Filed operation of a CO2 flood

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    4-Jan-06 1TRIMERIC CORPORATION

    www.trimeric.com

    Ken McIntush, 830 643 4553, [email protected]

    Kevin Fisher, 512 431 6323, [email protected]

    Joe Lundeen, 512 658 6313, [email protected]

    Presented by Joe Lundeen

    TRIMERIC CORPORATION

    Field Operations of aCO2 Flood

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    Outline EOR Operations Overview

    Unique CO2 Characteristics Production Facility Discussion

    Process Equipment Highlights

    Operational Considerations

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    Gas/Oil

    Separation SRU Dehydration

    NGLRecovery

    SRU$ Oil $

    $ NGL $

    CO2

    PurchasedCO2

    Production Injection

    $ Residue (Sales Gas) $

    Gas Processing Steps at

    Production Facility

    Gas processing stepsdepend on OIL qualities

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    EOR Upstream Operations Overview CO2 Source

    Naturally Occurring Reservoir

    Industrial Source

    Gas Processing Dehydration

    Liquid Desiccant Process Solid Desiccant Process

    Contaminant Removal

    EOR CO2 (limited)

    Food-grade CO2 (complete)

    Transportation Pipeline / Truck / Rail

    Meter Facility

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    Primary EOR Operations Overview EOR Production Facility (Oil/Gas)

    CO2 Recycle

    Gas / Liquid / Liquid Separation

    Oil Recovery

    CO2 Recycle / Compression

    NGL Recovery Residue gas cleanup

    Injection wells Compress / pump CO2 into formation

    Production wells Flow into test facility

    Use of corrosion inhibitors common

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    CO2 Characteristics Exists as gas, liquid, and dense phase at

    EOR conditions Critical pressure: 1,070 psia

    Water solubility in CO2 has a V-shape,

    minimum occurs at ~850 psi Some compounds (glycol, glycerol, etc.)

    have higher solubility in CO2 at lower

    temps Acts similar to a solvent in the reservoir,

    good affinity for hydrocarbon

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    Production Facility Complexity Permian Basin CO2 Flood

    Light crude oil

    Recycle CO2 has significant HCs

    Lighter HCs are soluble in CO2 More gas processing required

    NGL recovery (Ryan-Holmes, Refrigeration, etc.) Residue gas clean-up (CO2, H2S, N2, etc.)

    Mississippi CO2 Flood

    Heavy crude oil

    Recycle CO2 has only about 5% methane

    Main facility operations consist of separation andcompression

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    EOR Production Flow Diagram

    Production /

    CO2 Response

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    Process Equipment Highlights All process equipment is common to NG industry

    There is often a choice of compression or pumping CO2 to

    pressure when super-critical Recycle gas is typically compression Pumps are preferred if CO2 is a dense gas submersible or PD type

    (i.e., triplex)

    Vents from low pressure separators may require vapor recovery

    Dehydration process choice will depend on requirement to removeNGLs

    Common CO2 metering methods are orifice plate and coriolismeters; if orifice plate, very important to know fluid propertiesaccurately

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    Operational Considerations

    Industry and Field Observations Effect of supercritical CO2 on operations

    Phase change on level instrumentation Water solubility Solubility of compounds (i.e., glycol)

    Material selection Corrosion inhibitors SS vs. CS vs. coatings

    Dehydration methods Liquid and solid desiccants Compression from intermediate pressure (i.e., 850 psig)

    Emulsions in the produced oil Possibly due to presence of corrosion inhibitors

    Heat added to break emulsions Health & Safety Hazards

    Heavier than air Suffocates or asphyxiates at lower concentrations than other

    asphyxiants (more dangerous than other asphyxiants)

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    Questions_____________________________

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