Methylene Chloride 6.77 84.0 22791 52.60 UG/L 9110) trans-l,2-Dichloroethene 7.28 96.0 25035 50.18 UG/L 9611) 1,1-Dichloroethane 8.03 63.0 47061 51.16 UG/L 9912) cis-l,2-Dichloroethene 9.00 96.0 26537 53.19 UG/L 9213) 2-Butanone 9.04 43.0 4795 57.10 UG/L 9914) Chloroform 9.52 83.0 73697 49.73 UG/L 9415) l,2-Dichloroethane-d4 10.26 65.0 40336 49.48 UG/L 8716) 1,2-Dichloroethane 10.38 62.0 46834 48.47 UG/L 9717) *l,4-Difluorobenzene 10.94 114.0 81622 50.00 UG/L 9418) 1,1,1-Trichloroethane 9.80 97.0 67498 49.06 UG/L 9419) Carbon Tetrachloride 10.05 117.0 68920 47.86 UG/L 9620) Benzene 10.37 78.0 52671 53.63 UG/L 8721) Trichloroethene 11.33 130.0 39405 52.91 UG/L 9422) 1,2-DichIoropropane 11.66 63.0 24952 52.70 UG/L 9823) Bromodichloromethane 12.06 83.0 77510 50.02 UG/L 9624) cis-1,3-Dichloropropene 12.70 75.0 45426 53.27 UG/L . 8925) trans-1,3-Dichloropropene 13.50 75.0 16863 20.29 UG/L 9326) 1,1,2-Trichloroethane 13.75 97.0 28606 52.88 UG/L 9727) Dibromochloromethane 14.34 129.0 79531 50.12 UG/L 9728) Bromoform . 16.42 173.0 66724 49.39 UG/L 9729) *Chlorobenzene-d5 15.18 117.0 64583 50.00 UG/L 9230) 4-Methyl-2-Pentanone 12.92 43.0 14168 49.14 UG/L 9331) Toluene-d8 13.10 98.0 74348 52.97 UG/L 9132) Toluene 13.19 91.0 66860 52.16 UG/L 9833) Tetrachloroethene 13.99 164.0 43198 51.66 UG/L 9334) 2-Hexanone 14.12 43.0 8986 42.88 UG/L 9635) Chlorobenzene 15.22 112.0 62440 52.10 UG/L 9036) Ethylbenzene 15.37106.0 25146 52.40 UG/L 9637) m+o-Xylene 15.54106.0 62756 107.89Ufi/l. 9638) o-Xylene 16.12 106.0 30903 , 53.13 USAO 9339) Styrene 16.13 104.0 54614 51.54 UG/L 8240) 4-Bromofluorobenzene 16.88 95.0 55035 51.52 UG/L 90

AR3029I2

QUANT REPORT Page 2- - v

Operator ID: USER2 Quant Rev: 7 Quant Time: 950126 03:43Output File: "KJQS3::D7 Injected at: 950126 03:15Data File: >KJQS3::D3 Dilution Factor: 1.00000Name: USTD050 50 PPB CC Instrument ID: HP03973Misc: -TSS §SM XC -1 +DX




* Compound is ISTD

. 854

A.R3029I3


Lab Name: LANCASTER LABS Contract:

Lab Code: LANCAS Case No.: ____. SAS No.: ____. SDG No.: ____.



COMPOUND

ChloromethaneVinyl ChlorideBromomethaneChl or oethane1, 1-DichloroetheneAcetoneCarbon Disulfide -Methylene Chloride1 , 2 -Dichloroethene ( total )1, 1-Dichloroethane2-ButanoneChloroform1 , 2 -Dichlor oethane1,1, 1-TrichloroethaneCarbon TetrachlorideBenzeneTrichloroethene1 , 2-DichloropropaneBromodichloromethanecis-l, 3-Dichloropropenetrans-1, 3-Dichloropropene1,1, 2-TrichloroethaneDibromochloromethaneBromoform4 -Methyl -2 -PentanoneTolueneTetrachloroethene2-HexanoneChlorobenz eneEthylbenzeneXylene (total)Styrene

RRF

.607

.7751.235. .5141.007.1932.0021.0271.1172.078.219

3.2412.100.777.805.633.457.301.907.533.516.342.925.765.250.991.650.161.929.373.451.804

RRF 50

.502

.6491.174.453.822.2251.4481.0421.0792.093.191

3.6212.287.896.858.625.457.301

1.038.598.586.366

1.062.846.2351.030.605.140.953.393.486.852

MINRRF

0.1000.100

0.100

0.200

0.2000.1000.1000.1000.5000.300

0.2000.2000.1000.1000.1000.100

0.4000.200

0.5000.1000.3000.300

All other compounds must meet a minimum RRF of (

%D

17.416.34.911.918.4-16.527.7-1.53.4-.712.7-11.7-8.9-15.4-6.61.3-.1-.0

-14.4-12.1-13.6-6.9-14.8-10.66.1

-3.97.0

13.3-2.5-5.4-7.7-6.0

MAX%D

25.025.0

25.0

25.0

25.025.025.025.025.025.0

25.025.025.025.025.025.0

25.025.0

25.025.025.025.0

).010.

page 1 of 2 FORM VII VOA 3/90

1R3029H. 255


Lab Name: LANCASTER LABS Contract: ____.


Instrument ID: HP03973 Calibration Date: 01/26/95 Time: 1538\

Lab File ID: >KJQS4 Init. Calib. Date(s): 01/25/95 01/25/95


COMPOUND

1,1,2, 2-Tetrachloroethane1 , 2-Dichloroethane-d4Toluene-dS4 -Bromof luorobenzene

RRF

.645

1.7391.077.808

RRF 50

.676

2.0221.105.844

All other compounds must meet a minimum RIpage 2 of 2 FORM VII VOA

MINRRF

0.500

0.200

IF. Of i

%D

-4.8

-16.3-2.6-4.5

MAX%D

25. 0

25.0

.0 .

3/90

256

AR3029I5

TOTRL TON CHROMRTOSRPMFilm >KJQS4 36.0-300.0 **u. VSTD050 0̂ PPB CC "RCR 9SH ZC *1 +DX

8pO 100 1600

4 ' ' 6 ' k ' 1*0 ' IS' ' 14 ' 'l6' ' 'l8 ' &Q ' 'g'a

Data File: >KJQS4::D3 Quant Output File: /SKJQS4::D7Name: USTD050 50 PPB CC Instrument ID: HP03973Misc: ~RCR gSM XC -1 +DX



357

flR3029!6

QUANT REPORT Page 1

Operator ID: USER1 Quant Rev: 7 Quant Time: 950126 16:06Output File: AKJQS4::D7 Injected at: 950126 15:38Data File: >KJQS4::D3 Dilution Factor: 1.00000Name: USTD050 50 PPB CC Instrument ID: HP03973Misc: ~RCR @SM XC -1 +DX

ID File: IAS390::DBTitle: 3/90 SOU Uater/Med Soil ID File for Inst. HP03973Last Calibration: 910114 09:42 Last Qcal Time: 950126 03:15


1) *Bromochloromethane 9.38 128.0 18426 50.00 UG/L 852) Chloromethane 3.11 50.0 9242 40.36 UG/L 993) Uinyl Chloride 3.38 62.0 11954 39.55 UG/L 964) Bromomethane 3.90 94.0 21641 44.05 UG/L 925) Chloroethane 4.06 64.0 8344 40.43 UG/L 996) 1,1-Dichloroethene 5.75 96.0 15137 40.95 UG/L 897) Acetone 5.90 43.0 4144 83.69 UG/L 698) Carbon Disulfide 6.18 76.0 26672 35.82 UG/L 1009) Methylene Chloride 6.74 84.0 19209 50.64 UG/L 9410) trans-l,2-Dichloroethene 7.27 96.0 17392 40.52 UG/L 96It) l,l-Si..l-,!.jroi3thane 8.02 63.0 38558 49.23 UG/L 9912) cis-1,2-Dichloroethene 9.00 96.0 22389 52.17 UG/L 9513) 2-Butanone 9.07 43.0 3524M 44.16 UG/L 9814) Chloroform 9.52 83.0 66715 54.39 UG/L 9815) l,2-Dichloroethane-d4 10.27 65.0 37254 55.49 UG/L 8216) 1,2-Dichloroethane 10.39 62.0 42144 54.07 UG/L 9817) *l,4-Difluorobenzene 10.94 114.0 69332 50.00 UG/L 9318) 1,1,1-Trichloroethane 9.80 97.0 62154 54.20 UG/L 9419) Carbon Tetrachloride 10.06 117.0 59485 50.80 UG/L 9620) Benzene 10.36 78.0 43333 48.43 UG/L 8621) Trichloroethene 11.32 130.0 31704 47.36 UG/L 9222) 1,2-Dichloropropane 11.65 63.0 20873 49.24 UG/L 9623) Bromodichloromethane 12.05 83.0 71944 54.64 UG/L 9724) cis-1,3-Dichloropropene 12.70 75.0 41429 53.68 UG/L 8825) trans-l,3-Dichloropropena 13.49 75.0 15450 20.49 UG/L 9026) 1,1,2-Trichloroethane 13.75 97.0 25342 52.15 UG/L 9627) Dibromochloromethane 14.33 129.0 73602 54.47 UG/L 9728) Bromoform 16.42 173.0 58663 51.75 UG/L 9829) *Chlorobenzene-d5 15.18 117.0 55248 50.00 UG/L 8830) 4-Methyl-2-Pentanone 12.92 43.0 12971. 53.51 UG/L 9431) Toluene-d8 13.09 98.0 61060 48.00 UG/L 9532) Toluene 13.18 91.0 56902 49.74 UG/L 9833) Tetrachloroethene 13.97 164.0 33400 45.19 UG/L 9434) 2-Hexanone 14.11 43.0 7712 50.16 UG/L 9935) Chlorobenzene 15.21 112.0 52629 49.26 UG/L 8936) Ethylbenzene 15.36 106.0 21720 50.49 UG/L 9637) m+p-Xylene 15.53 106.0 52806 99.87 UG/L 9538) o-Xylene 16.11 106.0 26842 50.77 UG/L 9439) Styrene 16.14 104.0 47094 50.40 UG/L 8140) 4-Bromofluorobenzene 16.89 95.0 46656 49.55

AR3029I7

QUANT REPORT Page 2

Operator ID: USER1 Quant Rev: 7 Quant Time: 950126 16:06Output File: ~KJQS4::D7 Injected at: 950126 15:38Data File: >KJQS4::D3 Dilution Factor: 1.00000Name: USTD050 50 PPB CC Instrument ID: HP03973Misc: -RCR §SM XC -1 +DX




* Compound is ISTD

359

ftR3029!8

Fil« >KJQ64 VSTD050 60 PPB CC ~RCR »St1 XC "1 +DX Scan 688Bpk flb 1100. 9.07 »in.

•100

-80800-

.**•» /-6043

,J

t

,

1, ,

96/

*x>400-

i-20

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flR3Q2850 · 2020. 11. 16. · Film >KJPI4 48.7-43.7 a»U. VSTPUIO O1O PPB IC~TSS 9SH XC -X +D...

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